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Process Analytical Instruments

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0% found this document useful (0 votes)
202 views

Process Analytical Instruments

Uploaded by

Miguel
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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© Siemens AG 2014

Process Analytical Instruments


Process Automation

Catalog Edition
PA 01 2015
© Siemens AG 2014

Related catalogs
Process Automation FI 01
Field Instruments for
Process Automation

PDF (E86060-K6201-A101-B7-7600)

Process Automation PA 11
Components for system integration

PDF/e-book (E86060-K3511-A100-B2-7600)

Industrial Communication IK PI
SIMATIC NET

E86060-K6710-A101-B8-7600

SITRAIN ITC
Training for Industry

Only available in German

E86060-K6850-A101-C4

Products for Automation and Drives CA 01


Interactive Catalog, DVD

E86060-D4001-A510-D4-7600

Industry Mall
Information and Ordering Platform
in the Internet:

www.siemens.com/industrymall
© Siemens AG 2014

Process Analytical Instruments


Process Automation
Continuous Gas Analyzers, extractive
1

Continuous Gas Analyzers, in-situ


2

Process Gas Chromatographs


3
Catalog PA 01 · 2015

Supersedes:
Catalog PA 01 · 2014

Refer to the Industry Mall for current updates of Analytical Application Sets
4
this catalog:
www.siemens.com/industrymall
and as PDF at the following address:
www.siemens.com/pa01

For comfortable, fast and error free product selection you


will get support in our PIA Life Cycle Portal:
www.siemens.com/pia-portal General information
5
The products contained in this catalog can also be found
in the Interactive Catalog CA 01.
Article No.: E86060-D4001-A510-D4-7600 (DVD)

Please contact your local Siemens branch.

© Siemens AG 2014
Appendix
6

The products and systems described in


this catalog are manufactured/distributed
under application of a certified quality
management system in accordance with
DIN EN ISO 9001.
© Siemens AG 2014

2 Siemens PA 01 · 2015
© Siemens AG 2014

Answers for industry.


Integrated technologies, vertical market expertise and services

for greater productivity, energy efficiency, and flexibility.

The Siemens Industry Sector is the We consistently rely on integrated tech- Market launch times can be reduced
world's leading supplier of innovative nologies and, thanks to our bundled by up to 50% due to the combination
and environmentally friendly products portfolio, we can respond more quickly of powerful automation technology
and solutions for industrial companies. and flexibly to our customers' wishes. and industrial software from Siemens
End-to-end automation technology and With our globally unmatched range of Industry. At the same time, the costs for
industrial software, solid market exper- automation technology, industrial energy or waste water for a manufac-
tise, and technology-based services are control and drive technology as well turing company can be reduced signifi-
the levers we use to increase our cus- as industrial software, we equip compa- cantly. In this way, we increase our
tomers’ productivity, efficiency and nies with exactly what they need over customers’ competitive strength and
flexibility. With a global workforce of their entire value chain – from product make an important contribution to envi-
more than 100 000 employees, design and development to production, ronmental protection with our energy-
the Industry Sector comprises the sales and service. Our industrial custom- efficient products and solutions.
Industry Automation, Drive Technolo- ers benefit from our comprehensive
gies, and Customer Services divisions, portfolio, which is tailored to their
as well as the Metals Technologies market and their needs.
Business Unit.

Siemens PA 01 · 2015 3
© Siemens AG 2014

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Efficient automation starts with


efficient engineering.
Totally Integrated Automation: Efficiency driving productivity.

Efficient engineering is the first step toward better production that is faster,

more flexible, and more intelligent. With all components interacting efficiently,

Totally Integrated Automation (TIA) delivers enormous time savings right from

the engineering phase. The result is lower costs, faster time-to-market, and

greater flexibility.

4 Siemens PA 01 · 2015
© Siemens AG 2014

A unique complete approach for all industries

As one of the world's leading automation suppliers,


Siemens provides an integrated, comprehensive portfolio
for all requirements in process and manufacturing industries.
All components are mutually compatible and system-tested.
This ensures that they reliably perform their tasks in industrial
use and interact efficiently, and that each automation solu-
tion can be implemented with little time and effort based
on standard products. The integration of many separate indi-
Totally Integrated Automation
vidual engineering tasks into a single engineering environ-
Efficient interoperability of all automation components ment, for example, provides enormous time and cost savings.

With its comprehensive technology and industry-specific


expertise, Siemens is continuously driving progress in manu-
facturing industries – and Totally Integrated Automation plays
a key role.

Totally Integrated Automation creates real value added in


all automation tasks, especially for:

• Integrated engineering
Consistent, comprehensive engineering throughout the
entire product development and production process
• Industrial data management
Access to all important data occurring in productive
operation – along the entire value chain and across
all levels
352),1(7 • Industrial communication
,QGXVWULDO(WKHUQHW
Integrated communication based on international
352),%86
cross-vendor standards that are mutually compatible
$6,QWHUIDFH
• Industrial security
.1;*$00$LQVWDEXV
Systematic minimization of the risk of an internal or
7RWDOO\ external attack on plants and networks
,QWHJUDWHG
3RZHU • Safety Integrated
Reliable protection of personnel, machinery, and the
environment thanks to seamless integration of safety
technologies into the standard automation

Making things right with Totally Integrated Automation

Totally Integrated Automation, industrial automation from


Siemens, stands for the efficient interoperability of all auto-
mation components. The open system architecture covers
the entire production process and is based on end-to-end
shared characteristics: consistent data management, global
standards, and uniform hardware and software interfaces.

Totally Integrated Automation lays the foundation for


comprehensive optimization of the production process:
• Time and cost savings due to efficient engineering
• Minimized downtime due to integrated diagnostic
functions
• Simplified implementation of automation solutions due
to global standards
• Better performance due to interoperability of system-
tested components

Siemens PA 01 · 2015 5
© Siemens AG 2014

Totally Integrated Power


We bring power to the point –
safely and reliably.
Efficient, reliable, safe: These are the demands placed on electrification and especially
power distribution. And our answer – for all application areas of the energy system –
is Totally Integrated Power (TIP). It’s based on our comprehensive range of products,
systems, and solutions for low and medium voltage, rounded out by our support
throughout the entire lifecycle – from planning with our own software tools to installation,
operation, and services.

Smart interfaces allow linking to industrial or building automation, making it possible to fully
exploit all the optimization potential of an integrated solution. This is how we provide our
customers around the world with answers to their challenges. With highly efficient, reliable,
and safe power distribution, we lay the foundation for sustainable infrastructure and cities,
Comprehensive answers for
power distribution in complex buildings, and industrial plants. We bring power to the point – wherever and whenever it is
energy systems – from Siemens needed.

More information: www.siemens.com/tip

6 Siemens PA 01 · 2015
© Siemens AG 2014

Totally Integrated Power offers more:


• Consistency:
For simplified plant engineering and commissioning as well as smooth integration into automation solutions
for building or production processes
• One-stop-shop:
A reliable partner with a complete portfolio for the entire process and lifecycle – from the initial idea
to after-sales service
• Safety:
A comprehensive range of protection components for personnel safety and line and fire protection,
safety by means of type testing
• Reliability:
A reliable partner who works with customers to develop long-lasting solutions that meet the highest
quality standards
• Efficiency:
Bringing power to the point means greater plant availability and maximum energy efficiency in
power distribution
• Flexibility:
End-to-end consistency and modular design of Totally Integrated Power for any desired expansions and
adaptation to future requirements
• Advanced technology:
Reliable power distribution especially for applications in which supply is critical, continuous refinement of
the technology

Challenges are our speciality


Automation

Operation Load Load Forecast Mainte- Status Protocols Power Cost


Process/ & manage- curves nance reporting/ Quality center
Industrial Monitoring ment failure man- Building
automation agement automation

PROFINET PROFIBUS ... Industrial Ethernet Modbus

Electrification

Renewables

Storage Medium-voltage switchgear Transformer Low-voltage switchboard Low-voltage


technologies and protection technology with protection and measuring distribution
technology

≤ 110 kV

Products, systems and solutions

Consulting, Engineering Order, Installation, Operation Service,


planning delivery commissioning modernization

Siemens PA 01 · 2015 7
© Siemens AG 2014

Industries
In the field of process instrumentation, process analytics and weighing technology, Siemens focuses on a

number of key industries such as:

◼ Chemical

◼ Pharmaceutical

◼ Water/wastewater

◼ Mining, aggregates, cement

◼ Oil and gas/hydrocarbon processing

◼ Pulp and paper

◼ Food and beverage

◼ Marine

8 Siemens PA 01 · 2015
© Siemens AG 2014

Process Analytics
Siemens is a leading provider of process gas analyzers and analysis systems. We provide our global users the best

solutions for their applications based on innovative analysis technologies, customized system engineering, sound

knowledge of process applications and strong professional support. And with Totally Integrated Automation,

Siemens Process Analytics is your qualified partner for efficient solutions that seamlessly integrates process gas

analyzers into automation systems in the process industry.

Siemens PA 01 · 2015 9
© Siemens AG 2014

Continuous Gas Analytics

From emission monitoring in waste incinerators and power plants, gas analysis in the chemical
industry and rotary kiln monitoring in cement plants, the extremely accurate and reliable Siemens
gas analyzers are the perfect solution for the job.

SITRANS SL
Continuous gas analyzer with
benchmark-setting in-situ analysis
technology for process control
even under extreme measurement
conditions.

10 Siemens PA 01 · 2015
© Siemens AG 2014

[1] [2] [3]

The technology used in process gas analyzers is deter- The ULTRAMAT 23 is also available with a build-in H2S-
mined by the requirements of the specific application. The sensor for biogas applications.
analyzers must be cost-effective, functional, space- and
energy-saving, and must provide just the right amount of SERIES 6
power to meet all needs. The Series 6 gas analyzers are a family of gas analyzers
that meet a complete range of measurement require-
Siemens Process Analytics offers a comprehensive analyti-
ments:
cal portfolio to meet all user requirements for complete
measurement solutions. ◼ CALOMAT 6 [2] [3]
We combine proven expertise in developing high-perfor- is available in both 19” rack mount and field mount
mance analytical devices with in-depth application knowl- designs and uses the thermal conductivity measurement
edge from many process industry applications. principle to accurately measure the composition and
concentration of process gases. It is primarily designed for
The analyzers operate using a menu structure and comply
the measurement of hydrogen concentrations in inert gas
with the NAMUR recommendations. The analyzers can
such as blast furnace gases and carbon dioxide mixtures.
be easily integrated into the SIMATIC automation Totally
Integrated Automation (TIA) concept and are programmed ◼ CALOMAT 62 [2] [3]
using SIMATIC PDM software and PROFIBUS DP / PA uses the thermal conductivity detection (TCD) principle
interfaces. and is specially designed for use in applications with
For service and maintenance tasks with our extractive corrosive gases such as chlorine. The CALOMAT 62
process gas analyzers is the SIPROM GA software tool suit- measures the concentration of gas components such as
able. Integration into the Ethernet permits remote servic- H2, Cl2, HCl or NH3 in binary or quasi-binary gas mixtures.
ing and diagnostics over long distances.
◼ FIDAMAT 6 [3]
PROCESS GAS ANALYSIS – EXTRACTIVE measures the total hydrocarbon content in air or even in
◼ ULTRAMAT 23 [1] high-boiling gas mixtures. It is the ideal solution for nearly
all measurement requirements, from emission monitoring
is an innovative multicomponent analyzer for the as well as trace measurements of hydrocarbons in pure
measurement of up to 3 infrared sensitive gases using the gas analysis and total measurement of high hydrocarbon
NDIR principle as well as measuring oxygen (O2) using an concentrations, even in the presence of corrosive gases.
electrochemical or paramagnetic oxygen measuring cell.
The ULTRAMAT 23 is suitable for a wide range of stand-
ard applications, such as emission monitoring, furnace
optimization, room air monitoring and other applications.
Calibration using ambient air eliminates the need for ex-
pensive calibration gases.

Siemens PA 01 · 2015 11
© Siemens AG 2014

Continuous Gas Analytics

[1] [2] [3]

◼ OXYMAT 6 [1] [2] ◼ Ex-proof designs [2]


is an oxygen analyzer available in either a 19” rack mount are possible with an additional purge monitoring unit
or in a robust field housing for installation in harsh for the CALOMAT 6, OXYMAT 6 and ULTRAMAT 6 gas
environments. The OXYMAT 6 can be used for emission analyzers using the field housing for installation in
measurements in production process control and quality hazardous areas. Measurements can include both non-
assurance. Due to its ultrafast response, the OXYMAT 6 is flammable and flammable gases.
perfect for safety-related measurements.
◼ SIPROCESS UV600 [3]
◼ OXYMAT 61 [1] is an extractive UV gas analyzer for simultaneous
is a low-cost oxygen analyzer for standard applications. It measurement of up to 3 components. It is especially
can use ambient air as a reference gas that is supplied to suitable to measuring very low concentrations of NO,
the analyzer section by the internal pump. NO2, SO2 or H2S. Simultaneous measurement of NO and
NO2 offers total NOx determination without the need for
◼ OXYMAT 64 [1]
additional devices like NO2 converters or CLD analyzers.
is a gas analyzer for the measurement of extremely
low oxygen concentrations. Air separation plants and SIPROCESS GA700
production of technical gases – are just a few examples is the latest generation of Siemens gas analyzers.
where the OXYMAT 64 reliably detects traces of oxygen. A complete analyzer comprises a base unit and up to two
analyzer modules. The base units are available either as
◼ ULTRAMAT 6 [1] [2]
19” rack mount with three height units or in a housing
is an analyzer available in both 19” rack mount or field for wall mounting. The communication interfaces present
housing. Measurement of up to four infrared active in the base units can be adapted to the respective
components is possible in a single unit. It can be used process environment or the process control system using
in all applications from emission monitoring to process optionally available interface cards.
control, even in the presence of highly corrosive gases.
◼ OXYMAT 7 [4]
◼ ULTRAMAT/OXYMAT 6 [1]
The OXYMAT 7 module is used to measure oxygen be-
can be combined in a 19” rack to form multi-component tween 0 to 0.5% (smallest measuring range) and 0 to
devices with ULTRAMAT 6 and OXYMAT 6 benches. This 100% (largest measuring range). It is designed for use at
provides, in the smallest possible footprint, an infrared ambient temperatures up to 50°C and allows highly pre-
channel for the measurement of up to two IR components cise measurements through application of the paramag-
and a channel for oxygen measurement. netic alternating pressure principle. Due to the modular
design, the OXYMAT 7 module can be combined with a
further analyzer module in the same housing.

12 Siemens PA 01 · 2015
© Siemens AG 2014

[4] [5] [6]

PROCESS GAS ANALYSIS – IN-SITU (TDLS) Analyzer System Manager (ASM)


◼ LDS 6 [5] is a PC-based HMI system for monitoring, testing and ad-
ministration of gas analyzers in subsystems or in an entire
brings together the compact and service-friendly design,
plant. Key performance information of the analyzers is
simple operation and network capability of the Series 6
collected over a variety of common communication inter-
analyzers with the well-known exceptional performance
faces and is saved in a central database. By means of the
of in-situ gas analysis by using tunable diode laser
PC’s user-friendly operator interface, it is possible to ac-
spectroscopy (TDLS) and fiber optics. It can measure
cess measured-value trends, device statuses and statistical
gases even under extreme conditions such as 1,200 °C
evaluations, among others, or to start test routines for
(2,192 °F) or very high dust concentration with precise
validation of the results. A comprehensive reporting mod-
and reliable results. The LDS 6, for example, measures
ule is available to document the evaluations.
in-situ concentrations of O2, NH3, HCl, HF H2O, CO or CO2
The ASM is ideal for all analytical systems where high reli-
in flue gas before and after gas cleaning. Applications in
ability of the measured values and documentation of the
the chemical and petrochemical industries, for steel and
analyzer performances is required. Using the communica-
metal production, as well as in cement or paper plants are
tions network, remote analyzers can also be monitored
ideally suited for the LDS 6.
from a central workstation. The ASM is particularly suit-
◼ SITRANS SL [6] able for use in the oil and gas, petrochemical, and chemi-
combines the benefits of proven referencing technology cal industries, and can be applied in new plants or also in
with a direct operating mode as close as possible to existing plants to optimize the analyzer landscape.
the process. An integrated reference cell, filled with
a non-interfering gas allows laser locking completely
independent of process gas concentrations leading to
extremely stable operation, negligible drift values and
extended on-line availability. This patented feature
guarantees reliable measurement of gas concentration
even at values close to zero. SITRANS SL is housed with
a unique and compact design, including a local user
interface (LUI), making it the perfect solution for single
point measurement applications in rough environments.
SITRANS SL is used for process control in the chemical
industry, even in hazardous areas due to its Ex d design.
It is also suitable for installation in SIL applications. Other
applications include process optimization in the steel
industry and combustion control in boilers or waste incin-
erators.

Siemens PA 01 · 2015 13
© Siemens AG 2014

Process Gas Chromatography

Siemens application experience and innovative technology in the field of process gas
chromatography enables us provide the perfect measurement solutions for our customers. With our
analyzers, we solve a wide range of measurement challenges in almost any industry – combining
exceptional performance with the lowest cost-of-ownership.

SITRANS CV
Ultra compact gas chromatograph
for reliable, exact and fast analysis
of natural gas and biogas.

14 Siemens PA 01 · 2015
© Siemens AG 2014

[1] [2]

◼ MicroSAM [1] ◼ MAXUM edition II [2]


is a small flexible explosion-proof on-line process gas chro- is ideal for use in rough industrial environments
matograph made by Siemens. State-of-the-art silicon-based and performs a wide range of duties in the chemical and,
micromechanical components allow miniaturization as well petrochemical and refineries. A wide selection of columns
as increased performance at the same time. MicroSAM’s and detectors permits highly selective and sensitive analy-
ease of use and rugged small design that makes it ideal for sis of multiple process components.
mounting right at the sampling point. Its features include:
Benefits of MAXUM edition II include:
◼ Leading edge technology drastically reduces analysis
◼ A variety of oven options including temperature
times, providing better information about the process.
programmable and energy saving single or dual airless
◼ Valveless live sample injection and column switching ovens.
dramatically reduces hardware complexity and
◼ Wide selection of valve types for sample injection and
maintenance.
column switching including live valveless switching for
◼ Multiple detection for verification of the results. almost no dead volume.
◼ Synchronization of multiple analyzers that are connected ◼ Parallel chromatography simplifies even the most
in parallel for several sample streams, results in more complex analysis systems as well as dramatically reducing
information per time unit, a high degree of reliability measurement cycle times.
should one of the systems fail, and easy implementation
◼ New guiding technology with modular design for fast
of redundant systems.
maintenance and higher availability for measurement
◼ Cost-effective and compact design saves installation, and for customers process optimisation.
maintenance, and service costs.
◼ Open network with TCP/IP and Ethernet for
◼ SITRANS CV [1] communication with PC workstations, other
chromatographs or a DCS.
is a gas chromatograph for reliable, exact and fast analysis
of natural gas and biogas. The rugged and compact
design makes the SITRANS CV suitable for extreme
locations, e. g. off-shore platforms or direct mounting
on a pipeline. Operation of SITRANS CV using CV Control
software is simple and fast. The Software “CV Control“
has been specially developed for the requirements of the
natural gas market, e. g. custody transfer.

Siemens PA 01 · 2015 15
© Siemens AG 2014

Analytical Application Sets and Solutions

Our customers’ requirements drive the solution. We offer comprehensive designs covering the sampling
point and sample preparation up to complete analyzer cabinets whether used for portable applications or for
installation in a larger analyzer shelter. Signal processing and communications to the control room and process
control system is also part of the total system solution.

Our solutions for your application needs are based on dec- ◼ Remote maintenance, on-site servicing, spare parts
ades of global experience in process automation and engi- supplies and customized training.
neering as well as specialized knowledge in key industries
◼ Analytical Application Sets
and industrial sectors.
are standardized system solutions for a number of speci-
This guarantees you get Siemens quality from a single fic applications. Siemens offers ready-to-use developed
source with performance across the entire system. solution sets for various industries like energy, natural
Our portfolio of products and services include: gas, etc.
Standardized packages include the Set CEM 1 and Gas
◼ Customized services and solutions from front-end
met CEMS for the emission monitoring market. Specifi-
engineering and design (FEED) up to fully air-conditioned
cally designed for the natural gas market is the Set CV
analyzer shelters.
(calorific value). The Set CV includes a variety of modules,
◼ Support during the approval phase. which can be individually combined. For the monitoring
◼ Preliminary and detailed planning with state-of-the-art of hydrogen-cooled turbo generators the Set GGA is the
state-of-the-art solution. The Set BGA offers a modular a
tools and complete documentation.
standardized solution for the biogas market.
◼ System assembly and testing available in Siemens
We would be pleased to demonstrate our expertise as our
facilities in the USA, Germany and Singapore.
references speak for themselves!
◼ Experience with all relevant national and international
standards.
◼ Field commissioning and start-up by specialists all over
the world.

16 Siemens PA 01 · 2015
1
© Siemens AG 2014

Continuous Gas Analyzers, extractive

1/2 Introduction

1/5 SIPROCESS GA700


1/5 Base unit
1/18 Analyzer module OXYMAT 7

1/28 ULTRAMAT 23
1/28 General information
1/41 19" rack unit and portable version
1/59 Documentation,
Suggestions for spare parts

1/60 ULTRAMAT 6
1/60 General information
1/67 19" rack unit
1/81 Field device
1/92 Documentation
1/93 Suggestions for spare parts

1/94 ULTRAMAT/OXYMAT 6
1/94 General information
1/103 19" rack unit
1/115 Documentation
1/116 Suggestions for spare parts

1/117 OXYMAT 6
1/117 General information
1/125 19" rack unit
1/132 Field device
1/139 Documentation
1/140 Suggestions for spare parts

1/141 OXYMAT 61
1/141 General information
1/146 19" rack unit
1/151 Documentation
1/152 Suggestions for spare parts

1/153 OXYMAT 64
1/153 General information
1/160 19" rack unit
1/166 Documentation,
Suggestions for spare parts

1/167 CALOMAT 6
1/167 General information
1/172 19" rack unit
1/179 Field device
1/186 Documentation,
Suggestions for spare parts

1/187 CALOMAT 62
1/187 General information
1/192 19" rack unit
1/198 Field device
1/205 Documentation,
Suggestions for spare parts

1/206 FIDAMAT 6
1/206 General information
1/212 19" rack unit
1/219 Documentation
1/220 Suggestions for spare parts

1/221 SIPROCESS UV600

Siemens PA 01 · 2015
© Siemens AG 2014

Continuous Gas Analyzers, extractive


Introduction

1 ■ Overview
Siemens process gas analyzers have been used in the process Integrated Automation" concept which is globally unique. This
industry for more than 40 years, and are renowned for their concept permits design of uniform process communication from
quality, reliability and accuracy. The flexibility provided by the the operations management level down to the field level. The
continuous process gas analyzers with respect to housing simple integration of analyzers into the host control systems is
design, explosion protection, corrosion resistance and commu- the basis for a uniform automation and analysis solution.
nications capability means that optimum solutions can be found
for all applications. Many years of experience in the development and production of
analyzers as well as in the planning and installation of analyzer
Nowadays, the communications capability of analyzers is systems distinguishes Siemens as a solution provider - reliable,
becoming increasingly important. Siemens process gas innovative and with global presence.
analyzers are an integral component of Siemens’ "Totally
Process line

Process
Sample Sample feedback/
Sampling Analyzer
gas preparation exhaust

Schematic representation of the measuring setup of extractive site installations

1/2 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


Introduction

Extractive procedures for process gas analysis • ULTRAMAT 23 1


The ULTRAMAT 23 is an innovative multi-component gas
Extractive process gas analyzers are used for continuous deter- analyzer for measuring up to three infrared-sensitive gases
mination of the concentrations of one or more gases in a gas using the NDIR principle. Measurement of oxygen (O2) is also
mixture. Determination of the concentration of gases in a possible through the use of electrochemical oxygen sensors
process is used to control and monitor process flows, and is or measuring cells operating according to the paramagnetic
therefore decisive for the automation and optimization of principle ("dumbbell"). The use of an additional electro-
processes and ensuring product quality. In addition, process chemical H2S measuring cell permits use in biogas applica-
gas analyzers are used to check emissions, thus making an tions.
important contribution to environmental protection, as well as for
ensuring compliance with statutory directives. • ULTRAMAT/OXYMAT 6
For combined measurement of infrared-active components
With extractive measuring procedures, the sample to be and oxygen in complex applications.
analyzed is extracted from the process line and applied precon-
ditioned to the analyzer via a sample line and a sample prepa- • OXYMAT 6
ration system. This system, for example, adjusts the pressure, For measurement of oxygen concentration according to the
temperature and flow of the sample, and frees the sample gas of paramagnetic principle in complex applications. The
dust and moisture if necessary. This guarantees that the OXYMAT 6 measures oxygen according to the paramagnetic
measurement can be carried out under defined conditions. alternating pressure principle. This guarantees absolute
Furthermore, the analyzer is protected from damaging influ- linearity and allows the use of very small measuring ranges
ences. from 0 to 0.5 % (detection limit 50 ppm), ranges up to 0 to
100 %, and even 99.5 to 100 % in one unit.
Various measuring procedures with different physical and Suitable materials in the gas path even permit the analyzers to
electrochemical methods are used depending on the type of be used for measurement of corrosive gas mixtures. The
components to be measured and the measuring point. Siemens detector unit does not come into contact with the sample gas,
offers a range of measuring procedures for extractive gas and therefore permits use in harsh atmospheres while simulta-
analysis in two types of devices, SIPROCESS GA700 and neously guaranteeing a long service life.
Series 6 / ULTRAMAT 23. Each type of device provides peak • OXYMAT 61
analytical performances for its class. For measurement of oxygen concentrations according to the
SIPROCESS GA700 paramagnetic principle in standard applications. Ambient air
can be used as the reference gas for OXYMAT 61. This is
The SIPROCESS GA700 range is the latest generation of supplied by a pump integrated in the analyzer enclosure.
Siemens gas analyzers, and features a modular design. The • OXYMAT 64
base units are currently available with the OXYMAT 7 analyzer For measurement of oxygen concentrations in the trace range
module for paramagnetic measurement of oxygen. Up to two by means of ZrO2 sensors. The OXYMAT 64 can be used to
analyzer modules can be used per base unit. measure very small traces of oxygen, down to the smallest
Base unit measuring range of 0 to 10 ppm. This is particularly inter-
esting in systems for air separation. A catalytically inactive
The base unit is available in two models: as a 19" rack unit with ZrO2 sensor or a catalytically active ZrO2 sensor can be
3 height units, and in a housing for wall mounting. The commu- selected, depending on the application.
nication interfaces present in the base units can be adapted to
the respective process environment or the process control • CALOMAT 6
system using additional optionally available electronics For determining the concentration of hydrogen and inert
modules. gases in binary mixtures through measurement of thermal
conductivity. The CALOMAT 6 features a high dynamic
Analyzer modules measuring range (e.g. 0 … 1 % and 0 … 100 % H2, parame-
Depending on the measuring task, the SIPROCESS GA700 can terizable) and a short T90 time.
be individually adapted to the respective analytical or process • CALOMAT 62
requirements by fitting selectable analyzer modules. The CALOMAT 62 is a thermal conductivity analyzer that has
been specially designed for applications with corrosive
Analyzer module Measuring task gases. It is possible to directly measure the concentration of
OXYMAT 7 The OXYMAT 7 module is used to measure oxygen gas components such as Cl2, HCl and NH3, as well as e.g. H2
between 0 to 0.5 % (smallest measuring range) and 0 and N2 in a corrosive atmosphere.
to 100 % (largest measuring range). It is designed for
use at ambient temperatures up to 50 °C and allows
• FIDAMAT 6
highly exact measurements through application of the For measurement of total hydrocarbons according to the flame
paramagnetic alternating pressure principle. Thanks to ionization principle.
the modular design, the analyzer module can be com- The FIDAMAT versions feature a highly varied field of appli-
bined with a further OXYMAT 7 module. cation. From monitoring for traces of hydrocarbons in ultra-
pure gases - made possible by the high resolution and small
Series 6 / ULTRAMAT 23 differences in response factors - up to measurements of total
The classic analyzers from Siemens, Series 6 and hydrocarbons in the % range.
ULTRAMAT 23, have been proven at our customers all over the The widely adjustable operating temperature for the sample
globe in many years of use: gas path and detector also allows measurement of high-
• ULTRAMAT 6 boiling mixtures and of hydrocarbons at water vapor concen-
For highly-selective measurement of infrared-active compo- trations up to 100 %.
nents such as CO, CO2, NO, SO2, NH3, H2O, CH4 and other • SIPROCESS UV600
hydrocarbons. The ULTRAMAT 6 is a high-end analyzer in Gas analyzer based on UV resonance absorption
19" format or in a sturdy field housing for use in harsh spectrometry for measuring even very low NO, NO2, SO2, and
atmospheres. The field of application basically comprises all H2S concentrations.
types of emission measurements up to use in processes.
These serve to control production processes and guarantee
product quality, even in the presence of highly corrosive
gases.

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Continuous Gas Analyzers, extractive


Introduction

1 General information Calibration/adjustment


Introducing flammable gases The Series 6 analyzers (ULTRAMAT 6, OXYMAT 6, CALOMAT 6)
as well as the SIPROCESS GA700 analyzers (OXYMAT 7) should
Introducing frequently or permanently explosive gas/air mixtures be calibrated with zero and calibration gas at least every 14
to the gas analyzers mentioned in this chapter is not permitted. days.
The introduction of gases with flammable components at
concentrations above the lower explosive limit (LEL) should only Standard Zero gas N2 (5.0)
be carried out with analyzers fitted with piping. Purging of the Calibration gas Sample gas with approx. 60 … 90 % of
housing as well as further measures must be carried out measuring range in residual N2 (5.0)
depending on the application. When using SIPROCESS UV600,
please contact the technical department. An inert gas must be Note: With OXYMAT 6/61 and OXYMAT 7, the zero gas and the
used for purging (see manual for further information). reference gas must be the same.
Cross-sensitivity • Pre-purging of sample gas path via the sample gas inlet with
nitrogen (N2, quality 5.0), duration: min. 1 min, one further
Exact measurement results with regard to the technical specifi- minute in addition for each 10 m of sample gas line.
cations can only be expected if a sample gas is free to the
greatest possible extent of gases exhibiting a cross-sensitivity • Calibration gases for zero point adjustment (ULTRAMAT 6,
with the measured component. The influences of these inter- OXYMAT 6, CALOMAT 6, OXYMAT 7)
fering components can be reduced using various measures. Sufficient supply of inert gas via the sample gas inlet (free from
Please contact our specialists if you have any questions. measured component and free from gases with a cross-
influence on the measured component), usually N2, quality
General installation guide and operating instructions 5.0.
• Protected against low temperatures and thermal radiation • Gases for calibration of deflection
(see technical specifications) Connection of calibration gas via the sample gas inlet
• Protected against temperature variations (approx. 60 to 90 % of the measuring range of the measured
component with inert gas as the residual gas (e.g. N2,
• To achieve the best possible measuring quality, the installation quality 5.0)).
location should be free from vibrations
• Gases for calibration of the CALOMAT 62
• Protection of electronics from corrosive environments (use Since every residual gas (including nitrogen) has a specific
field devices with purging if necessary) thermal conductivity, the gases used for calibrating the zero
• Observation of directives for installation in hazardous areas point and full-scale values of the CALOMAT 62 must take this
(see manual) into account. When calibrating e.g. H2 in HCl, HCl can be
• Observation of directives for measurement in the presence of used as the zero gas (or an appropriate substitute in accor-
toxic gases, provide purging of enclosure and further safety dance with the data sheet enclosed with the device) and H2 in
measures if necessary (see manual) HCl (or a substitute gas) as the span gas.
• The analyzers in the basic version are set to a cross-influence You can find details on FIDAMAT 6, OXYMAT 64 and
of water vapor with a dew point of 4 °C (standard cooler ULTRAMAT 23 (AUTOCAL) in the chapters describing the
temperature for sample preparation). respective device.
• When calibrating with zero gas and span gas, these must be Explosion protection
connected via the sample gas cooler analogous to the sample
gases to allow correct adjustment. Refer to the separate manuals, references and standards
concerning the topic of explosion protection.
• In special cases (test measurements or long-term adjust-
ments), it is recommendable to connect the calibration gases
via a humidifier upstream of the cooler to avoid "drying-out" of
the gas cooler and thus changes in the concentration of the
water vapor.
• Correction of cross-interference which may be activated for a
gas is canceled for the duration of a calibration procedure
(zero point and sensitivity).

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SIPROCESS GA700
Base unit

■ Overview ■ Application
1
Application areas
Depending on the analyzer modules installed, the device is
predominantly used in the following sectors:
• Chemical industry
• Petrochemicals
• Steel
• Cement
• Power generation
• Environmental protection

■ Design
19" rack unit
• 19" rack unit with 3 height units (HU) for installation
- in hinged frames
- in cabinets with or without telescopic rails
• Gas connections for sample gas inlet and outlet: for pipe
The entire SIPROCESS GA700 device is configured in a modular diameter 6 mm or 1/4"
fashion and consists of a base unit and at least one – maximum • Purging gas connections 10 mm and 3/8" (optional)
two – analyzer modules. It can optionally be fitted with up to two
interfaces modules (option modules). Wall-mounted device
• Gas connections for sample gas inlet and outlet: Pipe union
■ Benefits for pipe diameter 6 mm or 1/4" (directly on the analyzer
modules)
The base unit provides: • Purging gas connections (optional), purging gas connection
• Transmission and evaluation of measurement results for 6 mm or 1/4" hose (optional)
• Display and transmission of device parameters Display and operator panel
• Operation (parameterization, configuration) • LCD panel for simultaneous display of:
- Measured value
In addition to the analyzer modules, the base unit contains the
- Status line
interfaces for the peripherals.
- Measuring ranges
• Menu-driven operation for parameterization, test functions,
adjustment
• Operator support in plain text
• Operating software (11 languages)

Special keys
Display Numeric keypad

Cursor and command keys

HELP and UNDO keys

Display and operator panel of the SIPROCESS GA700 devices

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Base unit
1 Inputs and outputs
• 8 digital inputs, designed for 24 V, potential-free, freely config-
urable (e.g. for measurement range switchover, processing of
external signals from sample preparation)
• 8 relay outputs, with changeover contacts, freely configurable
(e.g. for faults, maintenance requests, limit alarms, external
solenoid valves)
• Ethernet connection contained in the base unit (connection on
the rear side, Ethernet RJ 45, 100 MBit)
• Service interface (front side); Ethernet RJ 45, 100 MBit.
Interface modules
• Option module 2.1:
one analog output per measured component (max. 6, 0 to
20 mA, 4 to 20 mA or parameter assignment in accordance
with NAMUR), plus 6 digital outputs

■ Function
Essential characteristics
• Measuring range identification
• Storage of measured values possible during adjustments
• Four freely parameterizable measuring ranges, also with
suppressed zero point
• Autoranging possible; remote switching is also possible
• Wide range of selectable time constants (static/dynamic noise
suppression); i.e. the response time of the analyzer can be
matched to the respective measuring task
• Measuring point switchover for up to 12 measuring points
(programmable)
• Parameterizable measuring point identification
• Automatic, parameterizable measuring range calibration
• Operation based on the NAMUR recommendation
• Three control levels with their own authorization codes for the
prevention of accidental and unauthorized operator interven-
tions
• Simple handling using a numerical membrane keyboard and
operator prompting
• Customer-specific analyzer options such as:
- Customer acceptance
- TAG labels

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SIPROCESS GA700
Base unit

■ Technical specifications
1
19" rack unit Wall housing
General information General information

Operating position Horizontal Operating position Vertical

Conformity CE mark in accordance with Conformity CE mark in accordance with


EN 50081-1 and EN 50082-2 EN 50081-1 and EN 50082-2

Design, enclosure Design, enclosure


Weight without module 8.6 kg Weight without module 23 kg
Degree of protection IP20 according to EN 60529 Degree of protection IP65 in accordance with EN 60529,
restricted breathing enclosure to
Electrical characteristics EN 50021
Power supply 100 to 240 V AC (nominal range of Electrical characteristics
use 85 to 264 V), 50 to 60 Hz (nomi-
nal range of use 47 to 63 Hz) Power supply 100 to 240 V AC (nominal range of
use 85 to 264 V), 50 to 60 Hz (nomi-
Power consumption 280 VA max. nal range of use 47 to 63 Hz)
EMC interference immunity In accordance with the standard Power consumption 280 VA max.
(electromagnetic compatibility) requirements of NAMUR NE21
(05/2006) and EN 61326-1 EMC interference immunity (electro- In accordance with the standard
(01/2008) magnetic compatibility) requirements of NAMUR NE21
(05/2006) and EN 61326-1
Electrical safety In accordance with EN 61010-1, (01/2008)
overvoltage category II
Electrical safety In accordance with EN 61010-1,
Electrical inputs and outputs overvoltage category II
Relay outputs 8, with changeover contacts, can be Gas inlet conditions
freely parameterized, e.g. for mea-
suring range identification; max. Purging gas pressure
load: 24 V AC/DC/40 W (total load • Permanent < 100 hPa above atmospheric pres-
for all 8 relay outputs in continuous sure
operation max. 160 W), potential- • For short periods 165 hPa above atmospheric pres-
free, non-sparking sure
Digital inputs 8, designed for 24 V, potential-free,
can be freely parameterized, e.g. for Electrical inputs and outputs
measurement range switchover Relay outputs 8, with changeover contacts, can be
Ethernet interface (rear) Ethernet RJ 45, 100 MBit freely parameterized, e.g. for mea-
suring range identification; max.
Service interface (front) Ethernet RJ 45, 100 MBit load: 24 V AC/DC/40 W (total load
for all 8 relay outputs in continuous
Option module 2.1 6 analog outputs, 0/4 to 20 mA,
operation max. 160 W), potential-
potential-free; maximum load 750 
free, non-sparking
and 6 additional relay outputs, load-
ing capacity: 24 V AC/DC/40 W, Digital inputs 8, designed for 24 V, potential-free,
potential-free, non-sparking can be freely parameterized, e.g. for
measurement range switchover
Climatic conditions
Ethernet interface (bottom) Ethernet RJ 45, 100 MBit
Permissible operating altitude 3 000 m above sea level
Service interface (bottom) Ethernet RJ 45, 100 MBit
Permissible ambient temperature • -30 ... +70 °C during storage and
(with one module; application-depen- transportation Option module 2.1 6 analog outputs, 0/4 to 20 mA,
dent with two modules) • 0 ... 50 °C during operation with potential-free; maximum load 750 
one or two OXYMAT 7 analyzer and 6 additional relay outputs, load-
modules ing capacity: 24 V AC/DC/40 W,
potential-free, non-sparking
Ventilation slits must not be covered
(recommended minimum upward Climatic conditions
clearance from the next device
when installing 2 analyzer modules Permissible operating altitude 3 000 m above sea level
and at maximum ambient tempera- Permissible ambient temperature • -30 ... +65 °C during storage and
ture: min. 1 HU) (with one module; application-depen- transportation
Permissible humidity < 90 % RH (RH: relative humidity), dent with two modules) • 0 ... 50 °C during operation with
during storage and transportation one or two OXYMAT 7 analyzer
(dew point must not be undershot) modules
Permissible humidity < 90 % RH (RH: relative humidity),
during storage and transportation
(dew point must not be undershot)

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SIPROCESS GA700
Base unit
1 Selection and ordering data Article No.
SIPROCESS GA700 1) 7MB3000- 7 7 7 7 7 - 7 A 7 7 Cannot be
combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Base unit versions
Rack unit enclosure 0 0
Wall housing 3 3
Module, installation position 1
Without X X
OXYMAT 7 D
Module, installation position 2
Without X
OXYMAT 7 D D
Gas management (only with AM, with hoses)
No gas management, dummy plate without purging gas connection 0
No gas management, dummy plate with purging gas connection (on request) 6 6
Option module 1
Without 0
Option module 2
Without 0
Option module 2.1 (2 x 3 analog outputs and 2 x 3 digital outputs) 2
Ex version
Standard, set-up in non-hazardous zone A
Standard, set-up in non-hazardous zone with purging gas connection (wall structure) B B
Type
Standard 0
1) Compact operating instructions 1 must always be selected when ordering.

Selection and ordering data Ordering examples


Additional versions Order code OXYMAT 7 module in rack unit enclosure "Example1"
Add "-Z" to Article No. and specify Order code 7MB3000-0DX00-2AA0-Z + Y01 "Example1"
TAG labels (specific inscription based on customer B03
information) 7MB3020-0AD00-0AA0-Z + Y01 "Example1"
Device name, ........(plain text) Y01 OXYMAT 7 module in wall housing "Example2"
Power connector P01 7MB3000-3DX00-2AA0-Z + Y01 "Example2"
Compact operating instructions 1 7MB3020-0AD00-0AA0-Z + Y01 "Example2"
(must always be selected when ordering)
• German L50
• English L51
• French L52
• Italian L53
• Spanish L54
• Chinese (Simplified) L55
• Portuguese (Brazilian) L56
• Russian L57
• Korean L58
• Japanese L59
Compact operating instructions 2 (selectable as option)
• German L75
• English L76
• French L77
• Italian L78
• Spanish L79
• Chinese (Simplified) L80
• Portuguese (Brazilian) L81
• Russian L82
• Korean L83
• Japanese L84

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SIPROCESS GA700
Base unit

■ Dimensional drawings
1

132.55
37.7 57.15

10.3 170.8
13.5 421.5
482.3

441.3

421.5
419

Slot 1 Slot 2

47
80.5
104.5
128.5
205
297
389

SIPROCESS GA700, rack unit, dimensions in mm

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Base unit
1

370
20
291.5 0
272.5
237.5

Slot 1 Slot 2 202.5


167.5
132.5
120.5
98 97.5

0 0
168.5

260.5

408
425
0

76.5

450
196 338.3

0
28
164.6

493
549
567.6

SIPROCESS GA700, wall housing, dimensions in mm

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SIPROCESS GA700
Base unit

■ Schematics
1
Connection of the signal cables

Connector number

4 3 2 1 vtYUX

Power supply unit

Processing module
h Ethernet and SUB-D 37F,
digital inputs/outputs
1 Sample gas inlet
2 Sample gas outlet Option module 2.1
3 N.C. SUB-D 15M, binary inputs
4 Reference gas inlet and analog outputs

Expansion options for processing and option modules with the example of the rear wall of the rack unit

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Base unit
1 Pin assignments (rack unit enclosure)

SUB-D 15M connector, pin assignments for


analyzer module 1

8
Analog output 13-N 15
Relay 10
7
Analog output 13-P 14
6
13
Analog output 11-N 5
Relay 11 12
Analog output 11-P 4
11
3
Analog output 12-N 10
Relay 9 2
Analog output 12-P 9
1

Analog outputs floating


(also from each other), RL: ≤ 750 Ω SUB-D 15M connector, pin assignments for
analyzer module 2
Contact load
max. 24 V/1.7 A, AC/DC; 8
shown relay contacts: relay coil has Analog output 23-N 15
zero current
Relay 13 7
Analog output 23-P 14
6
13
Analog output 21-N 5
Relay 14 12
Analog output 21-P 4
11
3
Analog output 22-N 10
Relay 12 2
Analog output 22-P 9
1

Pin assignments of option module 2.1

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Base unit
1
SUB-D 37F connector

M 19 GND
37 NC
18 NC
36 Binary input 8-P
17 Binary input 7-P
35 Binary input 6-P
16 Binary input 5-P Floating via optocoupler
34 Binary input 4-P "0" = 0 V (-3 ... +5 V)
15 Binary input 3-P "1" = 24 V (15 ... 33 V)
33 Binary input 2-P
14 Binary input 1-P
32 Binary input 1 to 8-N
13
31 Relay 8
12
30
11 Relay 7
29
10
28 Relay 6
9
27
8 Relay 5 Contact load
26 max. 24 V/1.7 A, AC/DC; shown
7 relay contacts: relay coil has zero
25 current
Relay 4
6
24
5 Relay 3
23
4
22 Relay 2
3
21
2 Relay 1
20
M 1 GND

Pin assignment of the processing module (base unit)

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Base unit
1 Terminal assignment (wall housing)

Standard terminal block

Terminal row A

M 1 GND
2
3 Relay 1
4
5
6 Relay 2
7
8
9 Relay 3 Contact load
10 max. 24 V/1.7 A, AC/DC; shown
11 relay contacts: relay coil has zero
12 Relay 4 current
13
14
15 Relay 5
16
17
18 Relay 6
19

Terminal row B

1 NC Contact load
2 max. 24 V/1.7 A, AC/DC; shown
3 Relay 7 relay contacts: relay coil has zero
4 current
5 Binary input 1 to 8-N (GND)
6 Binary input 1-P
7 Binary input 2-P
8 Binary input 3-P Floating via optocoupler
9 Binary input 4-P "0" = 0 V (-3 ... +5 V)
10 Binary input 5-P "1" = 24 V (15 ... 33 V)
11 Binary input 6-P
12 Binary input 7-P
13 Binary input 8-P
14 Binary input 1 to 8-N (GND)
15 NC
16 NC Contact load
17 max. 24 V/1.7 A, AC/DC; shown
18 Relay 8 relay contacts: relay coil has zero
19 current

Terminal assignment, standard terminal block, terminal rows A and B

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SIPROCESS GA700
Base unit
1
Standard terminal block

Terminal row C

1 NC
2
3 Relay 21
4
5
6 Relay 22
7
8
9 Relay 23 Contact load
10 max. 24 V/1.7 A, AC/DC; shown
11 relay contacts: relay coil has zero
12 Relay 24 current
13
14
15 Relay 25
16
17
18 Relay 26
19

Terminal row D

1 NC
2 Analog output 11-P
3 Analog output 11-N
4 Analog output 12-P
5 Analog output 12-N
6 Analog output 13-P
7 Analog output 13-N Analog outputs floating
8 Analog output 21-P (also from each other), RL: ≤ 750 Ω
9 Analog output 21-N
10 Analog output 22-P
11 Analog output 22-N
12 Analog output 23-P
13 Analog output 23-N
14 NC
15 NC
16 NC
17 NC
18 NC
M 19 GND

Terminal assignment, standard terminal block, terminal rows C and D

Assignment between terminal block and analyzer module


Terminal row C
Relays 21 to 23 correspond to status display of analyzer module 1
Relays 24 to 26 correspond to status display of analyzer module 2
Terminal row D
Analog outputs 11 to 13 correspond to analyzer module 1
Analog outputs 21 to 23 correspond to analyzer module 2

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Base unit
1
Terminal block B (optional)

Terminal row A

M 1 GND
2
3 Relay 9
4
5
6 Relay 10
7 Contact load
8
max. 24 V/1.7 A, AC/DC; shown
9 Relay 11
relay contacts: relay coil has zero
10 current
11
12 Relay 12
13
14
15 Relay 13
16

Terminal row B

1 NC
Contact load
2
max. 24 V/1.7 A, AC/DC; shown
3 Relay 14 relay contacts: relay coil has zero
4 current
5 Binary input 9 to 16-N
6 Binary input 9-P
7 Binary input 10-P
8 Binary input 11-P
Floating via optocoupler
9 Binary input 12-P
"0" = 0 V (-3 ... +5 V)
10 Binary input 13-P
"1" = 24 V (15 ... 33 V)
11 Binary input 14-P
12 Binary input 15-P
13 Binary input 16-P
Contact load
14 max. 24 V/1.7 A, AC/DC; shown
15 Relay 15 relay contacts: relay coil has zero
16 current

Terminal assignment, terminal block B, terminal rows A and B

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SIPROCESS GA700
Base unit
1
Terminal block B (optional)

Terminal row C

1 NC
2
3 Relay 16
4
5
6 Relay 17
7 Contact load
8
max. 24 V/1.7 A, AC/DC; shown
9 Relay 18
relay contacts: relay coil has zero
10 current
11
12 Relay 19
13
14
15 Relay 20
16

Terminal row D

1 NC
2 Binary input 17 to 18-N Floating via optocoupler
Binary input 17-P "0" = 0 V (-3 ... 5 V)
3
Binary input 18-P "1" = 24 V (15 ... 33 V)
4
5 Analog input 1-P
M 6 Analog input 1-N
7 Analog input 2-P
M 8 Analog input 2-N Analog inputs non-floating,
9 Analog input 3-P 0 ... 20 mA/(internal resistance ≤ 100 Ω)
M 10 Analog input 3-N
11 Analog input 4-P
M 12 Analog input 4-N
13 Binary input 19 to 20-N Floating via optocoupler
14 Binary input 19-P "0" = 0 V (-3 ... 5 V)
15 Binary input 20-P "1" = 24 V (15 ... 33 V)
M 16 GND

Terminal assignment, terminal block B, terminal rows C and D

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7
1 ■ Overview ■ Application
The function of the OXYMAT 7 analyzer module is based on the Application areas
paramagnetic alternating pressure method and is used to • For boiler control in incineration plants
measure oxygen in gases.
• In chemical plants
■ Benefits • For ultra-pure gas quality monitoring
• Paramagnetic alternating pressure principle • In environmental protection
- Small measuring ranges (0 to 0.5 % or 99.5 to 100 % O2) • For quality control
- Absolute linearity • Purity control/air separator
• Detector element has no contact with the sample gas
- Applicable in the absence of corrosive sample gases
- Long service life
• Physically suppressed zero point possible, e.g. in the
measuring range 98 % or 99.5 % to 100 % O2

■ Design

1
2
3
4

1 Sample gas inlet


2 Sample gas outlet
3 N.C.
4 Reference gas inlet

Structure of high-pressure version, sample gas path with pipes

Designs – Parts wetted by sample gas, standard


Gas path Material Gas path Material
With hoses Bushing PVDF With pipes Bushing Stainless steel, mat. no. 1.4571
Hose FKM (e.g. Viton) Pipe Stainless steel, mat. no. 1.4571
Sample Stainless steel, mat. no. 1.4571 Sample Stainless steel, mat. no. 1.4571
chamber chamber
O-rings/seals FPM Sample gas Stainless steel, mat. no. 1.4571
restrictor
Restrictor PTFE (e.g. Teflon)
O-rings/seals FKM (Viton) or FFKM (Kalrez)
Special Materials adapted to the application
applications

Options
Pressure Diaphragm FKM (Viton)
switch
Enclosure PA 6.3 T

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SIPROCESS GA700
Analyzer module OXYMAT 7
Gas path 1
High-pressure version with optional pressure switch for
monitoring reference gas pressure

Reference gas pressure 2 000 … 4 000 hPa above sample


gas pressure, but max. 5 000 hPa
Sample gas pressure
• With hoses Max. 500 hPa above atmospheric
pressure
• With pipes Max. 1 500 hPa above atmospheric
pressure
Sample gas path With hoses or with pipes

7 6 10

4
8
11

5
1

1 Sample gas inlet 6 Pressure sensor p for sample gas pressure


2 Sample gas outlet 7 Analyzer unit
3 N. C. 8 Reference gas restrictor
4 Reference gas inlet 10 Pressure switch for reference gas monitoring
5 Sample gas restrictor (optional)
11 Reference gas fine filter

Gas path plan, high-pressure version with optional pressure switch for monitoring reference gas pressure

Siemens PA 01 · 2015 1/19


© Siemens AG 2014

Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7
1 Low-pressure version with external reference gas pump

Reference gas pressure 100 hPa above the sample gas


pressure (low-pressure version) for
the connection of an external pump
Sample gas pressure Atmospheric pressure ± 50 hPa
Sample gas path With hoses
Reference gas path With hoses

7 6

4
8 10
9

5
1

1 Sample gas inlet 6 Pressure sensor p for sample gas pressure


2 Sample gas outlet 7 Analysis part
3 Bypass outlet 8 Reference gas restrictor
4 Reference gas inlet, external pump, 9 Bypass restrictor
delivery pressure approx. 100 hPa 10 Damping restrictor
5 Sample gas restrictor

Gas path plan, low-pressure with external reference gas pump, with hoses

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7

■ Mode of operation
1
Oxygen is highly paramagnetic. This outstanding property of
paramagnetism is used as a physical measuring effect for
oxygen analysis. 1

Oxygen molecules in an inhomogeneous magnetic field always


move toward the higher field strength. This results in a higher
oxygen concentration where the field strength is higher (higher 2
oxygen partial pressure). If two gases with differing oxygen
content are combined in a magnetic field, a (O2 partial) pressure 4
difference arises between them.
Since the measuring effect is always based on the difference of
the oxygen content of the two gases, one refers to the sample
and reference gases.
5
For measuring oxygen in the OXYMAT 7, the reference gas (N2,
3
O2 or air) flows through two channels into the sample chamber
(6). One of these partial flows enters the measuring chamber (7) 6
in the area of the magnetic field. If the sample gas is O2-free, the
reference gas can flow out freely. If the sample gas does contain
O2, however, the oxygen molecules concentrate in the area of vY 7 8
vY
the magnetic field. The reference gas can then no longer flow off
vY
freely. An alternating pressure results between the two reference
gas inlets. This pulsates in step with the magnetic field and vY
depends on the oxygen concentration. This causes an alter- vY
nating flow in the microflow sensor (4). vY
The microflow sensor consists of two nickel-plated grids heated
to approximately 120ºC, which, along with two supplementary
resistors, form a Wheatstone bridge. The alternating flow results
in a change in the resistance of the nickel-plated grids. The 9
resulting offset in the bridge is a measure of the concentration of
oxygen in the sample gas.
Because the microflow sensor is located in the reference gas
flow, the measurement is not influenced by the thermal conduc- 11
tivity, the specific heat or the internal friction of the sample gas.
Additionally, the microflow sensor is protected through this
arrangement from corrosion caused by the sample gas. 10
Further information
The oscillating magnetic field (8) means that the basic flow at the 2
microflow sensor is not detected. The measurement is, thus,
independent of the module's operating position or the position of
the sample chamber.
The sample chamber is directly in the sample path and has a
small volume, and the microflow sensor is a low-lag sensor. As a 1
result, extremely short response times are realized.
Vibrations at the installation site can interfere with the measured
signal (e.g. large fluctuations in the output signal). This behavior 1 Reference gas inlet
can be compensated for by a second (optional) microflow 2 Restrictors
sensor (10), which functions as a vibration sensor. Since large 3 Reference gas channels
differences in density between the sample and reference gases 4 Microflow sensor for measured signal
further amplify the undesired influence of vibration, reference 5 Sample gas inlet
gas is channeled to both the compensation microflow sensor 6 Sample chamber
(10) and the sample microflow sensor (4). 7 Source of the paramagnetic measuring effect
8 Electromagnet with alternating current strength
The sample gases must be fed into the analyzers free of dust. 9 Sample gas and reference gas outlet
Condensation in the sample chambers must be prevented. 10 Microflow sensor in the vibration compensation system
Therefore, the use of gas modified for the measuring task is (order variant)
necessary in most application cases. 11 Compensation circuit (optional)

Flowing reference gas prevents the microflow sensor from being


damaged and maintains the measurement capability of the
analysis module.
OXYMAT 7, principle of operation

Siemens PA 01 · 2015 1/21


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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7
1 Essential characteristics
Technical features Features
Depending on the reference gas, the physical zero point can be • Electrically isolated measured value output 0/4 to 20 mA (also
set between 0 % and 100 % oxygen. inverted)
• Smallest measuring spans (up to 0.5 % O2) possible • Internal pressure sensor for correction of pressure variations
in sample gas in the range from 500 to 2 500 hPa (absolute)
• Measuring ranges with physically suppressed zero points
possible (e.g. 99.5 % to 100 %) • External pressure sensor - only with piping as the gas path -
can be connected for correction of variations in the sample
• Short response time gas pressure up to 3 000 hPa absolute (option)
• Low long-term drift • Monitoring of reference gas (option)
• Also suitable for use with highly corrosive sample gases • Analysis part with flow-type compensation circuit as an order
(material 1.4571 or Hastelloy C22) variant for reducing the vibration impact at the installation site
• Monitoring of reference gas pressure with reference gas • For sample gas path with hoses: Connection cable to the
connection 3 000 to 5 000 hPa (abs.) (option) pressure sensor with hoses
• Hardware adapted to application
• Customer-specific analyzer options such as:
- Drift recording
- Clean for O2 service
- Kalrez gaskets
• Sample chamber for use in presence of highly corrosive
sample gases
Reference gases
Measuring range Recommended reference gas Reference gas connection pressure Comments
0 to ... vol.% O2 N2 2 000 … 4 000 hPa above sample gas The reference gas flow is set auto-
pressure (max. 5 000 hPa absolute) matically to 5 … 10 ml/min (up to
... to 100 vol.% O2 (suppressed zero O2 20 ml/min with flow-type compensa-
with full-scale value 100 vol.% O2) tion branch)
Around 21 vol.% O2 (suppressed zero Air 100 hPa with respect to sample gas
point with 21 vol.% O2 within the mea- pressure, which may vary by max.
suring span) 50 hPa around the atmospheric pres-
sure

Table 1: Reference gases for OXYMAT 7

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7
Correction of zero point error/cross-sensitivities 1
Accompanying gas Zero point deviation Inert gases
(concentration 100 vol.%) in vol.% O2 absolute
Helium He +0.33
Organic gases
Neon Ne +0.17
Ethane C2H6 -0.49
Argon Ar -0.25
Ethene (ethylene) C2H4 -0.22
Krypton Kr -0.55
Ethine (acetylene) C2H2 -0.29
Xenon Xe -1.05
1.2 butadiene C4H6 -0.65
Inorganic gases
1.3 butadiene C4H6 -0.49
Ammonia NH3 -0.20
n-butane C4H10 -1.26
Hydrogen bromide HBr -0.76
iso-butane C4H10 -1.30
Chlorine Cl2 -0.94
1-butene C4H8 -0.96
Hydrogen chloride HCl -0.35
iso-butene C4H8 -1.06
Dinitrogen monoxide N2O -0.23
Dichlorodifluoromethane (R12) CCl2F2 -1.32
Hydrogen fluoride HF +0.10
Acetic acid CH3COOH -0.64
Hydrogen iodide HI -1.19
n-heptane C7H16 -2.40
Carbon dioxide CO2 -0.30
n-hexane C6H14 -2.02
Carbon monoxide CO +0.07
Cyclo-hexane C6H12 -1.84
Nitrogen oxide NO +42.94
Methane CH4 -0.18
Nitrogen N2 0.00
Methanol CH3OH -0.31
Nitrogen dioxide NO2 +20.00
n-octane C8H18 -2.78
Sulfur dioxide SO2 -0.20
n-pentane C5H12 -1.68
Sulfur hexafluoride SF6 -1.05
iso-pentane C5H12 -1.49
Hydrogen sulfide H2S -0.44
Propane C3H8 -0.87
Water H2O -0.03
Propylene C3H6 -0.64
Hydrogen H2 +0.26
Trichlorofluoromethane (R11) CCl3F -1.63
Vinyl chloride C2H3Cl -0.77
Vinyl fluoride C2H3F -0.55
1.1 vinylidene chloride C2H2Cl2 -1.22

Table 2: Zero point error due to diamagnetism or paramagnetism of some carrier gases with nitrogen as the reference gas at 60 °C and
1 000 hPa absolute (according to IEC 1207/3)
Conversion to other temperatures:
The deviations from the zero point listed in Table 2 must be multiplied by a correction factor (k):
• with diamagnetic gases: k = 333 K / ( [°C] + 273 K)
• with paramagnetic gases: k = [333 K / ( [°C] + 273 K)]2
(All diamagnetic gases have a negative deviation from zero point).

Siemens PA 01 · 2015 1/23


© Siemens AG 2014

Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7
1 ■ Technical specifications
The technical specifications are based on the definitions of Time response
DIN EN 61207-1.
Warm-up period at room temperature <2h
Unless specified otherwise, the data listed below relates to the Dead time (T10) < 0.5 s at 1 l/min
following measurement conditions:
Signal rise time or fall time for a flow <1s
Ambient temperature 25 °C rate of 1 l/min, a static attenuation
constant and a dynamic attenuation
Atmospheric pressure Atmospheric (approx. 1 000 hPa) constant of 0 s
Sample gas flow 0.6 l/min (or Nl/min) Time for device-internal signal approx. 1 s
processing
Reference gas Nitrogen
Delayed display T90 T90 < T10 + rise or fall time +
Site of installation Vibration- and impact-free
signal processing time
General information Measuring response
Weight Approx. 5.5 kg (standard version) Output signal fluctuation  0.5 % of the current measuring
span (6  value) for a static attenua-
Measuring ranges tion constant of 0 s and a dynamic
Number of measuring ranges Max. 4; parameters can be attenuation setting of 5 % / 10 s
assigned freely (with activated vibration compensa-
tion: 1.5 times the value
Parameters can be assigned in the
measuring ranges Detection limit  1 % of smallest measuring span
according to nameplate (with vibra-
• Smallest possible measuring spans 0.5 % ( 1 % for high-temperature tion compensation activated: 1.5
model), 2 % or 5 % O2 times the value)
• Largest possible measuring spans 100 % O2 Measured-value drift  0.5 %/month of current measuring
span or  50 vpm oxygen, which-
Gas inlet conditions ever is larger
Sample gas pressure Repeatability  0.5 % of current measuring span
• Devices with tubes 500 … 1 500 hPa (abs.) Linearity error with ambient air as  0,1 %
• Devices with pipes reference gas

- Without vibration compensation 500 to 3 000 hPa (abs.); Influencing variables


short-term max. 5 000 hPa (abs.) Ambient temperature
- With vibration compensation 500 to 2 500 hPa (abs.); • At the zero point  0.5 % of smallest measuring span
short-term max. 5 000 hPa (abs.) according to nameplate/10 K or
Correction of the internal pressure  50 vpm O2/10 K, whichever is
sensor larger

• Devices with tubes 500 … 1 450 hPa (abs.) • At span  0.5 % of the current measuring
span/10 K or  50 vpm O2/10 K,
• Devices with pipes 500 … 2 450 hPa (abs.) whichever is larger
Reference gas pressure Sample gas pressure
• High-pressure connection 0.2 to 0.4 MPa above the sample • Without pressure compensation Deviation approx. 2 % of current
gas pressure, but a maximum of measuring span/1 % pressure
0.5 MPa (absolute) variation
- Without vibration compensation 2 000 … 3 500 hPa above sample • With pressure compensation  0.2 % of the current measuring
gas pressure; max. 5 000 hPa (abs.) switched on span/1 % pressure variation or 
50 vpm O2/1 % pressure variation,
- With vibration compensation 2 500 … 4 000 hPa above sample
whichever is larger
gas pressure; max. 5 000 hPa (abs.)
Sample gas flow  1 % of the current measuring span
• Low-pressure connection with exter- 100 hPa above the sample gas
with a flow rate change of 0.1 l/min
nal reference gas pump (only for pressure
within the permissible flow range
sample gas pressure 500 ...
(0.3 ... 1 l/min)
1 500 hPa (absolute))
Carrier gases Zero point deviation (cross-sensitiv-
Pressure loss between sample gas < 100 hPa at 1 l/min
ity) in accordance with Table A.1 of
inlet and sample gas outlet
EN 61207-3
Sample gas flow 18 … 60 l/h (0.3 … 1 l/min)
Supply voltage (fluctuations of the  0.1 % of full-scale value of
Sample gas temperature 0 … 60 °C supply voltage of the base unit*) in the characteristic
range of 90 to 253 V AC/47 to 63 Hz)
Sample gas humidity (rel. humidity) < 90 % (condensation inside the
gas path is to be avoided)
Sample chamber temperature
Standard version Approx. 72 °C

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7
Electrical inputs and outputs
1
Analog and digital interfaces See base unit
Gas connections
With hoses Plastic screw connection for plastic
pipe or tube 4 mm/6 mm
With pipes Connection for threaded joint;
ISO female thread 1/8"
Climatic conditions
Storage and transport -30 … 70 °C
Permissible ambient temperature 0 … 50 °C
(for operation in base unit)
Relative humidity (RH) during storage, < 90 % (condensation from the
transport or operation installed components is to be
avoided)
Materials of wetted parts
Sample chamber Stainless steel:
• Plates: Mat. No. 1.4571
(X6CrNiMoTi 17-12-2)
• Screw-in glands: Mat. No. 1.4404
(X2CrNiMo17-12-2)
Hastelloy C22:
• Plates: Mat. No. 2.4602
(NiCr21Mo14W)
• Screw-in glands: Mat. No. 2.4819
(NiMo16Cr15W)
Gas path
• With hoses FPM (e.g. Viton), connections PVDF

• With pipes Stainless steel:


• Pipes: Mat. No. 1.4571
(X6CrNiMoTi 17-12-2)
• Gas connections: Mat. No. 1.4404
(X2CrNiMo 17-12-2)
Hastelloy C22:
• Pipes: Mat. No. 2.4602
(NiCr21Mo14W)
• Gas connections: Mat. No. 2.4819
(NiMo16Cr15W)
Sealing material FPM (e.g. Viton) or FFKM Com-
pound 2035 (e.g. Kalrez 2035 (see
device certificate))
Special applications
Gas path
• With pipes Materials adapted to the application

Siemens PA 01 · 2015 1/25


© Siemens AG 2014

Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7
1 Selection and ordering data Article No.
Analyzer module OXYMAT 7 7MB3020- 7 7 7 7 0 - 7 AA0 Cannot be
For measurement of oxygen combined

Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Integrated into base unit1)
Rack unit 0
Wall-mounted device 1
Reference gas pressure
Low-pressure version 100 hPa (for the connection of an external pump; without pressure switch) A A A
High pressure (3 000 ... 5 000 hPa) (absolute pressure values) C
High pressure (3 000 ... 5 000 hPa) (absolute pressure values), with pressure switch D
Smallest measuring range Largest measuring range
0 ... 0.5 % 0 ... 100 % B B
0 ... 1 % 0 ... 100 % C C
0 ... 2 % 0 ... 100 % D
0 ... 5 % 0 ... 100 % E
Gas path
Material of gas path Material of sample chamber Temperature of analysis part
Hose made of FKM (Viton) Stainless steel (1.4571) 72 °C (thermostatted) 0
Pipe made of stainless steel (1.4571) Stainless steel (1.4571) 72 °C (thermostatted) 2 2
Vibration compensation
Without 0
With 1
1)
With order code "W01", please specify option "0".

Selection and ordering data


Additional versions Order code
Add "-Z" to Article No. and specify Order code
Delivery
Supplied separately W01
Integrated into the base unit pos. no. ... (plain text); slot 1 (see dimensional drawing) Y01
Integrated into the base unit pos. no. ... (plain text); slot 2 (see dimensional drawing) Y02
Settings
Measuring range data in plain text, if different from the standard setting Y11

Ordering examples
OXYMAT 7 module in rack unit enclosure "Example1"
7MB3000-0DX00-2AA0-Z + Y01 "Example1"
7MB3020-0AD00-0AA0-Z + Y01 "Example1"
OXYMAT 7 module in wall housing "Example2"
7MB3000-3DX00-2AA0-Z + Y01 "Example2"
7MB3020-0AD00-0AA0-Z + Y01 "Example2"

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Continuous Gas Analyzers, extractive


SIPROCESS GA700
Analyzer module OXYMAT 7

■ Schematics
1
Gas connections

4 3 2 1

1 Sample gas inlet


2 Sample gas outlet
3 N.C., bypass outlet for version with internal and external reference gas pump
4 Reference gas inlet

Version with pipes


The gas connections are equipped with screw-in glands
(ISO female thread 1/8"). This ensures that threaded joints
can be used for pipes with a diameter of 1/4" and also with a
diameter of 6 mm.
The external gas lines are screwed on to the sample gas inlet (1),
sample gas outlet (2) and reference gas inlet.
Version with hoses
The gas connections consist of PVDF. Tubes made of FPM (e.g.
Viton) or of PTFE (Teflon) with an inner diameter of 4 mm and wall
thickness of 1 mm can be connected to the gas connections.
The tubes are fastened with the screw cap of the PVDF screwed
gland.
The reference gas connection is a screw connection as with the
piped version (see above).

