.

PHYSICS Max Marks: 100

(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
x 2
,
2
1. In a typical combustion engine the workdone by a gas molecule is given by W   e kT

where x is the displacement, k is the Boltzmann constant and T is the temperature. If 

and  are constants, dimensions of  will be:
1)  M 2 LT 2  2)  M 0 LT 0  3)  M LT 2  4)  M LT 1 
Key: 2
Solution:
as  x 2    KT    M 1 L2T 2 
    M 1 L0T 2 

And as   2   M 1L2T 2     2    M 0 L2T 0 

      M  LT
'
 
2. Four identical solid spheres each of mass ‘m’ and radius ‘a’ are placed with their centres
on the four corners of a square of side ‘b’. The moment of inertia of the system about one
side of square where the axis of rotation is parallel to the plane of the square is:
4 2 4 2 8 2 8 2
1) ma  2mb 2 2) ma 3) ma  2mb 2 4) ma  mb 2
5 5 5 5
Key: 3
Solution:
Given

axis
then moment of inertia about the given axis will be
 2  8
I  4  ma 2   2.  mb 2   ma 2  2mb 2
5  5
3. Find the gravitational force of attraction between the ring and sphere as shown in the
diagram, where the plane of the ring is perpendicular to the line joining the centres. If
8R is the distance between the centres of a ring (of mass ‘m’) and a sphere (mass M’)
where both have equal radius R
m M
R R
 
X 8R Y

8 GmM 1 GMm 2 2 GMm 8 GmM

1) . 2) .2
3) . 2 4) .
27 R 2 3 8 R 3 R 9 R
Key: 1
Solution:

 M

m M m

 gravitational force between them will be

Gm 8R 8 GMm
F M
 R  8R 2 
2
R2  8R2 27 R 2

4. Consider the combination of 2 capacitors C1 and C2 , with C2  C1 , when connected in

15
parallel, the equivalent capacitance is times the equivalent capacitance of the same
4
C
connected in series. Calculate the ratio of capacitors, 2
C1
15 15 111 29
1) 2) 3) 4)
4 11 80 15
Key: No Answer
Solution:
15 C C 15 C 15 xC12
Given CPeff  Cseff  C1  C2  1 2 .  let 2  x  1  x  C1 
4 C1  C2 4 C1 4 1  x  C1
7  49  64
 1  x 2  2 x  4  15 x  4 x 2  7 x  4  0 x
2
5. A large number of water drops, each of radius r, combine to have a drop of radius R. if
the surface tension is T and mechanical equivalent of heat is J, the rise in heat energy per
unit volume will be:
3T 1 1  3T 2T 1 1  2T
1)    2) 3)    4)
j r R rJ J r R rJ
Key: 1
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Solution:
loss of surface energy = N  4r 2T   4R 2T
Where R 3  Nr 3
 heat produced  4T  Nr 2  R 2 
J
4T  Nr 2  R 2 
 heat produced per unit volume 
4 3
R J
3
3T  Nr 2 1  3T  1 1 
  3    
J  R R  J  r R 
6. Five equal resistances are connected in a network as shown in figure. The net resistance
between the points A and B is:

R 3R
1) 2) 2R 3) R 4)
2 2
Key: 3
Solution:
After redrawing
D
R
R

A B,C

R R
E
as it is balanced  effective  R
7. In a Young’s double slit experiment two slits are separated by 2 mm and the screen is
placed one meter away. When a light of wavelength 500 nm is used, the fringe separation
will be:
1) 1 mm 2) 0.25 mm 3) 0.75 mm 4) 0.50 mm
Key: 2
Solution:
D
in YDSE fringe width 
d
1 500 109
  0.25 mm
2 103
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8. A planet revolving in elliptical orbit has:
A. a constant velocity of revolution
B. has the least velocity when it is nearest to the sun.
C. its areal velocity is directly proportional to its velocity.
D. areal velocity is inversely proportional to its velocity.
E. to follow a trajectory such that the areal velocity is constant.
Choose the correct answer from the options given below:
1) D only 2) C only 3) E only 4) A only
Key: 3
Solution:
When a planet revolving in elliptical orbit its velocity is not a constant but areal velocity
Remains constant

9. An alternating current is given by the equation i  i1 sin t  i2 cos t . The rms current will
be:
1
1 2 1 1 2 2 12 1
1)
2
 i1  i2  2)
2
 i1  i2  3)  i1  i2 
2
4)
2
 i12  i22  2
Key: 4
Solution:
If  i1 sin t  i2 cos t


i12  i2 2  2i1 , i2 cos   1

 irms 2  i12  i22  2

 irms   
2  2 
10. Find the electric field at point P (as shown in figure) on the perpendicular bisector of a
uniformly charged thin wire of length L carrying a charge Q. The distance of the point P
3
from the centre of the rod is a  L.
2

Q Q 3Q Q
1) 2) 3) 4)
4 0 L2 2 30 L2 4 0 L2 30 L2
Key: 2

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Solution:

a  r

net filled will be along Los

as dELos 
1 dl
cos   dELos 
Q
 
L a sec 2 d  cos 

Q
cos d 
4 0 r 2 4 0 2
a sec 2
40 La
0
Q Q  
E  cos d   sin 0 ,  0  tan 1  1  
4 0 La 0 2 0 La   3 
Q
E
20 L2 3
11. The normal density of a material is  and its bulk modulus of elasticity is K. the
magnitude of increase in density of material, when a pressure P is applied uniformly on
all sides, will be:
PK K P K
1) 2) 3) 4)
 P K P
Key: 3
Solution:
d  dv
say m  V   0
 V

dv dp p
 d    k 
v but  dv / v   dv / v  (given dp=p)
 p  P
 d         d 
 k  K
12. If 1 and  2 are the wavelengths of the third member of Lyman and first member of the
Paschen series respectively , then the value of 1 :  2 is:
1) 1: 9 2) 7 :108 3) 1: 3 4) 7 :135
Key: 4
Solution:
c  1 1  c 1 1
 13.6   2  2   13.6  2  2 
1  1 4  2 3 4 
1 16  9  / 9  16 7
 
