WBJEE

2021 Code

WBJEE (Engineering) : 2021 W

English Version
and
Bengali Version

Max. Marks : 100

Time : 2 Hours

Subjects

1. This question Paper contains only MCQ type objective questions having three categories namely
category-I, category-II and category-III. Each question has four answer options given, viz. A, B, C and D.
2. Category-I : Only one answer is correct. Correct answer will fetch full marks 1. Incorrect answer or any
combination of more than one answer will fetch -¼ marks. No answer will fetch 0 marks.
3. Category-II : Only one answer is correct. Correct answer will fetch full marks 2. Incorrect answer or any
combination of more than one answer will fetch -½ marks.
4. Category-III : One or more answer(s) is (are) correct. Correct answer(s) will fetch full marks 2. Any
combination containing one or more incorrect answer will fetch 0 marks. Also no answer will fetch 0
marks. If all correct answers are not marked and also no incorrect answer is marked then score = 2 ×
number of correct answers marked  actual number of correct answers.
5. Questions must be answered on OMR sheet by darkening the appropriate bubble marked A, B, C or D.
6. Use only Black ball point pen to mark the answer by complete filling up of the respective bubbles.

SEAL
7. Mark the answers only in the space provided. Do not make any stray mark on the OMR.
8. Write question booklet code, subject(s) and your enrolment number carefully in the specified locations
of the OMR. Also fill appropriate bubbles.
9. Write your name (in block letter), name of the examination centre and put your full signature and etc. in
appropriate boxes in the OMR.
10. The OMRs will be processed by electronic means. Hence it is liable to become invalid if there is any
mistake in enrolment number entered or if there is any mistake in filling corresponding bubbles. Also it
may become invalid if there is any discrepancy in the name of the candidate, name of the examination
centre or signature of the candidate vis-a-vis what is given in the candidate’s identity card. The OMR
may also become invalid due to folding or putting stray marks on it or any damage to it. The consequence
of such invalidation due to incorrect marking or careless handling by the candidates will be sole
responsibility of candidate.
11. Mobile phones, calculators, Slide Rules, Log tables and Electronic Watches with facilities of calculator,
charts Graph sheets or any other form of Tables are not allowed in the Examination hall. Possession
of such devices during the examinations shall lead to cancellation of the paper besides seizing of the
same.
12. Rough work must be done on the question paper itself. Additional blank pages are provided with the
question paper for rough work.

Name of the Candidate (in capital letters) :

Enrolment Number :

Head Office - 96K, S.P. Mukherjee Road, Hazra More, Kolkata-700026  24551840 / 24544817
XII-MT-4-WBJEE-PC AITS : 2020-2021

PHYSICS

Category-I (Q. 1 to Q. 30)

Only one answer is correct. Correct answer will fetch full marks 1. Incorrect answer or any combination of more
than one answer will fetch –¼ marks. No answer will fetch 0 marks.

1. A physical quantity n depends on quantities y and z as follows x Ay B tanCz , where A, B and C are constants.
Which of the following do not have the same dimensions ?
~„þ!Ýþ ö¦þï“þ îûy!Ÿ n ”%!Ýþ xþ™îû îûy!Ÿ y ~î‚ z ~îû vþzþ™îû ! ¦ÅþîûŸ#œ ! Á¬!œ!…“þ ¦þöìî x Ay B tanCz , öë…yöì A, B ~î‚ C £œ
•Ê%î„þÐ #öì‰þîû ö„þy !Ýþîû ›yey ~„þ ëûÚ
B
(A) x and B (B) C and z–1 (C) y and (D) x and A
A

B
x ~î‚ B (B) C ~î‚ z–1 (C) y ~î‚ (D) x ~î‚ A
A
2. A plank with a box on it at one end is gradually raised about the other end. As the angle of inclination with the
horizontal reaches 30°, the box starts to slip and slides 4.0 m down the plank in 4.0 s. The co-efficients of static
and kinetic friction between the box and the plank will be
~„þ!Ýþ “þ=þyîû vþzþ™îû ~„þ!Ýþ îy: xyöìŠé ~î‚ vþz£yöì„þ vþzþ™îû !”öì„þ ö“þyœy £ëû “þ=þyîû xþ™îû ²Ìyöìhsþîû ßþºyöìþ™öìÇþÐ x %¦)þ!›öì„þîû ¢yöìí !“þöì„þy’ ë…
30° £ëû “þ… îy:!Ýþ !þ™Šéöìœ öëöì“þ Ÿ%îû% „þöìîû ~î‚ 4.0 s ö¢öì„þöìuþ 4.0 m #öì‰þ yöì›Ð îy: ~î‚ “þ=þy ›•ÄÞí !Þí“þ ~î‚ †“þ#ëû ‡¡ìÅ’
†%’yöìA„þîû ›y £œ

mg

(A) 0.6 and 0.5 (B) 0.5 and 0.6 (C) 0.4 and 0.3 (D) 0.6 and 0.6
0.6 ~î‚ 0.5 (B) 0.5 ~î‚ 0.6 (C) 0.4 ~î‚ 0.3 (D) 0.6 ~î‚ 0.6
3. Four balls each of radius 10 cm and mass 1 kg, 2 kg, 3 kg and 4 kg are attached to the periphery of the massless
plate of radius 1 m.
²Ì!“þ!Ýþ 10 cm îÄy¢yöì•Åîû ‰þyîû!Ýþ îœ ëyöì”îû ¦þîû 1 kg, 2 kg, 3 kg ~î‚ 4 kg “þyöì”îû ë%=þ „þîûy xyöìŠé 1 m îÄy¢y•Å !î!ŸTþ ¦þîû£# ö²ÕöìÝþîû
þ™!îû!• îîûyîîûÐ
1 kg

4 kg 1m 2 kg

3 kg
What is moment of inertia of the system about the centre of the plate ?
ö²ÕöìÝþîû ö„þw ¢yöìþ™öìÇþ !¢öìÞÝþöì›îû ‹vþü“þy ¼y›öì„þîû ›y £œ
(A) 12.04 kg m2 (B) 10.04 kg m2 (C) 11.50 kg m2 (D) 5.04 kg m2

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M
4. Knowing that mass of moon is (where M is the mass of earth), find the distance of the point, where gravitational
81
field due to earth and moon cancel each other. Given that the distance between the earth and the moon is 60 R,
where R is the radius of earth
M
•öìîû yç ‰¤þyöì”îû ¦þîû 81
(M £œ þ™,!íî#îû ¦þîû), ö¢£z !î¨%îû ”)îûc ! ’Åëû „þîû öë…yöì þ™,!íî# ~î‚ ‰¤þyöì”îû ‹ Ä x!¦þ„þ¡ìÅ öÇþe þ™îûßþ™îûöì„þ
îy!“þœ „þöìîûÐ ²Ì”_ þ™,!íî# ~î‚ ‰¤þyöì”îû ›•Äî“þ#Å ”)îûc 60 R, öë…yöì R £œ þ™,!íî#îû îÄy¢y•Å
(A) 2 R (B) 4 R (C) 6 R (D) 8 R
5. At 0°C the density of a fixed mass of a gas divided by pressure is x. At 100°C, the ratio will be
0°C vþz¡ìŒ“þyëû ~„þ!Ýþ †Äyöì¢îû ! !”ÅTþ ¦þöìîûîû ‡ cöì„þ ‰þyþ™ myîûy ¦þy† „þöìîû x þ™yçëûy ëyëûÐ 100°C vþz¡ìŒ“þyëû x %þ™y“þ!Ýþ £öìî
273 373 100
(A) x (B) x (C) x (D) x
373 273 273
6. If the ratio of diameters, lengths and Young’s modulus of steel and copper wires shown in the figure are p, q and
s respectively, then corresponding ratio of increase in their lengths will be
!‰þöìe ²Ì”_ £zßþ™y“þ ~î‚ “þy›yîû îÄy¢– ÷”‡ÅÄ ~î‚ £zë‚û †%’yöìA„þîû x %þ™y“þ £œ ëíy„Êþöì› p, q ~î‚ sÐ “þyöì”îû ¢‚!ÙÕTþ ÷”‡ÅÄ î,!å•îû x %þ™y“þ £œ

