ADVANCED LEVEL PROBLEMS

Q. No. 1 to 3 (3 questions)
Acetic acid is added to the solution of sodium carbonate the gas evolved does not turn
purple colour of KMnO4 but turns lime water milky forming a compound (M) which
becomes soluble by passing the same gas in excess forming another compound (N). But
same observation is not obtained with boric acid

Q.1 Purple colour of KMnO4 has not changed because

(A) the gas has no oxidising property since central atom is with minimum oxidation state
(B) the gas has no reducing property since the central atom is with maximum oxidation
state
(C) the gas has no precipitation characteristics
(D) the gas precipitates CaCO3 from lime water

Q.2 The compound formed in the above sequence (M) and (N) are respectively
(A) water soluble CaCO3 and water soluble Ca(HCO3)2
(B) water insoluble CaCO3 and water insoluble Ca(HCO3)2
(C) water insoluble CaCO3 and water soluble Ca(HCO3)2
(D) water soluble CaCO3 and water insoluble Ca(HCO3)2

Q.3 The correct order of increasing acidity is

(A) Boric acid > Acetic acid > Carbonic acid
(B) Acetic acid > Carbonic acid > Boric acid
(C) Carbonic acid < Acetic acid < Boric acid
(D) Boric acid < Carbonic acid < Acetic acid

Q. No. Q.4 to Q.7 (4 questions)

A chemist opened a cupboard to find four bottles containing water solutions, each of
which has lost its label. Bottles 1, 2, 3 contained colourless solutions, whilst Bottle 4
contained a blue solution. The labels from the bottles were lying scattered on the floor of
the cupboard. They were:
copper (II) sulphate
sodium carbonate
lead nitrate
hydrochloric acid
By mixing samples of the contents of the bottles, in pairs, the chemist made the following
observations:
(i) Bottle 1 + Bottle 2 white precipitate
(ii) Bottle 1 + Bottle 3 white precipitate
(iii) Bottle 1 + Bottle 4 white precipitate
(iv) Bottle 2 + Bottle 3 colourless gas evolved
(v) Bottle 2 + Bottle 4 no visible reaction
(vi) Bottle 3 + Bottle 4 blue precipitate
Q.4 Chemical formula of white precipitate in (i) observation is
(A) CuCl2 (B) PbCl2 (C) PbCO3 (D) CuCO3
 ADVANCED LEVEL PROBLEMS

Q.5 Colourless solution present in Bottle 1 is:

(A) CuSO4 (B) HCl (C) Pb(NO3)2 (D) Na2CO3

Q.6 Nature of Gas evolved in (iv) observation is:

(A) Acidic (B) Neutral (C) Basic (D) Amphoteric

Q.7 Chemical formula of white ppt. formed in observation (iii) is

(A) PbCl2 (B) PbCO3 (C) CuCO3 (D) PbSO4

Question No. 8 to 10 (3 questions)

Q.8SHEET Type of hybridization of complex (M) is

(A) sp3d2 (B) d2sp3 (C) dsp2 (D) sp3

Q.9SHEET Water of crystallization in salt (A)

(A) 5 (B) 6 (C) 7 (D) 10

Q.10SHEET Compound (H) + X + FeCl3 —® Blood Red Colouration.

The unknown compound X is?
(A) NaOCN (B) NaCN (C) NaNC (D) Na2S2O3
 ADVANCED LEVEL PROBLEMS

Question No. 11 to 13 (3 questions)

Q.11 The colour of the compound R is

(A) white (B) yellow (C) black (D) brown

Q.12 The structure of compound P is

(A) linear (B) crown shaped (C) square pyramidal (D) zig-zag chain

Q.13 Compound M is used

I. In photography II. In analytical chemistry
III. As a dehydrating agent IV. As an oxidizing as well as reducing agent
Choose the correct code:
(A) I, III (B) I, II & III (C) I, II (D) I, II, III & IV

Question No. 14 to 17 (4 questions)

A great scientist 'TOM CAT' collected six sample solution in six test tube for a new
discovery and trying for " Nobel Prize" (Chemistry) in the year of 2006. But his very
close friend 'JERRY MOUSE' all of a sudden appears in the laboratory and kicked off
AgNO3 bottle on all these samples and spoiled the experiments, making all white ppt.
But 'TOM CAT' has not lost his enthusiasm at all and found the following observation
from all those white ppts.
Test tube No.Observations:
(a) ppt. is soluble on heating.
(b) the anion was present in (b) does not give brown ring test for nitrate if it is present
with nitrate.
(c) the ppt. becomes soluble with addition of excess of solution was present in (c) but on
heating it produces a black ppt. which does not dissolve in NH3.
(d) ppt. gives clear solution with excess of solution that was present in (d) and that clear
solution gives black residue on heating.
(e) the aqueous suspension of ppt produces black residue and an acidic gas on heating,
the above gas does not turn K2Cr2O7 solution green.
(f) the ppt. is soluble in NH3 but does not give chromyl chloride test.

Q.14 In which of observation black ppt is Ag2S.

(A) d (B) c (C) e (D) none
 ADVANCED LEVEL PROBLEMS

Q.15 White ppts in 'a', 'd', 'b' respectively

(A) Ag2SO3, HCO2Ag, AgBr (B) AgNO2, HCO2Ag, AgCl
(C) CH3CO2Ag, Ag2SO3, AgNO2 (D) HCO2Ag, Ag2CO3, AgNO2

Q.16 White ppt. in test tube'e' is:

(A) Ag2CO3 (B) Ag2S2O3 (C) Ag2SO4 (D) HCO2Ag

Q.17 The solution initially present in test tube 'c' + (M) + FeCl3 gives blood red colouration.
The M is:
(A) NaOCN (B) NaCN (C) Na2S2O3 (D) HgCl2

Question No. 18 to 21 (4 questions)

(A) + NaCl ¾® (B) (white ppt.)
(A) + KI ¾® (C) (green ppt.)
(C) + KI ¾® (D) + (E) (colourless solution)
(excess)
(E) + NH3 + KOH ¾® (F)

Q.18 Compounds (A) and (B) are respectively

(A) AgNO3 and AgCl (B) Pb(NO3)2 and PbCl2
(C) Hg2(NO3)2 and Hg2Cl2 (D) Cu2(NO3)2 and Cu2Cl2

Q.19 When compound (A) reacts with Na2CrO4 solution, then colour of the formed compound
is
(A) Black (B) Red (C) Yellow (D) White

Q.20 Type of Hybridization in compound (E) is

(A) d2sp3 (B) sp3d2 (C) sp3 (D) dsp2

Q.21 Colour of the compound (F) is

(A) yellow (B) blue (C) white (D) brown

Question No. 22to 25 (4 questions)

+ Air H SO4
Black solid ¾KOH
¾¾ ¾® (B) + (C)
¾® (A) ¾¾2 ¾
D ( green ) ( purple)

(i) KI on reaction with alkaline solution of (B) changes into a compound (D)
(ii) The colour of the compound (B) disappears on treatment with the acidic solution of
FeSO4
(iii) With cold conc. H2SO4 compound (B) gives (E) which being explosive decomposes to
yield (F) and oxygen.
Q.22 Nature of compound (E) is
(A) Acidic oxide (B) Basic oxide (C) Amphoteric oxide (D) Neutral oxide
 ADVANCED LEVEL PROBLEMS

Q.23 Colour of the solution obtained, when ferrous oxalate reacts with acidic solution of (B)
(A) colourless (B) pink (C) green (D) yellow

Q.24 Which of the following options is correct

(A) (C) and (F) are same compounds having same colour
(B) (C) and (F) are different compounds having same colour
(C) Compound (B) forms similar compound (E) with hot and conc. H2SO4
(D) Compound (A) doesn't give same type of reaction in acidic and neutral medium

Q.25 Type of hybridization in compound (D)

(A) sp2 (B) sp3 (C) sp3d (D) No hybridization

Question No. 26 to 29 ( 4 questions)

(i) A hot metal (M) burns in acidic gas (A), produces 'B' & 'C'
(ii) B reacts with KMnO4 giving rise to brown ppt.
(iii) C reacts with dil. H2SO4, gives same gas 'A'
(iv) C on heating produces 'E' and 'F'
(v) E reacts with dil. H2SO4 releasing rotten egg's smell.
(vi) F reacts with Pb(NO3)2 giving rise to white ppt which does not dissolve in dil. mineral
acid but soluble in (NH4)2C2O4.

Q.26 When the gas 'A' is passed through strongly acidic solution of light green compound
FeCl2, gives the ppt. of
(A) FeS (B) S (C) FeS2 (D) FeS + S

Q.27 'E' reacts with FeCl2 solution and the ppt. obtained is
(A) FeS (B) S (C) FeS + S (D) Fe2S3

Q.28 Analogous Na-compound of B on heating produces a polysulphide having the unit of

ion. The value of x is
(A) 2 (B) 3 (C) 5 (D) 6

Q.29 White ppt is obtained in (vi) observation is

(A) 2PbCO3 · Pb(OH)2 (B) Pb(OH)2 (C) PbSO3 (D) PbSO4

Question No. 30 to 32 ( 3 questions)

Recent X-ray work, IR and other spectroscopic methods have proved that Turnbull's blue
is identical to Prussian blue.

Q.30 What is the common formula of Turnbull's blue and Prussian blue?
(A) Fe3[Fe(CN)6]2 (B) Fe4[Fe(CN)6]3 (C) KFe[Fe(CN)6] (D) KFe2[Fe(CN)6]
 ADVANCED LEVEL PROBLEMS

Q.31 Intense blue colour arises as a result of:

(A) electron transfer between Fe(II) and Fe(I)
(B) electron transfer between Fe(II) and Fe(III)
(C) d–d transition
(D) spin magnetic moment

Q.32 Select correct statement(s)

(I) When excess FeCl3 solution is added to K4[Fe(CN)6] solution in addition to
FeIII[FeII(CN)6]–, FeII[FeIII(CN)6]– is also formed due to side redox reaction
(II) When FeCl2 is added to K3[Fe(CN)6] solution, in addition to FeII [FeIII(CN)6]–,
FeIII[FeII(CN)6]– is also formed due to side redox reaction.
(III) FeIII[FeII(CN)6]– is paramagnetic while FeII[FeIII(CN)6]– is diamagnetic
(IV) FeIII[FeII(CN)6]– is diamagnetic while FeII[FeIII(CN)6]– is paramagnetic
(A) I, II (B) III, IV (C) All (D) None

Question No. 33 to 34 (2 questions)

Q.33 Water of crystallisation in compound P

(A) 4 moles (B) 7 moles (C) 10 moles (D) 5 moles
Q.34 Blue compound Q is
(A) Co(BO2)2 (B) NaCoPO4 (C) CoO·Al2O3 (D) CoO·MgO

Question No. 35 to 38 (4 questions)

Ram is experimenting the electrolysis of 50% H2SO4 with high current density. The
product obtained (A) is heated with NH4OH to get the salt (B). Ram was puzzled and not
getting anything new. Suddenly he met Hari and Hari whispered to Ram to do according
to him. Ram added the compound (C) into (B). In the resulting solution (pink coloured)
BaCl2 is added, a precipitate was observed but to have the clearness H2O2 is added again
and pink coloured ppt. (D) is finally obtained. On passing H2S into (C) another ppt. (E) is
obtained which is soluble in acetic acid but on addition of dil. HCl into (E) gives back
(C).

Q.35 The pink coloured compound ‘D’ is originally of

(A) MnSO4 (B) BaSO4 (C) MnSO3 (D) BaSO3
 ADVANCED LEVEL PROBLEMS

Q.36 H2O2 in the last step acts as

I. decolouriser II. reducing agent III. oxidising agent
(A) I & II (B) II only (C) I & III (D) I only

Q.37 The compound ‘C’ is

(A) ZnCl2 (B) MnCl2 (C) MnSO4 (D) ZnSO4

Q.38 The product (A) is consisting of which of the following linkage

(A) –O–O– (B) –S–O–O–S– (C) both (D) none

Question No. 39 to 41 (3 questions)

A white crystalline solid 'A' on boiling with caustic soda solution gives a gas 'B' which on
passing through an alkaline solution of potassium tetraiodomercurate(II) solution gives a
brown ppt. The substance 'A' on heating gave a gas 'C' which rekindled a glowing
splinter but does not give brown fumes with nitric oxide

Q.39 The gas 'B' is

(A) H2S (B) NH3 (C) HCl (D) CO2
Q.40 The gas 'C' is
(A) N2O (B) O2 (C) NO (D) O3

Q.41 The substance 'A' is

(A) NH4Cl (B) NH4NO3 (C) NH4NO2 (D) NaNO3

Question No. 42 to 46 (5 questions)

A coloured compound (A) reacts with dilute. H2SO4 to produce a colourless gas (B) and
colourless solution (C). The reaction between (B) and the acidified K2Cr2O7 solution
produces a green solution and a slightly yellowish precipitate (D). The substance (D)
burns in air to produce a gas (E) which also can change the colour of K2Cr2O7 solution.

Q.42 “A” probably, is

(A) ZnSO3 (B) CoS (C) MnS (D) NiS

Q.43 When “B” reacts with “E”

(A) A new gas F will be produced (B) It produces D and a colourless liquid
(C) there will be no reaction between them (D) it yields B and an acidic oxide

Q.44 What is not correct about E?

(A) It is colourless and highly water soluble (B) The molecule is linear
(C) Its aqueous solution is acidic (D) It turns starch iodate paper blue
 ADVANCED LEVEL PROBLEMS

Q.45 When D is boiled with alkaline sulphite solution a compound F is formed. F can be used
in
(I) iodine titrations in volumetric analysis (II) bleaching industry to destroy excess Cl2
(III) photography for ‘fixing’ films (IV) Iodometric titration
Choose the correct codes:
(A) I & IV (B) I, III & IV (C) II & III (D) I, II, III & IV

Q.46 When colourless solution (C) reacts with Pb3O4 / H+, it acquires a violet red colour due to
formation of
(A) MnO -4 (B) PbO2 (C) I3- (D) [Ni(en)3]S2O3

Question No. 47 to 50 (4 questions)

Ram is experimenting the electrolysis of 50% H2SO4 with high current density. The
product obtained (A) is heated with NH4OH to get the salt (B). Ram was puzzled and not
getting anything new. Suddenly he met Hari and Hari whispered to Ram to do according
to him. Ram added the compound (C) into (B). In the resulting solution (pink coloured)
BaCl2 is added, a precipitate was observed but to have the clearness H2O2 is added again
and pink coloured ppt. (D) is finally obtained. On passing H2S into (C) another ppt. (E) is
obtained which is soluble in acetic acid but on addition of dil. HCl into (E) gives back
(C).

Q.47 The pink coloured compound ‘D’ is originally of

(A) MnSO4 (B) BaSO4 (C) MnSO3 (D) BaSO3

Q.48 H2O2 in the last step acts as

I. decolouriser II. reducing agent III. oxidising agent
(A) I & II (B) II only (C) I & III (D) I only

Q.49 The compound ‘C’ is

(A) ZnCl2 (B) MnCl2 (C) MnSO4 (D) ZnSO4

Q.50 The product (A) is consisting of which of the following linkage

(A) –O–O– (B) –S–O–O–S– (C) both (D) none
 ADVANCED LEVEL PROBLEMS

Question No. 51 (i) to 51(ii) (2 questions)

Q.51(i) When compound B undergoes in hydrolysis, evolved gas is

(A) Cl2 (B) HCl (C) H2 (D) O2

Q.51(ii) Choose the correct statement

(A) compound A, B & C have same type of bond
(B) compound C & D have same type of bond
(C) compound A & C have same type of bond
(D) compound A & D have same type of bond

Question No. 52 to 55 (4 questions)

Black solid ¾KOH + Air (A) (B)

¾¾ ¾4 ® ( purple) + (C)
¾® ( green ) ¾H¾2SO
¾
D

(i) KI on reaction with alkaline solution of (B) changes into a compound (D)
(ii) The colour of the compound (B) disappears on treatment with the acidic solution of
FeSO4
(iii) With cold conc. H2SO4 compound (B) gives (E) which being explosive decomposes to
yield (F) and oxygen.