Siemens PA 01 · 2015 1/27


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
1 ■ Overview ■ Benefits
• AUTOCAL with ambient air (dependent on the measured
component)
Highly cost effective because calibration gases are not
required
• High selectivity thanks to multi-layer detectors, e.g. low
cross-sensitivity to water vapor
• Sample chambers can be cleaned as required on site
Cost savings due to reuse after contamination
• Menu-assisted operation in plaintext
Operator control without manual, high level of operator safety
• Service information and logbook
Preventive maintenance; help for service and maintenance
personnel, cost savings
• Coded operator level against unauthorized access
Increased safety
• Open interface architecture (RS 485, RS 232, PROFIBUS,
SIPROM GA)
Up to four gas components can be measured simultaneously • Simplified process integration; remote operation and control
with the ULTRAMAT 23 gas analyzer: up to three infrared-active Special benefits when used in biogas plants
gases such as CO, CO2, NO, SO2, CH4, plus O2 with an electro-
chemical oxygen sensor. • Continuous measurement of all four important components,
including H2S
ULTRAMAT 23 basic versions for: • Long service life of the H2S sensor even at increased concen-
• 1 infrared gas component with/without oxygen measurement trations; no diluting or backflushing necessary
• 2 infrared gas components with/without oxygen measurement • Introduction and measurement of flammable gases as
• 3 infrared gas components with/without oxygen measurement occurring in biogas plants (e.g. 70 % CH4), is permissible
(TÜV certificate)
• With the ULTRAMAT 23 gas analyzer for use in biogas plants,
up to four gas components can be measured continuously:
two infrared-sensitive gases (CO2 and CH4), plus O2 and H2S
with electrochemical measuring cells.
• With the ULTRAMAT 23 gas analyzer with paramagnetic
oxygen cell, up to four gas components can be measured
continuously: three infrared-active gases, plus O2 ("dumbbell"
measuring cell).

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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information

■ Application
1
Areas of application Special versions
• Optimization of small firing systems • Separate gas paths
• Monitoring of exhaust gas concentration from firing systems The ULTRAMAT 23 with 2 IR components without pump is
with all types of fuel (oil, gas and coal) as well as operational also available with two separate gas paths. This allows the
measurements with thermal incineration plants measurement of two measuring points as used e.g. for the
NOx measurement before and after the NOx converter.
• Room air monitoring The ULTRAMAT 23 gas analyzer can be used in emission
• Monitoring of air in fruit stores, greenhouses, fermenting measuring systems and for process and safety monitoring.
cellars and warehouses • TÜV version/QAL/MCERTS
• Monitoring of process control functions TÜV-approved versions of the ULTRAMAT 23 are available for
• Atmosphere monitoring during heat treatment of steel measurement of CO, NO, SO2 and O2 according to
13th BlmSchV/27th BlmSchV/30th BImSchV (N2O)
• For use in non-potentially-explosive atmospheres and TA Luft.
Application areas in biogas plants Smallest TÜV-approved and permitted measuring ranges:
- 1- and 2-component analyzer
• Monitoring of fermenters for generating biogas (input and CO: 0 to 150 mg/m3
pure sides) NO: 0 to 100 mg/m3
• Monitoring of gas-driven motors (power generation) SO2: 0 to 400 mg/m3
• Monitoring of feeding of biogas into the commercial gas net- - 3-component analyzer
work CO: 0 to 250 mg/m3
NO: 0 to 400 mg/m3
Application area of paramagnetic oxygen sensor SO2: 0 to 400 mg/m3
• Flue gas analysis All larger measuring ranges are also approved.
• Inerting plants
Furthermore, the TÜV-approved versions of the ULTRAMAT 23
• Room air monitoring comply with the requirements of EN 14956 and QAL 1 accord-
• Medical engineering ing to EN 14181. Conformity of the analyzers with both stan-
dards is TÜV-certified.
Further applications
• Environmental protection Determination of the analyzer drift according to EN 14181
(QAL 3) can be carried out manually or with a PC using the
• Chemical plants SIPROM GA maintenance and servicing software. In addition,
• Cement industry selected manufacturers of emission evaluation computers of-
fer the possibility for downloading the drift data via the ana-
lyzer’s serial interface and to automatically record and process
it in the evaluation computer.
• Version with reduced response time
The connection between the two condensation traps is
equipped with a stopper to lead the complete flow through the
measuring cell (otherwise only 1/3 of the flow), i.e. the re-
sponse time is 2/3 faster. The functions of all other compo-
nents remain unchanged
• Chopper compartment flushing: consumption 100 ml/min
(upstream pressure: approx. 3 000 hPa)

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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
1 ■ Design
• 19" rack unit with 4 HU for installation Inputs/outputs
- in hinged frame • Three binary inputs for sample gas pump On/Off, triggering of
- in cabinets, with or without telescopic rails AUTOCAL and synchronization of several devices
• Flow indicator for sample gas on front plate; • Eight relay outputs can be freely configured for fault, mainte-
option: integrated sample gas pump (standard for bench-top nance request, maintenance switch, limits, measuring range
version) identification and external solenoid valves
• Gas connections for sample gas inlet and outlet as well as • Eight additional binary inputs and relay outputs as an option
zero gas; pipe diameter 6 mm or ¼"
• Galvanically isolated analog outputs
• Gas and electrical connections at the rear (portable version:
sample gas inlet at front) Communication
Display and control panel RS 485 present in basic unit (connection from the rear).
• Operation based on NAMUR recommendation Options
• Simple, fast parameterization and commissioning of analyzer • RS 485/RS 232 converter
• Large, backlit LCD for measured values • RS 485/Ethernet converter
• Menu-driven inputs for parameterization, test functions and • RS 485/USB converter
calibration • Incorporation in networks via PROFIBUS DP/PA interface
• Washable membrane keyboard • SIPROM GA software as service and maintenance tool
• User help in plain text
• 6-language operating software

LED backlit display; Dimension freely selectable


brightness adjustable via menu (ppm, vpm, %, mg/m3)

One line per component for Two columns reserved


measured value, dimension for status displays
and component name

Immediate return to ENTER key to call the


measurement mode main menu or to save
entered values
CAL key to start AUTOCAL
with ambient air or N2 ↑↓ → Keys for menu control;
or air without CO2 increasing/decreasing numerical values
Switch internal pump on and off; Scroll back in menu or
pump flowrate adjustable via menu cancel an input

ULTRAMAT 23, membrane keyboard and graphic display

1/30 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
Designs – parts wetted by sample gas 1
Gas path 19" rack unit Desktop unit
With hoses Condensation trap/gas inlet - PA (polyamide)
Condensation trap - PE (polyethylene)
Gas connections 6 mm PA (polyamide) PA (polyamide)
Gas connections ¼" Stainless steel, mat. no. 1.4571 Stainless steel, mat. no. 1.4571
Hose FPM (Viton) FPM (Viton)
Pressure switch FPM (Viton) + PA6-3-T (Trogamide) FPM (Viton) + PA6-3-T (Trogamide)
Flowmeter PDM/Duran glass/X10CrNiTi1810 PDM/Duran glass/X10CrNiTi1810
Elbows/T-pieces PA6 PA6
Internal pump, option PVDF/PTFE/EPDM/FPM/Trolene/ PVDF/PTFE/EPDM/FPM/Trolene/
stainless steel, mat. no. 1.4571 stainless steel, mat. no. 1.4571
Solenoid valve FPM70/Ultramide/ stainless steel, mat. FPM70/Ultramide/ stainless steel, mat.
no. 1.4310/1.4305 no. 1.4310/1.4305
Safety condensation trap PA66/NBR/PA6 PA66/NBR/PA6
Analyzer chamber
• Body Aluminum Aluminum
• Lining Aluminum Aluminum
• Fitting Stainless steel, mat. no. 1.4571 Stainless steel, mat. no. 1.4571
• Window CaF2 CaF2
• Adhesive E353 E353
• O-ring FPM (Viton) FPM (Viton)
With pipes, only Gas connections 6 mm / ¼" Stainless steel, mat. no. 1.4571
available in version
"without pump" Pipes Stainless steel, mat. no. 1.4571
Analyzer chamber
• Body Aluminum
• Lining Aluminum
• Fitting Stainless steel, mat. no. 1.4571
• Window CaF2
• Adhesive E353
• O-ring FPM (Viton)

Siemens PA 01 · 2015 1/31


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
1
ULTRAMAT 23 also available as bench-top unit:
● 2 handles on top cover
● 4 rubber feet for setting up
● No mounting frame

80-digit display Dust-tight and washable


(4 lines/20 characters) membrane keypad

Flowmeter in conjunction with


Also available pressure switch for monitoring
with slide rails the sample gas flow
Gas and electrical
connections on rear
panel (portable version
simple gas at front)

Control keys Optional O2 sensor,


for menus removable from front

3 function keys for


measurement, pump On/Off
and AUTOCAL

ULTRAMAT 23, design

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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
Gas path 1
Legend for the gas path figures
1 Inlet for sample gas/calibration gas 10 Solenoid valve
2 Gas outlet 11 Sample gas pump
3 Inlet for AUTOCAL/zero gas or 12 Pressure switch
inlet for sample gas/calibration gas (channel 2)
13 Flow indicator
4 Gas outlet (channel 2) 14 Analyzer unit
5 Enclosure flushing 15 Safety condensation trap
6 Inlet of atmospheric pressure sensor 16 Oxygen sensor (electrochemical)
7 Inlet of chopper compartment flushing 17 Atmospheric pressure sensor
8 Condensation trap with filter 18 Hydrogen sulfide sensor
9 Safety fine filter 19 Oxygen measuring cell (paramagnetic)

8
Gas outlet
12 2
13 P 10
F 11

Zero gas
3
14

15

16 with O2

2 Enclosure
without O2
15 5 flushing

17
9
P Chopper
compartment
7
flushing

ULTRAMAT 23, portable, in sheet-steel housing with internal sample gas pump, condensation trap with safety filter on front plate, optional oxygen
measurement

Siemens PA 01 · 2015 1/33


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
1
13
12 9
F P Gas inlet
11 10 1
Gas outlet
9 2
Zero gas
14 3
not used
4
Enclosure
5 flushing
Inlet atmospheric
9 6 pressure sensor
Chopper
15 7 purge

16 with O2

2 without O2

15

17
P

ULTRAMAT 23, 19" rack unit enclosure with internal sample gas pump, optional oxygen measurement

13
12
F P 9

Gas inlet
1
Gas outlet
14 2
not used
3
not used
4
Enclosure
5 flushing
Inlet atmospheric
9 pressure sensor
15 6
Chopper
purge
7
16 with O2

2 without O2

15

17
P

ULTRAMAT 23, 19" rack unit enclosure without internal sample gas pump, optional oxygen measurement

1/34 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information

13
1
12
F P 9
Gas inlet 1
14 1

15
16
with O2
2
15 without O2
13
12
P Gas outlet 1
F 9 2
Gas inlet 2
3
14

15

15 Gas outlet 2
4
Enclosure
5 flushing
17
Inlet atmospheric
P pressure sensor
9 6
Chopper
7 purge

ULTRAMAT 23, 19" rack unit enclosure without internal sample gas pump, with separate gas path for the 2nd measured component or for the 2nd and
3rd measured components, optional oxygen measurement

Gas inlet 1
1
14

Gas outlet 1
2
Gas inlet 2
3
14

Gas outlet 2
4
Enclosure flushing
5
Inlet atmospheric
pressure sensor
9 6
Chopper
purge
7

17
P

ULTRAMAT 23, 19" rack unit enclosure, sample gas path version in pipes, optional separate gas path, always without sample gas pump, without safety
filter and without safety condensation trap

Siemens PA 01 · 2015 1/35


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
1
13
12 9
F P Sample/calibration gas
11 10 1 inlet
Gas outlet
9 2
Zero gas inlet
14 3
Not used
4
Enclosure flushing
5 Inlet of
atmospheric
9 6 pressure sensor
Inlet of chopper
15 compartment
7
flushing (option)
18
16 ž›GvY

2 ž›–œ›GvY

15

17
P

ULTRAMAT 23, 19" rack unit enclosure with internal sample gas pump and H2S sensor

13
12 9
F P Sample/calibration gas
11 10 1 inlet
Gas outlet
9 2
Zero gas inlet
14 3
Not used
4
Enclosure flushing
5 Inlet of
atmospheric
9 6 pressure sensor
Inlet of chopper
15 compartment
7
flushing (option)

19

15

17
P

ULTRAMAT 23, 19" rack unit enclosure with internal sample gas pump and paramagnetic oxygen measurement

1/36 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information

■ Function
1
The ULTRAMAT 23 uses two independent measuring principles
which work selectively. 12
1
Infrared measurement 10
2
The measuring principle of the ULTRAMAT 23 is based on the
molecule-specific absorption of bands of infrared radiation,
which in turn is based on the "single-beam procedure". A radia- 3
tion source (7) operating at 600 C emits infrared radiation, 9
which is then modulated by a chopper (5) at 8 1/3 Hz.
The IR radiation passes through the sample chamber (4), into 11
which sample gas is flowing, and its intensity is weakened as a
function of the concentration of the measured component. 9
Sample gas
The reciever chamber - set up as a two- or three-layer detector -
outlet
is filled with the component to be measured.
The first detector layer (11) primarily absorbs energy from the 4
central sections of the sample gas IR bands. Energy from the pe-
ripheral sections of the bands is absorbed by the second (2) and Sample gas
third (12) detector layers. inlet
The microflow sensor generates a pneumatic connection be- 9
tween the upper layer and the lower layers. Negative feedback
from the upper layer and lower layers leads to an overall narrow-
ing of the spectral sensitivity band. The volume of the third layer
8 5
and, therefore, the absorption of the bands, can be varied using
a "slide switch" (10), thereby increasing the selectivity of each in- 6
dividual measurement.
The rotating chopper (5) generates a pulsating flow in the re- 7
ciever chamber that the microflow sensor (3) converts into an
electrical signal.
The microflow sensor consists of two nickel-plated grids heated 1 Capillary 7 IR source
to approximately 120 ºC, which, along with two supplementary 2 Second detector layer 8 Reflector
resistors, form a Wheatstone bridge. The pulsating flow together 3 Microflow sensor 9 Window
with the dense arrangement of the Ni grids causes a change in 4 Sample cell 10 Slide
5 Chopper wheel 11 First detector layer
resistance. This leads to an offset in the bridge, which is depen-
6 Chopper motor 12 Third detector layer
dent on the concentration of the sample gas.
Note ULTRAMAT 23, principle of operation of the infrared channel (example
with three-layer detector)
The sample gases must be fed into the analyzers free of dust.
Condensation in the sample chambers must be prevented.
Therefore, the use of gas modified for the measuring task is nec-
essary in most application cases.
As far as possible, the ambient air of the analyzer should not
have a large concentration of the gas components to be mea-
sured.

Siemens PA 01 · 2015 1/37


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
1 Automatic calibration with air (AUTOCAL)
The ULTRAMAT 23 can be calibrated using, for example, ambi- 8
ent air. During this process (between 1 and 24 hours (adjust- 8
able), 0 = no AUTOCAL), the chamber is purged with air. The de- ಭ
tector then generates the largest signal U0 (no pre-absorption in 8
the sample chamber). This signal is used as the reference signal
for zero point calibration, and also serves as the initial value for
calculating the full-scale value in the manner described below.
As the concentration of the measured component increases, so
too does absorption in the sample chamber. As a result of this
preabsorption, the detectable radiation energy in the detector
decreases, and thus also the signal voltage. For the single-beam FOHDQ
procedure of the ULTRAMAT 23, the mathematical relationship 8 ಭ
8
between the concentration of the measured component and the FRQWDPLQDWHG
measured voltage can be approximately expressed as the fol-
lowing exponential function:
&RQFHQWUDWLRQ &
U = U0  e-kc
c Concentration Calibration
k Device-specific constant
U0 Basic signal with zero gas (sample gas without measured Oxygen measurement
component)
U Detector signal The oxygen sensor operates according to the principle of a fuel
cell. The oxygen is converted at the boundary layer between the
Changes in the radiation power, contamination of the sample cathode and electrolyte. An electron emission current flows be-
chamber, or aging of the detector components have the same tween the lead anode and cathode and via a resistor, where a
effect on both U0 and U, and result in the following: measured voltage is present. This measured voltage is propor-
tional to the concentration of oxygen in the sample gas.
U’ = U’0  e-kc
The oxygen electrolyte used is less influenced by interference
Apart from being dependent on concentration c, the measured
influences (particularly CO2, CO, H2 and CH4) than other sensor
voltage thus changes continuously as the IR source ages, or
types.
with persistent contamination.
Note: The oxygen sensor can be used for concentrations of both
Each AUTOCAL tracks the total characteristic until the currently
> 1 % and < 1 % O2. In the event of sudden changes from high
valid value, thereby compensating for temperature and pressure
concentrations to low concentrations (< 1 %), the sensor will,
influences.
however, require longer running-in times to get a constant mea-
The influences of contamination and aging, as mentioned sured value. This is to be taken into consideration when switch-
above, will have a negligible influence on the measurement as ing between measuring points in particular, and appropriate
long as U’ remains in a certain tolerance range monitored by the rinsing times are to be set.
unit.
6DPSOHJDV
The tolerance "clamping width" between two or more AUTOCALs
can be individually parameterized on the ULTRAMAT 23 and an
alarm message output. A fault message is output when the value  
falls below the original factory setting of U0 < 50 % U. In most
cases, this is due to the sample chamber being contaminated.
Calibration
 
The units can be set to automatically calibrate the zero point ev-
ery 1 to 24 hours, using ambient air or nitrogen. The calibration
point for the IR-sensitive components is calculated mathemati-
cally from the newly determined U’o and the device-specific pa-
rameters stored as default values. It is recommendable to check
the calibration point once a year using a calibration gas. (For de-
tails on TÜV measurements, see Table "Calibration intervals
(TÜV versions)" under Selection and ordering data).
If an electrochemical sensor is installed, it is recommendable to
use air for the AUTOCAL. In addition to calibration of the zero
point of the IR-sensitive components, it is then also possible to H
simultaneously calibrate the calibration point of the electrochem-
ical O2 sensor automatically. The characteristic of the O2 sensor
is sufficiently stable following the single-point calibration such
that the zero point of the electrochemical sensor needs only be
8
checked once a year by connecting nitrogen. 

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ULTRAMAT 23, principle of operation of the oxygen sensor

1/38 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
Electrochemical sensor for H2S determination Paramagnetic oxygen cell 1
The hydrogen sulfide enters through the diffusion barrier (gas In contrast to other gases, oxygen is highly paramagnetic. This
diaphragm) into the sensor and is oxidized at the working elec- property is used as the basis for the method of measurement.
trode. A reaction in the form of a reduction of atmospheric oxy-
gen takes place on the counter electrode. The transfer of elec- Two permanent magnets generate an inhomogeneous magnetic
trons can be tapped on the connector pins as a current which is field in the measuring cell. If oxygen molecules flow into the
directly proportional to the gas concentration. measuring cell (1), they are drawn into the magnetic field. This
results in the two diamagnetic hollow spheres (2) being dis-
Calibration placed out of the magnetic field. This rotary motion is recorded
optically, and serves as the input variable for control of a com-
The zero point is automatically recalibrated by the AUTOCAL pensation flow. This generates a torque opposite to the rotary
function when connecting e.g. nitrogen or air. It is recommend- motion around the two hollow spheres by means of a wire loop
able to check the calibration point after 3 months using calibra- (3). The compensation current is proportional to the concentra-
tion gas (1 000 to 3 000 vpm). tion of oxygen.
The AUTOCAL (with ambient air, for example) must be per- Calibration
formed every hour. In so doing, the ambient air must be satu-
rated in accordance with a dew point of 11 °C. The calibration point is calibrated with the AUTOCAL function
when processing air (in a similar way to calibration with the elec-
Should this not be constantly guaranteed with dry ambient air, trochemical O2 sensor). In order to comply with the technical
the adjustment gas is to be fed through a moisture vessel and data, the zero point of the paramagnetic measuring cell must be
subsequently through a cooler (dew point 11 °C). calibrated with nitrogen weekly in the case of measuring ranges
The hydrogen sulfide sensor must not be used if the accompa- < 5 % or every two months in the case of larger measuring
nying gas contains the following components: ranges.
• Compounds containing chlorine Alternatively, inert gases (such as nitrogen) can be used for
• Compounds containing fluorine AUTOCAL. As the limit point of the measuring range remains
largely stable, an annual limit point adjustment will suffice.
• Heavy metals
• Aerosols *DVLQOHW
• Alkaline components
• NH3 > 5 vpm

H2S H 2S
H 2S H 2S 

Gas diaphragm 
Working electrode 
Reference electrode 
H2SO4 electrolyte

Counterelectrode
Connection pins

Operating principle of the H2S sensor


*DVRXWOHW

Operating principle of the paramagnetic oxygen cell

Siemens PA 01 · 2015 1/39


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
General information
1 Cross-interferences, paramagnetic oxygen cells
Accompanying gas Formula Deviation Deviation Accompanying gas Formula Deviation Deviation
at 20 °C at 50 °C at 20 °C at 50 °C

Acetaldehyde C2H4O -0.31 -0.34 Nitrogen dioxide NO2 5 16

Acetone C3H6O -0.63 -0.69 Nitrogen monoxide NO 42.7 43

Acetylene, ethyne C2H2 -0.26 -0.28 Styrene C8H8 -1.63 -1.8

Ammonia NH3 -0.17 -0.19 Toluene C7H8 -1.57 -1.73

Argon Ar -0.23 -0.25 Vinyl chloride C2H3Cl -0.68 -0.74

Benzene C6H6 -1.24 -1.34 Vinyl fluoride C2H3F -0.49 -0.54

Bromine Br2 -1.78 -1.97 Water (vapor) H2O -0.03 -0.03

Butadiene C4H6 -0.85 -0.93 Hydrogen H2 0.23 0.26

n-butane C4H10 -1.1 -1.22 Xenon Xe -0.95 -1.02

Iso-butylene C4H8 -0.94 -1.06 Cross-sensitivities (with accompanying gas concentration 100 %)

Chlorine Cl2 -0.83 -0.91 ULTRAMAT 23 essential characteristics


• Practically maintenance-free thanks to AUTOCAL with ambi-
Diacetylene C4H2 -1.09 -1.2
ent air (or with N2, only for units without an oxygen sensor);
Dinitrogen monoxide N2O -0.2 -0.22 both the zero point and the sensitivity are calibrated in the pro-
cess
Ethane C2H6 -0.43 -0.47
• Calibration with calibration gas only required every twelve
Ethyl benzene C8H10 -1.89 -2.08 months, depending on the application
Ethylene, ethene C2H4 -0.2 -0.22 • Two measuring ranges per component can be set within
specified limits;
Ethylene glycol C2H6O2 -0.78 -0.88 all measuring ranges linearized;
autoranging with measuring range identification
Ethylene oxide C2H4O -0.54 -0.6
• Automatic correction of variations in atmospheric pressure
Furan C4H4O -0.9 -0.99
• Sample gas flow monitoring;
Helium He 0.29 0.32 error message output if flow < 1 l/min
(only with Viton sample gas path)
n-hexane C6H14 -1.78 -1.97
• Maintenance request alert
Hydrogen chloride, HCl -0.31 -0.34 • Two freely configurable undershooting or overshooting limit
hydrochloric acid values per measured component
Hydrogen fluoride, HF 0.12 0.14
hydrofluoric acid
Carbon dioxide CO2 -0.27 -0.29
Carbon monoxide CO -0.06 -0.07
Krypton Kr -0.49 -0.54
Methane CH4 -0.16 -0.17
Methanol CH4O -0.27 -0.31
Methylene chloride CH2Cl2 -1 -1.1
Monosilane, silane SiH4 -0.24 -0.27
Neon Ne 0.16 0.17
n-octane C8H18 -2.45 -2.7
Phenol C6H6O -1.4 -1.54
Propane C3H8 -0.77 -0.85
Propylene, propene C3H6 -0.57 -0.62
Propylene chloride C3H7Cl -1.42 -1.44
Propylene oxide C3H6O -0.9 -1
Oxygen O2 100 100
Sulfur dioxide SO2 -0.18 -0.2
Sulfur hexafluoride SF6 -0.98 -1.05
Hydrogen sulfide H2S -0.41 -0.43
Nitrogen N2 0 0

1/40 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version

■ Technical specifications
1
General information Gas inlet conditions
Measured components Maximum of 4, comprising three Sample gas pressure
infrared-sensitive gases and oxy- • Without pump Unpressurized (< 1 200 hPa,
gen absolute)
Measuring ranges Two per measured component • With pump Depressurized suction mode, set
Display LCD with LED backlighting and in factory with 2 m hose at sample
contrast control; function keys; gas outlet; full-scale value cali-
80 characters (4 lines/20 charac- bration necessary under different
ters) venting conditions
(800 ... 1 050 hPa, absolute)
Operating position Front wall, vertical
Sample gas flow 72 … 120 l/h (1.2 … 2 l/min)
Conformity CE symbol EN 61000-6-2,
EN 61000-6-4 Sample gas temperature Min. 0 to max. 50 °C, but above
the dew point
Design, enclosure
Sample gas humidity < 90 % RH (relative humidity),
Weight Approximately 10 kg non-condensing
Degree of protection, 19" rack unit IP20 according to EN 60529
and desktop model Technical data, infrared channel
Electrical characteristics So that the technical data can be complied with, a cycle time of
 24 hours must be activated for the AUTOCAL. The cycle time of the
EMC In accordance with standard AUTOCAL function must be  6 hours when measuring small NO and
(Electromagnetic Compatibility) requirements of NAMUR NE21 SO2 measuring ranges ( 400 mg/m³) on TÜV/QAL-certified systems.
(safety extra-low voltage (SELV) (08/98) or EN 50081-1,
with safety isolation) EN 50082-2 Measuring ranges See ordering data
Power supply 100 V AC, +10 %/-15 %, 50 Hz, Chopper compartment flushing Upstream pressure approximately
120 V AC, +10 %/-15 %, 50 Hz, 3 000 hPa; purging gas con-
sumption approximately
200 V AC, +10 %/-15 %, 50 Hz, 100 ml/min
230 V AC, +10 %/-15 %, 50 Hz,
Time response
100 V AC, +10 %/-15 %, 60 Hz,
Warm-up period Approximately 30 min (at room
120 V AC, +10 %/-15 %, 60 Hz, temperature) (the technical speci-
230 V AC, +10 %/-15 %, 60 Hz fication will be met after 2 hours)
Power consumption Approx. 60 VA Delayed display (T90 time) Dependent on length of analyzer
chamber, sample gas line and
Electrical inputs and outputs parameterizable attenuation
Analog output Per component, 0/2/4 up to Attenuation(electrical time constant) Parameterizable from 0 … 99.9 s
20 mA, NAMUR, isolated,
max. load 750  Measuring response
(relating to sample gas pressure 1 013 hPa absolute, 1.0 l/min sample
Relay outputs 8, with changeover contacts, gas flow and 25 °C ambient temperature)
freely parameterizable, e.g. for
measuring range identification; Output signal fluctuation <  1 % of the current measuring
24 V AC/DC/1 A load, potential- range (see rating plate)
free, non-sparking Detection limit 1 % of the current measuring
Digital inputs 3, dimensioned for 24 V, potential- range
free Linearity error • In largest possible measuring
• Pump range:
<  1 % of the full-scale value
• AUTOCAL • In smallest possible measuring
• Synchronization range:
<  2 % of the full-scale value
Serial interface RS 485
Repeatability   1 % of the current measuring
AUTOCAL function Automatic unit calibration with range
ambient air (depending on mea-
sured component); adjustable Drift
cycle time from 0 (1) … 24 hours Zero point
Options Add-on electronics, each with 8 • With AUTOCAL Negligible
additional digital inputs and relay
outputs for e.g. triggering of auto- • Without AUTOCAL < 2 % of the current measuring
matic calibration and for range/week
PROFIBUS PA or PROFIBUS DP
Full-scale value drift
Climatic conditions
• With AUTOCAL Negligible
Permissible ambient temperature
• Without AUTOCAL < 2 % of the current measuring
• During operation 5 … 45 °C range/week
• During storage and transportation -20 ... +60 °C
Permissible ambient humidity < 90 % RH (relative humidity) dur-
ing storage and transportation
Permissible pressure fluctuations 600 … 1 200 hPa

Siemens PA 01 · 2015 1/41


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1 Influencing variables Technical data, H2S channel for measuring ranges of 5 ... 50 vpm
(relating to sample gas pressure 1 013 hPa absolute, 1.0 l/min sample
gas flow and 25 °C ambient temperature) Measured components Maximum of 4, comprising 1 or 2
infrared-sensitive gases, 1 oxy-
Temperature Max. 2 % of the smallest possible gen component and 1 hydrogen
measuring range according to sulfide component
rating plate per 10 K with an
AUTOCAL cycle time of 6 h Measuring ranges
Atmospheric pressure < 0.2 % of the current measuring • Smallest measuring range 0 ... 5 vpm
range per 1 % pressure variation • Largest measuring range 0 ... 50 vpm
Power supply < 0.1 % of the current measuring Service life of the sensor Approx. 12 months
range with a change of  10 %
Permissible atmospheric pressure 750 ... 1 200 hPa
Technical data, oxygen channel (electrochemical) Permissible operating temperature 5 ... 40 °C (41 ... 104 °F)
Measuring ranges 0 … 5 % … 0 … 25 % O2, Operating mode Continuous measurement
parameterizable between 0 and 12.5 vpm
Service life Approximately 2 years at 21 % Discontinuous measurement
O2; continuous duty < 0.5 % O2 between 12.5 and 50 vpm
will destroy the measuring cell Influencing variables
Detection limit 1 % of the current measuring Carrier gases The hydrogen sulfide sensor must
range not be used if the accompanying
Time response gas contains the following com-
ponents:
Delayed display (T90 time) Dependent on dead time and
parameterizable attenuation, not • Compounds containing chlorine
> 30 s at approximately 1.2 l/min • Compounds containing fluorine
sample gas flow • Heavy metals
Measuring response • Aerosols
(relating to sample gas pressure 1 013 hPa absolute, 1.0 l/min sample
• Alkaline components
gas flow and 25 °C ambient temperature)
(e.g. NH3 > 5 %)
Output signal fluctuation <  0.5 % of the current measur-
ing range Cross-inferences 1 360 vpm SO2 result in a cross-
(interfering gases) interference of < 20 vpm H2S
Linearity error <  0.2 % of the current measur-
ing range 180 vpm NO result in a cross-
interference of < 150 vpm H2S
Repeatability  0.05 % O2
No cross-interference of CH4,
Drift CO2 and H2 (1 000 vpm)
• With AUTOCAL Negligible
Drift < 1 % of the current measuring
• Without AUTOCAL 1 % O2/year in air, typical range per month
Influencing variables Temperature < 3 %/10 K relating to full-scale
(relating to sample gas pressure 1 013 hPa absolute, 1.0 l/min sample value
gas flow and 25 °C ambient temperature)
Atmospheric pressure < 0.2 % of the measured value
Temperature <  0.5 % O2 per 20 K, relating to per 1 % pressure variation
a measured value at 20 °C
Measuring response
Atmospheric pressure < 0.2 % of the measured value
per 1 % pressure variation Delayed display (T90 time) < 40 s with sample gas flow of
Carrier gases The oxygen sensor must not be approx. 1 ... 1.2 l/min
used if the accompanying gas
Output signal noise < 2 % of smallest measuring
contains the following compo-
range with an attenuation con-
nents: Chlorine or fluorine com-
stant of 30 s
pounds, heavy metals, aerosols,
mercaptans, alkaline components Display resolution < 0.01 vpm H2S
(such as NH3 in % range)
Typical combustion exhaust gases Influence: < 0.05 % O2 Output signal resolution < 1 % of smallest measuring
range with an attenuation con-
Humidity H2O dew point  2 °C; the oxygen stant of 30 s
sensor must not be used with dry
sample gases (however, no con- Repeatability < 4 % of smallest measuring
densation either) range

1/42 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version

Technical data, H2S channel for measuring ranges of 0 ... 5 000 vpm Technical data, paramagnetic oxygen cell
1
Measured components Maximum of 4, comprising 1 or 2 Measured components Maximum of 4, comprising up to 3
infrared-sensitive gases, 1 oxy- infrared-sensitive gases and an
gen component and 1 hydrogen oxygen component
sulfide component
Measuring ranges 2 per component
Measuring ranges of H2S sensor
MB 5000 • Min. 0 ... 2 % vol O2
• Smallest measuring range 0 ... 5 000 vpm • Max. 0 ... 100 % vol O2
• Suppressed measuring range
• Largest measuring range 0 ... 5 000 vpm possible; e.g. 95 ... 100 %
Service life of the sensor Approx. 12 months
Permissible atmospheric pressure 700 ... 1 200 hPa
Permissible atmospheric pressure 750 ... 1 200 hPa
Permissible operating temperature 5 ... 45 °C (41 ... 113 °F)
Permissible operating temperature 5 ... 40 °C (41 ... 104 °F)
Influencing variables Cross-inferences (interfering gases) See Table "Cross-sensitivities"
Zero point drift • Measuring range 2 %: max.
Carrier gases The hydrogen sulfide sensor must 0.1 % with weekly zero adjust-
not be used if the accompanying ment
gas contains the following com-
ponents: • Measuring range 5 %: max.
0.1 % with weekly zero adjust-
• Compounds containing chlorine ment
• Compounds containing fluorine • Measuring range 25 % or
• Heavy metals greater:
• Aerosols max. 0.5 % with monthly zero
adjustment
• Alkaline components
(e.g. NH3 > 5 vpm) Measured-value drift Negligible with AUTOCAL
Cross-inferences 100 ppm SO2 result in a cross- Temperature error < 2 %/10 K referred to measuring
(interfering gases) interference of < 30 ppm H2S range 5 %
Drift < 1 % of the current measuring < 5 %/10 K referred to measuring
range per month range 2 %

Temperature < 3 %/10 K relating to full-scale Humidity error for N2 with 90 % rela- < 0.6 % at 50 °C
value tive humidity after 30 min

Atmospheric pressure < 0.2 % of the measured value Atmospheric pressure < 0.2 % of measured value
per 1 % pressure variation per 1 % pressure variation
Measuring response Delayed display (T90 time) < 60 s
Delayed display (T90 time) < 80 s with sample gas flow of Output signal noise < 1 % of smallest measuring
approx. 1 ... 1.2 l/min range
Output signal noise < 15 ppm H2S Repeatability < 1 % of smallest measuring
range
Display resolution < 0.2 % of the full-scale value
Output signal resolution < 30 ppm H2S
Repeatability < 4 % referred to full-scale value

Siemens PA 01 · 2015 1/43


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Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1 Selection and ordering data Article No.
ULTRAMAT 23 gas analyzer 7MB2335- 7 7 7 7 7 - 7 A A 7 Cannot be
For measuring 1 infrared component, oxygen and hydrogen sulfide combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Enclosure, version and gas paths
19" rack unit for installation in cabinets
Gas connections Gas path Internal sample gas pump
6 mm pipe Viton Without2) 0
¼" pipe Viton Without2) 1
6 mm pipe Viton With 2
¼" pipe Viton With 3
6 mm pipe Stainless steel, mat. no. 1.4571 Without2) 6 6 6
¼" pipe Stainless steel, mat. no. 1.4571 Without2) 7 7 7
Portable, in sheet steel enclosure, 6 mm gas connections, Viton gas path, 8 8 8 8 E20
with integrated sample gas pump, condensation trap with safety filter on the front plate
Measured component Possible with measuring range identification
CO D, E, F, G ... R, U, X A
CO21) D6), G6), H6), J6), K ... R C
CH4 E, H, L, N, P, R D
C2H4 K F
C6H14 K M
SO2 B10), F ... L, W N
NO E, G ... J, T, V, W P
N2O7) E S
SF6 H V
Smallest measuring range Largest measuring range
0 ... 200 mg/m3 0 ... 1 000 mg/m3 B
0 ... 50 vpm 0 ... 250 vpm D
0 ... 100 vpm 0 ... 500 vpm E
0 ... 150 vpm 0 ... 750 vpm F
0 ... 200 vpm 0 ... 1 000 vpm G
0 ... 500 vpm 0 ... 2 500 vpm H
0 ... 1 000 vpm 0 ... 5 000 vpm J
0 ... 2 000 vpm 0 ... 10 000 vpm K
0 ... 0.5 % 0 ... 2.5 % L
0 ... 1 % 0 ... 5 % M
0 ... 2 % 0 ... 10 % N N
0 ... 5 % 0 ... 25 % P P
0 ... 10 % 0 ... 50 % Q
0 ... 20 % 0 ... 100 % R

}
0 ... 100 mg/m³ 0 ... 750 mg/m³ T
0 ... 150 mg/m³ 0 ... 750 mg/m³ U
TÜV version
0 ... 250 mg/m³ 0 ... 1 250 mg/m³ V
0 ... 400 mg/m³ 0 ... 2 000 mg/m³ W
0 ... 50 vpm 0 ... 2 500 vpm X
Oxygen measurement5)
Without O2 sensor 0
With O2 sensor 1 1
With paramagnetic oxygen measuring cell 8 8 8 8
Hydrogen sulfide measurement
Without 0
With H2S sensor 0 ... 5/50 ppm 1 1 1 1
With H2S sensor 0 ... 5 000 ppm 3 3 3 3
Power supply
100 V AC, 50 Hz 0
120 V AC, 50 Hz 1
200 V AC, 50 Hz 2
230 V AC, 50 Hz 3
100 V AC, 60 Hz 4
120 V AC, 60 Hz 5
230 V AC, 60 Hz 6
Operating software, documentation3)
German 0
English 1
French 2
Spanish 3
Italian 4
Footnotes: See next page.

1/44 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version

Selection and ordering data


1
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Add-on electronics with 8 digital inputs/outputs, PROFIBUS PA interface A12
Add-on electronics with 8 digital inputs/outputs, PROFIBUS DP interface A13
Telescopic rails (2 units), 19" rack unit version only A31
TAG labels (specific lettering based on customer information) B03
Gas path for short response time9) C01
Chopper compartment purging for 6 mm gas connection C02
Chopper compartment purging for ¼" gas connection C03
Presetting to reference temperature 0 °C for conversion into mg/m³, applies to all components D15
Certificate FM/CSA Class I, Div. 2, ATEX II 3 G E20
Calibration interval 5 months (TÜV/QAL), measuring CO: 0 ... 150/750 mg/m³ E50
ranges: NO: 0 ... 100/750 mg/m³
Measuring range indication in plain text4) Y11
Measurement of CO2 in forming gas8) (only in conjunction with measuring range 0 to 20/0 to 100 %) Y14
Accessories Article No.
CO2 absorber cartridge 7MB1933-8AA
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
Add-on electronics with 8 digital inputs/outputs and PROFIBUS PA A5E00056834
Add-on electronics with 8 digital inputs/outputs and PROFIBUS DP A5E00057159
Set of Torx screwdrivers A5E34821625

1)
For measuring ranges below 1 %, a CO2 absorber cartridge can be used for setting the zero point (see accessories)
2)
Without separate zero gas input or solenoid valve
3)
User language can be changed
4)
Standard setting: smallest measuring range, largest measuring range
5)
O2 sensor in gas path of infrared measured component 1
6)
With chopper compartment purging (N2 approx. 3 000 hPa required for measuring ranges below 0.1 % CO2),
to be ordered separately (see order code C02 or C03)
7)
Not suitable for use with emission measurements since the cross-sensitivity is too high
8)
CO2 measurement in accompanying gas Ar or Ar/He (3:1); forming gas
9)
Only for version with Viton hose
10)
Not checked for suitability, maximum possible AUTOCAL cycle 6 h, constant ambient conditions (max. deviation ±1 °C (1.8 °F)

Siemens PA 01 · 2015 1/45


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1 Selection and ordering data Article No.
ULTRAMAT 23 gas analyzer 7MB2337- 7 7 7 7 7 - 7 7 7 7 Cannot be
For measuring 2 infrared components, oxygen and hydrogen sulfide combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Enclosure, version and gas paths
19" rack unit for installation in cabinets
Gas connections Gas paths Internal sample gas
pump
6 mm pipe Viton, not separate Without2) 0
¼" pipe Viton, not separate Without2) 1
6 mm pipe Viton, not separate With 2
¼" pipe Viton, not separate With 3
6 mm pipe Viton, separate Without2) 4 4 A27, A29
¼" pipe Viton, separate Without2) 5 5 A27, A29
6 mm pipe Stainless steel, mat. no. 1.4571, separate Without2) 6 6 6
¼" pipe Stainless steel, mat. no. 1.4571, separate Without2) 7 7 7
Portable, in sheet steel enclosure, 6 mm gas connections, Viton gas path, 8 8 8 8 E20
with integrated sample gas pump, condensation trap with safety filter on the front plate
1. infrared measured component
Measured component Possible with measuring range identification
CO D, E, F, G ... R, U, X A
CO21) D6), G6), H6), J6), K ... R C
CH4 E, H, L, N, P, R D
C2H4 K F
C6H14 K M
SO2 B11), F ... L, W N
NO E, G ... J, T, V, W P
N2O7) E S
SF6 H V
Smallest measuring range Largest measuring range
0 ... 200 mg/m3 0 ... 1 000 mg/m3 B
0 ... 50 vpm 0 ... 250 vpm D
0 ... 100 vpm 0 ... 500 vpm E
0 ... 150 vpm 0 ... 750 vpm F
0 ... 200 vpm 0 ... 1 000 vpm G
0 ... 500 vpm 0 ... 2 500 vpm H
0 ... 1 000 vpm 0 ... 5 000 vpm J
0 ... 2 000 vpm 0 ... 10 000 vpm K
0 ... 0.5 % 0 ... 2.5 % L
0 ... 1 % 0 ... 5 % M
0 ... 2 % 0 ... 10 % N N
0 ... 5 % 0 ... 25 % P P
0 ... 10 % 0 ... 50 % Q
0 ... 20 % 0 ... 100 % R

}
0 ... 100 mg/m³ 0 ... 750 mg/m³ T
0 ... 150 mg/m³ 0 ... 750 mg/m³ U
TÜV version
0 ... 250 mg/m³ 0 ... 1 250 mg/m³ V
0 ... 400 mg/m³ 0 ... 2 000 mg/m³ W
0 ... 50 vpm 0 ... 2 500 vpm X
Oxygen measurement5)
Without O2 sensor 0
With O2 sensor 1 1
With paramagnetic oxygen measuring cell 8 88 8
Hydrogen sulfide measurement
Without 0
With H2S sensor 0 ... 5/50 ppm 1 1 1 1
With H2S sensor 0 ... 5 000 ppm 3 3 3 3
Power supply
100 V AC, 50 Hz 0
120 V AC, 50 Hz 1
200 V AC, 50 Hz 2
230 V AC, 50 Hz 3
100 V AC, 60 Hz 4
120 V AC, 60 Hz 5
230 V AC, 60 Hz 6

1/46 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
Selection and ordering data Article No.
1
ULTRAMAT 23 gas analyzer 7MB2337- 7 7 7 7 7 - 7 7 7 7 Cannot be
For measuring 2 infrared components, oxygen and hydrogen sulfide combined
2. infrared measured component
Measured component Possible with measuring range identification
CO D, E, F, G ... R, U, X A
CO21) D6), G6), H6), J6), K ... R C
CH4 E, H, L, N, P, R D
C2H4 K F
C6H14 K M
SO2 B11), F ... L, W N
NO E, G ... J, T, V, W P
N2O E7), Y10) S
SF6 H V
Smallest measuring range Largest measuring range
0 ... 200 mg/m3 0 ... 1 000 mg/m3 B
0 ... 50 vpm 0 ... 250 vpm D
0 ... 100 vpm 0 ... 500 vpm E
0 ... 150 vpm 0 ... 750 vpm F
0 ... 200 vpm 0 ... 1 000 vpm G
0 ... 500 vpm 0 ... 2 500 vpm H
0 ... 1 000 vpm 0 ... 5 000 vpm J
0 ... 2 000 vpm 0 ... 10 000 vpm K
0 ... 0.5 % 0 ... 2.5 % L
0 ... 1 % 0 ... 5 % M
0 ... 2 % 0 ... 10 % N
0 ... 5 % 0 ... 25 % P
0 ... 10 % 0 ... 50 % Q
0 ... 20 % 0 ... 100 % R

}
0 ... 100 mg/m³ 0 ... 750 mg/m³ T
0 ... 150 mg/m³ 0 ... 750 mg/m³ U
TÜV version
0 ... 250 mg/m³ 0 ... 1 250 mg/m³ V
0 ... 400 mg/m³ 0 ... 2 000 mg/m³ W
0 ... 50 vpm 0 ... 2 500 vpm X
0 ... 500 vpm 0 ... 5 000 vpm Y
Operating software, documentation3)
German 0
English 1
French 2
Spanish 3
Italian 4
Footnotes: See next page.

Siemens PA 01 · 2015 1/47


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1 ■ Selection and ordering data
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Add-on electronics with 8 digital inputs/outputs, PROFIBUS PA interface A12
Add-on electronics with 8 digital inputs/outputs, PROFIBUS DP interface A13
Stainless steel (mat. no. 1.4571) connection pipe, 6 mm, complete with screwed gland A27
(cannot be combined with Viton hose)
Stainless steel (mat. no. 1.4571) connection pipe, ¼", complete with screwed gland A29
(cannot be combined with Viton hose)
Telescopic rails (2 units, 19" rack unit version only) A31
TAG labels (specific lettering based on customer information) B03
Gas path for short response time9) C01
Chopper compartment purging for 6 mm gas connection C02
Chopper compartment purging for ¼" gas connection C03
Application with paramagnetic oxygen measuring cell and separate gas path C11
Presetting to reference temperature 0 °C for conversion into mg/m³, applies to all components D15
Measuring range indication in plain text4) Y11
Certificate FM/CSA Class I, Div. 2, ATEX II 3 G E20
Calibration interval 5 months (TÜV/QAL), measuring ranges: CO: 0 ... 150/750 mg/m³ E50
NO: 0 ... 100/750 mg/m³
Measurement of CO2 in forming gas8) Y14
(only in conjunction with measuring range 0 to 20/0 to 100 %)
Accessories Article No.
CO2 absorber cartridge 7MB1933-8AA
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
Add-on electronics with 8 digital inputs/outputs and PROFIBUS PA A5E00056834
Add-on electronics with 8 digital inputs/outputs and PROFIBUS DP A5E00057159
Set of Torx screwdrivers A5E34821625

1)
For measuring ranges below 1 %, a CO2 absorber cartridge can be used for setting the zero point (see accessories)
2)
Without separate zero gas input or solenoid valve
3)
User language can be changed
4)
Standard setting: smallest measuring range, largest measuring range
5)
O2 sensor in gas path of infrared measured component 1
6)
With chopper compartment purging (N2 approx. 3 000 hPa required for measuring ranges below 0.1 % CO2),
to be ordered separately (see order code C02 or C03)
7)
Not suitable for use with emission measurements since the cross-sensitivity is too high
8)
CO2 measurement in accompanying gas Ar or Ar/He (3:1); forming gas
9)
Only for version with Viton hose
10)
Only in conjunction with CO2 measuring range 0 to 5 % to 0 to 25 % (CP)
11)
Not checked for suitability, maximum possible AUTOCAL cycle 6 h, constant ambient conditions (max. deviation ±1 °C (1.8 °F)

1/48 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version

Selection and ordering data Article No.


1
ULTRAMAT 23 gas analyzer 7MB2338- 7 7 7 7 0 - 7 7 7 7 Cannot be
for measuring 3 infrared components and oxygen combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Enclosure, version and gas paths
19" rack unit for installation in cabinets
Gas connections Gas paths Internal sample gas pump
6 mm pipe Viton, not separate Without2) 0
¼" pipe Viton, not separate Without2) 1
6 mm pipe Viton, not separate With 2
¼" pipe Viton, not separate With 3
6 mm pipe Viton, separate Without2) 4 4 A27, A29
¼" pipe Viton, separate Without2) 5 5 A27, A29
6 mm pipe Stainless steel, mat. no. 1.4571, Without2) 6 6
separate
¼" pipe Stainless steel, mat. no. 1.4571, Without2) 7 7
separate
Portable, in sheet steel enclosure, 6 mm gas connections, Viton gas path, 8 8 E20
with integrated sample gas pump, condensation trap with safety filter on the front plate
1. and 2nd infrared measured components
Measured component Smallest measuring range Largest measuring range
CO 0 ... 500 vpm 0 ... 2 500 vpm AA
NO 0 ... 500 vpm 0 ... 2 500 vpm
CO 0 ... 2 000 vpm 0 ... 10 000 vpm AB
NO 0 ... 1 000 vpm 0 ... 5 000 vpm
CO 0 ... 1 000 vpm 0 ... 5 000 vpm AC
NO 0 ... 1 000 vpm 0 ... 5 000 vpm
CO 0 ... 1 % 0 ... 5 % AD
NO 0 ... 1 000 vpm 0 ... 5000 vpm
CO 0 ... 250 mg/m³ 0 ... 1 250 mg/m³ AK
TÜV version
NO 0 ... 400 mg/m³ 0 ... 2 000 mg/m³
CO 0 ... 10 % 0 ... 50 % BA
CO2 0 ... 10 % 0 ... 50 %
CO 0 ... 10 % 0 ... 50 % BB
CO2 0 ... 0,5 % 0 ... 2,5 %
CO 0 ... 20 % 0 ... 100 % BD
CO2 0 ... 20 % 0 ... 100 %
CO2 0 ... 5 % 0 ... 25 % BJ
CO 0 ... 100 vpm 0 ... 500 vpm
CO2 0 ... 10 % 0 ... 50 % BK
CO 0 ... 0.5 % 0 ... 2.5 %
CO2 0 ... 5 % 0 ... 25 % BL
CO12) 0 ... 75 mg/m³ 0 ... 750 mg/m³
CO2 0 ... 5 % 0 ... 25 % CA
CH4 0 ... 1 % 0 ... 5 %
CO2 0 ... 5 % 0 ... 25 % CB
CH4 0 ... 2 % 0 ... 10 %
CO2 0 ... 5 % 0 ... 25 % DC
NO 0 ... 500 vpm 0 ... 2 500 vpm
Oxygen measurement5)
Without O2 sensor 0
With O2 sensor 1 1
With paramagnetic oxygen measuring cell 8 88
Power supply
100 V AC, 50 Hz 0
120 V AC, 50 Hz 1
200 V AC, 50 Hz 2
230 V AC, 50 Hz 3
100 V AC, 60 Hz 4
120 V AC, 60 Hz 5
230 V AC, 60 Hz 6
Footnotes: See page 1/51.

Siemens PA 01 · 2015 1/49


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1 Selection and ordering data Article No.
ULTRAMAT 23 gas analyzer 7MB2338- 7 7 7 7 0 - 7 7 7 7 Cannot be
for measuring 3 infrared components and oxygen combined
3. infrared measured component
Measured component Possible with measuring range identification
CO D, E, F, G ... R, U, X A
CO21) D6), G6), H6), J6), K ... R C
CH4 E, H, L, N, P, R D
C2H4 K F
C6H14 K M
SO2 B13), F ... L, W N
NO E, G ... J, V, W P
N2O E7), S10) (biomass), Y11) S
SF6 H V
Smallest measuring range Largest measuring range
0 ... 200 mg/m3 0 ... 1 000 mg/m3 B
0 ... 50 vpm 0 ... 250 vpm D
0 ... 100 vpm 0 ... 500 vpm E
0 ... 150 vpm 0 ... 750 vpm F
0 ... 200 vpm 0 ... 1 000 vpm G
0 ... 500 vpm 0 ... 2 500 vpm H
0 ... 1 000 vpm 0 ... 5 000 vpm J
0 ... 2 000 vpm 0 ... 10 000 vpm K
0 ... 0.5 % 0 ... 2.5 % L
0 ... 1 % 0 ... 5 % M
0 ... 2 % 0 ... 10 % N
0 ... 5 % 0 ... 25 % P
0 ... 10 % 0 ... 50 % Q
0 ... 20 % 0 ... 100 % R

}
0 ... 50 mg/m³ 0 ... 500 mg/m³ S
0 ... 150 mg/m³ 0 ... 750 mg/m³ TÜV version U
0 ... 250 mg/m³ 0 ... 1 250 mg/m³ V
0 ... 400 mg/m³ 0 ... 2 000 mg/m³ W
0 ... 50 vpm 0 ... 2 500 vpm X
0 ... 500 vpm 0 ... 5 000 vpm Y
Operating software, documentation3)
German 0
English 1
French 2
Spanish 3
Italian 4
Footnotes: See page 1/51.

1/50 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version

■ Selection and ordering data


1
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Add-on electronics with 8 digital inputs/outputs, PROFIBUS PA interface A12
Add-on electronics with 8 digital inputs/outputs, PROFIBUS DP interface A13
Stainless steel (mat. no. 1.4571) connection pipe, 6 mm, complete with screwed gland A27
(cannot be combined with Viton hose)
Stainless steel (mat. no. 1.4571) connection pipe, ¼", complete with screwed gland A29
(cannot be combined with Viton hose)
Telescopic rails (2 units, 19" rack unit version only) A31
TAG labels (specific lettering based on customer information) B03
Gas path for short response time9) C01
Chopper compartment purging for 6 mm gas connection C02
Chopper compartment purging for ¼" gas connection C03
Application with paramagnetic oxygen measuring cell and separate gas path C11
Presetting to reference temperature 0 °C for conversion into mg/m³, applies to all components D15
Certificate FM/CSA Class I, Div. 2, ATEX II 3 G E20
Measuring range indication in plain text4) Y11
Measurement of CO2 in forming gas8) Y14
(only in conjunction with measuring range 0 to 20/0 to 100 %)
Accessories Article No.
CO2 absorber cartridge 7MB1933-8AA
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
Add-on electronics with 8 digital inputs/outputs and PROFIBUS PA A5E00056834
Add-on electronics with 8 digital inputs/outputs and PROFIBUS DP A5E00057159
Set of Torx screwdrivers A5E34821625

1)
For measuring ranges below 1 %, a CO2 absorber cartridge can be used for setting the zero point (see accessories)
2)
Without separate zero gas input or solenoid valve
3)
User language can be changed
4)
Standard setting: smallest measuring range, largest measuring range
5)
O2 sensor in gas path of infrared measured component 1
6)
With chopper compartment purging (N2 approx. 3 000 hPa required for measuring ranges below 0.1 % CO2),
to be ordered separately (see order code C02 or C03)
7)
Not suitable for use with emission measurements since the cross-sensitivity is too high
8)
CO2 measurement in accompanying gas Ar or Ar/He (3:1); forming gas
9)
Only for version with Viton hose
10)
Only in combination with CO/CO2, measuring range 0 to 75/750 mg/m³, 0 to 5/25 % [-BL-]
11)
Only in combination with CO2/NO, measuring range 0 to 5/25 %, 0 to 500/5 000 vpm [-DC-]
12)
Only in combination with N2O, measuring range 0 to 50/500 mg/m³ [-SS-]
13)
Not checked for suitability, maximum possible AUTOCAL cycle  6 h, constant ambient conditions (max. deviation ±1 °C (1.8 °F)

Siemens PA 01 · 2015 1/51


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1 Ordering notes
Special selection rules must be observed when measuring some 7MB2337 and 7MB2338
components. (application with paramagnetic oxygen measuring cell and
separate gas path)
Measured component N2O
7MB2337-4**80-**** - Z + C11
7MB2335, 7MB2337 and 7MB2338 7MB2337-5**80-**** - Z + C11
(application: Si chip production)
• Measuring range 0 to 100 / 500 ppm (MB designation "E") 7MB2338-4**80-**** - Z + C11
7MB2338-5**80-**** - Z + C11
• Can only be used to measure N2O in ultra-pure gases
Measured component SF6
7MB2337 and 7MB2338
(application: measurement in accordance with the requirements 7MB2335, 7MB2337 and 7MB2338
of the Kyoto protocol) (application: SI chip production)
• Measuring range 0 to 500 / 5 000 vpm (MB designation "Y") • Measuring range 0 to 500 / 2 500 ppm (MB designation "H")
• Requires simultaneous measurement of CO2 for correction of • Can only be used to measure SF6 in inert gases
cross-interference
7MB2337-*CP*0-*SY* or
7MB2338-*DC*0-*SY* (including NO measurement)
7MB2338
(application in accordance with the requirements of the 30th
BImSchV, "biomass")
• Measuring range 0 to 50 / 500 mg/m³ (MB designation "S")
• Requires simultaneous measurement of CO2 and CO for
correction of cross-interference
7MB2338-*BL*0-*SS*

Calibration interval (TÜV versions)

Component Smallest measuring range Calibration interval Remarks Z suffix


(TÜV)
CO 0 … 150 mg/m³ 5 months 13./27. BImSchV E50
CO 0 … 250 mg/m³ 12 months 13./27. BImSchV
NO 0 … 100 mg/m³ 5 months 13./27. BImSchV E50
NO 0 … 250 mg/m³ 12 months 13./27. BImSchV
SO2 0 … 400 mg/m³ 12 months 13./27. BImSchV
N2O 0 … 500 ppm Kyoto protocol
N2O 0 … 50 mg/m³ 6 months 30. BImSchV

AUTOCAL AUTOCAL Calibration with calibration gas Comment (keep


(ambient air) (inert gas e.g. N2) to technical
specs)
Zero point Calibration point Zero point Calibration point Zero point Calibration point
Hours Weeks
IR components 3 ... 24 3 ... 24 o 52
O2 - electrical Stable 3 ... 24 Stable - 52 o
chemical sensor
O2 paramagnetic - 3 ... 24 x x 1 o at MB < 5 %
Cell
- 3 ... 24 x x 8 o at MB > 5 %
O2 paramagnetic x x 3 ... 24 - o 52 at MB < 5 %
Cell
x x 3 ... 24 - o 52 at MB > 5 %
H2S sensor 3 - 3 - o 12
o = with AUTOCAL, x = not applicable

Calibration intervals, standard devices

1/52 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version

■ Dimensional drawings
1






0










  










      


















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&DXWLRQDOZD\VLQVWDOORQVXSSRUWLQJUDLOVZKHQ
PRXQWHGLQEHQFKWRSKRXVLQJRULQFDELQHW

ULTRAMAT 23, 19“ unit, dimensions in mm

Siemens PA 01 · 2015 1/53


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1











 





7 5 3 2 












*DVFRQQHFWLRQVVWXEVGLDPPP

ULTRAMAT 23, desktop unit, dimensions in mm

1/54 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version

■ Schematics
1
Pin assignment (electrical and gas connections)

&RQQHFWRU68%') 56 ;

0  *1'
*1'  5B/HYHO1
 1& ,WLVSRVVLEOHWRFRQQHFWEXV
 5'7'1 WHUPLQDWLQJUHVLVWRUVWRSLQV
 5'7'3 DQG
9  5B/HYHO3
 1&
 1&
0  *1'

&RQQHFWRU68%');

0 
 $QDORJRXWSXW1
$QDORJRXWSXW3 IRU,5FRPSRQHQW  ,QWHUQDOO\FRQQHFWHG
 $QDORJRXWSXW1
$QDORJRXWSXW3 IRU,5FRPSRQHQW  7KHOLQHDQGFRQQHFWRUPXVW
 $QDORJRXWSXW1 EHVKLHOGHGDQGUHVWDJDLQVW
$QDORJRXWSXW3 IRU,5FRPSRQHQW  WKHHQFORVXUHSRWHQWLDO
 $QDORJRXWSXW1
$QDORJRXWSXW3 IRU2 

5HOD\ 
5HOD\




 &RQWDFWORDG
5HOD\  PD[9$$&'&
 5HOD\
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 VKRZQ

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 6(/9 ZLWKVDIH
 HOHFWULFDOLVRODWLRQ

5HOD\


 5HOD\


,QSXWV

36\QFKURLQSXW 1 9

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 33XPSRQRII 6DIHW\H[WUDORZYROWDJH
 1  6(/9 ZLWKVDIH
HOHFWULFDOLVRODWLRQ

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VKLHOGHGDQGUHVWDJDLQVWWKHHQFORVXUHSRWHQWLDO

ULTRAMAT 23, pin assignment (standard)

Siemens PA 01 · 2015 1/55


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1
Connector SUB-D 37F (option) -X50

M 19 GND
37 NC
18 NC
36 Binary input 8-P
Isolated
17 Binary input 7-P
35 Binary input 6-P via optocoupler
16 Binary input 5-P "0" = 0 V (0 ... 4.5 V)
34 Binary input 4-P "1" = 24 V (13 ... 33 V)
15 Binary input 3-P Safety extra-low voltage
33 Binary input 2-P (SELV) with safe
14 Binary input 1-P electrical isolation.
32 Binary input 1 to 8-N
13
31 Relay 16
12
30
11 Relay 15
29
10
28 Relay 14
9
Contact load
27
8 Relay 13 max. 24 V/1 A, AC/DC
26 for shown
7 relay contact position,
25 Relay 12 the relay has zero current
6
24 Safety extra-low voltage
5 Relay 11 (SELV) with safe
23 electrical isolation.
4
22 Relay 10
3
21
2 Relay 9
20
M 1 GND

Connector SUB-D 9F-X90 optional Connector SUB-D 9M-X90


PROFIBUS DP PROFIBUS PA

5 DGND 5
9 CNTR-N 9
4 CNTR-P/direction control 4
8 RxD/TxD-N (A) 8 PA-N(-)
3 RxD/TxD-P (B) 3 PA-P(+)
7 7
2 2
6 VP /+ 5 V 6
1 1

Note:
All cables to the connectors or terminal blocks must
be shielded and rest against the enclosure potential.

ULTRAMAT 23, pin assignment of the optional PROFIBUS interface board

1/56 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
19“ unit 1

7 6 5 4 3 2 1

Power supply -X45 -X80


and fuse 9-pin socket 37-pin socket
RS 485 analog and digital
inputs/outputs
-X90 -X50
Gas connections: 9-pin interface 37-pin socket
stubs 6 mm or ¼" socket (option): option module
e.g. PROFIBUS binary inputs/
relay outputs

ULTRAMAT 23, 19“ unit, e.g. one infrared component with oxygen measurement
Desktop unit

7 5 3 2

Power switch Power supply -X45 -X80


and fuse 9-pin socket 37-pin socket
RS 485 analog and digital
inputs/outputs
-X90 -X50
9-pin interface 37-pin socket
socket (option): option module
Gas connections: stubs 6 mm e.g. PROFIBUS binary inputs/relay outputs
(gas inlet on front side)

When installing in a cabinet, mount only on support rails.