Steel

2m
Copper

5m

5q 7q 2q 7q
(A) (B) (C) (D)
7sp2 5sp2 5sp 5sp

7. ‘n’ identical droplets are charged to V volt each. If they coalesce to form a single drop, then its potential will be
‘n’ ¢‚…Ä„þ x %îû)þ™ ‹œ!î¨%öì„þ V ö¦þyöìÎÝþ xy!£“þ „þîûy xyöìŠéÐ “þyîûy ë!” ‹%öìvþü !†öìëû îvþü öš¤þyÝþyëû þ™!îû’“þ £ëû– “þöìî £z£yîû !î¦þî £öìî
2 1
V
(A) n 3 V (B) n 3 V (C) n V (D)
n
8. An equilateral triangular loop ACD of side ‘l’ carries a current ‘i’ in the directions as shown in the figure. The loop

is kept in a uniform horizontal magnetic field B as shown in the figure. Net force on the loop is
ACD ¢›îy£% !e¦%þ‹y„þyîû œ%þ™ ~îû ÷”‡Ä ‘l’ ~î‚ vþz£y ‘i’ “þ!vþüê þ™!îûî£ „þöìîû ëy !‰þöìe ²Ì”_Ð œ%þ™!Ýþöì„þ îûy…y £öìëûöìŠé ¢%¡ì› x %¦)þ!›„þ

‰%þÁº„þöìÇþe ö“þ ëy !‰þöìe ²Ì”_Ð œ%þ™!Ýþîû vþzþ™îû ö›yÝþ îœ
B
(A) zero (Ÿ) Ä)
3  A
(B) ilB
2
(C) perpendicular to paper inwards  B
i i
öþ™þ™yöìîûîû “þöìœîû ¢yöìí xhsþÅ !”öì„þ œÁº¦þyöìî
(D) perpendicular to paper outwards
D C
öþ™þ™yöìîûîû “þöìœîû ¢yöìí î!£Å!”öì„þ œÁº¦þyöìî

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9. The electron in the hydrogen atom is moving with a speed of 2.3 × 106 m/s in an orbit of radius 0.53Å. The
magnetic moment of the revolving electron is
£y£zöìvÈþyöì‹ þ™îû›y’%îû ›öì•Ä £zö위þÝþÆ ‰þœ›y 2.3 × 106 m/s o%!“þ ¢£ 0.53Å îÄy¢yöì•Åîû „þÇþ þ™öìíÐ ‡)’Åyëû›y £zö위þÝþÆöì îû ö‰þïÁº„þ
¼y›öì„þîû ›y £œ
(A) 9.13 × 10–24 A m2 (B) 8.7 × 10–24 A m2 (C) 9.00 × 10–24 A m2 (D) 9.753 × 10–24 A m2
10. In an electrical circuit R, L, C and ac voltage source are all connected in series. When L is removed from the

circuit, the phase difference between the voltage and the current in the circuit is . If instead, C is removed from
3

the circuit, the phase difference is again . The power factor of the circuit is
3
~„þ!Ýþ “þ!vþüê î“Åþ #öì“þ R, L, C ~î‚ ac !î¦þî vþzê¢ ¢„þöìœ ö×’#öì“þ ë%=þÐ ë… î“Åþ # £öì“þ L ö„þ …%öœ
ì ö çëûy £ëû– !î¦þî ~î‚ “þ!vþüê ²Ìîy£

›•ÄÞí ”Ÿy þ™yíÅöì„þÄîû ›y £ëû 3

Ð ë!” C ö„þ …%öìœ ö çëûy £ëû– “þöìî þ™% îûyëû ”Ÿy þ™yíÅöì„þÄîû ›y £ëû 3
Ð î“Åþ #îû Çþ›“þy †%’öì„þîû ›y £œ

1 1 3
(A) (B) (C) 1 (D)
2 2 2
11. In a photoelectric effect measurement, the stopping potential for a given metal is found to be V0 volt. When
radiation of wavelength 0 is used. If radiation of wavelength 2 0 is used with the same metal then the stopping
potential (in volt) will be
~„þ!Ýþ xyöìœy„þ “þ!vþüê þ™!îû›yöìþ™ ~„þ!Ýþ ²Ì”_ •y“%þîû ! î,!_ !î¦þöìîîû ›y V0 ö¦þyÎÝþÐ ë… 0 “þîûA†÷ì”öì‡ÅÄîû !î!„þîû’ îÄî£,“þ £ëûÐ ë!” 2 0
“þîûA†÷ì”öì‡ÅÄîû !î!„þîû’ îÄî£,“þ £ëû ¢›•y“%þ ¢£– ! î,!_ ›y ö¦þyÎÝþ ~„þöì„þ £öìî
V0 hC hC
(A) (B) 2V0 (C) V0 (D) V0
2 2e 0 2e 0

12. If and are the current gain in the CB and CE configurations respectively of the transistor circuit, then

ë!” ~î‚ £ëû “þ!vþüê ²Ìîy£ ö†£z CB ~î‚ CE „þ !šþ†yöìîûŸöì ~„þ!Ýþ ÝþÆy !‹Tþyîû î“Åþ #öì“þ– “þöìî

(A) zero (Ÿ) Ä) (B) 1 (C) 2 (D) 0.5

13. A spring mass system oscillates with a time period T1 when a certain mass is attached to the spring. When a
different mass is attached after removing the first mass the time period becomes T2. When both the masses are
attached to the free end of the spring with the other end fixed, the time period of oscillation is
~„þ!Ýþ !ßþ±‚ ¦þîû !¢öìÞÝþ› ö”yœ ¢Á™)’Å „þöìîû T1 þ™ëÅyëû„þyœ¢£ ë… vþz£yîû ¢yöìí ~„þ!Ýþ ¦þîû ë%=þ íyöì„þÐ ²Ìí› ¦þîûöì„þ …%öìœ ! öìëû ë… þ™,í„þ
¦þîûöì„þ ë%=þ „þîûy £ëû “þ… þ™ëÅyëû„þyœ £ëû T2Ð ë… vþz¦þëû ¦þîû£z ë%=þ „þîûy £ëû !ßþ±‚ ~îû ›%=þ ²Ìyöìhsþîû ¢yöìí xþ™îû ²Ìyhsþöì„þ ”,‘þü öîûöì…– ö”yœöì îû
þ™ëÅyëû„þyœ £öìî
T1 T2 2 2
(A) T1T2 (B) T1 + T2 (C) (D) T1 T2
2
14. A light pointer fixed to one prong of a tuning fork touches a vertical smoked plate. The fork is set into vibration and
the plate is allowed to fall freely. Eight complete waves are counted when the plate falls through 10 cm. The
frequency of the tuning fork is (g = 9.8 m/sec2)
~„þ!Ýþ £yœ„þy ! öì”ÅŸ„þöì„þ ë%=þ „þîûy £öìëûöìŠé ¢%îŸû œy„þyîû ~„þ!Ýþ Ÿœy„þyîû ¢yöìí ~„þ!Ýþ vþzÍÔÁº •)›y!ëû“þ ö²ÕÝþöì„þ ßþ™ŸÅ „þöìîÐû ¢%îŸû œ„þy!Ýþöì“þ „þÁ™
„þîûyöì y £œ ~î‚ ö²ÕÝþ!Ýþöì„þ ›%=þ ¦þyöìî þ™vþüöì“þ ö”çëûy £ëûÐ xyÝþ!Ýþ ¢Á™)’Å “þîûA† †’ y „þîûy £ëû ë… ö²ÕÝþ!Ýþöì„þ 10 cm þ™vþüöì“þ ö”çëûy £ëûÐ
¢%îûŸœy„þyîû „þÁ™yA„þ £œ (g = 9.8 m/sec2)
(A) 112 Hz (B) 14 Hz (C) 28 Hz (D) 56 Hz