 2 16  1 / 1 16 135

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13. Given below are two statements : one is labeled as Assertion A and the other is labelled
as Reason R.
Assertion A: An electron microscope can achieve better resolving power than an optical
microscope.
Reason R :The de Broglie’s wavelength of the electrons emitted from an electron gun is
much less than wavelength of visible light.
In the light of the above statements, choose the correct answer from the options given
below:
1) Both A and R are true but R is NOT the correct explanation of A
2) A is true but B is false:
3) A is false but R is true.
4) Both A and B are true and R is the correct explanation of A.
Key: 4
Solution:
The statements are correct but also correct explanation

14. Given below are two statements: one is labelled as Assertion A and the other is labelled
as Reason R.
Assertion A: Body ‘P’ having mass M moving with speed ‘u’ has head-on collision
elastically with another body ‘Q’ having mass ‘m’ initially at rest. If m << M, body ‘Q’
will have a maximum speed equal to ‘2u’ after collision.
Reason R: During elastic collision, the momentum and kinetic energy are both conserved.
In the light of the above statements, choose the most appropriate answer from the options
given below:
1) Both A and R are correct but R is NOT the correct explanation of A.
2) A is correct but R is not correct.
3) A is not correct but R is correct.
4) Both A and B are correct and R is the correct explanation of A.
Key: 4
Solution:
Mu  m  0   Mv1  mv2
1 1 1
Mu 2  Mv12  mv 2 2
2 2 2
Applying M  m  V1  2u
15.  
Assume that a tunnel is dug along a chord of the earth, at a perpendicular distance R 2
from the earth’s centre, where ‘R’ is the radius of the Earth. The wall of the tunnel is
frictionless. If a particle is released in this tunnel, it will execute a simple harmonic
notion with a time period:
R 2R 1 g g
1) 2 2) 3) 4)
g g 2 R 2R
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Key: 1
Solution:

 r }o y
C R
2

at a disp’y’ from’O’
 GMr 
ma   m  3 sm 
 R 
GMm
ma   y
R3
 GM  g R
 a   3  y     y  T  2
 R  R g
16. If two similar springs each of spring constant K1 are joined in series, the new spring
constant and time period would be changed by a factor:
1 1 1 1
1) , 2 2) ,2 2 3) , 2 4) ,2 2
2 2 4 4
Key: 1
Solution:
1 1 1 k
as    Ks  1
K s K1 K1 2
m m2
 T 1  2  2  2T
KS k1
1
i.e K s  K1 & T 1  2T
2
17. The temperature  at the junction of two insulating sheets, having thermal resistances R1
and R2 as well as top and bottom temperatures 1 and 2 (as shown in figure) is given by:

1 R2  2 R1 2 R2  1 R1 1 R2  2 R1 1 R1  2 R2
1) 2) 3) 4)
R2  R1 R2  R1 R1  R2 R1  R2
Key: 3

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Solution:

 

1 R1 R 2 2
 
 1   1  2
at steady state 
R1 R1  R2
 R11  R21   R1  R2    R11  R12
1 R2  2 R1

R1  R2
18. LED is constructed from Ga-As-P semiconducting material. The energy gap of this LED
is 1.9 eV. Calculate the wavelength of light emitted and its colour.
[ h  6.63  1034 Js and c  3  108 ms 1 ]
1) 654 nm and red colour 2) 1046 nm and blue colour
3) 654 nm and orange colour 4) 1046 nm and red colour
Key: 1
Solution:
c
as  E gap

6.63  1034  3  108
  6.54  107 m
1.9 1.6 10 19
  654nm i.e Red
19. A particle is moving with uniform speed along the circumference of a circle of radius R
3
under the action of a central fictitious force F which is inversely proportional to R . Its
time period of revolution will be given by:
5 3 4
1) T  R 2 2) T  R 2 3) T  R 2 4) T  R 3
Key: 3
Solution:
3
mR2  F  K R
 2  R  4  T 2  R 4  T  R 2

20. A short straight object of height 100 cm lies before the central axis of a spherical mirror
whose focal length has absolute value f  40 cm. The image of object produced by the
mirror is of height 25 cm and has the same orientation of the object. One may conclude
from the information:
1) Image is virtual, opposite side of convex mirror.
2) Image is virtual, opposite side of concave mirror.
3) Image is real, same side of concave mirror.
4) Image is real, same side of convex mirror.
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Key: 1
Solution:
Given real object and the image is erect
1 1 1 y x
As   & I m I
xI xo xF yo xo
25 1 x
Given m  Ve m    I
100 4 xo
 4 xI   xo  xI  Ve  virtual image
1 1 1 4
    xF  xI  Ve
xI 4 xI xF 3
f  40cm convex mirror
(NUMERICAL VALUE TYPE)
This section contains 10 questions. Each question is numerical value type. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded-off to second decimal place. (e.g. 6.25, 7.00, 0.33, 30, 30.27, 127.30). Attempt any five questions out of 10.
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
21. A container is divided into two chambers by partition. The volume of first chamber is 4.5
litre and second chamber is 5.5 litre. The first chamber contain 3.0 moles of gas at
pressure 2.0 atm and second chamber contain 4.0 moles of gas at pressure 3.0 atm. After
the partition is removed and the mixture attains equilibrium pressure existing in the
1
mixture is x 10 atm. Value of x is _________.