Q.52 Nature of compound (E) is

(A) Acidic oxide (B) Basic oxide (C) Amphoteric oxide (D) Neutral oxide

Q.53 Colour of the solution obtained, when ferrous oxalate reacts with acidic solution of (B)
(A) colourless (B) pink (C) green (D) yellow

Q.54 Which of the following options is correct

(A) (C) and (F) are same compounds having same colour
(B) (C) and (F) are different compounds having same colour
(C) Compound (B) forms similar compound (E) with hot and conc. H2SO4
(D) Compound (A) doesn't give same type of reaction in acidic and neutral medium

Q.55 Type of hybridization in compound (D)

(A) sp2 (B) sp3 (C) sp3d (D) No hybridization
 ADVANCED LEVEL PROBLEMS

Question No. 56 to 59 (4 questions)

(i) A hot metal (M) burns in acidic gas (A), produces 'B' & 'C'
(ii) B reacts with KMnO4 giving rise to brown ppt.
(iii) C reacts with dil. H2SO4, gives same gas 'A'
(iv) C on heating produces 'E' and 'F'
(v) E reacts with dil. H2SO4 releasing rotten egg's smell.
(vi) F reacts with Pb(NO3)2 giving rise to white ppt which does not dissolve in dil. mineral
acid but soluble in (NH4)2C2O4.

Q.56 When the gas 'A' is passed through strongly acidic solution of light green compound
FeCl2, gives the ppt. of
(A) FeS (B) S (C) FeS2 (D) FeS + S

Q.57 'E' reacts with FeCl2 solution and the ppt. obtained is
(A) FeS (B) S (C) FeS + S (D) Fe2S3

Q.58 Analogous Na-compound of B on heating produces a polysulphide having the unit of S2x-
ion. The value of x is
(A) 2 (B) 3 (C) 5 (D) 6

Q.59 White ppt is obtained in (vi) observation is

(A) 2PbCO3 · Pb(OH)2 (B) Pb(OH)2 (C) PbSO3 (D) PbSO4

Question No. 60 to 64 (5 questions)

A great scientist 'TOM CAT' collected six sample solution in six test tube for a new
discovery and trying for " Nobel Prize" (Chemistry) in the year of 2006. But his very
close friend 'JERRY MOUSE' all of a sudden appears in the laboratory and kicked off
AgNO3 bottle on all these samples and spoiled the experiments, making all white ppt.
But 'TOM CAT' has not lost his enthusiasm at all and found the following observation
from all those white ppts.
Test tube No. Observations:
(a) ppt. is soluble on heating.
(b) the anion was present in (b) does not give brown ring test for
nitrate if it is present with nitrate.
(c) the ppt. becomes soluble with addition of excess of solution was
present in (c) but on heating it produces a black ppt. which does
not dissolve in NH3.
(d) ppt. gives clear solution with excess of solution that was present in
(d) and that clear solution gives black residue on heating.
(e) the aqueous suspension of ppt produces black residue and an
acidic gas on heating, the above gas does not turn K2Cr2O7 solution
green.
(f) the ppt. is soluble in NH3 but does not give chromyl chloride test.
 ADVANCED LEVEL PROBLEMS

Q.60 In which of observation black ppt is Ag2S.

(A) d (B) c (C) e (D) none

Q.61 White ppts in 'a', 'd', 'b' respectively

(A) Ag2SO3, HCO2Ag, AgBr (B) AgNO2, HCO2Ag, AgCl
(C) CH3CO2Ag, Ag2SO3, AgNO2 (D) HCO2Ag, Ag2CO3, AgNO2

Q.62 White ppt. in test tube'e' is:

(A) Ag2CO3 (B) Ag2S2O3 (C) Ag2SO4 (D) HCO2Ag

Q.63 The solution initially present in test tube 'c' + (M) + FeCl3 gives blood red colouration.
The M is:
(A) NaOCN (B) NaCN (C) Na2S2O3 (D) HgCl2

Q.64 White ppt. in test tube 'f' and the soluble complex formed from white ppt. in test tube 'c'
are respectively
(A) AgCl, [Ag(S2O3)2]3– (B) Ag2S2O3, [Ag(NH3)2]+
(C) Ag2CO3, [AgSO3]– (D) Ag2SO4, [Ag(H2O)2]+

Q.65 Compounds (A) and (B) are respectively

(A) AgNO3 and AgCl (B) Pb(NO3)2 and PbCl2
(C) Hg2(NO3)2 and Hg2Cl2 (D) Cu2(NO3)2 and Cu2Cl2

Q.66 When compound (A) reacts with Na2CrO4 solution, then colour of the formed compound
is
(A) Black (B) Red (C) Yellow (D) White

Q.67 Type of Hybridization in compound (E) is

(A) d2sp3 (B) sp3d2 (C) sp3 (D) dsp2

Q.68 Colour of the compound (F) is

(A) yellow (B) blue (C) white (D) brown
 ADVANCED LEVEL PROBLEMS

Question No. 69 to 71 (3 questions)

Q.69 The colour of the compound R is

(A) white (B) yellow (C) black (D) brown
Q.70 The structure of compound P is
(A) linear (B) crown shaped (C) square pyramidal (D) zig-zag chain

Q.71 Compound M is used

I. In photography II. In analytical chemistry
III. As a dehydrating agent IV. As an oxidizing as well as reducing agent
Choose the correct code:
(A) I, III (B) I, II & III (C) I, II (D) I, II, III & IV

Question No. 72 to 74 ( 3 questions)

A white crystalline solid 'A' on boiling with caustic soda solution gives a gas 'B' which on
passing through an alkaline solution of potassium tetraiodomercurate(II) solution gives a
brown ppt. The substance 'A' on heating evolves a neutral gas 'C' which rekindled a
glowing splinter but does not give brown fumes with nitric oxide

Q.72 The gas 'B' is

(A) H2S (B) NH3 (C) HCl (D) CO2

Q.73 The gas 'C' is

(A) N2O (B) O2 (C) NO (D) O3

Q.74 The substance 'A' is

(A) NH4Cl (B) NH4NO3 (C) NH4NO2 (D) NaNO3
 ADVANCED LEVEL PROBLEMS

Question No. 75 to 78 (4 questions)

A chemist opened a cupboard to find four bottles containing water solutions, each of
which has lost its label. Bottles 1, 2, 3 contained colourless solutions, whilst Bottle 4
contained a blue solution. The labels from the bottles were lying scattered on the floor of
the cupboard. They were:
copper (II) sulphate
sodium carbonate
lead nitrate
hydrochloric acid
By mixing samples of the contents of the bottles, in pairs, the chemist made the following
observations:
(i) Bottle 1 + Bottle 2 white precipitate
(ii) Bottle 1 + Bottle 3 white precipitate
(iii) Bottle 1 + Bottle 4 white precipitate
(iv) Bottle 2 + Bottle 3 colourless gas evolved
(v) Bottle 2 + Bottle 4 no visible reaction
(vi) Bottle 3 + Bottle 4 blue precipitate
Q.75 Chemical formula of white precipitate in (i) observation is
(A) CuCl2 (B) PbCl2 (C) PbCO3 (D) CuCO3

Q.76 Colourless solution present in Bottle 1 is:

(A) CuSO4 (B) HCl (C) Pb(NO3)2 (D) Na2CO3

Q.77 Nature of Gas evolved in (iv) observation is:

(A) Acidic (B) Neutral (C) Basic (D) Amphoteric

Q.78 Chemical formula of white ppt. formed in observation (iii) is

(A) PbCl2 (B) PbCO3 (C) CuCO3 (D) PbSO4

Question No. 79 to 81 ( 3 questions)

Acetic acid is added to the solution of sodium carbonate the gas evolved does not turn
purple colour of KMnO4 but turns lime water milky forming a compound (M) which
becomes soluble by passing the same gas in excess forming another compound (N). But
same observation is not obtained with boric acid

Q.79 Purple colour of KMnO4 has not changed because

(A) the gas has no oxidising property since central atom is with minimum oxidation state
(B) the gas has no reducing property since the central atom is with maximum oxidation
state
(C) the gas has no precipitation characteristics
(D) the gas precipitates CaCO3 from lime water
 ADVANCED LEVEL PROBLEMS

Q.80 The compound formed in the above sequence (M) and (N) are respectively
(A) water soluble CaCO3 and water soluble Ca(HCO3)2
(B) water insoluble CaCO3 and water insoluble Ca(HCO3)2
(C) water insoluble CaCO3 and water soluble Ca(HCO3)2
(D) water soluble CaCO3 and water insoluble Ca(HCO3)2

Q.81 The correct order of increasing acidity is

(A) Boric acid > Acetic acid > Carbonic acid
(B) Acetic acid > Carbonic acid > Boric acid
(C) Carbonic acid < Acetic acid < Boric acid
(D) Boric acid < Carbonic acid < Acetic acid

Question No. 82 to 83 (2 questions)

heated
White compound "A" in¾absence
¾¾¾® B(solid) + C(g) + D(g)
of air

(i) gas 'C' reacts with PdCl2 solution into black deposit
(ii) gas 'D' is absorbed either by ethanol amine or by Na2CO3
(iii) solid 'B' dissolves easily in dil. HCl and the resulting solution reduces HgCl2 into
white ppt but cannot reduce Hg2Cl2

Q.82 'A' contains which of the following cations

(A) Fe2+ (B) Sn2+ (C) Pb2+ (D) As3+

Q.83 Which of the following statement is / are correct regarding gas (C)
(A) gas (C) is minor constituent of water gas
(B) gas (C) acts as p-acid ligand
(C) It burns with red flame.
(D) It has same bond order with gas (D).

Question No. 84 to 838 (5 questions)

A coloured compound (A) reacts with dilute. H2SO4 to produce a colourless gas (B) and
colourless solution (C). The reaction between (B) and the acidified K2Cr2O7 solution
produces a green solution and a slightly yellowish precipitate (D). The substance (D)
burns in air to produce a gas (E) which also can change the colour of K2Cr2O7 solution.

Q.84 “A” probably, is

(A) ZnSO3 (B) CoS (C) MnS (D) NiS

Q.85 When “B” reacts with “E”

(A) A new gas F will be produced (B) It produces D and a colourless liquid
(C) there will be no reaction between them (D) it yields B and an acidic oxide
 ADVANCED LEVEL PROBLEMS

Q.86 What is not correct about E?

(A) It is colourless and highly water soluble (B) The molecule is linear
(C) Its aqueous solution is acidic (D) It turns starch iodate paper blue

Q.87 When D is boiled with alkaline sulphite solution a compound F is formed. F can be used
in
(I) iodine titrations in volumetric analysis (II) bleaching industry to destroy excess Cl2
(III) photography for ‘fixing’ films (IV) Iodometric titration
Choose the correct codes:
(A) I & IV (B) I, III & IV (C) II & III (D) I, II, III & IV

Q.88 When colourless solution (C) reacts with Pb3O4 / H+, it acquires a violet red colour due to
formation of
(A) MnO -4 (B) PbO2 (C) I3- (D) [Ni(en)3]S2O3

Question No. 89 to 92 (4 questions)

Q.89 The structure of compound (A) is

(A) linear (B) crown shaped (C) square pyramidal (D) zig-zag chain

Q.90 Compound (B) on strong heating produces compound(s) which has/have

(A) chain structure (B) tetrahedral structure (C) both (D) none

Q.91 Which of the following statements is/are correct for the gas D.
(I) It has the state of hybridisation sp3.
(II) Gas can be identified by CaCl2 solution.
(III) Gas can be identified by Pb(OAc)2 solution.
(IV) Gas can be identified by passing through sodium nitropruside solution
(A) I, IV (B) I, III (C) III only (D) I, II, IV

Q.92 Compound (B) on reaction with [Ni(en)3](NO3)2 gives a coloured complex exhibiting
(A) Optical isomerism (B) Geometrical isomerism
(C) Linkage isomerism (D) No isomerism
 ADVANCED LEVEL PROBLEMS

Question No. 93 to 95 (3 questions)

Read the following short write up and answer subsequent questions based on (A) to (J)
observations

Q.93 Compound A & B is respectively

(A) FeCl2; FeCl3 (B) CuCl2 · 2H2O; [CuCl4]–2
(C) CrCl3; K2CrO4 (D) NiCl2; NiCl3

Q.94 Gas J is also produce by

(i) Heating NH4NO3 (ii) Heating NH4NO2
(iii) Heating NH4Cl (iv) Reaction of NH4Cl & Ca(OH)2
(A) (i) & (iii) (B) (i) & (ii) (C) (i) & (iv) (D) (iii) & (iv)

Q.95 Select the incorrect reaction

(A) C in solid state + KBr + conc. H2SO4 ¾® Red gas
(B) C in solid state + KCl + conc. H2SO4 ¾® Red gas
(C) C in solid state + FeCl3 + conc. H2SO4 ¾® Red gas
(D) C in solid state + HgCl2 + conc. H2SO4 ¾® Red gas
 ADVANCED LEVEL PROBLEMS

Question No. 96 to 98 (3 questions)

D
Compound 'A' ¾¾® Initially swelled ¾¾D¾¾® Amorphous powder
strong heating

Lilac flame in the flame test.

Compound 'A' ¾excess
¾¾¾¾® 'B'( No change in colour) ¾H¾
NaOH
¾® 'C' (Yellow solution)
2O2

(in aq. solution)

Q.96 Compound 'A' is having water of crystallization by the number of
(A) 10 (B) 20 (C) 24 (D) 36

Q.97 The compound 'B' is having oxidation state of

(A) zero (B) II (C) III (D) IV

Q.98 The hybridization of compound 'C' is

(A) sp3 (B) sp3d (C) d2sp3 (D) d3s

Question No. 99 to 101 (3 questions)

A white solid A reacts with dilute H2SO4 to produce a colourless gas B and a colourless
solution C. The reaction between B and acidified dichromate yields a green solution and
a slightly coloured precipitate D. The substance D, when burnt in air, gives a gas E which
reacts wih B to yield D and a colourless liquids. Anhydrous copper sulphate turns blue
with this colourless liquid. The addition of aqueous NH3 or NaOH to C produces a
precipitate that dissolves in an excess of the reagent to form a clear solution.
Answer the following questions based on above passage.

Q.99 Which of the following gases are B and E respectively?

(A) CO2 and SO2 (B) SO2 and H2S (C) H2S and SO2 (D) CO2 and H2S

Q.100 What would appear if the gas B is passed through an aqueous solution of Pb(NO3)2?
(A) white precipitate soluble in hot dilute HNO3
(B) A black precipitate soluble in hot dilute HNO3
(C) A black precipitate insoluble in hot dilute HNO3
(D) A yellow precipitate soluble in hot concentrated HNO3

Q.101 Suppose the solution obtained by the treatment of the solution C with an excess of NaOH
is acidified with acetic acid and the gas B is passed through it. Which of the following
will obtained?
(A) Colourless solution (B) Yellow precipitate
(C) Black precipitate (D) White precipitate
 ADVANCED LEVEL PROBLEMS

Question No. 102 to 104 (3 Question)

When redox reaction occurs within the reactant, in which one component acts as
oxidising agent and other component acts as reducing agent, then it is named as
intra-molecular redox reaction, which usually occur in thermal decomposition of ionic
compounds.