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15. The driver of a car travelling with speed 30 m/sec towards a hill sounds a horn of frequency 600 Hz. If the velocity
of sound in air is 330 m/sec, the frequency of reflected sound heard by the driver is
30 m/sec o%!“þ¢£ ‰þœ›y †yvþü#îû vÈþy£z¦þyîû ~„þ!Ýþ þ™y£yöìvþüîû !”öì„þ öëöì“þ öëöì“þ 600 Hz „þÁ™yöìA„þîû £’Å îy‹y Ð ë!” îyëû%öì“þ Ÿöì îû öî†
330 m/sec,“þöìî vÈþy£z¦þyîû „þ“,Åþ„þ ×%“þ ²Ì!“þšþ!œ“þ Ÿöì îû „þÁ™yA„þ £œ
(A) 500 Hz (B) 550 Hz (C) 655 Hz (D) 720 Hz
16. n-th bright fringe of red light ( 1 = 7500Å) coincides with (n + 1)th bright fringe of green light ( 2 = 6000Å), the
value of ‘n’ is
œyœ xyöìœyîû n-“þ› vþzIµœ þ™!Ýþ ( 1 = 7500Å) ¢›yþ™!“þ“þ £ëû ¢î%‹ xyöìœyîû ( 2= 6000Å) (n + 1)“þ› vþzIµœ þ™!Ýþîû ¢yöìíÐ ‘n’ ~îû
›y £œ
(A) 4 (B) 5 (C) 3 (D) 2
17. One cannot see through fog because
~„þ‹ îÄ!=þ „%þëûyŸyëû ö”…öì“þ þ™y y „þyîû’
(A) fog absorbs light (B) the refractive index of fog is very large
„%þëûyŸy xyöìœy öŸy¡ì’ „þöìîû „%þëûyŸyîû ²Ì!“þ¢îûyA„þ x“þÄhsþ îvþü
(C) light suffers total reflection at the droplet in fog (D) light is scattered by the droplets in fog
„%þëûyŸyëû xyöìœyîû ¢Á™)’Å ²Ì!“þšþœ £ëû öš¤þyÝþy †%!œöì“þ vÈþþ™öìœÝþ „þ“Å,þ„þ xyöìœy !îöìÇþ!þ™“þ £ëû „%þëûyŸyëû
18. A transparent cube of 15 cm edge contains a small air bubble. Its apparent depth when viewed through one face
is 6 cm and when viewed through opposite face is 4 cm. The refractive index of the material of the cube is
15 cm îy£% !î!ŸTþ ~„þ!Ýþ ßþºFŠé ‡ öì„þîû ›öì•Ä Ç%þo îyëû% î%”äî%”ä xyöìŠéÐ £z£yîû xyþ™y“þ †¦þ#îû“þy ë… ~„þ!Ýþ þ™,Ûþ £öì“þ ö”…y £ëû “þ… £ëû 6 cm
~î‚ !îþ™îû#“þ þ™,Ûþ £öì“þ ö”…öìœ †¦þ#îû“þy £ëû 4 cmÐ ‡ öì„þîû vþzþ™y”yöì îû ²Ì!“þ¢îûyöìA„þîû ›y £œ
(A) 2.0 (B) 1.5 (C) 1.6 (D) 2.5
19. The magnifying power of a telescope is 9. When it is focused for parallel rays, then the distance between its
objective and eye piece is 20 cm. The focal length of lenses used in it will be
~„þ!Ýþ öÝþ!œöìßþñyöìþ™îû !îî•Å Çþ›“þyîû ›y 9Ð ë… £z£yöì„þ öšþy„þy!¢“þ „þîûy £ëû ¢›yhsþîûyœ îû!ÙÂîû ‹ Ä “þ… x!¦þœÇþ ~î‚ x!¦þöì öìeîû ›öì•Ä
”)îûc £ëû 20 cmÐ îÄî£,“þ öœöìªîû öšþy„þy¢ ÷”öì‡ÅÄîû ›y £œ
(A) 15 cm, 5 cm (B) 10 cm, 5 cm (C) 18 cm, 2 cm (D) 11 cm, 9 cm
20. Two carnot engines A and B are operated in series. A receives heat at 800 K and rejects heat at TK. The engine
B receives heat at TK and rejects at 300 K. If their efficiencies are equal, what is T ?
”%!Ýþ „þy ÅÝþ £z!O A ~î‚ B ö„þ ‰þyœ y „þîûy £ëû ö×’#öì“þÐ A “þyþ™@ùÌ£’ „þöìîû 800 K vþz¡Œì “þyëû ~î‚ ²Ì“þÄy…Äy „þöìîû TK vþz¡Œì “þyëûÐ £z!O B, TK
vþz¡ìŒ“þyëû “þyþ™ @ùÌ£’ „þöìîû ~î‚ 300 K vþz¡ìŒ“þyëû “þyþ™ ²Ì“þÄy…Äy „þöìîûÐ “þyöì”îû „þyëÅÇþ›“þy ¢›y £öìœ T ~îû ›y £œ
(A) 400.9 K (B) 450.9 K (C) 489.9 K (D) 512.9 K
21. A uniformly charged thin spherical radius. R carries uniform surface charge density of per unit area. It is made
of two hemispherical shells, held together by pressing them with force (F) see figure. F is proportional to
~„þ!Ýþ ¢%¡ì›¦þyöìî xy!£“þ þ™y“þœy ö†yœ„þy„þyîû îÄy¢y•Å R î£ „þöìîû ¢%¡ì› þ™,Ûþ xy•y ‡ c ²Ì!“þ ~„þ„þ öÇþešþöìœÐ £z£y ”%!Ýþ x•Åöì†yœy„þyîû
ö…yœ„þ myîûy ! !›Å“þ ~î‚ vþz£yöì”îû ~„þ¢yöìí ö‰þöìþ™ ~„þ!e“þ „þîûy £œ (F) îœ myîûy ëy !‰þöìe ²Ì”_Ð F ëyîû ¢yöìí ¢›y %þ™y“þ#

F F

1 1
(A) R2 (B) R (C) (D)
R R2

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22. A charge Q is divided in two parts q and Q – q. What is value of q for maximum force between them ?
~„þ!Ýþ xy•y Q ö„þ !î¦þ=þ „þîûy £ëû ”%!Ýþ x‚öìŸ q ~î‚ Q – qÐ vþz£yöì”îû ›öì•Ä ¢îÅy!•„þ îöìœîû ‹ Ä q ~îû ›y „þ“þÚ
3Q Q Q
(A) (B) (C) Q (D)
4 3 2
23. The equivalent resistance between points A and B of an infinite network of resistances, each of 1 , connected as
shown is
²Ì!“þ!Ýþ 1 öîûyöì•îû x¢#› ö Ýþçëûyöì„Åþîû ”%!Ýþ !î¨% A ~î‚ B ~îû ›•Äî“þ#Å “%þœÄ öîûyöì•îû ›y „þ“þ ëy !‰þöìe ²Ì”_Ú
1 1 1
A

1 1 1

1 5
(A) infinite (x¢#›) (B) 2  (C) (D) zero (Ÿ) Ä)
2
24. A current I1 carrying wire AB is placed near another long wire CD carrying current I2. If wire AB is free to move,
it will have
~„þ!Ýþ “þ!vþüê ²Ìîy£ I1 ëy AB þ™!îûîy£# î£ „þöìîû xþ™îû ~„þ!Ýþ “þyîû CD îîûyîîû ëy I2 “þ!vþüê þ™!îûî£ „þöìîûÐ ë!” AB “þyîû ›%=þ ¦þyöìî ‰þœ›y
£ëû– “þöìî

I1
I2 A B

(A) Rotational motion only (B) Translational motion only

‡)’Å †!“þ Ÿ%•%›ye ÷îû!…„þ †!“þ Ÿ%•%›ye
(C) Rotational as well as translational motion (D) Neither rotational nor translational motion
‡)’Å ~î‚ ÷îû!…„þ †!“þ ‡)’Å îy ÷îû!…„þ †!“þ ö„þyöì y!Ýþ£z ëû
1
25. A rope of mass M and length L is resting on a horizontal smooth table with rd of its length hanging vertically..
3
The work done to lift the hanging part on the table will be

1
M ¦þîû ~î‚ L ÷”öì‡ÅÄîû ~„þ!Ýþ ”!vþüöì„þ ~„þ!Ýþ x %¦)þ!›„þ öÝþ!îöìœîû vþzþ™îû îûy…y £öìëûöŠì é vþz£yîû x‚Ÿ ÷”‡ÅÄ vþzÍÔÁ¦º þyöìî G%þœhsþ xîÞíyëûÐ G%þœhsþ
3
x‚Ÿ!Ýþöì„þ öÝþ!îöìœ “%þœöì“þ „,þ“þ„þyöìëîÅ û ›y
1 1 1 1
(A) MgL (B) MgL (C) MgL (D) MgL
3 6 9 18