Key: 25.5
Solution:

4.5 lt 5.5 lit

3 mol T1 4 mol T2  T mix
2atm 3atm

f f f
As Qnet  0   2  4.5    3  5.5   P  5.5  4.5 
2 2 2
 9  16.5  P 10   P  2.55 atm  P  25.5 10 1 atm
22. The circuit contains two diodes each with a forward resistance of 50  and with infinite
reverse resistance. If the battery voltage is 6 V, the current through the 120  resistance is
________mA.

Key: 20.

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Solution:

D2 : Reverse biased acts as  resistance

6 6
 current in 120  , I=  A I  20 mA
120  130  50 300

23. The maximum and minimum amplitude of an amplitude modulated wave is 16 V and 8 V
respectively. The modulation index for this amplitude modulated wave is x  10 2 . The
value of x is _______.

Key: 33.33

Solution:

E max 16 E 1  m  16 1
  c   1  m  2  2m  3m  1  m 
E min 8 Ec 1  m  8 3

1
m  0.3333  x  102  x  33.33
3

24. In an electrical circuit, a battery is connected to pass 20 C of charge through it in a certain

given time. The potential difference between two plates of the battery is maintained at 15
V. The workdone by the battery is _____________ J.

Key: 300

Solution:

Work done by the battery = Eq

 15  20  300 J

25. As shown in the figure , a block of mass 3 kg is kept on a horizontal rough surface of
1
coefficient of friction . The critical force to be applied on the vertical surface as
3 3
shown at an angle 60 with horizontal such that it does not move, will be 3x . The value
 3 1
of x will be ________.  g  10m / S 2 ;sin 60  ; cos 60  
 2 2

1
 m  3kg
3 3
60

Key: 0.33
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Solution:

N
F
60

mg

>f

N  mg  F sin 60  0

3 F  3 
N  mg  F And F cos 60  f  N     mg 

F
2 2  2 

F 1  3 
   10 3  F  3 3  20 3  3F
2 3 3 2 

10
 2 3F  20 3  F  10 N 3 x  10  x   0.33
3

26. In a series LCR resonant circuit, the quality factor is measured as 100. If the inductance is
increased by two fold and resistance is decreased by two fold, then the quality factor after
this change will be_____.

Key: 200 2 (282.84)

Solution:

L 1 1 L
Q where   if f= also fixed then Q1  400  Q   100 (given)
R LC R C

1 2L 1 L
 Q'  2 2  200 2  282.84
R C R C
2

27. The mass per unit length of a uniform wire is 0.135g/cm. A transverse wave of the form
y  0.21 sin  x  30t  is produced in it, where x is in meter and t is in second. Then, the

expected value of tension in the wire is x  10 2 N. Value of x is________(Round-off to the

nearest integer)

Key: 1215

Solution:

Wave velocity c  30 m/s

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 T
And as c   T  C 2  0.135  101  900  T  12.15  x  1215


28. A person standing on a spring balance inside a stationary lift measures 60 kg. the weight
of that person if the lift descends with uniform downward acceleration of 1.8 m / s 2 will
be _______N.  g  10m / s 2 

Key: 492

Solution:

Given mg=60g

Now in an accelerating lift w1  m  g  a 

w 1  60 10  1.8  N  6  8.2 kgwt w1  49.2 kgwt  492 N

29. A radiation is emitted by 1000 W bulb and it generates an electric field and magnetic
field at P, placed at a distance of 2 m. The efficiency of the bulb is 1.25%. The value of
peak electric field at P is x  101V / m . Value of x is _______. (Round-off to the nearest
interger) [Take 0  8.85  10 12 C 2 N 1m 2 , c  3  108 ms 1 ]

Key: 137

Solution:

s r p P 1
as I  2
 o E 0 2C
4r 2

1.25
1000
100 1
  8.85  1012  E 0 2  3 108
4  4 2

 E 0 2  187.2538  E 0  13.68 v / m  x  137


30. A boy pushes a box of mass 2 kg with force F  20i  10 j N on a frictionless surface. If
 
the box was Initially at rest, then_______ m is displacement along the x -axis after 10 s.

Key: 500

Solution:

2a x  20  a x  10m / s 2

1
In 10sec x  0  10  102  500m
2

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CHEMISTRY Max Marks: 100

(SINGLE CORRECT ANSWER TYPE)

This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. Find A, B and C in the following reactions:
NH 3  A  CO2   NH 4 2 CO3

 NH 4 2 CO3  H 2O  B  NH 4 HCO3
NH 4 HCO3  NaCl  NH 4 Cl  C

1) A  O2 ; B  CO2 ; C  Na2CO3 2) A  H 2O; B  O2 ; C  NaHCO3

3) A  H 2O; B  CO2 ; C  NaHCO3 4) A  H 2O; B  O2 ; C  Na2CO3
Key: 3
Solution:
2NH 3  H 2 O CO 2   NH 4  2 CO3
A

 NH 4 2 CO3  H 2O  CO 2  2NH 4 HCO3

 B

NH 4 HCO3  NaCl  NaHCO3  NH 4 Cl

C

32. The structure of Neoprene is:

CH 2 CH n
Cl

CH 2 C CH CH 2 n
1) 2) CN

CH 2 CH CH CH 2 CH 2 CH n

3) 4) CN

Key: 1
Solution:

CH 2 =C CH CH 2

Chloroprene is Cl Neoprene is an addition polymer of chloroprene

CH 2 C CH CH 2 n
Cl

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33. Statements about heavy water are given below:
A. Heavy water is used in exchange reactions for the study of reaction mechanisms.
B. Heavy water is prepared by exhaustive electrolysis of water.
C. Heavy water has higher boiling point than ordinary water.
D. Viscosity of H 2O is greater than D 2O .
Choose the most appropriate answer from the options given below:
1) A only C only 2) A and B only
3) A, B and C only 4) A and D only
Key: 3

Solution:

A, B, and C only

Viscosity of D 2O is greater than that of H 2O

34. The presence of ozone in troposphere:

1) generates photochemical smog

2) protects us from the UV radiation

3) protects us from the X-ray radiation

4) protects us from greenhouse effect

Key: 1

Solution:

In troposphere ozone causes photochemical smog

35. The orbital having two radial as well as two angular node is:

1) 4f 2) 5d 3) 3p 4) 4d

Key: 2
Solution:
For 5d orbital, no. of redial nodes =2, ( n  l  1 )
 of angular nodes =2, (l-value)

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36. Given below are two statements:
Statement I: A mixture of chloroform and aniline can be separated by simple distiliation
Statement II: When separating aniline from a mixture of aniline and water by steam
Distillation aniline boils below its boiling point.
In the light of the above statements, choose the most appropriate answer from the options
given below:
1) Statement I is true but Statement II is false
2) Statement I is false but Statement II is true
3) Both Statement I and Statement II are false
4) Both statement I and Statement II are true
Key: 4
Solution:
S1 Chloroform and aniline differ much in their boiling points.

( 61.2c ) (184.1c )
 They can be separated by single distiliation
S2 In the steam distiliation of aniline it boils at a temperature much below its normal
boiling point. It boils off at a lamp below 100c
37. Math list-I with List-II.
List-I List-II
Electronics Configuration of elements i H in kJ mol1
(a) 1s2 2s 2 (i) 801
(b) 1s 2 2s 2 2p 4 (ii) 899
(c) 1s 2 2s 2 2p3 (iii) 1314
(d) 1s 2 2s2 2p1 (iv) 1402
Choose the most appropriate answer from the options given below:
1)  a    i  ,  b    iv  ,  c    iii  ,  d    ii 

2)  a    ii  ,  b    iii  ,  c    iv  ,  d    i 

3)  a    i  ,  b    iii  ,  c    iv  ,  d    ii 

4)  a    iv  ,  b    i  ,  c    ii  ,  d    iii 

Key: 2
Solution:
Order of I.E values of Be, B, N and ‘O’ is N  O  Be  B
15 | Pa g e
38. Which one of the following lanthanoids does not form MO 2 ? [M is lanthanoid metal]
1) Nd 2) Dy 3) Yb 4) Pr
Key: 3
Solution:
Configuration of Yb is 6s 2 4f 14 Its main oxidation state is +2 only.
39. Given below are two statements:
Statement I: o  Nitrophenol is steam volatile due to intramolecular hydrogen bonding.
Statement II: o  Nitrophenol has high melting due to hydrogen bonding.
In the light of the above statements, choose the most appropriate answer from the options
given below:
1) Both Statement I and Statement II are false
2) Statement I is true but Statement II is false
3) Both Statement I and statement II are true
4) statement I is false but Statement II is true
Key: 2
Solution:
o  Nitrophenol - intramolecular hydrogen bonding-more volatile (i.e) lower B.P

p-nitrophenol-intramolecular hydrogen bonding – less volatile-(i.e) higher B.P

p-nitrophenol has higher m.p because if its symmetric structure which may lead to
close packing in solid state
40. Which of the following is ‘a’ FALSE statement?
1) Carius method is used for the estimation of nitrogen in an organic compound
2) Phosphoric acid produced on oxidation of phosphorus present in an organic compound
is precipitated as Mg 2 P2O7 by adding magnesia mixture.
3) Carius tube is used in the estimation of sulphur in an organic compound.
4) Kjeldahl’s method is used for the estimation of nitrogen in an organic compound.
Key: 1
Solution:
Estimation of 'S' and ' X ' carius method
Estimation of ' N ' -Kjeldahl method and dumes method

16 | Pa g e
 A
Hydrolysis B

41)  C4 H8Cl 2  373 K  C4 H8O 

B reacts with Hydroxy1 amine but does not give Tollen’s test. Identify A and B
1) 1,1-Dichlorobutane and 2-Butanone
2) 1,1-Dichlorobutane and Butanal
3) 2,2-Dichlorobutane and Butan-2-one
4) 2,2-Dichlorobutane and Butanal
Key: 3
Solution:
O

=
CH3  CH 2  CCl2  CH3 aq KOH CH3  CH2  C  CH3
 C4 H8Cl2  Hydrolysis  C4 H8 O

Gem halides give the corresponding carbonyl compounds on alkaline hydrolysis

42) An amine on reaction with benzenesulphonyl chloride produces a compound insoluble in
alkaline solution. This amine can be prepared by ammonolysis of ethyl chloride. The
correct structure of amine is:
NH CH 2CH 2CH 3

H
1) 2) CH 3CH 2CH 2 N  CH 2CH 3
3) CH 3CH 2CH 2 NHCH3 4) CH3CH 2 NH 2
Key: 2
Solution:
A 2 amine gives a product insoluble in alkaline solutions when treated with C6 H 5SO 2Cl
But the 2 amine is obtained by ammonolysis of ethyl chloride .
 The 2 amine has to be CH 3  CH 2  CH 2  NH  CH 2 CH 3

43) For the given reaction:

CH 2CH 3

Br2 'A'
UV light (major product)
monobrominated
CN
What is ' A ' ?
17 | Pa g e
 1) 2)