ULTRAMAT 23, portable unit, in sheet-steel housing, gas and electrical connections

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Continuous Gas Analyzers, extractive


ULTRAMAT 23
19" rack unit and portable version
1
1 Messgas/Prüfgas 1 Messgas/Prüfgas 1 Messgas/Prüfgas 1
Messgas/Prüfgas
Sample gas/Span gas Sample gas/Span gas Sample gas/Span gas
2 Sample gas/Span gas
Gaz de mesure/d’ajustage Gaz de mesure/d’ajustage Gaz de mesure/d’ajustage 1
Gaz de mesure/d’ajustage
2 2 2
AUTOCAL-Gas/Nullgas
AUTOCAL-Gas/Nullgas 3 AUTOCAL gas/Zero gas 3
3 AUTOCAL gas/Zero gas Gaz AUTOCAL/zéro nicht belegt 3 Messgas/Prüfgas 2
Gaz AUTOCAL/zéro not used Sample gas/Span gas 2
nicht belegt non utilisé Gaz de mesure/d’ajustage 2
4 not used 4 4
non utilisé
Gehäusebespülung
Gehäusebespülung Gehäusebespülung Gehäusebespülung
5 Enclosure purge
5
Balayage de l’appareil Enclosure purge 5 Enclosure purge 5 Enclosure purge
Balayage de l’appareil Balayage de l’appareil Balayage de l’appareil
atmosphärischer Druckaufnehmer atmosphärischer Druckaufnehmer atmosphärischer Druckaufnehmer

Chopperraumbespülung
6 atmospherical pressure transducer 6 atmospherical pressure transducer 6 atmospherical pressure transducer
capteur de pression atmosphérique capteur de pression atmosphérique capteur de pression atmosphérique
7 Chopper purge
Balayage de l’obturateur Chopperraumbespülung Chopperraumbespülung Chopperraumbespülung
7 Chopper purge
Balayage de l’obturateur
7 Chopper purge
Balayage de l’obturateur
7 Chopper purge
Balayage de l’obturateur

Key to symbols Key to symbols Key to symbols Key to symbols


ULTRAMAT 23 ULTRAMAT 23 ULTRAMAT 23 ULTRAMAT 23
portable, in sheet-steel housing 19” rack unit 19” rack unit 19” rack unit
with sample gas pump without sample gas pump with two separate
gas paths or pipe version

ULTRAMAT 23, designation of the different labels

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Continuous Gas Analyzers, extractive


ULTRAMAT 23
Documentation

■ Selection and ordering data


1
Operating instructions Article No.
ULTRAMAT 23
Gas analyzer for IR-absorbing gases
and oxygen
• German C79000-B5200-C216
• English C79000-B5276-C216
• French C79000-B5277-C216
• Spanish C79000-B5278-C216
• Italian C79000-B5272-C216

Suggestions for spare parts

■ Selection and ordering data


Description Quantity Quantity Article No.
for 2 years for 5 years
Analyzer unit
O-ring for analyzer chamber: 180, 90, 60, 20 mm 2 4 C71121-Z100-A99
Chopper
• With motor, for 1 IR channel (7MB2335-...) 1 1 C79451-A3468-B515
• With motor, for 2 IR channels (7MB2337-..., 7MB2338-...) 1 1 C79451-A3468-B516
Electronics
Motherboard, with firmware - 1 C79451-A3494-D501
Keypad 1 1 C79451-A3492-B605
LCD module 1 1 C79451-A3494-B16
Connector filter - 1 W75041-E5602-K2
Line switch (portable analyzer) - 1 W75050-T1201-U101
Fusible element 220 ... 240 V 2 4 W79054-L1010-T630
Fusible element 100 ... 120 V 2 4 W79054-L1011-T125
Other
Safety filter (zero gas), internal 2 2 A5E00059149
Safety filter (sample gas), internal 2 3 C79127-Z400-A1
Pressure switch 1 2 C79302-Z1210-A2
Flowmeter 1 2 C79402-Z560-T1
Set of gaskets for sample gas pump 2 5 C79402-Z666-E20
Condensation trap (for portable unit, in sheet steel enclosure) 1 2 C79451-A3008-B43
Filter (for portable unit, in sheet steel enclosure) 1 2 C79451-A3008-B60
Oxygen sensor 1 1 C79451-A3458-B55
Sample gas pump 50 Hz 1 1 C79451-A3494-B10
Sample gas pump 60 Hz 1 1 C79451-A3494-B11
Solenoid valve 1 1 C79451-A3494-B33

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
General information
1 ■ Overview Special versions
Special applications
Besides the standard combinations, special applications con-
cerning material in the gas path, material in the sample cells
(e.g. Titan, Hastelloy C22) and measured components are also
available on request
TÜV version/QAL
TÜV-approved versions are available for measurement of CO,
NO and SO2 according to 13th and 17th BlmSchV and TA Luft.
Smallest TÜV-approved and permitted measuring ranges:
• 1-component analyzer
CO: 0 to 50 mg/m3
NO: 0 to 100 mg/m3
SO2: 0 to 75 mg/m3
• 2-component analyzer (series connection)
CO: 0 to 75 mg/m3
NO: 0 to 200 mg/m3.
Furthermore, the TÜV-approved versions of the ULTRAMAT 6
The ULTRAMAT 6 single-channel or dual-channel gas analyzers comply with the requirements of EN 14956 and QAL 1 in ac-
operate according to the NDIR two-beam alternating light princi- cordance with EN 14181. Conformity of the analyzers with
ple and measure gases highly selectively whose absorption both standards is TÜV-certified.
bands lie in the infrared wavelength range from 2 to 9 m, such The analyzer drift can be determined in accordance with
as CO, CO2, NO, SO2, NH3, H2O as well as CH4 and other EN 14181 (QAL 3) either manually or with a PC using the
hydrocarbons. SIPROM GA maintenance and servicing software. In addition,
Single-channel analyzers can simultaneously measure up to 2 selected manufacturers of emission evaluation computers
gas components, while dual-channel analyzers can simultane- offer the possibility for downloading the drift data via the ana-
ously measure 3 (or 4 on request) gas components. lyzer’s serial interface and to automatically record and pro-
cess it in the evaluation computer.
■ Benefits Flow-type reference compartment
• High selectivity with double-layer detector and optical coupler • The flow through the reference compartment should be
- Reliable measurements even in complex gas mixtures adapted to the sample gas flow
• Low detection limits • The gas supply of the reduced flow-type reference compart-
- Measurements with low concentrations ment should have an upstream pressure of 3 000 to 5 000 hPa
(abs.). Then a restrictor will automatically adjust the flow to
• Corrosion-resistant materials in gas path (option)
approximately 8 ml/min
- Measurement possible in highly corrosive sample gases
• Analyzer cells can be cleaned as required on site
- Cost savings due to reuse after contamination ■ Design
• Electronics and physics: gas-tight isolation, purging is 19" rack unit
possible, IP65 • 19" rack unit with 4 HU for installation
- Long service life even in harsh environments - in hinged frame
• Heated versions (option) - in cabinets with or without telescopic rails
- Use also in presence of gases condensing at low • Front plate for service purposes can be pivoted down (laptop
temperature connection)
• EEx(p) for zones 1 and 2 (according to ATEX 2G and ATEX 3G) • Internal gas paths: hose made of FKM (Viton) or pipe made of
titanium or stainless steel
■ Application • Gas connections for sample gas inlet and outlet: pipe diame-
ter 6 mm or 1/4"
Areas of application
• Flow indicator for sample gas on front plate (option)
• Measurement for boiler control in incineration plants
• Pressure switch in sample gas path for flow monitoring
• Emission measurements in incineration plants
(option)
• Measurement in the automotive industry (test benches)
Field device
• Warning equipment
• Two-door enclosure with gas-tight separation of analyzer and
• Process gas concentrations in chemical plants
electronics sections from gas path
• Trace measurements in pure gas processes
• Individually purgeable enclosure halves
• Environmental protection
• Parts in contact with sample gas can be heated up to 65 °C
• TLV (Threshold Limit Value) monitoring at the workplace (option)
• Quality monitoring • Gas path: hose made of FKM (Viton) or pipe made of titanium
• Ex versions for analyzing flammable and non-flammable or stainless steel (further materials possible as special appli-
gases or vapors for use in hazardous areas cations)
• Gas connections for sample gas inlet and outlet: pipe union
for pipe diameter 6 mm or 1/4"
• Purging gas connections: pipe diameter 10 mm or 3/8"

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
General information
Display and control panel • Six binary inputs freely configurable (e.g. measurement range 1
• Large LCD field for simultaneous display of: changeover, processing of external signals from the sample
- Measured value (digital and analog displays) preparation)
- Status bar • Six relay outputs freely configurable e.g. for fault, mainte-
- Measuring ranges nance request, limit alarm, external solenoid valves)
• Contrast of the LCD field adjustable via the menu • Expansion by eight additional binary inputs and eight addi-
• Washable membrane keyboard with five softkeys tional relay outputs e.g. for autocalibration with up to four test
gases
• Menu-driven operator control for parameterization, test func-
tions, adjustment Communication
• Operator support in plain text RS 485 present in the basic unit (connection at the rear; for the
• Graphic display of concentration trend; programmable time rack unit also behind the front plate).
intervals Options
• Bilingual operating software: • AK interface for the automotive industry with extended
German/English, English/Spanish, French/English, functions
Spanish/English, Italian/English
• RS 485/RS 232 converter
Input and outputs • RS 485/Ethernet converter
• One analog output per medium (from 0, 2, 4 to 20 mA; • RS 485/USB converter
NAMUR parameterizable)
• Connection to networks via PROFIBUS DP/PA interface
• Two analog inputs freely configurable (e.g. correction of
cross-interferences or external pressure sensor) • SIPROM GA software as the service and maintenance tool

LED backlit graphic Status line for display Two code levels
display and of analyzer status according to NAMUR
membrane keyboard (programmable) (maintenance and
with noticeable click specialist level)

Easy operation with


menu control
Display of using five softkeys
concentrations as
numbers and bargraph
for channel 1

Display of current
Display of
measuring ranges
concentrations as
numbers and bargraph
for channel 2
Status line for channel 2
to display the unit
Display of status (programmable)
start-of-scale and
full-scale values
ESC key
to abort inputs
Keyboard to
enter values

INFO key
for help in plain text

CLEAR key
to delete inputs
ENTER key MEAS key
to accept to return to
input values measurement mode

ULTRAMAT 6, membrane keyboard and graphic display

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
General information
1 Designs – Parts wetted by sample gas, standard
Gas path 19" rack unit Field device Field device Ex
With hoses Bushing Stainless steel, mat. no. 1.4571 -
Hose FKM (e.g. Viton)
Sample chamber:
• Body Aluminum
• Lining Aluminum
• Fitting Stainless steel, mat. no. 1.4571,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
• Window CaF2, adhesive: E353, O-ring: FKM (e.g. Viton) or FFKM
(Kalrez)
With pipes Bushing Titanium
Pipe Titanium,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
Sample chamber:
• Body Aluminum
• Lining Tantalum (only for cell length 20 mm to 180 mm)
• Window CaF2, adhesive: E353, O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
With pipes Bushing Stainless steel, mat. no. 1.4571
Pipe Stainless steel, mat. no. 1.4571,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
Sample chamber:
• Body Aluminum
• Lining Aluminum or tantalum (tantalum only for cell length 20 mm to 180 mm)
• Window CaF2, adhesive: E353, O-ring: FKM (e.g. Viton) or FFKM (Kalrez)

Options
Gas path 19" rack unit Field device Field device Ex
Flow indicator Measurement pipe Duran glass - -
Variable area Duran glass
Suspension boundary PTFE (Teflon)
Angle pieces FKM (e.g. Viton)
Pressure switch Membrane FKM (e.g. Viton) - -
Enclosure PA 6.3T

Versions – Parts wetted by sample gas, special applications (examples)


Gas path 19" rack unit Field device Field device Ex
With pipes Bushing e.g. Hastelloy C22
Pipe e.g. Hastelloy C22,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
Sample chamber:
• Body e.g. Hastelloy C22
• Window CaF2, without adhesive
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
General information
Gas path (19" rack unit) 1
Legend for the gas path figures
1 Sample gas inlet channel 1 8 Restrictor
2 Sample gas outlet channel 1 9 Purge gas inlet
3 Reference gas outlet (option) 10 Gas inlet atmospheric pressure sensor
4 Reference gas inlet (option) 11 Atmospheric pressure sensor
5 Sample gas inlet channel 2 12 Flow indicator in sample gas path (option)
6 Sample gas outlet channel 2 13 Pressure switch in sample gas path (option)
7 IR physical system

9 10 2 1 4 3

8
P 13

P 11 12
F

Gas path ULTRAMAT 6, single-channel unit, 19" unit, with flow-type reference cell (option)

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Gas path ULTRAMAT 6, dual-channel unit, 19" unit

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
General information
1 Gas path (field device)
Legend for the gas path figures
1 Sample gas inlet 7 Purging gas outlet (analyzer side)
2 Sample gas outlet 8 Purging gas inlet (analyzer side)
3 Reference gas inlet (option) 9 Connection of atmospheric pressure sensor
4 Reference gas outlet (option) 10 IR physical system
5 Purging gas inlet (electronics side) 11 Atmospheric pressure sensor
6 Purging gas outlet (electronics side)

        



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Gas path ULTRAMAT 6, field unit, with flow-type reference cell (option)

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
General information

■ Function
1
Principle of operation
The ULTRAMAT 6 gas analyzer operates according to the infra-
red two-beam alternating light principle with double-layer detec- 1
tor and optical coupler.
2
The measuring principle is based on the molecule-specific
absorption of bands of infrared radiation. The absorbed wave-
lengths are characteristic to the individual gases, but may par-
tially overlap. This results in cross-sensitivities which are re-
duced to a minimum in the ULTRAMAT 6 gas analyzers by the
following measures: 3
• Gas-filled filter cell (beam divider) 4
• Double-layer detector with optical coupler
• Optical filters if necessary
The figure shows the measuring principle. An IR source (1)
which is heated to approx. 700 ºC and which can be shifted to
balance the system is divided by the beam divider (3) into two 5
equal beams (sample and reference beams). The beam divider
also acts as a filter cell. 6
The reference beam passes through a reference cell (8) filled
with N2 (a non-infrared-active gas) and reaches the right-hand
side of the detector (11) practically unattenuated. The sample
beam passes through the sample chamber (7) through which
the sample gas flows and reaches the left-hand side of the de- 7 8
tector (10) attenuated to a lesser or greater extent depending on
the concentration of the sample gas. The detector is filled with a
defined concentration of the gas component to be measured.
The detector is designed as a double-layer detector. The center
of the absorption band is preferentially absorbed in the upper
detector layer, the edges of the band are absorbed to approxi- 9
mately the same extent in the upper and lower layers. The upper
and lower detector layers are connected together via the micro-
flow sensor (12). This coupling means that the spectral sensitiv-
ity has a very narrow band. 10 11
The optical coupler (13) lengthens the lower receiver cell layer 12
optically. The infrared absorption in the second detector layer is
varied by changing the slider position (14). It is thus possible to
individually minimize the influence of interfering components.
A chopper (5) rotates between the beam divider and the sample
chamber and interrupts the two beams alternately and periodi-
cally. If absorption takes place in the sample chamber, a pulsat- 13
ing flow is generated between the two detector levels which is
converted by the microflow sensor (12) into an electric signal.
14
The microflow sensor consists of two nickel-plated grids heated
to approximately 120 ºC, which, along with two supplementary
resistors, form a Wheatstone bridge. The pulsating flow together
1 IR source, adjustable 8 Reference cell
with the dense arrangement of the Ni grids causes a change in
resistance. This leads to an offset in the bridge, which is depen- 2 Optical filter 9 Sample gas outlet
dent on the concentration of the sample gas. 3 Beam divider 10 Detector, meas. side
4 Eddy current drive 11 Detector, reference side
Notes 5 Chopper 12 Microflow sensor
The sample gases must be fed into the analyzers free of dust. 6 Sample gas inlet 13 Optical coupler
Condensation should be prevented from occurring in the sample 7 Sample cell 14 Slider, adjustable
chambers. Therefore, the use of gas modified for the measuring
task is necessary in most application cases.
ULTRAMAT 6, principle of operation
As far as possible, the ambient air of the analyzer should not
have a large concentration of the gas components to be mea- Channels with electronically suppressed zero point only differ
sured. from the standard version in the measuring range parameteriza-
tion.
Flow-type reference sides with reduced flow must not be oper-
ated with flammable or toxic gases. Physically suppressed zeros can be provided as a special ap-
plication.
Flow-type reference sides with reduced flow and an O2 content
> 70 % may only be used together with Y02 (Clean for O2).

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
General information
1 Essential characteristics Additional features, dual-channel version
• Dimension of measured value freely selectable • Separate design of physical unit, electronics, inputs/outputs
(e.g. vpm, mg/m3) and power supply for each channel
• Four freely-parameterizable measuring ranges per • Display and operation via common LCD panel and keyboard
component • Measurement channels 1 and 2 can be converted to series
• Measuring ranges with suppressed zero point possible connection (linking of gas connections from channel 1 to
• Measuring range identification channel 2 on rear)
• Galvanically isolated signal output 0/2/4 to 20 mA per compo-
nent
• Automatic or manual measuring range switchover selectable;
remote switching is also possible
• Differential measuring ranges with flow-type reference cell
• Storage of measured values possible during adjustments
• Time constants selectable within wide limits (static/dynamic
noise suppression); i.e. the response time of the analyzer or
component can be matched to the respective measuring task
• Short response time
• Low long-term drift
• Measuring point switchover for up to 6 measuring points
(programmable)
• Measuring point identification
• Monitoring of sample gas flow (option)
• Internal pressure sensor for correction of variations in atmo-
spheric pressure in the range 700 to 1 200 hPa absolute
• External pressure sensor can be connected for correction of
variations in the process gas pressure in the range 700 to
1 500 hPa absolute (option)
• Two control levels with separate authorization codes to pre-
vent unintentional and unauthorized inputs
• Automatic, parameterizable measuring range calibration
• Simple handling using a numerical membrane keyboard and
operator prompting
• Operation based on NAMUR recommendation
• Customer-specific analyzer options such as:
- Customer acceptance
- TAG labels
- Drift recording
• Easy device replacement since electric connections can be
simply disconnected from the device
• Sample chambers for use in presence of highly corrosive sam-
ple gases (e.g. tantalum layer or Hastelloy C22)

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit

■ Technical specifications
1
General information Pressure correction range
Measuring ranges 4, internally and externally switch- Pressure sensor
able; autoranging is also possible • Internal 700 … 1 200 hPa absolute
Smallest possible measuring range Dependent on the application: • External 700 … 1 500 hPa absolute
e.g. CO: 0 … 10 vpm,
CO2: 0 … 5 vpm Measuring response (relating to sample gas pressure 1 013 hPa
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Largest possible measuring span Dependent on the application
Output signal fluctuation <  1 % of the smallest possible
Measuring range with suppressed Any zero point within measuring range according to
zero point 0 … 100 vol.% can be imple- rating plate
mented; smallest possible span
20 % Zero point drift <  1 % of the current measuring
range/week
Operating position Front wall, vertical
Measured-value drift <  1 % of the current measuring
Conformity CE mark in accordance with range/week
EN 50081-1, EN 50082-2
Repeatability  1 % of the current measuring
Influence of interfering gases must be considered separately range
Design, enclosure Detection limit 1 % of the smallest possible
Weight Approx. 15 kg measuring range
(with one IR channel) Linearity error < 0.5 % of the full-scale value
Approx. 21 kg
(with two IR channels) Influencing variables (relating to sample gas pressure 1 013 hPa
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Degree of protection IP20 according to EN 60529
Ambient temperature < 1 % of current measuring
Electrical characteristics range/10 K (with constant
EMC In accordance with standard receiver cell temperature)
(Electromagnetic Compatibility) requirements of NAMUR NE21 Sample gas pressure • When pressure compensation
(08/98) has been switched on: < 0.15 %
Electrical safety According to EN 61010-1, of the span/1 % change in atmo-
overvoltage category III spheric pressure
Power supply 100 … 120 V AC (nominal range • When pressure compensation
of use 90 … 132 V), 48 … 63 Hz has been switched off: < 1.5 %
or of the span/1 % change in atmo-
200 … 240 V AC (nominal range spheric pressure
of use 180 … 264 V), 48 … 63 Hz Sample gas flow Negligible
Power consumption 1-channel unit: Approx. 40 VA Power supply < 0.1 % of the current measuring
2-channel unit: Approx. 70 VA range with rated voltage  10 %
Fuse values Environmental conditions Application-specific measuring
• 100 ... 120 V 1 T/250 (7MB2121) influences possible if ambient air
1.6 T/250 (7MB2123) contains measured components or
cross interference-sensitive gases
• 200 ... 240 V 0.63 T/250 (7MB2121)
1 T/250 (7MB2123) Electrical inputs and outputs

Gas inlet conditions Analog output 0/2/4 ... 20 mA, isolated;


load  750 
Permissible sample gas pressure
Relay outputs 6, with changeover contacts,
• With hoses freely parameterizable, e.g. for
measuring range identification;
- Without pressure switch 600 … 1 500 hPa (absolute) load: 24 V AC/DC/1 A, isolated,
- With pressure switch 700 … 1 300 hPa (absolute) non-sparking
• With pipes (without pressure switch) 600 … 1 500 hPa (absolute) Analog inputs 2, dimensioned for 0/2/4 ... 20 mA
for external pressure sensor and
Sample gas flow 18 … 90 l/h (0.3 … 1.5 l/min) accompanying gas influence cor-
Sample gas temperature Min. 0 ... max. 50 °C, but above rection (correction of cross-inter-
the dew point ference)
Sample gas humidity < 90 % RH (relative humidity), or Binary inputs 6, designed for 24 V, isolated,
dependent on measuring task, freely parameterizable, e.g. for
non-condensing measuring range switchover
Dynamic response Serial interface RS 485
Warm-up period At room temperature < 30 min Options AUTOCAL function with 8 addi-
(the technical specification will be tional binary inputs and relay out-
met after 2 hours) puts, also with PROFIBUS PA or
PROFIBUS DP
Delayed display (T90-time) Dependent on length of analyzer
chamber, sample gas line and Climatic conditions
parameterizable damping Permissible ambient temperature -30 ... +70 °C during storage and
Damping (electrical time constant) 0 … 100 s, parameterizable transportation,
5 ... 45 °C during operation
Dead time (purging time of the gas Approximately 0.5 ... 5 s,
path in the unit at 1 l/min) depending on version Permissible humidity < 90 % RH (relative humidity) as
annual average, during storage
Time for device-internal signal <1s and transportation (dew point
processing must not be undershot)

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit
1
■ Selection and ordering data Article No.
ULTRAMAT 6 gas analyzer 7MB2121- 7 7 7 7 7 - 7 A A 7 Cannot be combined
Single-channel 19" rack unit for installation in cabinets
Click on the Article No. for the online configuration in the PIA Life Cycle
Portal.
Gas connections for sample gas and reference gas
Pipe with 6 mm outer diameter 0 0 A21
Pipe with ¼" outer diameter 1 1 A20
Measured component Possible with measuring
range identification
CO 11 ... 30 A
CO highly selective (with optical filter) 12 ... 30 B
CO (TÜV; see table "TÜV single component", page 1/76) X
CO2 10 ... 30 C
CH4 13 ... 30 D
C2H2 15 ... 30 E
C2H4 15 ... 30 F
C2H6 14 ... 30 G
C3H6 14 ... 30 H
C3H8 13 ... 30 J
C4H6 15 ... 30 K
C4H10 14 ... 30 L
C6H14 14 ... 30 M
SO2 (TÜV; see table "TÜV single component", 13 ... 30 N
page 1/76)
NO (TÜV; see table "TÜV single component", 14 ... 20, 22 P
page 1/76)
NH3 (dry) 14 ... 30 Q Q
H2O 17 ... 20, 22 R R
N2O 13 ... 30 S
Smallest measuring Largest measuring Measuring range
range range identification
0 ... 5 vpm 0 ... 100 vpm 10 A
0 ... 10 vpm 0 ... 200 vpm 11 B
0 ... 20 vpm 0 ... 400 vpm 12 C
0 ... 50 vpm 0 ... 1 000 vpm 13 D
0 ... 100 vpm 0 ... 1 000 vpm 14 E
0 ... 300 vpm 0 ... 3 000 vpm 15 F
0 ... 500 vpm 0 ... 5 000 vpm 16 G
0 ... 1 000 vpm 0 ... 10 000 vpm 17 H
0 ... 3 000 vpm 0 ... 10 000 vpm 18 J
0 ... 3 000 vpm 0 ... 30 000 vpm 19 K
0 ... 5 000 vpm 0 ... 15 000 vpm 20 L
0 ... 5 000 vpm 0 ... 50 000 vpm 21 M
0 ... 1 % 0 ... 3 % 22 N
0 ... 1 % 0 ... 10 % 23 P
0 ... 3 % 0 ... 10 % 24 Q
0 ... 3 % 0 ... 30 % 25 R
0 ... 5 % 0 ... 15 % 26 S
0 ... 5 % 0 ... 50 % 27 T
0 ... 10 % 0 ... 30 % 28 U
0 ... 10 % 0 ... 100 % 29 V
0 ... 30 % 0 ... 100 % 30 W
Internal gas paths Sample chamber1) Reference chamber
(lining) (flow-type)
Hose made of FKM Aluminum Non-flow-type 0 0 0 A20, A21
(Viton) Aluminum Flow-type 1 1
Pipe made of titanium Tantalum Non-flow-type 4 4 A20, A21, Y02
Tantalum Flow-type 5 5 Y02
Stainless steel pipe Aluminum Non-flow-type 6 6 A20, A21
(mat. no. 1.4571) Tantalum Non-flow-type 8 8 A20, A21
With sample gas monitoring
Hose made of FKM Aluminum Non-flow-type 2 2 2 A20, A21
(Viton) Aluminum Flow-type 3 3
Footnotes: see next page

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Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit

■ Selection and ordering data Article No.


1
ULTRAMAT 6 gas analyzer 7MB2121- 7 7 7 7 7 - 7 A A 7 Cannot be combined
Single-channel 19" rack unit for installation in cabinets
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs/outputs 1
• With serial interface for the automotive industry (AK) 3 3 E20
• With 8 digital inputs/outputs, PROFIBUS PA interface 6
• With 8 digital inputs/outputs, PROFIBUS DP interface 7
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Operating software and documentation
German 0
English 1
French 2
Spanish 3
Italian 4
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Flow-type reference cell with reduced flow, 6 mm A20
Flow-type reference cell with reduced flow, ¼" A21
Telescopic rails (2 units) A31
TAG labels (specific lettering based on customer information) B03
Kalrez gaskets in sample gas path B04
FM/CSA certificate – Class I Div 2 E20
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting (only in conjunction with an application no., e.g. extended Y12
measuring range)
Extended special setting (only in conjunction with an application no., Y13
e.g. determination of cross-interferences)
TÜV version acc. to 13th and 17th BlmSchV Y17
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with serial interface for the automotive industry (AK) C79451-A3480-D512
AUTOCAL function with 8 digital inputs/outputs C79451-A3480-D511
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057307
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057312
Set of Torx screwdrivers A5E34821625
1)
Only for cell length 20 to 180 mm

Siemens PA 01 · 2015 1/69


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit
1 ■ Selection and ordering data Article No.
ULTRAMAT 6 gas analyzer 7MB2123- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
Two-channel 19" rack unit for installation in cabinets
for measuring 2 IR components
Click on the Article No. for the online configuration in the PIA Life Cycle
Portal.
Gas connections for sample gas and reference gas
Pipe with 6 mm outer diameter 0 0 A21, A41
Pipe with ¼" outer diameter 1 1 A20, A40
Channel 1 Possible with measuring
Measured component range identification
CO 11 ... 30 A
CO highly selective (with optical filter) 12 ... 30 B
CO (TÜV; see table "TÜV single component", page 1/76) X
CO2 10 ... 30 C
CH4 13 ... 30 D
C2H2 15 ... 30 E
C2H4 15 ... 30 F
C2H6 14 ... 30 G
C3H6 14 ... 30 H
C3H8 13 ... 30 J
C4H6 15 ... 30 K
C4H10 14 ... 30 L
C6H14 14 ... 30 M
SO2 (TÜV; see table "TÜV single component", 13 ... 30 N
page 1/76)
NO (TÜV; see table "TÜV single component", 14 ... 20, 22 P
page 1/76)
NH3 (dry) 14 ... 30 Q Q
H2O 17 ... 20, 22 R R
N2O 13 ... 30 S
Smallest measuring range Largest measuring Measuring range
range identification
0 ... 5 vpm 0 ... 100 vpm 10 A
0 ... 10 vpm 0 ... 200 vpm 11 B
0 ... 20 vpm 0 ... 400 vpm 12 C
0 ... 50 vpm 0 ... 1 000 vpm 13 D
0 ... 100 vpm 0 ... 1 000 vpm 14 E
0 ... 300 vpm 0 ... 3 000 vpm 15 F
0 ... 500 vpm 0 ... 5 000 vpm 16 G
0 ... 1 000 vpm 0 ... 10 000 vpm 17 H
0 ... 3 000 vpm 0 ... 10 000 vpm 18 J
0 ... 3 000 vpm 0 ... 30 000 vpm 19 K
0 ... 5 000 vpm 0 ... 15 000 vpm 20 L
0 ... 5 000 vpm 0 ... 50 000 vpm 21 M
0 ... 1 % 0 ... 3 % 22 N
0 ... 1 % 0 ... 10 % 23 P
0 ... 3 % 0 ... 10 % 24 Q
0 ... 3 % 0 ... 30 % 25 R
0 ... 5 % 0 ... 15 % 26 S
0 ... 5 % 0 ... 50 % 27 T
0 ... 10 % 0 ... 30 % 28 U
0 ... 10 % 0 ... 100 % 29 V
0 ... 30 % 0 ... 100 % 30 W
Internal gas paths Sample chamber1) Reference chamber
(lining) (flow-type)
Hose made of FKM Aluminum Non-flow-type 0 0 0 A20, A21, A40, A41
(Viton) Aluminum Flow-type 1 1
Pipe made of titanium Tantalum Non-flow-type 4 4 A20, A21, A40, A41, Y02
Tantalum Flow-type 5 5 Y02
Stainless steel pipe Aluminum Non-flow-type 6 6 A20, A21, A40, A41
(mat. no. 1.4571) Tantalum Non-flow-type 8 8 A20, A21, A40, A41
With sample gas monitoring
Hose made of FKM Aluminum Non-flow-type 2 2 2 A20, A21, A40, A41
(Viton) Aluminum Flow-type 3 3
1) Only for cell length 20 to 180 mm

1/70 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit

■ Selection and ordering data Article No.


1
ULTRAMAT 6 gas analyzer 7MB2123- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
Two-channel 19" rack unit for installation in cabinets
for measuring 2 IR components
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs/outputs each for channel 1 1
• With 8 additional digital inputs/outputs each for channel 2 2
• With 8 additional digital inputs/outputs each for channel 1 and channel 2 3
• With serial interface for the automotive industry (AK) 5 5 E20
• With 8 additional digital inputs/outputs each for channel 1 and channel 2 6
and PROFIBUS PA interface
• With 8 additional digital inputs/outputs each for channel 1 and channel 2 7
and PROFIBUS DP interface
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Channel 2 Possible with measuring
Measured component range identification
CO 11 ... 30 A
CO highly selective (with optical filter) 12 ... 30 B
CO (TÜV; see table "TÜV single component", page 1/76) X
CO2 10 ... 30 C
CH4 13 ... 30 D
C2H2 15 ... 30 E
C2H4 15 ... 30 F
C2H6 14 ... 30 G
C3H6 14 ... 30 H
C3H8 13 ... 30 J
C4H6 15 ... 30 K
C4H10 14 ... 30 L
C6H14 14 ... 30 M
SO2 (TÜV; see table "TÜV single component", 13 ... 30 N
page 1/76)
NO (TÜV; see table "TÜV single component", 14 ... 20, 22 P
page 1/76)
NH3 (dry) 14 ... 30 Q Q
H2O 17 ... 20, 22 R R
N2O 13 ... 30 S
Smallest measuring range Largest measuring Measuring range
range identification
0 ... 5 vpm 0 ... 100 vpm 10 A
0 ... 10 vpm 0 ... 200 vpm 11 B
0 ... 20 vpm 0 ... 400 vpm 12 C
0 ... 50 vpm 0 ... 1 000 vpm 13 D
0 ... 100 vpm 0 ... 1 000 vpm 14 E
0 ... 300 vpm 0 ... 3 000 vpm 15 F
0 ... 500 vpm 0 ... 5 000 vpm 16 G
0 ... 1 000 vpm 0 ... 10 000 vpm 17 H
0 ... 3 000 vpm 0 ... 10 000 vpm 18 J
0 ... 3 000 vpm 0 ... 30 000 vpm 19 K
0 ... 5 000 vpm 0 ... 15 000 vpm 20 L
0 ... 5 000 vpm 0 ... 50 000 vpm 21 M
0 ... 1 % 0 ... 3 % 22 N
0 ... 1 % 0 ... 10 % 23 P
0 ... 3 % 0 ... 10 % 24 Q
0 ... 3 % 0 ... 30 % 25 R
0 ... 5 % 0 ... 15 % 26 S
0 ... 5 % 0 ... 50 % 27 T
0 ... 10 % 0 ... 30 % 28 U
0 ... 10 % 0 ... 100 % 29 V
0 ... 30 % 0 ... 100 % 30 W
Operating software and documentation
German 0
English 1
French 2
Spanish 3
Italian 4

Siemens PA 01 · 2015 1/71


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit
1 ■ Selection and ordering data
Additional versions Order code Cannot be
combined
Add "-Z" to Article No. and specify Order codes.
Flow-type reference cell with reduced flow, 6 mm (channel 1) A20
Flow-type reference cell with reduced flow, ¼" (channel 1) A21
Flow-type reference cell with reduced flow, 6 mm (channel 2) A40
Flow-type reference cell with reduced flow, ¼" (channel 2) A41
Connection pipe
(can only be combined with the appropriate gas connection diameter and internal gas path materials)
• Made of titanium, 6 mm, complete with screwed gland, for sample gas side A22
• Made of titanium, 6 mm, complete with screwed gland, for reference gas side A23
• Made of titanium, ¼", complete with screwed gland, for sample gas side A24
• Made of titanium, ¼", complete with screwed gland, for reference gas side A25
• Made of stainless steel (mat. no. 1.4571), 6 mm, complete with screwed gland, for sample gas side A27
• Made of stainless steel (mat. no. 1.4571), 6 mm, complete with screwed gland, for reference gas side A28
• Made of stainless steel (mat. no. 1.4571), ¼", complete with screwed gland, for sample gas side A29
• Made of stainless steel (mat. no. 1.4571), ¼", complete with screwed gland, for reference gas side A30
Telescopic rails (2 units) A31
TAG labels (specific lettering based on customer information) B03
Kalrez gaskets in sample gas path (channel 1) B04
Kalrez gaskets in sample gas path (channel 2) B05
FM/CSA certificate – Class I Div 2 E20
Clean for O2 service (specially cleaned gas path; channels 1 + 2) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting (only in conjunction with an application no., e.g. extended measuring range) Y12
Extended special setting (only in conjunction with an application no., e.g. determination of Y13
cross-interferences)
TÜV version acc. to 13th and 17th BlmSchV (1st channel) Y17
TÜV version acc. to 13th and 17th BlmSchV (2nd channel) Y18
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with serial interface for the automotive industry (AK) C79451-A3480-D33
AUTOCAL function with 8 digital inputs/outputs for channel 1 or channel 2 C79451-A3480-D511
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA for channel 1 or channel 2 A5E00057307
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP for channel 1 or channel 2 A5E00057312
Set of Torx screwdrivers A5E34821625

1/72 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit

■ Selection and ordering data Article No.


1
ULTRAMAT 6 gas analyzer 7MB2124- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
Single-channel or dual-channel 19" rack unit for installation in cabinets
for measuring 2 or 3 IR components
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Gas connections for sample gas and reference gas
Pipe with 6 mm outer diameter 0 0 A21, A41
Pipe with ¼" outer diameter 1 1 A20, A40
Measured component Smallest measuring Largest measuring range
range
CO 0 ... 100 vpm 0 ... 1 000 vpm AA
NO 0 ... 100 vpm 0 ... 1 000 vpm
CO 0 ... 300 vpm 0 ... 3 000 vpm AB
NO 0 ... 300 vpm 0 ... 3 000 vpm
CO 0 ... 1 000 vpm 0 ... 10 000 vpm AC
NO 0 ... 1 000 vpm 0 ... 10 000 vpm
For CO/NO (TÜV; table "TÜV, 2 components in series", page 1/76)
CO2 0 ... 100 vpm 0 ... 1 000 vpm BA
CO 0 ... 100 vpm 0 ... 1 000 vpm
CO2 0 ... 300 vpm 0 ... 3 000 vpm BB
CO 0 ... 300 vpm 0 ... 3 000 vpm
CO2 0 ... 1 000 vpm 0 ... 10 000 vpm BC
CO 0 ... 1 000 vpm 0 ... 10 000 vpm
CO2 0 ... 3 000 vpm 0 ... 30 000 vpm BD
CO 0 ... 3 000 vpm 0 ... 30 000 vpm
CO2 0 ... 1 % 0 ... 10 % BE
CO 0 ... 1 % 0 ... 10 %
CO2 0 ... 3 % 0 ... 30 % BF
CO 0 ... 3 % 0 ... 30 %
CO2 0 ... 10 % 0 ... 100 % BG
CO 0 ... 10 % 0 ... 100 %
CO2 0 ... 10 % 0 ... 100 % CG
CH4 0 ... 10 % 0 ... 100 %
CO2 0 ... 300 vpm 0 ... 3 000 vpm DB
NO 0 ... 300 vpm 0 ... 3 000 vpm
Internal gas paths Sample chamber1) Reference chamber
(lining) (flow-type)
Hose made of FKM Aluminum Non-flow-type 0 0 0 A20, A21, A40, A41
(Viton) Aluminum Flow-type 1 1

Pipe made of titanium Tantalum Non-flow-type 4 4 A20, A21, A40, A41, Y02
Tantalum Flow-type 5 5 Y02
Stainless steel pipe Aluminum Non-flow-type 6 6 A20, A21, A40, A41
(mat. no. 1.4571) Tantalum Non-flow-type 8 8 A20, A21, A40, A41

With sample gas monitoring


Hose made of FKM Aluminum Non-flow-type 2 2 2 A20, A21, A40, A41
(Viton) Aluminum Flow-type 3 3

Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs/outputs each for channel 1 1
• With 8 additional digital inputs/outputs each for channel 1 and channel 2 2 2
• With serial interface for the automotive industry (AK), channel 1 3 3 E20
• With serial interface for the automotive industry (AK), 4 4 E20
channel 1 and channel 2
• With 8 additional digital inputs/outputs for channel 1 5
and PROFIBUS PA interface
• With 8 additional digital inputs/outputs each for channel 1 and channel 2 6 6
and PROFIBUS PA interface
• With 8 additional digital inputs/outputs for channel 1 7
and PROFIBUS DP interface
• With 8 additional digital inputs/outputs each for channel 1 and channel 2 8 8
and PROFIBUS DP interface
1)
Only for cell length 20 to 180 mm

Siemens PA 01 · 2015 1/73


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit
1 ■ Selection and ordering data Article No.
ULTRAMAT 6 gas analyzer 7MB2124- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
Single-channel or dual-channel 19" rack unit for installation in cabinets
for measuring 2 or 3 IR components
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Channel 2 Possible with measuring
Measured component range identification
Without channel 2 W W
CO 11 ... 30 A
CO highly selective (with optical filter) 12 ... 30 B
CO (TÜV; see table "TÜV single component", page 1/76) X
CO2 10 ... 30 C
CH4 13 ... 30 D
C2H2 15 ... 30 E
C2H4 15 ... 30 F
C2H6 14 ... 30 G
C3H6 14 ... 30 H
C3H8 13 ... 30 J
C4H6 15 ... 30 K
C4H10 14 ... 30 L
C6H14 14 ... 30 M
SO2 (TÜV; see table "TÜV single component", 13 ... 30 N
page 1/76)
NO (TÜV; see table "TÜV single component", 14 ... 20, 22 P
page 1/76)
NH3 (dry) 14 ... 30 Q Q
H2O 17 ... 20, 22 R R
N2O 13 ... 30 S
Smallest measuring Largest measuring Measuring range
range range identification
Without channel 2 X X A40, A41, B05
0 ... 5 vpm 0 ... 100 vpm 10 A
0 ... 10 vpm 0 ... 200 vpm 11 B
0 ... 20 vpm 0 ... 400 vpm 12 C
0 ... 50 vpm 0 ... 1 000 vpm 13 D
0 ... 100 vpm 0 ... 1 000 vpm 14 E
0 ... 300 vpm 0 ... 3 000 vpm 15 F
0 ... 500 vpm 0 ... 5 000 vpm 16 G
0 ... 1 000 vpm 0 ... 10 000 vpm 17 H
0 ... 3 000 vpm 0 ... 10 000 vpm 18 J
0 ... 3 000 vpm 0 ... 30 000 vpm 19 K
0 ... 5 000 vpm 0 ... 15 000 vpm 20 L
0 ... 5 000 vpm 0 ... 50 000 vpm 21 M
0 ... 1 % 0 ... 3 % 22 N
0 ... 1 % 0 ... 10 % 23 P
0 ... 3 % 0 ... 10 % 24 Q
0 ... 3 % 0 ... 30 % 25 R
0 ... 5 % 0 ... 15 % 26 S
0 ... 5 % 0 ... 50 % 27 T
0 ... 10 % 0 ... 30 % 28 U
0 ... 10 % 0 ... 100 % 29 V
0 ... 30 % 0 ... 100 % 30 W
Operating software and documentation
German 0
English 1
French 2
Spanish 3
Italian 4

1/74 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit

■ Selection and ordering data


1
Additional versions Order code Cannot be
combined
Add "-Z" to Article No. and specify Order codes.
Flow-type reference cell with reduced flow, 6 mm (channel 1) A20
Flow-type reference cell with reduced flow, ¼" (channel 1) A21
Flow-type reference cell with reduced flow, 6 mm (channel 2) A40
Flow-type reference cell with reduced flow, ¼" (channel 2) A41
Connection pipe
(can only be combined with the appropriate gas connection diameter and internal gas path materials)
• Made of titanium, 6 mm, complete with screwed gland, for sample gas side A22
• Made of titanium, 6 mm, complete with screwed gland, for reference gas side A23
• Made of titanium, ¼", complete with screwed gland, for sample gas side A24
• Made of titanium, ¼", complete with screwed gland, for reference gas side A25
• Made of stainless steel (mat. no. 1.4571), 6 mm, complete with screwed gland, for sample gas side A27
• Made of stainless steel (mat. no. 1.4571), 6 mm, complete with screwed gland, for reference gas side A28
• Made of stainless steel (mat. no. 1.4571), ¼", complete with screwed gland, for sample gas side A29
• Made of stainless steel (mat. no. 1.4571), ¼", complete with screwed gland, for reference gas side A30
Telescopic rails (2 units) A31
TAG labels (specific lettering based on customer information) B03
Kalrez gaskets in sample gas path (channel 1) B04
Kalrez gaskets in sample gas path (channel 2) B05
FM/CSA certificate – Class I Div 2 E20
Clean for O2 service (specially cleaned gas path; channels 1 + 2) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting (only in conjunction with an application no., e.g. extended measuring range) Y12
Extended special setting (only in conjunction with an application no., e.g. determination of Y13
cross-interferences)
TÜV version acc. to 13th and 17th BlmSchV (channel 1) Y17
TÜV version acc. to 13th and 17th BlmSchV (channel 2) Y18
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with serial interface for the automotive industry (AK) C79451-A3480-D33
AUTOCAL function with 8 digital inputs/outputs for channel 1 or channel 2 C79451-A3480-D511
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA for channel 1 or channel 2 A5E00057307
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP for channel 1 or channel 2 A5E00057312
Set of Torx screwdrivers A5E34821625

Siemens PA 01 · 2015 1/75


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit
1 TÜV single component
Component CO (TÜV) SO2 (TÜV) NO (TÜV)
Measuring range Smallest Largest Smallest Largest Smallest Largest
identification measuring range measuring range measuring range measuring range measuring range measuring range
from 0 to ... from 0 to ... from 0 to ... from 0 to ... from 0 to ... from 0 to ...
C 75 mg/m3 1 500 mg/m3
D 50 mg/m3 1 000 mg/m3 300 mg/m3 3 000 mg/m3
E 500 mg/m3 5 000 mg/m3 100 mg/m3 2 000 mg/m3
F 300 mg/m3 3 000 mg/m3 1 000 mg/m3 10 000 mg/m3 300 mg/m3 3 000 mg/m3
G 500 mg/m3 5 000 mg/m3 500 mg/m3 5 000 mg/m3
H 1 000 mg/m3 10 000 mg/m3 3 000 mg/m3 30 000 mg/m3 1 000 mg/m3 10 000 mg/m3
K 3 000 mg/m3 30 000 mg/m3 10 g/m3 100 g/m3 3 000 mg/m3 30 000 mg/m3
P 10 g/m3 100 g/m3 30 g/m3 300 g/m3 10 g/m3 100 g/m3
R 30 g/m3 300 g/m3 100 g/m3 1 000 g/m3 30 g/m3 300 g/m3
V 100 g/m3 1 160 g/m3 300 g/m3 2 630 g/m3 100 g/m3 1 250 g/m3

Example for ordering


ULTRAMAT 6, TÜV
Component: CO
Measuring range: 0 to 50 / 1 000 mg/m3
with hoses, non-flow-type reference compartment
without automatic adjustment (AUTOCAL)
230 V AC; German
7MB2121-0XD00-1AA0-Z +Y17

TÜV, 2 components in series


Component CO (TÜV) NO (TÜV)
Measuring range Smallest measuring range Largest measuring range Smallest measuring range Largest measuring range
identification from 0 to ... from 0 to ... from 0 to ... from 0 to ...
AA 75 mg/m3 1 000 mg/m3 200 mg/m3 2 000 mg/m3
AB 300 mg/m3 3 000 mg/m3 300 mg/m3 3 000 mg/m3
AC 1 000 mg/m3 10 000 mg/m3 1 000 mg/m3 10 000 mg/m3

Example for ordering


ULTRAMAT 6, TÜV, 2-component unit
Components: CO/NO + SO2
Measuring range: CO: 0 to 75 / 1 000 mg/m3, NO: 0 to 200 / 2 000 mg/m3, SO2: 0 to 75 / 1 500 mg/m3
with hoses, non-flow-type reference compartment
without automatic adjustment (AUTOCAL)
230 V AC; German
7MB2124-0AA00-1NC0-Z +Y17+Y18
Note: for 3 components take both tables into consideration.
Ordering information measured component N2O
Certification in accordance with AM0028 and AM0034 (Kyoto Protocol) for measuring N2O, measuring range 0 ... 300 ppm /
3 000 ppm.
Version: Standard device

1/76 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit

■ Dimensional drawings
1

s







8/75$0$7

 




















0










     









ULTRAMAT 6, 19“ unit, dimensions in mm (example: 1-channel version)

Siemens PA 01 · 2015 1/77


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit
1 ■ Schematics
Pin assignment (electrical and gas connections)

SUB-D 9F connector (RS 485)

M 5 GND
GND 9 R_Level-N-
4 NC It is possible to connect
8 RD/TD-N bus terminating resistors
3 RD/TD-P to pins 7 and 9.
+5 V 7 R_Level-P-
2 NC
6 NC
M 1 GND

SUB-D 15F connector

M 8 GND
15 Analog output 2-P For 2-component version only
7 Analog output 2-N of the ULTRAMAT part
14 Analog output 1-P Analog outputs isolated
6 Analog output 1-N (also from each other), RL: ≤ 750 Ω
13 NC
5 NC
12 Pressure correction Analog inputs
Analog input 2-P non-isolated,
M 4 Analog input 2-N Pressure correction
0 ... 20 mA/500 Ω
11 Analog input 1-P Correction of cross-interference or 0 ... 10 V
M 3 Analog input 1-N Correction of cross-interference (low-resistance)
10 Binary input 6-P Isolated via optocoupler
2 Binary input 5-P "0" = 0 V (0 ... 4.5 V)
9 Binary input 5 to 6-N "1" = 24 V (13 ... 33 V)
M 1 GND

SUB-D 25F connector

M 13 GND
25 Binary input 4-P Isolated via optocoupler
12 Binary input 3-P "0" = 0 V (0 ... 4.5 V)
24 Binary input 2-P "1" = 24 V (13 ... 33 V)
11 Binary input 1-P
23 Binary input 1 to 4-N
10
22 Relay 6
9
21
8 Relay 5
20
7
19 Relay 4 Contact load
6 max. 24 V/1 A, AC/DC; relay
18 contacts shown: relay coil has
5 Relay 3 zero current
17
4
16 Relay 2
3 1RWH
15 $OOFDEOHVWRWKHFRQQHFWRUVRUWHUPLQDOEORFNV
2 Relay 1 PXVWEHVKLHOGHGDQGUHVWDJDLQVWWKH
14 HQFORVXUHSRWHQWLDO
M 1 GND

ULTRAMAT 6, 19“ unit, pin assignment

1/78 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit
1
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ULTRAMAT 6, 19“ unit, pin assignment of AUTOCAL board and PROFIBUS connectors

Siemens PA 01 · 2015 1/79


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
19" rack unit
1
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ULTRAMAT 6, 19“ unit, gas and electrical connections (example: 2-channel version)

1/80 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device

■ Technical specifications
1
General information Gas inlet conditions
Measuring ranges 4, internally and externally switch- Permissible sample gas pressure
able; autoranging is also possible • With hoses (without pressure 600 … 1 500 hPa (absolute)
Smallest possible measuring range Dependent on the application, switch)
e.g. CO: 0 … 10 vpm, • With pipes (without pressure 600 … 1 500 hPa (absolute)
CO2 : 0 … 5 vpm switch)
Largest possible measuring range Dependent on the application - Ex (leakage compensation) 600 … 1 160 hPa (absolute)
Measuring range with suppressed Any zero point within - Ex (continuous purging) 600 … 1 500 hPa (absolute)
zero point 0 … 100 vol.% can be
implemented; smallest possible Purging gas pressure
span 20 %
• Permanent < 165 hPa above ambient pres-
Heated version 65 °C sure
Operating position Front wall, vertical • For short periods 250 hPa above ambient pressure
Conformity CE mark in accordance with Sample gas flow 18 … 90 l/h (0.3 … 1.5 l/min)
EN 50081-1, EN 50082-2
Sample gas temperature Min. 0 ... max. 50 °C, but above
Influence of interfering gases must be considered separately the dew point, for heated version
min. 0 … max. 80 °C
Design, enclosure
Sample gas humidity < 90 % RH (RH: relative humidity)
Weight Approx. 32 kg or dependent on measuring task
Degree of protection IP65 in accordance with Dynamic response
EN 60529, restricted breathing
enclosure to EN 50021 Warm-up period At room temperature < 30 min
(the technical specification will be
Electrical characteristics met after 2 hours)
Power supply 100 … 120 V AC (nominal range Delayed display (T90-time) Dependent on length of analyzer
of use 90 … 132 V), 48 … 63 Hz chamber, sample gas line and
or parameterizable damping
200 … 240 V AC (nominal range
of use 180 … 264 V), 48 … 63 Hz Damping (electrical time constant) 0 … 100 s, parameterizable

Power consumption Approx. 35 VA; approx. 330 VA Dead time (purging time of the gas Approximately 0.5 ... 5 s,
with heated version path in the unit at 1 l/min) depending on version

EMC In accordance with standard Time for device-internal signal pro- <1s
(Electromagnetic Compatibility) requirements of NAMUR NE21 cessing
(08/98) Pressure correction range
Electrical safety In accordance with EN 61010-1 Pressure sensor
• Heated units Overvoltage category II • Internal 700 … 1 200 hPa absolute
• Unheated units Overvoltage category III • External 700 … 1 500 hPa absolute
Fuse values (unheated unit) Measuring response (relating to sample gas pressure 1 013 hPa
• 100 ... 120 V F3: 1 T/250; F4: 1 T/250 absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)

• 200 ... 240 V F3: 0.63 T/250; F4: 0.63 T/250 Output signal fluctuation <  1 % of the smallest possible
measuring range according to
Fuse values (heated unit) rating plate
• 100 ... 120 V F1: 1 T/250; F2: 4 T/250 Zero point drift <  1 % of the current measuring
F3: 4 T/250; F4: 4 T/250 range/week
• 200 ... 240 V F1: 0.63 T/250; F2: 2.5 T/250 Measured-value drift <  1 % of the current measuring
F3: 2.5 T/250; F4: 2.5 T/250 range/week
Repeatability  1 % of the current measuring
range
Detection limit 1 % of the smallest possible mea-
suring range
Linearity error < 0.5 % of the full-scale value

Siemens PA 01 · 2015 1/81


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device
1 Influencing variables (relating to sample gas pressure 1 013 hPa
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Ambient temperature < 1 % of current measuring
range/10 K (with constant
receiver cell temperature)
Sample gas pressure When pressure compensation
has been switched on: < 0.15 %
of setpoint/1 % atmospheric pres-
sure change
Sample gas flow Negligible
Power supply < 0.1 % of the current measuring
range with rated voltage  10 %
Environmental conditions Application-specific measuring
influences possible if ambient air
contains measured component or
cross interference-sensitive
gases
Electrical inputs and outputs
Analog output 0/2/4 … 20 mA, isolated; load
750 
Relay outputs 6, with changeover contacts,
freely parameterizable, e.g. for
measuring range identification;
load: 24 V AC/DC/1 A, isolated,
non-sparking
Analog inputs 2, dimensioned for 0/2/4 ... 20 mA
for external pressure sensor and
accompanying gas influence cor-
rection (correction of cross-inter-
ference)
Binary inputs 6, designed for 24 V, isolated,
freely parameterizable, e.g. for
measuring range switchover
Serial interface RS 485
Options AUTOCAL function with 8 addi-
tional binary inputs and relay out-
puts, also with PROFIBUS PA or
PROFIBUS DP
Climatic conditions
Permissible ambient temperature -30 … +70 °C during storage and
transportation; 5 … 45 °C during
operation
Permissible humidity < 90 % RH (RH: relative humidity)
within average annual value, dur-
ing storage and transportation
(dew point must not be under-
shot)

1/82 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device
1
■ Selection and ordering data Article No.
ULTRAMAT 6 gas analyzer 7MB2111- 7 7 7 7 7 - 7 7 A 7 Cannot be combined
For installation in the field, single-channel, 1 component
Click on the Article No. for the online configuration in the PIA Life Cycle
Portal.
Gas connections
Ferrule screw connection for pipe, outer diameter 6 mm 0 0 A29
Ferrule screw connection for pipe, outer diameter ¼" 1 1 A28
Measured component Possible with measuring
range identification
CO 11 ... 30 A
CO highly selective (with optical filter) 12 ... 30 B
CO (TÜV; see table "TÜV single component", page 1/88) X
CO2 10 ... 30 C
CH4 13 ... 30 D
C2H2 15 ... 30 E
C2H4 15 ... 30 F
C2H6 14 ... 30 G
C3H6 14 ... 30 H
C3H8 13 ... 30 J
C4H6 15 ... 30 K
C4H10 14 ... 30 L
C6H14 14 ... 30 M
SO2 (TÜV; see table "TÜV single component", 13 ... 30 N
page 1/88)
NO (TÜV; see table "TÜV single component", 14 ... 20, 22 P
page 1/88)
NH3 (dry) 14 ... 30 Q Q
H2O 17 ... 20; 22 R R
(17 to 24, 26; heated)
N2O 13 ... 30 S
Smallest measuring Largest measuring Measuring range
range range identification
0 ... 5 vpm 0 ... 100 vpm 10 A
0 ... 10 vpm 0 ... 200 vpm 11 B
0 ... 20 vpm 0 ... 400 vpm 12 C
0 ... 50 vpm 0 ... 1 000 vpm 13 D
0 ... 100 vpm 0 ... 1 000 vpm 14 E
0 ... 300 vpm 0 ... 3 000 vpm 15 F
0 ... 500 vpm 0 ... 5 000 vpm 16 G
0 ... 1 000 vpm 0 ... 10 000 vpm 17 H
0 ... 3 000 vpm 0 ... 10 000 vpm 19 J
0 ... 3 000 vpm 0 ... 30 000 vpm 19 K
0 ... 5 000 vpm 0 ... 15 000 vpm 20 L
0 ... 5 000 vpm 0 ... 50 000 vpm 21 M
0 ... 1 % 0 ... 3 % 22 N
0 ... 1 % 0 ... 10 % 23 P
0 ... 3 % 0 ... 10 % 24 Q
0 ... 3 % 0 ... 30 % 25 R
0 ... 5 % 0 ... 15 % 26 S
0 ... 5 % 0 ... 50 % 27 T
0 ... 10 % 0 ... 30 % 28 U
0 ... 10 % 0 ... 100 % 29 V
0 ... 30 % 0 ... 100 % 30 W

Siemens PA 01 · 2015 1/83


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device
1 ■ Selection and ordering data Article No.
ULTRAMAT 6 gas analyzer 7MB2111- 7 7 7 7 7 - 7 7 A 7 Cannot be combined
For installation in the field, single-channel, 1 component
Internal gas paths Sample chamber Reference chamber
(lining) (flow-type)
Hose made of FKM Aluminum Non-flow-type 0 0 0 0 A28, A29
(Viton) Aluminum Flow-type 1 1 1
Pipe made of titanium Tantalum1) Non-flow-type 2 2 A28, A29, Y02
Tantalum1) Flow-type 3 3 Y02
Stainless steel pipe Aluminum Non-flow-type 6 6 A28, A29
(mat. no. 1.4571) Tantalum1) Non-flow-type 8 8 A28, A29

Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs/outputs 1
• With 8 digital inputs/outputs and PROFIBUS PA interface 6 6 E12
• With 8 digital inputs/outputs and PROFIBUS DP interface 7 7 E12
• With 8 digital inputs/outputs and PROFIBUS PA Ex i 8 8
Power supply
Standard unit and acc. to ATEX II 3G version (Zone 2)
• 100 ... 120 V AC, 48 ... 63 Hz 0 0
• 200 ... 240 V AC, 48 ... 63 Hz 1 1
ATEX II 2G versions (Zone 1), incl. certificate
• 100 ... 120 V AC, 48 ... 63 Hz, according to ATEX II 2G2) 2 2 2
(operating mode: leakage compensation)
• 200 ... 240 V AC, 48 ... 63 Hz, according to ATEX II 2G2) 3 3 3
(operating mode: leakage compensation)
• 100 ... 120 V AC, 48 ... 63 Hz, according to ATEX II 2G2) 6 6 6
(operating mode: continuous purging)
• 200 ... 240 V AC, 48 ... 63 Hz, according to ATEX II 2G2) 7 7 7
(operating mode: continuous purging)
Heating of internal gas paths and analyzer unit
Without A
With (max. 65 °C) B
Language (supplied documentation, software)
German 0
English 1
French 2
Spanish 3
Italian 4
1)
Only for cell length 20 to 180 mm
2)
Only in connection with an approved purging unit

1/84 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device

■ Selection and ordering data


1
Additional versions Order code
Add "-Z" to Article No. and specify Order codes.
Flow-type reference cell with reduced flow, 6 mm A28
Flow-type reference cell with reduced flow, ¼" A29
TAG labels (specific lettering based on customer information) B03
Kalrez gaskets in sample gas path B04
Ex versions
Possible combinations: see: Table "Ex configurations – principle selection criteria", page 5/16
ATEX II 3G certificate; restricted breathing enclosure, non-flammable gases E11
ATEX II 3G certificate; flammable gases E12
FM/CSA certificate – Class I Div 2 E20
ATEX II 3D certificate; potentially explosive dust atmospheres
• In non-hazardous gas zone E40
• In Ex zone acc. to ATEX II 3G, non-flammable gases E41
• In Ex zone acc. to ATEX II 3G, flammable gases1) E42
BARTEC EEx p control unit "Leakage compensation" E71
BARTEC EEx p control unit "Continuous purging" E72
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting (only in conjunction with an application no., e.g. extended measuring range) Y12
Extended special setting Y13
(only in conjunction with an application no., e.g. determination of cross-interferences)
TÜV version acc. to 13th and 17th BlmSchV Y17
Additional units for Ex versions Article No.
Category ATEX II 2G (zone 1)
BARTEC EEx p control unit, 230 V, "leakage compensation" 7MB8000-2BA
BARTEC EEx p control unit, 115 V, "leakage compensation" 7MB8000-2BB
BARTEC EEx p control unit, 230 V, "continuous purging" 7MB8000-2CA
BARTEC EEx p control unit, 115 V, "continuous purging" 7MB8000-2CB
Ex isolation amplifier 7MB8000-3AB
Ex isolating relay, 230 V 7MB8000-4AA
Ex isolating relay, 110 V 7MB8000-4AB
Differential pressure switch for corrosive and non-corrosive gases 7MB8000-5AA
Stainless steel flame arrestor 7MB8000-6BA
Hastelloy flame arrestor 7MB8000-6BB
Category ATEX II 3G (Zone 2)
BARTEC EEx p control unit, 230 V, "continuous purging" 7MB8000-2CA
BARTEC EEx p control unit, 115 V, "continuous purging" 7MB8000-2CB
FM/CSA (Class I Div. 2)
Ex purging unit MiniPurge FM 7MB8000-1AA
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with 8 digital inputs/outputs A5E00064223
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057315
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057318
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA Ex i (firmware 4.1.10 required) A5E00057317
Set of Torx screwdrivers A5E34821625
1)
Only in connection with an approved purging unit

Siemens PA 01 · 2015 1/85


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device
1
■ Selection and ordering data Article No.
ULTRAMAT 6 gas analyzer 7MB2112- 7 7 7 7 7 - 7 7 A 7 Cannot be combined
For installation in the field, single-channel, 2 components
Click on the Article No. for the online configuration in the PIA Life Cycle
Portal.
Gas connections
Ferrule screw connection for pipe, outer diameter 6 mm 0 0 A29
Ferrule screw connection for pipe, outer diameter ¼" 1 1 A28
Measured component Smallest measuring Largest measuring range
range
CO 0 ... 100 vpm 0 ... 1 000 vpm AA
NO 0 ... 100 vpm 0 ... 1 000 vpm
CO 0 ... 300 vpm 0 ... 3 000 vpm AB
NO 0 ... 300 vpm 0 ... 3 000 vpm
CO 0 ... 1 000 vpm 0 ... 10 000 vpm AC
NO 0 ... 1 000 vpm 0 ... 10 000 vpm
For CO/NO (TÜV; see table "TÜV, 2 components in series", page 1/88)
CO2 0 ... 100 vpm 0 ... 1 000 vpm BA
CO 0 ... 100 vpm 0 ... 1 000 vpm
CO2 0 ... 300 vpm 0 ... 3 000 vpm BB
CO 0 ... 300 vpm 0 ... 3 000 vpm
CO2 0 ... 1 000 vpm 0 ... 10 000 vpm BC
CO 0 ... 1 000 vpm 0 ... 10 000 vpm
CO2 0 ... 3 000 vpm 0 ... 30 000 vpm BD
CO 0 ... 3 000 vpm 0 ... 30 000 vpm
CO2 0 ... 1 % 0 ... 10 % BE
CO 0 ... 1 % 0 ... 10 %
CO2 0 ... 3 % 0 ... 30 % BF
CO 0 ... 3 % 0 ... 30 %
CO2 0 ... 10 % 0 ... 100 % BG
CO 0 ... 10 % 0 ... 100 %
CO2 0 ... 10 % 0 ... 100 % CG
CH4 0 ... 10 % 0 ... 100 %
CO2 0 ... 100 vpm 0 ... 1 000 vpm DA
NO 0 ... 100 vpm 0 ... 1 000 vpm
CO2 0 ... 300 vpm 0 ... 3 000 vpm DB
NO 0 ... 300 vpm 0 ... 3 000 vpm
Internal gas paths Sample chamber (lining) Reference chamber
(flow-type)
Hose made of FKM Aluminum Non-flow-type 0 0 0 A28, A29
(Viton) Aluminum Flow-type 1 1

Pipe made of titanium Tantalum1) Non-flow-type 2 2 A28, A29, Y02


Tantalum1) Flow-type 3 3 Y02
Stainless steel pipe Aluminum Non-flow-type 6 6 A28, A29
(mat. no. 1.4571) Tantalum1) Non-flow-type 8 8 A28, A29
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs/outputs 1
• With 8 digital inputs/outputs and PROFIBUS PA interface 6 6
• With 8 digital inputs/outputs and PROFIBUS DP interface 7 7
• With 8 digital inputs/outputs and PROFIBUS PA Ex i 8 8
Power supply
Standard unit and acc. to ATEX II 3G version (Zone 2)
• 100 ... 120 V AC, 48 ... 63 Hz 0 0
• 200 ... 240 V AC, 48 ... 63 Hz 1 1
ATEX II 2G versions (Zone 1), incl. certificate
• 100 ... 120 V AC, 48 ... 63 Hz, according to ATEX II 2G2) 2 2 2
(operating mode: leakage compensation)
• 200 ... 240 V AC, 48 ... 63 Hz, according to ATEX II 2G2) 3 3 3
(operating mode: leakage compensation)
• 100 ... 120 V AC, 48 ... 63 Hz, according to ATEX II 2G2) 6 6 6
(operating mode: continuous purging)
• 200 ... 240 V AC, 48 ... 63 Hz, according to ATEX II 2G2) 7 7 7
(operating mode: continuous purging)
Heating of internal gas paths and analyzer unit
none A
With (max. 65 °C) B

1/86 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device

■ Selection and ordering data Article No.


1
ULTRAMAT 6 gas analyzer 7MB2112- 7 7 7 7 7 - 7 7 A 7 Cannot be combined
For installation in the field, single-channel, 2 components
Language (supplied documentation, software)
German 0
English 1
French 2
Spanish 3
Italian 4
1)
Only for cell length 20 to 180 mm.
2)
See also next page "Additional units for Ex versions".

Additional versions Order code


Add "-Z" to Article No. and specify Order codes.
Flow-type reference cell with reduced flow, 6 mm A28
Flow-type reference cell with reduced flow, ¼" A29
TAG labels (specific lettering based on customer information) B03
Kalrez gaskets in sample gas path B04
Ex versions
Possible combinations: see: Table "Ex configurations – principle selection criteria", page 5/16
ATEX II 3G certificate; restricted breathing enclosure, non-flammable gases E11
ATEX II 3G certificate; flammable gases E12
CSA certificate – Class I Div 2 E20
ATEX II 3D certificate; potentially explosive dust atmospheres
• In non-hazardous gas zone E40
• In Ex zone acc. to ATEX II 3G, non-flammable gases E41
• In Ex zone acc. to ATEX II 3G, flammable gases E42
BARTEC EEx p control unit "Leakage compensation" E71
BARTEC EEx p control unit "Continuous purging" E72
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting (only in conjunction with an application no., e.g. extended measuring range) Y12
Extended special setting Y13
(only in conjunction with an application no., e.g. determination of cross-interferences)
TÜV version acc. to 13th and 17th BlmSchV Y17
Additional units for Ex versions Article No.
Category ATEX II 2G (zone 1)
BARTEC EEx p control unit, 230 V, "leakage compensation" 7MB8000-2BA
BARTEC EEx p control unit, 115 V, "leakage compensation" 7MB8000-2BB
BARTEC EEx p control unit, 230 V, "continuous purging" 7MB8000-2CA
BARTEC EEx p control unit, 115 V, "continuous purging" 7MB8000-2CB
Ex isolation amplifier 7MB8000-3AB
Ex isolating relay, 230 V 7MB8000-4AA
Ex isolating relay, 110 V 7MB8000-4AB
Differential pressure switch for corrosive and non-corrosive gases 7MB8000-5AA
Stainless steel flame arrestor 7MB8000-6BA
Hastelloy flame arrestor 7MB8000-6BB
Category ATEX II 3G (Zone 2)
BARTEC EEx p control unit, 230 V, "continuous purging" 7MB8000-2CA
BARTEC EEx p control unit, 115 V, "continuous purging" 7MB8000-2CB
FM/CSA (Class I Div. 2)
Ex purging unit MiniPurge FM 7MB8000-1AA
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with 8 digital inputs/outputs A5E00064223
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057315
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057318
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA Ex i (firmware 4.1.10 required) A5E00057317
Set of Torx screwdrivers A5E34821625

Siemens PA 01 · 2015 1/87


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device
1 TÜV, single component
(only with additional suffix Z (Y17, Y18))
Component CO (TÜV) SO2 (TÜV) NO (TÜV)
Measuring range Smallest Largest Smallest Largest Smallest Largest
identification measuring range measuring range measuring range measuring range measuring range measuring range
from 0 to ... from 0 to ... from 0 to ... from 0 to ... from 0 to ... from 0 to ...
C 75 mg/m3 1 500 mg/m3
D 50 mg/m3 1 000 mg/m3 300 mg/m3 3 000 mg/m3
E 500 mg/m3 5 000 mg/m3 100 mg/m3 2 000 mg/m3
F 300 mg/m3 3 000 mg/m3 1 000 mg/m3 10 000 mg/m3 300 mg/m3 3 000 mg/m3
G 500 mg/m3 5 000 mg/m3 500 mg/m3 5 000 mg/m3
H 1 000 mg/m3 10 000 mg/m3 3 000 mg/m3 30 000 mg/m3 1 000 mg/m3 10 000 mg/m3
K 3 000 mg/m3 30 000 mg/m3 10 g/m3 100 g/m3 3 000 mg/m3 30 000 mg/m3
P 10 g/m3 100 g/m3 30 g/m3 300 g/m3 10 g/m3 100 g/m3
R 30 g/m3 300 g/m3 100 g/m3 1 000 g/m3 30 g/m3 300 g/m3
V 100 g/m3 1 160 g/m3 300 g/m3 2 630 g/m3 100 g/m3 1 250 g/m3

Example for ordering


ULTRAMAT 6, TÜV (1-component unit)
Component: CO
Measuring range: 0 to 50 / 1 000 mg/m3
with hoses, non-flow-type reference compartment
without automatic adjustment (AUTOCAL)
230 V AC; without heating, German
7MB2111-0XD00-1AA0-Z +Y17

TÜV, 2 components in series


Component CO (TÜV) NO (TÜV)
Measuring range Smallest measuring range Largest measuring range Smallest measuring range Largest measuring range
identification from 0 to ... from 0 to ... from 0 to ... from 0 to ...
AA 75 mg/m3 1 000 mg/m3 200 mg/m3 2 000 mg/m3
AB 300 mg/m3 3 000 mg/m3 300 mg/m3 3 000 mg/m3
AC 1 000 mg/m3 10 000 mg/m3 1 000 mg/m3 10 000 mg/m3

Example for ordering


ULTRAMAT 6, TÜV (2 components in series)
Components: CO/NO
Measuring range CO: 0 to 75 / 1 000 mg/m3, NO: 0 to 200 / 2 000 mg/m3
with hoses, non-flow-type reference compartment
without automatic adjustment (AUTOCAL)
230 V AC; without heating, German
7MB2112-0AA00-1AA0-Z +Y17
Note: for 3 components take both tables into consideration.
Ordering information measured component N2O
Certification in accordance with AM0028 and AM0034 (Kyoto Protocol) for measuring N2O,
measuring range 0 to 300 ppm / 3 000 ppm.
Version: Standard device

1/88 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device

■ Dimensional drawings
1

148

184

250
259

394
418
112
20
42
77
0

271
253
237
222

201

127

65
58

438 311
328 26.5 20

14

s ULTRAMAT 6
440
480

14

ULTRAMAT 6, field unit, dimensions in mm

Siemens PA 01 · 2015 1/89


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device
1 ■ Schematics
Pin assignment (electrical and gas connections)

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ULTRAMAT 6, field device, pin and terminal assignment

1/90 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device
1
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ULTRAMAT 6, field device, pin and terminal assignment of the AUTOCAL board and PROFIBUS connectors

Siemens PA 01 · 2015 1/91


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Field device
1

a b c d 7
5
1 3
9
2 4

8
6

Gas connections Electrical connections


1 Sample gas inlet a-c Signal cable (Ø 10 ... 14 mm)
(analog + digital): cable gland M20x1.5
2 Sample gas outlet Clamping
gland for pipe d Interface connection: (Ø 7 ... 12 mm)
3 Reference gas inlet (option) Ø 6 mm or ¼" cable gland M20x1.5
e Power supply: (Ø 7 ... 12 mm)
4 Reference gas outlet (option) cable gland M20x1.5

5 - 8 Purging gas inlets/outlets, stubs Ø 10 mm or 3/8"


9 Connection atmospheric pressure sensor, stubs Ø ¼"

ULTRAMAT 6, field device, gas connections and electrical connections

Documentation

■ Selection and ordering data


Operating instructions Article No.
ULTRAMAT 6 / OXYMAT 6
Gas analyzer for IR-absorbing gases
and oxygen
• German C79000-G5200-C143
• English C79000-G5276-C143
• French C79000-G5277-C143
• Spanish C79000-G5278-C143
• Italian C79000-G5272-C143

1/92 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT 6
Suggestions for spare parts

■ Selection and ordering data


1

7MB-2111/2 Ex
Description 2 years 5 years Article No.
(quantity) (quantity)

7MB-2121

7MB-2123

7MB-2124

7MB-2111

7MB-2112
Analyzer unit
O-ring for cover (window) x x x x x x 2 4 C79121-Z100-A24
Cover (cell length 20 ... 180 mm) x x x x x x 2 2 C79451-A3462-B151
Cover (cell length 0.2 ... 6 mm) x x x x x x 2 2 C79451-A3462-B152
O-rings, set x x x x x x 1 C79451-A3462-D501
Sample gas path
O-ring (hose clip) x x x 2 4 C71121-Z100-A159
Pressure switch x x x 1 2 C79302-Z1210-A2
Flow indicator x x x 1 2 C79402-Z560-T1
Hose clip x x x x x x 1 C79451-A3478-C9
Heating cartridge (heated unit) x x x 1 W75083-A1004-F120
Electronics
Temperature fuse (heated unit) x x 1 W75054-T1001-A150
Fuse (device fuse) x 1 2 A5E00061505
Temperature controller - x x x 1 A5E00118527
electronics, 230 V AC
Temperature controller - x x x 1 A5E00118530
electronics, 115 V AC
Fan, 24 V DC (heated unit) x x x 1 A5E00302916
Front plate with keyboard x x x 1 1 C79165-A3042-B504
Temperature sensor x x x 1 C79165-A3044-B176
Adapter plate, LCD/keyboard x x x x x 1 1 C79451-A3474-B605
Motherboard, with firmware: see x x x x x x 1
spare parts list
LC display x x x x x 1 1 W75025-B5001-B1
Connector filter x x x x x 1 W75041-E5602-K2
Fusible element, T 0.63 A/250 V x x x x x 2 3 W79054-L1010-T630
Fusible element, T 1 A/250 V x x x x x x 2 3 W79054-L1011-T100
Fusible element, T 1.6 A/250 V x x 2 3 W79054-L1011-T160
Fusible element, T 2.5 A/250 V x x x 2 3 W79054-L1011-T250

If the ULTRAMAT 6 is supplied with a specially cleaned gas path for high oxygen content ("Cleaned for O2 service"), please ensure
that you specify this when ordering spare parts. This is the only way to guarantee that the gas path will continue to comply with the
special requirements for this version.