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26. Select correct one

¢!àþ„þ vþz_îû!Ýþ ! îÅy!‰þ“þ „þîû
(A) Newton’s second law of motion is applicable for non-inertial frame of reference
! vþzÝþöì îû !m“þ#ëû †!“þ¢)e ²Ìöìëy‹Ä x‹vþüc#ëû ! ö씟Š“þöìsþfîû ‹ Ä
(B) A body may have kinetic energy without linear momentum
~„þ!Ýþ îhßþ$ îû †!“þŸ!=þ íy„þöì“þ þ™yöìîû ÷îû!…„þ ¦þîûöîì † îÄy“þ#“þ
(C) Total energy of the system may be negative
!¢öìÞÝþöì›îû ö›yÝþ Ÿ!=þ }’yd„þ
(D) For uniform circular motion, kinetic energy of the particle, is not constant
¢%¡ì› î,_#ëû †!“þîû ‹ Ä îhß$þ„þ’yîû †!“þŸ!=þ •Ê%î„þ ëû
27. A stick of length ‘l’ is initially along vertical, its lower end is fixed with a table, when released, other end of the
stick hits the ground with a velocity V, then the value of V is
‘l’ ÷”öì‡ÅÄîû ~„þ!Ýþ ”uþ ²Ìyí!›„þ ¦þyöìî vþzÍÔÁº îîûyîîû íyöì„þÐ £z£yîû
#öì‰þîû ²Ìyhsþ ~„þ!Ýþ öÝþ!îöìœîû myîûy xyÝþ„þyöì y– ë… öŠéöìvþü ö”çëûy £ëû ”öìuþîû
xþ™îû ²Ìyhsþ!Ýþ V †!“þöìîöì† ¦)þ!›öì„þ xy‡y“þ „þöìîû– V ~îû ›y £œ
(A) gl (B) 2gl (C) 3gl (D) 5gl
28. Select the correct statement
¢!àþ„þ !îî,!“þ!Ýþ ! öì”ÅŸ „þîû
(A) With one semiconductor diode, we can produce full wave rectifier
~„þ!Ýþ x•Åþ™!îûîy£# vþyöìëûyöìvþîû ¢y£yöìëÄ xy›îûy þ™)’Å “þîûA† ~„þ›%…#„þyîû„þ vþzêþ™§¬ „þîûöì“þ þ™y!îû
(B) Dark current is associated with photodiode
„,þ¡ìŒ ²Ìîy£ šþöìÝþyvþyöìëûyöìvþîû ¢yöìí ¢‚!ÙÕTþ
(C) Germinium can be used to produce L.E.D
L.E.D ²Ìhß$þöì“þ ‹yöì›Å! ëûy› îÄî£yîû „þîûy öëöì“þ þ™yöìîû
(D) Inverter circuit is an example of NAND gate
£z ¦þyÝÅþyîû î“Åþ # £œ NAND ö†öìÝþîû vþz”y£îû’
29. An electric current of 5 amp is divided into three branches, the length of the wires in the three branches being
proportional to 1 : 2 : 3. The wires are of same material and cross-section. Then the current in the longest wire in
amp will be (nearly)
5 amp “þ!vþüê ²Ìîy£öì„þ !î¦þ=þ „þîûy £öìëûöìŠé !“þ !Ýþ Ÿy…yëû– “þyöìîûîû ÷”‡ÅÄ !“þ !Ýþ Ÿy…yëû ëyîû ¢yöìí ¢›y %þ™y“þ# “þy £œ 1 : 2 : 3Ð “þyîû †%!œ
¢›vþzþ™y”y ~î‚ ²ÌÞíöìFŠé” !î!ŸTþÐ ”#‡Å“þ› “þyöìîû “þ!vþüê ²Ìîy£ xÄy!Á™ëûyîû ~„þöì„þ £öìî
(A) 0.9 (B) 0.5 (C) 0.4 (D) 0.3
30. Select correct one
¢!àþ„þ vþz_îû!Ýþ ! îÅy!‰þ“þ „þîû
(A) X-ray is used to study crystal structure (B) Infrared ray is used in T.V. remote
X-îû!Ù îÄî£,“þ £ëû !„ÊþTþyœ †àþ ‰þ‰Åþyîû ‹ Ä £z šÊþyöìîûvþ îû!Ù îÄî£,“þ £ëû T.V. !îûöì›yöìÝþ
(C) Ultraviolet ray is used to destroy bacteria (D) All are correct
x!“þöìî†% # îû!Ù îÄî£,“þ £ëû îÄy„þöìÝþ!îûëûy ! ›)Åœ ~îû ‹ Ä ¢î„þ!Ýþ£z ¢!àþ„þ

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Category-II (Q. 31 to Q. 35)

Only one answer is correct. Correct answer will fetch full marks 2. Incorrect answer or any combination of more
than one answer will fetch –½ marks. No answer will fetch 0 marks.

31. Find the emf induced across the wire ab given in the figure
²Ì”_ !‰þöìe ab “þyöìîûîû ²Ìyöìhsþ xy!îTþ “þ!vþüê‰þyœ„þ îöìœîû ›y ! ’Åëû „þîû

B
C l
i a b

0 i C l 0 C 0 i C l 0 C
(A) ln (B) ln (C) ln (D) ln
2 C 2 C l 4 C 4 C l
32. Four balls of mass 5 kg each are placed on the top of a horizontal turn table and fastened together with four
string’s, each 1 m long to form a square of side 1 m. The axis of rotation passes through the centre of the square.
30
Then the tensions in the string when the turn table is rotated at the rate of revolutions per minute will be

5 kg ¦þöìîûîû ‰þyîû!Ýþ îœöì„þ îûy…y £öìëûöìŠé x %¦)þ!›„þ ‡)’Å öÝþ!îöìœîû vþzþ™öìîû ~î‚ ²Ì!“þ!Ýþ 1 m ”#‡Å ‰þyîû!Ýþ ”!vþü !”öìëû xyÝþ„þyöì y £œ ~î‚ 1 m
30
îy£% !î!ŸTþ î†ÅöìÇþe †àþ „þîûy £œÐ ‡)’Å xÇþ!Ýþ î†ÅöìÇþöìeîû ö„þw†y›#Ð ‡)’Å öÝþ!îœ!Ýþ ë… ²Ì!“þ !›! öìÝþ ¢‚…Ä„þ ‡)’Å „þöìîû “þöìî ¢)“þyëû
Ýþyöì îû ›y

1m

1m

(A) 2.5 N (B) 2.7 N (C) 1.9 N (D) 2.9 N

2
33. A steel wire of cross-sectional area 0.5 mm is held between two fixed supports. If the tension in the wire is
negligible and it is just taut at a temperature of 20°C, then the tension when the temperature falls to 0°C will be
(Given : Young’s modulus of steel = 2 × 1012 dyne/cm2 and co-efficient of linear expansion for steel = 12 × 66 per
°C)
0.5 mm2 ²ÌÞíöìFŠéö”ì îû öÇþešþœ !î!ŸTþ £zÜ™yöì“þîû “þyîûö„ì þ ”%!Ýþ ”,‘þü ¢yöìþ™yöìÝÅþîû ›öì•Ä xyÝþ„þyöì
y xyöìŠéÐ ë!” “þyöìîûîû Ýþy † Ä £ëû ~î‚ £z£yöì„þ
y £œ– “þöìî ë… vþz¡ìŒ“þy 0°C ~ þ™!“þ“þ £ëû– “þ… Ýþyöì îû ›y £öìî (²Ì”_ õ £zÜ™yöì“þîû £zëû‚ †%’yA„þ = 2 × 1012 dyne/
20°C vþz¡ìŒ“þyëû Ýþy
cm 2 ~î‚ £zÜ™yöì“þîû ÷”‡ÅÄ ²Ì¢yîû’ †%’yA„þ = 12 × 66 ²Ì!“þ °C)
(A) 24 N (B) 22 N (C) 26 N (D) 28 N

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34. Two sources S1 and S2 emitting light of wavelength 600 nm and placed at a distance 1.0 × 10–2 cm apart. A
detector can be moved on the line S1P which is perpendicular to S1S2. Then the position of the farthest minimum
detected will be
”%!Ýþ vþzê¢ S1 ~î‚ S2 ! †Å“þ „þöìîû 600 nm “þîûA†÷ì”öì‡ÅÄîû xyöìœy ~î‚ þ™îûßþ™îû £öì“þ 1.0 × 10–2 cm ”)îûöìc íyöì„þÐ ~„þ!Ýþ !vþöìÝþ„þÝþîû
‰þœ›y £öì“þ þ™yöìîû S1P œy£z îîûyîîû ëy !„þ y S1S2 ~îû ¢yöìí œÁºÐ ”)îû“þ› !vþöìÝþ„þÝþöìîûîû xîÞíy £œ
S2

S1
P
D

(A) 1.7 cm (B) 1.9 cm (C) 2.1 cm (D) 1.5 cm

V
35. Light described at a place by the equation, E 100 sin 5 1015 s–1 t sin 8 105 s–1 t falls on a metal
m
surface having work function 2.0 eV. Then the maximum kinetic energy of the photoelectrons will be

V
xyöìœy x!“þ„Êþ› „þöìîû ~„þ!Ýþ þ™í, E 100 sin 5 1015 s–1 t sin 8 105 s–1 t ¢›#„þîû’ myîûy ëy þ™!“þ“þ £ëû •y“þî þ™,öìÛþîû
m
vþzþ™îû ëyîû „þyëÅ xöìþ™Çþ„þ 2.0 eVÐ šþöìÝþy£zö위þÝþÆöì îû ¢îÅy!•„þ †!“þŸ!=þîû ›y £œ
(A) 3.0 eV (B) 3.27 eV (C) 3.83 eV (D) 3.13 eV

Category-III (Q. 36 to Q. 40)

One or more answer(s) is (are) correct. Correct answer(s) will fetch full marks 2. Any combination containing
one or more incorrect answer will fetch 0 marks. Also no answer will fetch 0 marks. If all correct answers are
not marked and also no incorrect answer is marked then score = 2 × number of correct answers marked actual
number of correct answers.