3) 4)
Key: 1
Solution:
CH 2 CH 3 Br

CH
CH 3

Br2
UV light

CN

CN

as kOH
monobominated

(Radical Substitution)
44) Compound A used as a strong oxidizing agent is amphoteric in nature. It is the part of
lead Storage batteries. Compound A is:
1) PbSO 4 2) PbO 2 3) PbO 4) Pb3O 4
Key: 2
Solution:
PbO 2 strong oxidant.Its amphoteric nature is reflected in its reaction with alkali forming
Plumbate.
Used in lead strong battery.
45. Which of the following vitamin is helpful in delaying the blood clotting?
1) Vitamin K 2) Vitamin B 3) Vitamin E 4) Vitamin C
Key: 1
Solution:
18 | Pa g e
 Vitamin K
Helpful in delaying blood clotting (NCERT)
46. Match List-I with List-II.
List-I List-II
(Ore) (Element Present)
(a) Kernite (i) Tin
(b) Cassiterite (ii) Boron
(c) Calamine (iii) Fluorine
(d) Cryolite (iv) Zinc
Choose the most appropriate answer from the options given below:
1)  a    ii  ,  b    i  ,  c    iv  ,  d    iii 
2)  a    i  ,  b    iii  ,  c    iv  ,  d    ii 
3)  a    ii  ,  b    iv  ,  c    i  ,  d    iii 
4)  a    iii  ,  b    i  ,  c    ii  ,  d    iv 
Key: 1
Solution:
Kernite : Na 2B4O7 4H 2O
Cassiterite : SnO 2
Calamine : ZnCO3
Cryolite : 3NaFAlF3
47. Identify the major products A and B respectively in the following reactions of phenol:
OH

(i) CHCl3NaOH Br2 in CS2

B A
(ii) H 3O
 273 K

OH OH
OH

OH CHO

Br and

CHO Br
1) and 2)

OH OH

OH
OH

Br CHO and
and
CHO
Br
3) 4)

19 | Pa g e
Key: 2
Solution:
OH OH

Br2 in CS2
273 K Major

Br
OH
OH
CHO

(i) CHCl3 NaOH

(ii) H 3O
 Major

48. On treating a compound with warm dil. H 2SO 4 , gas X is evolved which turns K 2Cr2O 7
paper acidified with dil. H 2SO 4 to a green compound Y, X and Y respectively are:
1) X  SO 2 , Y  Cr2O3 2) X  SO3 , Y  Cr2O3
3) X  SO3 , Y  Cr2 SO4 3 4) X  SO 2 , Y  Cr2 SO4 3

Key: 4
Solution:

dil H2SO4
Sulphite SO2g
warm

SO 2 g  reduces acidified dichronite to chronic sulphate, Cr2  SO 4 3 which is

is green in colour
49. For the given reaction:
CH CHBr
1. NaNH2 (A)
CH3 2. Red hot iron tube, 873 K (major product)

What is ' A ' ?

CH CH NH 2

CH 3
1) 2) 3) CH3CH 2CH 2 NH 2 4)

20 | Pa g e
Key: 2
Solution:
NaNH 2
CH3  CH  CHBr CH 3  C  CH
 HBr

red hot iron tube

50. Given below are two statements: one is labelled as Assertion A and the other is labelled
As Reason R.
Assertion A: Dipole-dipole interactions are the only non-covalent interactions, resulting
in hydrogen bond formation.
Reason R: Fluorine is the most electronegative element and hydrogen bonds in HF are
symmetrical.
In the light of above statements, choose the most appropriate answer from the options
given below:
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true but R is NOT the correct explanation of A
3) A is true but R is false
4) A is false but R is true
Key: 4
Solution:
S-1 : False
S-2: True
(NUMERICAL VALUE TYPE)
This section contains 10 questions. Each question is numerical value type. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded-off to second decimal place. (e.g. 6.25, 7.00, 0.33, 30, 30.27, 127.30). Attempt any five questions out of 10.
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
51. For a chemical reaction A  B  C  D
 H
r

 80kJ mol1  the entropy change  r S depends on the temperature T(in K) as

 r S  2T (J K 1mol1 ).

Minimum temperature at which it will become spontaneous is_______ K. (Integer)

Key: 201

21 | Pa g e
Solution:
For A  B  C  D ,
H  80  103 J mol1
S  2T J K 1 mol1
From G   H   TS for minimum temperature at which it becomes Spontaneous
H   TS  T  2T   4T 2
80 103
 T2   20 103
4
Or T  200K
52. 224 mL of SO2g  at 298 K and 1 atm is passed through 100 mL of 0.1 M NaOH
solution.The non-volatile solute produced is dissolved in 36 g of water. The lowering of
vapour Pressure of solution (assuming the solution is dilute) ( P H O  24 mm of Hg) is
2

2
x  10 mm of Hg, the value of x is ________ (Interger answer)
Key: Po  Ps  18.102
Solution:
1 224 103
PV 
no. of moles of SO 2 n  0.0821 298
RT
 9  103
= 9 milli moles
mill moles NaOH  0.1100  10
SO 2 ClO  NaOH ag   Na 2SO3

9 10 0
9-5 10-10 5
36
No. of moles of H 2 O  2
18
Po  Ps 3  5 10 3 15  24 103
 2 Po  Ps 
Po 2 2
Po  Ps  18.  102
53. 3.12 g of oxygen is adsorbed on 1.2 g of platinum metal. The volume of oxygen adsorbed
per gram of the adsorbent at 1 atm and 300 K in L is_______.
[R=0.0821 L atm K 1mol1 ]
Key: 2
Solution:
3.12
Amount of oxygen absorbed per gram of platinum}= gm
1.2
w KT
Volume of oxygen =
m P
3.12 1 0.0821  300
    2.0011  2
1.2 32 1