Q.102 Which of the following compounds does not give nitrogen gas on heating?
(A) NH4NO2 (B) (NH4)2SO4 (C) NH4ClO4 (D) (NH4)2Cr2O7

Q.103 Which of the following salt does not give NO2 gas on heating?
(A) Pb(NO3)2 (B) Hg(NO3)2 (C) KNO2 (D) AgNO3

Q.104 NH4ClO4 + HNO3 (dilute) ¾® X + HClO4

X ¾heat
¾ Y (gas)
¾®
Gas (Y) is :
(A) O2 (B) N2 (C) NO2 (D) N2O

Question No. 105to 107 (3 Question)

Using dil. H2SO4 gas evolution takes place from several acid radicals. If we consider their
smell, colour and other observation if any, several acid radicals can be detected in this
step.

Q.105 Using dil. H2SO4, which of the acid radical can not be confirmed.
- -
(A) NO 2 (B) CH3CO2 (C) HSO 3- (D) S2–

Q.106 When the aqueous suspension of Ag2SO3 and Ag2CO3 are heated, the respective ppts. are
obtained as
(A) Ag2O & Ag2O (B) Ag2O & Ag (C) Ag & Ag2O (D) Ag & Ag

Q.107 Which of the following radical(s) is/are producing same gas on treatment with (Zn + dil.
H2SO4).
I. SO32– II. HSO3¯ III. S2– IV. Cl¯
(A) I and II only (B) I, II and III only (C) I, II, III and IV (D) II, III and IV only
 ADVANCED LEVEL PROBLEMS

Question No. 108 to 110 (3 Question)

Red hot Mg HO NiCl2 solution

(I) 2 (J) (K)
White Deep blue
solid solution
(When excess J is passed)
(A) D
Anhydrous
(B) + (C) + (D) (E)
CoCl2
Orange Coloured Pink solid
solid solid

conc.
HCl
+
H O2 / OH¯
2 H2O2 / H
(F) (G) (H)
Et2O
Green Yellow Blue
Solution solution

Q.108 Which of following gas is turning the filter paper dipped into (MnSO4 + H2O2) solution
brownwish black.
(A) gas 'C' (B) gas 'D' (C) gas 'J' (D) None of these
Q.109 Type of hybridisation in compound (K)
(A) d2sp3 (B) sp3d2 (C) dsp2 (D) sp3

Q.110 Which of the following set of reagent is suitable to get (F) from (G) .
(A) Neutral H2O2 solution (B) H2O2 / H+ + amyl alcohol
(C) H2O2 / OH¯ (D) H2O2 / H+

Question No. 111 to 113 (3 Question)

All the anions are detected from soda extract except CO32– and HCO3¯. It is very useful
when any water insoluble salt is present in the given mixture.
Q.111 For which of the following salt preparation of soda extract is essential.
(A) (NH4)2SO4 (B) Na2S (C) KBr (D) AgCl

Q.112 Which of the following salt remains unchanged during preparation of soda extract.
(A) BaS2O3 (B) PbSO4 (C) CaCO3 (D) None of these

Q.113 Choose the correct statement regarding soda extract preparation.

(A) Instead of Na2CO3, Na2SO4 can also be used
(B) All Na–salts are usually soluble in water
(C) K2CO3 also can be used instead of Na2CO3.
(D) During soda extract preparation Hg2Cl2 gives metallic Hg as residue.
 ADVANCED LEVEL PROBLEMS

Question No. 114 to 116 (3 Question)

(A)
Cl is
Quick lime ¾H¾
2O
¾ ® (dried ) ¾¾2¾® (B) + H2O
Passed

Q.114 (B) on reaction with NH3 & PH3 produces _____ & ______ respectively.
(A) N2 & P4 (B) NCl3 & PCl3 (C) N2 & PCl3 (D) NCl3 & PCl5

Q.115 The oxidation states of Cl-atoms in B are

(A) +1, +1 (B) +1, 0 (C) –1, +1 (D) –1, –1

Q.116 When aqueous solution of (A) reacts with gas mixture (D) and turns milky. (D) may
consist of
(A) CO2 + H2 (B) SO2 + N2 (C) CO2 + SO2 (D) All of the three

Question No. 117 to 119 (3 Question)

(i) Salt 'A' ¾

¾® Anhydrous. 'A' ¾strongly
¾¾ ¾® 'B' + 'C' .
heated heated

(ii) Aqueous solution of 'C' + Hg(NO3)2 solution ¾® D¯ (Yellow ppt.).

(iii) Aqueous solution of 'A' + KCN ¾® [colourless solution] ¾FeCl
¾¾3 ® Blood red
solution
colouration.

Q.117 The ppt. 'D' is

(A) HgO (B) HgO. HgSO4 (C) HgSO4. 2HgO (D) CdS

Q.118 The structure of anionic part of 'B' is

(A) Linear (B) Zigzag chain (C) planar ring (D) Nonplanar ring

Q.119 The number of water of crystallisation in 'A' is

(A) 4 (B) 3 (C) 2 (D) 5

Question No. 120 to 122 (3 Question)

2– +
Cr2O7 /H
(A) dil HCl (B) + (C) (D)
(mixture of (gas) (gas) (Yellow
two salt) and
+

turbidity)
MnO4 /H

hot HNO 3
–

dil
dil HgCl2 (F)
(E)
(Yellow ppt.)

Q.120 Find the anion(s).

(A) SO32– (B) SO32–, S2– (C) SO32–, CO32– (D) S2O32–
 ADVANCED LEVEL PROBLEMS

Q.121 Find out (E)

(A) S2– (B) CO32– (C) S2O32– (D) SO42–

Q.122 Find out (F)

(A) HgSO4.2HgO (B) HgSO4.3HgO (C) HgSO4 (D) Hg2SO4.3HgO

Question No. 123 to 125 (3 Question)

Read the following sequence of reaction.
White ppt.
dil.H2SO4
conc.HCl
(A) Gas (B) + Compound (C), Soluble in hot water
Black
Mineral (CH3COO)2Pb

Heat/air
K2Cr2O 7 solution
(D) + Pungent gas (E) Green solution
NaOH

(F) CH COOH / K2CrO4 (G) Yellow ppt.

3

NaOH
Q.123 Gas (B) on passing through CdSO4 solution will give
(A) Black ppt. (B) Yellow ppt. (C) Orange ppt. (D) No ppt.

Q.124 Compound (A), (B) and (E) are respectively.

(A) CuS, H2S, SO2 (B) PbS, H2S, SO2 (C) PbS, H2S, SO3 (D) ZnS, H2S, SO2

Q.125 Compound (C) and (D) are respectively

(A) PbO, PbCl2 (B) PbCl2 , PbO (C) PbO, PbO2 (D) PbS, PbO

Question No. 126 to 128 (Question)

CuSO4 solution is heated in Liebig condenser.
Water

Distillation
flask CuSO4 Water
solution
Condensate ‘A’

When condensate 'A' is obtained, white powder 'B' is also obtained in the distillation
flask.
Q.126 The colour of condensate 'A' is
(A) Blue (B) Yellow (C) Colourless (D) Green
 ADVANCED LEVEL PROBLEMS

Q.127 'A' is added to KI solution, which of the following observation is correct.

(A) Dark brown solution is obtained
(B) Brownish yellow solution is obtained
(C) It s being diluted only without any colour change
(D) None of these is correct.

Q.128 When white powder 'B' is added to excess of KI solution. Which of the following
phenomenon is associated with it.
(A) Initially redox reaction takes place.
(B) Dark brown appearance is observed.
(C) White precipitate is formed which remains invisible by the brown colouration.
(D) All are correct.

Question No. 129 to 131 (Question)

A great scientist "PHUNSUKH WANGDU " collected four sample solution in different
test tube for a new discovery to achieve "Nobel Prize" (Chemistry) in the year of 2010.
But his very close friend "CHATUR" all of a sudden appears in the laboratory and
kicked off a bottle of ammonia solution on all these samples, which cause precipitation
from all samples and spoiled the experiments. But "PHUNSUKH WANGDU" told
himself "ALL IS WELL" and has not lost his enthusiasm at all and found the following
observation about the precipitates.
Test tube number Observation
(a) White ppt. which is soluble in excess of NH3 solution
(b) On heating white ppt. obtained from (b) produces a
compound which is white in cold but yellow on heating.
(c) The cation present in (c) form white ppt. with hypo solution
which gives black ppt. on heating
(d) The cation present in (d) form soluble complex with excess
of NH3 solution.

Q.129 White ppts. in "a", "b" and "c" respectively obtained after NH3 solution.
(A) Zn(OH)2, Zn(OH)2 , HgO. Hg(NH2)NO3
(B) Cd(OH)2,Zn(OH)2 , HgO.Hg (NH2)NO3
(C) HgO.Hg(NH2)NO3, Zn(OH)2, Cd(OH)2
(D) Al(OH)3, Zn(OH)2, Pb(OH)2

Q.130 The solution initially present in test tube "a" + H2S (basic medium) gives ppt., then test
tube "a" may have
(A) Zn2+ (B) Cd2+ (C) Co2+ (D) Ni2+
 ADVANCED LEVEL PROBLEMS

Q.131 White ppt. in test tube "c" and the soluble complex formed from white ppt. with the hypo
solution is/are
(A) Pb(OH)2, [Pb(S2O3)2]2– (B) Ag2O, [Ag(S2O3)2]3–
(C) HgO.Hg(NH2)NO3, [Hg(S2O3)2]2– (D) None of these

Question No. 132 to 134 (3 Question)

D on strong
Amorphous powder
(i) Compound 'A' Initially heating
(Solid) swelled

NaOH
(ii) Aq. Solution +
in excess
Compound 'A' Reddish
brown ppt.
KSCN

Blood red
colouration
passed into
(iii) Gas (B) (MnSO4 + H2O 2
Brownish black ppt.(D)
solution)

Q.132 The compound 'A' is

(A) Borax (B) Alum (C) Borax or Alum (D) Neither Borax nor Alum

Q.133 The cation present in the Alum (A) is / are

(A) Only K+ (B) NH4+ and Al3+ (C) K+ and Fe3+ (D) NH4+ and Fe3+

Q.134 The oxidation state of Mn in ppt. (D) is

(A) + 2 (B) + 7 (C) + 4 (D) + 6

Question No. 135 to 137 (3 Question)

D
(i) A ¾¾® Glassy transparent bead (B) on platinum wire loop
(B) + CuSO4 ® Coloured bead (C)
(ii) (A) + conc. H2SO4 + H3CCH2OH ¾ignite ¾¾® Green Flame (D)
(iii) Aqueous solution of (A) is alkaline.

Q.135 How many water molecules are present in compound (A)

(A) 4 (B) 5 (C) 10 (D) 6

Q.136 Aqueous solution of "A" form a complex compound then what is the coordination
number in that particular complex.
(A) 2 (B) 4 (C) 6 (D) 5
 ADVANCED LEVEL PROBLEMS

Q.137 What is the oxidation number of central atom is responsible for Green Flame in
compound (D)
(A) + 2 (B) + 1 (C) + 3 (D) Zero

Question No. 138 to 140 (3 Question)

The thermal stability of compound is defined as the temperature withstanding capacity of
it and at a particular temperature they undergo decomposition. Which is called as
decomposition temperature of that compound.
Q.138 Which of the following compound on heating does not produce NH3.
(A) (NH4)2CO3 (B) (NH4)2SO4 (C) NH4ClO4 (D) (NH4)3PO4

Q.139 Which of the following compound on heating produces anhydrous form of that
compound.
(A) FeCl3.6H2O (B) CoCl2.6H2O (C) AlCl3.6H2O (D) MgCl2.6H2O

Q.140 Which of the following statement is not true.

(A) HgI2 (red) and HgI2 (yellow) both exists at room temperature.
(B) Ferric sulphate produces brown residue on heating.
(C) Ferrous sulphate produces brown residue on heating
(D) Tertiary phosphate of sodium produces pyrophosphate on heating.

Question No. 141 to 143 (3 Question

FeSO4 + conc. H2SO4
Salt (A) Brown ring
Na CO
3 solutio
2
n
K2HgI4
(E) Brown ppt. (B) White ppt.
+ KOH

(X) gas in excess

White ppt.
(D) (C) Colourless solution
NH4Cl
D
(E) + (F) gives brickred colour
to flame (B) White ppt.

(G) + (H) + (I) + H2O

Basic gas Acidic gas Neutral gas

Q.141 Compound (H) is

(A) Linear (B) Trigonal planar
(C) Trigonal bipyramidal (D) Octahedral
 ADVANCED LEVEL PROBLEMS

Q.142 What will be the hybridisation in salt A.

(A) sp2 (B) sp (C) sp3 (D) sp3d

Q.143 Gas (I) when combine with Nickel metal gives tetahedral complex having oxidation state
of Nickel is zero and this reaction is involved in Mond's process. What will be the
effective atomic number of that tetrahedral complex:
(A) 36 (B) 34 (C) 54 (D) 84

Question No. 144 to 146 (3 Question)

D CuSO4
(A) (B) + (C) + (D) Blue solution (G)
Orange Gas Green Solid
compound
NaOH + H2O2

BaCl2
Yellow Yellow ppt. (F)
D Mg solution
Gas H2O
(E) (C)
White Solid
O3

Hydrogen
(B) (E)
Gas High temp. Gas
High pressure

Give answer from the above paragraph:–

Q.144 When Cl2 gas reacts with excess of (E) then product is:
(A) Gas B (B) Solid C (C) D compound (D) None of these

Q.145 What will be the hybridisation in compound (A)

(A) d3s (B) sp3 & d3s (C) sp3d2 & sp3 (D) None of these

Q.146 In how many different ways by which water molecules are attached in compound (G)
(A) 2 (B) 1 (C) 4 (D) 3
 ADVANCED LEVEL PROBLEMS

Question No. 147 to 149 (3 Question)

Read the following sequence of reaction.
White ppt.
dil.H2SO4
conc.HCl
(A) Gas (B) + Compound (C), Soluble in hot water
Black
Mineral (CH3COO)2Pb

Heat/air
K2Cr2O 7 solution
(D) + Pungent gas (E) Green solution
NaOH

(F) CH COOH / K2CrO4 (G) Yellow ppt.

3

NaOH
Q.147 The number of electron gained by Cr atom when gas (E) is passed through it
(A) 1 (B) 3 (C) 2 (D) 4

Q.148 Compound (F) is

(A) PbO (B) PbS (C) PbSO4 (D) Na2PbO2

Q.149 The compound (G) is

(A) Pb(OH)2 (B) PbCrO4 (C) PbCrO2 (D) Cr(OH)3

Question No. 150 to 152 (3 Question)

Soluble
conc.H2SO4

(Y)
BaCl2 White
ppt. (Z)
H2O2 HCl
SO2 (X)
Na2CO3(aq.) Insoluble
(aq.)
Boil
with S

(W)

Q.150 When (X) is treated with dilute HCl, a gas is evolved which would decolourise
(A) Acidified KMnO4 (B) Br2 + H2O (C) I2 + H2O (D) All of these
 ADVANCED LEVEL PROBLEMS

Q.151 Which of the following statements is correct regarding the compound (W)?
(A) It does not decolourise (starch I2) complex
(B) It gives orange ppt. with AgNO3
(C) It gives white ppt. with Pb(OAc)2 and the precipitate is soluble in excess of solution
of (W).
(D) All of these
(i ) KCN
Q.152 Aqueous solution of (W) ¾¾ ¾ ¾® ?
(ii ) FeCl3
Colouration obtained is
(A) Blue (B) Black (C) (Blood) red (D) Colourless

Question No. 153 to 155 (3 Question)

Gas colourless (A)
+
KMnO4 + H
Yellow powder (B)

(X)

(Y)
Zn+HCl
(i) X (A)
Ag
Cl 3
NO
Fe
3

(ii) [B + X® Y] Violet/Purple (C) White ppt. (E)

Exposure/D

Green (D) Black (F)

Q.153 Gas (A) when passed in alkaline sodium nitropruside and neutral sodium nitropruside,
what is its colour in alkaline medium and neutral medium respectively?
(A) Purple and Colourless (B) Purple and Green
(C) Green and Purple (D) Colourless and Purple

Q.154 When compound (Y) combines with I2 ,

(A) Coloured solution is obtained (B) I2 is disproportionated
(C) I2 gets reduced (D) I2 gets oxidised
Q.155 What will be the oxidation state of metal atom in (F)?
(A) 1+ (B) 6+ (C) 4+ (D) None of these
 ADVANCED LEVEL PROBLEMS

Question No. 156 to 158 (3 Question)

(A) + K2Cr2O7 + conc. H 2SO 4
Salt solid

NaOH
(B)
(E) gas Orange red fumes
NaOH
HCl
(C)
White fumes yellow solution
(A)
(CH3COO)2Pb CH3COOH

(D)
yellow ppt

Q.156 What will be the hybridisation of central atom in compound (B), (C) and (D)?
(A) sp2 (B) sp3d2 (C) d2sp3 (D) d3s

Q.157 BaCl2 + (C) ® (X)

For (X) which option is correct?
(A) X is soluble in NaOH (B) X is a yellow coloured compound
(C) X is amphoteric in nature (D) In X the –ve ion is octahedral
( Z) HNO 3 (Y)
(Y) ¾¾ ¾¾
Q.158 Salt (A) + AgNO3 ® white 2
® (so lub le solution¾
( E )+ H O
)
¾¾® ( white ppt )
ppt.