36. Three charges +Q each, which are free to move are placed at the corners of an equilateral triangle of side length
‘a’. A third charge – Q is placed (which is fixed) at the centroid. Then
!“þ !Ýþ xy•y ²Ì!“þ!Ýþ +Q ›y !î!ŸTþ ~î‚ ›%=þ ¦þyöìî ‰þœ›y “þyöì”îû îûy…y £öìëöû Šì é ‘a’ îy£% !î!ŸTþ ¢›îy£% !e¦%þöì‹îû !“þ !Ýþ ²ÌyöìhsþÐ ~„þ!Ýþ “,þ“þ#ëû
xy•y – Q ö„þ îûy…y £öìëûöŠì é ~„þ!Ýþ ¦þîûöì„þöìwÐ “þöìî
1 3Q2
(A) Repulsive force on any one of the charge at the corner will be
4 0 a2

1 3Q2
²Ìyhsþ !î¨%öì“þ öëöì„þy xy•yöì îû vþzþ™îû !î„þ¡ìÅ’ îöìœîû ›y 4 0 a2

1 3Q2
(B) Repulsive force will be
4 0 a2

1 3Q2
!î„þ¡ìÅ’ îœ 4 0 a2

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1 3Q2
(C) Attractive force will be
4 0 a2

1 3Q2
xy„þ¡ìÅ’ îœ 4 0 a2
(D) All charges will be at rest
¢„þœ xy•y †%!œ !ÞíîûyîÞíyëû íyöì„þ
37. A rectangular wooden block of dimension l × 2l × 3l is floating in water (i) ‘l’ as vertical height (ii) ‘2l’ as vertical
height, (iii) ‘3l’ as vertical height. Then
~„þ!Ýþ xyëû“þy„þyîû „þyöìàþîû îÏ„þ ëyîû ›yey l × 2l × 3l ‹öìœ ¦þy¢›y (i) ‘l’ öë…yöì vþzÍÁÔ º vþzF‰þ“þy (ii) ‘2l’ £œ vþzÍÔÁº vþzF‰þ“þy (iii) ‘3l’ £œ vþzÍÁÔ º
vþzF‰þ“þyÐ “þöìî
(A) Buoyant force will be maximum for case (i)
²Õî“þy îöìœîû ›y (i) ~îû ¢îÅy!•„þ
(B) Buoyant force is minimum for case (iii)
²Õî“þy îöìœîû ›y (iii) ~îû ¢îÅ! Á¬
(C) For case (i) and case (ii), buoyant forces are same
(i) ~î‚ (ii) ~îû öÇþöìe ²Õî“þy îœ ¢›y
(D) For case (ii) and case (iii), buoyant forces are same
(ii) ~î‚ (iii) ~îû öÇþöìe ²Õî“þy îœ ¢›y
38. Select correct statement(s)
¢!àþ„þ !îî,!“þ!Ýþ ! îÅy!‰þ“þ „þîû
(A) Induction cooker is based on E.M.I.
£z vþy„þŸy „%þ„þyîû †!àþ“þ £ëû E.M.I. ~îû vþzþ™îû !¦þ!_ „þöìîû
(B) Transformer is based on mutual inductance
ÝþÆyªšþ›Åyîû †!àþ“þ £ëû þ™yîûßþ™!îû„þ xyöìîöìŸîû vþzþ™îû !¦þ!_ „þöìîû
(C) Platinum resistance thermometer is based on Rt R0 1 t

²ÕÄy!Ýþ! ëûy› öîûy•„þ íyöì›Åy!›Ýþyîû †!àþ“þ Rt R0 1 t ~îû vþzþ™îû !¦þ!_ „þöìîû

(D) Shunt is a very high resistance connected in parallel to a galvanometer
¢yrÝþ £œ x!“þ vþzF‰þ öîûy• !î!ŸTþ ëy †Äyœ¦þyöì y!›Ýþyöìîûîû ¢yöìí ¢›yhsþîûyöìœ ë%=þ
39. There is a double layered convex lens. It is made of alternate parallel layers of refractive index 1 and 2, it is
placed vertically on the principle axis. An extended object is placed infront of this lens, then
”%!Ýþ hßþîû !î!ŸTþ ~„þ!Ýþ vþz_œ öœª î“Åþ›y Ð £z£y ! !›Å“þ xÎÝþyîûöì Ýþ ¢›yhsþîûyœ hßþîû !î!ŸTþ ”%!Ýþ ²Ì!“þ¢îûyA„þ 1 ~î‚ 2 myîûyÐ £z£yöì„þ vþzÍÔÁº
¦þyöìî ²Ì•y xöìÇþîû vþzþ™îû îûy…y £œÐ ~„þ!Ýþ ²Ì¢y!îû“þ îhß$þöì„þ öœöìªîû ¢y›öì îûy…y £œÐ “þöìî
(A) Lens have two focal lengths (B) More than two images will be formed
öœª!Ýþîû ”%!Ýþ öšþy„þy¢ ÷”öì‡ÅÄ î“Åþ›y ”%!Ýþîû x!•„þ ²Ì!“þ!îÁº †!àþ“þ £öìî
(C) Size of the images produced are different (D) Images are produced at different positions
vþzêþ™§¬ ²Ì!“þ!îöìÁºîû xy„þyîû þ™,í„þ £öìî ²Ì!“þ!îÁº †!àþ“þ £öìî þ™,í„þ þ™,í„þ xîÞíyöì

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40. Select the correct statement(s)

¢!àþ„þ vþz_îû!Ýþ ! îÅy!‰þ“þ „þîû
1 2
(A) A uniform rod of length ‘l’ and mass ‘m’ when rotating about one of its end, its moment of inertia will be ml
3

1 2
‘l’ ÷”‡ÅÄ ~î‚ ‘m’ ¦þöìîûîû ö„þy ¢%¡ì› ”uþ vþz£yîû ~„þ!Ýþ ²Ìyöìhsþîû ßþºyöìþ™öìÇþ ‡)’Å „þyöìœ ‹vþü“þy ¼y›„þ £öìî ml
3

1 2
(B) A uniform rod of length ‘l’ and mass ‘m’ when rotating about one of its end, its moment of inertia will be ml
6

1 2
‘l’ ÷”‡ÅÄ ~î‚ ‘m’ ¦þöìîûîû ö„þy ¢%¡ì› ”uþ vþz£yîû ~„þ!Ýþ ²Ìyöìhsþîû ßþºyöìþ™öìÇþ ‡)’Å „þyöìœ ‹vþü“þy ¼y›„þ £öìî ml
6
(C) A sphere under rotation and translation, its rotational kinetic energy is around 28.5% of the total energy
‡)’Å ~î‚ ÷îû!…„þ †!“þîû x•# ~„þ!Ýþ ö†yœ„þ– £z£yîû ‡)’Å †!“þŸ!=þ ö›yÝþ Ÿ!=þîû 28.5%
(D) A sphere under rotation and translation, its rotational kinetic energy is around 32.5% of the total energy
‡)’Å ~î‚ ÷îû!…„þ †!“þîû x•# ~„þ!Ýþ ö†yœ„þ– £z£yîû ‡)’Å †!“þŸ!=þ ö›yÝþ Ÿ!=þîû 32.5%

11
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CHEMISTRY

Category-I (Q. 41 to Q. 70)

Only one answer is correct. Correct answer will fetch full marks 1. Incorrect answer or any combination of more
than one answer will fetch –¼ marks. No answer will fetch 0 marks.