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
General information
1 ■ Overview ■ Application
Fields of application
• Measurement for boiler control in incineration plants
• Emission measurements in incineration plants
• Measurement in the automotive industry (test benches)
• Process gas concentrations in chemical plants
• Trace measurements in pure gas processes
• Environmental protection
• TLV (Threshold Limit Value) monitoring at places of work
• Quality monitoring
Special versions
• Special applications
Besides the standard combinations, special applications con-
cerning material in the gas path, material in the sample cells
(e.g. Titan, Hastelloy C22) and sample components are also
available on request.
• TÜV version/QAL
TÜV-approved versions of the ULTRAMAT/OXYMAT 6 are
available for measurement of CO, NO, SO2 and O2 according
The ULTRAMAT/OXYMAT 6 gas analyzer is a practical combina- to 13th and 17th BlmSchV and TA Luft.
tion of the ULTRAMAT 6 and OXYMAT 6 analyzers in a single en- Smallest TÜV-approved and permitted measuring ranges:
closure. - 1-component analyzer
CO: 0 to 50 mg/m3
The ULTRAMAT 6 channel operates according to the NDIR two-
NO: 0 to 100 mg/m3
beam alternating light principle and measures one or two gases
SO2: 0 to 75 mg/m3
highly selectively whose absorption bands lie in the infrared
- 2-component analyzer (series connection)
wavelength range from 2 to 9 m, such as CO, CO2, NO, SO2,
CO: 0 to 75 mg/m3
NH3, H2O as well as CH4 and other hydrocarbons.
NO: 0 to 200 mg/m3
The OXYMAT 6 channel is based on the paramagnetic alternat-
All larger measuring ranges are also approved.
ing pressure method and is used to measure oxygen in gases.
Furthermore, the TÜV-approved versions of the
■ Benefits ULTRAMAT/OXYMAT 6 comply with the requirements of
EN 14956 and QAL 1 according to EN 14181. Conformity of the
• Corrosion-resistant materials in gas path (option) devices with both standards is TÜV-certified.
- Measurement possible in highly corrosive sample gases
Determination of the analyzer drift according to EN 14181
• Sample chambers can be cleaned as required on site (QAL 3) can be carried out manually or also with a PC using the
- Cost savings due to reuse after contamination SIPROM GA maintenance and servicing software. In addition,
• Open interface architecture (RS 485, RS 232, PROFIBUS) selected manufacturers of emission evaluation computers offer
• SIPROM GA network for maintenance and servicing informa- the possibility for downloading the drift data via the analyzer’s
tion (option) serial interface and to automatically record and process it in the
evaluation computer.
ULTRAMAT channel • Flow-type reference compartment
• High selectivity with double-layer detector and optical coupler - The flow through the reference compartment should be
- Reliable measurements even in complex gas mixtures adapted to the sample gas flow
• Low detection limits - The gas supply of the reduced flow-type reference
- Measurements with low concentrations compartment should have an upstream pressure of 3 000 to
5 000 hPa (abs.). Then a restrictor will automatically adjust
OXYMAT channel the flow to approximately 8 hPa
• Paramagnetic alternating pressure principle
- Small measuring ranges (0 to 0.5 % or 99.5 to 100 % O2) ■ Design
- Absolute linearity
• Detector element has no contact with the sample gas 19" rack unit
- Can be used to measure corrosive gases • 19" rack unit with 4 HU for installation
- Long service life - in hinged frame
• Physically suppressed zero through suitable selection of refer- - in cabinets with or without telescopic rails
ence gas (air or O2), e.g. 98 to 100 % O2 for purity monitor- • Front plate can be swung down for servicing purposes
ing/air separation (laptop connection)
• Internal gas paths: hose made of FKM (Viton) or pipe made of
titanium or stainless steel
• Gas connections for sample gas inlet and outlet: pipe diame-
ter 6 mm or 1/4"
• Flow indicator for sample gas on front plate (option)
• Sample chamber (OXYMAT channel) – with or without flow-
type compensation branch – made of stainless steel (mat. no.
1.4571) or of tantalum for highly corrosive sample gases
(e.g. HCl, Cl2, SO2, SO3, etc.)
• Monitoring (option) of sample gas and/or reference gas
(both channels)

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
General information
Display and control panel Inputs and outputs (per channel) 1
• Large LCD panel for simultaneous display of: • One analog output for each measured component
- Measured value (digital and analog displays) • Two analog inputs freely configurable (e.g. correction of
- Status bar cross-interference or external pressure sensor)
- Measuring ranges
• Six binary inputs freely configurable (e.g. for measurement
• Contrast of LCD panel adjustable using menu range switchover, processing of external signals from sample
• Permanent LED backlighting preparation)
• Washable membrane keyboard with five softkeys • Six relay outputs freely configurable e.g. for fault, mainte-
• Menu-driven operation for parameterization, test functions, nance request, limit alarm, external solenoid valves)
adjustment • Expansion by eight additional binary inputs and eight addi-
• User help in plain text tional relay outputs e.g. for autocalibration with up to four
calibration gases
• Graphic display of concentration trend; programmable time
intervals Communication
• Bilingual operating software: RS 485 present in the basic unit (connection at the rear; for the
German/English, English/Spanish, French/English, rack unit also behind the front plate).
Italian/English, Spanish/English
Options
• AK interface for the automotive industry with extended func-
tions
• RS 485/RS 232 converter
• RS 485/Ethernet converter
• RS 485/USB converter
• Connection to networks via PROFIBUS DP/PA interface
• SIPROM GA software as the service and maintenance tool

LED backlit graphic


Dimensions Two code levels
display and
selectable according to NAMUR
membrane keyboard
(e.g. ppm, vpm, (maintenance and
with noticeable click
%, mg/m³) specialist level)

Status line for ULTRAMAT


channel to display the
unit status (programmable) Operation with
menu control
using five softkeys
Display of
concentrations as
numbers and bargraph
(ULTRAMAT channel) Display of current
measuring ranges
Display of
concentrations as
Status line for
numbers and bargraph
OXYMAT channel
(OXYMAT channel)
to display the
Display of unit status
start-of-scale and (programmable)
full-scale values
ESC key
to abort inputs
Keyboard to
enter values

INFO key
for help in plain text

CLEAR key
to delete inputs
ENTER key MEAS key
to accept to return to
input values measurement mode

ULTRAMAT/OXYMAT 6, membrane keyboard and graphic display

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
General information
1 Designs – Parts touched by sample gas, standard
Gas path ULTRAMAT channel 19" rack unit
With hoses Bushing Stainless steel, mat. no. 1.4571
Hose FKM (e.g. Viton)
Sample chamber:
• Body Aluminum
• Lining Aluminum
• Fitting Stainless steel, mat. no. 1.4571,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
• Window CaF2, adhesive: E353,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
With pipes Bushing Titanium
Pipe Titanium,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
Sample chamber:
• Body Aluminum
• Lining Tantalum (only for cell length 20 mm to 180 mm)
• Window CaF2, adhesive: E353,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
With pipes Bushing Stainless steel, mat. no. 1.4571
Pipe Stainless steel, mat. no. 1.4571,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
Sample chamber:
• Body Aluminum
• Lining Aluminum or tantalum (Ta: only for cell length 20 mm to 180 mm)
• Window CaF2, adhesive: E353,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
Flow indicator Measurement pipe Duran glass
Variable area Duran glass
Suspension boundary PTFE (Teflon)
Angle pieces FKM (e.g. Viton)
Pressure switch Membrane FKM (e.g. Viton)
Enclosure PA 6.3T

Options
Gas path ULTRAMAT channel 19" rack unit
Flow indicator Measurement pipe Duran glass
Variable area Duran glass
Suspension boundary PTFE (Teflon)
Angle pieces FKM (e.g. Viton)
Pressure switch Membrane FKM (e.g. Viton)
Enclosure PA 6.3T

Versions – Parts wetted by sample gas, special applications (examples)


Gas path ULTRAMAT channel 19" rack unit
With pipes Bushing e.g. Hastelloy C22
Pipe e.g. Hastelloy C22,
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)
Sample chamber:
• Body e.g. Hastelloy C22
• Window CaF2, without adhesive
O-ring: FKM (e.g. Viton) or FFKM (Kalrez)

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
General information
Designs – Parts touched by sample gas, standard 1
Gas path OXYMAT channel 19" rack unit
With hoses Bushing Stainless steel, mat. no. 1.4571
Hose FKM (e.g. Viton)
Sample chamber Stainless steel, mat. no. 1.4571 or tantalum
Fittings for sample chamber Stainless steel, mat. no. 1.4571
Restrictor PTFE (e.g. Teflon)
O-rings FKM (e.g. Viton)
With pipes Bushing Titanium
Pipe Titanium
Sample chamber Stainless steel, mat. no. 1.4571 or Tantalum
Restrictor Titanium
O-rings FKM (Viton) or FFKM (Kalrez)
With pipes Bushing Stainless steel, mat. no. 1.4571
Pipe Stainless steel, mat. no. 1.4571
Sample chamber Stainless steel, mat. no. 1.4571 or Tantalum
Restrictor Stainless steel, mat. no. 1.4571
O-rings FKM (Viton) or FFKM (Kalrez)
With pipes Bushing Hastelloy C 22
Pipe Hastelloy C 22
Sample chamber Stainless steel, mat. no. 1.4571 or Tantalum
Restrictor Hastelloy C 22
O-rings FKM (e.g. Viton) or FFKM (e.g. Kalrez)

Options
Gas path ULTRAMAT channel 19" rack unit
and OXYMAT channel
Flow indicator Measurement pipe Duran glass
Variable area Duran glass
Suspension boundary PTFE (Teflon)
Angle pieces FKM (e.g. Viton)
Pressure switch Membrane FKM (e.g. Viton)
Enclosure PA 6.3T

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
General information
1 Gas path
Legend for the gas path figures
1 Sample gas inlet (OXYMAT channel) 10 Connection of pressure sensor (ULTRAMAT channel)
2 Sample gas outlet (OXYMAT channel) 11 Restrictor (in reference gas inlet)
3 Not used 12 O2 physical system
4 Reference gas inlet 13 Pressure sensor
5 Sample gas inlet (ULTRAMAT channel) 14 Pressure switch in sample gas path (option)
6 Sample gas outlet (ULTRAMAT channel) 15 Flow indicator in sample gas path (option)
7 Reference gas outlet (ULTRAMAT channel, option) 16 IR physical system
8 Reference gas inlet (ULTRAMAT channel, option) 17 Filter
9 Purging gas 18 Pressure switch (reference gas) (option)

9 10 5 6 1 2 4

17

18 P

11

P
13
12

16

P P
14 14

P 13
F F
15 15
ULTRAMAT/OXYMAT 6, gas path (example) IR channel without flow-type reference side

9 10 5 6 8 7 1 2 4

17

18 P

11

P
13
12

16

P P
14 14

P 13
F F
15 15
ULTRAMAT/OXYMAT 6, gas path (example) IR channel with flow-type reference side

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ULTRAMAT/OXYMAT 6
General information

■ Function
1
Principle of operation, ULTRAMAT channel
The ULTRAMAT channel operates according to the infrared two-
beam alternating light principle with double-layer detector and 1
optical coupler.
2
The measuring principle is based on the molecule-specific ab-
sorption of bands of infrared radiation. The absorbed wave-
lengths are characteristic to the individual gases, but may par-
tially overlap. This results in cross-sensitivities which are
reduced to a minimum by the following measures:
3
• Gas-filled filter cell (beam divider)
4
• Double-layer detector with optical coupler
• Optical filters if necessary
The figure shows the measuring principle. An IR source (1)
which is heated to approx. 700 ºC and which can be shifted to
balance the system is divided by the beam divider (3) into two
equal beams (sample and reference beams). The beam divider 5
also acts as a filter cell.
6
The reference beam passes through a reference cell (8) filled
with N2 (a non-infrared-active gas) and reaches the right-hand
side of the detector (11) practically unattenuated. The sample
beam passes through the sample chamber (7) through which
the sample gas flows and reaches the left-hand side of the de-
tector (10) attenuated to a lesser or greater extent depending on 7 8
the concentration of the sample gas. The detector is filled with a
defined concentration of the gas component to be measured.
The detector is designed as a double-layer detector. The center
of the absorption band is preferentially absorbed in the upper
detector layer, the edges of the band are absorbed to approxi-
mately the same extent in the upper and lower layers. The upper 9
and lower detector layers are connected together via the micro-
flow sensor (12). This coupling means that the spectral sensitiv-
ity has a very narrow band.
The optical coupler (13) lengthens the lower receiver cell layer 10 11
optically. The infrared absorption in the second detector layer is 12
varied by changing the slider position (14). It is thus possible to
individually minimize the influence of interfering components.
A chopper (5) rotates between the beam divider and the sample
chamber and interrupts the two beams alternately and periodi-
cally. If absorption takes place in the sample chamber, a pulsat-
ing flow is generated between the two detector levels which is 13
converted by the microflow sensor (12) into an electric signal.
The microflow sensor consists of two nickel-plated grids heated
14
to approximately 120 ºC, which, along with two supplementary
resistors, form a Wheatstone bridge. The pulsating flow together
with the dense arrangement of the Ni grids causes a change in
1 IR source, adjustable 8 Reference cell
resistance. This leads to an offset in the bridge, which is depen-
dent on the concentration of the sample gas. 2 Optical filter 9 Sample gas outlet
3 Beam divider 10 Detector, meas. side
Note 4 Eddy current drive 11 Detector, reference side
The sample gases must be fed into the analyzers free of dust. 5 Chopper 12 Microflow sensor
Condensation should be prevented from occurring in the sample 6 Sample gas inlet 13 Optical coupler
chambers. Therefore, the use of gas modified for the measuring 7 Sample cell 14 Slider, adjustable
task is necessary in most application cases.
ULTRAMAT channel, principle of operation
As far as possible, the ambient air of the analyzer should not
have a large concentration of the gas components to be mea- Channels with electronically suppressed zero point only differ
sured. from the standard version in the measuring range parameteriza-
tion.
Flow-type reference sides with reduced flow must not be oper-
ated with flammable or toxic gases. Physically suppressed zeros can be provided as a special ap-
plication.
Flow-type reference sides with reduced flow and an O2 content
> 70 % may only be used together with Y02.

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
General information
1 Principle of operation, OXYMAT channel

In contrast to almost all other gases, oxygen is paramagnetic.
This property is utilized as the measuring principle by the
OXYMAT channel.
Oxygen molecules in an inhomogeneous magnetic field are  
drawn in the direction of increased field strength due to their
paramagnetism. When two gases with different oxygen contents
meet in a magnetic field, a pressure difference is produced
between them.
One gas (1) is a reference gas (N2, O2 or air), the other is the 
sample gas (5). The reference gas is introduced into the sample
chamber (6) through two channels (3). One of these reference
gas streams meets the sample gas within the area of a magnetic  
D3
field (7). Because the two channels are connected, the pressure,
which is proportional to the oxygen content, causes a cross flow.
This flow is converted into an electric signal by a microflow sen- 
sor (4).

The microflow sensor consists of two nickel-plated grids heated
to approximately 120 ºC, which, along with two supplementary
resistors, form a Wheatstone bridge. The pulsating flow results
in a change in the resistance of the Ni grids. This leads to an off-
set in the bridge which is dependent on the oxygen concentra-
tion of the sample gas. 2  

Because the microflow sensor is located in the reference gas 2


stream, the measurement is not influenced by the thermal con- 2
ductivity, the specific heat or the internal friction of the sample
gas. This also provides a high degree of corrosion resistance 2
because the microflow sensor is not exposed to the direct influ- 2
ence of the sample gas. 2

By using a magnetic field with alternating strength (8), the effect


of the background flow in the microflow sensor is not detected,
and the measurement is thus independent of the instrument’s
operating position.
The sample chamber is directly in the sample path and has a
small volume, and the microflow sensor is a low-lag sensor. This 
results in a very short response time.
Vibrations frequently occur at the place of installation and may
falsify the measured signal (noise). A further microflow sensor
(10) through which no gas passes acts as a vibration sensor. Its
signal is applied to the measured signal as compensation.
If the density of the sample gas deviates by more than 50 % from
that of the reference gas, the compensation microflow sensor 
(10) is flushed with reference gas just like the measuring sensor
(4) (option).
1 Reference gas inlet
Note
2 Restrictors
The sample gases must be fed into the analyzers free of dust. 3 Reference gas channels
Condensation should be prevented from occurring in the sample 4 Microflow sensor for measurement
chambers. Therefore, gas modified for the measuring tasks is 5 Sample gas inlet
necessary in most application cases. 6 Sample cell
7 Paramagnetic effect
8 Electromagnet with alternating field strength
9 Sample gas and reference gas outlet
10 Microflow sensor in compensation system
(without flow)

OXYMAT channel, principle of operation

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
General information
Essential characteristics ULTRAMAT channel 1
• Dimension of measured value freely selectable (e.g. vpm, • Differential measuring ranges with flow-type reference cell
mg/m3) • Internal pressure sensor for correction of variations in atmo-
• Four freely-parameterizable measuring ranges per compo- spheric pressure in the range 700 to 1 200 hPa absolute
nent • External pressure sensor - only with piping as the gas path -
• Measuring ranges with suppressed zero point possible can be connected for correction of variations in the process
• Measuring range identification gas pressure in the range 700 to 1 500 hPa absolute (option)
• Galvanically isolated signal output 0/2/4 to 20 mA per compo- • Sample chambers for use in presence of highly corrosive sam-
nent ple gases (e.g. tantalum layer or Hastelloy C22)
• Automatic or manual measuring range switchover selectable; OXYMAT channel
remote switching is also possible • Monitoring of sample gas and/or reference gas (option)
• Storage of measured values possible during adjustments • Different smallest measuring ranges (0.5 %, 2.0 % or
• Time constants selectable within wide limits (static/dynamic 5.0 % O2)
noise suppression); i.e. the response time of the analyzer or • Analyzer unit with flow-type compensation circuit (option): a
component can be matched to the respective measuring task flow is passed through the compensation branch to reduce
• Short response time the vibration dependency in the case of highly different densi-
• Low long-term drift ties of the sample and reference gases
• Measuring point switchover for up to 6 measuring points • Internal pressure sensor for correction of pressure variations
(programmable) in sample gas (range 500 to 2 000 hPa absolute)
• Measuring point identification • External pressure sensor - only with piping as the gas path -
can be connected for correction of variations in the sample
• Monitoring of sample gas flow (option) gas pressure up to 3 000 hPa absolute (option)
• Two control levels with separate authorization codes to pre- • Monitoring of reference gas with reference gas connection
vent unintentional and unauthorized inputs 3 000 to 5 000 hPa (option), absolute
• Automatic, parameterizable measuring range calibration • Sample chamber for use in presence of highly corrosive sam-
• Simple handling using a numerical membrane keyboard and ple gases
operator prompting
• Operation based on NAMUR recommendation
• Customer-specific analyzer options such as:
- Customer acceptance
- TAG labels
- Drift recording

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
General information
1 Reference gases
Measuring range Recommended reference gas Reference gas connection Remarks
pressure
0 to ... vol.% O2 N2 2 000 … 4 000 hPa above sample The reference gas flow is set auto-
gas pressure (max. 5 000 hPa matically to 5 … 10 ml/min (up to
... to 100 vol.% O2 (suppressed O2 absolute) 20 ml/min with flow-type compensa-
zero point with full-scale value tion branch)
100 vol. % O2)
Around 21 vol.% O2 (suppressed Air 100 hPa with respect to sample gas
zero point with 21 vol.% O2 within pressure which may vary by max.
the measuring span) 50 hPa around the atmospheric
pressure

Table 1: Reference gases for OXYMAT channel


Correction of zero error / cross-sensitivities (OXYMAT channel)
Accompanying gas Deviation from zero point in Accompanying gas Deviation from zero point in
(concentration 100 vol.%) vol.% O2 absolute (concentration 100 vol.%) vol.% O2 absolute
Organic gases Inert gases
Ethane C2H6 -0.49 Helium He +0.33
Ethene (ethylene) C2H4 -0.22 Neon Ne +0.17
Ethine (acetylene) C2H2 -0.29 Argon Ar -0.25
1.2 butadiene C4H6 -0.65 Krypton Kr -0.55
1.3 butadiene C4H6 -0.49 Xenon Xe -1.05
n-butane C4H10 -1.26
iso-butane C4H10 -1.30 Inorganic gases
1-butene C4H8 -0.96 Ammonia NH3 -0.20
iso-butene C4H8 -1.06 Hydrogen bromide HBr -0.76
Dichlorodifluoromethane (R12) CCl2F2 -1.32 Chlorine Cl2 -0.94
Acetic acid CH3COOH -0.64 Hydrogen chloride HCl -0.35
n-heptane C7H16 -2.40 Dinitrogen monoxide N2O -0.23
n-hexane C6H14 -2.02 Hydrogen fluoride HF +0.10
Cyclo-hexane C6H12 -1.84 Hydrogen iodide HI -1.19
Methane CH4 -0.18 Carbon dioxide CO2 -0.30
Methanol CH3OH -0.31 Carbon monoxide CO +0.07
n-octane C8H18 -2.78 Nitrogen oxide NO +42.94
n-pentane C5H12 -1.68 Nitrogen N2 0.00
iso-pentane C5H12 -1.49 Nitrogen dioxide NO2 +20.00
Propane C3H8 -0.87 Sulfur dioxide SO2 -0.20
Propylene C3H6 -0.64 Sulfur hexafluoride SF6 -1.05
Trichlorofluoromethane (R11) CCl3F -1.63 Hydrogen sulfide H2S -0.44
Vinyl chloride C2H3Cl -0.77 Water H2O -0.03
Vinyl fluoride C2H3F -0.55 Hydrogen H2 +0.26
1.1 vinylidene chloride C2H2Cl2 -1.22
Table 2: Zero point error due to diamagnetism or paramagnetism of some accompanying gases with reference to nitrogen at 60 °C und 1 000 hPa
absolute (according to IEC 1207/3)
Conversion to other temperatures:
The deviations from the zero point listed in Table 2 must be multiplied by a correction factor (k):
• with diamagnetic gases: k = 333 K / ( [°C] + 273 K)
• with paramagnetic gases: k = [333 K / ( [°C] + 273 K)]2
(All diamagnetic gases have a negative deviation from zero point)

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit

■ Technical specifications
1
ULTRAMAT/OXYMAT 6, 19" rack unit Technical data, ULTRAMAT channel
General information Measuring ranges 4, internally and externally switch-
able; autoranging is also possible
Operating position Front wall, vertical
Smallest possible measuring range Dependent on the application,
Conformity CE mark in accordance with e.g.
EN 50081-1, EN 50082-2 CO: 0 ... 10 vpm
Design, enclosure CO2: 0 ... 5 vpm
Weight Approx. 21 kg Largest possible measuring range Dependent on the application
Degree of protection IP20 according to EN 60529 Measuring ranges with suppressed Any zero point within 0 ... 100
zero point vol.% can be implemented; small-
Electrical characteristics est possible span 20 %
EMC In accordance with standard Characteristic Linearized
(Electromagnetic Compatibility) requirements of NAMUR NE21
(08/98) Influence of interfering gases must be considered separately
Electrical safety According to EN 61010-1, Gas inlet conditions
overvoltage category III Permissible sample gas pressure
Power supply 100 ... 120 V AC (nominal range • Without pressure switch 700 ... 1 500 hPa (absolute)
of use 90 ... 132 V), 48 ... 63 Hz or
200 ... 240 V AC (nominal range • With integrated pressure switch 700 ... 1 300 hPa (absolute)
of use 180 ... 264 V), 48 ... 63 Hz
Sample gas flow 18 ... 90 l/h (0.3 ... 1.5 l/min)
Power consumption Approx. 70 VA
Sample gas temperature Min. 0 to max. 50 °C, but above
Fuse values 120 ... 120 V: F1/F2 = T 1.6 A the dew point
200 ... 240 V: F1/F2 = T 1 A
Sample gas humidity < 90 % (relative humidity), or
Electrical inputs and outputs (per channel) dependent on measuring task,
non-condensing
Analog output 0/2/4 ... 20 mA, isolated;
max. load 750  Dynamic response
Relay outputs 6, with changeover contacts, Warm-up period At room temperature < 30 min
freely parameterizable, e.g. for (the technical specification will be
measuring range identification; met after 2 hours)
load: 24 V AC/DC/1 A, isolated,
non-sparking Delayed display (T90-time) Dependent on length of analyzer
chamber, sample gas line and
Analog inputs 2, dimensioned for parameterizable damping
0/2/4 … 20 mA for external pres-
sure sensor and correction of Damping (electrical time constant) 0 ... 100 s, parameterizable
influence of accompanying gas Dead time (purging time of the gas Approx. 0.5 ... 5 s, depending on
(correction of cross-interference) path in the unit at 1 l/min) version
Binary inputs 6, designed for 24 V, isolated, Time for device-internal signal <1s
freely parameterizable, e.g. for processing
measuring range switchover
Pressure correction range
Serial interface RS 485
Pressure sensor
Options AUTOCAL function each with
8 additional binary inputs and • Internal 700 ... 1 200 hPa absolute
relay outputs, also with • External 700 ... 1 500 hPa absolute
PROFIBUS PA or PROFIBUS DP
Measuring response (relating to sample gas pressure 1 013 hPa
Climatic conditions absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Permissible ambient temperature -30 ... +70 °C during storage and Output signal fluctuation <  1 % of the smallest possible
transportation, 5 … 45 °C during measuring range according to
operation rating plate
Permissible humidity < 90 % relative humidity, during Zero point drift <  1 % of the current measuring
storage and transportation (dew range/week
point must not be undershot)
Measured-value drift <  1 % of the current measuring
range/week
Repeatability  1 % of the current measuring
range
Detection limit 1 % of the smallest possible
measuring range
Linearity error < 0.5 % of the full-scale value

Siemens PA 01 · 2015 1/103


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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
1 Influencing variables (relating to sample gas pressure 1 013 hPa Pressure correction range
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Pressure sensor
Ambient temperature < 1 % of current measuring
range/10 K (with constant • Internal 500 ... 2 000 hPa absolute
receiver cell temperature) • External 500 ... 3 000 hPa absolute
Sample gas pressure • When pressure compensation Measuring response (relating to sample gas pressure 1 013 hPa
has been switched on: < 0.15 % absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
of the span/1 % change in atmo-
spheric pressure Output signal fluctuation < 0.75 % of the smallest possible
measuring range according to
• When pressure compensation rating plate, with electronic
has been switched off: < 1.5 % damping constant of 1 s (corre-
of the span/1 % change in atmo- sponds to  0.25 % at 2)
spheric pressure
Zero point drift < 0.5 %/month of the smallest
Sample gas flow Negligible possible measuring span accord-
Power supply < 0.1 % of the current measuring ing to rating plate
range with rated voltage  10 % Measured-value drift  0.5 %/month of the current mea-
Environmental conditions Application-specific measuring suring range
influences possible if ambient air Repeatability  1 %/month of the current mea-
contains measured component or suring range
cross interference-sensitive
gases Detection limit 1 % of the current measuring
range
Technical data, OXYMAT channel Linearity error 1 % of the current measuring
range
Measuring ranges 4, internally and externally switch-
able; automatic measuring range Influencing variables (relating to sample gas pressure 1 013 hPa
switchover also possible absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Smallest possible span (relating to 0.5 vol.%, 2 vol.% or 5 vol.% O2 Ambient temperature • < 0.5 %/10 K referred to smallest
sample gas pressure 1 000 hPa possible span according to rat-
absolute, 0.5 l/min sample gas flow ing plate
and 25 °C ambient temperature) • With measuring span
Largest possible measuring range 100 vol.% O2 0.5 %: 1 %/10 K
Measuring ranges with suppressed Any zero point within Sample gas pressure (with air • When pressure compensation
zero point 0 ... 100 vol.% can be imple- (100 hPa) as reference gas, correc- has been switched off: < 2 % of
mented, provided that a suitable tion of the atmospheric pressure the current measuring range/
reference gas is used fluctuations is only possible if the 1 % atmospheric pressure
sample gas can vent to ambient air) change
Gas inlet conditions
• When pressure compensation
Permissible sample gas pressure has been switched on: < 0.2 %
of the current measuring range/
• With pipes 500 ... 3 000 hPa absolute
1 % atmospheric pressure
• With hoses change
- Without pressure switch 500 ... 1 500 hPa absolute Accompanying gases Deviation from zero point corre-
sponding to paramagnetic or dia-
- With pressure switch 500 ... 1 300 hPa absolute magnetic deviation of
Sample gas flow 18 ... 60 l/h (0.3 ... 1 l/min) accompanying gas
Sample gas temperature 0 ... 50 ºC Sample gas flow < 1 % of the smallest possible
span according to rating plate
Sample gas humidity < 90 % RH (relative humidity) with a change in flow of 0.1 l/min
Reference gas pressure 2 000 ... 4 000 hPa above sam- within the permissible flow range
(high-pressure version) ple gas pressure, but max. Power supply < 0.1 % of the current measuring
5 000 hPa range with rated voltage  10 %
Reference gas pressure Min. 100 hPa above sample gas
(low-pressure version) pressure
Dynamic response
Warm-up period At room temperature < 30 min
(the technical specification will be
met after 2 hours)
Delayed display (T90 time) Min. 1.5 ... 3.5 s, depending on
version
Damping (electrical time constant) 0 ... 100 s, parameterizable
Dead time (purging time of the gas Approx. 0.5 ... 2.5 s, depending
path in the unit at 1 l/min) on version
Time for device-internal signal <1s
processing

1/104 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
1
■ Selection and ordering data Article No.
ULTRAMAT/OXYMAT 6 gas analyzer 7MB2023- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
19" rack unit for installation in cabinets
Combined measurement of IR-absorbing gas and O2
Click on the Article No. for the online configuration in the PIA Life Cycle
Portal.
Gas connections for sample gas and reference gas
Pipe with 6 mm outer diameter 0 0 A21
Pipe with ¼" outer diameter 1 1 A20
Smallest possible measuring span O2
0.5 % reference gas pressure 3 000 hPa A
0.5 % reference gas pressure 100 hPa (external pump) B B B A26, Y02
2 % reference gas pressure 3 000 hPa C
2 % reference gas pressure 100 hPa (external pump) D D D A26, Y02
5% reference gas pressure 3 000 hPa E
5% reference gas pressure 100 hPa (external pump) F F F A26, Y02
Sample chamber (OXYMAT channel)
Non-flow-type compensation branch
• Made of stainless steel, mat. no. 1.4571 A
• Made of tantalum B
Flow-type compensation branch
• Made of stainless steel, mat. no. 1.4571 C C
• Made of tantalum D D
Internal gas paths Sample chamber1) Reference chamber
(lining) (flow-type)
(both channels) (ULTRAMAT channel) (ULTRAMAT channel)
Hose made of FKM Aluminum Non-flow-type 0 0 0 A20, A21
(Viton) Aluminum Flow-type 1 1

Pipe made of titanium Tantalum Non-flow-type 4 4 A20, A21, Y02


Tantalum Flow-type 5 5 Y02
Stainless steel pipe Aluminum Non-flow-type 6 6 A20, A21
(mat. no. 1.4571) Tantalum Non-flow-type 8 8 A20, A21

With sample gas monitoring (both channels)


Hose made of FKM Aluminum Non-flow-type 2 2 2 A20, A21
(Viton) Aluminum Flow-type 3 3

Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs and outputs for OXYMAT channel 1
• With 8 additional digital inputs and outputs for ULTRAMAT channel 2
• With 8 additional digital inputs and 8 additional digital outputs for 3
ULTRAMAT channel and OXYMAT channel
• With serial interface for the automotive industry (AK) 5 5 Y02
• With 8 additional digital inputs/outputs 6
and PROFIBUS PA interface for
ULTRAMAT channel and OXYMAT channel
• With 8 additional digital inputs/outputs 7
and PROFIBUS DP interface for
ULTRAMAT channel and OXYMAT channel
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Footnotes, see next page

Siemens PA 01 · 2015 1/105


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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
1 ■ Selection and ordering data Article No.
ULTRAMAT/OXYMAT 6 gas analyzer 7MB2023- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
19" rack unit for installation in cabinets
Combined measurement of IR-absorbing gas and O2
ULTRAMAT channel Possible with measuring
Measured component range identification
CO 112), 12 ... 30 A
CO highly selective (with optical filter) 122), 13 ... 30 B
CO (TÜV; see table "TÜV single component (IR channel)", page 1/111) X
CO2 102), 11 ... 30 C
CH4 132), 14 ... 30 D
C2H2 152), 16 ... 30 E
C2H4 152), 16 ... 30 F
C2H6 142), 15 ... 30 G
C3H6 142), 15 ... 30 H
C3H8 132), 14 ... 30 J
C4H6 152), 16 ... 30 K
C4H10 142), 15 ... 30 L
C6H14 142), 15 ... 30 M
SO2 (TÜV; see table "TÜV single component 132), 14 ... 30 N
(IR channel)", page 1/111)
NO (TÜV; see table "TÜV single component 142), 15 ... 20, 22 P
(IR channel)", page 1/111)
NH3 (dry) 142), 15 ... 30 Q Q
H2O 172), 18 ... 20, 22 R R
N2O 132), 14 ... 30 S
Smallest measuring Largest measuring Measuring range
range range identification
0 ... 5 vpm 0 ... 100 vpm 10 A
0 ... 10 vpm 0 ... 200 vpm 11 B
0 ... 20 vpm 0 ... 400 vpm 12 C
0 ... 50 vpm 0 ... 1 000 vpm 13 D
0 ... 100 vpm 0 ... 1 000 vpm 14 E
0 ... 300 vpm 0 ... 3 000 vpm 15 F
0 ... 500 vpm 0 ... 5 000 vpm 16 G
0 ... 1 000 vpm 0 ... 10 000 vpm 17 H
0 ... 3 000 vpm 0 ... 10 000 vpm 18 J
0 ... 3 000 vpm 0 ... 30 000 vpm 19 K
0 ... 5 000 vpm 0 ... 15 000 vpm 20 L
0 ... 5 000 vpm 0 ... 50 000 vpm 21 M
0 ... 1 % 0 ... 3 % 22 N
0 ... 1 % 0 ... 10 % 23 P
0 ... 3 % 0 ... 10 % 24 Q
0 ... 3 % 0 ... 30 % 25 R
0 ... 5 % 0 ... 15 % 26 S
0 ... 5 % 0 ... 50 % 27 T
0 ... 10 % 0 ... 30 % 28 U
0 ... 10 % 0 ... 100 % 29 V
0 ... 30 % 0 ... 100 % 30 W
Operating software and documentation
German 0
English 1
French 2
Spanish 3
Italian 4
1) Only for cell length 20 to 180 mm
2) Can be ordered as special application (no. 3100 with order code Y12)

1/106 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit

■ Selection and ordering data


1
Additional versions Order code Cannot be combined
Add "-Z" to Article No. and specify Order codes.
Flow-type reference cell with reduced flow, 6 mm A20
(ULTRAMAT channel)1)
Flow-type reference cell with reduced flow, ¼" A21
(ULTRAMAT channel)1)
Reference gas monitoring (pressure switch ... 3 000 hPa), A26
for OXYMAT channel only
Connection pipes
(can only be combined with the appropriate gas connection diameter and internal gas path
materials)
• Titanium connection pipe, 6 mm, A22
complete with screwed gland, for sample gas side
• Titanium connection pipe, ¼", A24
complete with screwed gland, for sample gas side
• Stainless steel connection pipe (mat. no. 1.4571), 6 mm, A27
complete with screwed gland, for sample gas side
• Stainless steel connection pipe (mat. no. 1.4571), ¼", A29
complete with screwed gland, for sample gas side
Telescopic rails (2 units) A31
Kalrez gaskets in sample gas path (O2 side) B01
TAG labels (specific lettering based on customer information) B03
Kalrez gaskets in sample gas path (IR side) B04
FM/CSA certificate – Class I Div 2 E20
Clean for O2 service (specially cleaned gas path) Y02
(ULTRAMAT channel and OXYMAT channel)
Measuring range indication in plain text2), if different from the standard setting Y11
Special setting (only in conjunction with an application no., e.g. extended measuring range, Y12
only ULTRAMAT channel)
Extended special setting (only in conjunction with an application no., e.g. determination of inter- Y13
ference influences, only ULTRAMAT channel)
TÜV version acc. to 13th and 17th BlmSchV (only ULTRAMAT channel) Y17 E20
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with serial interfaces for the automotive industry (AK) C79451-A3480-D33
AUTOCAL function with 8 digital inputs/outputs C79451-A3480-D511
for ULTRAMAT channel or OXYMAT channel
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057307
for ULTRAMAT channel or OXYMAT channel
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057312
for ULTRAMAT channel or OXYMAT channel
Set of Torx screwdrivers A5E34821625
1)
Cannot be combined with non-flow-type reference cell.
2)
Standard setting: Smallest measuring range
25 % of largest measuring range
50 % of largest measuring range
Largest measuring range } in % or
ppm (vpm)

Siemens PA 01 · 2015 1/107


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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
1
■ Selection and ordering data Article No.
ULTRAMAT/OXYMAT 6 gas analyzer 7MB2024- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
19" rack unit for installation in cabinets
Combined measurement of IR-absorbing gas and O2
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Gas connections for sample gas and reference gas
Pipe with 6 mm outer diameter 0 0 A21
Pipe with ¼" outer diameter 1 1 A20
Smallest possible measuring span O2
0.5 % reference gas pressure 3 000 hPa A
0.5 % reference gas pressure 100 hPa (external pump) B B B A26, Y02
2 % reference gas pressure 3 000 hPa C
2 % reference gas pressure 100 hPa (external pump) D D D A26, Y02
5 % reference gas pressure 3 000 hPa E
5 % reference gas pressure 100 hPa (external pump) F F F A26, Y02
Sample chamber (OXYMAT channel)
Non-flow-type compensation branch
• Made of stainless steel, mat. no. 1.4571 A
• Made of tantalum B
Flow-type compensation branch
- Made of stainless steel, mat. no. 1.4571 C C
- Made of tantalum D D
Internal gas paths Sample chamber1) Reference chamber
(lining) (flow-type)
(both channels) (ULTRAMAT channel) (ULTRAMAT channel)
Hose made of FKM Aluminum Non-flow-type 0 0 A20, A21
(Viton) Aluminum Flow-type 1

Pipe made of titanium Tantalum Non-flow-type 4 4 A20, A21, Y02


Tantalum Flow-type 5 5 Y02
Stainless steel pipe Aluminum Non-flow-type 6 6 A20, A21
(mat. no. 1.4571) Tantalum Non-flow-type 8 8 A20, A21

With sample gas monitoring (both channels)


Hose made of FKM Aluminum Non-flow-type 2 2 A20, A21
(Viton) Aluminum Flow-type 3

Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs and outputs for 1
ULTRAMAT channel and OXYMAT channel
• With serial interface for the automotive industry (AK) 5 5 Y02
• With 8 additional digital inputs/outputs and PROFIBUS PA interface for 6
ULTRAMAT channel and OXYMAT channel
• With 8 additional digital inputs/outputs and PROFIBUS DP interface for 7
ULTRAMAT channel and OXYMAT channel
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Footnote, see next page

1/108 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit

■ Selection and ordering data Article No.


1
ULTRAMAT/OXYMAT 6 gas analyzer 7MB2024- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
19" rack unit for installation in cabinets
Combined measurement of IR-absorbing gas and O2
ULTRAMAT channel Smallest measuring range Largest measuring range
Measured component
CO/NO CO 0 ... 100 vpm 0 ... 1 000 vpm AH
NO 0 ... 300 vpm 0 ... 1 000 vpm
CO/NO CO 0 ... 300 vpm 0 ... 3 000 vpm AJ
NO 0 ... 500 vpm 0 ... 3 000 vpm
CO/NO CO 0 ... 1 000 vpm 0 ... 10 000 vpm AC
NO 0 ... 1 000 vpm 0 ... 10 000 vpm
For CO/NO (TÜV; see table "TÜV, 2 components in series", page 1/111)
CO2/CO CO2 0 ... 100 vpm 0 ... 1 000 vpm BA
CO 0 ... 100 vpm 0 ... 1 000 vpm
CO2/CO CO2 0 ... 300 vpm 0 ... 3 000 vpm BB
CO 0 ... 300 vpm 0 ... 3 000 vpm
CO2/CO CO2 0 ... 1 000 vpm 0 ... 10 000 vpm BC
CO 0 ... 1 000 vpm 0 ... 10 000 vpm
CO2/CO CO2 0 ... 3 000 vpm 0 ... 30 000 vpm BD
CO 0 ... 3 000 vpm 0 ... 30 000 vpm
CO2/CO CO2 0 ... 1 % 0 ... 10 % BE
CO 0 ... 1 % 0 ... 10 %
CO2/CO CO2 0 ... 3 % 0 ... 30 % BF
CO 0 ... 3 % 0 ... 30 %
CO2/CO CO2 0 ... 10 % 0 ... 100 % BG
CO 0 ... 10 % 0 ... 100 %
CO2/CH4 CO2 0 ... 10 % 0 ... 100 % CG
CH4 0 ... 10 % 0 ... 100 %
CO2/NO CO2 0 ... 300 vpm 0 ... 3 000 vpm DJ
NO 0 ... 500 vpm 0 ... 3 000 vpm
Operating software and documentation
German 0
English 1
French 2
Spanish 3
Italian 4
1)
Only for cell length 20 to 180 mm

Siemens PA 01 · 2015 1/109


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
1 ■ Selection and ordering data
Additional versions Order code Cannot be combined
Add "-Z" to Article No. and specify Order codes.
Flow-type reference cell with reduced flow, 6 mm (ULTRAMAT channel)1) A20
1)
Flow-type reference cell with reduced flow, ¼" (ULTRAMAT channel) A21
Reference gas monitoring (pressure switch ... 3 000 hPa), for OXYMAT channel only A26
Connection pipes
(can only be combined with the appropriate gas connection diameter and internal gas
path materials)
• Titanium connection pipe, 6 mm, complete with screwed gland, for sample gas side A22
• Titanium connection pipe, ¼", complete with screwed gland, for sample gas side A24
• Stainless steel connection pipe (mat. no. 1.4571), 6 mm, complete with screwed gland, A27
for sample gas side
• Stainless steel connection pipe (mat. no. 1.4571), ¼", complete with screwed gland, A29
for sample gas side
Telescopic rails (2 units) A31
Kalrez gaskets in sample gas path (O2 side) B01
TAG labels (specific lettering based on customer information) B03
Kalrez gaskets in sample gas path (IR side) B04
FM/CSA certificate – Class I Div 2 E20
Clean for O2 service (specially cleaned gas path) Y02
(ULTRAMAT channel and OXYMAT channel)
Measuring range indication in plain text2), if different from the standard setting Y11
Special setting (only in conjunction with an application no., Y12
e.g. extended measuring range, only ULTRAMAT channel)
Extended special setting (only in conjunction with an application no., Y13
e.g. determination of interference influences, only ULTRAMAT channel)
TÜV version acc. to 13th and 17th BlmSchV (only ULTRAMAT channel) Y17 E20
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with serial interfaces for the C79451-A3480-D33
automotive industry (AK)
AUTOCAL function with 8 digital inputs/outputs C79451-A3480-D511
for ULTRAMAT channel or OXYMAT channel
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057307
for ULTRAMAT channel or OXYMAT channel
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057312
for ULTRAMAT channel or OXYMAT channel
Set of Torx screwdrivers A5E34821625
1) Cannot be combined with non-flow-type reference cell.
2) Standard setting: Smallest measuring range
25 % of largest measuring range
50 % of largest measuring range
Largest measuring range } in % or
ppm (vpm)

1/110 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
TÜV, single component (IR channel) 1
Component CO (TÜV) SO2 (TÜV) NO (TÜV)
Measuring range Smallest Largest Smallest Largest Smallest Largest
identification measuring range measuring range measuring range measuring range measuring range measuring range
from 0 to ... from 0 to ... from 0 to ... from 0 to ... from 0 to ... from 0 to ...
C 75 mg/m3 1 500 mg/m3
D 50 mg/m3 1 000 mg/m3 300 mg/m3 3 000 mg/m3
E 500 mg/m3 5 000 mg/m3 100 mg/m3 2 000 mg/m3
F 300 mg/m3 3 000 mg/m3 1 000 mg/m3 10 000 mg/m3 300 mg/m3 3 000 mg/m3
G 500 mg/m3 5 000 mg/m3 500 mg/m3 5 000 mg/m3
H 1 000 mg/m3 10 000 mg/m3 3 000 mg/m3 30 000 mg/m3 1 000 mg/m3 10 000 mg/m3
K 3 000 mg/m3 30 000 mg/m3 10 g/m3 100 g/m3 3 000 mg/m3 30 000 mg/m3
P 10 g/m3 100 g/m3 30 g/m3 300 g/m3 10 g/m3 100 g/m3
R 30 g/m3 300 g/m3 100 g/m3 1 000 g/m3 30 g/m3 300 g/m3
V 100 g/m3 1 160 g/m3 300 g/m3 2 630 g/m3 100 g/m3 1 250 g/m3

Example for ordering


ULTRAMAT/OXYMAT 6, TÜV
IR channel
Component: CO
Measuring range: 0 to 50/1 000 mg/m3
with hoses, non-flow-type reference compartment
without automatic adjustment (AUTOCAL)
230 V AC; German
7MB2023-0EA00-1XD0-Z +Y17

TÜV, two components in series


Component CO (TÜV) NO (TÜV)
Measuring range Smallest measuring range Largest measuring range Smallest measuring range Largest measuring range
identification from 0 to ... from 0 to ... from 0 to ... from 0 to ...
AH 75 mg/m3 1 000 mg/m3 200 mg/m3 2 000 mg/m3
AJ 300 mg/m3 3 000 mg/m3 500 mg/m3 3 000 mg/m3
AC 1 000 mg/m3 10 000 mg/m3 1 000 mg/m3 10 000 mg/m3

Example for ordering


ULTRAMAT/OXYMAT 6, TÜV
IR channel
Components: CO/NO
Measuring range CO: 0 to 75 / 1 000 mg/m3, NO: 0 to 200/2 000 mg/m3
with hoses, non-flow-type reference cell
without automatic adjustment (AUTOCAL)
230 V AC; German
7MB2024-0EA00-1AH0-Z +Y17

Siemens PA 01 · 2015 1/111


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
1 ■ Dimensional drawings

s







8/75$0$72;<0$7












 

0 
























ULTRAMAT/OXYMAT 6, 19“ unit, dimensions in mm

1/112 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit

■ Schematics
1
Pin assignment (electrical and gas connections)

SUB-D 9F connector (RS 485)

M 5 GND
GND 9 R_Level-N-
4 NC It is possible to connect
8 RD/TD-N bus terminating resistors
3 RD/TD-P to pins 7 and 9.
+5 V 7 R_Level-P-
2 NC
6 NC
M 1 GND

SUB-D 15F connector

M 8 GND
15 Analog output 2-P For 2-component version only
7 Analog output 2-N of the ULTRAMAT part
14 Analog output 1-P Analog outputs isolated
6 Analog output 1-N (also from each other), RL: ≤ 750 Ω
13 NC
5 NC
12 Pressure correction Analog inputs
Analog input 2-P non-isolated,
M 4 Analog input 2-N Pressure correction
0 ... 20 mA/500 Ω
11 Analog input 1-P Correction of cross-interference or 0 ... 10 V
M 3 Analog input 1-N Correction of cross-interference (low-resistance)
10 Binary input 6-P Isolated via optocoupler
2 Binary input 5-P "0" = 0 V (0 ... 4.5 V)
9 Binary input 5 to 6-N "1" = 24 V (13 ... 33 V)
M 1 GND

SUB-D 25F connector

M 13 GND
25 Binary input 4-P Isolated via optocoupler
12 Binary input 3-P "0" = 0 V (0 ... 4.5 V)
24 Binary input 2-P "1" = 24 V (13 ... 33 V)
11 Binary input 1-P
23 Binary input 1 to 4-N
10
22 Relay 6
9
21
8 Relay 5
20
7
19 Relay 4 Contact load
6 max. 24 V/1 A, AC/DC; relay
18 contacts shown: relay coil has
5 Relay 3 zero current
17
4
16 Relay 2
3 1RWH
15 $OOFDEOHVWRWKHFRQQHFWRUVRUWHUPLQDOEORFNV
2 Relay 1 PXVWEHVKLHOGHGDQGUHVWDJDLQVWWKH
14 HQFORVXUHSRWHQWLDO
M 1 GND

ULTRAMAT/OXYMAT 6, 19“ unit, pin assignment

Siemens PA 01 · 2015 1/113


© Siemens AG 2014

Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
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ULTRAMAT/OXYMAT 6, 19“ unit, pin assignment of AUTOCAL board and PROFIBUS connectors

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Continuous Gas Analyzers, extractive


ULTRAMAT/OXYMAT 6
19" rack unit
1
OXYMAT ULTRAMAT
OXYMAT channel ULTRAMAT channel channel channel

Sample gas outlet Sample gas inlet Reference gas outlet 15-pin connector: 9-pin
binary inputs and connector:
Reference Reference Sample Sample analog inputs/outputs RS 485
gas inlet gas inlet gas outlet gas inlet

4 2 1 8 7 6 5 Purging gas
inlet
9-pin interface
connector
(option): e.g.
PROFIBUS

37-pin connector:
binary inputs
and
relay outputs
(optional board)

Power supply
and miniature
fuses
25-pin connector:
binary inputs and
relay outputs
Gas connections: stubs 6 mm or ¼"

ULTRAMAT/OXYMAT 6, 19“ unit, gas and electrical connections

Documentation

■ Selection and ordering data


Operating instructions Article No.
ULTRAMAT 6 / OXYMAT 6
Gas analyzer for IR-absorbing gases
and oxygen
• German C79000-G5200-C143
• English C79000-G5276-C143
• French C79000-G5277-C143
• Spanish C79000-G5278-C143
• Italian C79000-G5272-C143

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ULTRAMAT/OXYMAT 6
Suggestions for spare parts
1 ■ Selection and ordering data
Description 7MB2023 7MB2024 2 years 5 years Article No.
(quantity) (quantity)
Analyzer unit
Analyzer unit, ULTRAMAT channel
• O-ring for cover (window, rear) x x 2 2 C79121-Z100-A24
• Cover (cell length 20 ... 180 mm) x x 2 2 C79451-A3462-B151
• Cover (cell length 0.2 ... 6 mm) x x 2 2 C79451-A3462-B152
• O-rings, set (ULTRAMAT) x x — 1 C79451-A3462-D501
Analyzer unit, OXYMAT channel
• O-ring x x 1 2 C74121-Z100-A6
• O-ring (measuring head) x x 2 4 C79121-Z100-A32
• O-ring x x 2 4 C71121-Z100-A159
• Sample chamber, stainless steel, mat. no. x x — 1 C79451-A3277-B535
1.4571; non-flow-type compensation branch
• Sample chamber, tantalum, non-flow-type x x — 1 C79451-A3277-B536
compensation branch
• Sample chamber, stainless steel, mat. no. x x — 1 C79451-A3277-B537
1.4571; flow-type compensation branch
• Sample chamber, tantalum, flow-type x x — 1 C79451-A3277-B538
compensation branch
• Measuring head, non-flow-type compensation x x 1 1 C79451-A3460-B525
branch
• Measuring head, flow-type compensation x x 1 1 C79451-A3460-B526
branch
Sample gas path
Pressure switch x x 1 2 C79302-Z1210-A2
Restrictor, stainless steel, mat. no. 1.4571; hose x x 2 2 C79451-A3480-C10
gas path
Flow indicator x x 1 2 C79402-Z560-T1
Sample gas path, ULTRAMAT channel
• Hose clip x x — 1 C79451-A3478-C9
Sample gas path, OXYMAT channel
• Restrictor, titanium, pipe gas path x x 2 2 C79451-A3480-C37
• Reference gas path, 3000 hPa x x 1 1 C79451-A3480-D518
• Capillary, 100 hPa, connection set x x 1 1 C79451-A3480-D519
• Restrictor, stainless steel, mat. no. 1.4571; pipe x x 1 1 C79451-A3520-C5
gas path
Electronics
Front plate with keyboard x x 1 1 C79165-A3042-B506
Adapter plate, LCD/keyboard x x 1 1 C79451-A3474-B605
LC display x x 1 1 W75025-B5001-B1
Connector filter x x — 1 W75041-E5602-K2
Fusible element, T 0.63 A/250 V x x 2 3 W79054-L1010-T630
Fusible element, T 1 A/250 V x x 2 3 W79054-L1011-T100
Fusible element, T 2.5 A/250 V x x 2 3 W79054-L1011-T250
Electronics, ULTRAMAT channel
• Motherboard, with firmware: see spare parts list x x — 1
Electronics, OXYMAT channel
• Motherboard, with firmware: see spare parts list x x — 1

If the device was supplied with a specially cleaned gas path for high oxygen context ("Clean for O2 service"), please ensure that you
specify this when ordering spare parts. This is the only way to guarantee that the gas path will continue to comply with the special
requirements for this version.

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Continuous Gas Analyzers, extractive


OXYMAT 6
General information

■ Overview Special versions 1


Special applications
Besides the standard combinations, special applications con-
cerning the material in the gas path and the material in the sam-
ple chambers are also available on request.
TÜV version QAL
As a reference variable for emission measurements according to
TA-Luft, 13th and 17th BlmSchV

■ Design
19" rack unit
• With 4 HU for installation
- in hinged frame
- in cabinets with or without telescopic rails
• Front plate can be swung down for servicing purposes
(laptop connection)
The function of the OXYMAT 6 gas analyzers is based on the • Internal gas paths: hose made of FKM (Viton) or pipe made of
paramagnetic alternating pressure method and are used to titanium or stainless steel (mat. no. 1.4571)
measure oxygen in gases.
• Gas connections for sample gas inlet and outlet and for refer-
ence gas: fittings, pipe diameter of 6 mm or ¼"
■ Benefits • Flow indicator for sample gas on front plate (option)
• Paramagnetic alternating pressure principle • Pressure switch in sample gas path for flow monitoring
- Small measuring ranges (0 to 0.5 % or 99.5 to 100 % O2) (option)
- Absolute linearity
• Detector element has no contact with the sample gas Field device
- Can be used under harsh conditions • Two-door enclosure with gas-tight separation of analyzer and
- Long service life electronics sections
• Physically suppressed zero through suitable selection of • Each half of the enclosure can be purged separately
reference gas (air or O2), e.g. 98 to 100 % O2 for purity moni- • Analyzer unit and piping can be heated up to 130 °C (option)
toring/air separation
• Gas path and stubs made of stainless steel (mat. no. 1.4571)
• Open interface architecture (RS 485, RS 232, PROFIBUS) or titanium, Hastelloy C22
• SIPROM GA network for maintenance and service information • Purging gas connections: pipe diameter 10 mm or 3/8"
(option)
• Gas connections for sample gas inlet and outlet and for refer-
• Electronics and physics: gas-tight isolation, purging is possi- ence gas: clamping ring connection for a pipe diameter of
ble, IP65, long service life even in harsh environments (field 6 mm or ¼"
device only)
• Heated versions (option), use also in presence of gases con- Display and control panel
densing at low temperature (field device only) • Large LCD panel for simultaneous display of:
• EEx(p) for zones 1 and 2 according to ATEX 2G and ATEX 3G - Measured value (digital and analog displays)
(field device only) - Status bar
- Measuring ranges
■ Application • Contrast of LCD panel adjustable using menu
• Permanent LED backlighting
Fields of application • Washable membrane keyboard with five softkeys
• For boiler control in incineration plants • Menu-driven operation for parameterization, test functions,
• For safety-relevant applications (SIL) adjustment
• In the automotive industry (testbed systems) • User help in plain text
• In chemical plants • Graphic display of concentration trend; programmable time
• For ultra-pure gas quality monitoring intervals
• Environmental protection • Bilingual operating software German/English,
English/Spanish, French/English, Spanish/English,
• Quality monitoring Italian/English
• Versions for analyzing flammable and non-flammable gases
or vapors for use in hazardous areas

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OXYMAT 6
General information
1 Input and outputs Communication
• One analog output per measured component (from 0, 2, 4 to RS 485 present in the basic unit (connection at the rear; for the
20 mA; NAMUR parameterizable) rack unit also behind the front plate).
• Two analog inputs configurable (e.g. correction of cross-inter- Options
ference, external pressure sensor)
• AK interface for the automotive industry with extended func-
• Six binary inputs freely configurable (e.g. for measurement tions
range switchover, processing of external signals from sample
preparation) • RS 485/RS 232 converter
• Six relay outputs freely configurable (failure, maintenance re- • RS 485/Ethernet converter
quest, maintenance switch, threshold alarm, external mag- • RS 485/USB converter
netic valves) • Connection to networks via PROFIBUS DP/PA interface
• Expansion: by eight additional binary inputs and eight addi- • SIPROM GA software as the service and maintenance tool
tional relay outputs each, e.g. for autocalibration with up to
four calibration gases

LED backlit graphic Status line for display Two code levels
display and of analyzer status according to NAMUR
membrane keyboard (programmable) (maintenance and
with noticeable click specialist level)

Easy operation with


menu control
using five softkeys

Display of
concentrations as
numbers and bargraph Display of current
measuring ranges
Display of
start-of-scale and
full-scale values

ESC key
to abort inputs
Keyboard to
enter values

INFO key
for help in plain text

CLEAR key
to delete inputs
ENTER key MEAS key
to accept to return to
input values measurement mode

OXYMAT 6, membrane keyboard and graphic display

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OXYMAT 6
General information
Designs – Parts touched by sample gas, standard 1
Gas path 19" rack unit Field device Field device Ex
With hoses Bushing Stainless steel, mat. no. - -
1.4571
Hose FKM (e.g. Viton)
Sample chamber Stainless steel, mat. no.
1.4571 or Tantalum
Fittings for sample chamber Stainless steel, mat. no.
Restrictor 1.4571
O-rings PTFE (e.g. Teflon)
FKM (e.g. Viton)
With pipes Bushing Titanium
Pipe Titanium
Sample chamber Stainless steel, mat. no. 1.4571 or Tantalum
Restrictor Titanium
O-rings FKM (Viton) or FFKM (Kalrez)
With pipes Bushing Stainless steel, mat. no. 1.4571
Pipe Stainless steel, mat. no. 1.4571
Sample chamber Stainless steel, mat. no. 1.4571 or tantalum
Restrictor Stainless steel, mat. no. 1.4571
O-rings FKM (Viton) or FFKM (Kalrez)
With pipes Bushing Hastelloy C 22
Pipe Hastelloy C 22
Sample chamber Stainless steel, mat. no. 1.4571 or tantalum
Restrictor Hastelloy C 22
O-rings FKM (e.g. Viton) or FFKM (e.g. Kalrez)

Options
Flow indicator Measurement pipe Duran glass - -
Variable area Duran glass, black
Suspension boundary PTFE (Teflon)
Angle pieces FKM (Viton)
Pressure switch Membrane FKM (Viton) - -
Enclosure PA 6.3 T

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OXYMAT 6
General information
1 Gas path (19" rack unit)
Legend for the gas path figures
1 Sample gas inlet 8 Pressure switch in sample gas path (option)
2 Sample gas outlet 9 Purging gas
3 Not used 10 Pressure switch in reference gas path (option)
4 Reference gas inlet 11 Pressure sensor
5 Restrictor in reference gas inlet 12 Filter
6 O2 physical system 13 Flow indicator in sample gas path (option)
7 Restrictor in sample gas path 14 Outlet restrictor

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Gas path, reference gas connection 1 100 hPa, absolute

F
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13 7 8

P
11

4
5
12
P

10

Gas path, reference gas connection 3 000 to 5 000 hPa, absolute

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Continuous Gas Analyzers, extractive


OXYMAT 6
General information
Gas path (field device) 1
Legend for the gas path figures
1 Not used 8 Purging gas inlet (analyzer side)
2 Sample gas inlet 9 Pressure sensor
3 Reference gas inlet 10 O2 physical system
4 Sample gas outlet 11 Restrictor in sample gas path
5 Purging gas inlet (electronics side) 12 Pressure sensor in reference gas path (option)
6 Purging gas outlet (electronics side) 13 Restrictor
7 Purging gas outlet (analyzer side) 14 Outlet restrictor




3 




     
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Gas path, reference gas connection 1 100 hPa, absolute






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Gas path, reference gas connection 3 000 to 5 000 hPa, absolute

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Continuous Gas Analyzers, extractive


OXYMAT 6
General information
1 ■ Function
Principle of operation

In contrast to almost all other gases, oxygen is paramagnetic.
This property is utilized as the measuring principle by the
OXYMAT 6 gas analyzers.
Oxygen molecules in an inhomogeneous magnetic field are  
drawn in the direction of increased field strength due to their
paramagnetism. When two gases with different oxygen contents
meet in a magnetic field, a pressure difference is produced be-
tween them.
In the case of OXYMAT 6, one gas (1) is a reference gas (N2, O2 
or air), the other is the sample gas (5). The reference gas is in-
troduced into the sample chamber (6) through two channels (3).
One of these reference gas streams meets the sample gas within  
D3
the area of a magnetic field (7). Because the two channels are
connected, the pressure, which is proportional to the oxygen
content, causes a cross flow. This flow is converted into an elec- 
tric signal by a microflow sensor (4).