What will the hybridisation of central atom in complex (Z)?

(A) sp3d2 (B) d2sp3 (C) sp3 (D) sp

Question No. 159 to 161 (3 Question)

Red hot Mg HO NiCl2 solution
(I) 2 (J) (K)
White Deep blue
solid solution
(When excess J is passed)
(A) D
Anhydrous
(B) + (C) + (D) (E)
CoCl2
Orange Coloured Pink solid
solid solid

Q.159 Hybridisation in compound (A) is :

(A) sp3 & d3s (B) sp3 & dsp2 (C) sp3 & sp2 (D) dsp2 & sp2

Q.160 Type of hybridisation in compound (K)

(A) d2sp3 (B) sp3d2 (C) dsp2 (D) sp3

Q.161 Difference of Bond angle between (J) and (C) is:

(A) 180° (B) 107.5° (C) 72.5° (D) 90°
 ADVANCED LEVEL PROBLEMS

Question No. 162 to 164 (3 Question)

NH4 Cl + Na2HPO4 + 4 Z A + NaCl
(sparingly
soluble salt)
D
A A' + 4Z

D
A' X +Y + Z
High temperature

Compound (Z) is a neutral oxide and turns anhydrous CuSO4 blue. Gas(Y) is a basic gas
which can also be obtained by treating ammonium sulphate with lime water. Sequences
mentioned above involve balanced reactions.

Q.162 The compound 'X' is

(A) NaHPO4 (B) Na3PO3 (C) NaPO3 (D) Na3PO4

Q.163 Which of the following reactions would produce gas 'Y'?

(A) Mg3N2 + H2O ¾¾ ¾® (B) Zn + NaOH + NaNO3 ¾¾D¾®
(C) (NH4)2CO3 ¾¾D¾® (D) All of these

Q.164 Formula of (A) is :

(A) Na2(NH4)PO4.4H2O (B) Na(NH4)HPO4.4H2O
(C) Na(NH4)2PO4.4H2O (D) (NH4)2HPO4.4H2O

Question No. 165 to 167 (3 Question)

Salt (W) gives golden yellow colouration in Bunsen flame. When (W) is oxidised by
acidified K2Cr2O7, a colourless gas (X) is evolved which turns lime water milky and the
milkiness disappears on passing excess of gas (X). However gas (X) does not decolourise
pink solution of acidified KMnO4. When aqueous solution of salt (W) is added slowly to
hydrated MnO2, red coloured solution is obtained due to formation of soluble complex
(Y) along with evolution of gas (X).

Q.165 Gas (X) is

(A) CO2 (B) SO2 (C) SO3 (D) NO2

Q.166 The red coloured complex (Y) is

(A) [Mn(C2O4)3]2– (B) [Mn(C2O4)3]3– (C) [MnCl4]¯ (D) [Mn(NH3)6]2+

Q.167 The salt (W) is

(A) HCOONa (B) CH3COONa (C) Na2C2O4 (D) Na2SO3
 ADVANCED LEVEL PROBLEMS

Question No. 168 to 170 (3 Question)

Compound (A) when treated with excess of caustic soda produces a gas (X) which turns
red litmus blue and the resulting solution on heating with Zn powder yields the same gas
(X). The compound (A) on dry heating produces only two neutral oxides (Y) and (Z),
leaving behind no residue. (Z) turns anhydrous copper sulphate blue. Another compound
(A') also undergoes the above mentioned reactions except that (A') on dry heating
produces (Z) and an inert gas (Y').
II
Ru2+ + 5NH3 + Y' ® [Ru ( NH 3 )5 Y' ]2+; (Atomic number of Ru = 44)
This complex is used as an anaesthetic.
Q.168 The compound (A) is
(A) NH4NO3 (B) NH4NO2 (C) NH4IO3 (D) (NH4)2CO3

Q.169 Choose the correct statement(s)

(A) Bond length between similar atoms in free molecule of (Y') is longer than that in the
complex formed.
(B) Bond length between similar atoms in free molecule of (Y') is shorter than that in the
complex formed
(C) The complex is diamagnetic.
(D) Both (B) and (C) are correct.
Q.170 Which of the following is/are correctly matched?
(A) Y > NH2– OH (N–O bond length)
(B) Y > N2 (N–N bond length)
(C) Y < NO(N–O bond length)
(D) All of these

Question No. 171 to 173 (3 Question)

Two salts A and B both gives white ppt with BaCl2, these white ppt. is insoluble in conc.
HCl and conc. HNO3 and Brown ppt with alkaline Nessler's reagent. Salt A gives blue
colour with reagent X. Reagent X on oxidation gives reagent Y. That reagent Y gives
blue colour with salt B.
(X and Y are potassium containing reagents)

Q.171 The ratio of number of water molecules as crystallisation in salt A and B is

(A) 4 (B) 24 (C) 6 (D) 18

Q.172 The reagent 'X' on reaction with conc. H2SO4 gives gas.
(A) CO (B) CO2 (C) N2 (D) NH3

Q.173 What will be the oxidation state of the red-brown coloured residue obtain by thermal
decomposion of salt B?
(A) + 2 (B) + 3 (C) + 6 (D) + 1
 ADVANCED LEVEL PROBLEMS

Question No. 174 to 176 (3 Question)

Salt (X) gives white ppt. with BaCl2 which is insoluble in conc. HNO3 and conc.HCl.
Salt (X) on reaction with NaOH in presence of H2O2 gives green solution (Y) which on
acidification turns into purple coloured compound (Z).

Q.174 Compound (Y) is

(A) Paramagnetic with one unpaired electron
(B) Diamagnetic
(C) Paramagnetic with two unpaired electron
(D) Paramagnetic with four unpaired electrons.

Q.175 The ratio of p bonds in compound (Y) and (Z) respectively is

(A) 2 : 3 (B) 3 : 4 (C) 3 : 2 (D) 3 : 3

Q.176 Anions of compounds X, Y and Z are :

(A) Tetrahedral Square planar Square planar
(B) Square planar Tetrahedral Square planar
(C) Tetrahedral Tetrahedral Tetrahedral
(D) Square planar Square planar Square planar

Question No. 177 to 179 (3 Question)

(A) + Na2CO3(aq) B) + (C) + (D)

® (! $!#! "
white ppt. so lub le

(D) + CO2 ® (C) + Na2CO3

D

Blue bead ¬¾¾¾ (E) +

CoO (D)
Q.177 (A) is a mineral of
(A) Boron (B) Iron (C) Copper (D) Zinc
Q.178 (E) + Cr2O3 ® coloured bead. The colour of bead is
(A) Blue (B) Green (C) Black (D) Brown
Q.179 (C) + H2SO4 ® (X) ¾hydrolysis D
¾ ¾¾® (Y) ¾¾® (Z).
(A) (Y) is a monobasic acid (B) (Y) is a dibasic acid
(C) (Y) is a tribasic acid (D) (Y) is a tetrabasic acid
 ADVANCED LEVEL PROBLEMS

Question No. 180 to 182 (3 Question)

Salt (A) reacts with NaOH gives gas (B) and compound (C), compound (C) on reaction
with Zn in the solution gives gas (B), salt (A) on decomposition gives two neutral oxide
(D) and (E), (D) on reaction with P4 gives dehydrating agent (F).
Q.180 What is covalency of central atom 'F'?
(A) 5 (B) 4 (C) 3 (D) 2

Q.181 Hybridisation of salt 'A' is:

(A) sp3 (B) sp2 (C) both (A) & (B) (D) None

Q.182 The oxidation state of central atom in compound 'D' is :

(A) 1+ (B) 2– (C) 1– (D) 2+

Question No. 183 to 184 (3 Question)

When white crystalline compound 'X' is heated with K2Cr2O7 and conc. H2SO4 reddish
brown gas 'A' is evolved on passing 'A' into caustic soda solution yellow coloured
solution of 'B' is obtained neutralizing the solution of 'B' with acetic acid on subsequent
addition of (CH3COO)2Pb yellow ppt. 'C' is obtained. When 'X' is heated with NaOH
solution a colourless gas is evolved which gives brown ppt. 'D' with Nessler's reagent.

Q.183 The d-orbital which will not participate in hybridisation of compound 'C' is :
(A) d x 2 -y2 (B) d 2z (C) both (A) and (B) (D) dxy

Q.184 Which of the following is correct regarding the property of compound (A)?
(i) It has two pp-dp bonds
(ii) tetrahedral
(iii) paramagnetic
(iv) its colour is due to charge transfer.
(A) TTFT (B) TTTT (C) TTFF (D) FTFT

Question No. 185 to 187 (3 Question)

A powdered substance 'A' on treatment with fusion mixture gives a green coloured
compound 'B' the solution of 'B' in boiling water on acidification with dil H2SO4 gives a
pink coloured compound 'C' the aqueous solution of 'A' on treatment with excess of
NaOH and Br2 water give compound 'D'. Solution of 'D' in conc. HNO3 on treatment with
PbO2 at boiling temperature produce compound 'E' which has same colour that of 'C'

Q.185 A solution of 'A' on treatment with solution of BaCl2 give a white ppt. of compound 'F'
which is insoluble in conc. HNO3 and conc. HCl.
(A) BaSO4 (B) BaSO3 (C) BaCrO4 (D) MnSO4
 ADVANCED LEVEL PROBLEMS

Q.188 Compound 'B' is:

(A) Diamagnetic (B) Paramagnetic (C) Tetrahedral (D) Both 'B' and 'C'

Q.187 Which of the following acts as Bronsted acid?

(A) Compound 'A' (B) compound 'B' (C) compound 'C' (D) compound 'E

Question No. 188 to 189 (2 Question)

Boron on heating at 700°C in air gives white infusible amorphous powder 'A' which
decomposed when heated in a current of steam to give a white powder 'B' and gas 'C'.
Same gas 'C' is evolved when solution of LiH is treated with sodium nitrate. Compound
'B' on strong heating gives 'D'. Mixture of 'D' and carbon on heating in a current of Cl2
gives a colourless fuming liquid 'E'. On reduction LiAlH4 produce gas 'G'. G has
disagreeable smell causes headache. 'G' on heating with 'C' at 200°C produce benzene
like compound 'H'.
Q.188 Gas 'H' when reacts with HCl protonation occurs at :
(A) B (B) N (C) H (D) None

Q.189 Gas 'C' when reacts with bleaching powder gives gas 'J'.
(A) Gas 'J' is inert gas
(B) Gas 'J' reacts with Mg gives white solid
(C) both are correct
(D) None

Question No. 190 to 192 (3 Question)

Salt (W) gives golden yellow colouration in Bunsen flame. When (W) is oxidised by
acidified K2Cr2O7, a colourless gas (X) is evolved which turns lime water milky and the
milkiness disappears on passing excess of gas (X). However gas (X) does not decolourise
pink solution of acidified KMnO4. When aqueous solution of salt (W) is added slowly to
hydrated MnO2, red coloured solution is obtained due to formation of soluble complex
(Y) along with evolution of gas (X).

Q.190 Gas (X) is

(A) CO2 (B) SO2 (C) SO3 (D) NO2

Q.191 The red coloured complex (Y) is

(A) [Mn(C2O4)3]2– (B) [Mn(C2O4)3]3– (C) [MnCl4]¯ (D) [Mn(NH3)6]2+

Q.192 The salt (W) is

(A) HCOONa (B) CH3COONa (C) Na2C2O4 (D) Na2SO3
 ADVANCED LEVEL PROBLEMS

Question No. 193 to 195 (3 Question)

An aqueous solution of salt(X) gives white precipitate with barium chloride solution
which is insoluble in dilute HCl and dilute HNO3. When ammonia (aq) is added to the
aqueous solution of salt(X), blue precipitate is obtained which dissolves in excess
ammonia producing deep blue colouration due to formation of complex (Y). With KCN,
(X) gives first a yellow precipitate which quickly decomposes into white precipitate,
liberating highly poisonous gas(Z). (Z) on hydrogenation produces (Z ') which gives
yellowish orange coloured complex(P) with CoCl3.

Q.193 Salt (X) is :

(A) CuSO4 (B) NiSO4 (C) Ag2SO4 (D) ZnSO4

Q.194 Select the correct statement regarding complex (Y)

(A) It is paramagnetic (B) It has square planar geometry
(C) It gives black precipitate with H2S (D) All of these

Q.195 Which of the following statements is/are correct regarding the complex(P)?
(A) It shows optical isomerism (B) It is diamagnetic
(C) It has octahedral geometry (D) All of these

Question No. 196 to 198 (3 Question)

Metal cations (A+2, B+2,
C+2, D+2) precipitate in form of sulphides by (NH4Cl + NH4OH +
H2S) and not by (dil. HCl + H2S), their precipitates show the following observations.
Sulphides AS BS CS DS
Reagent
CH3COOH Soluble Insoluble Insoluble Insoluble

dil. HCl Soluble Soluble Insoluble Insoluble

hot &
conc.HNO3 Soluble Soluble Soluble Soluble

Q.196 "A" is :
(A) Mn+2 (B) Zn+2 (C) Co+2 (D) Ni+2

Q.197 Hybridisation of B2+ in the soluble compound which is formed with excess of NH4OH,
is
(A) sp3 (B) dsp2 (C) sp2 (D) d2sp3

Q.198 C2+ forms green precipitate with NH4OH which dissolves in excess of NH4OH forming
deep blue solution. C2+ forms rosy red precipitate with dmg in slightly basic medium. C2+
is
(A) Co+2 (B) Ni+2 (C) Pb+2 (D) Cu+2
 ADVANCED LEVEL PROBLEMS

Question No. 199 to 200 (2 Question)

Xa+ NaOH Blue ppt.(P) excess NaOH insoluble
cation
NH4OH
DMG excess
Na2S No ppt. NH4OH

Black deep blue solution (Q)

ppt.

hot & soluble

conc. HNO3

Another cation Yb+ undergoes all the above mentioned reactions showing similar
observation except that it produces green coloured ppt with NaOH / NH4OH which
dissolves in excess of NH4OH producing deep blue solution forming (R) and rosy red
precipitate with dimethyl glyoxime in mild basic medium.

Q.199 The difference in coordination number of central metal ions in (R) and (Q) is :
(A) 0 (B) 1 (C) 2 (D) 3

Q.200 Xa+ and Yb+ are respectively.