41. Select the incorrect statement regarding and bonds

~î‚ îr• ¢Á™öì„Åþ ¦%þœ !îî,!“þ!Ýþ ! îÅy‰þ „þîû
(A) -bond lies on the internuclear axis of bonded atoms
-îr• íyöì„þ îr• ë%=þ þ™îû›y’%îû xyhsþƒ! vþz!„Ïþëûyîû xöìÇþîû vþzþ™îû
(B) -electron cloud lies in the molecular plane of the bonded atoms
-£zöœ
ì „þÝþÆöì îû ö›‡ íyöì„þ îr• ë%=þ þ™îû›y’%†!% œîû xy’!î„þ “þöìœ
(C) (3p -3d ) bond is stronger than (2p -3d ) bond
(3p -3d ) îr• – (2p -3d ) îr• xöìþ™Çþy Ÿ!=þŸyœ#
(D) -bonds affect the geometry of the molecule whereas bonds has no primary effect in the geometry of the
molecule
-îr• x’%îû ‹Äy!›!“þöì„þ ²Ì¦þy!î“þ „þöìîû ë… îr•öì îû ö„þy ²Ì¦þyî ö £z x’%îû ‹Äy!›!“þöì“þ
42. Which of the following elements has positive value of first electron affinity ?
! öìÁ¬îû ö„þy ö›ïœ!Ýþîû ²Ìí› £zö위þÝþÆ xy¢!=þ • yd„þÚ
(A) P (B) Ar (C) Ca (D) N
43. The correct order of stability of the following hydrides is
! öìÁ¬îû £y£zvÈþy£zvþ †%!œîû ¢%!Þí!“þîû ¢!àþ„þ „Êþ› £œ
(A) CaH2 < SrH2 < BaH2 (B) KH < CsH < RbH (C) KH < RbH < CsH (D) CaH2 > SrH2 > BaH2
44. Carbon dioxide gas cannot be prepared by heating which of the following ?
! öìÁ¬ ö„þy !Ýþöì„þ vþz_® „þöìîû „þyîÅ vþy£zx:y£zvþ †Äy¢ ²Ìhß$þ“þ „þîûy ëyëû yÚ
(A) ZnCO3 (B) Na2CO3 (C) Li2CO3 (D) NaHCO3
45. Iodine will be oxidised to iodic acid by
xyöìëûy!vþ ö„þy !Ýþîû myîûy ‹y!îû“þ £öìëû xyöìëûy!vþ„þ xÄy!¢vþ ö”ëûÚ
(A) conc. HCl (B) conc. H3PO4 (C) conc. HNO3 (D) dil. H2SO4
†y‘þü HCl †y‘þü H3PO4 †y‘þü HNO3 œ‡% H2SO4
46. Which of the following will form diamagnetic tripositive ions ?
! öìÁî¬ û ö„þy !Ýþ †àþ „þîûöìî !“þîûØ%þÁº„þ#ëû !e• yd„þ xyëû’Ú
(A) La and Ce (B) Ce and Yb (C) La and Lu (D) Eu and Lu
La ~î‚ Ce Ce ~î‚ Yb La ~î‚ Lu Eu ~î‚ Lu
47. Which of the following will form a coloured double salt with solution containing carbonate radicals ?
! öìÁ¬îû ö„þy !Ýþ „þyîÅöì Ýþ ›)œ„þ ¢£ oîöì’îû ¢yöìí îû!ˆ !méôéœî’ †àþ „þîûöìîÚ
(A) ZnCl2 (B) CuCl2 (C) MgCl2 (D) PbCl2

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48. The correct match of the following oxides according to their nature is
! öìÁ¬îû x:y£zvþ †%!œîû ¢!àþ„þ !›œ vþz£yöì”îû ²Ì„,þ!“þ x %¢yöìîû £öìî
Columne Shßþ½þV - I Column hßþ½þ - II
(a) SnO2 (p) Neutral (²ÌŸ›)
(b) ZnO (q) Acidic (xy!ÁÔ„þ)
(c) N2O (r) Basic (Çþyîû„þ#ëû)
(d) Cr2O3 (s) Amphoteric (vþz¦þ•›#Å)
(A) (a) - (r) ; (b) - (s) ; (c) - (p) ; (d) - (p) (B) (a) - (p) ; (b) - (q) ; (c) - (r) ; (d) - (s)
(C) (a) - (s) ; (b) - (s) ; (c) - (p) ; (d) - (q) (D) (a) - (s) ; (b) - (s) ; (c) - (q) ; (d) - (p)
49. Choose the correct statement
¢!àþ„þ !îî,!“þ!Ýþ ! îÅy‰þ „þîû
(I) dyz orbital lies in the xz plane (II) pz orbital lies along x-axis
dyz „þÇþ„þ!Ýþ xz “þöìœ íyöì„þ pz „þÇþ„þ!Ýþ íyöì„þ x-xÇþ îîûîyîû
(III) Lobes of px orbital are at 90° with z-axis (IV) Lobes of dxy orbital are at 90° with z-axis
px „þÇþöì„þîû öœyî ”%!Ýþ z-xöìÇþîû ¢yöìí 90° ö„þyöì’ íyöì„þ dxy „þÇþöì„þîû öœyî†%!œ z-xöìÇþîû ¢yöìí 90° ö„þyöì’ íyöì„þ
(A) III, IV (B) II, III (C) I, II (D) I, IV
50. Which of the following has highest viscocity at room temperature ?
! öìÁ¬ ö„þy !Ýþîû ¢yw“þy ‡öìîûîû vþz¡Œì “þyëû ¢îÅy!•„þÚ
(A) Water (B) Ethanol (C) Glycerol (D) Diethyl ether
‹œ £zíy œ !@Õ¢yîûœ vþy£z£zíy£zœ £zíyîû
51. Which of the following oxoanions does not disproportionate ?
! öìÁî¬ û ö„þy xöì:yxÄy yëû’!Ýþîû !vþ¢öì²Ìyþ™îûŸöì ¢ £ëû yÚ
(A) ClO (B) ClO2 (C) ClO 4 (D) ClO3

52. Determine H° of the following reaction using the listed heats of formation
! öìÁî¬ û !î!„Êþëûyîû H° ! ’Åëû „þîû– “þy!œ„þy¦%þ=þ †àþ “þyþ™†%!œ îÄî£yîû „þöìîû
4HNO3 (l ) P4O10 (s) 2N2O5 (s) 4HPO3 (s)

Given (²Ì”_),

H0f (HNO3, l) = – x kJ/mol

H0f (N2O5, s) = – y kJ/mol

H0f (P4O10, s) = – z kJ/mol

H0f (HPO3, s) = – w kJ/mol

(A) 2y + 4w – 4x – z kJ/mol (B) 4x + 4w – 2y – z kJ/mol
(C) 4x + z – 2y – 4w kJ/mol (D) 4x + 4w + 2y + z kJ/mol

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53. The highest nucleophilicity among the following ions in aqueous medium is
‹œ#ëû oîöì’ ! öìÁ¬îû ö„þy xyëû’!Ýþîû ! vþz!„Ïþ!šþ!œ!¢!Ýþ ¢îÅy!•„þÚ
(A) PhO (B) OH (C) CH3COO (D) CH3S
54. How many chiral centres are present in the following compound ?
! öìÁî¬ û öëï†!Ýþöì“þ „þ“þ†%!œ „þy£zîyû œ ö„þw xyöìŠéÚ
CH3
H3C
H3C CH3

H3C

HO
(A) 7 (B) 8 (C) 9 (D) 10

CH2OH
H2SO4/ NBS
P Q
55. h
(Major) (Major)
S²Ì•y V S²Ì•y V
The structure of ‘Q’ is
‘Q’ ~îû †àþ £œ
Br
Br Br Br
Br
(A) (B) (C) (D)

56. Consider the SN1 solvolysis of the following halides in aqueous formic acid
‹œ#ëû šþîû!›„þ xÄy!¢öìvþ ! öìÁ¬îû £Äyœy£zvþ †%!œîû SN1 oyî„þ !îöìÙÕ¡ì’ (solvolysis) !îöìî‰þ y „þîû
Br
Br Br CH3
H3C
(i) CH—CH—CH3 (ii) (iii) C 6H5—CH—C 6H5 (iv)
H3C
Br
Which one of the following is correct sequence of the halides given above in the decreasing order of thier reactivity ?
! öìÁ¬îû ö„þy !Ýþ £Äyœy£zvþ †%!œîû ¢!„Êþëû“þyîû ¢!àþ„þ £Éy¢›y „Êþ›Ú
(A) (iii) > (iv) > (ii) > (i) (B) (ii) > (iv) > (i) > (iii) (C) (i) > (ii) > (iii) > (iv) (D) (iii) > (i) > (ii) > (iv)
57. Which of the following schemes would be the best for the synthesis of the compound, 2-bromo-1-chloro-4-
nitrobenzene ?
2-öîÊyöì›y-1-ö„Ïþyöìîûy-4- y£zöÝì þÆyöìî!Oöì îû ¢‚öìÙÕ¡ìöì’ ! öìÁî¬ û ö„þy þ™å•!“þ!Ýþ vþz_›Ú
Br2 HNO3 Cl2 Br2 Cl2 HNO3
(A) FeBr3 H2SO4 AlCl3 (B) FeBr3 AlCl3 H2SO4

