FIITJEE – Phase Test (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

CPT-1 CODE: SET: A PAPER - 2

(PHASE – III)

Time Allotted: 3 Hours Maximum Marks: 183

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
BATCHES – CTY 2022

3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.

4. All the section can be filled in PART-A of OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For Part - A.

(i) Part-A (01-07) - Contains seven (07) multiple choice questions which have One or More correct answer.
Full Marks: +4 if only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 for darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks: 0 if none of the bubbles is darkened.
Negative Marks: 1 in all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B)
will result in 1 mark, as a wrong option is also darkened.
(ii) Part-A (08-14) - Contains seven (07) multiple choice questions which have Only One correct
answer. Each question carries +3 marks for correct answer and -1 mark for wrong answer.
(iii) Part-A (15-18) - This section contains Two Paragraphs. Based on each paragraph, there are Two
multiple choice questions. Each question has only one correct answer and carries +3 marks for the
correct answer and -1 mark for wrong answer.

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination : __________________

Enrolment Number :__________________________________________________

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P2

USEFUL DATA
PHYSICS CHEMISTRY
2
Acceleration due to gravity : g = 10 m/s 1 1
Gas Constant R = 8.314 J K mol
34
Planck constant : h = 6.6  10 J  s = 0.0821 Lit atm
19 1 1
Charge of electron : e = 1.6  10 C K mol
Mass of electron : me  9.1  10
31
kg
= 1.987  2 Cal
1 1
12 2 2 K mol
Permittivity of free space :  0  8.85  10 C /N m
Avogadro’s Number Na = 6.023  1023
: water  10 kg / m
3 3
Density of water
34
5 2 Planck’s constant h = 6.625 10 J .s
Atmospheric pressure : Pa  10 N / m 27
Gas constant : R = 8.314 J = 6.625 10 erg .s
1 Faraday = 96500 coulomb
K 1 mol 1 1 calorie = 4.2 joule
27
1 amu = 1.66 10 kg
19
1 eV = 1.6  10 J
Atomic No: H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9, Ne = 10, Na = 11,
Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18, K = 19, Ca = 20,
Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29, Zn = 30, As = 33, Br = 35,
Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92.

Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,

Mg = 24, Si = 28, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Co= 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
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 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P3

Section – I Physics
PART – A
(Multi Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE THAN ONE is/are correct.

1.
@QS
A simple pendulum consists of a bob of mass m and a light string of length  as shown in figure.
Another identical ball moving with the small velocity v 0 collides with the pendulum’s bob and sticks to it.
For this new pendulum of mass 2m, choose the correct statement(s):

v0 m

(A) Time period of the pendulum is 2  / g

(B) Time period of the pendulum is 2 2 / g
v0  g
(C) The equation of motion for this pendulum is   sin   t
2 g   
v0  g
(D) The equation of motion for this pendulum is   cos   t
2 g   
@QE
@TagS
QT:MCO,
CA:AC,
CC:P111107,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

2.
@QS
A solid sphere of radius R and density  is attached to one end of a mass-less spring of force constant
k. The other end of the spring is connected to another solid sphere of radius R and density 3 . The
complete arrangement is placed in a liquid of density 2 and is allowed to reach equilibrium. The
correct statement(s) is (are)
4 R 3  g
(A) the net elongation of the spring is
3k
8 R3  g
(B) the net elongation of the spring is
3k
(C) the light sphere is partially submerged.
(D) the light sphere is completely submerged.
@QE
@TagS
QT:MCO,
CA:AD,

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
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FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P4

CC:P111106,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

3.
@QS
An ideal gas can be expanded from an initial state to a certain volume through two different processes:
2 2
(i) PV = constant and (ii) P = KV , where K is a positive constant. Then,
(A) Final temperature in (i) will be greater than in (ii)
(B) Final temperature in (ii) will be greater than in (i)
(C) Total heat given to the gas in (i) case is greater than in (ii)
(D) Total heat given to the gas in (ii) case is greater than in (i)
@QE
@TagS
QT:MCO,
CA:BD,
CC:P111213,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

4.
@QS
‘n’ moles of an ideal gas undergoes a process A  B as shown in the figure. The maximum
temperature of the gas during the process will be:
P

2 P0 A

P0 B

V
V0 2V 0
9P0 V0 3P0 V0
(A) (B)
4nR 2nR
9P0 V0 9P0 V0
(C) (D)
2nR nR
@QE
@TagS
QT:MCO,
CA:A,
CC:P111212,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