22 | Pa g e
54. Number of bridging CO ligands in  Mn 2  CO 10  is _________.
Key: 0
Solution:
CO
CO
OC CO
OC Mn Mn CO

OC CO
CO CO

Number of bridging 'CO ' ligands –Zero

55. An exothermic reaction X  Y has an activation energy 30 kJ mol1 , If energy change
E during the reaction is 20 kJ , then the activation energy for the reverse reaction in kJ

is _______ (Interger answer)

Key:
Solution:
E  Ea forward  Ea backward

20 kJ = 30 kJ Ea  backward 

Ea backward =30+20 = 50 kJ

56. The number of significant figures in 50000.020  103 is _______.

Key: 8
57. Consider the following reaction
MnO4  8H   5e  Mn 2  4H2 O, E  1.51V

The quantity of electricity required in Faraday to reduce five moles of MnO 4 is______
(Interger answer)
Key: 25
Solution:
1 mol of MnO 4  5mole e
5F
5 mol of MnO 4  25 F
58. A homogeneous ideal gaseous reaction AB2g   A  g   2B g  is carried out in a 25 litre flask

at 27C . The intial amount of AB2 was 1 mole and the equilibrium pressure was 1.9 atm.
The value of K p is x  10 2 . The value of x is ______ (Interger answer)

[ R  0.08206 dm3atm K 1 mol1 ]

Key: 100

23 | Pa g e
Solution:
 A  g   2B9 
AB29  

1  
1  x x 2x

nRT 1 1 300
Intial P=  
V 12 25
=1
PA  PB 2
Kp  total no. of moles= 1 
PAB2
0.45  0.9  0.9
Kp   66.2  102
0.55
nRT
Intial pressure P 
V
11 300
  =1
12 25
 A g   2 B 9
AB2 
1 x x 2x
Total P= 1  2x
1  2 x  1.9 x  0.45
Z xb
59. A certain gas obeys P  Vm  b   RT . The value of   is . The value of x is_____
 P  T RT
(Interger answer) (Z : compressibility factor)
Key: 1
Solution:
P Vm  b   KT
PVm  KT  Pb
Pb  Z  b
Z  1
RT  P   RT
T

x 1
60. Dichromate ion is treated with base, the oxidation number of Cr in the product formed is
______. Given—
Key:
Solution:
In alkaline medium Cr2 O7 2  changes to CrO4 2
There is no change in oxidation of ‘Cr’
In the product oxidation state of ‘Cr’ is +6

24 | Pa g e
MATHEMATICS Max Marks: 100

(SINGLE CORRECT ANSWER TYPE)

This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1
61. The maximum slope of the curve y  x 4  5x 3  18x 2  19x occurs at the point:
2
21
1)  3,  2)  2, 2  3)  2, 9  4)  0, 0 
 2
Key : 2
Solution:
1 4
y x  5x 3  18x 2  19x
2
dy
m  2x 3  15x 2  36x
dx
dm
 6x 2  30x  36  0
dx
x 2  5x  6  0
 x  2 x  3  0
d2m
 6  2x  5   0 for x = 2  max .at x  2
dx 2
y  8  40  72  38  2
62. The number of seven digit integers with sum of the digits equal to 10 and formed by
using the digits 1,2 and 3 only is :
1) 77 2) 35 3) 82 4) 42
Key : 1
Solution:
The required numbers contain
7!
1,1,1,1,1,2,3   42
5!
7!
1,1,1,1,2,2,2,   35
4!3!
Total wags = 77
63. The rate of growth of bacteria in a culture is proportional to the number of bacteria
present and the bacteria count is 1000 at initial time t  0 . The number of bacteria is
k
increased by 20% in 2 hours. If population of bacteria is 2000 after hours, then
6
log e  
5
2
 k 
  is equal to :
 log e 2 
1) 2 2) 8 3) 16 4) 4
Key : 4

25 | Pa g e
Solution:
Let x be the number of bacteria present at t
dx
Then  kx
dt
 ln  x   kt  c, At t = 0 , x  1000
 c  ln1000
20
At t = 2, x  1000  1000   1200
100
Log 1200  2k1  log1000
 1200  6 1 6
 2k1  log    log    k1  log  
 1000  5 2 5
1 6
 log x  log   t  log 1000 
2 5
1 6 6
Given log 2000  log   .k  log 1000  log    k  2 log 2
2 5  5
 k  2
 2 
  2  4
 log e 
sin 1 x cos 1 x tan 1 y  c 
64. If   ;0  x  1, then the value of cos   is :
a b c ab
1  y2 1  y2 1  y2
1) 2) 1  y 2 3) 4)
y y 2y 1  y2
Key : 4
Solution:
sin 1 x cos 1 x tan 1 y sin 1 x  cot 1 x 
   
a b c ab 2 a  b 
c  c  1  y2
tan 1 y 
2a  b
cos 
ab
  cos  2 tan 1
y  
1  y2
65. In the circle given below, let OA = 1 unit, OB = 13 unit and PQ  OB . Then , the area of
the triangle PQB ( in square units ) is :
y