Cl2 HNO3 Br2 Cl2 Br2 HNO3

(C) AlCl3 H2SO4 FeBr3 (D) AlCl3 FeBr3 H2SO4

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1 2
58. What is the difference in pH for rd and rd stages of neutralisation of 0.1 M CH3COOH with 0.1 M NaOH ?
3 3

1 2
0.1 M NaOH myîûy 0.1 M CH3COOH ~îû x‚Ÿ ~î‚ x‚Ÿ ²ÌŸ›öì îû •yþ™ ”%!Ýþöì“þ pH ~îû þ™yíÅ„þÄ £öìî
3 3

1 2
(A) 2log3 (B) 2log (C) 2log (D) 2log2
4 3



59. At a certain temp, the equilibrium constant (KC) is 16 for the reaction SO2 (g) NO2 (g) 
 SO3 (g) NO(g) . If
1.0 mole each of all the four gases are taken in a 1 L container, the concentration of NO2 at equilibrium will be

ö„þy “þyþ™›yeyëû 


SO2 (g) NO2 (g) 
 SO3 (g) NO(g) !î!„Êþëûy!Ýþîû ¢y›Ä•Ê%î„þ (KC) £œ 16Ð ë!” ‰þyîû!Ýþ †Äyöì¢îû ²Ì!“þ!Ýþîû 1.0
ö›yœ „þöìîû ~„þ!Ýþ 1 L þ™yöìe ö çëûy £ëû– “þöìî ¢y›ÄyîÞíyëû NO2 ~îû †y‘þüc £öìî
(A) 1.6 mol L–1 (B) 0.8 mol L–1 (C) 0.4 mol L–1 (D) 0.6 mol L–1
60. Consider the following P-V process for an ideal gas. Calculate the total work done in the process of abca loop.
Provided the process is carried out in a reversible way and path ‘c’ is isothermally performed
! öìÁ¬ ~„þ!Ýþ xy”ŸÅ †Äyöì¢îû P-V þ™å•!“þ!Ýþ !îöìî‰þ y „þîûÐ ²Ì!„Êþëûy!Ýþöì“þ abca œ%öìþ™ ö›yÝþ „,þ“þ„þyöìëÅîû þ™!îû›y ! ’Åëû „þîûÐ ²Ì!„Êþëûy!Ýþ þ™îûyî“Åþ
¦þyöìî ¢Á™§¬ „þîûy £öìëûöìŠé ~î‚ þ™í ‘c’ ö„þ ¢öì›y¡ìŒ ²Ì!„Êþëûyëû ¢Á™y” „þîûy £öìëûöìŠéÐ

a
1
P (atm) b
c
0.5

Litre
20 40 V

(A) – 6.14 L-atm (B) 6.14 L-atm (C) 20 L-atm (D) – 13.86 L-atm
61. Here are three possible synthesis of phenylpropylether. Which one would work ?
~…yöì !šþ y£zœ ö²Ìyþ™y£zœ £zíyîû ²Ìhß$þ!“þîû !“þ !Ýþ ¢½þyîÄ þ™å•!“þ ö”…yöì y £œÐ ö„þy !Ýþ „þyëÅ„þ!îû £öìîÚ
OH KNH2 Br
O
(i)

Br

NaOH
O
(ii) OH

Br

NaH
O
(iii) OH

(A) (i) only (B) (iii) only (C) (ii) or (iii) (D) (i) or (iii)
Ÿ%•›% ye (i) Ÿ%•%›ye (iii) (ii) îy (iii) (i) îy (iii)

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Ph Ph
dil. H2SO4
62. H3CO C—C—CH3 The major product is (²Ì•y vþzêþ™§¬ þ™”yíÅ £œ)
OH OH

Ph Ph

(A) H3CO C—C—CH3 (B) H3CO C—C—Ph

O Ph H3C O

Ph Ph Ph
(C) H3CO C C—CH3 (D) H3CO C—C—CH3
Ph O
63. The best reagent for the following conversion is
! öìÁ¬îû îû)þ™yhsþîû!Ýþîû öÇþöìe vþz_› !î„þyîû„þ!Ýþ £öìî
O

HO HO

(A) Zn–Hg/conc. HCl (B) Mg–Hg/H2O (C) NH2–NH2/ OH /heat (D) HI/red P, 150°C

Zn–Hg/†y‘þü HCl NH2–NH2/ OH /“þyþ™ HI/œyœ P, 150°C

O
(i) (CH3)2CuLi
64. A , the product (A) is [vþzêþ™§¬ þ™”yíÅ (A) £œ]
(ii) H3O

O O
H3C OH
OH
(A) CH3 (B) (C) (D)
CH3 CH3 CH3

65. A mineral having the formula AB2 crystalises in the CCP lattice with the A atoms occupying the lattice points.
What is the coordination number of the B atoms ?
~„þ!Ýþ …! ‹ þ™”yíÅ– ¢‚öì„þ“þ AB2– CCP œÄy!ÝþöìŸ ö„þœy!¢“þ £ëû– A þ™îû›y’% †%!œ œÄy!ÝþŸ !î¨% †%!œ x!•„þyîû „þöìîûÐ B þ™îû›y’%îû ö„þy!vÅþöì Ÿ
¢‚…Äy £öìî
(A) 4 (B) 6 (C) 8 (D) 12
66. The standard reduction potentials in acidic conditions are 0.77 V and 0.53 V, respectively, for Fe3+|Fe2+ and
I3– | I – couples. The equilibrium constant for the reaction ; 2Fe3 3 I – 


 2Fe
2
I3– is (2.303 RT/F = 0.06)

xy!ÁÔ„þ ›y•Äöì› ²Ì›y !î‹yîû’ !î¦þî £œ 0.77 V ~î‚ 0.53 V ëíy„Êþöì›– Fe3+|Fe2+ ~î‚ I3– | I – ë%öì@Âîû öÇþöìeÐ
2Fe3 3 I – 


 2Fe
2
I3– !î!„Êþëûyîû ¢y›Ä•Ê%î„þ £œ (2.303 RT/F = 0.06)

(A) 2 × 108 (B) 108 (C) 104 (D) 10–8

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67. Which of the following graph truly represents the titration of CH3COOH solution against NaOH solution ?

! öìÁ¬îû ö„þy öœ…!‰þe!Ýþ NaOH oî’ myîûy CH3COOH oîöì’îû Ýþy£zöÝì þÆŸ öì„þ ¢!àþ„þ ¦þyöìî ²Ì”ŸÅ „þöìîûÚ
[Cond. Conductance of solution]

[Cond. oîöì’îû þ™!îûîy!£“þy]

[VNaOH Volume of NaOH added to CH3COOH solution]

[VNaOH CH3COOH oîöì’ öëy† „þîûy NaOH ~îû xyëû“þ ]

Cond.
Cond.

Cond.