The microflow sensor consists of two nickel-plated grids heated
to approximately 120 ºC, which, along with two supplementary
resistors, form a Wheatstone bridge. The pulsating flow results
in a change in the resistance of the Ni grids. This leads to an off-
set in the bridge which is dependent on the oxygen concentra-
tion of the sample gas. 2  

Because the microflow sensor is located in the reference gas 2


stream, the measurement is not influenced by the thermal con- 2
ductivity, the specific heat or the internal friction of the sample
gas. This also provides a high degree of corrosion resistance 2
because the microflow sensor is not exposed to the direct influ- 2
ence of the sample gas. 2

By using a magnetic field with alternating strength (8), the effect


of the background flow in the microflow sensor is not detected,
and the measurement is thus independent of the instrument’s
operating position.
The sample chamber is directly in the sample path and has a
small volume, and the microflow sensor is a low-lag sensor. This 
results in a very short response time for the OXYMAT 6.
Vibrations frequently occur at the place of installation and may
falsify the measured signal (noise). A further microflow sensor
(10) through which no gas passes acts as a vibration sensor. Its
signal is applied to the measured signal as compensation.
If the density of the sample gas deviates by more than 50 % from
that of the reference gas, the compensation microflow sensor 
(10) is flushed with reference gas just like the measuring sensor
(4).
1 Reference gas inlet
Note
2 Restrictors
The sample gases must be fed into the analyzers free of dust. 3 Reference gas channels
Condensation should be prevented from occurring in the sample 4 Microflow sensor for measurement
chambers. Therefore, the use of gas modified for the measuring 5 Sample gas inlet
task is necessary in most application cases. 6 Sample cell
7 Paramagnetic effect
8 Electromagnet with alternating field strength
9 Sample gas and reference gas outlet
10 Microflow sensor in compensation system
(without flow)

OXYMAT 6, principle of operation

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OXYMAT 6
General information
Advantages of the function-based application of reference Essential characteristics 1
gas • Four freely parameterizable measuring ranges, also with sup-
• The zero point can be defined specific to the application. It is pressed zero point, all measuring ranges linear
then also possible to set "physically" suppressed zero points. • Measuring ranges with physically suppressed zero point pos-
For example, it is possible when using pure oxygen as the sible
zero gas to set a measuring range of 99.5 to 100 % O2 with a
resolution of 50 ppm. • Measuring range identification
• The sensor (microflow sensor) is located outside the sample • Galvanically isolated measured-value output 0/2/4 to 20 mA
gas. Through use of an appropriate material in the gas path (also inverted)
this also allows measurements in highly corrosive gases. • Autoranging possible; remote switching is also possible
• Pressure variations in the sample gas can be compensated • Storage of measured values possible during adjustments
better since the reference gas is subjected to the same fluctu- • Wide range of selectable time constants (static/dynamic noise
ations. suppression); i.e. the response time of the analyzer can be
• No influences on the thermal conductivity of the sample gas matched to the respective measuring task
since the sensor is positioned on the reference gas side. • Short response time
• The same gas is used for the serial gas calibration and as the • Low long-term drift
reference gas. As a result of the low consumption of reference
gas (3 to 10 ml/min), one calibration cylinder can be used for • Measuring point switchover for up to 6 measuring points
both gases. (programmable)
• No measuring effect is generated in the absence of oxygen. • Measuring point identification
The measured signal need not therefore be set electronically • Internal pressure sensor for correction of pressure variations
to zero, and is thus extremely stable with regard to tempera- in sample gas range 500 to 2 000 hPa (abs.)
ture and electronic influences. • External pressure sensor - only with piping as the gas path -
can be connected for correction of variations in the sample
gas pressure up to 3 000 hPa absolute (option)
• Monitoring of sample gas flow (option for version with hoses)
• Monitoring of sample gas and/or reference gas (option)
• Monitoring of reference gas with reference gas connection
3 000 to 5 000 hPa (abs.) (option)
• Automatic, parameterizable measuring range calibration
• Operation based on the NAMUR recommendation
• Two control levels with their own authorization codes for the
prevention of accidental and unauthorized operator interven-
tions
• Simple handling using a numerical membrane keyboard and
operator prompting
• Customer-specific analyzer options such as:
- Customer acceptance
- TAG labels
- Drift recording
- Clean for O2 service
- Kalrez gaskets
• Analyzer unit with flow-type compensation branch: a flow is
passed through the compensation branch (option) to reduce
the vibration dependency in the case of highly different densi-
ties of the sample and reference gases
• Sample chamber for use in presence of highly corrosive sam-
ple gases

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OXYMAT 6
General information
1 Reference gases
Measuring range Recommended reference gas Reference gas connection Remarks
pressure
0 to ... vol.% O2 N2 2 000 … 4 000 hPa above sample The reference gas flow is set auto-
gas pressure (max. 5 000 hPa matically to 5 … 10 ml/min (up to
... to 100 vol.% O2 (suppressed O2 absolute) 20 ml/min with flow-type compensa-
zero point with full-scale value tion branch)
100 vol.% O2)
Around 21 vol.% O2 (suppressed Air 100 hPa with respect to sample gas
zero point with 21 vol.% O2 within pressure which may vary by max.
the measuring span) 50 hPa around the atmospheric
pressure

Table 1: Reference gases for OXYMAT 6


Correction of zero point error / cross-sensitivities
Accompanying gas Deviation from zero point in Accompanying gas Deviation from zero point in
(concentration 100 vol. %) vol. % O2 absolute (concentration 100 vol. %) vol. % O2 absolute
Organic gases Inert gases
Ethane C2H6 -0.49 Helium He +0.33
Ethene (ethylene) C2H4 -0.22 Neon Ne +0.17
Ethine (acetylene) C2H2 -0.29 Argon Ar -0.25
1.2 butadiene C4H6 -0.65 Krypton Kr -0.55
1.3 butadiene C4H6 -0.49 Xenon Xe -1.05
n-butane C4H10 -1.26
iso-butane C4H10 -1.30 Inorganic gases
1-butene C4H8 -0.96 Ammonia NH3 -0.20
iso-butene C4H8 -1.06 Hydrogen bromide HBr -0.76
Dichlorodifluoromethane (R12) CCl2F2 -1.32 Chlorine Cl2 -0.94
Acetic acid CH3COOH -0.64 Hydrogen chloride HCl -0.35
n-heptane C7H16 -2.40 Dinitrogen monoxide N2O -0.23
n-hexane C6H14 -2.02 Hydrogen fluoride HF +0.10
Cyclo-hexane C6H12 -1.84 Hydrogen iodide HI -1.19
Methane CH4 -0.18 Carbon dioxide CO2 -0.30
Methanol CH3OH -0.31 Carbon monoxide CO +0.07
n-octane C8H18 -2.78 Nitrogen oxide NO +42.94
n-pentane C5H12 -1.68 Nitrogen N2 0.00
iso-pentane C5H12 -1.49 Nitrogen dioxide NO2 +20.00
Propane C3H8 -0.87 Sulfur dioxide SO2 -0.20
Propylene C3H6 -0.64 Sulfur hexafluoride SF6 -1.05
Trichlorofluoromethane (R11) CCl3F -1.63 Hydrogen sulfide H2S -0.44
Vinyl chloride C2H3Cl -0.77 Water H2O -0.03
Vinyl fluoride C2H3F -0.55 Hydrogen H2 +0.26
1.1 vinylidene chloride C2H2Cl2 -1.22
Table 2: Zero point error due to diamagnetism or paramagnetism of some accompanying gases with reference to nitrogen at 60 °C und 1 000 hPa
absolute (according to IEC 1207/3)
Conversion to other temperatures:
The deviations from the zero point listed in Table 2 must be multiplied by a correction factor (k):
• with diamagnetic gases: k = 333 K / ( [°C] + 273 K)
• with paramagnetic gases: k = [333 K / ( [°C] + 273 K)]2
(all diamagnetic gases have a negative deviation from zero point)

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Continuous Gas Analyzers, extractive


OXYMAT 6
19" rack unit

■ Technical specifications
1
General information Dynamic response
Measuring ranges 4, internally and externally switch- Warm-up period At room temperature < 30 min
able; autoranging is also possible (the technical specification will be
met after 2 hours)
Smallest possible span (relating to 0.5 vol.%, 2 vol.% or 5 vol.% O2
sample gas pressure 1 000 hPa Delayed display (T90-time) Min. 1.5 … 3.5 s, depending on
absolute, 0.5 l/min sample gas flow version
and 25 °C ambient temperature) Damping (electrical time constant) 0 … 100 s, parameterizable
Largest possible measuring span 100 vol.% O2 (for a pressure Dead time (purging time of the gas Approximately 0.5 ... 2.5 s,
above 2 000 hPa: 25 vol.% O2) path in the unit at 1 l/min) depending on version
Measuring ranges with suppressed Any zero point can be imple- Time for device-internal signal <1s
zero point mented within 0 … 100 vol.%, processing
provided that a suitable reference
gas is used (see Table 1 in Pressure correction range
"Function")
Pressure sensor
Operating position Front wall, vertical
• Internal 500 … 2 000 hPa absolute
Conformity CE mark in accordance with
• External 500 … 3 000 hPa absolute
EN 50081-1, EN 50082-2
Measuring response (relating to sample gas pressure 1 013 hPa
Design, enclosure
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Degree of protection IP20 according to EN 60529
Output signal fluctuation <  0.75 % of the smallest possi-
Weight Approx. 13 kg ble measuring range according to
rating plate, with electronic
Electrical characteristics damping constant of 1 s (corre-
Power supply 100 … 120 V AC (nominal range sponds to  0.25 % at 2 )
of use 90 … 132 V), 48 … 63 Hz Zero point drift <  0.5 %/month of the smallest
or 200 … 240 V AC (nominal possible span according to rating
range of use 180 … 264 V), plate
48 … 63 Hz
Measured-value drift <  0.5 %/month of the current
Power consumption Approx. 35 VA measuring range
EMC In accordance with standard Repeatability < 1 % of the current measuring
(Electromagnetic Compatibility) requirements of NAMUR NE21 range
(08/98), EN 61326
Detection limit 1 % of the current measuring
Electrical safety According to EN 61010-1, range
overvoltage category III
Linearity error < 0.1 % of the current measuring
Fuse values 100 ... 120 V: 1.0 T/250 range
200 ... 240 V: 0.63 T/250
Influencing variables (relating to sample gas pressure 1 013 hPa
Gas inlet conditions absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Permissible sample gas pressure Ambient temperature < 0.5 %/10 K relating to the small-
est possible measuring range
• With pipes 500 … 3 000 hPa absolute according to rating plate, with
• With hoses measuring span 0.5 %: 1 %/10 K
- Without pressure switch 500 … 1 500 hPa absolute Sample gas pressure (with air • When pressure compensation is
(100 hPa) as reference gas, correc- switched off: < 2 % of the current
- With pressure switch 500 … 1 300 hPa absolute tion of the atmospheric pressure measuring range/1 % pressure
Sample gas flow 18 … 60 l/h (0.3 … 1 l/min) fluctuations is only possible if the change
sample gas can vent to ambient air) • When pressure compensation is
Sample gas temperature Min. 0 ... max. 50 °C, but above switched on: < 0.2 % of the cur-
the dew point rent measuring range/1 % pres-
Sample gas humidity < 90 % RH (RH: relative humidity) sure change
Reference gas pressure 2 000 ... 4 000 hPa above sample Carrier gases Deviation from zero point corre-
(high-pressure version) gas pressure, but max. 5 000 hPa sponding to paramagnetic or dia-
magnetic deviation of carrier gas
Reference gas pressure Min. 100 hPa above sample gas
(low-pressure version) pressure Sample gas flow at zero point < 1 % of the current measuring
range according to rating plate
with a change in flow of 0.1 l/min
within the permissible flow range
Power supply < 0.1 % of the current measuring
range with rated voltage  10 %

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OXYMAT 6
19" rack unit
1 Electrical inputs and outputs
Analog output 0/2/4 … 20 mA, isolated;
max. load 750 
Relay outputs 6, with changeover contacts,
freely parameterizable, e.g. for
measuring range identification;
load: 24 V AC/DC/1 A, isolated
Analog inputs 2, dimensioned for 0/2/4 ... 20 mA
for external pressure sensor and
residual gas influence correction
(correction of cross-interference)
Binary inputs 6, designed for 24 V, isolated,
freely parameterizable, e.g. for
measuring range switchover
Serial interface RS 485
Options AUTOCAL function with 8 addi-
tional binary inputs and relay out-
puts each, also with PROFIBUS
PA or PROFIBUS DP
Climatic conditions
Permissible ambient temperature -30 … +70 °C during storage and
transportation, 5 … 45 °C during
operation
Permissible humidity < 90 % RH (RH: relative humidity)
within average annual value, dur-
ing storage and transportation
(dew point must not be under-
shot)

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Continuous Gas Analyzers, extractive


OXYMAT 6
19" rack unit

Selection and ordering data Article No.


1
OXYMAT 6 gas analyzer 7MB2021- 7 7 7 7 0 - 7 7 7 7 Cannot be combined
19" rack unit for installation in cabinets
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Gas connections
Pipe with 6 mm outer diameter 0
Pipe with ¼" outer diameter 1
Smallest possible measuring span O2
0.5 % reference gas pressure 3 000 hPa A
0.5 % reference gas pressure 100 hPa (external pump) B B B B Y02
2 % reference gas pressure 3 000 hPa C
2 % reference gas pressure 100 hPa (external pump) D D D D Y02
5% reference gas pressure 3 000 hPa E
5% reference gas pressure 100 hPa (external pump) F F F F Y02
Sample chamber
Non-flow-type compensation branch
• Made of stainless steel, mat. no. 1.4571 A
• Made of tantalum B
Flow-type compensation branch
• Made of stainless steel, mat. no. 1.4571 C C
• Made of tantalum D D
Internal gas paths
Hose made of FKM (Viton) 0
Pipe made of titanium 1 1 1 Y02
Pipe made of stainless steel, mat. no. 1.4571 2 2
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Monitoring (reference gas, sample gas)
Without A
Reference gas only B B
Reference gas and sample gas (with flow indicator and pressure switch for C C C
sample gas)
Sample gas only D D
Add-on electronics
Without A
AUTOCAL function
• With 8 additional digital inputs/outputs B
• With serial interface for the automotive industry (AK) D D E20
• With 8 additional digital inputs/outputs and PROFIBUS PA interface E
• With 8 additional digital inputs/outputs and PROFIBUS DP interface F
Language
German 0
English 1
French 2
Spanish 3
Italian 4
Additional versions Order code Cannot be combined
Add "-Z" to Article No. and specify Order codes.
Telescopic rails (2 units) A31
Kalrez gaskets in sample gas path B01
TAG labels (specific lettering based on customer information) B03
SIL conformity declaration (SIL 2) Functional Safety according to IEC 61508 and C20
IEC 61511
FM/CSA certificate – Class I Div 2 E20
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11

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Continuous Gas Analyzers, extractive


OXYMAT 6
19" rack unit
1 ■ Selection and ordering data
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with serial interface for the automotive industry (AK) C79451-A3480-D512
AUTOCAL function with 8 digital inputs/outputs C79451-A3480-D511
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057307
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057312
Set of Torx screwdrivers A5E34821625

■ Dimensional drawings





 












0

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OXYMAT 6, 19“ unit, dimensions in mm

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Continuous Gas Analyzers, extractive


OXYMAT 6
19" rack unit

■ Schematics
1
Pin assignment (electrical and gas connections)

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OXYMAT 6, 19“ unit, pin assignment

Siemens PA 01 · 2015 1/129


© Siemens AG 2014

Continuous Gas Analyzers, extractive


OXYMAT 6
19" rack unit
1
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OXYMAT 6, 19“ unit, pin assignment of AUTOCAL board and PROFIBUS connectors

1/130 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


OXYMAT 6
19" rack unit
1
Sample gas outlet Sample gas inlet 15-pin connector 9-pin
Binary inputs and connector:
Reference gas inlet relay outputs RS 485

4 2 1 Purging gas
inlet
9-pin
interface
connector
(option): e.g.
PROFIBUS

Power supply
and fuses

37-pin connector
Binary inputs and
relay outputs (option)
25-pin connector
Binary inputs and
Gas connections: stubs 6 mm or ¼" relay outputs

OXYMAT 6, 19“ unit, gas and electrical connections

Siemens PA 01 · 2015 1/131


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Continuous Gas Analyzers, extractive


OXYMAT 6
Field device
1 ■ Technical specifications
General information Gas inlet conditions
Measuring ranges 4, internally and externally switch- Permissible sample gas pressure
able; autoranging is also possible • With pipes 500 … 3 000 hPa absolute
Smallest possible span 0.5 vol.%, 2 vol.% or 5 vol.% O2 • With pipes, Ex version
(relating to sample gas pressure
1 000 hPa absolute, 0.5 l/min sam- - Leakage compensation 500 … 1 160 hPa absolute
ple gas flow and 25 °C ambient
- Continuous purging 500 … 3 000 hPa absolute
temperature), smallest possible
span with heated version: 0.5 % Reference gas pressure 2 000 ... 4 000 hPa above sample
(< 65 °C); 0.5 … 1 % (65 … 90 °C); (high-pressure version) gas pressure, but max. 5 000 hPa
1 … 2 % (90 … 130 °C))
Reference gas pressure Min. 100 hPa above sample gas
Largest possible measuring span 100 vol.% O2 (for a pressure (low-pressure version) pressure
above 2 000 hPa: 25 vol.% O2)
Purging gas pressure
Measuring ranges with suppressed Any zero point can be imple-
zero point mented within 0 … 100 vol.%, • Permanent < 165 hPa above ambient pres-
provided that a suitable reference sure
gas is used (see Table 1 in • For short periods Max. 250 hPa above ambient
"Function") pressure
Operating position Front wall, vertical Sample gas flow 18 … 60 l/h (0.3 … 1 l/min)
Conformity CE mark in accordance with Sample gas temperature • Min. 0 to max. 50 °C, but above
EN 50081-1, EN 50082-2 the dew point (unheated)
Design, enclosure • 15 °C above temperature ana-
lyzer unit (heated)
Degree of protection IP65 in accordance with
EN 60529, restricted breathing Sample gas humidity < 90 % relative humidity
enclosure to EN 50021
Dynamic response
Weight Approx. 28 kg
Warm-up period At room temperature < 30 min
Electrical characteristics (the technical specification will be
met after 2 hours)
Power supply 100 … 120 V AC (nominal range
of use 90 … 132 V), 48 … 63 Hz Delayed display (t90-time) < 1.5 s
or 200 … 240 V AC (nominal
range of use 180 … 264 V), Damping (electrical time constant) 0 … 100 s, parameterizable
48 … 63 Hz Dead time (purging time of the gas Approx. 0.5 s
Power consumption Approx. 35 VA, approx. 330 VA path in the unit at 1 l/min)
with heated version Time for device-internal signal <1s
EMC In accordance with standard processing
(Electromagnetic Compatibility) requirements of NAMUR NE21 Pressure correction range
(08/98), EN 61326
Pressure sensor
Electrical safety In accordance with EN 61010-1
• Internal 500 … 2 000 hPa absolute
• Heated units Overvoltage category II
• External 500 … 3 000 hPa absolute
• Unheated units Overvoltage category III
Measuring response (relating to sample gas pressure 1 013 hPa
Fuse values (unheated unit) absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
• 100 ... 120 V F3: 1 T/250; F4: 1 T/250 Output signal fluctuation <  0.75 % of the smallest possi-
• 200 ... 240 V F3: 0.63 T/250; F4: 0.63 T/250 ble measuring range according to
rating plate, with electronic
Fuse values (heated unit) damping constant of 1 s (corre-
sponds to  0.25 % at 2 )
• 100 ... 120 V F1: 1 T/250; F2: 4 T/250
F3: 4 T/250; F4: 4 T/250 Zero point drift <  0.5 %/month of the smallest
possible span according to rating
• 200 ... 240 V F1: 0.63 T/250; F2: 2.5 T/250 plate
F3: 2.5 T/250; F4: 2.5 T/250 Measured-value drift <  0.5 %/month of the current
measuring range
Repeatability < 1 % of the current measuring
range
Detection limit 1 % of the current measuring
range
Linearity error < 0.1 % of the current measuring
range

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Continuous Gas Analyzers, extractive


OXYMAT 6
Field device
Influencing variables (relating to sample gas pressure 1 013 hPa
1
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Ambient temperature < 0.5 %/10 K relating to the small-
est possible measuring range
according to rating plate, with
measuring span 0.5 %: 1 %/10 K
Sample gas pressure (with air • When pressure compensation is
(100 hPa) as reference gas, correc- switched off: < 2 % of the current
tion of the atmospheric pressure measuring range/1 % pressure
fluctuations is only possible if the change
sample gas can vent to ambient air) • When pressure compensation is
switched on: < 0.2 % of the cur-
rent measuring range/1 % pres-
sure change
Carrier gases Deviation from zero point corre-
sponding to paramagnetic or dia-
magnetic deviation of carrier gas
Sample gas flow at zero point < 1 % of the current measuring
range according to rating plate
with a change in flow of 0.1 l/min
within the permissible flow range;
heated version up to double error
Power supply < 0.1 % of the current measuring
range with rated voltage  10 %
Electrical inputs and outputs
Analog output 0/2/4 … 20 mA, isolated; max.
load 750 
Relay outputs 6, with changeover contacts,
freely parameterizable, e.g. for
measuring range identification;
load: 24 V AC/DC/1 A, isolated
Analog inputs 2, dimensioned for 0/2/4 ... 20 mA
for external pressure sensor and
residual gas influence correction
(correction of cross-interference)
Binary inputs 6, designed for 24 V, isolated,
freely parameterizable, e.g. for
measuring range switchover
Serial interface RS 485
Options AUTOCAL function with
8 additional binary inputs and
relay outputs each, also with
PROFIBUS PA or PROFIBUS DP
Climatic conditions
Permissible ambient temperature -30 … +70 °C during storage and
transportation, 5 … 45 °C during
operation
Permissible humidity < 90 % RH (relative humidity) as
annual average (maximum accu-
racy achieved after 2 hours), dur-
ing storage and transportation
(dew point must not be under-
shot)

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Continuous Gas Analyzers, extractive


OXYMAT 6
Field device
1
■ Selection and ordering data Article No.
OXYMAT 6 gas analyzer 7MB2011- 7 7 7 0 7 - 7 7 7 7 Cannot be combined
For field installation
Click on the Article No. for the online configuration in the PIA Life Cycle
Portal.
Gas connections for sample gas and reference gas
Ferrule screw connection made of stainless steel (mat. no. 1.4571)
• Pipe with 6 mm outer diameter 0 0 D02
• Pipe with ¼" outer diameter 1 1 D01
Ferrule screw connection made of titanium
• Pipe with 6 mm outer diameter 2 2 D01, D02, Y02
• Pipe with ¼" outer diameter 3 3 D01, D02, Y02
Piping and gas connections made of Hastelloy C22:
7MB2011-0/1.... + order code D01 or D02
Smallest possible measuring span O2
0.5 % reference gas pressure 3 000 hPa A
0.5 % reference gas pressure 100 hPa (external pump) B B B B B B Y02
2 % reference gas pressure 3 000 hPa C
2 % reference gas pressure 100 hPa (external pump) D D D D D Y02
5% reference gas pressure 3 000 hPa E
5% reference gas pressure 100 hPa (external pump) F F F F F Y02
Sample chamber
Non-flow-type compensation branch
• Made of stainless steel, mat. no. 1.4571 A
• Made of tantalum B
Flow-type compensation branch
• Made of stainless steel, mat. no. 1.4571 C C
• Made of tantalum D D
Heating of internal gas paths and analyzer unit
None 0
With (65 ... 130 °C) 1 1
Power supply
Standard unit and acc. to ATEX II 3G version (Zone 2)
• 100 ... 120 V AC, 48 ... 63 Hz 0 0
• 200 ... 240 V AC, 48 ... 63 Hz 1 1
ATEX II 2G versions (Zone 1), incl. certificate
• 100 ... 120 V AC, 48 ... 63 Hz, according to ATEX II 2G1) 2 2 2 2 E11, E12
(operating mode: leakage compensation)
• 200 ... 240 V AC, 48 ... 63 Hz, according to ATEX II 2G1) 3 3 3 3 E11, E12
(operating mode: leakage compensation)
• 100 ... 120 V AC, 48 ... 63 Hz, according to ATEX II 2G1) 6 6 6 6 E11, E12
(operating mode: continuous purging)
• 200 ... 240 V AC, 48 ... 63 Hz, according to ATEX II 2G1) 7 7 7 7 E11, E12
(operating mode: continuous purging)
Reference gas monitoring
Without A A
With B B
Add-on electronics
Without A
AUTOCAL function
• With 8 additional digital inputs and 8 additional relay outputs B
• With 8 additional digital inputs/outputs and PROFIBUS PA interface E E E12
• With 8 additional digital inputs/outputs and PROFIBUS DP interface F F E12
• With 8 additional digital inputs/outputs and PROFIBUS PA Ex-i G G
Language
German 0
English 1
French 2
Spanish 3
Italian 4
1) See also next page, "Additional units for Ex versions".

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Continuous Gas Analyzers, extractive


OXYMAT 6
Field device

■ Selection and ordering data


1
Additional versions Order code Cannot be
combined
Add "-Z" to Article No. and specify Order codes.
Set of Torx screwdrivers A32
Kalrez gaskets in sample gas path B01
TAG labels (specific lettering based on customer information) B03
SIL conformity declaration (SIL 2) Functional Safety according to IEC 61508 and IEC 61511 C20
Gas connections and piping made of Hastelloy C22
• Outer diameter 6 mm D01 E20
• Outer diameter ¼" D02 E20
Ex versions
For possible combinations, see Table "Ex configurations – principle selection criteria", page 5/16
ATEX II 3G certificate; restricted breathing enclosure, non-flammable gases E11
ATEX II 3G certificate; flammable gases E12
FM/CSA certificate – Class I Div 2 E20
ATEX II 3D certificate; potentially explosive dust atmospheres
• In non-hazardous gas zone E40
• In Ex zone acc. to ATEX II 3G, non-flammable gases E41
• In Ex zone acc. to ATEX II 3G, flammable gases1) E42
BARTEC EEx p control unit "Leakage compensation" E71
BARTEC EEx p control unit "Continuous purging" E72
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Additional units for Ex versions Article No.
Category ATEX II 2G (zone 1)
BARTEC EEx p control unit, 230 V, "leakage compensation" 7MB8000-2BA
BARTEC EEx p control unit, 115 V, "leakage compensation" 7MB8000-2BB
BARTEC EEx p control unit, 230 V, "continuous purging" 7MB8000-2CA
BARTEC EEx p control unit, 115 V, "continuous purging" 7MB8000-2CB
Ex isolation amplifier 7MB8000-3AB
Ex isolating relay, 230 V 7MB8000-4AA
Ex isolating relay, 110 V 7MB8000-4AB
Differential pressure switch for corrosive and non-corrosive gases 7MB8000-5AA
Stainless steel flame arrestor 7MB8000-6BA
Hastelloy flame arrestor 7MB8000-6BB
Category ATEX II 3G (Zone 2)
BARTEC EEx p control unit, 230 V, "continuous purging" 7MB8000-2CA
BARTEC EEx p control unit, 115 V, "continuous purging" 7MB8000-2CB
FM/CSA (Class I Div. 2)
Ex purging unit MiniPurge FM 7MB8000-1AA
Accessories
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with 8 digital inputs/outputs A5E00064223
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057315
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057318
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA Ex i (firmware 4.1.10 required) A5E00057317
Set of Torx screwdrivers A5E34821625
1)
Only in connection with an approved purging unit

Siemens PA 01 · 2015 1/135


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Continuous Gas Analyzers, extractive


OXYMAT 6
Field device
1 ■ Dimensional drawings
























 



 
  
º 

s &$/20$7





OXYMAT 6, field unit, dimensions in mm

1/136 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


OXYMAT 6
Field device

■ Schematics
1
Pin assignment (electrical and gas connections)

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OXYMAT 6, field unit, connector and terminal assignment

Siemens PA 01 · 2015 1/137


© Siemens AG 2014

Continuous Gas Analyzers, extractive


OXYMAT 6
Field device
1
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OXYMAT 6, field unit, connector and terminal assignment of the AUTOCAL board and PROFIBUS connectors

1/138 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


OXYMAT 6
Field device
1
a b c d 7
5
1 3

2 4

8
6

Gas connections Electrical connections


1 not used a-c Signal cable (Ø 10 ... 14 mm)
(analog + digital): cable gland M20x1.5
2 Sample gas inlet Clamping
gland for pipe d Interface connection: (Ø 7 ... 12 mm)
3 Reference gas inlet Ø 6 mm or ¼" cable gland M20x1.5
4 Sample gas outlet e Power supply: (Ø 7 ... 12 mm)
cable gland M20x1.5
5 - 8 Purging gas inlets/outlets stubs Ø 10 mm or 3/8 "

OXYMAT 6, field unit, gas and electrical connections

Documentation

■ Selection and ordering data


Operating instructions Article No.
ULTRAMAT 6 / OXYMAT 6
Gas analyzer for IR-absorbing gases
and oxygen
• German C79000-G5200-C143
• English C79000-G5276-C143
• French C79000-G5277-C143
• Spanish C79000-G5278-C143
• Italian C79000-G5272-C143

Siemens PA 01 · 2015 1/139


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Continuous Gas Analyzers, extractive


OXYMAT 6
Suggestions for spare parts
1 ■ Selection and ordering data
Description 7MB2021 7MB2011 7MB2011 Ex 2 years 5 years Article No.
(quantity) (quantity)
Analyzer unit
O ring (sample cell) x x x 2 4 C71121-Z100-A159
O ring (fitting) x x x 1 2 C74121-Z100-A6
O-ring (measuring head) x x x 2 4 C79121-Z100-A32
Spacer x x - 1 C79451-A3277-B22
Sample chamber, stainless steel, mat. no. 1.4571; x x x - 1 C79451-A3277-B535
non-flow-type compensation branch
Sample chamber, tantalum, non-flow-type x x x - 1 C79451-A3277-B536
compensation branch
Sample chamber, stainless steel, mat. no. 1.4571; x x x - 1 C79451-A3277-B537
flow-type compensation branch
Sample chamber, tantalum, flow-type x x x - 1 C79451-A3277-B538
compensation branch
Measuring head, non-flow-type compensation x x x 1 1 C79451-A3460-B525
branch
Measuring head, flow-type compensation branch x x x 1 1 C79451-A3460-B526
Magnetic field connection plate x x x - 1 C79451-A3474-B606
Temperature sensor x x - 1 C79451-A3480-B25
Heating cartridge x x - 1 W75083-A1004-F120
Sample gas path
Pressure switch (sample gas) x 1 2 C79302-Z1210-A2
Flowmeter x 1 2 C79402-Z560-T1
Restrictor, stainless steel, mat. no. 1.4571; hose x 2 2 C79451-A3480-C10
gas path
Restrictor, titanium, pipe gas path x x x 2 2 C79451-A3480-C37
Reference gas path, 3000 hPa x x x 1 1 C79451-A3480-D518
Capillary, 100 hPa, connection set x x x 1 1 C79451-A3480-D519
Restrictor, stainless steel, mat. no. 1.4571; pipe x x x 1 1 C79451-A3520-C5
gas path
Electronics
Temperature controller - electronics, 230 V AC x x - 1 A5E00118527
Temperature controller - electronics, 115 V AC x x - 1 A5E00118530
Fusible element (analyzer fuse) T 0.125 A/250 V x 1 2 A5E00061505
Front plate with keyboard x 1 1 C79165-A3042-B505
Motherboard, with firmware: see spare parts list x x x - 1
Adapter plate, LCD/keyboard x x 1 1 C79451-A3474-B605
LC display x x 1 1 W75025-B5001-B1
Connector filter x x x - 1 W75041-E5602-K2
Temperature fuse (heated version only) x - 1 W75054-T1001-A150
Fusible element, T 0.63 A/250 V x x x 2 3 W79054-L1010-T630
Fusible element, T 1 A/250 V x x x 2 3 W79054-L1011-T100
Fusible element, T 2.5 A/250 V x x 2 3 W79054-L1011-T250

If the OXYMAT 6 was supplied with a specially cleaned gas path for high oxygen context ("Clean for O2 service"), please ensure that
you specify this when ordering spare parts. This is the only way to guarantee that the gas path will continue to comply with the special
requirements for this version.

1/140 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


OXYMAT 61
General information

■ Overview ■ Design
1
• 19" rack unit with 4 HU for installation
- in hinged frame
- in cabinets with or without telescope rails
• Front plate can be swung down for servicing purposes
(laptop connection)
• Gas connections for sample gas inlet and outlet;
pipe diameter 6 mm or ¼"
• Gas and electrical connections at the rear
Display and control panel
• Large LCD field for simultaneous display of:
- Measured value
- Status bar
- Measuring ranges
• Contrast of LCD panel adjustable using menu
• Permanent LED backlighting
• Washable membrane keyboard with five softkeys
• Menu-driven operation for parameterization, test functions,
The measuring principle of the OXYMAT 61 gas analyzers is adjustment
based on the paramagnetic alternating pressure method and is
used to measure oxygen in gases in standard applications. • User help in plain text
• Graphic display of concentration trend; programmable time
■ Benefits intervals
• Bilingual operating software German/English, English/
• Integrated pump for reference gas (option, e.g. ambient air)
Spanish, French/English, Spanish/English, Italian/English
• High linearity
Input and outputs
• Compact design
• One analog output per medium (from 0, 2, 4 to 20 mA; NAMUR
• Physically suppressed zero possible
parameterizable)

■ Application • Six binary inputs freely configurable (e.g. for measurement


range switchover, processing of external signals from sample
Application areas preparation)
• Environmental protection • Six relay outputs freely configurable (failure, maintenance re-
quest, maintenance switch, threshold alarm, external mag-
• Boiler control in firing systems netic valves)
• Quality monitoring (e.g. in ultra-pure gases) • Two analog inputs configurable (e.g. correction of cross-inter-
• Process exhaust monitoring ference, external pressure sensor)
• Process optimization • Extension with eight additional binary inputs and eight addi-
tional relay outputs, e.g. for autocalibration with up to four cal-
Further applications ibration gases
• Chemical plants
Communication
• Gas manufacturers
• Research and development RS 485 present in basic unit (connection from the rear).
Options
• RS 485/RS 232 converter
• RS 485/Ethernet converter
• RS 485/USB converter
• Connection to networks via PROFIBUS DP/PA interface
• SIPROM GA software as service and maintenance tool

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OXYMAT 61
General information
1
LED backlit graphic Status line to display Two code levels
display and the analyzer status according to NAMUR
membrane keyboard (programmable) (maintenance and
with noticeable click specialist level)

Easy operation
menu controlusing
the softkeys

Display of
concentrations as
numbers and bargraph Display of current
measuring ranges
Display of
start-of-scale and
full-scale values

ESC key
to abort inputs
Keyboard to
enter values

INFO key
for help in plain text

CLEAR key
to delete inputs ENTER key MEAS key
to accept to return to
input values measurement mode

OXYMAT 61, membrane keyboard and graphic display


Designs – Parts touched by sample gas, standard
Gas path 19" rack unit
With hoses Bushing Stainless steel, mat. no. 1.4571
Hose FKM (Viton)
Sample chamber Stainless steel, mat. no. 1.4571
Fittings for sample chamber Stainless steel, mat. no. 1.4571
Restrictor PTFE (Teflon)
O-rings FKM (Viton)
Hose coupling Polyamide 6

Options
Flow indicator Measurement pipe Duran glass
Variable area Duran glass, black
Suspension boundary PTFE (Teflon)
Angle pieces FKM (Viton)
Pressure switch Membrane FKM (Viton)
Enclosure PA 6.3 T

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OXYMAT 61
General information
Gas path 1
Legend for the gas path figures
1 Sample gas inlet 9 Purging gas
2 Sample gas outlet 10 Restrictor in reference gas path (outlet)
3 Not used 11 Pressure switch for reference gas monitoring
4 Reference gas inlet 12 Pump
5 Restrictor in reference gas path 13 Filter
6 O2 physical system 14 Flow indicator in sample gas path (option)
7 Restrictor in sample gas path 15 Pressure sensor
8 Pressure switch in sample gas path (option)

F
14 7 P
8

3
15
6 2

10

4
5
12 13
P

11

Gas path OXYMAT 61 with integrated reference gas pump (connection for 1 100 hPa, absolute)

F
14 7 P
8

3
15
6 2

4
5
13

Gas path OXYMAT 61 with reference gas connection 3 000 to 5 000 hPa, absolute

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OXYMAT 61
General information
1 ■ Function
In contrast to almost all other gases, oxygen is paramagnetic.
This property is utilized as the measuring principle by the 1
OXYMAT 61 gas analyzers.
Oxygen molecules in an inhomogeneous magnetic field are
drawn in the direction of increased field strength due to their
paramagnetism. When two gases with different oxygen contents 2 2
meet in a magnetic field, a pressure difference is produced be-
tween them.
In the case of OXYMAT 61, one gas (1) is a reference gas (N2,
O2 or air), the other is the sample gas (5). The reference gas is
introduced into the sample chamber (6) through two channels 4
(3). One of these reference gas streams meets the sample gas
within the area of a magnetic field (7). Because the two channels 3 3
are connected, the pressure, which is proportional to the oxygen DP
content, causes a cross flow. This flow is converted into an elec-
tric signal by a microflow sensor (4).
5
OXYMAT 61, principle of operation
The microflow sensor consists of two nickel-plated grids heated 6
to approximately 120 ºC, which, along with two supplementary
resistors, form a Wheatstone bridge. The pulsating flow results
in a change in the resistance of the Ni grids. This leads to an off-
set in the bridge which is dependent on the oxygen concentra-
tion of the sample gas. 7 8

Because the microflow sensor is located in the reference gas O2


stream, the measurement is not influenced by the thermal con- O2
ductivity, the specific heat or the internal friction of the sample O2
gas. This also provides a high degree of corrosion resistance O2
because the microflow sensor is not exposed to the direct influ- O2
ence of the sample gas.
By using a magnetic field with alternating strength (8), the effect
of the background flow in the microflow sensor is not detected,
and the measurement is thus independent of the instrument’s
operating position.
The sample chamber is directly in the sample path and has a
small volume, and the microflow sensor is a low-lag sensor. This 9
results in a very short response time for the OXYMAT 61. 1 Reference gas inlet
Note 2 Restrictors
3 Reference gas channels
The sample gases must be fed into the analyzers free of dust. 4 Microflow sensor for measurement
Condensation should be prevented from occurring in the sample 5 Sample gas inlet
chambers. Therefore, gas modified for the measuring tasks is 6 Sample cell
necessary in most application cases. 7 Paramagnetic effect
8 Electromagnet with alternating field strength
Essential characteristics 9 Sample gas and reference gas outlet
• Four freely parameterizable measuring ranges, also with sup-
pressed zero point, all measuring ranges linear
• Galvanically isolated measured-value output 0/2/4 to 20 mA OXYMAT 61, principle of operation
(also inverted)
• Autoranging possible; remote switching is also possible • Customer-specific analyzer options such as:
• Storage of measured values possible during adjustments - Customer acceptance
- TAG labels
• Wide range of selectable time constants (static/dynamic noise - Drift recording
suppression); i.e. the response time of the device can be
adapted to the respective measuring task • Simple handling using a numerical membrane keyboard and
operator prompting
• Easy handling thanks to menu-driven operation
• Short response time
• Low long-term drift
• Reference gas supply either externally (N2, O2 or air, approx.
• Two control levels with their own authorization codes for the 3 000 hPa) or via built-in reference gas pump (ambient air,
prevention of accidental and unauthorized operator interven- approx. 1 100 hPa abs.)
tions
• Monitoring of reference gas with reference gas connection;
• Automatic, parameterizable measuring range calibration only on version with built-in reference gas pump
• Operation based on the NAMUR recommendation • Different smallest measuring ranges, depending on version
• Monitoring of sample gas (option) 2.0 % or 5.0 % O2
• Internal pressure sensor for correction of fluctuations in the
sample gas pressure

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OXYMAT 61
General information
Correction of zero error / cross-sensitivities 1
Accompanying gas Deviation from zero point Accompanying gas Deviation from zero point
(concentration 100 vol.%) in vol. % O2 absolute (concentration 100 vol.%) in vol. % O2 absolute
Organic gases Inert gases
Ethane C2H6 -0.49 Helium He +0.33
Ethene (ethylene) C2H4 -0.22 Neon Ne +0.17
Ethine (acetylene) C2H2 -0.29 Argon Ar -0.25
1.2 butadiene C4H6 -0.65 Krypton Kr -0.55
1.3 butadiene C4H6 -0.49 Xenon Xe -1.05
n-butane C4H10 -1.26
iso-butane C4H10 -1.30 Inorganic gases
1-butene C4H8 -0.96 Ammonia NH3 -0.20
iso-butene C4H8 -1.06 Hydrogen bromide HBr -0.76
Dichlorodifluoromethane (R12) -1.32 Chlorine Cl2 -0.94
CCl2F2
Hydrogen chloride HCl -0.35
Acetic acid CH3COOH -0.64
Dinitrogen monoxide N2O -0.23
n-heptane C7H16 -2.40
Hydrogen fluoride HF +0.10
n-hexane C6H14 -2.02
Hydrogen iodide HI -1.19
Cyclo-hexane C6H12 -1.84
Carbon dioxide CO2 -0.30
Methane CH4 -0.18
Carbon monoxide CO +0.07
Methanol CH3OH -0.31
Nitrogen oxide NO +42.94
n-octane C8H18 -2.78
Nitrogen N2 0.00
n-pentane C5H12 -1.68
Nitrogen dioxide NO2 +20.00
iso-pentane C5H12 -1.49
Sulfur dioxide SO2 -0.20
Propane C3H8 -0.87
Sulfur hexafluoride SF6 -1.05
Propylene C3H6 -0.64
Hydrogen sulfide H2S -0.44
Trichlorofluoromethane (R11) -1.63
CCl3F Water H2O -0.03

Vinyl chloride C2H3Cl -0.77 Hydrogen H2 +0.26

Vinyl fluoride C2H3F -0.55


1.1 vinylidene chloride C2H2Cl2 -1.22

Table 1: Zero error due to diamagnetism or paramagnetism of some accompanying gases with nitrogen as the reference gas at 60 °C and 1 000 hPa
absolute (according to IEC 1207/3)
Conversion to other temperatures:
The deviations from the zero point listed in Table 1 must be multiplied by a correction factor (k):
• with diamagnetic gases: k = 333 K / ( [°C] + 273 K)
• with paramagnetic gases: k = [333 K / ( [°C] + 273 K)]2
(all diamagnetic gases have a negative deviationfrom zero point)
Reference gases
Measuring range Recommended reference gas Reference gas connection pressure Remarks
0 to … vol.% O2 N2 2 000 … 4 000 hPa above sample gas The reference gas flow is set
pressure (max. 5 000 hPa absolute) automatically to 5 … 10 ml/min
... to 100 vol.% O2 (suppressed O2
zero point with full-scale value
100 vol.% O2)
Around 21 vol.% O2 (suppressed Air Atmospheric pressure with internal
zero point with 21 vol.% O2 within reference gas pump
the measuring span)

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Continuous Gas Analyzers, extractive


OXYMAT 61
19" rack unit
1 ■ Technical specifications
General information Measuring response (relating to sample gas pressure 1 013 hPa
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Measuring ranges 4, internally and externally switch-
able; autoranging is also possible Output signal fluctuation <  0.75 % of the smallest possi-
ble measuring range according to
Smallest possible span (relating to 2 vol. % or 5 vol. % O2 rating plate, with electronic
sample gas pressure 1 000 hPa damping constant of 1 s (corre-
absolute, 0.5 l/min sample gas flow sponds to  0.25 % at 2 )
and 25 °C ambient temperature)
Zero point drift <  0.5 %/month of the smallest
Largest possible measuring span 100 vol. % O2 possible span according to rating
Measuring ranges with suppressed Any zero point within plate
zero point 0 ... 100 vol.% can be imple- Measured-value drift <  0.5 %/month of the current
mented, provided that a suitable measuring range
reference gas is used
Repeatability < 1 % of the current measuring
Operating position Front wall, vertical range
Conformity CE mark in accordance with Detection limit 1 % of the current measuring
EN 50081-1, EN 50082-2 range
Design, enclosure Linearity error < 1 % of the current measuring
Degree of protection IP20 according to EN 60529 range

Weight Approx. 13 kg Influencing variable (relating to sample gas pressure 1 013 hPa
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Electrical characteristics
Ambient temperature < 2 %/10 K with span 5 %
Power supply 100 … 120 V AC (nominal range
of use 90 … 132 V), 48 … 63 Hz Sample gas pressure (with air • When pressure compensation
or 200 … 240 V AC (nominal (100 hPa) as internal reference gas has been switched off: < 2 % of
range of use 180 … 264 V), supply, correction of the atmo- the current measuring
48 … 63 Hz spheric pressure fluctuations is only range/1 % pressure change
possible if the sample gas can vent • When pressure compensation
Power consumption Approx. 45 VA to ambient air.) has been switched on: < 0.2 %
EMC In accordance with standard of the current measuring
(Electromagnetic Compatibility) requirements of NAMUR NE21 range/1 % pressure change
(08/98) Accompanying gases Deviation from zero point corre-
Electrical safety According to EN 61010-1, sponding to paramagnetic or dia-
overvoltage category III magnetic deviation of
accompanying gas (see table)
Fuse values 100 ... 120 V: 1.0 T/250
Sample gas flow at zero point < 1 % of the current measuring
200 ... 240 V: 0.63 T/250 range according to rating plate
Gas inlet conditions with a change in flow of 0.1 l/min
within the permissible flow range
Permissible sample gas pressure
Power supply < 0.1 % of the current measuring
• External reference gas supply 800 … 1 200 hPa absolute range with rated voltage  10 %
• With integrated pump Atmospheric pressure 50 hPa Electrical inputs and outputs
Sample gas flow 18 … 60 l/h (0.3 … 1 l/min) Analog output 0/2/4 … 20 mA, isolated;
Sample gas temperature Min. 0 to max. 50 °C, but above max. load 750 
the dew point Relay outputs 6, with changeover contacts,
Sample gas humidity < 90 % relative humidity freely parameterizable, e.g. for
measuring range identification;
Reference gas pressure (high-pres- 2 000 ... 4 000 hPa above sam- load: 24 V AC/DC/1 A, potential-
sure version) ple gas pressure, but max. free
5 000 hPa absolute (version
without reference gas pump) Analog inputs 2, dimensioned for
0/2/4 … 20 mA for external pres-
Reference gas pressure (low-pres- Min. 100 hPa above sample gas sure sensor and accompanying
sure version) with external pump pressure gas influence correction (correc-
tion of cross-interference)
Dynamic response
Binary inputs 6, designed for 24 V, isolated,
Warm-up period At room temperature < 30 min
freely parameterizable, e.g. for
(the technical specification will be
measuring range switchover
met after 2 hours)
Serial interface RS 485
Delayed display (T90) 3.5 s
Options AUTOCAL function with 8 addi-
Damping (electrical time constant) 0 … 100 s, parameterizable
tional binary inputs and relay out-
Dead time (purging time of the gas Approximately 0.5 ... 2.5 s, puts, also with PROFIBUS PA or
path in the unit at 1 l/min) depending on version PROFIBUS DP
Time for device-internal signal pro- <1s Climatic conditions
cessing
Permissible ambient temperature -30 … +70 °C during storage and
Pressure correction range transportation
5 … 45 °C during operation
Pressure sensor internal 500 … 2 000 hPa, absolute
(see gas inlet conditions for per- Permissible humidity < 90 % relative humidity as
missible sample gas pressure) annual average, during storage
and transportation (must not fall
below dew point)

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Continuous Gas Analyzers, extractive


OXYMAT 61
19" rack unit

Selection and ordering data Article No.


1
OXYMAT 61 gas analyzer 7MB2001- 7 7 A 0 0 - 7 7 7 7 Cannot be combined
19" rack unit for installation in cabinets
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Gas connections for sample gas and reference gas
Pipe with 6 mm outer diameter 0
Pipe with ¼" outer diameter 1
Smallest possible measuring span O2
2 % Reference gas pressure 3 000 hPa C
2 % reference gas supply with internal pump D D Y02
5 % Reference gas pressure 3 000 hPa E
5 % reference gas supply with internal pump F F Y02
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Sample gas monitoring
Without A
With (incl. flow indicator and pressure switch) D
Add-on electronics
Without A
AUTOCAL function
• With 8 additional digital inputs/outputs B
• With serial interface for the automotive industry (AK) D
• With 8 additional digital inputs/outputs and PROFIBUS PA interface E
• With 8 additional digital inputs/outputs and PROFIBUS DP interface F
Language
German 0
English 1
French 2
Spanish 3
Italian 4
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Telescopic rails (2 units) A31
TAG labels (specific lettering based on customer information) B03
Attenuation element for sample gas B04 Y02
SIL conformity declaration (SIL 2) Functional Safety according to IEC 61508 and C20
IEC 61511
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting1) Y11
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function each with 8 digital inputs/outputs C79451-A3480-D511
AUTOCAL function 8 digital inputs/outputs each and PROFIBUS PA A5E00057307
AUTOCAL function 8 digital inputs/outputs each and PROFIBUS DP A5E00057312
Set of Torx screwdrivers A5E34821625
1)
Standard setting: Measuring range 1: 0 to smallest measuring span
Measuring range 2: 0 to 10 %
Measuring range 3: 0 to 25 %
Measuring range 4: 0 to 100 %

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OXYMAT 61
19" rack unit
1 ■ Dimensional drawings

384.5
351.5
27.5
15.6

173 128 4

s
101.6

37.7

149.5
177

82
172
M4

2;<0$7

86.5
465
483

440

411.5
104
132

320
345
36
0

  

OXYMAT 61, 19“ unit, dimensions in mm

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Continuous Gas Analyzers, extractive


OXYMAT 61
19" rack unit

■ Schematics
1
Pin assignment (electrical connections)

&RQQHFWRU68%') 56

0  *1'
*1'  5B/HYHO1
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9  5B/HYHO3
 1&
 1&
0  *1'

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0  *1'
 1&
 1&
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 1&
 1&
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0 9 ORZUHVLVWDQFH
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0  *1'

68%')FRQQHFWRU

0  *1'
 %LQDU\LQSXW3 ,VRODWHGYLDRSWRFRXSOHU
 %LQDU\LQSXW3  9 9
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 5HOD\


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0  *1' HQFORVXUHSRWHQWLDO

OXYMAT 61, 19“ unit, pin assignment

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Continuous Gas Analyzers, extractive


OXYMAT 61
19" rack unit
1 Pin assignment (electrical connections)

Connector SUB-D 37F (option)

M 19 GND
37 NC
18 NC
36 Binary input 14-P
17 Binary input 13-P
35 Binary input 12-P Isolated
16 Binary input 11-P via optocoupler
34 Binary input 10-P "0" = 0 V (0 ... 4.5 V)
15 Binary input 9-P "1" = 24 V (13 ... 33 V)
33 Binary input 8-P
14 Binary input 7-P
32 Binary input 7 to 14-N
13
31 Relay 14
12
30
11 Relay 13
29
10
28 Relay 12
9
27 Contact load
8 Relay 11 max. 24 V/1 A, AD/DC
26
7 for shown
25 Relay 10 relay contact position,
6 the relay has zero current
24
5 Relay 9
23
4
22 Relay 8
3
21
2 Relay 7
20
M 1 GND

Connector SUB-D 9F-X90 Connector SUB-D 9M-X90


Optional
PROFIBUS DP PROFIBUS PA

5 DGND 5
9 CNTR-N 9
4 CNTR-P/direction control 4
8 RxD/TxD-N (A) 8 PA-N(-)
3 RxD/TxD-P (B) 3 PA-P(+)
7 7
2 2
6 VP /+ 5 V 6
1 1

1RWH
$OOFDEOHVWRWKHFRQQHFWRUVRUWHUPLQDOEORFNVPXVWEH
VKLHOGHGDQGUHVWDJDLQVWWKHHQFORVXUHSRWHQWLDO

OXYMAT 61, 19“ unit, pin assignment of the AUTOCAL board and PROFIBUS connectors

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Continuous Gas Analyzers, extractive


OXYMAT 61
19" rack unit
Gas and electrical connections 1
Sample gas outlet Sample gas inlet 15-pin connector: 9-pin
Binary inputs and connector:
analog inputs/outputs RS 485
Reference gas inlet

4 2 1 Purging gas
inlet
9-pin interface
connector
(option):
e.g. PROFIBUS

Power supply
and fuses

37-pin connector:
Binary inputs and
relay outputs (option)
25-pin connector:
Binary inputs and
relay outputs
Gas connections: stubs 6 mm or ¼"

OXYMAT 61, 19“ unit, gas and electrical connections

Documentation

■ Selection and ordering data


Operating instructions Article No.
OXYMAT 61
Gas analyzer for measurement of
oxygen
• German A5E00123066
• English A5E00123067
• French A5E00123068
• Spanish A5E00123069
• Italian A5E00123070

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OXYMAT 61
Suggestions for spare parts
1 ■ Selection and ordering data
Description Quantity for Quantity for Article No.
2 years 5 years
Analyzer unit
Reference gas supply (pump, restrictor, pressure switch, hose) 1 1 A5E00114838
O-ring 1 2 C74121-Z100-A6
Pressure switch (sample gas) 1 2 C79302-Z1210-A2
Flowmeter 1 2 C79402-Z560-T1
Sample chamber
• Stainless steel, mat. no. 1.4571; non-flow-type compensation branch - 1 C79451-A3277-B535
• O-ring (measuring head) 2 4 C79121-Z100-A32
• O ring (fitting) 2 4 C71121-Z100-A159
Measuring head (non-flow-type compensation branch) 1 1 C79451-A3460-B525
Restrictor for sample gas path, hose 2 2 C79451-A3480-C10
Reference gas path, 3000 hPa (set of parts) 1 1 C79451-A3480-D518
Electronics
Front plate with keyboard 1 1 A5E00259978
Motherboard, with firmware: see spare parts list - 1
Adapter plate, LCD/keyboard 1 1 C79451-A3474-B605
Magnetic field connection plate - 1 C79451-A3474-B606
LC display 1 1 W75025-B5001-B1
Connector filter - 1 W75041-E5602-K2
Fuse
• 0.63 A/250 V (230 V version) 2 3 W79054-L1010-T630
• 1.0 A/250 V (110 V version) 2 3 W79054-L1011-T100

If the OXYMAT 61 was supplied with a specially cleaned gas path for high oxygen context ("Clean for O2 service"), please ensure
that you specify this when ordering spare parts. This is the only way to guarantee that the gas path will continue to comply with the
special requirements for this version.

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Continuous Gas Analyzers, extractive


OXYMAT 64
General information

■ Overview ■ Design
1
• 19" rack unit with 4 HU for installation
- in hinged frames
- in cabinets with or without telescopic rails
• Front plate for service purposes can be pivoted down
(laptop connection)
• Connections for sample gas
- Input: Clamping ring connection for a pipe diameter of 6 mm
or ¼"
- Output: Pipe connection with diameter 6 mm or ¼"
• High-pressure and low-pressure versions
• Catalytically active and inactive cell
Display and control panel
• Large LCD field for simultaneous display of
- Measured value
- Status bar
- Measuring ranges
• Contrast of the LCD field adjustable via the menu
The OXYMAT 64 gas analyzer is used for the trace measurement • Permanent LED backlighting
of oxygen.
• Washable membrane keyboard with five softkeys
■ Benefits • Five-digit measured-value display
(decimal point counts as one digit)
• High linearity • Menu-driven operation for parameterization, configuration,
• Compact design test functions, adjustment
• Open interface architecture (RS 485, RS 232, PROFIBUS) • Operator support in plain text
• SIPROM GA network for maintenance and service information • Graphical display of the concentration progression; time inter-
(option) vals parameterizable
• Bilingual operating software German/English,
■ Application English/Spanish, French/English, Spanish/English,
• Production of technical gases Italian/English
- Measurements in N2 and CO2 • Switchover from ppm measuring range to % measuring range
• Welding Inputs and outputs
- Measurements in protective gases during welding of highly
alloyed steels, titanium, etc. • One analog output per medium (from 0, 2, 4 to 20 mA; NAMUR
parameterizable)
• Systems for air separation
- Measurements in N2 and in inert gases (e.g. Ne, Ar) • Six binary inputs freely configurable (e.g. for measurement
- Measurements in CO2 range switchover, processing of external signals from sample
preparation)
• Food production
- Measurement in CO2 (e.g. breweries) • Six relay outputs freely configurable (failure, maintenance re-
quest, maintenance switch, threshold alarm, external solenoid
• Electronics industry valves)
- Low-pressure version with pump
• Two analog inputs configurable (e.g. correction of cross-inter-
• Flow soldering systems ference, external pressure sensor)
• Extension with eight additional binary inputs and eight addi-
tional relay outputs, e.g. for autocalibration with up to four cal-
ibration gases
Communication
RS 485 present in basic unit (connection from the rear).
Options
• RS 485/RS 232 converter
• RS 485/Ethernet converter
• RS 485/USB converter
• Connection to networks via PROFIBUS DP/PA interface
• SIPROM GA software as the service and maintenance tool

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OXYMAT 64
General information
1
LED backlit graphic Status line to display Two code levels
display and the analyzer status according to NAMUR
membrane keyboard (programmable) (maintenance and
with noticeable click specialist level)

Easy operation
menu controlusing
the softkeys

Display of
concentrations as
numbers and bargraph Display of current
measuring ranges
Display of
start-of-scale and
full-scale values

ESC key
to abort inputs
Keyboard to
enter values

INFO key
for help in plain text

CLEAR key
to delete inputs

ENTER key MEAS key


to accept to return to
input values measurement mode

OXYMAT 64, membrane keyboard and graphic display


Designs – Parts wetted by sample gas, standard
Gas path 19" rack unit
Sample gas path Bushing Stainless steel, mat. no. 1.4571
Pipe inlet Stainless steel
O2 sensor ZrO2 ceramic
Bypass line FPM (Viton)
Connection pieces PTFE (Teflon)
Pressure sensor Enclosure Polycarbonate
Membrane SiO4
Sensor adapter Aluminum
Bypass restrictor Stainless steel, mat. no. 1.4571
Flow indicator Measurement pipe Duran glass
Variable area Duran glass, black
Suspension boundary PTFE (Teflon)
Angle pieces FKM (Viton)
Pressure switch Enclosure Polycarbonate
Membrane NBR

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Continuous Gas Analyzers, extractive


OXYMAT 64
General information
Gas path (high-pressure version) 1
Legend for the gas path figure
1 Sample gas inlet; inlet pressure 5 Pressure sensor
- without internal pressure regulator: 2 000 hPa (abs.), regulated 6 Bypass restrictor
- with internal pressure regulator: 2 000 ... 6 000 hPa (abs.) 7 Pressure switch
2 Sample gas outlet; sample gas flows off free of dynamic pressure 8 Flow measuring tube
3 Pressure regulator (order version) 9 Purging gas connection
4 O2 sensor 10 Restrictor

9 1 2

10 10 4
O2 sensor
(KAZ /KIZ)

5 P 7
6

F
8

Gas path OXYMAT 64, high-pressure version


The sample gas pressure (2 000 to 6 000 hPa) is regulated by the pressure regulator (3) at approx. 2 000 hPa or is provided by the
operator with 2 000 hPa. This pressure is applied at the restrictor (10). The restrictor (10) reduces the pressure such that a sample
gas flow of 15 to 30 l/h is created. This flow is subdivided via the sample gas restrictor (11) and the adjustable bypass restrictor (6)
such that there is a sample gas flow of 7.5 l/h through the sensor.
If the sample gas can flow off into the atmosphere unhampered, the sample gas pressure corresponds to the atmospheric pressure.
If the sample gas flows off via an exhaust gas line, it works like a flow resistance. If the resulting dynamic pressure exceeds 100 hPa
(rel.), a maintenance request is output.

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Continuous Gas Analyzers, extractive


OXYMAT 64
General information
1 Gas path (low pressure)
Legend for the gas path figure
1 Sample gas inlet; flow 125 ml/min (7.5 l/h) 5 Pressure switch
2 Sample gas outlet; sample gas flows off free of dynamic pressure 6 Flow measuring tube
3 O2 sensor 7 Purging gas connection
4 Pressure sensor 8 Restrictor

7 1 2

8
O2 sensor 3
(KAZ /KIZ)

4 P 5

F
6

Gas path OXYMAT 64, low-pressure version


With the low-pressure version, the sample gas flow must be set externally to 125 ml/min. With a built-in pressure switch, the sample
gas pressure is approx. 30 hPa above the current atmospheric pressure since the sample gas flows off via a restrictor. If the resulting
dynamic pressure exceeds 100 hPa (rel.), a maintenance request is output. In order to reduce the 90 % time, we recommend instal-
lation of a bypass upstream of the gas inlet which then provides a faster exchange of gas. This is particularly important with long
sample gas lines between the gas sampling point and the analyzer. Please make absolutely sure that the flow in the OXYMAT 64
does not exceed 125 ml/min.

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Continuous Gas Analyzers, extractive


OXYMAT 64
General information
Gas path (low pressure with integrated sample gas pump) 1
Legend for the gas path figure
1 Sample gas inlet 6 Flow measuring tube
2 Sample gas outlet; sample gas flows off free of dynamic 7 Sample gas pump
pressure
3 O2 sensor 8 Restrictor
4 Pressure sensor 9 Purging gas connection
5 Needle valve

9 1 2

Oxygen sensor module, complete


O2 sensor 3
CIZ/CAZ
5

Δp

8 4

6
F

Low-pressure version with integral sample gas pump


The device version "OXYMAT 64 low-pressure with pump" is equipped with a sample gas pump which automatically provides a con-
stant sample gas flow of 125 ml/min through the sensor. By means of an internal bypass, the total flow of sample gas through the
analyzer is increased to approx. 0.4 l/min. This measure significantly improves the analyzer’s response time.

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Continuous Gas Analyzers, extractive


OXYMAT 64
General information
1 ■ Function
The measuring cell consists of a cylindrical (pipe-shaped) ZrO2 Measuring effect
membrane. The sample gas (low O2 content) flows at a constant
rate through the inside of the membrane, which is regulated at U = UA + RT/4F (In [O2,air] - In [O2] (equation 1)
650 °C. The exterior of the sensor is exposed to the ambient air U measuring effect
(approx. 21 % O2). UA asymmetric voltage (voltage, at [O2] = [O2,air]
T ceramic temperature
Both sides of the ZrO2 membrane are coated with thin platinum [O2,air] O2 concentration in the air
films that act as electrodes. This forms a solid, electrochemical [O2] O2 concentration in sample gas
cell. The amount of oxygen atoms ionized depends on the oxy-
gen concentration at the electrodes. Note

The differences in concentration at each side means that a dif- The sample gas must be fed into the analyzer free of dust. Con-
ferential partial pressure prevails. Since ZrO2 conducts ions at densation should be avoided. Therefore, gas modified for the
650 °C, ionic migration takes place in the direction of the lower measuring tasks is necessary in most application cases.
partial pressure. Calibration
An oxygen gradient arises across the width of the ZrO2 mem- Calibration of the calibration point is carried out as with the other
brane, which, according to equation (1), results in an electrical analyzers of Series 6 after a maximum of 14 days by connecting
potential difference between the platinum electrodes. the calibration gas O2 in residual N2 at concentrations of approx.
Defects in the crystal lattice, caused by contamination of the 60 to 90 % of the master measuring range.
ZrO2 material with Y2O3 and/or CaO (introduced originally to Contrary to the other analyzers of Series 6, the zero point calibra-
prevent cracks forming in ceramic material) make it easier for O2 tion cannot be carried out using pure nitrogen, but with a "small"
ions to diffuse in the ZrO2 grid. concentration of oxygen in nitrogen appropriate to the selected
measuring range (e.g.: measuring range 0 to 10 vpm; calibration
Catalytically active ZrO2 sensor (CAZ) gas approx. 2 ppm O2 in residual N2).
The electrode material is made of platinum (Pt). This type of sen-
sor has a higher cross-sensitivity when flammable accompany- Essential characteristics
ing gas components are present. • Four measurement ranges freely parameterizable, all mea-
surement ranges linear
Catalytically inactive ZrO2 sensor (CIZ)
• Galvanically isolated measurement value output 0/2/4 through
The catalytically inactive sensor has the same general design as 20 mA (also inverted) and as per NAMUR
the CAZ. The contacts and electrode surface inside the pipe are • Autoranging selectable; possibility of remote switching
made of a specially developed material which largely prevents
catalytic oxidation except of H2, CO and CH4. • Storage of measured values possible during adjustments
• Wide range of selectable time constants (static/dynamic noise
suppression); i.e. the response time of the device can be
       adapted to the respective measuring task
• Easy handling thanks to menu-driven operation
• Low long-term drift
• Two control levels with their own authorization codes for the
prevention of accidental and unauthorized operator interven-
tions
• Automatic, parameterizable measuring range calibration
• Operation based on the NAMUR recommendation
• Monitoring of the sample gas (via pressure switch)
• Customer-specific analyzer options such as:
- Customer acceptance
- TAG labels
- Drift recording
• Simple handling using a numerical membrane keyboard and
operator prompting
• Smallest span 0 to 10 vpm O2
• Largest span 0 to 100 % (testing with ambient air)
• Internal pressure sensor for correction of the influence of sam-
1 Pipe made of ZrO2 and Y2O3 or ple gas pressure fluctuations
ceramic CaO-mixed oxide
2 Ceramic protective coating
3 Sample electrode (Pt)
4 Reference electrode (Pt)
5 Thermoelement
6 Contact to reference electrode
7 Contact to sample electrode

OXYMAT 64, principle of operation

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Continuous Gas Analyzers, extractive


OXYMAT 64
General information
Influence of interfering gas 1
Catalytically active sensor (CAZ)
Very large cross-interference of all combustible accompanying
gases. Thus not suitable for use with combustible accompany-
ing gases!
Catalytically inactive sensor (CIZ)
There is only a slight cross-interference in the case of accompa-
nying gases with a concentration in the range of the O2 concen-
tration. H2, CO and CH4 still have a noticeable effect in the case
of flammable accompanying gas components.
Measured component / interfering gas Diagonal gas offset
78 vpm O2/140 vpm CO -6.1 vpm
10 vpm O2/10 vpm CO -0.6 vpm
74 vpm O2 / 25 vpm CH4 -0.3 vpm
25 vpm O2 / 357 vpm CH4 -1.1 vpm
25 vpm O2 / 70 vpm H2 -3 vpm
5 vpm O2 / 9.6 vpm H2 -0.55 vpm
170 vpm O2 / 930 vpm C2H4 -118 vpm
Examples of typical diagonal gas offsets on a catalytically inactive sensor
The listed deviations depend on the exemplar and can deviate
up to  0.2 vpm. The actual deviation must be determined indi-
vidually or the error will be eliminated through a corresponding
calibration measure (displacement of the diagonal gas offset).

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Continuous Gas Analyzers, extractive


OXYMAT 64
19" rack unit
1 ■ Technical specifications
General Measuring response (referred to sample gas pressure 1 013 hPa
absolute, sample gas flow 7.5 l/min, and ambient temperature 25 °C)
Measurement ranges 4, internally and externally switch-
able; automatic measuring range Output signal fluctuation <  1 % of the smallest possible
switchover also possible measuring range according to rat-
ing plate, with electronic damping
Smallest possible span (relating to 0 ... 10 vpm O2 constant of 1 s
sample gas pressure 1 000 hPa
absolute, 0.5 l/min sample gas flow, Zero point drift <  1 % of the current span/month
and 25 °C ambient temperature) Measured-value drift <  1 % of the current span/month
Largest possible measuring span 0 ... 100 % Repeatability < 3 % of the current measuring span
Operating position Front wall vertical Detection limit 1 % of current measuring range,
Conformity CE mark in accordance with < 0.1 vpm in measuring range
EN 50081-1, EN 50082-2 and 0 ... 10 vpm
RoHS Linearity error < 2 % of the current measuring span
Design, enclosure Influencing variables (relating to sample gas pressure 1 013 hPa
Degree of protection IP20 according to EN 60529 absolute, 7.5 l/min sample gas flow and 25 °C ambient temperature)
Weight Approx. 11 kg Ambient temperature < 2 %/10 K referred to current
measuring span
Electrical characteristics
Sample gas pressure only possible • When pressure compensation
EMC In accordance with standard if the sample gas can flow out into has been switched off: < 1 % of
(Electromagnetic Compatibility) requirements of NAMUR NE21 the ambient air current span/1 % pressure
(08/98) and EN 61326 change
Electrical safety In accordance with EN 61010-1, • When pressure compensation
overvoltage category II has been switched on: < 0.2 % of
current span/1 % pressure
Power supply 100 ... 120 V AC (nominal range of change
use 90 ... 132 V), 48 ... 63 Hz or
200 ... 240 V AC (nominal range of Residual gases, deviation from zero
use 180 ... 264 V), 48 ... 63 Hz point

Power consumption Approx. 37 VA • Catalytically active sensor (CAZ) Only gases with non-combustible
residual gas components can be
Fuse values 100 ... 120 V: 1.0T/250 introduced
200 ... 240 V: 0.63T/250 • Catalytically inactive sensor (CIZ) Residual gas concentration of
Gas inlet conditions 10 vpm H2; CO and CH4 have a
lower cross-interference; higher
Sample gas flow HCs are negligible
• through the sensor 7.5 l/h Sample gas flow < 2 % of the smallest possible
span with a change in flow of
• Overall consumption 15 ... 30 l/h
10 ml/min
Permissible sample gas pressure
Power supply < 0.1 % of the current measuring
• without internal pressure regulator 2 000 hPa (abs.) range with rated voltage  10 %
• with internal pressure regulator 2 000 ... 6 000 hPa (abs.) Electrical inputs and outputs
Sample gas temperature Min. 0 ... max. 50 °C, but above Analog output 0/2/4 ... 20 mA, 4 … 20 mA
the dew point (NAMUR), isolated; max. load
750 
Sample gas humidity < 1 % relative humidity
Relay outputs 6, with changeover contacts, freely
Dynamic response parameterizable, e.g. for measur-
Warm-up period At room temperature < 30 min (the ing range identification;
technical specification will be met load: 24 V AC/DC/1 A, isolated
after 2 hours) Analog inputs 2, dimensioned for 0/2/4 … 20 mA
Damping (electrical time constant) 0 ... 100 s, parameterizable for external pressure sensor and
correction of influence of residual
Dead time (high-pressure version) 10 ... 30 s gas (correction of cross-interfer-
(purging time of the gas path in the ence)
unit at 125 ml/min)
Binary inputs 6, designed for 24 V, isolated,
Dead time (low-pressure version <5s freely parameterizable, e.g. for
without pump) measurement range switchover
Dead time (low-pressure version < 10 s Serial interface RS 485
with pump)
Options AUTOCAL function each with 8
Time for device-internal signal <1s additional binary inputs and relay
processing outputs, also with PROFIBUS PA or
Pressure correction range PROFIBUS DP

Pressure sensor internal 800 ... 1 100 hPa (abs.) Climatic conditions
Permissible ambient temperature -40 ... +70 °C during storage and
transportation, 5 … 45 °C during
operation
Permissible humidity < 90 % relative humidity as annual
average, during storage and trans-
portation (must not fall below dew
point)

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Continuous Gas Analyzers, extractive


OXYMAT 64
19" rack unit

Selection and ordering data Article No.