5.
@QS
A uniform bar of length 6a and mass 8m lies on a smooth horizontal table. Two point masses m and 2m
moving in the same horizontal plane with speeds 2v and v, respectively, strike the bar (as shown in the

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 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P5

figure) and stick to the bar after collision. Denoting angular velocity (about the centre of mass), total
energy and centre of mass velocity by , E and Vc , respectively, we have after collision

v 2m
3a
C

a 2a

m 2v

3v
(A) Vc  0 (B)  
5a
v 3mv 2
(C)   (D) E 
5a 5
@QE
@TagS
QT:MCO,
CA:ACD,
CC:P110720,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

6.
@QS

The position vector r of a particle of mass m is given by the following equation
 10
r  t   t 3i   t 2 ˆj , where   ms 3 ,   5 ms 2 and m = 0.1 kg . At t = 1 s, which of the following
3
statement(s) is (are) true?
 
(A) The velocity 
v is given by v  10iˆ  10 ˆj ms 1 
  5 ˆ
(B) The angular momentum L with respect to the origin is given by L     k Nms
3
 
(C) The force F is given by 
F  iˆ  2 ˆj N 
   20 
(D) The torque  with respect to the origin is given by      kˆ Nm
 3 
@QE
@TagS
QT:MCO,
CA:ABD,
CC:P110713,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

7.
@QS
Two blocks A and B, each of mass m, are connected by a massless spring of natural length L and
spring constant k. The blocks are initially resting on a smooth horizontal floor with the spring at its

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FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P6

natural length as shown in the figure. A third identical block C, also of mass m, moves on the floor with
a speed v along the line joining A and B and collides elastically with A, then
v L
C A B

(A) The KE of the AB system at maximum compression of the spring is zero.

(B) The KE of the AB system at maximum compression of the spring is 1/ 4  mv2 .
m
(C) The maximum compression of the spring is . v
k
m
(D) The maximum compression of the spring is v
2k
@QE
@TagS
QT:MCO,
CA:BD,
CC:P111106,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

PART – A
(Single Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

8.
@QS
If the maximum speed of a particle on a travelling wave is v0, then find the speed of the particle when
the displacement is half of the maximum value.
v 3v 0
(A) 0 (B)
2 4
3v 0
(C) (D) v 0
2
@QE
@TagS
QT:SCO,
CA:C,
CC:P111305,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

9.
@QS
A rope of mass m0 and length L is suspended vertically. If a mass m is suspended from the bottom of
the rope, find the time for a transverse wave to travel the length of the rope.

(A) 2
L
m0 g

m0  m  m  (B)
L
m0 g

m0  m  m 
(C)
L
2m0 g
 m0  m  m  (D) None of these

@QE
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
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 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P7

@TagS
QT:SCO,
CA:A,
CC:P111303,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

10.
@QS
A metal rod of length 1 m is clamped at two points as shown in figure. Distance of the clamps from two
ends are 5 cm and 15 cm respectively. Find the minimum frequency of natural longitudinal oscillations
11
of the rod. Given that, Young’s modulus and density of the material of the rod are Y = 1.6 × 10 Pa and
–3
 = 2500 kgm respectively.
Clamped Clamped

5 cm 80cm 15cm

(A) 30 kHz (B) 40 kHz

(C) 50 kHz (D) 25 kHz
@QE
@TagS
QT:SCO,
CA:B,
CC:P111310,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

11.
@QS
A block is partially immersed in a liquid and the vessel is accelerating upwards with an acceleration “a”.
The block is observed by two observers O1 and O2, one at rest and the other accelerating with an
acceleration “a” upward. The total buoyant force on the block is:

a
a O2

O1 At rest

(A) same for O1 and O2 (B) greater for O1 than O2

(C) greater for O2 than O1 (D) data is not sufficient
@QE
@TagS
QT:SCO,
CA:A,
CC:P111019,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

12.
@QS
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
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FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P8

On heating water, bubbles being formed at the bottom of the vessel detach and rise. Take the bubbles
to be spheres of radius R and making a circular contact of radius r with the bottom of the vessel. If
r  R and the surface tension of water is T, the value of r just before bubbles detach is (density of
water is pw )

2r

pw g 3 pw g
(A) R2 (B) R2
T T
2 pw g pw g
(C) R2 (D) R2
3T 3T
@QE
@TagS
QT:SCO,
CA:C,
CC:P111030,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