(A) Cu2+ and Cr3+ (B) Cu2+ and Ni2+ (C) Cu2+ and Fe2+ (D) Fe2+ and Fe3+

Question No. 201 to 203 (3 Question)

(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured
compound (B).
(ii)The solution of (B) on acidification with hot dilute H2SO4 gives a pink coloured
compound (C).
(iii)The aqueous solution of (A) on treatment with excess of NaOH and bromine water
gives a compound (D).
(iv)A solution of (D) in conc. HNO3 with lead dioxide at boiling temperature produces a
compound (E), which has of the same colour as that of (C).
(v)A solution of (A) in dilute HCl on treatment with a solution of barium chloride gave a
white precipitate of compound (F), which was insoluble in conc.HNO3 and conc. HCl.
Identify (A) to (F) and give balanced chemical equations for the reactions at steps (i) to
(v).

Q.201 What is A?
(A) FeSO4 (B) HMnO4 (C) MnSO4 (D) Na2MnO4

Q.202 Compound (C) and (E) are coloured due to

(A) d-d transition (B) covalent nature (C) charge transfer (D) all the above
 ADVANCED LEVEL PROBLEMS

Q.203 What is D?
(A) MnO2 (B) FeS (C) Na2MnO4 (D) MnO

Question No. 204 to 205 (2 Question)

+
(A) H (B)
H2S Yellow ppt.
BaCl2 [Insoluble in yellow
solution ammonium sulphide]

(C)
white ppt. HNO3
Insoluble in conc. HCl
& conc. HNO3 (D)
KCN s) NH4OH (excess)
es
xc
(e
(E) (F)

H2S H2S

(B) (B)

Q.204 What is 'C'?

(A) PbCl2 (B) BaSO4 (C) BaSO3 (D) PbSO4

Q.205 What is 'B'?

(A) CdS (B) PbCrO4 (C) HgO (D) K3[Co(NO2)6]

Question No. 206 to 208 (3 Question)

(i)A powdered substance (A) on treatment with fusion mixture gives a green coloured
compound (B).
(ii)The solution of (B) on acidification with hot dilute H2SO4 gives a pink coloured
compound (C).
(iii)The aqueous solution of (A) on treatment with excess of NaOH and bromine water
gives a compound (D).
(iv)A solution of (D) in conc. HNO3 with lead dioxide at boiling temperature produces a
compound (E), which has of the same colour as that of (C).
(v)A solution of (A) in dilute HCl on treatment with a solution of barium chloride gave a
white precipitate of compound (F), which was insoluble in conc.HNO3 and conc. HCl.
Identify (A) to (F) and give balanced chemical equations for the reactions at steps (i) to
(v).

Q.206 What is A?
(A) FeSO4 (B) HMnO4 (C) MnSO4 (D) Na2MnO4
 ADVANCED LEVEL PROBLEMS

Q.207 Compound (C) and (E) are coloured due to

(A) d-d transition (B) covalent nature (C) charge transfer (D) all the above

Q.208 What is D?
(A) MnO2 (B) FeS (C) Na2MnO4 (D) MnO

Question No. 209 to 210 (2 Question)

(A) D (B) + 'C'

dil HCl D

'X' CO + CO2 + (D) + Carbon

SO2

(E) + CO2
'S'
(F)
AgNO3
BiCl3
Exp.
(J) (I)
Black White ppt. (G)
White ppt.
(excess) Na2S2O3
(excess) Na2S2O3

(K)
Soluble complex (H)
Transparent
complex
D

(J)
Black

Q.209 Compound 'A' is :

(A) Oxalate salt (B) Formate salt (C) Acetate salt (D) Carbonate salt

Q.210 Coordination number 'K' is :

(A) 2 (B) 4 (C) 3 (D) 6
 ADVANCED LEVEL PROBLEMS

Question No. 211 to 212 (2 Question)

Salt is a mixed form of acidic and basic radical. The confirmatory test of basic and acidic
radicals by using chemical reagent is called qualitative analysis. Precipitation reaction is
used for the confirmatory test of radicals.
Q.211 Which of the following is an example of IIA group basic radical sulphide?
(A) MnS (B) FeS (C) CdS (D) Na2S

Q.212 Which of following iodide has scarlet red colour?

(A) PbI2 (B) HgI2 (C) AgI (D) All the above

Question No. 213 to 214 (2 Question)

Aqueous solution +NaOH White ppt. excess NaOH Soluble complex
solution (B) solution (C)
(A)

Aqueous solution +NaOH White ppt. excess NaOH Insoluble

solution (E) solution
(D)

(C) Black metallic Soluble complex

(D) or (E)
deposition + (G)
(F)

Q.213 Which of the following cation is present in the aqueous solution of (A)?
(A) Zn2+ (B) Fe2+ (C) Sn2+ (D) Pb2+

Q.214 Aqueous solution of + a few drops of Brownish yellow

(D) H2O2 solution solution of
(H)

The oxidation state of metal ion in the solution (H) is

(A) + 2 (B) + 3 (C) + 4 (D) + 5

Question No. 215 to 217 (3 Question)

Consider the following sequences of reactions:
¾¾® Black ¯ (X)
-
(I) MnSO ¾H¾2O¾ 2 +OH
4
(i ) acidified
(II) (X) ¾¾¾¾ ¾® red colouration (Z)
(ii) Na 2C2O4

Q.215 Which of the following options is correct?

(A) (Z) is diamagnetic (B) (Z) exhibits optical isomerism
(C) (Z) exhibits geometrical isomerism (D) (Z) has tetrahedral geometry

Q.216 The difference in oxidation state of central metal atom or ion in (X) and (Z) is
(A) 1 (B) 2 (C) 0 (D) 3
 ADVANCED LEVEL PROBLEMS

Q.217 Select the correct statement(s).

(A) (X) acts an oxidising agent in IInd experiment.
(B) IInd experiment involves evolution of CO2 gas.
(C) Both Ist and IInd involve redox reaction.
(D) All of these

Paragraph for question nos. 218 to 220

Aq. suspension solution
Clear excess on heating White ppt. of AgNO3
solution of Z Black ppt. Hypo solution
U T S R

Crystal water
Q

Element X which has Disproportionation

+ NaOH Z + Y
six valence electron (alk.solution)

Aqueous solution

Na2[Fe(CN)5NO]
of A
White ppt.
excess A
NaOH

Soluble +Y Purple
compound White ppt. colouration
B C P
Q.218Select the compound which has/have zero unpaired electron on central metal atom.
(A) B (B) P (C) U (D) All of these

Q.219 Identify the value of Q which are present in compound R.

(A) 7 (B) 24 (C) 5 (D) 4

Q.220 Compound T is :
(A) Ag2S2O3 (B) [Ag(S2O3)2]–3 (C) Ag2S (D) Ag
 ADVANCED LEVEL PROBLEMS

Paragraph for question nos. 221 & 222

D
Unknown Salt [X]gas + [Y]gas + [Z]neutral oxide
(Solid)
H2O
dil H2SO4
Pink HPh [Y]gas
colour

NaOH
N2Cl Red colour
NaOH +
compound
[X]gas
NO2

Q.221 The red colour compound is :

ONH4 Å
N2 Cl

(A) (B)

NO2
Å
N2 ONH4
(C) (D) O2N N = N – ONH4

Q.222 Choose the incorrect statement :

(A) [X]gas is sp3 hybridised (B) [X]gas is linear
(C) Bond angle in [X]gas is greater than [Z] (D) [X]gas is soluble in H2O

Paragraph for question nos. 224 & 225

H2 O D AgNO3 NaCN
[R] [Y] [P] [X] [W]
–5 gas solution
(Kb = 1.8 × 10 ) pH < 7 White Soluble
ppt. compound

Alkaline
[Z]
solution
Brown ppt.
K2[HgI4]

Q.223 What is the hybridisation of [W] compound ?

(A) sp3 (B) sp (C) sp2 (D) d3s

Q.224 If [P] concentration is taken 0.01 M then what is the actual pH of [P] in aqueous solution?
(A) 3.63 (B) 5.63 (C) 4.63 (D) 6.62
 ADVANCED LEVEL PROBLEMS

ANSWER KEY

1 (B) 2 (C) 3 (D) 4 (B) 5 (C)

6 (A) 7 (D) 8 (D) 9 (C) 10 (B)

11 (B) 12 (D) 13 (C) 14 (B) 15 (C)

16 (D) 17 (B) 18 (C) 19 (B) 20 (C)

21 (D) 22 (A) 23 (D) 24 (A) 25 (B)

26 (B) 27 (A) 28 (C) 29 (D) 30 (C)

31 (B) 32 (A) 33 (A) 34 (B) 35 (B)

36 (A) 37 (B) 38 (C) 39 (B) 40 (A)

41 (B) 42 (C) 43 (B) 44 (B) 45 (D)

46 (A) 47 (B) 48 (A) 49 (B) 50 (C)

(i)(C)
51 52 (A) 53 (D) 54 (A) 55 (B)
(ii)(B)
56 (B) 57 (A) 58 (C) 59 (D) 60 (B)

61 (C) 62 (D) 63 (B) 64 (A) 65 (C)

66 (B) 67 (C) 68 (D) 69 (B) 70 (D)

71 (C) 72 (B) 73 (A) 74 (B) 75 (B)

76 (C) 77 (A) 78 (D) 79 (B) 80 (C)

81 (D) 82 (A) 83 (B) 84 (C) 85 (B)

86 (B) 87 (D) 88 (A) 89 (B) 90 (C)

91 (C) 92 (A) 93 (C) 94 (D) 95 (D)

96 (C) 97 (C) 98 (D) 99 (C) 100 (B)

101 (D) 102 (B) 103 (C) 104 (D) 105 (C)
 ADVANCED LEVEL PROBLEMS

106 (C) 107 (B) 108 (C) 109 (B) 110 (D)

111 (D) 112 (C) 113 (B) 114 (C) 115 (C)

116 (D) 117 (C) 118 (B) 119 (D) 120 (B)

121 (D) 122 (A) 123 (B) 124 (B) 125 (B)

126 (C) 127 (C) 128 (D) 129 (A*,B) 130 (A)

131 (A,C) 132 (B) 133 (D) 134 (C) 135 (C)

136 (B) 137 (C) 138 (C) 139 (B) 140 (D)

141 (A) 142 (A) 143 (A) 144 (A) 145 (A)

146 (D) 147 (B) 148 (D) 149 (B) 150 (D)

151 (C) 152 (C) 153 (A) 154 (C) 155 (A)

156 (D) 157 (B) 158 (D) 159 (A) 160 (B)

161 (B) 162 (C) 163 (D) 164 (B) 165 (A)

166 (B) 167 (C) 168 (A) 169 (D) 170 (B)

171 (A) 172 (A) 173 (B) 174 (A) 175 (A)

176 (C) 177 (A) 178 (B) 179 (A) 180 (A)

181 (C) 182 (A) 183 (C) 184 (A) 185 (A)

186 (D) 187 (D) 188 (B) 189 (C) 190 (A)

191 (B) 192 (C) 193 (A) 194 (D) 195 (D)

196 (A) 197 (A) 198 (B) 199 (C) 200 (B)

201 (C) 202 (C) 203 (A) 204 (B) 205 (A)

206 (C) 207 (C) 208 (A) 209 (B) 210 (A)

211 (C) 212 (B) 213 (C) 214 (D) 215 (B)

216 (A) 217 (D) 218 (A,B) 219 (C) 220 (C)
 ADVANCED LEVEL PROBLEMS

221 (D) 222 (B) 223 (B) 224 (B)

SOLUTION
Q1
[Sol. (B) CO2 has no reducing character as carbon is in its maximum oxidation state of +4]

Q2
[Sol. (C) Ca(OH)2 + CO2 ¾® CaCO3 ¯ + H2O

CaCO3 ¯ H2O + CO2 ¾® Ca(HCO3)2 ]

Q3
[Sol. (D) Boric Acid < Carbonic Acid < Acetic Acid
(Ka = 5.8 × 10–10) (Ka = 4.31 × 10–7) (Ka = 1.76 × 10–5)
Stronger acid can decompose salt of weak acid

Q4
[Sol. (B) Pb(NO3)2 + 2HCl ® PbCl2 ¯ + 2HNO3
white
Q5
[Sol. (C) Pb(NO3)2 ® completely soluble in water]

Q6
[Sol. (A) Na2CO3 + 2HCl ® 2NaCl + CO2 ­ + H2O
Acidic
character
Q7
[Sol. (D) Pb(NO3)2 + CuSO4 ® Cu(NO3)2 + PbSO4 ¯
white ppt.
 ADVANCED LEVEL PROBLEMS

Question No. 8 to 10 (3 questions)

-300°C
[Sol. FeSO4·7H2O ¾-¾ ¾
¾® FeSO —® Fe O + SO ­ + SO ­
7 H 2O 4 2 3 2 3
green black
(A)
Fe2O3 + 6HCl ¾Boil¾¾® 2FeCl3 + 3H2O
(B) (E)
FeCl3 + 3NaOH —® Fe(OH)3¯ + 3NaCl
(F)
SO2 + 2H2S —® 3S¯ + 2H2O
(C) (G)
Na2SO3 + S —® Na2S2O3 ¾HgCl ¾¾2 ® HgS2O3¯ + 2NaCl
(G) (H) (I)
SO3 + H2SO4 —® H2S2O7 ¾H¾¾ 2O 2H 2SO4¾¾ ¾ ¾® CO­ + CO2­
H 2C 2O 4
®
(D) (J) (K) (L)
Ni + 4CO ­ ¾¾¾® [Ni(CO)4]
40°C

(L) (M)

Ans. (i) Ni in [Ni(CO)4]

Ans. (iii) S2O3– – + CN– —® SCN– + SO3– –

Fe3+ + 3SCN– —® Fe(SCN)3
Blood red colouration

Q 12
SOL.
 ADVANCED LEVEL PROBLEMS

Q13
[Sol. 4Na2S2O3·5H2O Na2S5 + 3Na2SO4
(M) (P) (Q)

Na2SO4 + Hg(NO3)2—® HgSO4 ¯ + 2Na+ + 2NO3–

(Q) (R)
yellow

Na2S2O3 + HgCl2 —® HgS2O3¯ + 2NaCl

(M) white
(N)

HgS2O3¯ + H2O ¾¾®

D
HgS¯ + 2H+ + SO4– –
(N) (O)
Black
HgS2O3¯ + Na2S2O3 —® 2Na+ + [Hg(S2O3)2]2–
(N) (M) soluble

Na2S2O3 + 2HCl —® 2NaCl + SO2- + S¯ + H2O

white/yellow
Turbidity

S¯ + 2HNO3 —®H2SO4 + 2NO­

clear sol.

Question No. 18 to 21 (4 questions)

[Sol. Hg2(NO3)2 + 2NaCl —® Hg2Cl2¯ + 2NaNO3

(A) white ppt (B)
Hg2(NO3)2 + 2KI —® Hg2I2¯(green ppt.)
(A) (C)
Hg2I2 + 2KI —® K2[HgI4]2– + Hg
(C) excess (E) soluble complex
$!!Nesslers
!!#reagent
!!!!"