1
OXYMAT 64 gas analyzer 7MB2041- 7 7 7 1 7 - 7 A 7 7 Cannot be combined
19" rack unit for installation in cabinets
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Sensor
ZrO2: Catalytically active cell (CAC) 0 0
ZrO2: Catalytically inactive cell (CIC) 1 1
ZrO2: Catalytically active cell (CAC); with differential pressure sensor 2 2
ZrO2: Catalytically inactive cell (CIC); with differential pressure sensor 3 3
Sample gas pressure
High pressure, without pressure regulator 2 000 hPa (abs.) A A
High pressure, with pressure regulator 2 000 ... 6 000 hPa (abs.) B B
Low pressure, with pump Atmosphere C C
Low pressure, without suction pump Atmosphere D D
Gas connection
Input Clamping ring connection 6 mm A
Output Fittings 6 mm
Input Clamping ring connection ¼" B
Output Fitting ¼"
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs/outputs 1
• With 8 additional digital inputs/outputs and PROFIBUS PA interface 6
• With 8 additional digital inputs/outputs and PROFIBUS DP interface 7
Power supply
100 to 120 V AC, 48 to 63 Hz 0

200 to 240 V AC, 48 to 63 Hz 1

Explosion protection
Without A
Language
German 0
English 1
French 2
Spanish 3
Italian 4
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Telescopic rails (2 units) A31
TAG labels (specific lettering based on customer information) B03
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting Y12
(only in conjunction with an application no., e.g. extended measuring range)
Extended special setting Y13
(only in conjunction with an application no., e.g. determination of cross-interfer-
ences)
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function each with 8 digital inputs/outputs C79451-A3480-D511
AUTOCAL function 8 digital inputs/outputs each and PROFIBUS PA A5E00057307
AUTOCAL function 8 digital inputs/outputs each and PROFIBUS DP A5E00057312
Set of Torx screwdrivers A5E34821625

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Continuous Gas Analyzers, extractive


OXYMAT 64
19" rack unit
1 ■ Dimensional drawings

384.5
351.5
27.5
15.6

173 128 4

s
101.6

37.7

149.5
177

82
172
M4

2;<0$7

86.5
465
483

440

411.5
104
132

320
345
36
0

  

OXYMAT 64, 19" rack unit, size in mm

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OXYMAT 64
19" rack unit

■ Schematics
1
Pin assignment (electrical connections)

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OXYMAT 64, 19" rack unit, pin assignment

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Continuous Gas Analyzers, extractive


OXYMAT 64
19" rack unit
1
Connector SUB-D 37F (option)

M 19 GND
37 NC
18 NC
36 Binary input 14-P
17 Binary input 13-P
35 Binary input 12-P Isolated
16 Binary input 11-P via optocoupler
34 Binary input 10-P "0" = 0 V (0 ... 4.5 V)
15 Binary input 9-P "1" = 24 V (13 ... 33 V)
33 Binary input 8-P
14 Binary input 7-P
32 Binary input 7 to 14-N
13
31 Relay 14
12
30
11 Relay 13
29
10
28 Relay 12
9
27 Contact load
8 Relay 11 max. 24 V/1 A, AD/DC
26
7 for shown
25 Relay 10 relay contact position,
6 the relay has zero current
24
5 Relay 9
23
4
22 Relay 8
3
21
2 Relay 7
20
M 1 GND

Connector SUB-D 9F-X90 Connector SUB-D 9M-X90


Optional
PROFIBUS DP PROFIBUS PA

5 DGND 5
9 CNTR-N 9
4 CNTR-P/direction control 4
8 RxD/TxD-N (A) 8 PA-N(-)
3 RxD/TxD-P (B) 3 PA-P(+)
7 7
2 2
6 VP /+ 5 V 6
1 1

1RWH
$OOFDEOHVWRWKHFRQQHFWRUVRUWHUPLQDOEORFNVPXVWEH
VKLHOGHGDQGUHVWDJDLQVWWKHHQFORVXUHSRWHQWLDO

OXYMAT 64, 19" rack unit, pin assignment of the AUTOCAL plate and PROFIBUS plug

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Continuous Gas Analyzers, extractive


OXYMAT 64
19" rack unit
Gas connections and pin assignment 1
Sample gas outlet Sample gas inlet 15-pin connector: 9-pin
Binary inputs and connector:
analog inputs/outputs RS 485

2 1 Purge gas
inlet
9-pin
interface
connector
(Optional):
e.g.
PROFIBUS

Mains connection
and miniature
fuses
37-pin connector:
Binary inputs and
relay outputs (optional)
25-pin connector:
Binary inputs and
Gas connections relay outputs
Sample gas inlet: Clamping ring connection 6 mm or ¼"
Sample gas outlet: Fittings 6 mm or ¼"

OXYMAT 64, 19" rack unit, gas connections and electrical connections

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OXYMAT 64
Documentation
1 ■ Selection and ordering data
Operating instructions Article No.
OXYMAT 64
Gas analyzer for measuring trace
oxygen
• German A5E00880382
• English A5E00880383
• French A5E00880384
• Spanish A5E00880385
• Italian A5E00880386
Gas analyzers of Series 6 and
ULTRAMAT 23
Schnittstelle/Interface
PROFIBUS DP/PA
• German and English A5E00054148

Suggestions for spare parts

■ Selection and ordering data


Description 7MB2041 2 years 5 years Article No.
(quantity) (quantity)
Pressure regulator as spare part x – 1 A5E01008972
Flowmeter x – 1 A5E01061561
Adapter plate, LC display/keypad x 1 1 C79451-A3474-B605
LC display x – 1 W75025-B5001-B1
Connector filter x – 1 W75041-E5602-K2
Fuse, T 0.63 A, line voltage 200 … 240 V x 2 4 W79054-L1010-T630
Fuse, T 1 A, line voltage 100 … 120 V x 2 4 W79054-L1011-T100

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Continuous Gas Analyzers, extractive


CALOMAT 6
General information

■ Overview Special versions 1


Special applications
In addition to the standard combinations, special applications
are also available upon request (e.g. higher sample gas pres-
sure up to 2 000 hPa absolute).

■ Design
19" rack unit
• With 4 HU for installation
- in hinged frame
- in cabinets with or without telescopic rails
• Front plate for service purposes can be pivoted down
(laptop connection)
• Internal gas paths: stainless steel pipe (mat. no. 1.4571)
• Gas connections for sample gas inlet and outlet and for purg-
ing gas: fittings, pipe diameter of 6 mm or ¼"
Field device
The CALOMAT 6 gas analyzer is primarily used for quantitative • Two-door enclosure (IP65) with gas-tight separation of ana-
determination of H2or He in binary or quasi-binary non-corrosive lyzer and electronics sections
gas mixtures. • Individually purgeable enclosure halves
Concentrations of other gases can also be measured if their • Stainless steel gas path and stubs (mat. no. 1.4571)
thermal conductivities differ significantly from the residual gases • Purging gas connections: pipe diameter 10 mm or 3/8"
like Ar, CO2, CH4, NH3.
• Gas connections for sample gas inlet and outlet: clamping
ring connection for a pipe diameter of 6 mm or ¼"
■ Benefits
Display and control panel
• Small T90 time due to micromechanical-produced Si sensor
• Large LCD panel for simultaneous display of:
• Universally applicable hardware basis, high measuring range - Measured value (digital and analog displays)
dynamics (e.g. 0 to 1 %, 0 to 100 %, 95 to 100 % H2) - Status bar
• Integrated correction of cross-interference, no external calcu- - Measuring ranges
lation required • Contrast of LCD panel adjustable using menu
• Open interface architecture (RS 485, RS 232, PROFIBUS) • Permanent LED backlighting
• SIPROM GA network for maintenance and service information • Washable membrane keyboard with five softkeys
(option)
• Menu-driven operation for parameterization, test functions,
• Electronics and analyzer part: gas-tight separation, purge- adjustment
able, IP65, long service life even in harsh environments
• User help in plain text
• EEx(p) for Zones 1 and 2 (in accordance with 94/9/EC
(ATEX 2G and ATEX 3G), and Class I Div 2 (CSA) Ex(n) • Graphic display of concentration trend; programmable time
intervals
■ Application • Bilingual operating software German/English, English/
Spanish, French/English, Spanish/English, Italian/English
Fields of application
Input and outputs
• Pure gas monitoring (0 to 1 % H2 in Ar)
• One analog output per medium (from 0, 2, 4 to 20 mA; NAMUR
• Protective gas monitoring (0 to 2 % He in N2) parameterizable)
• Hydroargon gas monitoring (0 to 25 % H2 in Ar) • Two analog inputs configurable (e.g. correction of cross-inter-
• Forming gas monitoring (0 to 25 % H2 in N2) ference or external pressure sensor)
• Gas production: • Six binary inputs freely configurable (e.g. for measurement
- 0 to 2 % He in N2 range switchover, processing of external signals from sample
- 0 to 10 % Ar in O2 preparation)
• Chemical applications: • Six relay outputs freely configurable (e.g. failure, maintenance
- 0 to 2 % H2 in NH3 request, limit alarm, external solenoid valves)
- 50 to 70 % H2 in N2 • Each can be expanded by eight additional binary inputs and re-
• Wood gasification (0 to 30 % H2 in CO/CO2/CH4) lay outputs (e.g. for autocalibration with max. four test gases)
• Blast furnace gas (0 to 5 % H2 in CO/CO2/CH4/N2) Communication
• Bessemer converter gas (0 to 20 % H2 in CO/CO2) RS 485 present in basic unit (connection from the rear; for the
• Monitoring equipment for hydrogen-cooled turbo-alternators: rack unit also behind the front plate).
- 0 to 100 % CO2/Ar in air
- 0 to 100 % H2 in CO2/Ar Options
- 80 to 100 % H2 in air • RS 485/RS 232 converter
• Versions for the analysis of flammable and non-flammable • RS 485/Ethernet converter
gases or vapors for use in hazardous areas (Zone 1 and • RS 485/USB converter
Zone 2)
• Connection to networks via PROFIBUS DP/PA interface
• SIPROM GA software as the service and maintenance tool

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Continuous Gas Analyzers, extractive


CALOMAT 6
General information
1 LED backlit graphic Status line for display Two code levels
display and of analyzer status according to NAMUR
membrane keyboard (programmable) (maintenance and
with noticeable click specialist level)

Easy operation with


menu control
using five softkeys

Display of
concentrations as
numbers and bargraph Display of current
measuring ranges
Display of
start-of-scale and
full-scale values

ESC key
to abort inputs
Keyboard to
enter values

INFO key
for help in plain text

CLEAR key
to delete inputs
ENTER key MEAS key
to accept to return to
input values measurement mode

CALOMAT 6, membrane keyboard and graphic display


Designs – parts wetted by sample gas
Gas path 19" rack unit Field device Field device Ex
With pipes Bushing Stainless steel, mat. no. 1.4571
Pipe Stainless steel, mat. no. 1.4571
Sample cell body Stainless steel, mat. no. 1.4571
O-rings FFKM-Chemraz
Sensor Si, SiOxNy, AU, epoxy resin, glass
Tightness Leakage < 1 l/s

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Continuous Gas Analyzers, extractive


CALOMAT 6
General information
1

  
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CALOMAT 6, 19" rack unit, gas path

     
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CALOMAT 6, field device, gas path

Siemens PA 01 · 2015 1/169


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Continuous Gas Analyzers, extractive


CALOMAT 6
General information
1 ■ Function
Principle of operation • Two control levels with their own authorization codes for the
prevention of accidental and unauthorized operator interven-
The measuring principle is based on the different thermal con- tions
ductivity of gases.
• Simple handling using a numerical membrane keyboard and
The CALOMAT 6 works with a micromechanically produced operator prompting
Si chip whose measuring membrane is equipped with thin-film
resistors. • Customer-specific analyzer options such as:
- Customer acceptance
The resistors are kept at a constant temperature. This requires - TAG labels
an current intensity depending on the thermal conductivity of the - Drift recording
sample gas. This "raw value" is processed further electronically - Clean for O2 service
to calculate the gas concentration.
Measuring spans
The sensor is located in a thermostatically-controlled stainless
steel enclosure in order to prevent the influence of changes in The smallest and largest possible spans depend on both the
ambient temperature. measured component (type of gas) and the respective applica-
tion.
To prevent the influence of changes in flow, the sensor is posi-
tioned in a bore located to the side of the main flow. The smallest possible spans listed below refer to N2 as the resid-
ual gas. With other gases which have a larger/smaller thermal
Note conductivity than N2, the smallest possible span is also
The sample gases must be fed into the analyzers free of dust. larger/smaller.
Condensation (dew point sample gas < ambient temperature) is Component Smallest possible span
to be avoided in the measurement chambers. Therefore, the use H2 0 ... 1 % (95 ... 100 %)
of gas modified for the measuring tasks is necessary in most ap-
plication cases. He 0 ... 2 %
Ar 0 ... 10 %
Measuring
CO2 0 ... 20 %
membrane
with thin-film CH4 0 ... 15 %
resistors H2 in blast furnace gas 0 ... 10 %
H2 in converter gas 0 ... 20 %
H2 with wood gasification 0 ... 30 %
Sample
gas Influence of interfering gases
Knowledge of the sample gas composition is necessary to de-
termine the influence of residual gases with several interfering
components.
The following table lists the zero offsets expressed in % H2 re-
CALOMAT, principle of operation sulting from 10 % residual gas (interfering gas) in each case.
Component Zero offset
Essential characteristics
Ar -1.28 %
• Four freely parameterizable measuring ranges, also with sup-
pressed zero point, all measuring ranges linear CH4 +1.59 %
• Smallest measuring spans up to 1 % H2 (with disabled zero C2H6 (non-linear response) +0.04 %
point: 95 to 100 % H2) possible C3H8 -0.80 %
• Measuring range identification
CO -0.11 %
• Galvanically isolated measured-value output 0/2/4 to 20 mA
(also inverted) CO2 -1.07 %

• Autoranging or manual measurement range switchover possi- He +6.51 %


ble; remote switching is also possible H2O (non-linear response) +1.58 %
• Storage of measured values possible during adjustments NH3 (non-linear response) +1.3 %
• Wide range of selectable time constants (static/dynamic noise O2 +0.18 %
suppression); i.e. the response time of the analyzer can be
matched to the respective measuring task SF6 -2.47 %

• Short response time SO2 -1.34 %


• Low long-term drift 100 % air (dry) +0.27 %
• Measuring point switchover for up to 6 measuring points For residual gas concentrations differing from 10 %, the corre-
(programmable) sponding multiple of the associated value in the table provides
• Measuring range identification an acceptable approximation. This is valid for for residual gas
concentrations up to 25 % (dependent on type of gas).
• Measuring point identification
• External pressure sensor can be connected – for the correc- The thermal conductivity of most gas mixtures has a non-linear
tion of sample gas fluctuations response. Even ambiguous results, such as e.g. with NH3/N2
mixtures, can occur within a specific concentration range.
• Automatic range calibration can be parameterized
• Operation based on the NAMUR recommendation

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© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
General information
In addition to a zero offset, it should also be noted that the gra- Bus terminating resistors 1
dient of the characteristic is influenced by the residual gas. How-
ever, this effect is negligible for most gases. Pins 3-7 and 8-9 of the first and last connectors of a bus cable
must be bridged (see image).
In case of correction of the influence of interfering gases with ad-
ditional analyzers (ULTRAMAT 6/ULTRAMAT 23), the resulting Note
measuring error can – depending on the application – amount It is advisable to install a repeater on the device side in the case
up to 5 % of the smallest measuring range of the respective ap- of a cable length of more than 500 m or with high interferences.
plication.
Up to four components can be corrected via the ELAN bus, cor-
Example of correction of cross-interference rection of cross-interference can be carried out for one or two
components via the analog input.
Specification for the interface cable
Surge impedance 100 ... 300 , with a measuring
frequency of > 100 kHz
Cable capacitance Typ. < 60 pF/m
Core cross-section > 0.22 mm2,
corresponds to AWG 23
Cable type Twisted pair, 1 x 2 conductors of
cable section
Signal attenuation Max. 9 dB over the whole length
Shielding Copper braided shield or braided
shield and foil shield
Connection Pin 3 and pin 8

0 
*1' 
 9-pin connector

 (RS 485)
9  (device 1)


0 

0 
*1' 
 9-pin connector

 (RS 485)
9  (device 2)


0 

0 
*1' 
 9-pin connector

 (RS 485)
9  (device 3)


0 

Bus cable with plug connections, example

Siemens PA 01 · 2015 1/171


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Continuous Gas Analyzers, extractive


CALOMAT 6
19" rack unit
1 ■ Technical specifications
General (based on EN 61207/IEC 1207. All data refers to the binary Measuring response (relating to sample gas pressure 1 013 hPa
mixture H2 in N2) absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Measuring ranges 4, internally and externally switch- Output signal fluctuation <  0.75 % of the smallest possi-
able; automatic measurement ble measuring range according to
range switchover also possible rating plate, with electronic
damping constant of 1 s
Largest possible measuring span 100 vol.% H2 (for smallest mea- ( = 0.25 %)
suring span, see "Function")
Zero point drift <  1 %/week of the smallest pos-
Measuring ranges with suppressed Any zero point within sible measuring span according
zero point 0 ... 100 vol.% can be to rating plate
implemented, smallest possible
measuring span: 5 % H2 Measured-value drift <  1 %/week of the smallest pos-
sible measuring span according
Operating position Front wall, vertical to rating plate
Conformity CE mark in accordance with Repeatability < 1 % of the current measuring
EN 61326/A1 and EN 61010/1 range
Design, enclosure Detection limit 1 % of the current measuring
Degree of protection IP20 according to EN 60529 range

Weight Approx. 10 kg Linearity error <  1 % of the current measuring


range
Electrical characteristics
Influencing variable (relating to sample gas pressure 1 013 hPa
EMC In accordance with standard absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
(Electromagnetic Compatibility) requirements of NAMUR NE21
(All signal lines must be shielded. (08/98) Ambient temperature < 1 %/10 K referred to smallest
Measured value deviations of up to possible measuring span accord-
4 % of the smallest measuring ing to rating plate
range may occur in ranges with Carrier gases Deviation from zero point (for
strong electromagnetic interfer- influence of interfering gas see
ence.) paragraph titled "Interference
Electrical safety In accordance with EN 61010-1; influences")
overvoltage category II Sample gas flow < 0.2 % of the smallest possible
Power supply (see rating plate) 100 V -10 % ... 120 V +10 % AC, span according to rating plate
48 ... 63 Hz or 200 V -10 % ... with a change in flow of 0.1 l/min
240 V +10 % AC, 48 ... 63 Hz within the permissible flow range

Power consumption Approx. 20 VA Sample gas pressure < 1 % of the current measuring
range with a pressure change of
Fuse values 100 ... 120 V: 1.0T/250 100 hPa
200 ... 240 V: 0.63 T/250
Power supply < 0.1 % of the current measuring
Gas inlet conditions range with rated voltage  10 %
Sample gas pressure 800 ... 1 100 hPa (absolute) Electrical inputs and outputs
Sample gas flow 30 ... 90 l/h (0.5 ... 1.5 l/min) Analog output 0/2/4 ... 20 mA, isolated;
load max. 750 
Sample gas temperature Min. 0 to max. 50 °C, but above
the dew point Relay outputs 6, with changeover contacts,
freely parameterizable, e.g. for
Temperature of the measuring cell Approx. 60 ºC measuring range identification;
Sample gas humidity < 90 % relative humidity load: 24 V AC/DC/1 A, isolated
Dynamic response Analog inputs 2, dimensioned for
0/2/4 … 20 mA for external pres-
Warm-up period < 30 min (the technical specifica- sure sensor and correction of
tion will be met after 2 hours) cross-interference
Delayed display (T90) <5s Binary inputs 6, designed for 24 V, isolated,
Damping (electrical time constant) 0 ... 100 s, parameterizable freely parameterizable, e.g. for
measurement range switchover
Dead time (purging time of the gas Approx. 0.5 s
path in the unit at 1 l/min) Serial interface RS 485
Options AUTOCAL function with
8 additional binary inputs and
relay outputs each, also with
PROFIBUS PA or PROFIBUS DP
Climatic conditions
Permissible ambient temperature -30 … +70 °C during storage and
transportation, 5 … 45 °C during
operation
Permissible humidity (dew point < 90 % relative humidity as
must not be undershot) annual average, during storage
and transportation

1/172 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
19" rack unit

Selection and ordering data Article No.


1
CALOMAT 6 gas analyzer 7MB2521- 7 7 7 00 7 - 7 A 7 7 Cannot be combined
19" rack unit for installation in cabinets
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Connections for sample gas
0
Pipe with 6 mm outer diameter
1
Pipe with 1/4" outer diameter
Measured component Smallest/largest
measuring range
H2 in N2 0 ... 1/100 % AA
H2 in N2 (blast furnace gas measurement)1) 0 ... 5/100 % AW
H2 in N2 (converter measurement)1) 0 ... 5/100 % AX
H2 in N2 (wood gasification)1) 0 ... 5/100 % AY
H2 in Ar 0 ... 1/100 % AB
H2 in NH3 0 ... 1/100 % AC
He in N2 0 ... 2/100 % BA
He in Ar 0 ... 2/100 % BB
He in H2 0 ... 10/80 % BC
Ar in N2 0 ... 10/100 % CA
Ar in O2 0 ... 10/100 % CB
CO2 in N2 0 ... 20/100 % DA
CH4 in Ar 0 ... 15/100 % EA
NH3 in N2 0 ... 10/30 % FA
H2 monitoring (turbo generators) GA GA
• CO2 in air 0 ... 100 %
• H2 in CO2 0 ... 100 %
• H2 in air 80 ... 100 %
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs and outputs 1
• With 8 additional digital inputs/outputs and PROFIBUS PA interface 6 6
• With 8 additional digital inputs/outputs and PROFIBUS DP interface 7 7
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Explosion protection
Without A
Certificate: ATEX II 3G, flammable and non-flammable gases B
FM/CSA certificate – Class I Div 2 D
Language (supplied documentation, software)
German 0
English 1
French 2
Spanish 3
Italian 4
1)
Ready to enter external correction of cross-interferences for CO, CO2 and CH4 (CH4 only for blast furnace gas and wood gasification).

Siemens PA 01 · 2015 1/173


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Continuous Gas Analyzers, extractive


CALOMAT 6
19" rack unit
1 ■ Selection and ordering data
Additional versions Order code
Add "-Z" to Article No. and specify Order codes.
Telescopic rails (2 units) A31
TAG labels (specific lettering based on customer information) B03
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with 8 digital inputs/outputs C79451-A3480-D511
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057307
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057312
Set of Torx screwdrivers A5E34821625

1/174 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
19" rack unit

■ Dimensional drawings
1
 

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CALOMAT 6, 19“ unit, dimensions in mm

Siemens PA 01 · 2015 1/175


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
19" rack unit
1 ■ Schematics
Pin assignment (electrical and gas connections)

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CALOMAT 6, 19“ unit, pin assignment

1/176 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
19" rack unit
1
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CALOMAT 6, 19“ unit, pin assignment of AUTOCAL board and PROFIBUS connectors

Siemens PA 01 · 2015 1/177


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
19" rack unit
1
Sample gas outlet Sample gas inlet 15-pin connector 9-pin
Binary inputs and connector:
relay outputs RS 485 Purging gas inlet

9-pin
interface
connector
(option): e.g.
PROFIBUS

Power supply
and fuses

37-pin connector
Binary inputs and
relay outputs (option)
25-pin connector
Binary inputs and
Gas connections: stubs 6 mm or ¼" relay outputs

CALOMAT 6, 19“ unit, gas and electrical connections

1/178 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
Field device

■ Technical specifications
1
General (based on DIN EN 61207 / IEC 1207. All data refers to the Measuring response (relating to sample gas pressure 1 013 hPa
binary mixture H2 in N2) absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
Measuring ranges 4, internally and externally switch- Output signal fluctuation (maximum <  0.75 % of the smallest possi-
able; automatic measuring range accuracy achieved after 2 hours) ble measuring range according to
changeover also possible rating plate, with electronic
damping constant of 1 s
Largest possible measuring span 100 vol.% H2 (for smallest mea- ( = 0.25 %)
suring span, see "Function")
Zero point drift <  1 %/week of the smallest pos-
Measuring ranges with suppressed Any zero point within sible measuring span according
zero point 0 ... 100 vol.% can be to rating plate
implemented; smallest possible
measuring span: 5 % H2 Measured-value drift <  1 %/week of the smallest pos-
sible measuring span according
Operating position Front wall, vertical to rating plate
Conformity CE mark in accordance with Repeatability < 1 % of the current measuring
EN 61326/A1 and EN 61010/1 range
Design, enclosure Detection limit 1 % of the current measuring
Degree of protection IP65 according to EN 60529 range

Weight Approx. 25 kg Linearity error <  1 % of the current measuring


range
Electrical characteristics
Influencing variables (relating to sample gas pressure 1013 hPa
EMC In accordance with standard absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature)
(Electromagnetic Compatibility) requirements of NAMUR NE21
(All signal lines must be shielded. (08/98) Ambient temperature < 1 %/10 K referred to smallest
Measured value deviations of up to possible measuring span accord-
4 % of the smallest measuring ing to rating plate
range may occur in ranges with Carrier gases Deviation from zero point (for
strong electromagnetic interfer- influence of interfering gas see
ence.) paragraph titled "Interference
Electrical safety In accordance with EN 61010-1; influences")
overvoltage category II Sample gas flow < 0.2 % of the smallest possible
Power supply (see rating plate) 100 V -10 % ... 120 V +10 % AC, span according to rating plate
48 ... 63 Hz or with a change in flow of 0.1 l/min
200 V -10 % ... 240 V +10 % AC, within the permissible flow range
48 ... 63 Hz Sample gas pressure < 1 % of the current measuring
Power consumption (unit) Approx. 20 VA range with a pressure change of
100 hPa
Fuse values 100 ... 120 V: 1.0T/250
200 ... 240 V: 0.63 T/250 Electrical inputs and outputs

Gas inlet conditions Analog output 0/2/4 ... 20 mA, isolated;


load max. 750 
Sample gas pressure 800 ... 1 100 hPa (absolute)
Relay outputs 6, with changeover contacts,
Sample gas flow 30 ... 90 l/h (0.5 ... 1.5 l/min) freely parameterizable, e.g. for
measuring range identification;
Sample gas temperature Min. 0 to max. 50 °C, but above load: 24 V AC/DC/1 A, isolated
the dew point
Analog inputs 2, dimensioned for 0/2/4 ... 20 mA
Temperature of the measuring cell Approx. 60 ºC for external pressure sensor and
Sample gas humidity < 90 % relative humidity correction of cross-interference
Purging gas pressure Binary inputs 6, designed for 24 V, isolated,
freely parameterizable, e.g. for
• Permanent 165 hPa above ambient pressure measurement range switchover
• For short periods Max. 250 hPa above ambient Serial interface RS 485
pressure
Options AUTOCAL function with
Dynamic response (relating to sample gas pressure 1 000 hPa 8 additional binary inputs and
absolute, 0.5 l/min sample gas flow and 25 °C ambient temperature) relay outputs each, also with
Warm-up period < 30 min (the technical specifica- PROFIBUS PA or PROFIBUS DP
tion will be met after 2 hours) Climatic conditions
Delayed display (T90) <5s Permissible ambient temperature -30 ... +70 °C during storage and
Electrical damping 0 ... 100 s, parameterizable transportation, 5 … 45 °C during
operation
Dead time (at 1 l/min) Approx. 0.5 s
Permissible humidity (dew point < 90 % relative humidity as
must not be undershot) annual average, during storage
and transportation

Siemens PA 01 · 2015 1/179


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
Field device
1 Selection and ordering data Article No.
CALOMAT 6 gas analyzer 7MB2511- 7 7 7 00 7 - 7 A 7 7 Cannot be combined
For field installation
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Connections for sample gas
Ferrule screw connection for pipe, outer diameter 6 mm 0
Ferrule screw connection for pipe, outer diameter 1/4" 1
Measured component Smallest/largest
measuring range
H2 in N2 0 ... 1/100 % AA AA
H2 in N2 (blast furnace gas measurement)1) 0 ... 5/100 % AW AW
H2 in N2 (converter measurement)1) 0 ... 5/100 % AX AX
H2 in N2 (wood gasification)1) 0 ... 5/100 % AY AY
H2 in Ar 0 ... 1/100 % AB AB
H2 in NH3 0 ... 1/100 % AC AC
He in N2 0 ... 2/100 % BA
He in Ar 0 ... 2/100 % BB
He in H2 0 ... 10/80 % BC BC
Ar in N2 0 ... 10/100 % CA
Ar in O2 0 ... 10/100 % CB
CO2 in N2 0 ... 20/100 % DA
CH4 in Ar 0 ... 15/100 % EA EA
NH3 in N2 0 ... 10/30 % FA FA
H2 monitoring (turbo generators) GA GA GA
• CO2 in air 0 ... 100 %
• H2 in CO2 0 ... 100 %
• H2 in air 80 ... 100 %
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs and outputs 1
• With 8 additional digital inputs/outputs and PROFIBUS PA interface 6 6 6
• With 8 additional digital inputs/outputs and PROFIBUS DP interface 7 7 7
• With 8 additional digital inputs/outputs and PROFIBUS PA Ex-i interface 8 8 8
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Explosion protection, incl. certificate
Without A
Acc. to ATEX II 3G, non-flammable gases B B
Acc. to ATEX II 3G; flammable gases2) C
FM/CSA certificate – Class I Div 2 D D
According to ATEX II 2G, leakage compensation2) E E
According to ATEX II 2G, continuous purging2) F F
ATEX II 3D certificate; potentially explosive dust atmospheres
• In non-hazardous gas zone G
• In Ex zone acc. to ATEX II 3G, non-flammable gases H
• In Ex zone acc. to ATEX II 3G, flammable gases2) J
Language (supplied documentation, software)
German 0
English 1
French 2
Spanish 3
Italian 4
1) Ready to enter external correction of cross-interferences for CO, CO2 and CH4 (CH4 only for blast furnace gas and wood gasification).
2) Only in connection with an approved purging unit.

1/180 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
Field device

■ Selection and ordering data


1
Additional versions Order code
Add "-Z" to Article No. and specify Order codes.
TAG labels (specific lettering based on customer information) B03
BARTEC EEx p control unit "Leakage compensation" E71
BARTEC EEx p control unit "Continuous purging" E72
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Additional units for Ex versions Article No.
ATEX Category II 2G (zone 1)
BARTEC EEx p control unit, 230 V, "leakage compensation" 7MB8000-2BA
BARTEC EEx p control unit, 115 V, "leakage compensation" 7MB8000-2BB
BARTEC EEx p control unit, 230 V, "continuous purging" 7MB8000-2CA
BARTEC EEx p control unit, 115 V, "continuous purging" 7MB8000-2CB
Ex isolation amplifier 7MB8000-3AB
Ex isolating relay, 230 V 7MB8000-4AA
Ex isolating relay, 110 V 7MB8000-4AB
Differential pressure switch for corrosive and non-corrosive gases 7MB8000-5AA
Stainless steel flame arrestor 7MB8000-6BA
Hastelloy flame arrestor 7MB8000-6BB
ATEX Category II 3G (zone 2)
BARTEC EEx p control unit, 230 V, "continuous purging" 7MB8000-2CA
BARTEC EEx p control unit, 115 V, "continuous purging" 7MB8000-2CB
FM/CSA (Class I Div. 2)
Ex purging unit Minipurge FM 7MB8000-1AA
Accessories
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with 8 digital inputs/outputs A5E00064223
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057315
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057318
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA Ex i (firmware 4.1.10 required) A5E00057317
Set of Torx screwdrivers A5E34821625

Siemens PA 01 · 2015 1/181


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
Field device
1 ■ Dimensional drawings
























 



 
  
º 

s &$/20$7





CALOMAT 6, field unit, dimensions in mm

1/182 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, extractive


CALOMAT 6
Field device

■ Schematics
1
Pin assignment (electrical and gas connections)

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CALOMAT 6, field unit, connector and terminal assignment

Siemens PA 01 · 2015 1/183


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Continuous Gas Analyzers, extractive


CALOMAT 6
Field device
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CALOMAT 6, field unit, connector and terminal assignment of the AUTOCAL board and PROFIBUS connectors

1/184 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


CALOMAT 6
Field device
1

a b c d 5 7

1 3

2 4

8
6

Gas connections Electrical connections


1 not used a-c Signal cable (Ø 10 ... 14 mm)
(analog + digital): cable gland M20x1.5
2 Sample gas inlet Clamping
gland for pipe d Interface connection: (Ø 7 ... 12 mm)
3 not used cable gland M20x1.5
Ø 6 mm or ¼"
4 Sample gas outlet e Power supply: (Ø 7 ... 12 mm)
cable gland M20x1.5
5 - 8 Purging gas inlets/outlets stubs Ø 10 mm or 3/8 "

CALOMAT 6, field unit, gas and electrical connections

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Continuous Gas Analyzers, extractive


CALOMAT 6
Documentation
1 ■ Selection and ordering data
Operating instructions Article No.
CALOMAT 6
Thermal conductivity gas analyzer
• German A5E00116454
• English A5E00116455
• French A5E00116456
• Italian A5E00116457
• Spanish A5E00116458
Gas analyzers of Series 6 and
ULTRAMAT 23
Schnittstelle/Interface
PROFIBUS DP/PA
• German and English A5E00054148

Suggestions for spare parts

■ Selection and ordering data


7MB2521 7MB2511 7MB2511 Ex 2 years 5 years Article No.
(quantity) (quantity)
Analyzer unit
Measuring cell x x x 1 1 A5E00095332
O ring (set of 4) x x x 1 2 A5E00124182
Electronics
Fuse (device fuse) x 1 2 A5E00061505
Front plate without LC display x 1 1 C79165-A3042-B508
Motherboard, with firmware: see spare x x x - 1
parts list
Adapter plate, LCD/keyboard x x 1 1 C79451-A3474-B605
LC display (non-Ex version) x 1 1 W75025-B5001-B1
Line transformer, 115 V x x x - 1 W75040-B21-D80
Line transformer, 230 V x x x - 1 W75040-B31-D80
Connector filter x x x - 1 W75041-E5602-K2
Fusible element, T 0.63/250 V x x 2 3 W79054-L1010-T630
Fusible element, 1 A, 110/120 V x x x 2 3 W79054-L1011-T100

If the CALOMAT 6 is supplied with a specially cleaned gas path for high oxygen context ("Cleaned for O2 service"), please ensure
that you specify this when ordering spare parts. This is the only way to guarantee that the gas path will continue to comply with the
special requirements for this version.

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Continuous Gas Analyzers, extractive


CALOMAT 62
General information

■ Overview ■ Design
1
19" rack unit
• With 4HE for installation
- in hinged frame
- in cabinets with or without telescope rails
- With closed or flow-type reference chambers
• Front plate for service purposes can be pivoted down
(laptop connection)
• IP20 degree of protection, with purging gas connection
• Internal gas routes: Pipe made of stainless steel
(mat. no. 1.4571)
• Gas connections for sample gas inlet and outlet and for refer-
ence gas: Internal thread 1/8" – 27 NPT
• Purging gas connections: Pipe diameter 6 mm or 1/4"
• With closed or flow-type reference chambers
Field device
• Two-door enclosure (IP65) for wall mounting with gas-tight
The CALOMAT 62 gas analyzer is primarily used for quantitative separation of analyzer and electronic parts, purgeable
determination of one gas component (e.g. H2, N2, Cl2, HCl, NH3) • Individually purgeable enclosure halves
in binary or quasi-binary gas mixtures.
• Gas path with screw pipe connection made of stainless steel
The CALOMAT 62 is specially designed for use in corrosive gas (mat. no. 1.4571), or Hastelloy C22
mixtures. • Purging gas connections: Pipe diameter 10 mm or 3/8"
• Gas connections for sample gas inlet and outlet and for refer-
■ Benefits ence gas: Internal thread 1/8" – 27 NPT
• Universally applicable hardware basis • With closed or flow-type reference chambers
• Integrated correction of cross-interference, no external calcu-
Display and control panel
lation required
• Large LCD field for simultaneous display of:
• Open interface architecture (RS 485, RS 232, PROFIBUS)
- Measured value (digital and analog displays)
• SIPROM GA network for maintenance and servicing informa- - Status bar
tion (option) - Measuring ranges
• Electronics and analyzer unit: gas-tight isolation, purging is • Contrast of the LCD field adjustable via the menu
possible, IP65, long service life even in harsh environments
• Permanent LED backlighting
(field device)
• Washable membrane keyboard with five softkeys
■ Application • Menu-driven operator control for parameterization, test func-
tions, adjustment
Fields of application • Operator support in plain text
• Chlorine-alkali electrolysis • Graphical display of the concentration progression; time inter-
• Metallurgy (steel production and processing) vals parameterizable
• H2 measurement in LNG (Liquefied Natural Gas) process • Bilingual operating software German/English,
• Ammonia synthesis English/Spanish, French/English, Spanish/English,
Italian/English
• Fertilizer production
• Petrochemicals Input and outputs
• One analog output per medium (from 0, 2, 4 to 20 mA; NAMUR
Special versions parameterizable)
Special applications • Two analog inputs configurable (e.g. correction of cross-inter-
In addition to the standard combinations, special applications ference or external pressure sensor)
are also available upon request (e.g. higher sample gas pres- • Six binary inputs freely configurable (e.g. measurement range
sure up to 2 000 hPa absolute). changeover, processing of external signals from the sample
preparation)
• Six relay outputs, freely configurable (e.g. failure, mainte-
nance request, threshold alarm, external magnetic valves)
• Each can be expanded by eight additional binary inputs and
relay outputs (e.g. for autocalibration with max. four test
gases)

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CALOMAT 62
General information
1 Communication
RS 485 present in basic unit (connection from the rear; for the
rack unit also behind the front plate).
Options
• RS 485/RS 232 converter
• RS 485/Ethernet converter
• RS 485/USB converter
• Connection to networks via PROFIBUS DP/PA interface
• SIPROM GA software as the service and maintenance tool

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CALOMAT 62, membrane keyboard and graphic display


Designs – parts wetted by sample gas
Gas connection 19" rack unit Field device
Input block with gas connection Stainless steel, mat. no. 1.4571 Stainless steel, mat. no. 1.4571
Seal FPM (e.g. Viton) or FFPM FPM (e.g. Viton) or FFPM
Sensor Glass Glass
Input block with gas connection Hastelloy C22
Seal FFPM (e.g. Kalrez)
Sensor Glass

1/188 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


CALOMAT 62
General information
1

9 22 21 12 11
Purging gas Reference gas Sample gas

CALOMAT 62, 19" rack unit, gas path

5 6 7 8 22 21 12 11
Purging gas Purging gas Reference gas Sample gas
(flow-type, option)
Electronics side Analyzing side

CALOMAT 62, field device, gas path

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Continuous Gas Analyzers, extractive


CALOMAT 62
General information
1 ■ Function
Principle of operation • Time constants are selectable within wide ranges (static/dy-
namic noise suppression); i.e. the response time of the ana-
The measuring principle is based on the different thermal con- lyzer can be adapted to the respective task
ductivity of gases.
• Short response time
The temperature of a heated resistor surrounded by gas is de-
termined by the thermal conductivity of the gas. Four such resis- • Low long-term drift
tors are connected as a bridge. • Measuring point switchover for up to 6 measuring points
(parameterizable)
Sample gas flows around two of them, reference gas surrounds
the other two. A constant DC voltage heats the resistors above • Measuring point identification
the temperature of the measurement block. • External pressure sensor can be connected – for correction of
variations in sample gas pressure
The different thermal conductivities of the sample and reference
gases result in different temperatures of the resistors. A change • Possibility for correcting the influence of residual gases
in the composition of the sample gas thus also causes a change (correction of cross-interference)
in the resistance values. • Automatic measuring range calibration can be programmed
The electrical equilibrium of the measuring bridge is disrupted, • Operation based on the NAMUR recommendation
and a voltage is generated in the bridge diagonal. This is a mea- • Two operator input levels with their own authorization codes to
sure of the concentration of the measured component. prevent unintentional and unauthorized interventions
Note • Simple handling using a numerical membrane keyboard and
operator prompting
The sample gases must be fed into the analyzers free of oil,
grease, and dust. The formation of condensation in the sample • Customer-specific device versions, such as:
chambers (dew point of sample gas < ambient temperature) - Customer acceptance
must be avoided. Therefore, gas prepared for the respective - TAG labels
task must be provided in most applications. - Drift recording
- Clean for O2 service
Spans
U
The smallest and largest possible spans depend on both the
measured component (gas type) and the respective application
(see ordering data).
Cross-interferences
Information on the sample gas composition is required in order
to determine the cross-interference of residual gases with sev-
eral interfering components.
The zero offsets in % H2 which result from 1 % residual gas
(interfering gas) are listed in the following table; the specified
values are approximate values.
It should be noted that the influence of interfering gas is not lin-
ear to its concentration. Information on the sample gas compo-
Measurement sition is required in order to determine the cross-interference of
block residual gases with several interfering components.
Ar Approx. -0.15 %
O2 Approx. +0.02 %
M V CO2 Approx. -0.13 %
CH4 Approx. +0.17 %
M Measurement chamber
SO2 Approx. -0.31 %
V Reference gas chamber (optional: flow-type)
Air (dry) Approx. +0.25 %

CALOMAT 62, principle of operation, example of a non-flow-type refer- Effect of 1 % gas component with nitrogen as the residual gas,
ence chamber expressed in % H2

Important features Moreover, it must be noted that - in addition to a zero offset - the
gradient of the characteristic can also be affected by the resid-
• Four freely-programmable measuring ranges, also with sup- ual gas. However, this effect is negligible in the case of variations
pressed zero, all ranges linear in the interfering gas concentration below 10 %.
• Smallest spans down to 1 % H2 (with suppressed zero: 99 to
100 % H2) possible Taking these facts into consideration and due to the fact that the
cross-interference analyzers cause further measuring inaccura-
• Measuring range identification cies, a larger error in measurement occurs than with binary gas
• Electrically isolated measured-value output 0/2/4 to 20 mA mixtures despite correction of cross-interference.
(also inverted)
• Automatic or manual measuring range switchover selectable;
remote switching is also possible
• Measured value can be saved during adjustment

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CALOMAT 62
General information
Specification for the interface cable Bus terminating resistors 1
Surge impedance 100 ... 300 , with a measuring Pins 3-7 and 8-9 of the first and last connectors of a bus cable
frequency of > 100 kHz must be bridged (see figure).
Cable capacitance Typ. < 60 pF/m Note
Core cross-section > 0.22 mm2, corresponds to
AWG 23 It is advisable to install a repeater on the device side in the case
of a cable length of more than 500 m or with high interferences.
Cable type Twisted pair, 1 x 2 conductors of
cable section Up to four components can be corrected via the ELAN bus, cor-
rection of cross-interference can be carried out for one or two
Signal attenuation Max. 9 dB over the whole length
components via the analog input.
Shielding Copper braided shield or braided
shield and foil shield
Connection Pin 3 and pin 8

0 
*1' 
 9-pin connector

 (RS 485)
9  (device 1)


0 

0 
*1' 
 9-pin connector

 (RS 485)
9  (device 2)


0 

0 
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 9-pin connector

 (RS 485)
9  (device 3)


0 

Bus cable with plug connections, example

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Continuous Gas Analyzers, extractive


CALOMAT 62
19" rack unit
1 ■ Technical specifications
General (based on DIN EN 61207/IEC 1207. All data refers to the binary Measuring response(the dynamic and measuring response refers to
gas mixture H2 in N2) the measurement of H2 in N2) (referred to sample gas pressure
1 000 hPa absolute, sample gas flow 0.5 l/min, and ambient tempera-
Measuring ranges 4, internally and externally switch- ture 25 °C)
able; automatic measuring range
switchover also possible Output signal fluctuation (3 value) <  1 % of the smallest possible
span according to rating plate,
Span Application-dependent with electronic damping constant
(see ordering data) of 1 s
Measuring ranges with suppressed Application-dependent Zero point drift <  1 % of the current span/week
zero point (see ordering data)
Measured-value drift <  1 % of the smallest possible
Operating position Front wall, vertical span (according to rating
Conformity CE marking in accordance with plate)/week
EN 50081-1/EN 50081-2 and Repeatability <  1 % of the current span
RoHS
Detection limit 1% of the smallest possible span
Design, enclosure according to rating plate
Degree of protection IP20 according to EN 60529 Linearity error <  1 % of the current span
Weight Approx. 13 kg Influencing variables (referred to sample gas pressure 1 000 hPa
Electrical characteristics absolute, sample gas flow 0.5 l/min, and ambient temperature 25 °C)

EMC In accordance with standard Ambient temperature < 2 %/10 K referred to smallest
(Electromagnetic Compatibility) requirements of NAMUR NE21 possible span according to label
(08/98) and EN 61326 Accompanying gases Deviation from zero point (for
Electrical safety In accordance with EN 61010-1; influence of interfering gas, see
overvoltage category II section "Cross-interference")

Power supply (see nameplate) 100 V AC -10 % ... 120 V AC Sample gas flow 0.2 % of the current measuring
+10 %, 48 ... 63 Hz span with a change in flow of
0.1 l/min within the permissible
or flow range
200 V AC -10 % ... 240 V AC Sample gas pressure < 1 % of the current span with a
+10 %, 48 ... 63 Hz change in pressure of 100 hPa
Power consumption Approx. 30 VA Power supply < 0.1 % of the current span with
Fuse values 100 ... 120 V: 1.0T/250 rated voltage  10 %
200 ... 240 V: 0.63T/250 Electrical inputs and outputs
Gas inlet conditions Analog output 0/2/4 ... 20 mA, isolated;
max. load 750 
Sample gas pressure 800 ... 1 100 hPa (absolute)
Relay outputs 6, with changeover contacts,
Sample gas flow 30 ... 90 l/h freely parameterizable, e.g. for
Sample gas temperature Min. 0 to max. 50 °C, but above measuring range identification;
the dew point load: 24 V AC/DC/1 A, isolated
Temperature of the measuring cell 70 ºC Analog inputs 2, dimensioned for 0/2/4 ... 20 mA
for external pressure sensor and
Dynamic response (the dynamic and measuring response refers to the correction of cross-interference
measurement of H2 in N2)
Binary inputs 6, designed for 24 V, isolated,
Warm-up period < 30 min at room temperature freely parameterizable, e.g. for
(the technical specification will be measuring range switchover
met after 2 hours)
Serial interface RS 485
Delayed display (T90) Approx. 35 s (including dead
time) Options AUTOCAL function with 8 addi-
tional binary inputs and 8 addi-
Damping (electrical time constant) 0 ... 100 s, parameterizable tional relay outputs, also with
Dead time (the diffusion to the Approx. 34 s PROFIBUS PA (on request) or
probes is the determining variable) PROFIBUS DP (on request)
Dead time (special application) 10 ... 15 s Climatic conditions
Permissible ambient temperature -40 ... +70 °C during storage and
transportation, 5 ... 45 °C during
operation
Permissible humidity (dew point < 90 % relative humidity as
must not be fallen below) annual average, during storage
and transportation

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Continuous Gas Analyzers, extractive


CALOMAT 62
19" rack unit

Selection and ordering data Article No.


1
CALOMAT 62 gas analyzer 7MB2541- 7 7 7 700 7 - 7 A 7 7
19" rack unit for installation in cabinets
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Material of sample gas path
Stainless steel, mat. no. 1.4571; Purging gas stub 6 mm 0
non-flow-type reference chamber, 1/8''-27 NPT
Stainless steel, mat. no. 1.4571; Purging gas stub 1/4" 4
non-flow-type reference chamber, 1/8''-27 NPT
Application Possible with measuring
range identification
H2 in N2 0, 1, 5, 6 AN
SO2 in air 1, 6 EL
CO2 in H2 0, 1, 5, 6 KA
CO2 in N2 2, 6 KN
Smallest Largest Reference gas
measuring range measuring range or filling gas
0 ... 1 % 0 ... 100 % 0
0 ... 5 % 0 ... 100 % 1
0 ... 5 % 0 ... 60 % Accompanying gas 2
component
0 ... 10 % 0 ... 100 % 3
0 ... 20 % 0 ... 40 % 4
100 ... 99 % 100 ... 0 % 5
100 ... 95 % 100 ... 0 % Sample gas component 6
100 ... 90 % 100 ... 0 % 7
100 ... 80 % 100 ... 60 % 8
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs and outputs 1
• With 8 additional 8 digital inputs/outputs and PROFIBUS PA interface 6
• With 8 additional digital inputs/outputs and PROFIBUS DP interface 7
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Explosion protection
Without A
Language (supplied documentation, software)
German 0
English 1
French 2
Spanish 3
Italian 4

Additional versions Order code


Add "-Z" to Article No. and specify Order codes.
TAG labels (specific lettering based on customer information) B03
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting (only in conjunction with an application no., e.g. extended measuring range) Y12
Extended special setting (only in conjunction with an application no., e.g. determination of cross- Y13
interferences)
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with 8 digital inputs/outputs C79451-A3480-D511
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057307
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057312
Set of Torx screwdrivers A5E34821625

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Continuous Gas Analyzers, extractive


CALOMAT 62
19" rack unit
1 ■ Dimensional drawings

173 128
101.6
37.7
177

173
149.5
M4

CALOMAT 6

86.5
27.5
351.5
9
465 20 384.5
483

440

320
345

420
55
91
0
106.5

70.5

CALOMAT 62, 19" rack unit, dimensions in mm

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Continuous Gas Analyzers, extractive


CALOMAT 62
19" rack unit

■ Schematics
1
Pin assignment (electrical and gas connections)

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CALOMAT 62, 19" rack unit, pin assignment

Siemens PA 01 · 2015 1/195


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Continuous Gas Analyzers, extractive


CALOMAT 62
19" rack unit
1
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CALOMAT 62, 19" rack unit, pin assignment of the AUTOCAL board and PROFIBUS connectors

1/196 Siemens PA 01 · 2015


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Continuous Gas Analyzers, extractive


CALOMAT 62
19" rack unit
1
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CALOMAT 62, 19" rack unit, gas connections and electrical connections

Siemens PA 01 · 2015 1/197


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Continuous Gas Analyzers, extractive


CALOMAT 62
Field device
1 ■ Technical specifications
General (based on DIN EN 61207/IEC 1207. All data refers to the binary Dynamic response (the dynamic and measuring response refers to the
gas mixture H2 in N2) measurement of H2 in N2) (referred to sample gas pressure 1 000 hPa
absolute, sample gas flow 0.5 l/min, and ambient temperature 25 °C)
Measuring ranges 4, internally and externally switch-
able; automatic measuring range Warm-up period < 30 min at room temperature (the
switchover also possible technical specification will be met
after 2 hours)
Span Application-dependent
(see ordering data) Delayed display (T90) Approx. 35 s (including dead time)
Measuring ranges with Application-dependent Electrical damping 0 ... 100 s, parameterizable
suppressed zero point (see ordering data) Dead time (the diffusion to the Approx. 34 s
Operating position Front wall, vertical probes is the determining variable)
Conformity CE marking in accordance with Dead time (special application) 10 ... 15 s
EN 50081-1/EN 50081-2 and RoHS Measuring response (the dynamic and measuring response refers to
Design, enclosure the measurement of H2 in N2) (referred to sample gas pressure
1 000 hPa absolute, sample gas flow 0.5 l/min, and ambient tempera-
Degree of protection IP65 according to EN 60529 ture 25 °C)
Weight Approx. 25 kg Output signal fluctuation <  1 % of the smallest possible
Electrical characteristics (3 value) span according to rating plate with
electronic damping constant of 1 s
EMC In accordance with standard
(Electromagnetic Compatibility) requirements of NAMUR NE21 Zero point drift <  1 % of the current span/week
(08/98) and EN 61326 Measured-value drift <  1 % of the smallest possible
Electrical safety In accordance with EN 61010-1; span (according to rating
overvoltage category II plate)/week
Power supply (see nameplate) 100 AC -10 % ... 120 V AC +10 %, Repeatability <  1 % of the current span
48 ... 63 Hz or Detection limit 1 % of the smallest possible span
200 AC -10 % ... 240 V AC +10 %, according to rating plate
48 ... 63 Hz
Linearity error <  1 % of the current span
Power consumption • Approx. 25 VA (gas connection
block unheated) Influencing variables (referred to sample gas pressure 1 000 hPa
• Approx. 330 VA (gas connection absolute, sample gas flow 0.5 l/min, and ambient temperature 25 °C)
block heated) Ambient temperature < 2 %/10 K referred to smallest pos-
Fuse values (gas connection 100 ... 120 V sible span according to rating plate
unheated) F3 1T/250 Accompanying gases Deviation from zero point (for influ-
F4 1T/250 ence of interfering gas, see section
200 ... 240 V "Cross-interference")
F3 0.63T/250
F4 0.63T/250 Sample gas flow 0.2 % of the current measuring span
with a change in flow of 0.1 l/min
Fuse values (gas connection 100 ... 120 V within the permissible flow range
heated) F1 1T/250
F2 4T/250 Sample gas pressure < 1 % of the span with a change in
F3 4T/250 pressure of 100 hPa
F4 4T/250 Power supply < 0.1 % of the output signal span
200 ... 240 V with rated voltage  10 %
F1 0.63T/250 Electrical inputs and outputs
F2 2.5T/250
F3 2.5T/250 Analog output 0/2/4 ... 20 mA, isolated;
F4 2.5T/250 max. load 750 
Gas inlet conditions Relay outputs 6, with changeover contacts, freely
parameterizable, e.g. for measuring
Sample gas pressure 800 ... 1 100 hPa (absolute) range identification; load:
Sample gas flow 30 ... 90 l/h 24 V AC/DC/1 A, isolated
Sample gas temperature Min. 0 to max. 50 °C, but above the Analog inputs 2, dimensioned for 0/2/4 … 20 mA
dew point for external pressure sensor and
correction of cross-interference
Temperature
Binary inputs 6, designed for 24 V, isolated, freely
• of the measuring cell (sensor) 70 ºC parameterizable, e.g. for measur-
• of the measureming cell block 80 ºC (heated) ingrange switchover
(base)
Serial interface RS 485
Sample gas humidity < 90 % relative humidity
Options AUTOCAL function with 8 additional
Purging gas pressure binary inputs and 8 additional relay
• Permanent 165 hPa above ambient pressure outputs, also with PROFIBUS PA
• For short periods Max. 250 hPa above ambient pres- (on request) or PROFIBUS DP
sure (on request)
Climatic conditions
Permissible ambient temperature -40 ... +70 °C during storage and
transportation, 5 … 45 °C during
operation
Permissible humidity (dew point < 90 % relative humidity as annual
must not be fallen below) average, during storage and trans-
portation

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CALOMAT 62
Field device

Selection and ordering data Article No.


1
CALOMAT 62 gas analyzer 7MB2531- 7 7 7 700 7 - 7 7 7 7 Cannot be combined
For field installation
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Material of sample gas path
Stainless steel, mat. no. 1.4571; non-flow-type reference Purging gas stub 10 mm 0 00
chamber, 1/8"-27 NPT
Hastelloy C22; non-flow-type reference chamber, 1/8"-27 NPT 2
Hastelloy C22; flow-type reference chamber, 1/8"-27 NPT 3 3
Stainless steel, mat. no. 1.4571; non-flow-type reference Purging gas stub 3/8" 4 4
chamber, 1/8"-27 NPT
Hastelloy C22; non-flow-type reference chamber, 1/8"-27 NPT 6
Hastelloy C22; flow-type reference chamber, 1/8"-27 NPT 7 7
Application Possible with measuring
range identification
H2 in N2 0; 5 AN AN
H2 in Cl2 0; 5 AB AB
H2 in HCl 0; 5 AC AC
Cl2 in air 1; 6 BL BL
HCl in air 1; 6 CL CL
SO2 in air 1; 6 EL EL
CO2 in H2 0; 5 KA KA
CO2 in N2 1; 6 KN KN
Smallest Largest Reference gas
measuring range measuring range or filling gas
0 ... 1 % 0 ... 100 % 0
0 ... 5 % 0 ... 100 % 1
0 ... 5 % 0 ... 60 % Accompanying gas 2
component
0 ... 10 % 0 ... 100 % 3
0 ... 20 % 0 ... 40 % 4
100 ... 99 % 100 ... 0 % 5
100 ... 95 % 100 ... 0 % Sample gas component 6
100 ... 90 % 100 ... 0 % 7
100 ... 80 % 100 ... 60 % 8
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs and outputs 1
• With 8 additional 8 digital inputs/outputs and PROFIBUS PA interface 6
• With 8 additional digital inputs/outputs and PROFIBUS DP interface 7
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Heating of internal gas paths and analyzer unit
Without A
With (max. 80 °C) B
Explosion protection
Without A
According to ATEX II 2G, leakage compensation1) E
According to ATEX II 2G, continuous purging1) F
Language (supplied documentation, software)
German 0
English 1
French 2
Spanish 3
Italian 4
1)
Only in connection with an approved purging unit.

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CALOMAT 62
Field device
1 ■ Selection and ordering data
Additional versions Order code
Add "-Z" to Article No. and specify Order codes.
TAG labels (specific lettering based on customer information) B03
BARTEC EEx p control unit "Leakage compensation" E71
BARTEC EEx p control unit "Continuous purging" E72
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting (only in conjunction with an application no., e.g. extended measuring range) Y12
Extended special setting (only in conjunction with an application no., e.g. determination of cross-inter- Y13
ferences)
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function with 8 digital inputs/outputs A5E00064223
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS PA A5E00057315
AUTOCAL function with 8 digital inputs/outputs and PROFIBUS DP A5E00057318
Set of Torx screwdrivers A5E34821625

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CALOMAT 62
Field device

■ Dimensional drawings
1
























 



 
  
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CALOMAT 62, field device, dimensions in mm

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Continuous Gas Analyzers, extractive


CALOMAT 62
Field device
1 ■ Schematics
Pin assignment (electrical and gas connections)

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CALOMAT 62, field device, pin and terminal assignment

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CALOMAT 62
Field device
1
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CALOMAT 62, field device, pin and terminal assignment of the AUTOCAL board and PROFIBUS connectors

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Continuous Gas Analyzers, extractive


CALOMAT 62
Field device
1

a b c d 5 7

11 21 9

12 22 10

8
6

Gas connections Electrical connections


11 Sample gas inlet a-c Signal cable (Ø 10 ... 14 mm)
(analog + digital): cable gland M20x1.5
12 Sample gas outlet Internal thread d Interface connection: (Ø 7 ... 12 mm)
21 Reference gas inlet 1/8" - 27 NPT cable gland M20x1.5
22 Reference gas outlet e Power supply: (Ø 7 ... 12 mm)
cable gland M20x1.5
5 - 8 Purge gas inlets/outlets Fittings Ø 10 mm or 3/8"
9 Unassigned
10 Unassigned

CALOMAT 62, field device, gas connections and electrical connections

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Continuous Gas Analyzers, extractive


CALOMAT 62
Documentation

■ Selection and ordering data


1
Operating instructions Article No.
CALOMAT 62
Thermal conductivity gas analyzer
• German A5E00881392
• English A5E00881393
• French A5E00881395
• Italian A5E00881398
• Spanish A5E00881396
Gas analyzers of Series 6 and
ULTRAMAT 23
Schnittstelle/Interface
PROFIBUS DP/PA
• German and English A5E00054148

Suggestions for spare parts

■ Selection and ordering data


Description 7MB2541 7MB2531 2 years 5 years Article No.
(quantity) (quantity)
Temperature limiter x – 1 A5E00891855
Adapter plate, LC display/keypad x x 1 1 C79451-A3474-B605
Temperature sensor x – 1 C79451-A3480-B25
LC display x – 1 W75025-B5001-B1
Line transformer, 115 V x x – 1 W75040-B21-D80
Line transformer, 230 V x x – 1 W75040-B31-D80
Fuse, T 0.63 A, line voltage 200 … 240 V x x 2 3 W79054-L1010-T630
Fuse, T 1 A, supply voltage 100 … 120 V x x 2 3 W79054-L1011-T100
Heating cartridge x – 1 W75083-A1004-F120

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Continuous Gas Analyzers, extractive


FIDAMAT 6
General information
1 ■ Overview ■ Application
Areas of application
• Environmental protection
• Wastewater (in conjunction with a stripping device, verification
of the hydrocarbon content of liquids)
• TLV (Threshold Limit Value) monitoring at places of work
• Quality monitoring
• Process exhaust monitoring
• Ultra-pure gas measurements in media such as O2, CO2,
inert gases and cold sample gases
• Measurement of corrosive and condensing gases
• Process optimization
Further applications
• Chemical plants
• Gas manufacturers (ultra-pure gas monitoring)
• Research and development
The FIDAMAT 6 gas analyzer is suitable for the determination of • Cement industry (measurement of emissions)
the total hydrocarbon content in the air and high-boiling gas mix- • Paint shops and dry-cleaning systems
tures.
• Refineries (tank farms, wastewater)
■ Benefits • Drying systems
• Solvent recovery systems
The FIDAMAT 6 gas analyzer is distinguished by its wide range
of applications: • Pharmaceutical industry
• In the presence of up to 100 % H2O vapor • Automotive industry (engine development, engine and trans-
mission development and certification)
• In ultra-pure gas applications
• With high-boiling components (up to 200 °C) Special applications
• In the presence of corrosive gases (with preliminary filter). Special applications
The FIDAMAT 6 exhibits: Special applications are available on request in addition to the
standard combinations, e.g. measuring range 0 to 100 %.
• Extremely low cross-sensitivity to interfering gases
• Low consumption of combustion air TÜV version
• Low influence of oxygen on measured value Measurement of flue gases according to 13th BlmSchV/17th
BlmSchV and TA Luft for oil, coal, gas, and waste as fuels.
The analyzer is additionally equipped with warning and fault
messages: Furthermore, the TÜV-approved versions of the FIDAMAT 6 com-
• For failure of combustion gas ply with the requirements of EN 14956 and QAL 1 according to
EN 14181. Conformity of the analyzers with both standards is
• If the flame is extinguished TÜV-certified.
• To indicate pump and filter faults
Determination of the analyzer drift according to EN 14181
(QAL 3) can be carried out manually or also with a PC using the
SIPROM GA maintenance and servicing software. In addition,
selected manufacturers of emission evaluation computers offer
the possibility for downloading the drift data via the analyzer’s
serial interface and to automatically record and process it in the
evaluation computer.

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FIDAMAT 6
General information

■ Design
1
• 19" rack unit with 4 HU for installation Input and outputs
- in hinged frame • One analog output for each measured component
- in cabinets with or without telescopic rails
• Two programmable analog inputs
• Front plate can be swung down for servicing purposes
(laptop connection) • Six binary inputs freely configurable (e.g. for measurement
range switchover, processing of external signals from sample
• Gas connections for sample gas inlet and outlet as well as preparation)
combustion gas and combustion air; pipe diameter 6 mm
or ¼" • Six relay outputs freely configurable (failure, maintenance re-
quest, maintenance switch, limit alarm, external solenoid
• Gas and electrical connections at the rear valves, measuring point switchover)
• Internal gas paths: stainless steel (mat. no. 1.4571) • Extension with eight additional binary inputs and eight addi-
Display and control panel tional relay outputs for autocalibration with up to four calibra-
tion gases
• Large LCD field for simultaneous display of:
- Measured value Communication
- Status bar
- Measuring ranges RS 485 present in basic unit (connection from the rear).
• Contrast of LCD panel adjustable using menu Options
• Permanent LED backlighting • RS 485/RS 232 converter
• Washable membrane keyboard with five softkeys • RS 485/Ethernet converter
• Menu-driven operation for parameterization, test functions, • RS 485/USB converter
adjustment • Incorporation in networks via PROFIBUS DP/PA interface
• User help in plain text • SIPROM GA software as service and maintenance tool
• Graphic display of concentration trend; programmable time
intervals

LED backlit graphic Status line for display Two code levels
display and of analyzer status according to NAMUR
membrane keyboard (programmable) (maintenance and
with noticeable click specialist level)

Operation with
menu control
using five softkeys

Display of
concentrations as
numbers and bargraph
Display of current
measuring ranges
Display of
start-of-scale and
full-scale values

ESC key
to abort inputs
Keypad to
enter values

INFO key
for help in plain text

CLEAR key
to delete inputs
ENTER key MEAS key
to accept to return to
input values measurement mode

FIDAMAT 6, membrane keyboard and graphic display

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FIDAMAT 6
General information
1 Designs – parts wetted by sample gas
Gas path Material
Piping Stainless steel, mat. no. 1.4571
Gas inlet Stainless steel, mat. no. 1.4571
Gaskets Graphite
Sample gas restrictor Quartz
Auxiliary gas restrictors Stainless steel, mat. no. 1.4571
Pump membrane PTFE
Pump head Stainless steel, mat. no. 1.4571
Detector
Nozzle Quartz
FID housing Stainless steel, mat. no. 1.4571

Gas path

Combustion
gas H2
Mechan. Solenoid Restrictor
Sample chamber pressure valve
Pressure sensor
regulator
Gas outlet

Combustion air
Pressure sensor
Mechan.
pressure
Restrictor regulator

Damping Pump 1

Sample gas
Filter

Zero gas
Calibration
gas

FIDAMAT 6 total hydrocarbon analyzer, gas path with pump and with connection for combustion air

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Continuous Gas Analyzers, extractive


FIDAMAT 6
General information
1
Combustion
gas H2
Mechan. Solenoid Restrictor
Sample chamber pressure valve
Pressure sensor
regulators
Gas outlet

Combustion air
Pressure sensor
Mechanical
pressure
Restrictor regulators

Sample gas

Zero gas

Calibration gas

Purging

FIDAMAT 6 total hydrocarbon analyzer, gas path without pump and with connection for combustion air

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Continuous Gas Analyzers, extractive


FIDAMAT 6
General information
1 ■ Function
Principle of operation The FIDAMAT 6 provides various messages in the form of float-
ing contacts:
The FIDAMAT 6 carries out substance-specific measurements
and not component-specific measurements. It measures the to- • Maintenance request
tal of all hydrocarbons in a sample gas, but with different weight- E.g. sample gas flow (filter/pump)
ing of the hydrocarbon molecules. To a first approximation, the Fan failure (advance warning for measuring accuracy)
display is proportional to the number of C atoms in the respec- The measured value remains unaffected.
tive molecule. However, there are fluctuations in practice. The • Fault
display deviation for the respective molecule is expressed by the E.g. hydrogen, combustion air and sample gas pressures,
response factor. temperature, analyzer part and pump, fault in the electronics
The sample gas is supplied to the FIDAMAT 6 through overpres- (temperature).
sure or drawn in by the built-in diaphragm pump (optionally via The measured value may be influenced.
a heated line and an additional filter) and passed on to the flame • Failure
ionization detector via an obstruction-proof fused-silica restric- In the event of failure of, for example, the electronics, power
tor. supply, combustion gas, combustion air or sample gas, the
analyzer automatically shuts down (the combustion gas valve
In the detector, the hydrocarbons in the sample gas are burned is closed).
in an oxyhydrogen gas flame. Burning partially ionizes the pro-
portion of organically-bound hydrocarbons. The released ions Note
are converted into an ionic current by the voltage present be- The sample gases must be fed into the analyzers free of dust.
tween two electrodes, and measured using a highly sensitive Condensation should be avoided. Therefore, the use of gas
amplifier. The current measured is proportional to the quantity of modified for the measuring task is necessary in most application
organically-bound C atoms in the sample gas. cases.
A pressure regulator keeps the combustion gas pressure con- Calibration
stant. The balanced system of pump, capillary tubes, and pres-
sure regulator for combustion air ensures that the sample gas The calibrating interval should be adapted to the respective
pressure is kept constant. measuring task.
When the analyzer is switched on, ignition is carried out auto- We recommend N2 as zero gas (at least 5.0; for measuring of hy-
matically when the setpoint temperature has been reached and, drocarbons < 1 ppm: at least 6.0).
for versions "with pump", the pump is also started up.
The calibration gas should have a concentration of at least 60 %
of the leading measuring range. The concentration of residual
hydrocarbons must not exceed 0.1 ppm.
For pure gas measurement, use suitable additional gases.
Example:
200 V DC 1. Emission measurement
Measuring range 0 ... 50 mg C/m3
Zero gas N2 (5.0 or better)
Exhaust Calibration gas 21 ppm C3H8 in N2
gas
(corresponds to 31.43 mg C/m3 at 20 °C)
Combus-
Combus- tion air
tion gas 2. Purity measurement in 100 % O2
Measuring range 0 ... 50 ppm C1
Zero gas N2 (5.0 or better)
Calibration gas At least 30 ppm CH4 in O2

OVEN

Sample gas

FIDAMAT 6, principle of operation

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FIDAMAT 6
General information
Essential characteristics Response factors (examples, mean values) 1
• Four freely parameterizable measuring ranges, also with sup- Substance Mean response factor
pressed zero, all measuring ranges linear
n-butane 1.00
• Galvanically isolated measured-value output 0/2/4 to 20 mA
(also inverted) n-propane 1.00

• Autoranging possible; remote switching is also possible n-heptane 1.00


• Storage of measured values possible during adjustments Cyclohexane 1.08
• Measuring range identification Isopropanol 0.81
• Measuring point switchover for up to 6 measuring points Toluene 1.06
• Measuring point identification Acetone 0.92
• Wide range of selectable time constants (static/dynamic noise Ethyl acetate 0.76
suppression); i.e. the response time of the device can be Isobutyl acetate 0.83
adapted to the respective measuring task
Methane 1.06
• Easy handling thanks to menu-driven operation
• Low long-term drift Ethane 0.99

• Two control levels with their own authorization codes for the n-hexane 1.01
prevention of accidental and unauthorized operator interven- iso-octane 1.04
tions
Ethine (acetylene) 0.91
• Automatic, parameterizable measuring range calibration
Propene 0.84
• Operation based on the NAMUR recommendation
Methanol 0.87
• Customer-specific analyzer options such as:
- Customer acceptance Ethanol 0.83
- TAG labels Ethanoic acid 1.13
- Drift recording
Methyl acetate 0.67
• Wear-free, corrosion-proof filter housing
Benzene 1.01
• No blocking of the sample gas capillaries through the use of a
quartz restrictor Ethyl benzene 0.96
• Purge function in the event of analyzer or power supply failure p-xylene 1.03
(avoids build-up of toxic and corrosive substances in the de- Dichloromethane 1.13
vice)
Trichloroethene 1.01
• Low consumption of combustion air
Tetrachlorethene 1.07
• Response factors comply with the minimum requirements in
accordance with German air purity guidelines and the Work- Chloroform 0.72
ing Group of the German automotive Industry Chlorobenzene 1.15
• Simple handling using a numerical membrane keyboard and
operator prompting
Cross-interferences (examples)1)
Interfering Concentration of the Induced
component interfering component cross-interference
O2 in N2 (21 vol. %) < 0.3 mg/m3
SO2 in N2 (258 mg/m3) < 0.15 mg/m3
NO in N2 (310 mg/m3) < 0.5 mg/m3
NO2 in synth. air (146 mg/m3) < 0.1 mg/m3
CO in N2 (461 mg/m3) < 0.15 mg/m3
CO2 in N2 (18 vol. %) < 0.1 mg/m3
HCl in N2 (78 mg/m3) < 0.3 mg/m3
1) With measuring range 0 to 15 mg/m3.