13.
@QS
A fixed mass of a gas is taken through a process A  B  C  A (as shown in the figure). Here
A  B is isobaric. B  C is adiabatic and C  A is isothermal. Find efficiency of the process (take
  1.5)
P
A B
P0

V
V0 4V 0

 3  2 In2   3  2 In2 
(A)  % (B)  %
 2   3 
 3  2 In2   2  In2 
(C)  % (D)  %
 3   3 
@QE
@TagS
QT:SCO,
CA:C,
CC:P111213,

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
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 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P9

FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

14.
@QS
Three masses 700 gm, 500 gm, 400 gm are suspended at the end of a spring and are in equilibrium.
When 700 gm mass is removed, the system oscillates with a period of 3 seconds. When 500 gm is
also removed, it will now oscillate with a period of
(A) 1 sec (B) 2 sec
12
(C) 3 sec (D) sec
5
@QE
@TagS
QT:SCO,
CA:B,
CC:P111105,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

PART – A
(Paragraph Type)
This part contains 4 multiple choice questions relating to two paragraphs with two questions on each
paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 15 & 16

The friction coefficient between the two blocks shown in figure is . The horizontal plane is smooth. The system
is slightly displaced and released. The system executes S.H.M.

m
k
M

15.
@QS
Find the magnitude of frictional force between the blocks when displacement from mean position is x.
mkx Mkx
(A) (B)
Mm Mm
kx kx
(C) (D)
Mm Mm
@QE
@TagS
QT:COM,
CA:A,
CC:P111105,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

16.
@QS

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FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P10

What can be the maximum amplitude if the upper block does not slip relative to lower block?
(M  m)g (M  m)g
(A) (B)
k k
Mg mg
(C) (D)
k k
@QE
@TagS
QT:COM,
CA:A,
CC:P111105,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

Paragraph for Questions 17 & 18

A ball at rest does not disturb the molecules close to it and vice-versa. When the molecules of air above the ball
are given sufficiently larger velocity, there exists a pressure difference between points above and below the
ball. This may cause the lifting of the ball according to Magnus effect – a result under Bernoulli’s energy
conservation. Use this idea in the given situation and answer the following questions:
r

A light ball A made of plastic is placed in a glass funnel.

17.
@QS
The pressure at M and N are PM and PN. They are best related by
(A) PM  PN  mg (B) PN  PM  2mgr
(C) PM  PN (D) May Be (A) or (B)
@QE
@TagS
QT:COM,
CA:C,
CC:P111010,
FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

18.
@QS
When you hold the funnel in your hand and blow fast above the ball, then the ball
(A) Remains at rest (B) Gets pressed against the funnel
(C) Gets lifted (D) Gets into rotational motion
@QE
@TagS
QT:COM,
CA:C,
CC:P111010,
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 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P11

FACID:PAMD,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
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FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P12

Section – II Chemistry
PART – A
(Multi Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE THAN ONE is/are correct.

1.
@QS
O
||
CH3  C CH  CH  CH3 can show
(A) tautomerism (B) geometrical isomerism
(C) position isomerism (D) functional isomerism
@QE
@TagS
QT:MCO,
CA:ABCD,
CC:C111401,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

2.
@QS
Which of the following alkene(s) do not give different products with HBr?
H3C CH3
(A) But-2-ene (B) C C
H3C CH3

(C) (D)  CH3 2 C  CH2

CH3
@QE
@TagS
QT:MCO,
CA:AB,
CC:C111707,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

3.
@QS
Which of the following is characteristic of carbocation?
(i) it can rearrange to a more stable carbocation
(ii) it can eliminate a proton to form an alkene
(iii) it can add to an alkene to form a new carbocation
(iv) it can abstract a hydride ion to form an alkene
(A) i (B) iii
(C) iv (D) ii
@QE
@TagS
QT:MCO,
CA:ABD,
CC:C111303,
FACID:CPKJ,
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P13

RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

4.
@QS
Correct order of stability of intermediate is/are:

(A) > (B) >

CH 2 CH 2

(C) CCl3 > CF3 (D) <

CH3
CH3
@QE
@TagS
QT:MCO,
CA:AC,
CC:C111303,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

5.
@QS
Consider the following statements regarding the given projection.
CH 2Cl CH 2Cl
H Br Cl H
(W) (X)
Cl H H Cl
CH3 CH3
CH 2Cl
CH3 H Cl
Br H
(Y) (Z)
Cl
H Cl
H CH2Cl
CH 3
(A) W and Y are diastereoisomers (B) Z is the Newmann projection of X
(C) W, X, Y and Z are optically active (D) Y and Z isomers are meso
@QE
@TagS
QT:MCO,
CA:ABC,
CC:C111405,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

6.
@QS

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P14

Which of the following can show tautomerism?