K2HgI4 + NH3 + KOH —®

Hg2(NO3)2 + Na2CrO4 —® Hg2CrO4

(A) Red ppt.
K2[HgI4] —® sp Hybridization
3 ]
 ADVANCED LEVEL PROBLEMS

Question No. 22to 25 (4 questions)

[Sol. 2MnO2 + 4KOH + O2 ¾® 2K2MnO4 + 2H2O

Black solid green
(A)
3 MnO+-4 -4H+ ¾® 2 MnO -4 +MnO2 + 2H2O
(A) (B) (C)
purple
(i) 2KMnO4 + H2O + KI ¾® 2KOH + 2MnO2 + KIO3
(D)
(ii) 2KMnO4 + 8H2SO4 + 10FeSO4 ¾® 2MnSO4 + 5Fe2(SO4)3 + K2SO4 + 8H2O
(iii) 2KMnO4 + H2SO4 (conc) ¾cold
¾¾® Mn2O7 + K2SO4 + H2O
(E)
3
Mn2O7 ¾® 2MnO2 + O2
(E) (F)
2
6KMnO4 + 10FeC2O4 + 24H2SO4 ¾® 6MnSO4 + 5Fe2(SO4)3 + 20CO2 + 3K2SO4 + 24H2O
(yellow) ]

Question No. 26 to 29 ( 4 questions)

[Sol. 4K + 3SO2(g) ¾® K2SO3 + K2S2O3

(M) (A) (C) (B)

2KMnO4 + H2O + 3K2S2O3 ¾® 2KOH + 2MnO2 + 3K2SO4 + 3S¯

(B) Brown

K2SO3 + H2SO4 ¾® K2SO4 + SO2­ + H2O

(C) (A)
4K2SO3 ¾¾®
D K2S + 3K2SO4
(C) (E) (F)

K2S + H2SO4 ¾® K2SO4 + H2S­

Pb(NO3)2 + K2SO4 ¾® 2KNO3 + PbSO4¯
white

PbSO4¯ + 2(NH4)2C2O4 ¾® (NH4)2[Pb(C2O4)2] + (NH4)2SO4

soluble
4FeCl2 + SO2 + 4HCl ¾® 4FeCl3 + S¯ + 2H2O
4Na2S2O3 ¾>¾ ¾® Na2S5 + 3Na2SO4
220°C
¾
 ADVANCED LEVEL PROBLEMS

Question No. 33 to 34 (2 questions)

[Sol. Ans.1 (A) ; Ans.2 (B)

P: Na(NH4)HPO4·4H2O Microcosmic salt
Na(NH4)HPO4 + Mg++ + NH3 ¾® Mg(NH4)PO4 + Na+ + NH +4
(P) Magnesia Mixture (R) White ppt.
Na(NH4)HPO4 ¾¾® D NaPO3 + NH3 + H2O
CoSO4 + NaPO3 ¾¾® NaCoPO4 + SO3
D

Blue mass Q.
Na(NH4)HPO4 + 2NaOH ¾® Na3PO4 + NH3­+2H2O
+
Hg 22++ NO 3- + 4NH3 + H2O ¾® HgO. Hg(NH2)NO3 + 2Hg + 3 N H 4
$!!!!!#!!!!!"
Black

Question No. 35 to 38 (4 questions)

[Sol. Ans.5 (B); Ans.6 (A); Ans.7 (B); Ans.8 (C)

H2SO4 l H+ + HSO -4
On electrolysis with high current density:

At anode: 2HSO -4¾® H2S2O8 + 2 e

(A)
At cathode: 2H + 2 e ¾® H2­
+

H2S2O8 + 2NH4OH ¾® (NH4)2S2O8 + 2H2O

(A) (B)
2Mn++ + 5(NH4)2S2O8 + 8H2O ¾® 2MnO -4 +10SO-4 - + 16H+
(C) (B) Purple
BaCl2 + SO4 ¾® BaSO4¯ + 2Cl
-- –

(white)

Some MnO -4 ions adsorb on BaSO4, and produce pink (violet) colour, rest MnO -4 remain in
sol. which are reduced to Mn++ (colourless) by H2O2. Hence finally pink coloured ppt (D)
is formed.
\ D: (Pink colour ppt.because some MnO -4 ions adsorbed on BaSO4) Here adsorbed MnO -4
is not reduced by H2O2.
2MnO -4 + 5H2O2 + 6H+ ¾® 2Mn++ + 8H2O + O2
Mn++ + H2S ¾® MnS¯
(E)
Buff colour
MnS + 2HCl ¾® MnCl2 + H2S ­
(E) (C)
In contrast to ZnS, MnS is soluble in CH3COOH.
O O
|| ||
H -O -S-O -O -S-O - H
|| ||
O O
 ADVANCED LEVEL PROBLEMS

Question No. 39 to 41 (3 questions

[Sol. NH4NO3 + NaOH ¾® NH3­ + NaNO3 + H2O
(A) (B)
NH3 + 2K2[HgI4] + 3KOH ¾® HgO. Hg(NH2)I ¯ + 3H2O + 7KI
Brown ppt.
NH4NO3 ¾¾® N2O(g) + 2H2O
D

(C) ]

Question No. 42 to 46 (5 questions)

[Sol. MnS + H2SO4 ¾® H2S (g) + MnSO4

(A) (dil.) (B) (C)
Pink/Buff colour colourless colourless
K2Cr2O7 + 4H2SO4 + 3H2S ¾® K2SO4 + Cr2(SO4)3 + 3S¯
(green) (Yellow)
(D)
S + O2 ¾® SO2
(E)
K2Cr2O7 + H2SO4 + 3SO2 ¾® K2SO4 + Cr2(SO4)3 + H2O
(green)
2H2S + SO2 ¾® 3S ¯ + 2H2O
(B) (E) (D)

Na2SO3 + S ¾® Na2S2O3
(F)
Hypo solution is used as an antichlor ie to remove excess of Cl2 from bleached articles.
Na2S2O3 + Cl2 + H2O ¾® Na2SO4 + S + 2HCl
2Mn++ + 5PbO2 + 4H+ ¾® 2MnO -4 + 5Pb++ + 2H2O
violet red ]
 ADVANCED LEVEL PROBLEMS

Question No. 47 to 50 (4 questions)

[Sol. Ans.6 (B)
Ans.7 (A)
Ans.8 (B)
Ans.9 (C)
H2SO4 l H+ + HSO -4
On electrolysis with high current density:

At anode: 2HSO -4 ¾® H2S2O8 + 2 e

(A)
At cathode: 2H + + 2 e ¾® H2­
H2S2O8 + 2NH4OH ¾® (NH4)2S2O8 + 2H2O
(A) (B)
2Mn + 5(NH4)2S2O8 + 8H2O ¾® 2MnO -4 + 10SO-4 - + 16H+
++

(C) (B) Purple

BaCl2 + SO-4¾®-
BaSO4¯ + 2Cl–
(white)
Some MnO -4 ions adsorb on BaSO4, and produce pink (violet) colour, rest MnO -4 remain
in sol. which are reduced to Mn++ (colourless) by H2O2. Hence finally pink coloured ppt
(D) is formed.
\ D: (Pink colour ppt.because some MnO -4 ions adsorbed on BaSO4) Here adsorbed MnO -4
is not reduced by H2O2.
2MnO -4 + 5H2O2 + 6H+ ¾® 2Mn++ + 8H2O + O2
Mn++ + H2S ¾® MnS¯
(E)
Buff colour
MnS + 2HCl ¾® MnCl2 + H2S ­
(E) (C)
In contrast to ZnS, MnS is soluble in CH3COOH.
O O ]
|| ||
H -O -S-O -O -S-O - H
|| ||
O O
 ADVANCED LEVEL PROBLEMS

Question No. 51 (i) to 51(ii) (2 questions)

[Sol. (i) (C)
(ii) (B)
LiH + AlCl3 ¾® LiAlH4
(A) (B)
3Li AlH4 + 4BCl3 ¾® 2B2H6 + 3AlCl3 + 3LiCl
(B) (D)
LiAlH4 + 2BeCl2 ¾® Be2H4 + LiCl + AlCl3
(B) (C)
2AlCl3 + 3H2SO4 ¾® 6HCl + Al2(SO4)3
conc. (E)
4HCl + MnO2 ¾® Cl2 + MnCl2 + 2H2O
LiAlH4 + 4H2O ¾® LiOH + Al(OH)3 + 4H2­

(3C-)bonds (3C-)bonds ]

Question No. 52 to 55 (4 questions)

[Sol. 2MnO2 + 4KOH + O2 ¾® 2K2MnO4 + 2H2O

Black solid green
(A)
3 MnO -4 -+ 4H+ ¾® 2MnO -4 + MnO2 + 2H2O
(A) (B) (C)
purple

(i) 2KMnO4 + H2O + KI ¾® 2KOH + 2MnO2 + KIO3

(D)
(ii) 2KMnO4 + 8H2SO4 + 10FeSO4 ¾® 2MnSO4 + 5Fe2(SO4)3 + K2SO4 + 8H2O
(iii) 2KMnO4 + H2SO4 (conc) ¾cold
¾¾® Mn2O7 + K2SO4 + H2O
(E)
Mn2O7 ¾® 2MnO2 + 3O2
(E) (F) 2
6KMnO4 + 10FeC2O4 + 24H2SO4 ¾® 6MnSO4 + 5Fe2(SO4)3 + 20CO2 + 3K2SO4 + 24H2O
(yellow) ]
 ADVANCED LEVEL PROBLEMS

Question No. 56 to 59 (4 questions)

[Sol. 4K + 3SO2(g) ¾® K2SO3 + K2S2O3

(M) (A) (C) (B)

2KMnO4 + H2O + 3K2S2O3 ¾® 2KOH + 2MnO2 + 3K2SO4 + 3S¯

(B) Brown

K2SO3 + H2SO4 ¾® K2SO4 + SO2­ + H2O

(C) (A)
4K2SO3 ¾¾® K2S + 3K2SO4
D

(C) (E) (F)

K2S + H2SO4 ¾® K2SO4 + H2S­

Pb(NO3)2 + K2SO4 ¾® 2KNO3 + PbSO4¯
white

PbSO4¯ + 2(NH4)2C2O4 ¾® (NH4)2[Pb(C2O4)2] + (NH4)2SO4

soluble
4FeCl2 + SO2 + 4HCl ¾® 4FeCl3 + S¯ + 2H2O
4Na2S2O3 ¾>¾ ¾® Na2S5 + 3Na2SO4
220°C
¾ ]

Question No. 60 to 64 (5 questions)

[Sol. (i)-(v)(except (iv))] ppt. a® CH3CO2Ag insoluble in old condition

ppt. b® AgNO2 (NO2– does not give ring test in presence of NO3–)
ppt. c® [Ag(S2O3)2]3– & black ppt. is of Ag2S
ppt. d® Ag2SO3
ppt. e® 2HCOOAg ¾¾® D
2Ag¯ + HCOOH + CO2­
ppt. f® AgCl, soluble in NH3 due to formation of complex
compound but due to its less ionisation it does not respond to
chromyl chloride test.]
[Sol. (iv) S2O32– + NaCN —® NaSCN + SO32–
(M)
3NaSCN + FeCl3 —® Fe(SCN)3¯ + 3NaCl
Blood red
colouration ]
 ADVANCED LEVEL PROBLEMS

Question No. 65 to 68 (4 questions)

[Sol. Hg2(NO3)2 + 2NaCl —® Hg2Cl2¯ + 2NaNO3

(A) white ppt (B)
Hg2(NO3)2 + 2KI —® Hg2I2¯(green ppt.)
(A) (C)
Hg2I2 + 2KI —® K2[HgI4]2– + Hg
(C) excess (E) soluble complex
$!!Nesslers
!!#reagent
!!!!"

K2HgI4 + NH3 + KOH —®

Hg2(NO3)2 + Na2CrO4 —® Hg2CrO4

(A) Red ppt.
K2[HgI4] —® sp Hybridization
3

Question No. 69 to 71 (3 questions)

Q 70
[Sol.
]

Q. 71
[Sol. 4Na2S2O3·5H2O Na2S5 + 3Na2SO4
(M) (P) (Q)

Na2SO4 + Hg(NO3)2—® HgSO4 ¯ + 2Na+ + 2NO3–

(Q) (R)
yellow
Na2S2O3 + HgCl2 —® HgS2O3¯ + 2NaCl
(M) white
(N)
HgS2O3¯ + H2O ¾¾® HgS¯ + 2H+ + SO4– –
D

(N) (O)
Black
HgS2O3¯ + Na2S2O3 —® 2Na+ + [Hg(S2O3)2]2–
(N) (M) soluble
Na2S2O3 + 2HCl —® 2NaCl + SO2- + S¯ + H2O
white/yellow
Turbidity
S¯ + 2HNO3 —®H2SO4 + 2NO­
clear sol. ]
 ADVANCED LEVEL PROBLEMS

Question No. 72 to 74 ( 3 questions)

Q.74

[Sol. NH4NO3 + NaOH ¾® NH3­ + NaNO3 + H2O

(A) (B)
NH3+ 2K2[HgI4] + 3KOH ¾® HgO. Hg(NH2)I ¯ + 3H2O + 7KI
Brown ppt.
NH4NO3 ¾¾® N2O(g) + 2H2O
D

(C) ]

Question No. 75 to 78 (4 questions)

Q.75
[Sol. (B) Pb(NO3)2 + 2HCl ® PbCl2 ¯ + 2HNO3
white

Q.76
[Sol. (C) Pb(NO3)2 ® completely soluble in water]

Q.77
[Sol. (A) Na2CO3 + 2HCl ® 2NaCl + CO2 ­ + H2O
Acidic
character ]

Q.78
[Sol. (D) Pb(NO3)2 + CuSO4 ® Cu(NO3)2 + PbSO4 ¯
white ppt.

Question No. 79 to 81 ( 3 questions)

Q.79
[Sol. (B) CO2 has no reducing character as carbon is in its maximum oxidation state of +4]

Q.80
[Sol. (C) Ca(OH)2 + CO2 ¾® CaCO3 ¯ + H2O
CaCO3 ¯ H2O + CO2 ¾® Ca(HCO3)2 ]

Q.81
[Sol. (D) Boric Acid < Carbonic Acid < Acetic Acid
(Ka = 5.8 × 10–10) (Ka = 4.31 × 10–7) (Ka = 1.76 × 10–5)
Stronger acid can decompose salt of weak acid
 ADVANCED LEVEL PROBLEMS

Question No. 82 to 83 (2 questions)

[Sol. Fe2C2O4 FeO+ CO (g) + CO2 (g)

(A) (B) (C) (D)
(i) PdCl2 + CO + H2O ¾® Pd¯ + CO2 + 2HCl
(C) black
(ii) CO2 gas can be absorbed in either Na2CO3 or ethanolamine
Na2CO3 + CO2 + H2O 2NaHCO3
2HOCH2CH2NH2 + CO2 + H2O (HOCH2CH2NH3)2CO3 (Girbotol process)
ethanolamine
(iii) FeO + 2HCl ¾® FeCl2 + H2O
2FeCl2 + 2HgCl2 ¾® Hg2Cl2 ¯ + 2FeCl3
white
Hg 2 + Fe ¾® No reduction of Hg +2 + into Hg. ]
++ ++

Question No. 84 to 88 (5 questions)

[Sol. MnS + H2SO4 ¾® H2S (g) + MnSO4

(A) (dil.) (B) (C)
Pink/Buff colour colourless colourless
K2Cr2O7 + 4H2SO4 + 3H2S ¾® K2SO4 + Cr2(SO4)3 + 3S¯
(green) (Yellow)
(D)
S + O2 ¾® SO2
(E)
K2Cr2O7 + H2SO4 + 3SO2 ¾® K2SO4 + Cr2(SO4)3 + H2O
(green)
2H2S + SO2 ¾® 3S ¯ + 2H2O
(B) (E) (D)

Na2SO3 + S ¾® Na2S2O3
(F)
Hypo solution is used as an antichlor ie to remove excess of Cl2 from bleached articles.
Na2S2O3 + Cl2 + H2O ¾® Na2SO4 + S + 2HCl
2Mn++ + 5PbO2 + 4H+ ¾® 2MnO+-4 5Pb++ + 2H2O
violet red ]
 ADVANCED LEVEL PROBLEMS