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FIDAMAT 6
19" rack unit
1 ■ Technical specifications
General information Measuring response
Measuring ranges 4, internally and externally switch- (relating to sample gas pressure 1 013 hPa absolute, 0.5 l/min sample
able; manual and autoranging gas flow and 25 °C ambient temperature)
possible Output signal fluctuation < 0.75 % of the smallest possible
Smallest possible measuring span 0 ... 10 vpm measuring range according to
rating plate, with electronic
Largest possible measuring span 99.999 vpm*) damping constant of 1 s (corre-
sponds to  0.25 % at 2 )
Concentration units ppm, C1, C3, C6 or mgC/m3
Zero point drift < 0.5 %/month of the smallest
Autoranging Hysteresis, selectable possible measuring span accord-
Measured-value display Digital concentration display ing to rating plate
(5 digits with floating point) Measured-value drift < 1 %/week of the current mea-
Resolution of digital display 0.1 % of measured value suring range
Operating position Front wall, vertical Repeatability < 1 % of the current measuring
range
Conformity CE mark in accordance with
EN 50081-1, EN 50082-2 Detection limit 0.1 ppm (version for ultra-pure
gas measurement: 50 ppb)
Oven temperature Adjustable, 100 ... 200 °C
Linearity error < 1 % of the current measuring
Design, enclosure range
Degree of protection IP20 according to EN 60529 Influencing variables
Weight Approx. 23 kg (relating to sample gas pressure 1 013 hPa absolute, 0.5 l/min sample
gas flow and 25 °C ambient temperature)
Electrical characteristics
Ambient temperature < 1 %/10 K referred to smallest
Power supply 100 ... 120 V AC (nominal range possible span according to rating
of use 90 ... 132 V), 48 ... 63 Hz or plate
200 ... 240 V AC (nominal range
of use 180 ... 264 V), 48 ... 63 Hz Atmospheric pressure < 1 %/50 hPa

Power consumption • Approx. 150 VA during opera- Sample gas pressure < 2 % of the current measuring
tion, range range/1 % pressure
change (within 600 ... 1 100 hPa)
• Approx. 350 VA during warm-up
phase Power supply < 1 % of the current measuring
range with rated voltage  10 %
EMC In accordance with standard
(Electromagnetic Compatibility) requirements of NAMUR NE21 Position influence < 1 % with < 15° inclination
(08/98) Electrical inputs and outputs
Electrical safety In accordance with EN 61010-1, Analog output 0/2/4 ... 20 mA, isolated;
overvoltage category II max. load 750 
Fuse values • 100 ... 120 V: 4.0T/250 Relay outputs 6, with changeover contacts,
• 200 ... 240 V: 2.5 T/250 freely parameterizable, e.g. for
measuring range identification;
Gas inlet conditions
load: 24 V AC/DC/1 A, potential-
Permissible sample gas pressure free
• Without pump < 2 000 hPa abs. Analog inputs 2, dimensioned for 0/2/4 to 20 mA
for external pressure sensor and
• With integrated pump 600 ... 1 100 hPa correction of influence of accom-
Sample gas flow 18 ... 60 l/h (0.3 ... 1 l/min) panying gas (correction of cross-
interference)
Sample gas temperature 0 ... 200 °C
Binary inputs 6, designed for 24 V, floating,
Sample gas humidity < 90 % RH (RH: relative humidity) freely parameterizable, e.g. for
Dynamic response measuring range switchover

Warm-up period At room temperature, Serial interface RS 485


approx. 2 ... 3 h Options AUTOCAL function with 8 addi-
Delayed display (T90) 2 ... 3 s tional binary inputs and relay out-
puts each, also with PROFIBUS
Damping (electrical time constant) 0 ... 100 s, parameterizable PA or PROFIBUS DP
Dead time (purging time of the gas With filter, 2 ... 3 s Climatic conditions
path in the unit at 1 l/min)
Permissible ambient temperature 5 ... 45 °C during operation,
Time for device-internal signal <1s -30 ... +70 °C during storage and
processing transportation
Permissible humidity < 90 % RH (RH: relative humidity)
as annual average, during stor-
age and transportation (must not
fall below dew point)
*) 100 % as special application

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FIDAMAT 6
19" rack unit

FIDAMAT 6 with pump and heated oven, with combustion air connection
1
Gases Operating pressure
Inlet pressure Pump startup Flow through FID Flow through bypass
Without With
hPa (abs.) hPa (abs.) hPa (abs.) ml/min ml/min
Combustion gas 3 000 ... 5 000 2 000  20 ~ 25 —
Combustion air 3 000 ... 5 000 1 420  20 1 500 ~ 320 ~ 500
Sample gas ~ 1000 — 1 500  2 ~3 ~ 1 000
Zero gas 3 500 ... 4 000 — 1 500  2 ~3 ~ 1 000
Calibration gas 3 500 ... 4 000 — 1 500  2 ~3 ~ 1 000

FIDAMAT 6 without pump, with heated oven, with combustion air connection
Gases Operating pressure
Inlet pressure Sample/calibration gas Flow through FID Flow through bypass
Without With
hPa (abs.) hPa (abs.) hPa (abs.) ml/min ml/min
Combustion gas 3 000 ... 5 000 2 000  20 ~ 25 —
Combustion air 3 000 ... 5 000 1 480  5 — ~ 320 ~ 300
Sample gas 1 500 ... 2 000 — 1 500  2 ~3 ~ 500
Zero gas 1 500 ... 2 000 — 1 500  2 ~3 ~ 500
Calibration gas 1 500 ... 2 000 — 1 500  2 ~3 ~ 500

The supply gases (combustion gas, combustion air) must have a degree of purity of 5.0 in order to guarantee correct measurements.
The degree of purity must be increased in the case of very small hydrocarbon concentrations (< 1 ppm).

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FIDAMAT 6
19" rack unit
1
■ Selection and ordering data Article No.
FIDAMAT 6 gas analyzer 7MB2421- 7 7 7 7 7 - 7 7 A 7
19" rack unit for installation in cabinets
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Gas connections
Pipe with 6 mm outer diameter 0
Pipe with ¼" outer diameter 1
Version
Without pump, for sample gas with overpressure B
With heated pump, for sample gas with atm. pressure D
Combustion air feed
With connection for combustion air A
Number of channels
1-channel version 1
Add-on electronics
Without 0
AUTOCAL function
• With 8 additional digital inputs/outputs 1
• With 8 digital inputs/8 digital outputs, PROFIBUS PA interface 6
• With 8 digital inputs/8 digital outputs, PROFIBUS DP interface 7
Power supply
100 ... 120 V AC, 48 ... 63 Hz 0
200 ... 240 V AC, 48 ... 63 Hz 1
Combustion gases
H2 A
Language (supplied documentation, software)
German 0
English 1
French 2
Spanish 3
Italian 4
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Telescopic rails (2 units) A31
TAG labels (specific lettering based on customer information) B03
Clean for O2 service (specially cleaned gas path) Y02
Measuring range indication in plain text, if different from the standard setting Y11
Special setting (only in conjunction with an application No.) Y12
Extended special setting (only in conjunction with an application No.) Y13
TÜV version acc. to 17th BlmSchV Y17
Accessories Article No.
RS 485/Ethernet converter A5E00852383
RS 485/RS 232 converter C79451-Z1589-U1
RS 485/USB converter A5E00852382
AUTOCAL function each with 8 digital inputs/outputs C79451-A3480-D511
AUTOCAL function 8 digital inputs/outputs each and PROFIBUS PA A5E00057307
AUTOCAL function 8 digital inputs/outputs each and PROFIBUS DP A5E00057312
Set of Torx screwdrivers A5E34821625

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FIDAMAT 6
19" rack unit

■ Dimensional drawings
1

Front view Side view


s

101.6
177

86.5
    &/($5 (6&

    ,1)2

    (17(5 0($6

),'$0$7

465 M4
9 483 426.5 347 155.5 27.5

Top view Rear view


440 426.5
446

0 80 155 234.5 264.5 370 395

FIDAMAT 6, 19“ unit, dimensions in mm

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FIDAMAT 6
19" rack unit
1 ■ Schematics
Pin assignment (electrical and gas connections)

&RQQHFWRU68%') 56

0  *1'
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9  5B/HYHO3
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0  *1'

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0  *1'
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 1&
 1&
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0
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0  *1'
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 %LQDU\LQSXW3  9 9
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 5HOD\


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0  *1'

FIDAMAT 6, 19" rack unit, pin assignment

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Continuous Gas Analyzers, extractive


FIDAMAT 6
19" rack unit
1
&RQQHFWRU68%') RSWLRQ

0  *1'
 1&
 1&
 %LQDU\LQSXW3
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 %LQDU\LQSXW3  9 9
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0  *1'

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FIDAMAT 6, 19" rack unit, pin assignment of the AUTOCAL board and PROFIBUS connectors

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Continuous Gas Analyzers, extractive


FIDAMAT 6
19" rack unit
1
15-pin connector: 9-pin
Combus- binary inputs and connector:
Combustion gas tion air analog inputs/outputs RS 485

2 3

8 4 5 9-pin interface
connector (option)
1 6 7 (e.g. PROFIBUS)

37-pin connector:
binary inputs and
relay outputs
(option board)
Power supply
and fuses

Sample gas inlet Calibration Zero gas 25-pin connector:


gas binary inputs and
Sample gas outlet relay outputs

Gas connections
1 ... 7 Swagelok, 6 mm or ¼ “
8 Stubs , 6 mm or ¼ “

FIDAMAT 6, gas connections and pin assignment, version with pump

9-pin
Combustion air connector:
Calibration gas Combustion gas Zero gas RS 485

2 3

4 5 9-pin interface
8
connector (option)
6 7 (e.g. PROFIBUS)

37-pin connector:
binary inputs and
relay outputs
(option board)
Power supply
and fuses

25-pin connector:
binary inputs and
Sample inlet Flushing relay outputs
Sample gas outlet Outlet 15-pin connector:
binary inputs and
Gas connections analog inputs/outputs
2 ... 7 Swagelok, 6 mm or ¼ “
8 Stubs , 6 mm or ¼ “

FIDAMAT 6, gas connections and pin assignment, version with pump

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Continuous Gas Analyzers, extractive


FIDAMAT 6
Documentation

■ Selection and ordering data


1
Operating instructions Article No.
FIDAMAT 6
Gas analyzer for determination of
total hydrocarbon concentration
• German A5E00221703
• English A5E00222135
• French A5E00222138
• Spanish A5E00222141
• Italian A5E00222144
FIDAMAT 6-G
Gas analyzer for determination of
total hydrocarbon content
• German A5E00476038
• English A5E00478463
• French A5E00478466
• Spanish A5E00478468
• Italian A5E00478469

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FIDAMAT 6
Suggestions for spare parts
1 ■ Selection and ordering data
Article No. FIDAMAT 6
Description 2 years 5 years With pump Without pump
(quantity) (quantity)
Analyzer unit
FI detector, complete 1 A5E00295816 A5E00295816
Sample gas path
Pump (KNF) 1 1 A5E00882121
Set of gaskets for pump (KNF) 4 10 A5E03792459
Filter, with gasket for sample gas 1 3 A5E00248845
Pressure regulators 1 1 A5E00248851 A5E00248851
Gasket for pressure regulator 1 2 A5E00295107 A5E00295107
Filter, complete (sample gas inlet, 6 mm) 1 A5E00295928
Filter, complete (sample gas inlet, ¼") 1 A5E00295976
Solenoid valve (1-way) 1 2 A5E00296562 A5E00296562
Solenoid valve (2-way) 1 2 A5E00296565
Gasket, PTFE, 1.5 mm (20 units) 1 2 C79451-A3040-D101 C79451-A3040-D101
Gasket, graphite, 0.5 to 1 mm (20 units) 1 2 C79451-A3040-D102 C79451-A3040-D102
Gasket, graphite, 1.5 mm (20 units) 1 2 C79451-A3040-D103 C79451-A3040-D103
Gasket, graphite, 3 mm (20 units) 1 2 C79451-A3040-D105 C79451-A3040-D105
Pressure ring, 1 mm (20 units) 1 C79451-A3040-D112 C79451-A3040-D112
Pressure ring, 1.5 mm (20 units) 1 C79451-A3040-D113 C79451-A3040-D113
Pressure ring, 3 mm (20 units) 1 A5E00295333 A5E00295333
Outer rings, 0.5 … 1 mm (20 units) 1 C79451-A3040-D121 C79451-A3040-D121
Outer rings, 1.5 … 3 mm (1/8") (20 units) 1 C79451-A3040-D122 C79451-A3040-D122
Electronics
Front plate 1 1 A5E00248790 A5E00248790
Adapter plate 1 1 A5E00248795 A5E00248795
Temperature fuse (retrofitting set) 1 2 A5E01040317 A5E01040317
Temperature fuse (spare part), from N1-V3-940 A5E01040312 A5E01040312
onwards
Fusible element, 230 V AC 2 3 A5E00248819 A5E00248819
Fusible element, 110 V AC 2 3 A5E00248822 A5E00248822
LC display 1 1 A5E00248920 A5E00248920
Cable, temperature sensor for oven 1 A5E00283770 A5E00283770
Cable, temperature sensor for analyzer part 1 A5E00283780 A5E00283780
Cable, magnetic distributor 1 A5E00283800 A5E00283800
Cable, heater for oven, 230 V AC 1 A5E00283817 A5E00283817
Cable, heater for oven, 110 V AC 1 A5E00295469 A5E00295469
Cable, electrode voltage, complete 1 A5E00284092 A5E00284092
Cable, signal cable 1 A5E00284094 A5E00284094
Cable, connecting cable (4-pole) 1 1 A5E00284095 A5E00284095
Cable, connecting cable (5-pole) 1 1 A5E00284096 A5E00284096
Axial-flow fan, 24 V DC 1 A5E00313839 A5E00313839

If the device was supplied with a specially cleaned gas path for high oxygen context ("Clean for O2 service"), please ensure that you
specify this when ordering spare parts. This is the only way to guarantee that the gas path will continue to comply with the special
requirements for this version.

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Continuous Gas Analyzers, extractive


SIPROCESS UV600

■ Overview ■ Application
1
Fields of application
• Emission measurements
- Measurement of low NO concentrations in power plants or
gas turbines
- Monitoring of NOx in denitrification plants by direct
measurement of NO and NO2, as well as summation to NOx
in the analyzer
- Efficient measurement in desulfurization plants
- Monitoring of very small SO2 and NO concentrations
- Emission measurements in the paper and cellulose indus-
tries
• Process monitoring
- Measurement of SO2 in process gases in the paper and
petrochemical industries
- Optimization of NOx emissions in exhaust gas in the
automotive industry
The function of the SIPROCESS UV600 gas analyzer is based on
- H2S and SO2 measurements in the residual gas purification
UV resonance absorption spectrometry. It also is used to
of sulfur recovery units
measure very low NO, NO2, SO2 or H2S concentrations in gases.
• H2S measurement
- In typical emission applications
■ Benefits - Taking account of possible cross-sensitivities (e.g. from
• For NO, NO2, SO2: Very low cross-sensitivity with other gases mercaptan)
• All modules are thermostatically-controlled, and thus Special versions
independent of the ambient temperature
Special applications
• Simultaneous measurement of NO and NO2 with subsequent
calculation of total. Therefore neither an NO2 converter nor a In addition to the standard combinations, special applications
CLD analyzer is required. are also available upon request, e.g. as regards the material in
• Measurement in the UV range: the gas path and the sample chambers.
- No cross-sensitivity with H2O and CO2
- Very low SO2 and NO measuring ranges possible
• UV resonance absorption spectrometry:
- Measurement of very low NO concentrations
- Very low cross-sensitivity possible
• Very long service life of UV lamp (usually 2 years)
• Low drifts and high stability thanks to four-channel measuring
method with double generation of quotient
• True reference measurement for low-drift, stable results
• Interface for remote monitoring in networks and linking to
process control systems
• Optional calibration unit
- Filter wheel with calibration cells which can be automatically
swung into the optical path
- Low consumption of calibration gas
- Manual or automatic calibration possible

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SIPROCESS UV600

1 ■ Design
• 19" rack unit with 4 HU for installation Inputs and outputs
- in hinged frame • 2 configurable analog inputs
- in cabinets with or without telescopic rails
• 4 configurable analog outputs
• Internal gas paths: hose made of FKM (VitonTM) or pipe made
of PTFE or stainless steel • 8 digital inputs
• Gas connections for sample gas inlet and outlet and for • 8 digital outputs
reference gas: fittings, pipe diameter of 6 mm or ¼" Communications
Display and control panel Connection via SIPROCESS-UV600-specific software tool
• Large LCD panel for simultaneous display of measured value
and device status Materials wetted by sample gas
• Sensor buttons with context-based functions Component Material
• Display protected by glass pane Analyzer unit (sample chamber) Aluminum or stainless steel
mat. no. 1.44041), epoxy resin
• Contrast of the LC display can be adjusted
Optical window CaF2 or quartz1), epoxy resin
Gas path, gaskets FKM (Viton), PTFE, stainless steel
mat. no. 1.45711)
Chamber Aluminum or stainless steel1)
Gas inlet/outlet PVDF, stainless steel,
mat. no. 1.44011)
Moisture sensor Stainless steel mat. no. 1.4571,
platinum, epoxy resin
Diaphragm pump
• Central body PVDF
• Diaphragm FKM (Viton), EPDM
1)
Depending on the version

SIPROCESS UV600, display and control panel


Gas flow chart

Sample gas inlet


o
Filter Moisture Sample gas outlet
(optional) sensor
(optional)

UV
module

SIPROCESS UV600, gas flow chart

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SIPROCESS UV600

■ Mode of operation
1
The measuring principle of the SIPROCESS UV600 is based on
the molecule-specific absorption of gases in the ultraviolet
wavelength range. Radiation of a wavelength appropriate to the
measurement is passed through the sample, and the selective
absorption which is proportional to the concentration of the
measured component is determined.
Measuring method
An electrodeless discharge lamp (1) emits broadband in the
ultraviolet spectral range. A filter wheel unit (2) generates the
ultraviolet radiation suitable for the respective measured
component. Either interference filter correlation (IFC) or gas filter
correlation (GFC), or a combination of the two methods, can be
used for this purpose.
Interference filter correlation (IFC)
The sample and reference radiations are generated alternately
with two different interference filters being swung into the beam
path (filter wheel 2a).
Gas filter correlation (GFC)
Especially when NO is the measured component, the reference
radiation is generated by swinging in a gas filter which is filled
with the associated gas (filter wheel 2b).
IFC and GFC
The two filter wheels are combined in order to measure NO in
combination with other measured components.
Design of the analyzer module
After passing through the filter unit, the beam is directed via a
lens (3), a beam divider (4) and a mirror (4) into the sample
chamber (6) and reference chamber (7).
The sample beam passes through the sample chamber (6), into
which sample gas flows, and its intensity is weakened in line with
the concentration of the measured component. The reference
beam is directed via a mirror (5) into the reference chamber (7).
This is filled with a neutral gas.
The detectors (9) receive the sample and reference beams in
succession. These measured signals are amplified and
evaluated using electronics.
The measuring system is temperature-controlled to minimize
external temperature influences.
The physical state of the measuring system is recorded simulta-
neously through time-offset detection of the reference beam,
and compensated if necessary.
A quotient is generated for each detector from the determined
signal values, and the ratio of these quotients determined. This
double generation of quotients means that symmetrical signal
drifts are compensated in the best possible manner in addition
to proportional signal drifts.
Note
The sample gases must be fed into the analyzers free of dust.
Condensation in the sample chambers must be prevented.
Therefore, the use of gas modified for the measuring task is
necessary in most application cases.
Additional measures depending on the application must be
taken when introducing gases with flammable components at
concentrations above the lower explosive limit (LEL). Please
contact the technical department in such cases.

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SIPROCESS UV600

1 ■ Function

IFC 2a M

2a
2b

GFC 2b M
IFC + GFC

M
10

2a
2
2b

M
3 M

6 8

4 9

7 8

5 9

1 UV lamp 5 Mirror GFC Gas filter correlation


2 Filter wheel unit 6 Sample chamber IFC Interference filter correlation
2a Filter wheel 1 7 Reference chamber M Motor
2b Filter wheel 2 8 Focus lens
3 Collimator lens 9 Detector
4 Beam divider 10 Optional calibration unit

SIPROCESS UV600, operating principle

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SIPROCESS UV600

■ Technical specifications
1
General information Electrical characteristics
Measuring ranges 3, automatic measuring range Line voltage (optional, see nameplate) 93 ... 132 V AC, 186 ... 264 V AC
switching
Line frequency (AC) 47 ... 63 Hz
Detection limit (2) < 1% of span
Permissible overvoltages (transient Up to overvoltage category II in
Smallest possible span Dependent on order configuration surges in the power supply network) accordance with IEC 60364-4-443
NO: 0 ... 10 / 0 … 20 / 0 … 25 /
0 … 50 vpm Power consumption Approx. 50 VA, max. 300 VA
NO2: 0 … 101) / 0 ... 20 / 0 … 25 / EMC interference immunity In accordance with EN 61326-1,
0 … 50 vpm (electromagnetic compatibility) EN 61326-2-1, EN 61000-6-2,
SO2: 0 … 101) / 0 ... 20 / 0 … 25 / EN 61000-6-4 and EU Directive
0 … 50 vpm 2004/108/EC. In the case of electro-
H2S: 0 … 25 / 0 … 50 vpm magnetic radiation in the frequency
Largest possible span Dependent on order configuration range from 750 MHz ± 20 MHz,
NO, NO2, SO2: 0 … 300 to increased measuring errors can
0 ... 1 000 vpm occur for small measuring ranges
H2S: 0 … 500 to 0 ... 1 000 vpm Electrical safety In accordance with EN 61010-1
UV lamp Internal line fuses
• Design EDL, electrodeless discharge lamp • primary 6.3 A, not replaceable
• Service life  2 years (17 500 h) • secondary 8A
Conformity CE mark Gas inlet conditions
Design, enclosure Permissible sample gas pressure Relative to ambient/atmospheric air
Degree of protection IP40 pressure:
-200 ... +300 hPa (-0.2 ... +0.3 bar)
Weight approx. 17 kg
Sample gas flow 20 ... 120 l/h (333 ... 2 000 ml/min)
Requirements of location of use
Sample gas temperature 5 ... 55 °C
Installation location Within closed building
Measuring response
Atmospheric pressure in the 700 …1 200 hPa
environment (relating to sample gas pressure 1 013 hPa absolute, 0.5 l/min sample gas
flow and 25 °C ambient temperature)
Relative humidity 10 ... 95%, non-condensing
Reference point drift < ± 1%/week of respective span
Permissible contamination Pollution degree 1
Zero point drift
Maximum geographic altitude of 2 500 m above sea level
location of use • Standard measuring ranges < ± 1%/week of respective span
• Small measuring ranges < ± 2%/week of respective span
Permissible ambient temperature ( 2x smallest measuring range)
• Operation +5 ... +45 °C (41 ... 113 °F) • Measured components NO, NO2, < ± 1%/day of respective span
• Transport and storage -10 ... +70 °C (14 ... 158 °F) SO2
Operating position Front wall, vertical, max. ± 15° angle Repeatability (reproducibility) < ± 1% of respective span
for each spatial axis
(maximum permissible inclination of Linearity error < ± 1% of respective span
the base surface during operation Electric inputs and outputs
wtih constant operating position)
Analog output 4, 0 ... 24 mA; floating (electrically
Permissible vibration/shock isolated), residual ripple 0.02 mA,
• Vibration displacement 0.035 mm (in the range 5 ... 59 Hz) resolution 0.1% (20 A), max.
• Amplitude of the starting accelera- 5 m/s2 (in the range 59 … 160 Hz) load 500 , max. voltage ± 50 V
tion Relay outputs 8, with changeover contacts, max.
voltage ± 50 V loading capacity:
Max. 30 V AC / max. 48 V DC /
max. 500 mA
Analog inputs 2, 0 ... 20 mA, reference potential
GND, signal strength max. 30 mA,
overcurrent protection max. ± 1 A,
voltage max. ± 50 V
Digital inputs 8, switching range 14 ... 42 V
(external control voltage),
max. voltage ± 50 V
Serial interface RS485, Ethernet (LAN)
1)
Only for daily recalibration and air-conditioned environment ( +/- 2 °C)

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Continuous Gas Analyzers, extractive


SIPROCESS UV600

1 ■ Selection and ordering data


Product description Article No.
SIPROCESS UV600 gas analyzer, incl. gas module and barometric 7MB2621- Cannot be combined
pressure compensation
7 7 7 7 7 - 0 7 7 7
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Enclosure, version and gas paths 19" rack unit for installation in cabinets
Gas connections Gas connections Gas paths
Diameter Material Material
• 6 mm pipe • PVDF • Hose / Viton 0 0
• 6 mm pipe • Swagelok • PTFE 1
• 6 mm pipe • Swagelok • Stainless steel, with pipes 2
• 1/4" pipe • Swagelok • Stainless steel, with pipes 3
1. UV measured component
Measured Smallest/largest corresponds to
component measuring range
NO 0 ... 10 / 0 ... 300 ppmv 0 … 15 / 0 ... 450 mg/m3 A A AA Y17
0 ... 20 / 0 ... 400 ppmv 0 … 25 / 0 ... 500 mg/m3 A B AB Y17
0 ... 25 / 0 ... 500 ppmv 0 … 35 / 0 … 700 mg/m3 A C
0 ... 50 / 0 ... 1 000 ppmv 0 … 50 / 0 ... 1 000 mg/m3 A D
NO2 0 ... 10 / 0 ... 300 ppmv1) 0 … 20 / 0 … 600 mg/m3 1) B A B A B A BA Y17
0 ... 20 / 0 ... 400 ppmv 0 … 40 / 0 … 800 mg/m3 B B B B B B BB Y17
0 ... 25 / 0 ... 500 ppmv 0 … 50 / 0 … 1 000 mg/m3 B C B C B C
0 ... 50 / 0 ... 1 000 ppmv 0 … 100 / 0 ... 2 000 mg/m3 B D B D B D
SO2 0 ... 10 / 0 ... 300 ppmv1) 0 … 25 / 0 … 750 mg/m3 1) C A C A CA Y17
0 ... 20 / 0 ... 400 ppmv 0 … 50 / 0 … 1 000 mg/m3 C B C B CB Y17
0 ... 25 / 0 ... 500 ppmv 0 … 75 / 0 … 1 500 mg/m3 C C C C
0 ... 50 / 0 ... 1 000 ppmv 0 … 130 / 0 … 2 600 mg/m3 C D C D
H2S 0 ... 25 / 0 ... 500 ppmv 0 … 40 / 0 … 800 mg/m3 D C DC DC DC Y17
0 ... 50 / 0 ... 1 000 ppmv 0 … 75 / 0 ... 1 500 mg/m3 D D DD DD DD Y17
2. UV measured component
Measured Smallest/largest measuring
component range
none 0 0 0 0
NO2 0 ... 10 / 0 ... 300 ppmv1) 0 … 20 / 0 … 600 mg/m3 1) 2 1 2 1 2 1 2 1 Y17
0 ... 20 / 0 ... 400 ppmv 0 … 40 / 0 … 800 mg/m3 2 2 2 2 2 2 2 2 Y17
0 ... 25 / 0 ... 500 ppmv 0 … 50 / 0 … 1 000 mg/m3 2 3 2 3 2 3
0 ... 50 / 0 ... 1 000 ppmv 0 … 100 / 0 ... 2 000 mg/m3 2 4 2 4 2 4
SO2 0 ... 10 / 0 ... 300 ppmv1) 0 … 25 / 0 … 750 mg/m3 1) 3 1 3 1 3 1 Y17
0 ... 20 / 0 ... 400 ppmv 0 … 50 / 0 … 1 000 mg/m3 3 2 3 2 3 2 Y17
0 ... 25 / 0 ... 500 ppmv 0 … 75 / 0 … 1 500 mg/m3 3 3 3 3
0 ... 50 / 0 ... 1 000 ppmv 0 … 130 / 0 … 2 600 mg/m3 3 4 3 4
H2S 0 ... 25 / 0 ... 500 ppmv 0 … 40 / 0 … 800 mg/m3 4 3 4 3 4 3 4 3 Y17
0 ... 50 / 0 ... 1 000 ppmv 0 … 75 / 0... 1 500 mg/m3 4 4 4 4 4 4 4 4 Y17
3. UV measured component
Measured Smallest/largest measuring
component range
none X X
SO2 0 ... 10 / 0 ... 300 ppmv1) 0 … 25 / 0 … 750 mg/m3 1) C A C A C A CA Y17
0 ... 20 / 0 ... 400 ppmv 0 … 50 / 0 … 1 000 mg/m3 C B C B C B CB Y17
0 ... 25 / 0 ... 500 ppmv 0 … 75 / 0 … 1 500 mg/m3 C C C C C C
0 ... 50 / 0 ... 1000 ppmv 0 … 130 / 0 … 2 600 mg/m3 C D C D C D
H2S 0 ... 25 / 0 ... 500 ppmv 0 … 40 / 0 … 800 mg/m3 D C DC DC DC DC Y17
0 ... 50 / 0 ... 1 000 ppmv 0 … 75 / 0 ... 1 500 mg/m3 D D DD DD DD DD Y17
Language of software and documentation
German 0
English 1
French 2
Spanish 3
Italian 4
1)
Smallest measuring range 0...10 ppmv requires daily calibration and temperature-controlled environment (± 2 °C). Use of an additional calibration unit
(B11, B12 or B13) recommended. 2 measured-value outputs are required on the I/O module for this measurement range switchover. A maximum of
4 measured-value outputs are available per I/O module. For versions with 3 sample gas components - including more than 1 component with measuring
range 0...10/0...300 vpm - a second I/O module (option: A13) is required!

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Continuous Gas Analyzers, extractive


SIPROCESS UV600

Product description
1
Additional versions Order code
Please add "-Z" to Article No. and specify Order code.
Second IO module A13
Calibration unit for 1st sample gas component B11
Calibration unit for 1st and 2nd sample gas components B12
Calibration unit for all 3 sample gas components B13
Flow monitor C11
Humidity monitor C12
Pressure sensor (sample gas) C14
Special setting (only in conjunction with an application no., Y12
e.g. special measuring range)
Extended special setting (only in conjunction with an Y13
application no., e.g. determination of cross-interferences)
Prepared for QAL1 (MCERTS), standard measured-value output in mg/m3 Y17

Spare parts recommendation for preventative maintenance Quantity for Quantity for Article No.
2 years 5 years
Article No.Safety filter FI64 1 2 A5E03707235
Power supply units, 24 V DC, 10 A 1 A5E03707236
Distribution board 1 A5E03707240
FKM hose d = 3/5, length = 1 m 2 5 A5E03707757
MEDL UV lamp with heater 1 1 ... 2 A5E03707918
Motor flange 3 1 A5E03707919
Motor flange 2 1 A5E03707920
Gas filter with holder, for measurement of NO 1 2 A5E03707921
SIPROCESS UV600 chamber H = 300 mm, aluminum 1 A5E03707925
Calibration chamber with holder for NO 1 A5E03707941
Calibration chamber with holder for SO2 and H2S 1 A5E03707942
Calibration chamber with holder for NO2 1 A5E03707943
Heater with 380 mm long cable, for SIPROCESS UV600: 1 2 A5E03707968
MEDL, chamber, motor flange
Moisture sensor 1 2 A5E03707969
Spare parts set - pressure sensor with gasket and O-ring 1 A5E03707970
Flow sensor with temperature sensor 1 2 A5E03707971
Diaphragm pump type 123, 24 V DC / 50 Hz 1 A5E03707986
Diaphragm assembly, EPDM for types 110-125 1 2 A5E03707987
O-ring for gas pump suspension 1 2 A5E03707988

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Continuous Gas Analyzers, extractive


SIPROCESS UV600

1 ■ Dimensional drawings






ป


SIPROCESS UV600, 19" rack unit, dimensions in mm

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Continuous Gas Analyzers, extractive


SIPROCESS UV600

■ Schematics
1
Electrical connections

Interfaces:
A RS 485 / external input/output
B RS 485 / external input/output Signal connections of the Signal connections of the
C Reserved for service second, internal input/output internal input/output module
D Ethernet (LAN) module (optional) (standard)

A
B
D
C

SIEMENS
wu XX\VYZW}G[_T]Yo¡
zu YWTYWW}h pwG[W
jlyt
xˆGzWX
zŒ”Œ•šGhn GGGGGGGGGGGGGGGGGGGGGGGGGGGtˆ‹ŒG•GnŒ™”ˆ• 

Power connection

SIPROCESS UV600, gas connections and electrical connections


The SIPROCESS UV600 is supplied as standard with one or The signal connections are available at terminal strips X3, X4, X5
(optionally) two input/output modules. The logic function of the and X7 on the 12-pin plug connectors of the input/output
signal connections can be configured individually with the modules. The scope of delivery includes the corresponding
service and maintenance software specific to SIPROCESS counterparts (plug connectors) with screw terminals.
UV600.

Internal input/output module (standard) with


terminal strips X3, X4, X5 and X7
Connection plug

XY

[ \

Z ^
X

SIPROCESS UV600, signal connections and plug connectors

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Continuous Gas Analyzers, extractive


SIPROCESS UV600

1 Pin assignments

*1' ',& ', ', ', ', ', ', ', ', '2 '2 '2 '2

N

N
N

N

N

N

N

N
;             ;            

'2 '2 '2 '2

'&9

;            

SIPROCESS UV600, pin assignments of digital inputs X3 (DI1 to DI8) and digital outputs X4 (DO1 to DO4) and X5 (DO5 to DO8)
Characteristics of the digital inputs: Characteristics of the digital outputs:
• Floating optocouplers with common reference potential (DIC) • Floating relay changeover contacts
• Switching range 14 ... 42 V DC (external control voltage) • Single-pole changeover switch, three connections
• The digital inputs can be operated either with positive or • Maximum voltage: ± 50 V
negative voltage • Connect inductive loads (e.g. relays, solenoid valves ...)
• With inverted switching logic, the logic function of the control via spark-quenching diodes only
input is active if no current is flowing through the control input • Maximum load-carrying capacity (standard): Max. 30 V AC,
• Maximum voltage: ± 50 V max. 48 V DC, max. 500 mA.

*1' $, $, $ $ $ $


  $2 $2 $2 $2 *1' $, $,
   
P$ P$ P$ P$ P$ P$
N

N

;             ;            

P$
˖

SIPROCESS UV600, pin assignment of the analog inputs X7 (AI1 and AI2) and analog outputs X7 (AO1 to AO4)
Characteristics of the analog inputs: Characteristics of the analog outputs:
• The input signal is an analog current signal • Analog outputs are floating (electrically isolated) and provide
(standard 0 ... 20 mA, maximum 30 mA) a load-independent current signal
• The signal current must be provided by an external current • Signal range 0 ... 24 mA
source • Residual ripple 0.02 mA
• Load (internal resistance) of analog input: 10  • Resolution 0.1%
• Reference potential GND (see figure, analog inputs) • Accuracy 0.25% of full-scale value
• Overcurrent protection: ± 1 000 mA • Maximum load 500 
• Max. voltage: ± 50 V • Maximum voltage ± 50 V
• Adjustable start or error state
Note for electrical isolation:
The electrical isolation is canceled if the negative poles of the
analog outputs are connected to GND.

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2
© Siemens AG 2014

Continuous Gas Analyzers, in-situ

2/2 Introduction
2/2 Introduction to TDLS:
LDS 6 and SITRANS SL

2/3 LDS 6
2/3 General information
2/10 19" central unit
2/20 Cross-duct sensor CD 6
2/30 Documentation
2/30 Suggestions for spare parts

2/31 SITRANS SL
2/31 In-situ O2 and CO gas analyzer
2/48 Documentation

Siemens PA 01 · 2015
© Siemens AG 2014

Continuous Gas Analyzers, in-situ


Introduction
Introduction to TDLS: LDS 6 and SITRANS SL

■ Overview
In-situ process gas analysis The SITRANS SL gas analyzer for highly sensitive measurement
of oxygen and carbon monoxide has a more integrated design
Process gas analyzers are used for continuous determination of without fiber-optic cables and with only one pair of cross-ducts
the concentrations of one or more gases in a gas mixture. Deter- sensors - a transmitter unit and a detector unit. In this case the
mination of the concentration of gases in a process is used to receiver has a local user interface (LUI) which is controlled using
control and monitor process flows, and is therefore decisive for IR remote control.
the automation and optimization of processes and ensuring
2 product quality. In addition, process gas analyzers are used to
check emissions, thus making an important contribution to
A maintenance-free reference gas cell integrated in both
analyzers drastically reduces the need for recalibration
environmental protection, as well as for ensuring compliance (SITRANS SL) or even makes its superfluous (LDS 6). Remote
with statutory directives. scanning and diagnostics of the analyzers is possible using the
Ethernet interface present as standard.
In-situ analytical procedures feature physical measurements in
the flow of process gas directly in the actual process gas line. In The list of gas components measurable using NIR diode laser
contrast to extractive gas analysis, a sample is not taken and technology already comprises:
routed on to the analyzer via a sample line and sample prepa- • For the LDS 6 analyzer:
ration. Only in exceptional cases, the process conditions make O2, NH3, HCl, HF, H2O, CO, CO2, ...
it necessary to condition the sample gas stream in a bypass line
with respect to process temperature, pressure and/or optical • For the SITRANS SL analyzer: O2, CO
path length. Further conditioning of the process gas, such as The list is being permanently extended as laser technology is
drying or dust precipitation, is unnecessary. The analyzer developed further. The LDS 6 O2 analyzers additionally allow
carrying out in-situ measurements must always take into account simultaneous non-contact determination of high process gas
changing process conditions (if these occur) and be able to temperatures.
automatically process them in the calibration model. Computed
temperature and pressure compensation is frequently required Gas measurements with diode lasers feature exceptional selec-
for this. In addition, the analyzer must be extremely rugged since tivity and flexibility. Neither high process temperatures nor high
its sensors have direct contact with the process gas. The fast and varying concentrations of particles in the gas have an
and non-contact measurement of gas concentrations directly in influence on the quality of the result within wide ranges. For
the process is the domain of in-situ diode laser gas analyzers. example, it is possible with the LDS 6 to determine trace
concentrations of NH3, HCl or HF directly in moist process gases
The gas analyzer LDS 6 combines the compact and service- even before any gas purification stage.
friendly design, simple operation and network capability of the
Series 6 analyzers with the well-known exceptional performance These features together with fast measurements free of dead
data of in-situ gas analysis - namely high ruggedness and avail- times mean that diode laser gas analysis with the LDS 6 or the
ability as well as low maintenance - by using diode laser SITRANS SL is an extremely interesting alternative to estab-
technology and fiber-optics. Up to three CD 6 in-situ cross-duct lished extractive analyses.
sensors (which are also optionally available in an intrinsically-
safe version for operation in hazardous areas) can be combined
with an LDS 6 analyzer in the compact 19" rack unit enclosure.
The distance between the analyzer’s control unit - typically in an
existing instrument room or the process plant’s control room -
and the max. three measuring points can be up to 700 m in each
case.

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Continuous Gas Analyzers, in-situ


LDS 6
General information

■ Overview ■ Application
LDS 6 is a diode laser gas analyzer with a measuring principle Applications
based on the specific light absorption of different gas compo- • Process optimization
nents. LDS 6 is suitable for fast and non-contact measurement
of gas concentrations or temperatures in process or flue gases. • Continuous emission monitoring for all kinds of fuels
One or two signals from up to three measuring points are pro- (oil, gas, coal, and others)
cessed simultaneously by the central analyzer unit. The in-situ • Process measurements in power utilities and any kind of

2
cross-duct sensors at each measuring point can be separated incinerator
up to 700 m from the central unit by using fiber-optic cables. The • Process control
sensors are designed for operation under harsh environmental
conditions and contain a minimum of electrical components. • Explosion protection
• Measurements in corrosive and toxic gases
• Quality control
• Environmental protection
• Plant and operator safety
Sectors
• Power plants
• Steel works
• Cement industry
• Chemical and petrochemical plants
• Automotive industry
• Waste incinerators
• Glass and ceramics production
• Research and development
Special applications

LDS 6, typical installation with cross-duct sensors In addition to the standard applications, special applications are
available upon request.
■ Benefits
The in-situ gas analyzer LDS 6 is characterized by a high avail-
ability and unique analytical selectivity, and is optimally suitable
for numerous applications. LDS 6 enables the measurement of
one or two gas components or - if desired - the gas temperature
directly in the process:
• With high dust load
• In hot, humid, corrosive, explosive, or toxic gases
• In applications showing strong varying gas compositions
• Under harsh environmental conditions at the measuring point
• Highly selective, i.e. mostly without cross-sensitivities
LDS 6 properties:
• Little installation effort
• Minimum maintenance requirements
• Extremely rugged design
• High long-term stability through built-in, maintenance-free
reference gas cell, field calibration is unnecessary
• Real-time measurements
Moreover, the instrument provides warning and failure
messages upon:
• Need for maintenance
- Erroneous reference function
- Bad signal quality
• Violation of a lower or upper alarm level for the measured
variable
• Transmitted amount of light violating an upper or lower limit

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Continuous Gas Analyzers, in-situ


LDS 6
General information

■ Design
The gas analyzer LDS 6 consists of a central unit and up to three Inputs and outputs
in-situ sensors. The connection between the central unit and the • One to three measurement channels with hybrid connections
sensors is established by a so-called hybrid cable, which con- for the sensors at the measuring points
tains optical fibers and copper wires. An additional cable con-
nects the transmitter and receiver parts of the cross-duct sensor. • 2 analog inputs per channel for process gas temperature and
pressure
Central unit
2
• 2 analog outputs per channel for gas concentration(s). For se-
The central unit is housed in a 19" rack unit housing with 4 fixing lected versions, the transmission can be read out as an alter-
points for mounting: native.
• In a hinged frame • 6 freely configurable binary inputs per channel for signaling
faults or maintenance requests from external temperature or
• In racks with or without telescopic rails pressure transducers or sensor purging failure.
Display and control panel • 6 freely configurable binary outputs per channel (signaling of
• Large LCD field for simultaneous display of measurement fault, maintenance requirements, function control, transmis-
result and device status sion limit alarm, concentration limit alarm, store analog output)
• Contrast of the LCD field is adjustable via the menu Communication
• LED background illumination of the display with Network connection: Ethernet (T-Base-10) for remote diagnos-
energy-saving function tics and maintenance.
• Easy-to-clean membrane touch pad with softkeys
• Menu-driven operation for parameterization and diagnostics
• Operation support in plain text

LED-backlit graphic Status line to indicate Two code levels


display and membrane the device status according to NAMUR
tactile-touch keyboard

Menu-driven
operator control
with five softkeys

Numeric display
of concentrations

ESC key
to cancel entries
Numeric keypad
for entering digits

INFO key
for help in plain text

CLEAR key
to delete the
digits entered ENTER key MEAS key
to adopt to return direct to
the numbers measurement mode

LDS 6 central unit, membrane keyboard and graphic display

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Continuous Gas Analyzers, in-situ


LDS 6
General information
Cross-duct sensors Parts in contact with the process gas
The sensors normally do not come into contact with the process
gas, since purging with a gaseous media is applied at the pro-
cess side. Stainless steel purging gas tubes in front of the sensor
windows immerse slightly into the process gas and thus limit the
purging volume. Special materials such as Hastelloy and plas-
tics (PP) are available on request.
Hybrid and sensor cables
A combination of fiber-optic cables and twisted copper wires 2
connects the sensors to the central unit. The hybrid cable con-
nects the central unit with the detector unit of the sensor, the sen-
sor cable connects the transmitter and receiver units of the sen-
sor.

Sensor CD 6, transmitter or detector unit


For installation in Ex-protected environments, the legislative reg-
ulations have to be complied with, such as the spatial separation
• In-situ cross-duct sensors, configured as transmitter and of intrinsically-safe from non-intrinsically-safe cables.
detector unit, connected via sensor cable
In compliance with standard EN IEC 60079-14, systems with in-
• Connection to the LDS 6 central unit via a so-called hybrid
trinsically-safe circuits must be installed such that their intrinsic
cable of max. 700 meters in length (total hybrid and sensor
safety is not impaired by electric or magnetic fields. Therefore
connecting cable length: max. 250 m in Ex Zone 0 and Ex
the hybrid and sensor cables of the LDS 6 in an Ex application
Zone 1)
must be routed in such a way that they cannot generate electric
• Stainless steel, some painted aluminum or magnetic fields, e.g. by coiling them in more than one cable
• IP65 degree of protection for sensor loop. To guarantee a good signal quality and to avoid impermis-
sible inductance loops, the hybrid and sensor cables should be
• Adjustable flanges with flange connection
kept as short as possible.
• DN 65/PN 6, ANSI 4"/150 lbs
• The distance between central unit and measuring point can
• Optional flameproof window flanges with dimensions: be
DN 65/PN 6, DN 80/PN 16, ANSI 4"/150 lbs, other process - up to 250 m for Ex units when used in Zone 0 and Zone 1
interfaces available on request (total hybrid and sensor connecting cable length)
• Purging facilities on the process and the sensor sides, - up to 700 m for Ex units used in Zone 2 and for non-Ex units
configurable application with purging gas connections for: • Hybrid and sensor cables
- Instrument air - Multimode fiber-optic cable, provided with SMA connections
- Purging air blower for transmission of the measured signal
- Steam - Two-wire copper cable, in twisted pair version, for +24 V
- Nitrogen supply of the detector electronics (+12 V in the case of Ex-
- Process gases to which the pressure equipment directive suitable instruments)
cat. 2 does not apply
• Additionally for the hybrid cable:
• In combination with high-pressure window flanges, purging - Single-mode fiber-optic cable, configured double-sided with
with instrument air or nitrogen is possible E2000 connectors for transmission of laser light
• Quick release fasteners for cleaning the measurement open- • Rugged cable sheath for laying in open cable ducts or duct-
ings and the sensor window works
• Optional: Version with explosion protection in accordance with • Sheath material: oil-resistant polyurethane
ATEX / IEC Ex ia
• Sensor type CD 6 is compliant with the pressure equipment
directive

Connections of the hybrid cable

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Continuous Gas Analyzers, in-situ


LDS 6
General information

■ Function
Operating principle
LDS 6 is a gas analyzer employing single-line molecular absorp- The result is a fully resolved single molecular line which is ana-
tion spectroscopy. A diode laser emits a beam of near-infrared lyzed in terms of absorption strength and line shape. The influ-
light, which passes through the process gas and is detected by ence of cross-sensitivities on the measurement is negligible,
a receiver unit. The wavelength of the laser diode output is tuned since the quasi-monochromatic laser light is absorbed very se-
to a gas-specific absorption line. The laser continuously scans lectively by only one specific molecular line in the scanned
2 this single absorption line with a very high spectral resolution. spectral range.

Central unit Hybrid cables Measurement path

Laser light
Electrical signals P1
Reflected LED light
Measured
volume
Channel 1
CPU and Laser
display control E/O

Signal Diode
processing laser

P2
E/O Measured
Optocoupler volume
P0 Channel 2
E/O
E/O
E/O PR
Reference
cell

P3
Measured
volume
Channel 3

E/O

Basic design of the LDS 6


Configuration examples Gas concentration
Flue gas
composition
A feature of the in-situ analytical procedure is that the physical Steam
Dust load
measurement takes place directly in the stream of process gas, Central unit Process flange Gas velocity
Gas temperature
and usually also directly in the actual process gas line. All pro- Transmitter unit Gas pressure Receiver
cess parameters such as gas matrix, pressure, temperature,
moisture, dust load, flow velocity and mounting orientation can Measurement
influence the measuring properties of the LDS 6 and must there- Hybrid cable path length
fore be systematically investigated for each new application.
Sensor connecting cable
A feature of the standard applications defined in the ordering
Supplementary channel (option)
data of the LDS 6 is that the typical process conditions are well-
Supplementary channel (option)
known and documented, and that the guaranteed measuring
properties can be proven by reference installations. If you can-
not find your application among the standard applications, Typical transmitted light setup of LDS 6, in-situ
please contact Siemens. We will be pleased to check your pos-
sible individual application of the LDS 6. You can find an appli- To avoid contamination of sensor optics on the process side,
cation questionnaire on the LDS 6 product sites on the Internet. clean gaseous purging media such as instrument air, N2 or
steam are used. Purging air tubes on the sensor heads, which
slightly penetrate into the process gas stream, define the effec-
tive measuring path length.

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Continuous Gas Analyzers, in-situ


LDS 6
General information
The LDS 6 can measure in both the transverse and longitudinal In some specific cases, two components can be measured si-
directions of the process gas flow. In certain cases, the process multaneously if their absorption lines are so close to each other
conditions make it necessary to condition the sample gas that they can be detected within the laser spectrum by one sin-
stream in a bypass line with respect to process temperature, gle scan (for example water (H2O) and ammonia (NH3)).
pressure and/or optical path length. Further treatment of the pro-
cess gas, such as drying or dust precipitation, is usually unnec-
essary. 


Central unit
Sensor connecting cable Transmitter unit


+2
2
Sample
gas 
inlet
Temperature 
Hybrid cable sensor 
Sample gas 
Supplementary 1+SSP
channel (option) outlet 
Supplementary
channel (option)
Receiver 

      
Typical transmitted light setup of LDS 6, in bypass
A flow cell is available by special application for the LDS 6 which Absorption spectra of water and ammonia
has been specially optimized for use with the LDS 6 and its Typical measurable gases for LDS 6 are:
transmitted-light sensors with respect to handling and measur-
ing performance. It is designed to reduce surface effects, and is • Oxygen (O2) for low and high pressure
therefore also highly suitable for polar gases like ammonia. This • Hydrogen fluoride (HF) + water
flow cell is available in heated and non-heated versions. Wheel • Hydrogen chloride (HCl) + water
mounted and wall mounted versions are available.
• Ammonia (NH3) + water
• Water vapor (H2O)
Transmitter unit • Carbon monoxide (CO)
Central unit Heating
Sensor connecting cable

• Carbon dioxide (CO2)


(option)
• CO + CO2
Sample gas inlet

By using an internal reference cell normally filled with the gas


Hybrid cable Pump measured, the stability of the spectrometer is permanently
checked in a reference channel.
Supplementary
channel (option)
By doing so, the continuous validity of the calibration is ensured
Supplementary without the need to carry out external recalibration using bottled
channel (option)
Receiver calibration gases or reference gas cells.

$EVRUSWLRQOLQH
Measuring configuration of LDS 6 with heated flow cell
General information
LDS 6 is connected to the measuring points by fiber optics. The
laser light is guided by a single-mode fiber from the central unit 
to the transmitter unit of the in-situ sensor. The sensor consists of
a transmitter and a receiver; the distance between them defines
the measurement path. In the receiver box, the light is focused
onto a suitable detector. The detector signal is then converted
into an optical signal and transmitted via a second optical fiber
to the central unit, where the concentration of the gas compo- 
nent is determined from the detected absorption signal.
/DVHUOLQH
LDS 6 usually measures a single gas component by means of
the absorption capacity of a single fully resolved molecular ab-
sorption line. The absorption results from conversion of the radi- Typical spectral bandwidth of an absorption line compared to the band-
ation energy of the laser light into the internal energy of the mol- width of the laser light.
ecule. In the working range of the LDS 6, both rotation-vibration
transitions and electronic transitions - such as with O2 - can be
triggered.

Siemens PA 01 · 2015 2/7


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Continuous Gas Analyzers, in-situ


LDS 6
General information
Influences on the measurement Maintenance and fault messages
Dust load LDS 6 outputs different warnings via relays:
As long as the laser beam is able to generate a suitable detector • Need for maintenance (measured value is not influenced)
signal, the dust load of the process gases does not influence the • Operating error (measured value might be influenced)
analytical result. By applying a dynamic background correction,
measurements can be carried out without any negative impact. Note
Under good conditions, particle densities up to 100 g/Nm3 can Individual requirements for the measuring point can make the
be handled by the LDS 6. Varying dust loads are compensated
2
utilization of special sensor equipment necessary. The possibili-
by scanning the laser over the gas absorption line and the cur- ties for adapting the sensors are:
rent background. At a scan position next to the absorption line,
the instrument can "see" only absorption caused by the dust load • Different purging media, such as instrument air, ambient air,
where at the line center the signal is composed of the molecular nitrogen or steam
absorption and the continuous, unspecific background absorp- • Different purging modes on process and sensor sides
tion. With the wavelength modulation technique, the actual mea- • Special materials of purging tubes and/or sensor flanges
sured transmission is always compared with the baseline. After
signal processing, phase-sensitive application delivers a signal • Cooling or heating of the sensors
only from the molecular line free of background. • Explosion-protected sensor configurations
The influence of a high dust load is complex and depends on the
path length and particle size. The optical damping increases at Essential characteristics
longer path lengths. Smaller particles also have a large influence • Integrated calibration adjustment with an internal reference
on the optical damping. With a combination of high dust load, cell
long path length and small particle size, the technical support at • Negligible long-term drifts of zero and span
Siemens should be consulted.
• Dynamic background correction for varying dust loads
Temperature • Isolated signal outputs, 4 to 20 mA
The temperature influence on the absorption line strength is • User-friendly, menu-driven operation
compensated by a correction factor determined during calibra- • Selectable time constants (response time)
tion. A temperature signal can be fed into the instrument from an
external temperature sensor. This signal is then used to correct • Two user levels with individual access codes for prevention of
the influence of the temperature on the observed line strength. unwanted and unauthorized operations
If the temperature of the sample gas remains constant, it is alter- • Operation according to NAMUR recommendations
natively possible to carry out a static correction using a preset • Monitoring of overall optical transmission
value.
At high process gas temperatures, generally from approximately • Remote preventive maintenance and servicing via
1 000 °C, there may be noticeable broadband IR radiation of gas Ethernet/modem
and dust, or flames may occasionally occur in the measurement • Straightforward replacement of the central unit, since connec-
path. An additional optical bandpass filter can be set upstream tions can easily be removed
of the detector to protect it and prevent saturation by the strong • Sensor and central unit housing free of wear and corrosion
background radiation.
• Easy operation with a numerical keypad and menu prompting
Pressure
Certified versions for emission monitoring
The gas pressure can affect the line shape of the molecular ab-
sorption line. LDS 6 uses a special algorithm to adapt the line The LDS 6 is available as certified instrument for emission mon-
shape. Additionally, an external pressure signal can be fed to the itoring of NH3, NH3/H2O, H2O, HCl, HCl/H2O. The certificates
instrument to provide complete compensation for the pressure are issued by TÜV for Germany and MCERTS for the United
influence including the density effect. Kingdom. For conducting regular calibration and linearity
checks, test kits for ammonia, water and HCl should be used.
Optical path length These kits can be ordered separately as instrument accessories.
The absorption values analyzed by the LDS 6 are typically small. For new analyzer orders, the NH3, NH3/H2O and H2O kits named
As a result of Beer-Lambert’s law, the absorption of laser light de- "Version 2" must be ordered. For already installed analyzers,
pends on the optical path length within the gas. Therefore, the please contact Siemens for spotting the correct kit version, or
precision in determining the effective optical path length in the consult the instrument manual.
process might limit the overall precision of the measurement.
As the sensor optics on the process side normally need to be
purged to keep them clean over a long period of time, the thick-
ness of the mixing zone between the purging medium and the
process gas and its concentration distribution need to be con-
sidered. In a typical in-situ installation directly in the line and with
some meters of path, the influence of the purging gas on the ef-
fective path length can be neglected.
Path length and dust load are mutually influencing: the higher
the dust load in the process, the shorter the max. possible path
length.

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Continuous Gas Analyzers, in-situ


LDS 6
General information
Verification of calibration
Assembly with certified, maintenance-free calibration gas cell
with connections for laser fiber-optic conductors and detector
module of cross-duct sensor. Serves to rapidly verify the factory
calibration in the field without compressed gas bottles and flow
cell.
Calibration verification kits are available for the following sample
gases: O2 (application codes AA, AC), NH3, CO, CO2, CO/CO2.
A "Zero gas test kit" is also available. (see "Additional units") 2

Example of an assembly for verification of calibration

Siemens PA 01 · 2015 2/9


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
19" central unit

■ Technical specifications
Electrical characteristics
Analytical performance
Power supply 100 ... 240 V AC 50 ... 60 Hz,
Measuring range Adjustable
automatically adapted by the sys-
Detection limit (DL): Depending on sample gas com- tem; with a 3-channel central unit,
Calculated in accordance with ponent: see table for standard an additional external power sup-
VDI 2449, measured on every sup- applications. ply +24 V DC, 50 VA is included
in the scope of delivery
2
plied analyzer during the tempera- For application code ET and FT:
ture test (between 5 ... 45 °C) in in accordance with the require- Power consumption 50 W
accordance with VDI 4203. ments of 17th and 27th BImSchV
EMC According to EN 61326 and stan-
Smallest recommended measuring Depending on sample gas com- dard classification of NAMUR
range (with 1 m path length) ponent: see table for standard NE21
applications.
Electrical safety According to EN 61010-1,
The maximum applicable measuring ranges can be found in the table overvoltage classification II
of standard combinations. These can only be applied if the individual
process conditions allow it. Please contact the Technical Support from Fuse specifications 100 ... 240 V: T2.5L250V
Siemens for checking the applicability. Dynamic response
Accuracy 2 % / 5 %, depending on sample Warm-up time at 20 °C ambient Approx. 15 min
gas component and application temperature
code. At best: detection limit. See
table for standard applications. Response time Min. of 1 s, depending on appli-
cation
For application code ET and FT:
in accordance with the require- Integration time 1 … 100 s, adjustable
ments of 17th and 27th BImSchV
Influencing variables
Linearity Better than 1 %
Ambient temperature < 0.5 %/10 K of the measured
Repeatability 2 % of the measured value or value
minimum detection limit (which-
ever is largest) Atmospheric pressure Negligible
For application code ET and FT: Process gas pressure compensa- Recommended
in accordance with the require- tion
ments of 17th and 27th BImSchV Process gas temperature compen- Recommended
Calibration interval No recalibration required thanks sation
to internal reference cell Process gas pressure range See table for standard applica-
General information tions
Concentration units ppmv, Vol%, mg/Nm3 Power supply changes < 1 %/30 V
Display Digital concentration display Electrical inputs and outputs
(5 digits with floating decimal Number of measurement channels 1 … 3, optional
point)
Analog output 2 per channel, 4 ... 20 mA, float-
Laser protection class Class 1, safe to the eye ing, ohmic resistance max. 750 
Certificates CE marking, TÜV, MCERTS Analog inputs 2 per channel,
Design, enclosure designed for 4 ... 20 mA, 50 
Degree of protection IP20 according to EN 60529 Binary outputs 6 per channel, with changeover
contacts, configurable, 24 V
Dimensions 177 x 440 x 380 mm AC/DC/1 A, floating
Weight Approx. 13 kg Binary inputs 6 per channel, designed for 24 V,
Mounting Horizontal floating, configurable
Communication interface Ethernet 10BaseT (RJ-45)
Climatic conditions
Temperature range 5 … 45 °C during operation,
-40 … +70 °C during storage
and transportation
Atmospheric pressure 800 … 1 200 hPa
Humidity < 85 % relative humidity,
above dew point
(in operation and storage)

2/10 Siemens PA 01 · 2015


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Continuous Gas Analyzers, in-situ


LDS 6
19" central unit

Selection and ordering data Article No.


LDS 6 in-situ gas analyzer 7MB6121- 7 7 7 0 7 - 0 7 7 7
19" rack unit for installation in cabinets
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Explosion protection
Without, not suitable for connection to Ex sensors 0
Without, suitable for connection to Ex sensors in accordance 1

2
with II 1 G Ex ia op is IIC T4 Ga, II 1 D Ex ia op is IIIC T135 °C Da
Measured component Possible with application code
of the respective channel
O2 B, C, P A
NH3 A, E, F, T C
NH3/H2O A, E, F, T D
HCl A, H, T E
HCl/H2O A, H, T F
HF A, H G
HF/H2O A, H H
CO C J
CO/CO2 D K
CO2 A L
H2O A, T M
Application code of Application examples channel 11)
measured component channel 1
A Emission monitoring, non-certified A
B Emission monitoring, combustion B
optimization
C Safety monitoring with appropriate C
plant concept
D Process control D
E SNCR-DeNOx E
F SCR-DeNOx F
H Filter optimization H
P Process control (high pressure) P
T Emission monitoring, QAL1 according EN T
15267-3 (TÜV and MCERTS), in combination
with measured component variants C, D, E,
F, M
CD 6, sensor alignment kit
With 0
Without 1
Application code of Application examples channel 21)
measured component channel 2
X Channel 2 not used X
A Emission monitoring A
B Combustion optimization B
C Safety monitoring with appropriate C
plant concept
D Process control D
E SNCR-DeNOx E
F SCR-DeNOx F
H Filter optimization H
P Process control (high pressure) P
T Emission monitoring, QAL1 according EN T
15267-3 (TÜV and MCERTS), in combination
with measured component variants C, D, E,
F, M

1)
The examples shown represent possible applications where appropriately configured LDS 6 solutions can be used. The user is responsible for the prevailing
conditions (plant concept (possibly redundant), application of appropriate components required in addition, compliance with possible directives, etc.).

Siemens PA 01 · 2015 2/11


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
19" central unit
Selection and ordering data Article No.
LDS 6 in-situ gas analyzer 7MB6121- 7 7 7 0 7 - 0 7 7 7
19" rack unit for installation in cabinets
Application code of Application examples channel 31)
measured component channel 3 External 24 V DC power supply
included in scope of delivery
X Channel 3 not used X
A Emission monitoring A

2 B
C
Combustion optimization
Safety monitoring with appropriate
B
C
plant concept
D Process control D
E SNCR-DeNOx E
F SCR-DeNOx F
H Filter optimization H
P Process control (high pressure) P
T Emission monitoring, QAL1 according EN T
15267-3 (TÜV and MCERTS), in combination
with measured component variants C, D, E,
F, M
Language (supplied documentation, software)
German 0
English 1
French 2
Spanish 3
Italian 4

Selection and ordering data


Additional versions Order code
Add "-Z" to Article No. and specify Order code
Telescopic rails (2 units) A31
Set of Torx tools A32
TAG labels (customized inscription) Y30
Additional units Article No.
Optical band-pass filter for suppressing IR background radiation (flame filter) A5E00534668
External power supply for hybrid cable length > 500 m A5E00854188
Calibration verification kit for NH3 (version 2) A5E01075594
TÜV/MCERTS linearity verification kit NH3 (version 2), 2 cells A5E00823339013
TÜV/MCERTS linearity verification kit NH3/H2O (version 2), 3 cells A5E00823339014
TÜV/MCERTS linearity verification kit H2O (version 2), 2 cells A5E00823339015
Calibration verification kit for NH3 (version 1) A5E00534675
TÜV/MCERTS linearity verification kit NH3 (version 1), 2 cells A5E00823339003
TÜV/MCERTS linearity verification kit NH3/H2O (version 1), 3 cells A5E00823339004
TÜV/MCERTS linearity verification kit H2O (version 1), 2 cells A5E00823339005
TÜV/MCERTS linearity verification kit HCl, 2 cells A5E00823339008
TÜV/MCERTS linearity verification kit HCl/H2O, 3 cells A5E00823339009
TÜV/MCERTS linearity verification kit H2O (only for HCl/H2O analyzers), 5 cells A5E00823339007
TÜV/MCERTS linearity verification kit H2O (only for NH3/H2O analyzers), version 1, A5E00823339002
5 cells
TÜV/MCERTS linearity verification kit H2O (only for NH3/H2O analyzers), version 2, A5E00823339012
5 cells
TÜV/MCERTS linearity verification kit HCl, 5 cells A5E00823339006
TÜV/MCERTS linearity verification kit NH3, version 1, 5 cells A5E00823339001
TÜV/MCERTS linearity verification kit NH3, version 2, 5 cells A5E00823339011
Linearity verification kit NH3 (version 2), 10 cells A5E03693426
Calibration verification kit for O2 (only for application codes AA, AC and AD) A5E01143755001
Calibration verification kit for CO A5E01143755003
Calibration verification kit for CO2 A5E01143755004
Calibration verification kit for CO/CO2 A5E01143755006
Zero gas verification kit for all gases except O2 A5E00823386009
1) The examples shown represent possible applications where appropriately configured LDS 6 solutions can be used. The user is responsible for the prevailing
conditions (plant concept (possibly redundant), application of appropriate components required in addition, compliance with possible directives, etc.).

2/12 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
19" central unit

■ Dimensional drawings

101.6
178
LDS 6

465 355
483 432

177
428
351.5

437
483

440

LDS 6, 19" central unit, dimensions in mm

Siemens PA 01 · 2015 2/13


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
19" central unit

■ Schematics
Pin assignments

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0  *1'
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IORDWLQJ DOVR
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LIDYDLODEOH
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 1&
 *1'
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0  *1'
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 5HOD\


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LDS 6, 19" central unit, pin assignments

2/14 Siemens PA 01 · 2015


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Continuous Gas Analyzers, in-situ


LDS 6
19" central unit
Optical and electrical connections

25-pin connector: 15-pin connector:


Binary inputs and Binary inputs and
relay outputs analog inputs/outputs

Ethernet
converter
RJ-45

Power supply Hybrid cable E2000 SMA 24 V DC


and fuses support single mode multimode sensor
opto-connector opto-connector supply

LDS 6, three-channel 19" central unit, optical and electrical connections

Siemens PA 01 · 2015 2/15


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
19" central unit

■ More information
The following table lists the measuring conditions for standard Please note that the values for the detection limit and the maxi-
applications. The listed values for the measuring range and de- mum measuring range refer to a path length of 1 m. Longer path
tection limit (DL) are only approximate values. The exact values lengths will improve the detection limit, but not linearly. due to
at the respective measuring point depend on the totality of all in- limiting effects such as dust load. The maximum applicable
fluencing variables and can be determined by Siemens for the measuring ranges can only be used if permitted by the process
specific case. conditions such as dust load.