(A) HCN (B) CH3CN
(C) CH3NO2 (D) CH3ONO
@QE
@TagS
QT:MCO,
CA:AC,
CC:C111402,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

7.
@QS
Select correct IUPAC name:
(A) Methane-1,1,1,1,-tetra carboxylic acid (B) 5-carboxy-heptane-1,7-dioic acid
(C) 2-chloro-ethanoyl chloride (D) 1-bromo-3-fluoro-4-methyl cyclohexane
@QE
@TagS
QT:MCO,
CA:AC,
CC:C111304,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

PART – A
(Single Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

8.
@QS
o
In the given information, if C2 is rotated about C2  C3 bond anticlockwise by an angle of 120 , then
the conformation obtained is:
4CH3

H
H
3
2
H
H
1CH3
(A) staggered conformation (B) gauche conformation
(C) fully eclipsed conformation (D) partially eclipsed conformation
@QE
@TagS
QT:SCO,
CA:B,
CC:C111405,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

9.
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P15

@QS
Which is the correct order of stability of carbanion?
(P) F  CH2  CH2  CH2
(Q) O2N  CH2  CH2  CH2
(R) Cl  CH2  CH2  CH2

(S) Me3 N CH2  CH2  CH2
(A) P > R > Q > S (B) S > P > R > Q
(C) S > Q > P > R (D) S > R > P > Q
@QE
@TagS
QT:SCO,
CA:C,
CC:C111301,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

10.
@QS
Which of the following is least acidic?
COOH SO3H

(A) (B)

OH

(C) (D)

@QE
@TagS
QT:SCO,
CA:C,
CC:C111302,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

11.
@QS
Increasing order of stability among the three main conformation (i.e. eclipse, anti, gauche) of ethylene
glycol is
(A) Eclipse, gauche, anti (B) Gauche, eclipse, anti
(C) Eclipse, anti, gauche (D) Anti, gauche, eclipse
@QE
@TagS
QT:SCO,
CA:C,
CC:C111405,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P16

12.
@QS
CH3
H Cl
HO H
C 2H 5
The compound with the above configuration is called
(A) (2S, 3S)-2-chloro-3-pentanol (B) (2S, 3R)-2-chloro-3-pentanol
(C) (2R, 3R)-2-chloro-3-pentanol (D) (2R, 3S)-2-chloro-3-pentanol
@QE
@TagS
QT:SCO,
CA:A,
CC:C111404,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

13.
@QS
Cl

Name of the compound is

(A) 5-chloro-2-ethyl-1-methyl cyclohexane (B) 1-chloro-4-ethyl-3-methyl cyclohexane
(C) 1-ethyl-2-methyl-4-chloro cyclohexane (D) 4-chloro-1-ethyl-2-methyl cyclohexane
@QE
@TagS
QT:SCO,
CA:D,
CC:C111304,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

14.
@QS
OH

The IUPAC name of is:

CH3
(A) 3-methyl cyclobut-1-ene-2-ol (B) 4-methyl cyclobut-2-ene-1-ol
(C) 4-methyl cyclobut-1-ene-3-ol (D) 2-methyl cyclobut-3-ene-1-ol
@QE
@TagS
QT:SCO,
CA:B,
CC:C111304,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P17

@TagE

PART – A
(Paragraph Type)
This part contains 4 multiple choice questions relating to two paragraphs with two questions on each
paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 15 & 16

An unsaturated hydrocarbon (X) contains six carbon atoms. On reductive ozonolysis it forms two moles of
ethanal (CH3CHO) and one mole ethan-1, 2-dial (glyoxal). When treated with acidified KMnO4 solution, a
colourless solution is obtained. Answer the following questions on the basis of above write up.