Question No. 89 to 92 (4 questions)

[Sol. S8 + 12NaOH ¾® 2Na2S2O3 + 4Na2S + 6H2O

(A) (B) (C)
Na2S + 2HCl ¾® 2NaCl + H2S ­
(B) (D)
2Na2S2O3 + FeCl3 ¾® [Fe(S2O3)2]– + 3Cl– + 4Na+
Violet sol.
(E)
Na2S2O3 + 2HCl ¾® 2NaCl + SO2¯ + S­ + H2O
(A)
Na2S2O3 + CaCl2 ¾® No ppt as CaS2O3 is soluble
Na2S + CaCl2 ¾® No ppt
D
Na2S2O3 ¾ ¾¾® Na S + Na SO
above 220°C 2 5 2 4

(Chain structure) (Tetrahedral)

H2S reacts with sodiumnitroprusside only in alkali medium
Na2 [Fe(CN)5(NO)] + 2NaOH + H2S ­ ¾® Na4[Fe(CN)5 (NOS)] + 2H2O
purple
Na2S2O3 + [Ni(en)3] (NO3)2 ¾® [Ni(en)3]S2O3 ¯ + 2Na + 2NO3-
+

Violet
(optically active) ]
 ADVANCED LEVEL PROBLEMS

Question No. 93 to 95 (3 questions)

[Sol. CrCl3 + 3AgNO3 ¾® 3AgCl ¯ + Cr3+ +
(A) white
AgCl + 2NH3 l [Ag(NH3)2]+ + Cl–
white soluble

CrCl3 + 3NaOH ¾® Cr(OH)3¯ + 3Na+ + 3Cl–

(A) green
Cr(OH)3¯ + OH – l [Cr(OH)4]–
excess soluble

2Cr3+ + 3H2O2 + 10OH– ¾® 2CrO24- + 8H2O

(A) (B)
yellow solution
+2-
2H + ¾® Cr O 2- + H O
2CrO4 2 7 2
Orange solution
(C)
Cr2O72-+ 2NH4Cl ¾® (NH4)2 Cr2O7 + 2Cl–
(D)

(NH4)2Cr2O7 ¾¾®D Cr2O3 + N2 (g) + 4H2O(G)

(D) (H)
Residue
N2 + 6Li ¾® 2Li3N ¾H¾¾2O
® NH3 + 6LiOH
(G) (I) (J)

2-
[Cu(NH3)4]2+ + SO4
deep blue sol.

4KCl + K2Cr2O7 + 6H2SO4 ¾® 2CrO2Cl2 ­ + 6KHSO4 + 3H2O

solid conc. (E)
red vapours
CrO2Cl2­ + 2OH– ¾® CrO24-+ 2HCl
(B)
CrO4 + Pb ¾¾¾® PbCrO4¯
2- 2+ AcOH

Yellow
(F)
– HgCl2 does not give chromyl chloride test
– In case of Br–, Reddish brown/ Red vapours of Br2 are evolved on heating it with
K2Cr2O7 and conc. H2SO4 ]
 ADVANCED LEVEL PROBLEMS

Question No. 96 to 98 (3 questions)

[Sol. D
K2SO4.Cr2(SO4)3. 24H2O ¾¾® swell due to K 2SO 4 + Cr2O3 + SO3 ­
removal of water $!!!!#!!!! "
Amorphous powder
(A) (green)
(Lilac or violet flame)

Na+ . K+ , SO 24+- [Cr(OH)4]–

green (B)

CrO 24- (Yellow sol.)

Hyb : d3s, µeff = 0 ]

Question No. 99 to 101 (3 questions)

[Sol. D

Pb2+ + H2S ® PbS¯ + 2H+

Black
[Zn(OH)4]2– + 4CH3COOH ® Zn++ + 4CH3COO¯ + 4H2O
Zn++ + H2S ® ZnS¯ + 2H+ ]

Question No. 102 to 104 (3 Question)

Q. 102
[Sol. (A) NH4NO2 ¾¾®D N2 + 2H2O
D
(B) (NH4)2SO4 ¾¾® NH3 + H2SO4
D
(C) 2NH4ClO4 ¾¾® N2 + Cl2 + 2O2 + 4H2O
D
(D) (NH4)2Cr2O7 ¾¾®N2 + Cr2O3 + 4H2O ]
 ADVANCED LEVEL PROBLEMS

Q.103
D
[Sol. (A) 2Pb(NO3)2 ¾¾® 2PbO + 4NO2 + O2

(B) Hg(NO3)2 ¾¾®

D Hg + 2NO2 + O2

D
1
(C) KNO2 ¾¾® KNO2 + O2
2

(D) 2AgNO3 ¾¾®

D 2Ag + 2NO2 + O2 ]

Q.104
[Sol. NH4ClO4 + HNO3 (dil.) ¾® NH4NO3 + HClO4
(X)
NH4NO3 ¾heat
¾ N2O + 2H2O
¾®
(X) (Y) ]

Question No. 105 to 107 (3 Question)

Q.105
[Sol. SO2 Vapour may also be evolved from SO32– and S2O32– ion by decomposition with dil.
H2SO4 ]

Q.106
[Sol. Aq. suspension of Ag2CO3 Aq. suspension of Ag2SO3
Boil
+ H2O Boil

Ag2O ¯ + CO2­ 2Ag ¯ + H2SO4

(Brown) (Black) ]

Q.107
[Sol. SO32– + 3Zn + 8H+ ¾¾®
D H2S ­ + 3Zn2+ + 3H2O
D
HSO3¯ + 3Zn + 7H+ ¾¾® H2S ­ + 3Zn2+ + 3H2O
D
S2– + Zn + 2H+ ¾¾® H2S ­ + Zn ]
 ADVANCED LEVEL PROBLEMS

Question No. 108 to 110 (3 Question)

[Sol. (NH4)2Cr2O7 D
Cr2O3(s) + N2 ­ + H2O (g)
(A) (B) (C) (D)
Orange solid Green CoCl2
D Mg
D Conc. HCl
Mg3N2
CrCl3 (I) CoCl2.6H2O
(F) Pink
H2 O (E)
Green sol.

H2O2/OH¯ NH3­
2–
(J)
CrO4 NiCl2
(G) sol.
Yellow sol. 2+
+
[Ni(NH3)6]
Et2O H2O2/H
Deep blue
CrO5.OEt2 (K)
(H)
Blue
Ans.(i) (C) Mn2+ + NH3 + 2H2O ¾® Mn(OH)2 ¯ + 2NH4+

H2O2

MnO.(OH)2¯
or
MnO2
Brownish-block

3d 4s 4p 4d
Ans.(ii) (B) Ni2+ in [Ni (NH3)6 ]2 +
3 2
Hyb.:sp d
O µeff=2.8 B.M.
O O
Ans.(iii) (D) + 2H2O2 + 2H+ ¾® Cr + 3H2O
O O
deep blue
(unstable in the absence
of organic solvent)
O
O O 4Cr 3+
+ 12 H+ ¾® Green + 7O2 ­ + 6H2O
Cr
O O
® CrO5 is stabilized in presence of ether, Amyl alcohol, amylacetate ]
 ADVANCED LEVEL PROBLEMS

Question No. 111 to 113 (3 Question)

Q.111
[Sol. (NH4)2SO4 , Na2S and KBr are water soluble while AgCl is insoluble in water, hence for
AgCl sodium carbonate extract is formed. ]

Q.112

[Sol. BaS2O3 + Na2CO3 ¾Aq ¾.® BaCO3 ¯ + Na2S2O3

¾.Med
¾
D

Aq.Med .
PbSO4 + Na2CO3 ¾¾D¾ ¾® PbCO ¯ + Na SO
3 2 4

CaCO3 + Na2CO3 ¾Aq ¾.® CaCO3 + Na2CO3 Þ i.e. No change ]

¾.Med
¾
D

Q.113
[Sol. Except NaHCO3 other sodium salts are water soluble.
Na2SO4 is not used, as sulphates of most basic radicals are water soluble.
K2CO3 is not used because some acidic radicals like ClO4¯, H4C4O62– form insoluble ppt.
with K+, also fusion temperature of K2CO3 is higher than that of Na2CO3
Hg2Cl2 + Na2CO3 ¾¾® D
2NaCl + + CO2­ ]

Question No. 114 to 116 (3 Question)

Q.114
[Sol. CaO ¾H¾ 2O
¾ ® Ca(OH)2 ¾Cl¾is¾ ¾¾® Ca(OCl)Cl + H2O
2 passed
(A) (B)
NH3 + Ca(OCl)Cl ¾® N2 + CaCl2 + H2O
PH3 + Ca(OCl)Cl ¾® PCl3 + Ca(OH)2 + HCl
(Reactions are unbalanced) ]

Q.115 +1 -1
[Sol. Ca (O Cl) Cl ]

Q.116
[Sol. CO2 or SO2 or CO2 + SO2 can turn lime water milky. ]
 ADVANCED LEVEL PROBLEMS

Question No. 117 to 119 (3 Question)

Q.117
[Sol. A : Na2S2O3 . 5H2O . [! observation (iii) is unique for S2O32– ion]
Na2S2O3 . 5H2O ¾¾®D Na2S2O3 + 5H2O ­ ¾¾®
D Na2S5 + Na2SO4
(B) (C)
Na2SO4 solution + Hg2+ ¾® HgSO4 . 2HgO ¯ + H+
yellow ppt.
SO4 + 3Hg + 2H2O ¾® HgSO4. 2HgO + 4H+ ]
2– 2+

Q.118 S S S
[Sol. Na2S5 : structure of S52– : S S ]

Q.119
[Sol. The water of crystallisation in 'A' is 5.

Question No. 120 to 122 (3 Question)

[Sol.
S2–, SO32–
(A) mixture of two salt
dil HCl

SO2­ + H2S­
(B) (C)

MnO4–/H+ CrO72–/H+

SO42– conc. S
(E) HNO3 (D)
]
HgCl2

HgSO4 · 2HgO¯
(F) yellow
 ADVANCED LEVEL PROBLEMS

Question No. 123 to 125 (3 Question)

[Sol.
Conc.
PbS H2S + PbCl2
(A) HCl (C)
(B)
D Air dil H4SO4
PbSO4 (White ppt)
K2Cr2O7 3+
PbO + SO2 Cr
(D) (E) dil H2SO4 (Green sol.)

NaOH
2– AcOH/
[Pb(OH)4] PbCrO4
K2Cr2O7 (G) (Yellow ppt)
(F)

Excess of NaOH

Question No. 126 to 128 (Question)

D H2O
[Sol. ® CuSO4(Aq.) CuSO4 +
Light Blue White powder condensate
(B) (A)
colourless

® On adding H2O to KI sol. it is simply dilluted without any colour change.

Cu2I2
® 2CuSO4 + Excess
5KI + KI3 + 2K2SO4
(White) Brown colourless
sol.
 ADVANCED LEVEL PROBLEMS

Question No. 129 to 131 (Question)

[Sol. For test tube "a"
® If it contains Cd2+ then

Cd2+ ¾¾¾3 ® Cd (OH) 2 ¯

NH
Solution ( W)

¯Excess of NH 3 solution

[Cd(NH3)4]2+
colourless solution
® If it contains Zn2+ then
NH Excess
Zn2+ ¾¾¾3 ® Zn(OH)2 of¾¾¾® [Zn(NH3)4]2+ (colourless solution)
NH solution
Solution 3

For test tube "b"

Zn2+ ¾NH ¾¾3 ® Zn(OH)2¯ ¾D

¾® ZnO
solution
(white) (White : cold)
(Yellow : Hot)
For test tube "c"
If it contains Hg2+ then
Hg2+
NH3 solution Excess
HgO.Hg(NH2)NO3¯ NH Insoluble
3
solution
Hypo D
HgS2O3¯ HgS¯
Excess of (Black)
Hypo
2–
[Hg(S2O3)2]
Soluble
If this test contains Pb2+ then
2+ NH3
Pb Pb(OH)2¯
Solution
(W)
Hypo
D
PbS2O3¯ PbS¯
(W) (Black)
Excess of
Hypo
2– ]
[Pb(S2O3)2]
 ADVANCED LEVEL PROBLEMS

Question No. 132 to 134 (3 Question)

Q.132
D Initially ¾¾On ¾
¾® Amorphous power ]
[Sol. (NH4)2SO4 . Fe2 (SO 4 )3 . 24H2O ¾ ¾®
¾
- 24 H O 2 swelled
Strong heating
( A)

Q.133
[Sol.
+3 + NaOH
Fe , NH4 NH3(g) + Fe(OH)3
(B) (C) ]
KSCN

Fe(SCN)3
Blood red
colouration

Q.134
[Sol. NH (g) MnSO4 + H2O2
3 MnO2 (D)
Solution Brownish Black ppt

Question No. 135 to 137 (3 Question

Q.135
[Sol. Na2B4O7·10H2O ]

Q.136
[Sol. Na2B4O7 + 5H2O ® 2H3BO3 + 2Na [B(OH)4]

Question No. 138 to 140 (3 Question)

Q.138
[Sol. (A) (NH4)2CO3 ¾¾®
D NH3 + H2O + CO2
(B) (NH4)2SO4 ¾¾®
D NH3 + H2SO4
(C) NH4ClO4 ¾¾®D N2 + Cl2 + H2O
(D) (NH4)3PO4 ¾¾®
D NH3 + P2O5 + H2O ]
 ADVANCED LEVEL PROBLEMS

Q.139 D
[Sol. (A) FeCl3.6H2O ¾¾® Fe2O3 + 6HCl + 9H2O
140°C
(B) CoCl2.6H2O ¾¾¾® CoCl2 (blue)
- 6 H 2O

(C) AlCl3.6H2O ¾¾®

D Al2O3 + 6HCl + 9H2O

D
(D) MgCl2.6H2O ¾¾® MgO + 2HCl + 5H2O ]

Q.140
[Sol. Na3PO4 ¾¾®
D No reaction ]

Question No. 141 to 143 (3 Question

Q.141
[Sol. Gas 'H' is CO2 ® Linear]

Q.142 sp2
[Sol. Ca2+ N
O O¯
O
2

Q.143
[Sol. [Ni(CO)4] = 28 + 4 × 2 = 36 ]

Question No. 144 to 146 (3 Question)

Q.144
[Sol. D CuSO4
(NH4)2 Cr2O7 N2 + Cr2O3 + H2O CuSO4.5H2O
(B) (C) (G)
Mg/D NaOH + H2O2

H2O BaCl2
NH3 Mg3N2 Na2CrO4 BaCrO4
(E) (C) yellow (F)
O3 solution

H2
N2 NH
(B) high T/P (E) 3

Sol. 2NH3 + 3Cl2 ¾¾® N2 + 6 HCl

gas (E) gas (B) ]
 ADVANCED LEVEL PROBLEMS

Q.145
Sol. (NH4)2 Cr2O7 ¾¾® compound (A)

sp3 d3s ]

Q.146
[Sol. (G) is CuSO4.5H2O
H
H2O O O O
H
H
Cu O S
H
H2O O H O O
H
]
second
one way way third
from less way

Question No. 147 to 149 (3 Question)

[Sol. PbSO4 (White ppt.)

dil.H SO4
(A) (B) 2

conc.HCl Soluble
PbS H2S + PbCl2 hot water
Black (C)
Mineral (CH3COO)2Pb

Heat/air
K2Cr2O 7 solution 3+
(D) PbO + SO2 ­ Green solution (Cr )
Pungent gas (E)
NaOH

(F) Na2PbO2 CH COOH / K2CrO4 PbCrO4 (Yellow ppt.)