O A B x

Q
1) 26 3 2) 24 2 3) 24 3 4) 26 2
Key : 3

26 | Pa g e
Solution:
OA = 1 , OB = 13  AB = 12
AP.AQ  OA.AB
AP 2  112  AP  AQ 
AP  2 3  PQ  4 3
1
Area of = PQB  PQ.AB
2
1
  4 3  12  24 3
2
66. The intersection of three lines x  y  0, x  2y  3 and 2x  y  6 is a :
1) Right angled triangle 2) Equilateral triangle
3) Isosceles triangle 4) None of the above
Key : 3
Solution:
Given line x  y  0 -------(1)
x  2y  3 --------(2)
2x  4  6 -------(3)
If A is angle between (1) ,(2)
|1  2 | 1
cos A  
10 10
If B is angle between (1),(3)
2 1 1
Cos B = 
10 10
4
Cos C =
5
 The triangle is isosceles
2 7 12 17 22
67. The sum of the infinite series 1       ......... is equal to :
3 32 33 34 35
9 11 15 13
1) 2) 3) 4)
4 4 4 4
Key : 4
Solution:
 1  7 12 17
1  2    2  3  3  .....
 3 3 3 3
1
 1  3  3   3  5     .....
 3
1
5 
 4
 3    3  9 15 13
2
 4  
1  1 2 4 4
1 1 

3  3 

27 | Pa g e
 25
68. In an increasing geometric series, the sum of the second and the sixth term is and the
2
product of the third and fifth term is 25. Then, the sum of 4th, 6th and 8th terms is equal to :
1) 35 2) 26 3) 32 4) 30
Key : 1
Solution:
25
Given ar  ar 5 
2
 ar  ar   25
2 4

 ar   25
3

ar 3  5
5 5 25
3
 r  3  r5 
r r 2
1 5 1
2
 r2    2  r2  2
r 2 2
T6  T6  T8  ar 3 1  r 2  r 4  5 1  2  4   35
69. Consider the three planes
P1 : 3x  15y  21z  9
P2 : x  3y  z  5 and P3 : 2x  10y  14z  5
Then , which one of the following is true ?
1) P1 and P2 are parallel 2) P1 and P3 are parallel
3) P2 and P3 are parallel 4) P1 , P2 and P3 all are parallel
Key : 2
Solution:
D.R 's of normal of P1 =  3,15, 21 or 1,5,7 
,, ,, P2  1, 3, 1
,, ,, P3   2,10,14  or 1,5,7 
 P1 is parallel to P3
70. Let A be a symmetric matrix of order 2 with integer entries . If the sum of the diagonal
2
elements of A is 1, then the possible number of such matrices is :
1) 6 2) 1 3) 12 4) 4
Key : 4
Solution:
a b 
Let A   
b c 
 a b  a b 
A2     
 b c  b c 
 a 2  b2 ab  bc 
 
 ab  bc b2  c2 
28 | Pa g e
 Given a 2  2b 2  c2  1 , a, b,c are integers
a  1, b  c  0 (or) a  b  0 , c  1
 Total number of matrices = 4

2
cos 2 x
71. The value of  dx is :
 1  3x
2

 
1) 2 2) 4 3) 4)
4 2
Key : 3
Solution:
  
2
cos 2 x 2
cos 2 x 2
3x cos 2 x
I  dx =  dx   dx

1  3x 
1  3 x 
3x  1
2 2 2
 
2 2
 2I  cos x dx = 2  cos 2 x dx
2

 0
2

1   I
 2 
2 2 4
72. Let R  {  P, Q  |P and Q are at the same distance from the origin} be a relation , then the
equivalence class of 1, 1 is the set :
1) S   x, y  | x 2  y 2  2  2) S   x, y  | x 2  y 2  2
3) S   x, y  | x 2  y 2  1 4) S   x, y  | x 2  y 2  4
Key : 2
Solution:
P ,Q lie on the circles x 2  y 2  r 2  OP  OQ  1, 1 lies on the circle x 2  y 2  r 2  r 2  2
 Equialance class of 1, 1 is S   x, y  /  x 2

 y2  2 
1 10
 1 
73. The maximum value of the term independent of ‘t’ in the expansion of  tx 5 
1  x  10

 t 
 
where x   0,1 is :
10! 2.10! 10! 2.10!
1) 2
2) 2
3) 2
4) 2
3  5! 3 3  5! 3  5! 3  5!
Key : 2
Solution:
The term independent of t is T6 (  middle term )
1 x 2
T6  10c5 x 1  x  2 , is maximum when  1 x x
2 3
10! 2 1
Maximum of T6    2
 5! 3 3

29 | Pa g e
     
 3 sin  6  h   cos  6  h  
74. The value of lim      is :

h 0
 3h 3 cosh  sinh   
 
2 4 2 3
1) 2) 3) 4)
3 3 3 4
Key : 2
Solution:
    
 3 lim  6  h   cos  6  h  
lim 2     

h 0
 
3h 3 cosh  sinh  
 
 
2 
 6

3 sin   h   cos   h
 6   2

6



6

3 cos   h   sin   h 

lim    Let
h 0 3 3  h  3
h 0 1
 
2 3 1 4
    
3 2 2 3
75. A fair coin is tossed a fixed number of times. If the probability of getting 7 heads is equal
to probability of getting 9 heads, then the probability of getting 2 heads is :
15 15 15 15
1) 2) 3) 4)
214 28 213 212
Key : 3
Solution:
P  x  7   P  x  9   n c7  n c9  n  16
16c 15
P  x  2   162  13
2 2
      
76. If a and b are perpendicular , then a  a  a  a  b     is equal to :
1 4 4   
1) a b 2) a b 3) 0 4) a  b
2
Key :2
Solution:
a.b  0

       a   a   0 | a | b  
a a a ab 2

2
  a a ab  
4
a b
100 n
x  x 
77. The value of e dx , where  x  is the greatest integer  x, is :
n 1 n 1