15.
@QS
How many geometrical isomer(s) is/are possible for compound(X)?
(A) 2 (B) 3
(C) 4 (D) 6
@QE
@TagS
QT:COM,
CA:B,
CC:C111403,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

16.
@QS
How many 1, 2 – addition product(s) is/are possible when compound (X) is treated with HCl in presence
of CCl4? (consider major and minor products and stereoisomers)
(A) 6 (B) 8
(C) 4 (D) 10
@QE
@TagS
QT:COM,
CA:B,
CC:C111707,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

Paragraph for Questions 17 & 18

Conformational isomers are generated due to the free rotation about single bond. Due to torsional strain
eclipsed form is less thermodynamically stable than staggered form. The gauche is specific conformer of
staggered in which bulky groups are oriented closer to one another. Hence, generally gauche form is less stable
than staggered form. But sometimes it is not true when hydrogen bonding is present

17.
@QS
The most stable conformer of 2-fluoro ethanol is

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www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
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FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P18

F
F

H H H OH

(A) (B)
H H H H

OH
H
H F H H
H H OH H OH F
H
(C) (D)

HH HH
HH HH
@QE
@TagS
QT:COM,
CA:B,
CC:C111405,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

18.
@QS
Which of the following conformer is optically active?
CH3
CH3

D H H CH3

(A) (B)
H D H D

CH3 D
CH3
CH3 CH3
H H

(C) (D)
D H H
H
D H
CH3
@QE
@TagS
QT:COM,
CA:B,
CC:C111404,
FACID:CPKJ,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P19

Section – III Mathematics

PART – A
(Multi Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE THAN ONE is/are correct.

1.
@QS
2 2
If z1  z2  z1  | z2 |2 , then
z1 z1
(A) is purely real (B) is purely imaginary
z2 z2
(C) z1 z2  z2 z1  0 (D) z1 z2  z2 z1  0
@QE
@TagS
QT:MCO,
CA:BC,
CC:M110304,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

2.
@QS
If one of the lines given by the equation ax 2  6 xy  by 2  0 bisects the angle between the co-ordinate
axes then value of (a + b) can be :
(A) –6 (B) 3
(C) 6 (D) 12
@QE
@TagS
QT:MCO,
CA:AC,
CC:M110731,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

3.
@QS
x2 y 2
Eccentricity of the hyperbola conjugate to the hyperbola   1 is :
4 12
2
(A) (B) 2
3
4
(C) 3 (D)
3
@QE
@TagS
QT:MCO,
CA:A,
CC:M111103,
FACID:MAKS6,

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P20

RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

4.
@QS
Consider the series 21  18  15  12  ........ If Tn and Sn are nth term and sum of first n terms of
series respectively, then:
(A) T6  T10  0 (B) S5  S10
(C) T5  T9  0 (D) S 4  S11
@QE
@TagS
QT:MCO,
CA:ABD,
CC:M110501,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

5.
@QS
 
If cos  is the geometric mean between sin  and cos , where ,   0,  , then cos 2 is equal
 2
to:
   
(A) 2sin 2     (B) 2 cos 2    
4  4 
2  2 
(C) 2 sin     (D) 2 cos    
4  4 
@QE
@TagS
QT:MCO,
CA:AB,
CC:M110504,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

6.
@QS
If the point P  4, 2  is one end of the focal chord PQ of the parabola y 2  x, then the slope of the
tangent at Q is
(A) 1/ 4 (B) 1/4
(C) 4 (D) –4
@QE
@TagS
QT:MCO,
CA:C,
CC:M110910,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P21

7.
@QS
The number of selections of four letters taken from the word COLLEGE must be
(A) 22
(B) 18
4
(C) coefficient of x in the expansion of 1  x  x  1  x 
2 2 3

in the expansion of 1  x  x  1  x 
4 2 3 2
(D) coefficient of x
@QE
@TagS
QT:MCO,
CA:BC,
CC:M111218;M111221,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:4_1,WM:-1,
@TagE

PART – A
(Single Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

8.
@QS
18 points are indicated on the perimeter of a triangle ABC (see figure). How many triangles are there
with vertices at these points?
A

B C
(A) 331 (B) 408
(C) 710 (D) 711
@QE
@TagS
QT:SCO,
CA:D,
CC:M111221,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

9.
@QS

Number of solution(s) of following equation is : cos 1 1  x   2 cos 1 x 
2
(A) 3 (B) 2
(C) 1 (D) 0
@QE
@TagS

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P22

QT:SCO,
CA:C,
CC:M113559,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

10.
@QS
y-intercept of the common tangent to the parabola y  32 x and x 2  108 y is :
2