Cond.
(A) (B) (C) (D)

VNaOH VNaOH VNaOH VNaOH

68. Consider the following ions

! öìÁ¬îû xyëû’ †%!œ !îöìî‰þ y „þîû

H3C
(i) N N (ii) O2N N
H3C
N N

(iii) O N (iv) N
H3C
N N
The reactivities of these ions in azo-coupling reactions (under similar conditions) will be such that

~„þ£z Ÿöì“þÅ ~£z xyëû’ †%!œîû xÄyöì‹y„þyþ™!œ‚ !î!„Êþëûyëû ¢!„Êþëû“þyîû „Êþ› £öìî
(A) (i) < (iv) < (ii) < (iii) (B) (i) < (iii) < (iv) < (ii)
(C) (iii) < (i) < (ii) < (iv) (D) (iii) < (i) < (iv) < (i)
69. A quantity of 3.125 g of a mixtue of KCl and NaCl dissolved in 1 kg of water produces a depression of 0.186°C in
freezing point. The molar ratio of KCl to NaCl in the solution (assuming complete dissociation of the salts) is

1 kg ‹ö윖 KCl ~î‚ NaCl ~îû 3.125 g !›×’öì„þ oî#¦)þ“þ „þîûy £œÐ oî’!Ýþîû !£›yöìA„þîû xî › £œ 0.186°CÐ oîöì’ KCl ~î‚
NaCl ~îû ö›yœyîû x %þ™y“þ £öìî Sœî’ †%!œîû ¢Á™)’Å !îöìëûy‹ •öìîû yçV
(Kf = 1.86 deg/molal)
(A) 1 : 3 (B) 2 : 3 (C) 1 : 1 (D) 3 : 1
70. A positron is emitted from 11Na23. The ratio of the mass number and atomic number in the resulting nuclide is
23 öíöì„þ ~„þ!Ýþ þ™!‹ÝþÆ ! †Å“þ £ëûÐ vþzêþ™§¬ ! vþz!„Ïþëûyöìvþ ¦þîû ¢‚…Äy ç þ™yîû›y’!î„þ ¢‚…Äyîû x %þ™y“þ £öìî
11Na

22 22 23 23
(A) (B) (C) (D)
10 11 10 12

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Category-II (Q. 71 to Q. 75)

Only one answer is correct. Correct answer will fetch full marks 2. Incorrect answer or any combination of more
than one answer will fetch –½ marks. No answer will fetch 0 marks.

71. Find the mass (in g) of P4O10 produced if 31 g phosphorous (P4) is mixed with 32 g of O2
[Atomic mass ; P = 31, O = 16]
31 g šþ¢öìšþyîûyöì¢îû (P4) ¢yöìí 32 g O2 !›!דþ „þ!îûöìœ vþzêþ™§¬ P4O10 ~îû ¦þîû (g ~„þöì„þ) £öìî
[þ™yîû›y’!î„þ ¦þîû ; P = 31, O = 16]
(A) 26.8 (B) 56.8 (C) 568 (D) 5.68

72. In a system, A(s)  
 2B(g) + 3C(g), if the concentration of C at equilbrium is increased by a factor 2, it will
cause the equilibrium concentration of B change to


 2B(g) + 3C(g) ¢‚Þíy!Ýþöì“þ ¢y›ÄyîÞíyëû C ~îû †y‘þüc ë!” 2 †%’ î,!å• „þîûy £ëû– “þy£öìœ ¢y›ÄyîÞíyëû B ~îû †y‘þüc þ™!îûî!“Åþ“þ
A(s) 
£öìî
(A) two times of its original value (B) 2 2 times of its original value

›)œ þ™!îû›yöì îû 2 †%’ ›)œ þ™!îû›yöì îû 2 2 †%’

1
(C) one-half of its original value (D) times of its original value
2 2

1
›)œ þ™!îû›yöì îû xöì•Å„þ ›)œ þ™!îû›yöì îû †%’
2 2
73. Equal volumes of 0.02 M AgNO3 and 0.02 M HCN were mixed, calculate [Ag+] at equilibrium.
[Take Ka(HCN) = 9 × 10–10, Ksp(AgCN) = 4 × 10–16]
¢› xyëû“þöì 0.02 M AgNO3 ~î‚ 0.02 M HCN ~„þöìe !›!דþ „þîûy £œÐ ¢y›ÄyîÞíyëû [Ag+] ! ’Åëû „þîû
[•îû Ka(HCN) = 9 × 10–10, Ksp(AgCN) = 4 × 10–16]
(A) 6.67 × 10–4 M (B) 6.00 × 10–3 M (C) 6.7 × 10–5 M (D) 4.5 × 10–8 M
74. A crystal is made of particles A and B. A forms FCC packing and B occupies all the octahedral voids. If all the
particles along the plane as shown in figure are removed, then the formula of the crystal would be
~„þ!Ýþ ö„þœy¢ A ~î‚ B „þ’y myîûy †!àþ“þÐ A †àþ „þöìîû FCC þ™Äy!„þ‚ ~î‚ B x!•„þyîû „þöìîû ¢›hßþ xTþ“þœ„þ#ëû š¤þy„þy ‹yëû†yÐ ë!” !‰þöìe
²Ì”!ŸÅ“þ “þöìœ vþzþ™!Þí“þ ¢›hßþ „þ’y†%!œ ¢!îûöìëû ö çëûy £ëû– “þöìî ö„þœyöì¢îû ¢‚öì„þ“þ £öìî

–A
–B

(A) AB (B) A5B7 (C) A7B5 (D) A2B3

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75. For the elimentary reaction 2A + B2 2AB, calculate how much the rate of reaction will change if the
volume of the vessel is reduced to one third of its original volume ?
ö›ï!œ„þ !î!„Êþëûy 2A + B2 2AB ~îû öÇþöìe !î!„Êþëûyîû £yîû „þ“þÝþy þ™!îûî“Åþ „þîûöìî ë!” þ™yöìeîû xyëû“þ £Éy¢ „þöìîû xyëû“þöì îû
~„þéôé“,þ“þ#ëûy‚Ÿ „þîûy £ëûÚ
1 1
(A) times (†%’) (B) 9 times (†%’) (C) 27 times (†%’) (D) times (†%’)
27 54

Category-III (Q. 76 to Q. 80)

One or more answer(s) is (are) correct. Correct answer(s) will fetch full marks 2. Any combination containing one
or more incorrect answer will fetch 0 marks. Also no answer will fetch 0 marks. If all correct answers are not
marked and also no incorrect answer is marked then score = 2 × number of correct answers marked actual
number of correct answers.

76. Which of the following process is involved in the extraction of lead from galena ?
! öìÁ¬îû ö„þy þ™å•!“þ S†%!œV †Äyöìœ y öíöì„þ öœöìvþîû ! ÜñyŸöì xhsþÅ ¦%þ=þÚ
(A) Self reduction (B) Calcination (C) Roasting (D) Froth floatation process
ßþº“þƒ !î‹yîû’ ¦þßþ¿#„þîû’ “þyþ™‹yîû’ öšþ y ¦þy¢ þ™å•!“þ
77. Identify the compound that gives same Osazone
öëï†!Ýþ/öëï† †%!œöì„þ ¢ y=þ „þîû öë †%!œ ~„þ£z ç¢yöì‹y †àþ „þöìîû

O O OH O

H OH HO H O HO H
HO H HO H HO H HO H
(A) HO H (B) H OH (C) HO H (D) HO H
H OH H OH H OH H OH

OH OH OH OH

78. Radiation of wavelength 200 Å falls on a platinum surface. If the work function of the metal is 5 eV, which of the
following results are correct about the experiment ?
200 Å “þîûA†÷ì”öì‡ÅÄîû !î!„þîû’ ²Õy!Ýþ y› “þöìœîû vþzþ™îû xyþ™y!“þ“þ £ëûÐ ë!” •y“%þîû „þyëÅ xöìþ™Çþ„þ 5 eV £ëû– “þöìî ! öìÁ¬îû ö„þy †%!œ ¢!àþ„þ
þ™îû#Çþy ¢Á™öì„ÅþÚ
(A) The velocity of photoelectrons increase with increase in intensity of radiation
xyöìœy„þ £zö위þÝþÆöì îû öî† î,!å• þ™yëû !î!„þîûöì’îû “þ#îÊ“þy î,!å•îû ¢yöìí
(B) Photo emission of electrons takes place
xyöìœy„þ £zö위þÝþÆöì îû ! †Å› ‡öìÝþ
(C) The threshold frequency of the metal is 1.21 × 1015 sec–1
•y“%þîû ²Ìyîû!½þ„þ „þÁ™yA„þ £œ 1.21 × 1015 sec–1
(D) Photo emission of electrons does not occur
xyöìœy„þ £zöœ
ì „þÝþÆöì îû ! †Å› ‡öìÝþ y

19
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79. Which of the following acid will give isopentane on decarboxylation with sodalime ?
! öìÁ¬îû ö„þy xÄy!¢vþ!Ýþ/xÄy!¢vþ †%!œ ö¢yvþyœy£z› !”öìëû !vþ„þyîÅ!:ö윟 „þ!îûöœ
ì xy£zö¢ì yöìþ™öìrÝþ ö”öìîÚ
COOH COOH
(A) H3C—C—CH2CH3 (B) H3C—CH—CH—CH3
CH3 CH3

COOH
(C) H2C—CH—CH—CH3 (D) H3C—CH—CH2—COOH
CH3 CH3

80. Dipole moment of which compound(s) is/are not zero ?

ö„þy öëï†/öëï† †%!œîû !möì›îû% ¼y›„þ Ÿ) Ä ëûÚ
Cl

(A) (B) (C) (D)

Cl
O

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