3

(G)
NaOH
]
 ADVANCED LEVEL PROBLEMS

Question No. 153 to 165 (3 Question)

[Sol. Gas colourless (A)= H2S

+
KMnO4 + H
(B) = S

2–
(X) = SO3

2–
(Y)=S2O3
Zn+HCl
(i) X (A)

A
Cl 3

gN
Fe

O3
(ii) [B + X® Y] Violet/Purple White ppt. (E) = Ag2S2O3
(C)= [Fe(S2O3)2]¯
3+
Exposure/D
Fe
Black (F)= Ag2S + H2SO4
2+ 2–
(D)= Fe + S4O6
Green
H2 S + Na2 [Fe(CN)5NO] ¾® No reaction colourless solution
H2S + OH¯ ¾® S2– ; Na2S + Na2 [Fe(CN)5NO] ¾® Na4 [Fe(CN)5NOS] (Violet
colour) ]

Question No. 156 to 158 (3 Question)

[Sol. (i) NH4Cl + K2Cr 2O7 + conc. H2SO4

Salt solid

NaOH
CrO2Cl2
NaCl + NH3 + H2O (B)
(E) gas Orange red fumes
NaOH
HCl
Na2CrO4
NH4Cl (C)
White fumes yellow solution
(A)
(CH3COO)2Pb CH3COOH

PbCrO4
(D)
yellow ppt

O O
(ii)
Cr Cr
O Cl O — O—
Cl O
3
d s hybridisation
 ADVANCED LEVEL PROBLEMS

BaCl2 + CrO4–2 ® BaCrO 4

Yellow colour

(iii) NH4Cl + AgNO3 ® AgCl ¾NH ¾® [Ag(NH3)2]Cl ¾¾¾3 ® AgCl

+ H 2O
¾3¾ ¾
HNO
White ppt
Z = [Ag(NH3)2]+Cl–
C.N. = 2 , hybridisation = sp ]

Question No. 159 to 161 (3 Question)

[Sol.
D
(NH4)2Cr2O7 Cr2O3(s) + N2 ­ + H2O (g)
(A) (B) (C) (D)
Orange solid Green CoCl2
D Mg
D Conc. HCl
Mg3N2
CrCl3 (I) CoCl2.6H2O
(F) Pink
H2 O (E)
NH3­
(J)
NiCl2
sol.
2+
[Ni(NH3)6]
Deep blue
(K)
Sol.(i) (NH4)2 Cr2O7
Cationic ® NH4+® sp3
Anionic ® Cr2O7–2 ® d3s
3d 4s 4p 4d
Sol.(ii) Ni2+ in [Ni (NH3)6]2+
3 2
Hyb.:sp d
µeff=2.8 B.M.

Sol.(iii) NH3 (J) ® Bond angle 107.5°

N2(C) ® Bond angle not defined
Difference of Bond angle between (J) and (C) is 107.5° ]
 ADVANCED LEVEL PROBLEMS

Question No. 162 to 164 (3 Question)

Q .162
D
[Sol. Na(NH4)H2PO4.4H2O ¾¾® Na(NH4)H2PO4 + 4H2O
(A) A'

A' D

NaPO3 + NH3 + H2O

Q.163
[Sol. (A) Mg3N2 + 6H2O ¾¾ ¾® 2NH + 3Mg(OH)
3 2
(B) 4Zn + 7NaOH + NaNO3 ¾¾D¾® 4Na2ZnO2 + NH3 + 2H2O
(C) (NH4)2CO3 ¾¾D¾® 2NH3 + CO2 + H2O]

Question No. 165 to 167 (3 Question)

Sol. Na2C2O4 H2C2O4 + Na2SO4

(W) Oxalic acid
K2Cr2O7 + 3H2SO4 + 3H2C2O4 ¾® K2SO4 + Cr2(SO4)3 + 6CO2 ­ + 6H2O
(X)
Ca(OH)2 + CO2 ¾® CaCO3 + H2O
milky
CaCO3 + H2O + CO2 ¾® Ca(HCO3)2
excess colourless
CO2 + Acidified ¾® No colour change
KMnO4
III
2MnO(OH)2 + 7C2O42– + 8H+ ¾® 2[Mn (C2O4 )3 ]3- + 2CO2 ­ + 6H2O
red (Y)

Question No. 168 to 171 (3 Question)

Q.168
[Sol. NH4NO3 N 2 O + H2 O
(A) (Y) (Z)
NH4NO2 ¾¾®D N2 + H2 O
(A') (Z)
4Zn + 7NaOH + NaNO3 ® 4Na2ZnO2 + NH3 + 2H2O
3Zn + 5NaOH + NaNO2 ¾¾®D 3Na2ZnO2 + NH3 + H2O]
 ADVANCED LEVEL PROBLEMS

Q.169
[Sol. (B) Due to synergic bonding.
(C) RuII belongs to 4d - series and hence pairing of electrons takes place.]

Q.170
[Sol. N º N + - O- > N º N (B.O or N–O in N2O is less than that inN2) ]

Question No. 171 to 173 (3 Question)

[Sol.(i) (NH4)2 SO4.Fe(SO4)3 . 24H2O ® Salt A

FeSO4.(NH4)2SO4.6H2O ® Salt B
Salt (A) Fe + K4 [Fe(CN)6] ® Prussian blue ppt.
+3

Oxidation

Salt (B) Fe2+ + K3[Fe(CN)6]

Turnbulls blue ppt
(ii) K4[Fe(CN)6] + conc. H2SO4

K2SO4 + FeSO4 + (NH4)2SO4 + CO

(iii) FeSO4 . (NH4)2 SO4.6H2O ¾¾®
D Fe2O3 ¯ + NH3 + SO2 + SO3 + H2O
red brown ]

Question No. 174 to 176 (3 Question)

Q. 174

[Sol. MnSO4 + BaCl2 BaSO4 + MnCl2

Na2MnO4 + HCl ® NaMnO4(Z)

Green (Y)
+6
Y = Na 2MnO 4

= d1 (paramagnetic with 1 unpaired electron) ]

Q.175
[Sol. O O

Mn Mn
O O
—
O— O O O—
 ADVANCED LEVEL PROBLEMS

Question No. 177 to 179 (3 Question)

CaCO 3 (!
B) Na 2 B4 O 7 (C) + NaBO 2 (D)
[Sol. Ca2B6O11 (A) + Na2CO3(aq) ® + $ !!!!#!!!!"
white ppt . so lub le

NaBO2 (D) + CO2 ® Na2B4O7(C) + Na2CO3

CoO·B2O3 (Blue bead) ¬¾¾¾ B2O3(E)

CoO + NaBO2(D) ]

Question No. 180 to 182 (3 Question)

[Sol. NH4NO3 (A) + NaOH ® NH3(B) + H2O + NaNO3 (C)

N2O + H2O O
(D)
P
N2O + P4 ® P4O10 + N2
O O
Covalency of phosphorous is 5.
N2O ® Oxidation state of N is +1 O P O P O
O
NaNO3 + Zn + 2NaOH ® Na2ZnO2 + H2
O O
NaNO3 on reduction gives NH3 gas(B)]
P
O

Question No. 183 to 184 (3 Question)

Q.183
D
[Sol. NH4Cl + K2Cr2O7 + conc. H2SO4 CrO2Cl2
(X) (A)

+NaOH D NaOH

Pb(OAc)2
NH3 PbCrO4 Na2CrO4
(D) (C) (B)
Hybridisation orbital which are participate in hybridisation
Pb2+ CrO4 2– d3s dxy + dyz + dzx + s ]
 ADVANCED LEVEL PROBLEMS

Q.184 O
[Sol. CrO2Cl2 : +6
Cr
O Cl
Cl
® 2 pp–dp bond
® d3s
® Tetrahedral
® Diamagnetic
® Coloured due to charge transfer

Question No. 185 to 187 (3 Question)

MnSO4 + Na2CO3 + KNO3

[Sol. (A)

Na2MnO4 + KNO2 + CO2

(B)
[O] NaOH
H+

(D) MnO2 Na2MnO4

+ PbO2 (C) Pink
+ HNO3

HMnO4
(E) Pink

(i) MnSO4 + BaCl2 ® BaSO4

Soln (White ppt)
+6
(ii) Na 2MnO 4 : 3d ,
1 Hybridisation : d3s
: Paramagnetic , Geometrical : Tetrahedral
(iii) HMnO4(E) ® H + + MnO4– (Bronsted acid) ]
 ADVANCED LEVEL PROBLEMS

Question No. 188 to 189 (2 Question)

Q .188
+3 –3
[Sol. B + air (N2) BN
(A)

D H2O(Steam)

B(OH)3 + NH3 LiH + NaNO3

(B) (C)

+C D
BCl3
+Cl2 B2O3
(E) (D)

LiAlH4
NH3(C)
B2H6 B3N3H6
(G) 200°C (H)
HCl

H B H+
:

:N N
Protonation occurs at 'N' H
H+ B B
:N H

H+ H

Q.189
[Sol. N2 + CaCl2 + H2O
NH3 + Ca(OCl2)
(C) (J)
Inert gas
Mg
Mg3N2
(White solid)

Question No. 190 to 192 (3 Question)

Sol. Na2C2O4 H2C2O4 + Na2SO4

(W) Oxalic acid
K2Cr2O7 + 3H2SO4 + 3H2C2O4 ¾® K2SO4 + Cr2(SO4)3 + 6CO2 ­ + 6H2O
(X)
 ADVANCED LEVEL PROBLEMS

Ca(OH)2 + CO2 ¾® CaCO3 + H2O

milky
CaCO3 + H2O + CO2 ¾® Ca(HCO3)2
excess colourless
CO2 + Acidified ¾® No colour change
KMnO4
III
2MnO(OH)2 + 7C2O42– + 8H+ ¾® 2[Mn (C2O4 )3 ]3- + 2CO2 ­ + 6H2O
red (Y)

Question No. 193 to 95 (3 Question)

[Sol. CuSO4 BaSO4(white)

CuSO4 ¾excess
¾ ¾NH ¾3 ® [Cu(NH3)4]SO4 (deep blue)
¾

Cu2+ + 2CN– ¾¾¾® Cu(CN)2 (yellow)

2Cu(CN)2 ¾¾¾® 2CuCN + (CN)2

CH2 NH2
(CN)2 ¾Pt
¾/ H¾2 ® H2N CH2

(en)

CoCl3 + 3en ¾¾¾

¾® [ Co(en)3]Cl3
(P) ]

Question No. 196 to 198 (3 Question)

Q.196
Sol. A ® Mn+2 B ® Zn+2 C ® Ni+2 D ® Co+2

Q.197
Sol. [Zn(NH3)4]2+ ¾® sp3 hybridisation of Zn+2

Q.198 NH 4OH
Sol. Ni+2 ¾¾ ¾¾® Ni(OH)2 ¯ green ppt
Ni(OH)2 ¾NH ¾4¾¾® [Ni(NH3)6] deep blue colour
OH +2

Ni2+ + 2H2 dmg ¾® [Ni(dmg)2] + 2H+

Rosy red
 ADVANCED LEVEL PROBLEMS

Question No. 199 to 200 (2 Question)

Sol. Cu2+ + 2NaOH ¾® Cu(OH)2¯ + 2Na+

(P)
Cu2+ + 2NH4OH ¾® Cu(OH)2 ¯ + 2NH4+
Cu(OH)2 + 2NH4OH + 2NH4+ ¾® [Cu(NH3)4]2+ + 4H2O
deep blue (Q)
Ni2+ + 2NaOH ¾® Ni(OH)2¯ + 2Na+
green
Ni2+ + 2NH4OH ¾® 4NH4OH ¾® [Ni(NH3)6]2+ + 6H2O
(excess) deep blue(R)
Cu ¾¾¾® CuS ¯
2+ Na 2S

(Black)
Ni ¾¾¾® NiS ¯
2+ Na 2S

(Black)
Cu ¾¾¾® X
2+ DMG

Ni2+ + 2dmgH ¾Slightly

¾¾ ¾® [Ni(dmg)2] + 2H+
basic
Rosy red ppt.

Question No. 204 to 205 (2 Question)

+
Sol. A ¾H¾/¾ ¾® B (Yellow ppt.)
H2S

Only CdS & As2S3 are yellow

CdS insoluble in Yellow Ammonium Sulphide
As2S3 soluble in Yellow Ammonium Sulphide

So B is CdS
A ¾BaCl
¾¾2 ® C (White ppt.)
BaSO4 are white ppt.
BaSO4 insoluble in mineral acids
BaSO3 soluble in mineral acids

So C is BaSO4
\ A is CdSO4
¾¾3 ® Cd (aq.) + S ¯ + NO3 (aq)
CdS [B] ¾HNO 2+ 1–

$!!!#!!!"
D

Cd2+ (aq) ¾KCN¾¾® K2Cd(CN)4

( excess )
[D]
 ADVANCED LEVEL PROBLEMS

Question No. 209 to 210 (2 Question)

Q.210
[Sol. HCOONa D Na2C2O4 + H2
(A) (B) + 'C'

dil HCl D

Na2CO3
'X' CO + CO2 + (D) + Carbon
SO2
Na2SO3
(E) + CO2
Na2S2O3 'S'
(F)
AgNO3
BiCl3
Exp. Ag2S2O3
Ag2S (I) Bi2(S2O3)3
(J) Black White ppt. (G)
White ppt.
(excess) Na2S2O3
(excess) Na2S2O3
Na3[Ag(S2C3)2]
(K) Na3[Bi(S2C3)3]
Soluble complex (H)
Transparent
D
complex

(J)
Black

Question No. 213 to 214 (2 Question)

Q.213
Sol. 2+ excess NaOH Soluble complex
Sn Solution +NaOH Sn(OH)2¯ solution 2–
solution
(A) white ppt.(B) [Sn(OH)4] (C)

3+
Bi Solution +NaOH Bi(OH)3¯ excess NaOH
solution Insoluble
solution
(D) white ppt.(E)
3+ +2 +4
Bi (OH)3 + [Sn (OH ) 4 ]2-¾® Bi¯ + [Sn(OH)6 ]2-
(F) (G)

Q.119
Sol. Bi(OH)3 + H2O2 ¾® (H)
 ADVANCED LEVEL PROBLEMS

Question No. 215 to 217 (3 Question)

[Sol. (I) ¯ (X)

(i ) acidified
(II) MnO·(OH)2(X) ¾¾¾¾
¾® [Mn(C2O4)3]3– (Z)
(ii) Na 2C2O4

(i) [Mn(C2O4)3]3– exhibits optical isomerism

(ii) Compound(X) have Ox.No. 4 and (Z) have Ox. No. 3. The difference between = 1 ]

Paragraph for question nos. 218 to 220

Sol. Aqueous suspension
[Ag(S2O3)2] excess Ag S + SO
–3 on heating AgNO3
Ag2S2O3 Na2S2O3.5H2O
soluble Na2S2O3 T
2 3
D S R
U Z 5H2O
Q

S8 + NaOH Disproporticnation Na2S (Y) + Na2S2O3(Z)

X (alk.solution)

Na2[Fe(CN)5NO]
Zn+2
A
Zn(OH)2
excess A
NaOH
Na4[Fe(CN)5NOS]
Na2[Zn(OH)4] purple colour P
B

Na2S
ZnS
Y
C

Å
N2 Cl Paragraph for question nos. 221 & 222

Sol. + OH¯ + NH4Å ¾® O2N N = N – ONH4 + HCl

NO2

Unknown salt (NH4)2CO3

X = NH3
Y = CO2
Z = H2 O
 ADVANCED LEVEL PROBLEMS

Paragraph for question nos. 223 & 224

Q.223 H2O AgNO3

NH3 D AgCl NaCN [Ag(CN)2]
SOL. NH4OH NH4Cl solution
[Y] [X]
pH < 7

Q.224
pK 1
Sol. pH = 7 – b - log C
2 2
4.74 1
=7– - log 10 - 2 = 5.63 Ans
2 2