(A) –18 (B) –12

(C) –9 (D) –6
@QE
@TagS
QT:SCO,
CA:B,
CC:M110922,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

11.
@QS
y2
 x  3   y  4  
2 2
The eccentricity of the ellipse is :
9
3 1
(A) (B)
2 3
1 1
(C) (D)
3 2 3
@QE
@TagS
QT:SCO,
CA:B,
CC:M111002,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

12.
@QS
1 1 1 1
The sum o o
 o o
 o o
 ....  is equal to:
sin 45 sin 46 sin 47 sin 48 sin 49 sin 50 sin133 sin134o
o

(A) sec 1 (B) cosec 1

o o

cot 1
o
(C) (D) none of these
@QE
@TagS
QT:SCO,
CA:B,
CC:M111302,
FACID:MAKS6,
RELEXAM:P3,
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P23

IU:,
CM:3,WM:-1,
@TagE

13.
@QS
The complex number z satisfies z  | z | 2  8i. The value of z is:
(A) 10 (B) 13
(C) 17 (D) 23
@QE
@TagS
QT:SCO,
CA:C,
CC:M110315,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

14.
@QS
The number of possible straight lines, passing through (2, 3) and forming a triangle with coordinate
axes, whose area is 12 sq. units, is:
(A) one (B) two
(C) three (D) four
@QE
@TagS
QT:SCO,
CA:C,
CC:M110712,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

PART – A
(Paragraph Type)
This part contains 4 multiple choice questions relating to two paragraphs with two questions on each
paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 15 & 16

Let the sides of a triangle are three consecutive integers and the largest angle is twice the smallest. Then

15.
@QS
Perimeter of the triangle is:
(A) 9 (B) 12
(C) 15 (D) 18
@QE
@TagS
QT:COM,
CA:C,
CC:M111502,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P24

16.
@QS
Radius of the circle inscribed in the triangle is:
7 7
(A) (B)
2 4
7
(C) 7 (D)
2
@QE
@TagS
QT:COM,
CA:A,
CC:M111511,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

Paragraph for Questions 17 & 18

Let A, B, C be three sets of real numbers  x, y  defined as

A :  x, y  : y  1
B :  x, y  : x 2  y 2  4 x  2 y  4  0 

C :  x, y  : x  y  2 

17.
@QS
Number of elements in the A  B  C is
(A) 0 (B) 1
(C) 2 (D) infinite
@QE
@TagS
QT:COM,
CA:B,
CC:M110827,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
@TagE

18.
@QS
 x  1   y  1   x  5    y  1
2 2 2 2
has the value equal to
(A) 16 (B) 25
(C) 36 (D) 49
@QE
@TagS
QT:COM,
CA:C,
CC:M110827,
FACID:MAKS6,
RELEXAM:P3,
IU:,
CM:3,WM:-1,
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
 FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P25

@TagE

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
FCT2021-CTY-2022-B-LOT-PH-III-ADV-PCM-2-SET-A - P26

TWO YEAR CRP (CTY - 2022)

BATCHES: B - LOT
PCM (PAPER – II) PHASE - III
PAPER CODE: XXXX.X DATE: DD.MM.YYYY
ANSWER KEYS [SET – A]

SECTION – I (PHYSICS) SECTION – II (CHEMISTRY) SECTION – III (MATHS)

PART - A PART - A PART - A
1. AC P111107 1. ABCD C111401 1. BC M110304
2. AD P111106 2. AB C111707 2. AC M110731
3. BD P111213 3. ABD C111303 3. A M111103
4. A P111212 4. AC C111303 4. ABD M110501
5. ACD P110720 5. ABC C111405 5. AB M110504
6. ABD P110713 6. AC C111402 6. C M110910
7. BD P111106 7. AC C111304 7. BC M111218,
M111221
8. C P111305 8. B C111405 8. D M111221
9. A P111303 9. C C111301 9. C M113559
10. B P111310 10. C C111302 10. B M110922
11. A P111019 11. C C111405 11. B M111002
12. C P111030 12. A C111404 12. B M111302
13. C P111213 13. D C111304 13. C M110315
14. B P111105 14. B C111304 14. C M110712
15. A P111105 15. B C111403 15. C M111502
16. A P111105 16. B C111707 16. A M111511
17. C P111010 17. B C111405 17. B M110827
18. C P111010 18. B C111404 18. C M110827

FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
www.fiitjeelucknow.com
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.