1) 100 1  e  2) 100 1  e  3) 100e 4) 100  e  1

30 | Pa g e
Key : 4
Solution:
100 n 100 1
dx    e x dx ( x   x  is periodic with period 1)
x  x 
:  e  100  e  1
n 1 n 1 n 1 0

 a  1 a  2  a2 1
78. The value of  a  2  a  3 a  3 1 is :
 a  3 a  4  a  34 1
1)  a  2  a  3 a  4  2)  a  1 a  2  a  3
3) 0 4) 2
Key : 4
Solution:
R 2  R 2  R1 , R 3  R 3  R 2
 a  1 a  2  a2 1
2  a  2 1 0  2
2  a  3 1 0
79. Let f be any function defined on R and let it satisfy the condition :
2
| f  x   f  y  |  x  y  |,   x, y   R If f  0   1, then :
1) f  x   0, x  R 2) f  x   0, x  R
3) f  x   0, x  R 4) f  x  can take any value in R
Key : 1
Solution:
f  x   f  y
lim  lim x  y f 1  y   0, y  f 1  x   0, x
x y xy x y

 f  x   1, x  f  0   1  f  x   0, x
80. If 1,5, 35 ,  7,5,5  , 1, , 7  and  2,1, 2  are coplanar , then the sum of all possible values of
 is :
44 44 39 39
1) 2)  3)  4)
5 5 5 5
Key : 1
Solution:
6 0  30
 AB BC CD   0  6 5 2 0
 
2  1 1   5
6  25  5  2  2   30 6  6  2 2  11  5   0
10 2  88  78  0
88 44
Sum of the values of   
10 5

31 | Pa g e
 (NUMERICAL VALUE TYPE)
This section contains 10 questions. Each question is numerical value type. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded-off to second decimal place. (e.g. 6.25, 7.00, 0.33, 30, 30.27, 127.30). Attempt any five questions out of 10.
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
 30   30   30   30 
81. Let m, n  N and gcd  2, n   1 . If 30    29    .....  2    1   n.2m , then n+m is
 0  1  28   29 
equal to _____
Key : 45
Solution:
g.c.d  2,    1  n is odd
   
30 30c0  29 30c1  .........  1 30c29  n.2m  
1.30c1  2.30c2  .......  30.30c30  n.2m
30.229  n.2m
 15  230  n.2m  n is odd 
 n  15, m  30
 n  m  45
82. The number of solutions of the equation log 4  x  1  log 2  x  3  is ____
Key : 1
Solution:
2
log 4  x  1  log 22  x  3
2
 x  3  x  1, x  3
x 2  7x  10  0
x  5 only  one solution
83. The difference between degree and order of a differential equation that represents the
 a 
family of curves given by y 2  a  x   , a  0 is ____
 2 
Key : 2
Solution:
 a
y2  a  x   , a  0  order = 1
 2 

dy
2y a
dx
3
2
2 dy 1  dy 
 y  2y  x    2y 
dx 2  dx 
3
2
 dy   dy 
2  y 2  2xy    2y 
 dx   dx 
2 3
 dy   dy 
4  y 2  2xy   y3    degree = 3
 dx   dx 
Difference  3  1  2
32 | Pa g e
84. Let  , 2,1 be a point on the plane which passes through the point  4, 2, 2  . If the plane is
2
 4
perpendicular to the line joining the points  2, 21, 29 and  1, 16, 23 then     4
 11  11
is equal to ________
Key : 8
Solution:
D.R’s of the normal to the plane
  1  2, 16  21, 23  29 
 1,5, 6 
Eg of plane 1 x  4   5  y  2   6  z  2   0
  4  5  2  2   6 1  2   0
  22
2
   4
    4  484  8
 11  11

85. The value of the integral  | sin 2x | dx is _____
0

Key : 2
Solution:
 2
1
 sin 2x dx 
0 2  sin t dt
0

1
  2  sin t dt  2
2 0

86. The sum of 162 th power of the roots of the equation x 3  2x 2  2x  1  0 is _____
Key: 3
Solution:
Given equation x 2  2x 2  2x  1  0
 x  1  x 2  x  1  0
x  1, x   w,  w 2
54 54
162  162  162  1    w 3    w 6 
 1  1 1  3
87. The number of integral values of ‘k’ for which the equation 3sin x  4cos x  k  1 has a
solution , k  R is___
Key : 11
Solution:
3sin x  4cos x  k  1 has a solution
  9  16  k  1  9  16
6  k  4
Number of integer of k = 11
33 | Pa g e
 dy sin y
88. If y  y  x  is the solution of the equation esin y cos y  e cos x  cos x, y  0   0 ; then
dx
 3  1 
1 y    y  y   is equal to __
6 2 3 2 4
Key : 1
Solution:
dy sin y
esin y cos y  e cos x  cos x, y  0   0
dx
esin y  t
dy dt
 esin y cos y 
dx dx
dt
 t  cos x   cos x
dx
I.F  e 
cos xdx
 esin x
Solution is tesin x   esin x .cos xdx
 esin x  c
esin y  1  ce  sin x , y  0   0  c  0
 y  0, x
 3 
Given expression 1  y    y   .............  1  0  1
6 2  3
89. If 3  cos 2 x    3  1 cos x  1 , the number of solution of the given equation when
 
x   0,  is ____
 2
Key : 1
Solution:
3 cos 2 x   
3  1 cos x  1

3 cos x  cos x  1   cos x  1  0

 
3 cos x  1  cos x  1  0, x  0,  
 2
n  0 Only, No. of solutions=1
90. The area bounded by the lines y | x  1| 2 | is_____
Key: No solution (Question wrong)
Solution:
Given equation should be as y  x  1  2

34 | Pa g e