2 Standard application Process gas Process gas Min. Max. measuring (Max. measur- (DL x path (DL x path Accu-
Effective optical path temperature pressure measuring range ing range x length) length) racy3)
length: 0.3 … 12 m Tmin … Tmax pmin … pmax range (also depen- path length) under stan- At
(with 1 m dent on eff. opt. dard con- 1 013 hPa
Dust load2): ditions1) with cross-
< 50 g/Nm3 eff. opt. path path length:
length) see following without interference
column) cross-inter- of gas 2
ference of
other gases
Gas Gas Gas Appl. Gas 1 Gas 1 Gas 1 Gas 1 Gas 1 Gas 1
1 2 code code
O2 A B6) 600 … 1 200 °C 950 … 1 050 hPa 0 … 15 vol% 0 … 100 vol% 240 vol%*m 0.3 vol%*m 5%
At 600 °C
C 0 … 600 °C 950 … 1 050 hPa 0 … 5 vol% 0 … 100 vol% 75 vol%*m 0.1 vol%*m 2 %4)
P 0 … 200 °C 950 … 5 000 hPa 0 … 5 vol% 0 … 100 vol% 75 vol%*m 0.1 vol%*m 2%
NH3 C A 0 … 150 °C 950 … 1 050 hPa 0 … 25 ppmv 0 … 500 ppmv 2 500 ppmv*m 0.5 ppmv*m 0.9 ppmv*m 2 %
At 15 vol%
H2O, 55 °C
T 0 … 150 °C 950 … 1 050 hPa 0 … 25 ppmv 0 … 500 ppmv 2 500 ppmv*m 0.5 ppmv*m 0.9 ppmv*m 2 %
At 15 vol%
H2O, 55 °C
E 250 … 350 °C 950 … 1 050 hPa 0 … 45 ppmv 0 … 500 ppmv 2 500 ppmv*m 0.9 ppmv*m 1.4 ppmv*m 2 %
At 250 °C at 15 Vol%
H2O, 250 °C
F 300 … 400 °C 950 … 1 050 hPa 0 … 50 ppmv 0 … 500 ppmv 2 500 ppmv*m 1 ppmv*m 1.5 ppmv*m 2 %
At 300 °C at 15 Vol%
H2O, 300 °C
NH3 H2O D A 0 … 150 °C 950 … 1 050 hPa 0 … 25 ppmv 0 … 100 ppmv 1 200 ppmv*m 0.5 ppmv*m 0.9 ppmv*m 2 %
At 15 vol%
H2O, 55 °C
T 0 … 150 °C 950 … 1 050 hPa 0 … 25 ppmv 0 … 100 ppmv 1 200 ppmv*m 0.5 ppmv*m 0.9 ppmv*m 2 %
At 15 vol%
H2O, 55 °C
E 250 … 350 °C 950 … 1 050 hPa 0 … 45 ppmv 0 … 100 ppmv 1 200 ppmv*m 0.9 ppmv*m 1.4 ppmv*m 2 %
At 250 °C At 15 vol%
H2O, 250 °C
F 300 … 400 °C 950 … 1 050 hPa 0 … 50 ppmv 0 … 100 ppmv 1 200 ppmv*m 1 ppmv*m 1.5 ppmv*m 2 %
At 300 °C At 15 vol%
H2O, 300 °C
HCl E A 0 … 150 °C 950 … 1 050 hPa 0 … 30 ppmv 0 … 6 000 ppmv 1 200 ppmv*m 0.6 ppmv*m 2.2 ppmv*m 5 %
At 15%
H2O, 55 °C
T 120 … 210 °C 950 … 1 050 hPa 0 … 10 ppmv 0 … 60 ppmv 720 ppmv*m
H 150 … 250 °C 950 … 1 050 hPa 0 … 50 ppmv 0 … 6 000 ppmv 1 200 ppmv*m 1.0 ppmv*m 3.1 ppmv*m 5 %
At 150 °C at 15 Vol%
H2O, 150 °C
HCl H2O F A 0 … 150 °C 950 … 1 050 hPa 0 … 30 ppmv 0 … 100 ppmv 1 200 ppmv*m 0.6 ppmv*m 2.2 ppmv*m 5 %
At 15%
H2O, 55 °C
T 120 … 210 °C 950 … 1 050 hPa 0 … 10 ppmv 0 … 60 ppmv 720 ppmv*m
H 150 … 250 °C 950 … 1 050 hPa 0 … 50 ppmv 0 … 100 ppmv 1 200 ppmv*m 1.0 ppmv*m 3.1 ppmv*m 5 %
At 150 °C At 15 vol%
H2O, 150 °C
Footnotes: See page 2/18.

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Continuous Gas Analyzers, in-situ


LDS 6
19" central unit

Standard application Min. measuring Max. mea- (Max. (DL x path (DL x path Accu- Purging gas Purging 2
Effective optical path range suring range measuring length) length) racy4) mode gas
length: 0.3 … 12 m (with 1 m eff. opt. (usually also range x under At 1 013 hPa medium
path length) dependent on path standard with cross-
Dust load3): < 50 g/Nm3 eff. opt. path length) conditions interference
1) 2)
length: see of gas 1
following
column)

Gas 1 Gas 2 Gas Appl. Gas 2 Gas 2 Gas 2 Gas 2 Gas 2 Gas 2 Stan- Optio-
code code dard nal
O2 A B6) E, F G, H Steam +
air, N2
C D B N2
P D B N2
NH3 C A C G Air

T C G Air

E E G Air

F E G Air

NH3 H2O D A 0 … 5 vol% 0 … 30 vol% 240 vol%*m 0.1 vol%*m 0.1 vol%*m 5% C G Air

T 0 … 5 vol% 0 … 30 vol% 240 vol%*m 0.1 vol%*m 0.1 vol%*m 5% C G Air

E 0 … 5 vol% 0 … 30 vol% 240 vol%*m 0.1 vol%*m 0.1 vol%*m 5% E G Air


At 250 °C At 250 °C

F 0 … 5 vol% 0 … 30 vol% 240 vol%*m 0.1 vol%*m 0.1 vol%*m 5% E G Air


At 300 °C" At 300 °C"

HCl E A C G Air

T C G Air
H E G Air

HCl H2O F A 0 … 5 vol% 0 … 30 vol% 360 vol%*m 0.1 vol%*m 0.1 vol%*m 5% C G Air

T 0 … 5 vol% 0 … 30 vol% 360 vol%*m C G Air


H 0 … 5 vol% 0 … 30 vol% 360 vol%*m 0.1 vol%*m 0.1 vol%*m 5% E G Air
At 150 °C At 150 °C

Footnotes: See page 2/19.

Siemens PA 01 · 2015 2/17


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
19" central unit

Standard application Process gas Process gas Min. Max. measuring (Max. measur- (DL x path (DL x path Accu-
Effective optical path temperature pressure measuring range ing range x length) length) racy3)
length: 0.3 … 12 m Tmin … Tmax pmin … pmax range (also depen- path length) under stan- At
(with 1 m dent on eff. opt. dard con- 1 013 hPa
Dust load2): ditions1) with cross-
< 50 g/Nm3 eff. opt. path path length:
length) see following without interference
column) cross-inter- of gas 2
ference of
other gases

2 Gas Gas Gas Appl.


1 2 code code
Gas 1 Gas 1 Gas 1 Gas 1 Gas 1 Gas 1

HF G A 0 … 150 °C 950 … 1 050 hPa 0 … 5 ppmv 0 … 1 500 ppmv 200 ppmv*m 0.1 ppmv*m 0.6 ppmv*m 5 %
At 15 vol%
H2O, 55 °C
H 150 … 250 °C 950 … 1 050 hPa 0 … 5 ppmv 0 … 1 500 ppmv 200 ppmv*m 0.11 ppmv*m 0.6 ppmv*m 5 %
At 150 °C At 15 vol%
H2O, 150 °C
HF H2O H A 0 … 150 °C 950 … 1 050 hPa 0 … 5 ppmv 0 … 200 ppmv 200 ppmv*m 0.1 ppmv*m 0.6 ppmv*m 5 %
At 15 vol%
H2O, 55 °C
H 150 … 250 °C 950 … 1 050 hPa 0 … 5 ppmv 0 … 200 ppmv 200 ppmv*m 0.11 ppmv*m 0.6 ppmv*m 5 %
At 150 °C At 15 vol%
H2O, 150 °C
CO J C 0 … 600 °C 950 … 1 050 hPa 0 … 1.5 vol% 0 … 100 vol% 40 vol%*m 300 ppmv*m 1 500 ppmv 2 %
*m
at 50 vol%
CO2, 20 °C
CO CO2 K D 0 … 400 °C 800 …1 400 hPa 0 … 3.0 vol% 0 … 100 vol% 35 vol%*m 0.06 vol%*m 0.5 Vol% 2 %5)
at 50 vol%
CO2, 20 °C
CO2 L A 0 … 150 °C 950 … 1 050 hPa 0 … 7.5 vol% 0 … 100 vol% 40 vol%*m 300 ppmv*m 2%
H2O M A 0 … 150 °C 950 … 1 050 hPa 0 … 5 vol% 0 … 30 vol% 240 vol%*m 0.1 vol%*m 5%
T 0 … 150 °C 950 … 1 050 hPa 0 … 5 vol% 0 … 30 vol% 240 vol%*m 0.1 vol%*m 5%
1)
All technical data apply to an optical path distance of 1 m in a nitrogen atmosphere under standard conditions 25 °C (or Tmin) and 1 013 hPa. The effective
detection limit, the measuring range and the accuracy can be influenced by process parameters such as pressure, temperature and gas composition. Not all
combinations of maximum pressure and temperature can be realized with the minimum measuring ranges. If the process conditions deviate from the specifi-
cations of the standard applications, special applications are also possible on request.
Please complete the application questionnaire which can be found on the Internet at www.siemens.com/insituquestionnaire.
2)
At 0.3 m effective optical path length, average diameter of the dust particles: 15 µm, specific weight of the dust particles: 650 kg/m3
3)
At least: Detection limit
4)
Up to 200 °C, 5 % above this
5)
Up to 60 vol% CO or up to 60 vol% CO2. Higher CO or CO2 concentrations on request.
6)
At high process temperatures, the use of an IR filter A5E00534668 is recommended for the CD 6 sensor (see page 2/26).

2/18 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
19" central unit

Standard application Min. measuring Max. mea- (Max. (DL x path (DL x path Accu- Purging gas Purging
Effective optical path range suring range measuring length) length) racy4) mode gas
length: 0.3 … 12 m (with 1 m eff. opt. (usually also range x under stan- At 1 013 hPa medium
path length) dependent on path dard condi- with cross-
Dust load3): < 50 g/Nm3 eff. opt. path length) tions1) 2) interference
length: see of gas 1
following
column)

Gas 1 Gas 2 Gas Appl. Gas 2


code code
Gas 2 Gas 2 Gas 2 Gas 2 Gas 2 Stan-
dard
Optio-
nal
2
HF G A C G Air

H E G Air

HF H2O H A 0 … 5 vol% 0 … 30 vol% 360 vol%*m 0.1 vol%*m 0.1 vol%*m 5% C G Air

H 0 … 5 vol% 0 … 30 vol% 360 vol%*m 300 ppmv*m 300 ppmv*m 5 % E G Air


At 200 °C At 200 °C

CO J C E G Air, N2

CO CO2 K D 0 … 7.5 vol% 0 … 100 vol% 75 vol%*m 0.15 vol%*m 0.5 vol% at 2 … 5 %5) C G Air
50 vol% CO,
20 °C
CO2 L A C G Air
H2O M A C G Air
T C G Air
1)
At 20 °C, 1 013 hPa
2)
If the smallest permissible process gas temperature of the application is Tmin > 20 °C, the detection limit refers to Tmin and standard pressure (1 013 hPa)
3)
At 0.3 m optical path length, average diameter of the dust particles: 15 µm, specific weight of the dust particles: 650 kg/m3
4)
At least: Detection limit
5)
Depends on temperature (higher values at higher temperatures)
6)
At high process temperatures, the use of an IR filter A5E00534668 is recommended for the CD 6 sensor (see page 2/26).

Special applications
If the process conditions deviate from the specifications of the standard applications, special applica-
tions are also possible on request. Please complete the application questionnaire which can be found at
www.siemens.com/insituquestionnaire on the Internet.

Siemens PA 01 · 2015 2/19


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6

■ Overview
Cross-duct sensors CD 6 and cables for non-Ex applications Purging on the process side with moderate flow
The standard cross-duct sensor consists of a transmitter unit Is selected e.g. for pure gas applications, emission monitoring,
and a detector unit with the same dimensions. The transmitter inerting monitoring. The purging gas flow can be adjusted be-
unit provides a connector for the fiber-optic cable. The laser light tween 0 and approx. 120 l/min at each sensor head using a nee-
is transmitted through this cable. The receiver unit contains a dle valve (included in delivery).
photodetector and an electronics PCB, and is connected to the
2 detector unit by a sensor cable.
The sensors are mounted onto flanges. The easiest way to avoid
condensation and dust deposits on the sensor windows is to use
a purging gas, e.g. with instrument air. Purging must be selected
depending on the application. The cross-duct sensors can
therefore be configured for the respective situation. The applica-
tion reference table provides recommendations for suitable
purging with standard applications.
If a component is to be measured which is also present in mea-
surable quantities in the purging medium - such as oxygen or
moisture - it is necessary to use purging gases such as nitrogen,
superheated process steam or similar. In such cases it is usually
also necessary to purge the sensor heads, since the ambient air Moderate purging on the process side
must also be displaced here out of the laser beam path. A differ- Purging on the process side with increased flow
entiation is therefore made between purging on the process side
and purging on the sensor side. Through omission of needle valve. This type of purging is se-
lected in crude gas applications with higher concentrations of
Note: For measurement of O2 at gas temperatures above particles and/or condensation as well as in non-purified flue
600 °C, it may also be possible to tolerate air as the purging me- gases in combustion plants. The purging gas flow is typically set
dium since its influence on the measurement can be compen- between 200 and 500 l/min on each sensor head depending on
sated. In contrast, the combination O2/temperature always re- the input pressure of the purging medium.
quires O2-free purging.
Applications with oxygen (high-pressure)
For oxygen measurements with a higher process gas pressure
(1 to 5 bar), the sensor CD 6 can be used together with a suitable
window flange as the process connection. This window flange is
also available in the standard sizes DN 65/PN 6, DN 80/PN 16 or
ANSI 4"/150 lbs. The optical surface to the process is made of
borosilicate glass. Flanges can be equipped with window purg-
ing, but without purging tubes. Possible purge modes for the
window flanges are "A-C" (no purging or moderate purging on
the process side). Window flanges are tested for leakage before
delivery using overpressure, and show leakage rates of less
than 10-5 mbarl/s.
Increased purging on the process side
For ordering this application, the MLFB code of the central unit
with the application code "P" must be selected. The process in- Purging on the process side with high flow
terface suitable for the sensors can be chosen by selection of Through use of air blower or dry process steam. Connectors with
the corresponding code in the 6th configurable position of the hose adapters are included in the delivery. An additional
MLFB number. Swagelok adapter must be ordered if a high flow of steam or in-
The most important sensor purging configurations are presented strument air purging is required (option A27). This type of purg-
below: ing is selected in crude gas applications with very high concen-
trations of particles and/or condensation such as in the furnaces
of combustion plants. If instrument air is not available, an air
blower is also an alternative for purging in applications with
lower demands. On the process side, dry steam can be used as
the inert purging gas instead of nitrogen (Tmax. 240 °C). The
purging gas flow is automatically set between 500 and <1 000
l/min on each sensor head depending on the purging air blower
or the steam pressure.

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Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6

Increased purging on the process side, with hose connection adapter Sensor configuration with high purging on the process side, with 6 mm
joint for use with steam, and with N2 purging on the sensor side
Purging on sensor side
The purging media used on the process side flow through purg-
Can be combined with any purging mode on the process side, ing gas tubes into the process gas flow. The tubes extend a few
and is always selected if the ambient air must never have an in- centimeters into the process area, and usually provide a flow
fluence on the measurement. The volumes within the sensor from the side. This results in a wedge being generated in the in-
head are then continuously purged with an O2-free gas. The flow let zone of the purging gas. The effective measuring path in the
of purging gas required in this case is approx. 1 to 6 l/min and is process gas is therefore well-defined as the distance between
set using a needle valve (included in delivery). The combination the ends of the two purging gas inlet tubes.
shown here of purging with superheated process steam on the
process side and with nitrogen from a compressed gas bottle on
the sensor side may satisfy the necessity for O2-free purging Cross-duct sensor CD 6: Options and accessories
e.g. also in combustion plants with boilers without own nitrogen
network. Sensor alignment kit
Note Includes a battery-operated visible light source, a centering aid
with crosshair, and two hook spanners for opening the optics
With purging on the process side, it may be necessary to use tube of the sensors.
non-return valves to ensure no process gas can enter the purg-
ing gas line in the event of failure of the purging gas supply. This Please note: the sensor alignment kit is not explosion protected.
applies especially in the case of cascaded process and sensor
purging where there is otherwise the danger that, for example,
corrosive process gases could enter the sensor enclosure.

125 ... 375 mm


typ. 0 ... 25 mm

Process wall

2° (maximum)

Process flange DN 65/PN 6


Process wall thickness or ANSI 4"/150 lbs
(incl. insulation)

Installation requirements for the cross-duct sensors CD 6

Siemens PA 01 · 2015 2/21


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Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6
Purging air blower
Two purging air blowers are required to purge the sensor heads.
Both 230 V AC and 115 V AC versions can be ordered.

Electrical connections:
2 230 V AC 50 Hz
or 115 V AC 60 Hz

Ø12
Air
filter
1 ¼” hose connection

CD 6 sensor for
blower air purging

Sensor configuration with purging air blower


Flow cell (available on special application)
For implementation of measuring configurations with bypass
mode. The cell consists of a stainless steel tube whose internal
surfaces are coated with PTFE to minimize surface effects. With
an effective measuring path of 1 m, the inner volume is only 1.2 l,
and fast gas displacement times can therefore be achieved. The
flow of sample gas can be from the ends or from the center of
the tube, since appropriate 6 mm joints are present here. The
flow cell can be ordered in four configurations:
• Unheated, including assembly for wall mounting
• Unheated, including assembly for wall mounting and a 19"
housing with an air jet pump with a delivery rate of max.
30 l/min
• As above, but can be heated up to approx. 200 °C
• As above, but can be heated up to approx 200 °C and
mounted on a rack with wheels and integrated 19" frame
Optical bandpass filter
Serves to protect the light-sensitive detector in the receiver unit
of the sensor from saturation by IR background radiation. Is used
with measurements in very hot process gases (T > 1000 °C) or
with unavoidable appearances of flames in the measurement
path.

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Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6

■ Technical specifications
Cross-duct sensor CD 6 Accessories
General information Purging
Design Transmitter and detector units, Nitrogen is permissible as the purging gas for the sensor side. Nitrogen,
connected by a sensor cable steam, air and gases which are not subject to the pressure equipment
directive Cat. 2 are permissible as purging gases for the process side.
Materials Stainless steel, aluminum
Installation
Laser protection class
Vertical or parallel to the gas flow
Class 1, safe to the eye
Purging with instrument air, N2
• Max. overpressure in the sensor < 500 hPa
2
• Quality
Explosion protection II 1 G Ex ia op is IIC T4 Ga,
II 1 D Ex ia op is IIIC T135 °C Da - Instrument air According to
A defined leak rate can only be ISO 8573-1:2010 [2:3:3]
guaranteed when using high- Note: It is sufficient if the pressure
pressure window flanges. Other- condensation point is min. 10 K
wise it may be necessary for the below the minimum ambient tem-
owner to carry out an evaluation perature.
in accordance with ATEX
DEMKO 06 ATEX 139648X; - Nitrogen Purity better than 99.7 %. For oxy-
IECEx UL 13.0029X gen measurements, an O2 con-
tent < 0.01 % in the purging gas
Design, enclosure (optical path length  1 m, min.
5 % oxygen in the process gas)
Degree of protection IP65
• Maximum flow rate 500 l/min
Dimensions Diameter: 163, L: 450 mm (process purging)
Purging gas tube in mm 400 (370 net) x 44 x 40 • Dew point Benchmark: < -10 °C, condensa-
800 (770 net) x 44 x 40 tion on the optics must be
1 200 (1 170 net) x 44 x 40 avoided

Weight 2 x approx. 11 kg Blower purging

Mounting DN 65/PN 6, DN 80/PN 16, • Maximum counter pressure 40 hPa


ANSI 4"/150 lbs • Maximum flow rate 850 l/min
Please note: • Power consumption 370 W
• For purging tubes with a length of 800 and 1 200 mm, the wall thickness • Degree of protection (fan) IP54, cover required to protect
must not exceed 200 mm with DN 65/PN 6 connections. To carry out against rain
measurements with thicker walls, please contact Siemens.
• The optimum adjustment of the flanges can change with high Steam purging
differences in temperature depending on the type of assembly. • Steam conditioning Overheated
Electrical characteristics • Maximum temperature 240 °C
Power supply 24 V DC, supply from central unit • Minimum pressure > 4 000 hPa
via hybrid cable
• Maximum pressure 16 000 hPa, refers to a volume
Power consumption < 2 W during operation, flow of approx. 1 100 l/min
max. 0.6 W with Ex configuration
Climatic conditions
Sensor temperature
• Non-Ex -20 ... +70 °C during operation,
-30 ... +70 °C during storage and
transportation
• Ex -20 ... +60 °C during operation,
-30 ... +70 °C during storage and
transportation
Humidity < 95 % RH, above dew point
Pressure 800 ... 1 100 hPa
Temperature range on the sensor -20 … +70 °C
side of the process interface (con-
nection plate)
Measuring conditions
Measurement path 0.3 ... 12 m (other lengths on
request)
Dust load The influence of dust is very com-
plex and depends on the path
length and particle size. The opti-
cal attenuation increases expo-
nentially at longer path lengths.
Smaller particles also have a
large influence on the optical
attenuation. With high dust load,
long path length and small parti-
cle size, the technical support at
Siemens should be consulted.

Siemens PA 01 · 2015 2/23


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Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6
Hybrid and sensor cables
General information
Configuration hybrid cable Two optical fibers and two twisted
copper wires in one cable for
24 V DC. Single-mode optical
fiber configured at both ends with
E2000 angle connectors. Multi-
mode optical fiber configured at

2
both ends with SMA connectors.
Cable is flame-retardant, very
good resistance to oil, gasoline,
acids and alkalis, outer sheath
UV-resistant
Cable sheath Oil-resistant polyurethane
Dimensions • For > 500 m, an external power
supply must be additionally or-
dered
• For installation in hazardous
zones, non-intrinsically-safe ca-
bles have to be spatially sepa-
rated from intrinsically-safe lines
• Diameter < 8.5 mm
• Length • Use in non-hazardous and
Ex Zone 2: Up to 700 m
• Use in Ex Zone 0 and Zone 1:
Up to 250 m
Weight 75 kg/km
Maximum tensile force 200 N
Maximum lateral pressure 1 000 N/cm
Impact resistance 200 N/cm
Maximum tensile strength 500 N
Minimum bending radius 12 cm
Climatic conditions
Ambient temperature -40 ... +70 °C during transport,
storage and operation
-5 ... +50 °C during laying
Humidity < 95 % rel. humidity, above dew
point (in operation and storage)

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Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6
Selection and ordering data Article No.
LDS 6 in-situ gas analyzer 7MB6122- 7 7 7 7 7 - 7 7 7 7
Pair of sensors (cross-duct sensor)
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Explosion protection
Without 0
II 1 G Ex ia op is IIC T4 Ga, II 1 D Ex ia op is IIIC T135 °C Da 1
Sensor type Measured component
Standard cross-duct sensor O2
All gases except O2
A
W 2
Purging, process side Sensor side
Without purging Without purging A
Air or N2, 1 to 2 l/min; B
incl. needle valve, 6 mm Swagelok
Instrument air or N2 Without purging C
Reduced flow: 0 ... 120 l/min
incl. needle valve, 6 mm Swagelok
Air or N2, 1 to 2 l/min; D
incl. needle valve, 6 mm Swagelok
Air or N2 Without purging E
Increased flow: 200 ... 500 l/min
incl. 6 mm Swagelok
Air or N2, 1 to 2 l/min; F
incl. needle valve, 6 mm Swagelok
Air, fan or steam; Without purging G
high flow: > 500 l/min
incl. 1¼" hose adapter
Air or N2, 1 to 2 l/min; H
incl. needle valve, 6 mm Swagelok
Purging tubes, material
No purging tubes 0
Stainless steel, EN 1.4432/316L 1
Purging tubes, length
No purging tubes 0
400 mm 1
800 mm 2
1 200 mm 3
75 mm, e.g. for engine test rigs 4
Process connection
Stainless steel flange (1.4404/316L), 0
connection dimension DN65/PN6, MAWP (PS) @ 20 °C: 0.05 MPa
Stainless steel flange (1.4404/316L), 1
connection dimension ANSI 4"/150 lbs, MAWP (PS) @ 20 °C: 7.25 psi
Stainless steel flange (1.4404/316L), 2
connection dimension DN65/PN6, MAWP (PS) @ 20 °C: 0.05 MPa,
incl. enclosed welding flanges, e.g. for engine test rigs
Pressure-resistant window flange (1.4404/316L, borosilicate glass), 3
connection dimension DN65/PN6, MAWP (PS) @ 20 °C: 0.6 MPa
Pressure-resistant window flange (1.4404/316L, borosilicate glass), 4
connection dimension DN80/PN16, MAWP (PS) @ 20 °C: 1.6 MPa
Pressure-resistant window flange (1.4404/316L, borosilicate glass), 5
connection dimension ANSI 4"/150 lbs, MAWP (PS) @ 20 °C: 232 psi
Hybrid cable Length [m]
No hybrid cable X
Standard length 5 A
10 B
25 E
40 G
50 H
Customized length (specified in complete meters) Z

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Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6
Selection and ordering data Article No.
LDS 6 in-situ gas analyzer 7MB6122- 7 7 7 7 7 - 7 7 7 7
Pair of sensors (cross-duct sensor)
Sensor connecting cable Length [m]
No sensor connecting cable X
Standard length 5 A
10 B

2
25 E
Customer-specific length (specified in complete meters) Z
Language (supplied documentation)
German 0
English 1
French 2
Spanish 3
Italian 4

Selection and ordering data


Additional versions Order code
Add "-Z" to Article No. and specify Order code
6 mm Swagelok adapter for purging with steam, purging modes G and H A27
Acceptance test certificate 3.1 (leak test) in accordance with EN 10204 C12
(only in combination with pressure-resistant window flanges)
Acceptance test certificate 3.1 (material certificate) in accordance with EN 10204 C13
(only in combination with pressure-resistant window flanges)
Purging tube, special length M1Y
Hybrid cable, customized length P1Y
Sensor cable, customized length Q1Y
TAG label, customized inscription Y30
Additional units Article No.
Purging air blower 230 V A5E00829151
Purging air blower 115 V A5E00829150
CD 6, sensor alignment kit A5E00253142
Optical filter for reducing IR background radiation (flame filter) A5E00534668

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Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6

■ Dimensional drawings
Ø 163 Ø 163

2
105

105
395

395
Ø 6 mm fitting
400 (800, 1 200)

400 (800, 1 200)


370 (770, 1 170)

370 (770, 1 170)

Process flange Process flange


(provided by (provided by
customer) customer)

Ø 44.5 at 400 length Ø 44.5 at 400 length


Ø 54 at 800, 1 200 length Ø 54 at 800, 1 200 length

Cross-duct sensor CD 6, moderate purging (instrument air), version Cross-duct sensor CD 6, increased purging (instrument air), version
according to Article No. 7MB6122-**C1*-0***, dimensions in mm according to Article No. 7MB6122-**E1*-0***, dimensions in mm

Siemens PA 01 · 2015 2/27


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6

Ø 163 Ø 163

105

105
2

Test valve

395
395

1¼” hose (OD)


Ø 6 mm fitting
370 (770, 1 170)

400 (800, 1 200)

400 (800, 1200)


370 (770, 1170)

Process flange Process flange


(provided by (provided by
customer) customer)

Ø 44.5 at 400 length


Ø 54 at 800, 1 200 length Ø 44.5 at 400 length
Ø 54 at 800, 1200 length

Cross-duct sensor CD 6, blower purging, version according to Cross-duct sensor CD 6, sensor and process side purging, version
Article No. 7MB6122-**G1*-0***, dimensions in mm according to Article No. 7MB6122-**H1*-0***-Z A27, dimensions in mm

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Continuous Gas Analyzers, in-situ


LDS 6
Cross-duct sensor CD 6

š Ø 163

105


Fitting

431
for Ø 6 mm


OD hose

Check valve


High pressure flange




Cross-duct sensor CD 6, purged version according to CD 6 high-pressure sensor for oxygen, dimensions in mm
Article No. 7MB6122-*WC14-2***, dimensions in mm

Siemens PA 01 · 2015 2/29


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


LDS 6
Documentation

■ Selection and ordering data


Manual Article No.
LDS 6 manual
• German A5E00295893
• English A5E00295894
• French A5E00295895
2 • Italian A5E00295896
• Spanish A5E00362720

Suggestions for spare parts

■ Selection and ordering data


Description Quantity for Quantity for Article No.
2 years 5 years
CD 6, window module, quartz 1 2 A5E00338487
CD 6, window module, engine test rig, no purging 1 2 A5E00338490
CD 6, high-pressure window flange (1.4404/316L), DN 65/PN 6 1 2 A5E00534662
CD 6, high-pressure window flange (1.4404/316L), DN 80/PN 16 1 2 A5E00534663
CD 6, high-pressure window flange (1.4404/316L), ANSI 4"/150 lbs 1 2 A5E00534664
Gasket for CD 6 hybrid cable 1 2 A5E00853911
CD 6, sensor electronics FO InGaAs (version 2) 1 1 A5E01090409
CD 6, sensor electronics FO Ge, only HCl (version 2) 1 1 A5E01090413
CD 6, sensor electronics SW, only O2 1 1 A5E00338533
CD 6, sensor electronics ATEX SW, only O2 1 1 A5E00338563
CD 6, sensor electronics ATEX HCI 1 1 A5E00853896
CD 6, sensor electronics ATEX NH3, CO, CO2, HF, H2O, low gain 1 1 A5E00338572
CD 6, purging tube 400 mm 1.4432/316L 1 2 A5E00253111
CD 6, purging tube 800 mm 1.4432/316L 1 2 A5E00253112
CD 6, purging tube 1200 mm 1.4432/316L 1 2 A5E00253113

■ More information
For demanding applications it is recommended to keep purging For the suitability of different parts (version 1 or version 2) please
tubes, window modules and detector electronics in stock (quan- consult the instrument manual or contact Siemens directly. In
tities stated per measuring point, i.e. per pair of sensors). general, all new analyzers are compatible with spare parts of
version 2.

2/30 Siemens PA 01 · 2015


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Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

■ Overview ■ Benefits
SITRANS SL is a diode laser gas analyzer with a measuring prin- The in-situ SITRANS SL gas analyzer features high operational
ciple based on the specific light absorption of different gas com- availability, unique analytical selectivity, and a wide range of
ponents. SITRANS SL is suitable for fast, non-contact measure- possible applications. SITRANS SL permits measurement of a
ment of gas concentrations in process or flue gases. An analyzer gas component directly in the process:
consisting of transmitter and receiver units (sensors) is used for • With high dust load
each measuring point. The hardware for further processing of
• In hot, humid, corrosive, explosive, or toxic gases
2
the measured signal into a concentration value, as well as the
monitoring, control and communication functions, are integrated • In applications showing strong varying gas compositions
in these two main modules. The sensors are designed for oper- • Under harsh environmental conditions at the measuring point
ation under harsh environmental conditions.
• Highly selective, i.e. mostly without cross-sensitivities
Special features of the SITRANS SL:
• Little installation effort
• Minimum maintenance requirements
• Extremely rugged design
• High long-term stability through built-in, maintenance-free
reference gas cell
• Real-time measurements
Moreover, the analyzer provides warning and error messages:
• When maintenance is required
- With large variations in the reference signal
- With poor signal quality
• If the transmission violates an upper or lower limit
SITRANS SL

Siemens PA 01 · 2015 2/31


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

■ Application
Applications Sectors
• Control of combustion processes • Chemical and petrochemical plants
• Process optimization • Power plants
• Plant and operator safety • Waste incinerators
• Process measurements in all types of power and combustion • Iron and steel industry
2 plants
• Process control
The following table lists the measuring conditions for standard
applications. The listed values for the measuring range and de-
• Explosion protection tection limit are only approximate values. The exact values at the
• Measurements in corrosive and toxic gases respective measuring point depend on the totality of all influenc-
ing variables and can be determined by Siemens for the specific
• Quality control case. Please note that the values for the detection limit and the
maximum measuring range refer to a path length of 1 m. Longer
path lengths will improve the detection limit, but not linearly. due
to limiting effects such as dust load. The maximum applicable
measuring ranges can only be used if permitted by the process
conditions such as dust load.
Standard application Process gas Process gas Min. Max. Max. DL x path Repeata- Purging
Effective optical path temperature pressure measuring measuring measuring length bility3) gas
length: 0.3 … 8 m Tmin … Tmax pmin … pmax range range range x path (under medium
Dust load2): < 50 g/Nm3 (with 1 m (also dependent length standard
1)
eff. opt. path on eff. opt. path conditions
length) length: see fol- without
lowing column) cross-inter-
ference of
other gases)
Sample Gas Appl.
gas com- code code
ponent
O2 A B 0 … 600 °C 900 ... 1 100 hPa 0 … 1 vol% 0 … 100 vol% 75 vol%*m 200 ppmv*m 2% N2
O2 A C 0 … 200 °C 700 … 5 000 hPa 0 … 1 vol% 0 … 100 vol% 75 vol%*m 200 ppmv*m 2% N2
CO J C -20 … 700 °C 700 ... 2 000 hPa, 0 … 100 ppmv 0 … 6 000 ppmv 2 000 ppmv*m 0.6 ppmv*m 2% Air, N2
max. 300 °C
800 ... 1 200 hPa,
above 300 °C
Reference table: Standard applications. The specified pressures are absolute.
DL = detection limit
1) At 20 °C, 1 013 hPa, without dust
2) With 0.3 m effective optical path length
Average diameter of the dust particles: 15 µm
Specific weight of the dust particles: 650 kg/m3
The influence of dust load is extremely complex, and depends on the path length and particle size. The optical attenuation increases exponentially at longer
path lengths. Smaller particles also have a very large influence on the optical attenuation. With high dust load, long path length and small particle size, the
technical support at Siemens should be consulted.
3) Referred to measuring range.
With stable or externally measured and software-compensated process gas temperature and pressure conditions.

Special applications
In addition to the standard applications, special applications are available upon request. If the process
conditions deviate from the specifications of the standard applications, special applications are also
possible on request. Please complete the application questionnaire which can be found at
www.siemens.com/insituquestionnaire on the Internet.

2/32 Siemens PA 01 · 2015


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Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

■ Design
The SITRANS SL gas analyzer consists of a pair of cross-duct
sensors, a transmitter unit and a detector unit, both with the
same dimensions. The complete analyzer is integrated in these
two enclosures. The transmitter unit contains the laser source
whose light is transmitted to the receiver through the measure-
ment path. The detector unit contains a photodetector including

2
electronics as well as a reference cell. The detector unit is con-
nected to the transmitter unit by means of a sensor cable. A fur-
ther cable on the receiver is used to connect the power supply
and the communication interfaces. The receiver enclosure con-
tains a local user interface (LUI) with an LC display which can be
read through a window in the cover. The LUI is operated by re-
mote-control.
Transmitter and detector units
Local user interface (LUI) of SITRANS SL in the detector unit
Special features of the transmitter and detector units: (display of measured value)
• In-situ cross-duct sensors, designed as transmitter and detec-
tor units, connected via sensor cable
• Powder-coated aluminium; stainless steel
• Degree of protection IP65
• Adjustable process connection plates
• Flange sizes (provided by customer): DN50/PN25,
ANSI 4’’/150 lbs
• Purging gas connections (see "Purging")
• Optional: Explosion-protected version in accordance with
- Ex II 2G Ex de op is IIC T6
Ex II 2D Ex tD A21 IP65 T85°C

Remote control keypad for SITRANS SL


Connection cables
SITRANS SL is supplied as standard without connecting cables.
These must be provided by the customer or are available as ac-
cessories. Exception: the ATEX version is supplied as standard
with cabling.
The sensor cable connects together the transmitter and detector
SITRANS SL, detector unit units of the analyzer.

Parts in contact with the process gas The sensor connecting cable available as a cable set for the
ATEX version as standard, and for non-Ex applications option-
Only the stainless steel and borosilicate window flange of the ally, is offered in lengths of 5, 10 or 25 m. This (optional) cable
sensor is wetted by the process gas. This has optional connec- set also enables permanent installation of an Ethernet cable
tions for purging the process gas side with an appropriate gas- used for service and maintenance purposes.
eous medium.
A rugged cable sleeve should be used as UV protection for in-
Display and control panel stallations in open cable ducts or channel systems.
Special features of the detector unit: The statutory directives must be observed in the event of instal-
• Display for simultaneous output of result and device status lation in hazardous areas.
• LED backlighting of display For the ATEX version of SITRANS SL, the sensor connecting ca-
ble must be connected between the two Ex-e terminal boxes se-
• Remote operation using membrane keypad and softkeys
cured on the transmitter and receiver units.
which are easy to clean
• Menu-driven operation for parameterization and diagnostics
• Remote operation via infrared interface for safe use in hazard-
ous zones

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Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
Inputs/outputs Optional
• 2 analog inputs (4 to 20 mA) for process gas temperature and • 1 Modbus interface with
pressure - Output of concentration as cyclic data
• 2 analog outputs (4 to 20 mA) for gas concentration or for con- - Alarm output, alarm classification
centration and transmission - Input for temperature and/or pressure data for compensation
• 1 configurable binary input • 1 Ethernet 10Base-TX port, only for servicing and mainte-
nance
• 2 configurable binary outputs (display of faults, maintenance

2
requirement, function monitoring, alarms for limit violations of Note:
measured value or transmission) In contrast to the other interfaces, the Ethernet plug-in connector
• Optional: 1 PROFIBUS DP interface with: on standard non-Ex devices is only accessible following removal
- Output of concentration as cyclic data of the detector unit cover. With the help of the sensor connection
- Alarm output, alarm classification cable set (optional with non-Ex devices), an Ethernet cable can
- Input for temperature and/or pressure data for compensation be permanently installed via the terminal box of the sensor con-
The PROFIBUS DP protocol provides DPV0, cyclic data. Mea- necting cable. The Ethernet connection via the sensor connect-
sured values are provided with additional quality data. ing cable can also only be used for temporary service and main-
tenance purposes.
NOTICE:
In an Ex environment, Ethernet connections may only be made
or removed with the permission of the plant operator!

■ Function
Operating principle
SITRANS SL is a gas analyzer employing single-line molecular to a gas-specific absorption line. The laser continuously scans
absorption spectroscopy. A diode laser emits a beam of infrared this single absorption line with a very high spectral resolution.
light which passes through the process gas and is received by The degree of absorption and the line shape are used for the
a detector unit. The wavelength of the laser diode output is tuned evaluation.

Transmitter Receiver
Optics tube (transmitter) Optics tube (receiver)
Laser Detector
Optics Optics Measured Reference Optics Optics
Laser electronics volume cell Reference cell
Electric filter

Electric interface Electric interface

Sensor head (transmitter) Sensor head (receiver)

Computer for control and evaluation


Laser control

Electric
interface

Customer Local
interface display

Measurement External sensors


Alarms for compensation

Basic design of the SITRANS SL

2/34 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
The field design of the SITRANS SL in-situ gas analyzer consists Configuration
of a transmitter unit and a detector unit. The light which is not ab-
sorbed by the sample is detected in the receiver. The concentra- A feature of the in-situ analytical procedure is that the physical
tion of the gas component is determined from the absorption. measurement takes place directly in the stream of process gas
and directly in the actual process gas line. All process parame-
The SITRANS SL analyzer measures a single gas component by ters such as gas matrix, pressure, temperature, moisture, dust
means of the absorption capacity of a single fully resolved mo- load, flow velocity and mounting orientation can influence the
lecular absorption line. measuring properties of the SITRANS SL and must therefore be
investigated for each new application.
The standard applications listed in the ordering data for the
SITRANS SL are distinguished in that the typical process condi-
2
tions are adequately well-known and documented. If you cannot
find your application among the standard applications, please
Absorption

contact Siemens. We will be pleased to check your possible in-


dividual application of the SITRANS SL. You can find an applica-
tion questionnaire on the SITRANS SL product site on the Inter-
net.

Gas concentration
Flue gas
Process flange composition
- Dimensions Steam Purging tube length
Dust load
Wavelength [nm] - Temperature Gas velocity
Gas temperature
Absorption spectrum of measured signal and reference signal with Transmitter unit Gas pressure Receiver
SITRANS SL
SITRANS SL is designed for measuring oxygen (O2) and carbon
monoxide (CO) at high sensitivity. Measuring
path length
Typical application specifications:
Oxygen concentration 0 ... 21 vol %
Sensor cable
Process pressure/temperature con- 700 ... 5 000 hPa

Purging on the process side


Purging on the sensor side
ditions (with O2 application) (absolute)/0 ... 200 °C
900 ... 1 100 hPa
(absolute)/0 ... 600 °C
Carbon monoxide concentration Smallest measuring range:
0 … 100 ppm @ 1 m
Largest measuring range:
0 … 6 000 ppm @ 30 cm
Process gas pressure/temperature 700 … 2 000 hPa (absolute) /
conditions with CO application -20 … 300 °C
800 … 1 200 hPa (absolute) / Typical cross-duct arrangement of the SITRANS SL
-20 … 700 °C
The SITRANS SL can be optionally purged on the process side
The measuring performance of the SITRANS SL depends, using appropriate purging gases to prevent contamination of the
among others, on the actual, individual process conditions with sensor optics on the process side. Purging tubes on the sensor
regard to concentration ranges, pressure and temperature. heads, which slightly extend into the process gas stream, define
the effective measuring path length.
An internal reference cell is used to constantly check the stability
of the spectrometer.
The self-calibration of the analyzer is therefore valid for at least
one year without the necessity for external recalibration using
calibration gases.

$EVRUSWLRQOLQH



/DVHUOLQH

Typical spectral bandwidth of an absorption line compared to the band-


width of the laser light.

Siemens PA 01 · 2015 2/35


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
Influences on the measurement Pressure
Dust load The process gas pressure can affect the line shape of the mo-
lecular absorption line. For known pressure values, the
As long as the laser beam is able to generate a suitable detector SITRANS SL uses a special algorithm to adapt the line shape.
signal, the dust load in the process gas does not influence the Additionally, an external pressure signal can be fed to the instru-
analytical result. By applying a dynamic background correction, ment to provide complete mathematical compensation for the
measurements can be carried out without any negative impact. pressure influence including the density effect. Without compen-
Under optimal conditions, the SITRANS SL can cope with dust sation, the relative error caused by changes in the process gas
loads up to 20 g/Nm³ and up to a measured path length of 8 m.
2 The influence of a high dust load is extremely complex, and de-
pends on the optical path length and particle size. The optical
pressure is approx. 0.1 %/hPa. An external pressure signal is
therefore recommended in most cases.
damping increases exponentially at longer path lengths. Smaller
particles also have a very large influence on the optical damp-
ing. With high dust load, long path length and small particle size, Effective optical path length
the technical support at Siemens should be consulted. As a result of Beer-Lambert’s law, the absorption of laser light de-
Temperature pends on the optical path length within the sample gas. There-
fore the precision of the effective optical path length measure-
The influence of temperature on the absorption line is compen- ment can have an effect on the precision of the total
sated by a correction file. A temperature signal can be fed into measurement.
the instrument from an external temperature sensor. The signal
is then used for mathematical correction of the influence of the Since the sensor optics on the process side usually has to be
temperature on the observed line strength. If the process gas purged to keep it clean for a longer period, the extent of the
temperature remains constant, a static correction can be carried mixed zone between the purging medium and the process gas
out as an alternative. Without temperature compensation, the rel- as well as the latter’s concentration distribution must be consid-
ative error caused by changes in the gas temperature has an ex- ered. In a typical in-situ installation with an optical path length of
tensive effect on the measurement (e.g. up to 0.24 %/K with the several meters, the influence of the purging gas on the effective
O2 application). An external temperature signal is therefore rec- path length can be ignored.
ommended in most cases. The path length and dust load are mutually influencing: the
higher the dust load in the process, the shorter the max. possible
path length.

Transmitter unit Flange connection plate Receiver unit Connecting


(process interface) cable (optional)

Customer flange Cable gland

Purging tube
(optional)

Sensor connecting cable Reference cell integrated Cable gland


(optional) into receiver unit

Sensor connecting
cable (optional)

Design of the non-Ex version of the SITRANS SL system

2/36 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

Connection cable Connection cable


Analog-I/O, Modbus PROFIBUS DP

Transmitter unit Receiver unit


Connection
cable
ATEX cable
gland 2

Remote control

ATEX cable
gland

Cable gland

¥XG” s”ˆŸdGY\G” ¥XG”


Ex-e junction box Ex-e junction box

Design of the ATEX version of the SITRANS SL system

Conduit connection 1/2” NPT Conduit connection 1/2” NPT Ui: 30.2 V DC
(not shown) (not shown) Pi: 10 VA

Transmitter unit Receiver unit

Remote control

FM label FM label
Conduit connection 1/2” NPT
(not shown)

Design of the FM version of the SITRANS SL system


The transmitter and detector units are mounted on process
flanges provided by the customer. Correct alignment of these
flanges must be guaranteed, e.g. by using the optional sensor
alignment kit.

Siemens PA 01 · 2015 2/37


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
Adjustment of the pair of sensors
The flange connection plates (process interface) of the
SITRANS SL to the process flanges on the customer side must
be correctly aligned so that the laser beam generated by the
transmitter hits the photodetector in the detector unit This is
guaranteed in that the transmitter and detector units have a
curved surface integrated in the connection plates. The adjust-
ment is carried out by shifting the flanges on these surfaces,

2 through which the symmetry axis is aligned. The axis can be off-
set by  1 degree, which means that the process flanges must
be welded onto the process wall with at least this accuracy - see
following figure.

Min. 150 mm Approx. 25 to 40 mm

PROCESS

Maximum deviation

± 1°

Process flange

Wall thickness
(incl. insulation)

Dimension B
Dimension A, is measured following installation

Installation/adjustment requirements for the pair of cross-duct sensors

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© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
Purging
The easiest way to avoid condensation and dust deposits on the If oxygen is to be measured with the SITRANS SL - which is also
sensor windows or excessively high thermal load of the windows present in measurable quantities in the ambient air - oxygen-free
and the sealing material as well as the sensor electronics is to purging gases must be used, such as nitrogen. It is equally nec-
purge them (with O2 application: nitrogen). Purging must be se- essary to purge the inside of the sensor heads, since the ambi-
lected depending on the application. The transmitted-light sen- ent air must also be displaced here out of the laser beam path.
sors can therefore be configured for the respective situation. The A differentiation is therefore made between purging on the pro-
application reference table provides recommendations for suit- cess side and purging on the sensor side.
able purging for the standard applications.
2
Input for purging on the process side

Optics tube (transmitter or receiver)


Output for
Process flange
purging on the sensor side

Purging tube

Flange connection plate Sensor head (transmitter or receiver)


(process interface)

Input for purging on the sensor side

Arrangement for purging on the sensor side of the SITRANS SL


Purging on process side
For purging on the process side, the flow of purging gas can be
adjusted between 0 and approx. 50 l/min at each sensor head
using a needle valve (included in delivery).
Purging on sensor side
This can be combined with the purging on the process side, if
required. Purging with nitrogen on the sensor side is almost al-
ways necessary for O2 applications to avoid an offset caused by
the oxygen of the air present in the unit. The cells in the sensor
head are then continuously purged with nitrogen. Particularly
when (re)starting the SITRANS SL O2, a sufficiently high flow of
purging gas of approx. 3 to 5 l/min must be provided for several
minutes to ensure that all residues of oxygen are displaced. The
flow of sensor purging gas can subsequently be set to a lower
value using the needle valve (included in delivery).
Note:
With purging on the process side, it may be necessary to use
non-return valves to ensure no process gas can enter the purg-
ing gas line in the event of failure of the purging gas supply. This
applies especially in the case of cascaded process and sensor
purging where there is otherwise the danger that, for example,
corrosive process gases could enter the sensor enclosure.

Siemens PA 01 · 2015 2/39


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
Purging tubes
The purging media used on the process side flow through purg- measuring path in the process gas is therefore defined as the
ing tubes into the process gas stream. The tubes extend into the distance between the ends of the two purging tubes. The stan-
process area by a few centimeters, usually perpendicular to the dard length of the purging tubes is 340 mm. To enable sufficient
process gas stream. This means that an exactly defined optical pivoting, the process wall should be max. 150 mm thick.
path length is defined through the sample gas. The effective

Optical path length

Process wall Purging tube

Measurement of the optical path length between the ends of the purging gas tubes
Maintenance and fault messages Note
The SITRANS SL carries out continuous self-monitoring, and Specific requirements for the measuring point can make the uti-
outputs alarms and warnings to indicate maintenance require- lization of special sensor equipment necessary. The possibilities
ments or a system fault. The information is output as plain text on for adapting the sensors are:
the LUI display, where symbols identify the category and the se- • Special materials for purging tubes (on request)
verity of the fault.
• Various types/sizes of sensor flanges
Alarm categories: • Explosion-protected sensor configurations
• Maintenance (system must be cleaned or repaired)
Essential characteristics
• Process value (problem with external sensor, or process con-
ditions outside the permissible range for SITRANS SL) • Long-term stability through use of an internal reference cell;
calibration interval at least one year
• Configuration (SITRANS SL is not correctly configured)
• Dynamic background correction for varying dust loads
Severity:
• Isolated signal outputs of 4 to 20 mA
• Fault (measurements could not be carried out)
• User-friendly, menu-driven operation
• Warning (measurements may be inaccurate, or the system will
soon shut down measuring mode if an intervention is not • Selectable time constants (response time)
made) • Password-protected user interface
• Advanced warning/information • I/O operation in accordance with NAMUR recommendations
(measurements are carried out) • Monitoring of overall optical transmission
The two binary (relay) outputs can be configured freely for the • Sensor enclosure resistant to wear and corrosion
alarm output. • Simple local operation using remote-control unit with numeric
The response of the analog outputs in the event of an alarm is keypad and menu prompting
configurable; possible actions are:
• Off (current measured value is displayed)
• Last measured value (freezing of last value displayed)
• Standard level (setting to predefined value)
• 3 mA (NAMUR NE43 fault status)
In addition, the transmission is available as an output variable.

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© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

■ Technical specifications
Analytical performance Electrical characteristics
Measuring range Internally adjustable Power supply 24 V DC nominal (18 ... 30.2 V DC)
Detection limit at standardized O2: 200 ppmv Power consumption, maximum 10 VA
conditions: CO: 0.6 ppmv
25 °C gas temperature, 1 000 hPa, EMC In accordance with EN 61326-1
1 m effective optical path length, 3 s Electrical safety In accordance with EN 61010-1

2
integration time and constant ambi-
ent conditions. Fuse specifications T1.6L250V
Linearity Better than 1 % Dynamic performance
(under standard conditions)
Warm-up time at 20 °C ambient Approx. 15 min
Repeatability O2: 1 % of the measuring range temperature
(under standard conditions) CO: 0.5 % of the measuring range Response time (T90) Approx. 2 s,
General information depends on application

Design Transmitter and detector units, Integration time 0 ... 100 s, selectable
connected by a sensor cable Influencing variables
Materials • Sensor enclosure: treated Variations in ambient temperature < 0.5 %/10 K of the measuring
aluminium/stainless steel range
• Process interface: acid-resistant Process gas temperature With compensation: < 1 %/100 K
stainless steel of the measuring range
• Window: hardened borosilicate
glass Variations in atmospheric pressure Negligible

Installation In-situ or bypass Process gas pressure O2: With compensation:


< 1 %/4 000 hPa of the
Concentration units ppm, vol. %, mg/Nm3 measuring range
Display Digital concentration display CO: Negligible
(4 digits with floating decimal Variations in supply voltage Negligible
point)
Electrical inputs and outputs
Laser protection class Class 1, safe to the eye
Number of measurement channels 1
Explosion protection Optionally, according to
• ATEX II 2G Ex de op is IIC T6 Analog outputs 2 outputs, 4 ... 20 mA, floating,
ATEX II 2D Ex tD A21 IP65 ohmic resistance max. 660 .
T85 °C External isolating power supplies
may have to be provided by the
• FM Class I, II, III Div 1 Groups A, customer.
B, C, D, E, F, G T6
FM Class I, Zn 1, AEx d IIC T6 Analog inputs 2 inputs, designed for 4 ... 20 mA,
FM Class II, Zn 21, AEx td 120 
T85 °C Digital outputs 2 outputs, with switchover con-
• XP Class I, II, III Div 1 Groups C, tacts, configurable, 24 V/0.5 A,
D T6 Ta = 55 °C; floating, single pole double throw
DIP Class II,III Div 1 Groups E, F, (SPDT)
G T6 Ta = 55 °C; Class I, Zn 1,
Ex d IIC T6 Ta =55 °C; Zn 21, Ex Digital input 1 input, designed for 24 V,
tD T85 °C Ta = 55 °C floating, configurable

Design, enclosure Service port Ethernet 10BaseT (RJ-45)

Degree of protection IP65 according to EN 60529 RS 485 PROFIBUS DPV0 version Two-wire interface, up to 3 Mbit/s,
-7 … 12 V
Dimensions For each unit
(transmitter, detector) RS 485 Modbus version Two-wire interface, up to
• Diameter: 165 mm 115 200 bit/s, -7 … 12 V
• Length: 357 mm Cable to customer interface
Purging tube Length, outer diameter, inner (not included in standard delivery, ATEX or optional)
diameter: Analog connection cable 10 x 2, with shielding in twisted-
340, 48, 44 mm (with ATEX configuration: only pair configuration (depending on
Weights supplied cables may be used!) type and number of I/Os used)

• Detector unit 6.0 kg PROFIBUS DP connection cable 1 x 2 + 4 (PROFIBUS DP hybrid


(with ATEX configuration: only cable)
• Transmitter unit 5.2 kg supplied cables may be used!)
• Process interface Modbus connection cable 1 x 2 + 3, with shielding in
5.3 kg (with ATEX configuration: only twisted-pair configuration
- for DN50/PN25 supplied cables may be used!)
- for ANSI4’’/150 lbs Approx. 12 kg
Cable length for ATEX configuration 3m
Connection dimension customer DN 50/PN 25, DN 50/PN40 or Conductor cross-section Min. 0.34 mm²
flange ANSI 4"/150 lbs
Cable diameter 8 ... 12 mm or 13 ... 18 mm
Minimum bending radius 110 mm
ATEX-PROFIBUS

Siemens PA 01 · 2015 2/41


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
Sensor cable (not included in standard delivery, ATEX or optional)
Sensor cable type configuration 4 x 2, with shielding,
in twisted-pair configuration
Conductor cross-section Min. 0.34 mm²
Cable sheath PUR (polyurethane)
Dimensions • Diameter: 11 mm
• Length: up to 25 m
2 Minimum bending radius ATEX: 85 mm
Climatic conditions
Ambient temperature range • -20 ... +55 °C during operation
(additional solar radiation not
permissible!)
• -40 ... +70 °C during transport
and storage
Temperature range on the sensor -20 ... +70 °C
side of the process interface (con-
nection plate)
Atmospheric pressure 800 ... 1100 hPa
(for ATEX and FM version)
Humidity < 100 % rel. humidity
Measuring conditions
Measurement path 0.3 ... 8 m (other lengths: please
contact Siemens)
Process gas pressure, temperature • O2: 900 ... 1 100 hPa,
0 … 600 °C
• O2: 700 … 5 000 hPa,
0 … 200 °C
• CO: 700 … 2 000 hPa,
-20 … 300 °C
• CO: 800 … 1 200 hPa,
-20 … 700 °C
Dust load The influence of a high dust load
is complex, and depends on the
optical path length and particle
size distribution.
Purging
Purging gas • Oxygen
(for O2 and CO applications)
• Instrument air
(for CO applications)
• Quality O2 application: Purity better than
99.7 % in order to achieve full
performance. For oxygen mea-
surements, an O2 content
< 0.01 vol. % in the purging gas
is recommended.
• Dew point < -10 °C, condensation on the
optics must be avoided
Sensor purging
• Max. overpressure in the sensor 500 hPa
• Purging gas temperature 0 ... +55 °C
on sensor side
• Flow O2 application: When commis-
sioning a sensor enclosure previ-
ously filled with air: 3 ... 5 l/min
(for at least 15 min), subse-
quently: at least 0.25 l/min
Purging on the process side
(optional)
• Pressure at purging gas inlet 2 000 ... 8 000 hPa
• Flow Dependent on process gas pres-
sure, process gas velocity, dust
load, moisture, etc. up to max.
50 l/min

2/42 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

■ Accessories
SITRANS SL sensor alignment kit Calibration test kit
The SITRANS SL sensor alignment kit includes a battery-oper- The SITRANS SL has already been factory-calibrated. If it is de-
ated lamp, a centering aid with crosshair, and two hook span- sirable or necessary to check the calibration, this can be per-
ners for loosening the sensors from the flange connection plates. formed using an external calibration test kit following removal of
the transmitter and detector units. This procedure has no influ-
Please note: ence on the optical adjustment of the unit since the flange con-
The SITRANS SL sensor alignment kit is not explosion-pro-
tected! Therefore it must never be used in a hazardous area
nection plates remain mounted on the customer flange. The cal-
ibration test kit for O2 consists of a stainless steel calibration
2
without approval by the plant operator! tube and a thermometer. To carry out the calibration, it is
mounted between the transmitter and receiver. The calibration
tube for O2 can then be filled with air or a calibration gas.

7KHUPRPHWHU
7UDQVPLWWHU 5HFHLYHU
Calibration tube for O2

1HHGOHYDOYHV

$7(;DGDSWHUFDEOH

Calibration setup of SITRANS SL O2

Siemens PA 01 · 2015 2/43


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

■ Dimensional drawings
Note
the SITRANS SL sensors must be accessible from the side. A
space of at least 60 cm must be provided next to the SITRANS
SL transmitter and detector units in order to facilitate mainte-
nance and servicing.

2 To fulfill the safety requirements, a space of at least 10 cm must


be provided around the SITRANS SL to facilitate cooling.

Process purging input


/RRSFDEOHMXQFWLRQER[
$7(;YHUVLRQRUDVDQRSWLRQ
112

Process interface

Purging tube

163
Process flange

Sensor purging input


340 357

SITRANS SL, transmitter/detector unit (same housing for DN50/PN25 process interface version), dimensions in mm

Ø 3/4"
Ø 18 (for 5/8 screwed gland)"
(for M16
screwed gland)
Ø 7½"
Ø 125
Ø 50

Ø 4"

Ø 9"

Connection dimensions of process flanges provided by customer DN50/PN25 and ANSI 4’’/150 lbs

2/44 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

■ Schematics
Electrical connections
Non-EEx version: connection cable - customer interface
Terminal block in the receiver enclosure Function/voltage Ethernet cable
1 + Power supply
19 … 30.2 V, 10 VA1)

2
2 -
3 Normally closed under power4) Binary output 0 (relay)
30 V, 0.5 A3)
4
5 Normally closed under power4) Binary output 1 (relay)
30 V, 0.5 A3)
6
7 + Binary input 0
0 … 30 V2)
8 -
9 + Analog output 0 (measurement)
30 V, 24 mA3)
10 -
11 + Analog output 1 (measurement)
30 V, 24 mA3)
12 -
13 PROFIBUS A line Modbus D1 RS 485
(RxD/TxD_N - data inverted) (RxD/TxD_N - data inverted) (PROFIBUS/Modbus)
14 PROFIBUS B line Modbus D0 -7 ... +12 V DC
(RxD/TxD_P - data not inverted) (RxD/TxD_P - data not inverted)
15 PROFIBUS/Modbus shield
16 T x+ Ethernet5) White/orange
17 T x- Orange
18 Rx+ White/green
19 Rx- Green
20 + Analog input 0 (temperature)
0 … 30 mA2), 120 
21 -
22 + Analog input 1 (pressure)
0 … 30 mA2), 120 
23 -
24 Grounding
25 Grounding
Ground Grounding
Ground Grounding Shielding
1)
This is the maximum power consumption of the SITRANS SL
2)
These are the maximum input values
3)
These are the maximum output values
4)
Note:
"Normal operation" stands for normal operation of the analyzer. The system is connected to the voltage source and is running without problems;
no error message generated or displayed.
"Normal under power" refers to the status of the relay under the above-named normal operation. The relay contact of the alarm signal is closed.
5)
We recommend that the Ethernet connection is not made via the cable to the Ethernet terminals in the detector unit. Instead, the Ethernet connection should
be made via the sensor cable connection set which is optionally available for the detector unit.

Siemens PA 01 · 2015 2/45


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
Examples of digital output and analog output Sensor cable terminal box on the receiver side (ATEX version)

Terminal strip in Function Color code


Customer side < > SITRANS SL terminal box
1 + 24 V DC voltage supply Red
for transmitter unit
Imeas 2 - Blue
3
V0 3 Com + Communication with transmitter Pink

2
4 Com - Gray
5 Sync + Synchronization with transmitter White

Rload 6 Sync - Brown


4 7 NC Not used -
8 Tx+ Ethernet Gray/pink
9 Tx- Red/blue
V0 can be up to 30 V 10 Rx+ Black

Rload must be at least 60 Ω 11 Rx- Violet


(max. 0.5 mA in relay) PE - Grounding Green
terminal
PE Grounding Yellow
Example of digital output 0 terminal
Gland Grounding Shielding

Customer side < > SITRANS SL

Imeas
9
V0

Rload
10

V0 must be min 7.5 and max 30 V


V0 - 7.5
Rload can be maximum Ω
0.025

Example of analog output 0


Caution:
Please note that an external isolating power supply may be
required!

2/46 Siemens PA 01 · 2015


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

Selection and ordering data Article No.


SITRANS SL in-situ gas analyzer 7MB6221- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Explosion protection
Without 0 0
Ex II 2 G Ex de op is IIC T6 1 1
Ex II 2 D Ex tD A21 IP65 T85°C
FM USA:
XP Class I, II, III Div 1 Groups A, B, C, D T6 Ta = 55°C
2 2 2
2
DIP Class II,III DIV 1 Group EFG Ta = 55°C
Class I, Zn 1, AEx d IIC T6 Ta = 55°C
Zn 21, AEx tD T85°C Ta = 55°C
FM Canada:
XP Class I, II, III Div 1 Groups C, D T6 Ta = 55°C
DIP Class II,III DIV 1 Group EFG
Class I, Zn 1, Ex d IIC T6 Ta =55°C
Class II, III Zn 21, Ex t IIIC T85°C Ta = 55°C
Measured component
O2 A A
CO J J
Application examples1)
Control of combustion processes B B B
Process control, safety monitoring in appropriate plant concepts C
Communication interface
Analog 0
PROFIBUS DP 1
Modbus 2
Purging tubes, material Length
No purging tubes 0
Stainless steel 340 mm 1
Purging mode, process side Sensor side
No purging No purging 0 0
No purging 3 ... 5 l/min 1 1
0 ... 50 l/min No purging 2 2
0 ... 50 l/min 3 ... 5 l/min 3
Process interface 2)
Connection dimension ANSI 4" 150 lbs (EN 1.4404/316L), MAWP (PS) @ 20 °C: 232 psi B
Connection dimension DN 50/PN 25 (EN 1.4404/316L), MAWP (PS) @ 20°C: 2.5 MPa C
Connection dimension DN 50/PN 40 (EN 1.4404/316L), MAWP (PS) @ 20°C: 4.0 MPa E E
Sensor cable Length
Standard length 5m A A A
10 m B B B
25 m C C C
Without cable X X
Documentation language
German 0
English 1
French 2
Spanish 3
Italian 4

Selection and ordering data


Additional versions Order code
Add "-Z" to Article No. and specify Order code
Acceptance test certificate 3.1 (leak test) in accordance with EN 10204 C12 3)
Acceptance test certificate 3.1 (material certificate) in accordance with EN 10204 C13 3)
SIL 1 conformity declaration in accordance with standards IEC 61508/IEC 61511 C20 3)
(for the measured component oxygen in combination with analog interfaces)
TAG label, customized inscription Y30
1)
The examples shown represent possible applications where appropriately configured SITRANS SL solutions can be used. The user is responsible for the prevailing
conditions (plant concept (possibly redundant), application of appropriate components required in addition, compliance with possible directives, etc.).
2)
MAWP: Maximum Allowable Working Pressure
3)
Together with explosion protection as per FM, on request

Siemens PA 01 · 2015 2/47


© Siemens AG 2014

Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer
Selection and ordering data
Additional units Article No. Item number
(see figure on the next
page)
Calibration verification kit O2, SITRANS SL A5E01000694
Calibration verification kit CO, SITRANS SL A5E03090938002
SITRANS SL sensor alignment kit A5E01000740
Ex-e junction box for 25-wire cable A5E01267567
2 Cable set analog (for non-Ex SITRANS SL)
Cable set PROFIBUS DP (for non-Ex SITRANS SL)
A5E03328474
A5E03328473
UV protective hose for outdoor use, ND = 48 mm, per 30 m A5E01714061
Sensor connecting cable set
• 25 m A5E02528052 2
• 10 m A5E02528048 2
•5m A5E02509347 2
Spare parts
Process interface for DN50/PN10 ... PN40 including gaskets A5E01009881
Process interface for ANSI 4"/150 lbs including gaskets A5E01009883
Purging tube 340 mm including gasket for DN50/PN10 ... PN40 A5E01009892
Cover for SITRANS SL transmitter housing A5E02568437
Window cover of receiver housing A5E01009897
Union nut SITRANS SL A5E01010033
Gasket for DN50/PN10 ... PN40 A5E02522036
Gasket for ANSI 4'' 150 lbs A5E02789535
Analog cable (IECEx) A5E02608597
PROFIBUS cable (ATEX) A5E02608594
Analog cable (ATEX) A5E01009905 6
Sensor cable connection set for transmitter side (IECEx) A5E02568463 3
Sensor cable connection set for receiver side (IECEx) A5E02568465 4
Non-Ex cable gland for SITRANS SL A5E02568457
Sensor cable for SITRANS SL, R1.1 and higher, 5 m long A5E02571180 5
Sensor cable for SITRANS SL, R1.1 and higher, 10 m long A5E02571184 5
Sensor cable for SITRANS SL, R1.1 and higher, 25 m long A5E02571186 5
Needle valves for SITRANS SL A5E02569944
Spare capillary tubes for SITRANS SL A5E02183375
Ex-e connection box for 7-pole SITRANS SL cable A5E02091532 1
Remote control for SITRANS SL, IS, CSA, FM, ATEX certified A5E02091214

Documentation

■ Selection and ordering data


Manual Article No.
SITRANS SL manual
• German A5E01132949
• English A5E01132948
• French A5E01132951
• Italian A5E01132952
• Spanish A5E01132953

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Continuous Gas Analyzers, in-situ


SITRANS SL
In-situ O2 and CO gas analyzer

Z
Y
X

SITRANS SL spare parts, item numbers

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Continuous Gas Analyzers, in-situ


SITRANS SL
Notes

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3
© Siemens AG 2014

Process Gas Chromatographs

3/2 Introduction

3/3 MAXUM edition II

3/18 MicroSAM

3/27 SITRANS CV

Siemens PA 01 · 2015
© Siemens AG 2014

Process Gas Chromatographs


Introduction

■ Overview
Process gas chromatography is one of the most powerful
measuring and analysis methods for process engineering. It is a
procedure which is both discrete and extractive. This procedure
is frequently used for online monitoring of processes since the
sequences are easy to automate and a large number of compo-
nents can be measured simultaneously.
Process gas chromatography can be used to separate and
quantify the components of almost all homogenous gaseous or
liquid mixtures. It must be possible to vaporize the liquid compo-
nents without decomposition. The individual components of a
discrete sample pass through the column system at different
velocities, and are recorded in succession by a detector.
The time between sample introduction and registering of a
substance at the detector (the retention time) is characteristic of
the substance and is used to identify it. The magnitude of the
3 detector signal is a measure of the volume concentration of the
component in the gas or liquid.

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Process Gas Chromatographs


MAXUM edition II

■ Overview ■ Benefits
MAXUM edition II with its combination of different analytical
components offers a wide range of analytical possibilities. It is
therefore possible to solve highly different measuring tasks with
just one product. This reduces the costs for investment, training
and stocking of spare parts.
The MAXUM edition II platform offers:
• Numerous oven configurations permit an optimum solution for
almost every application
• Numerous types of detector and valve for the optimum
analytical solution
• Intelligent electronics, local operation and central workstation
for fast and simple operation, monitoring and maintenance
• Powerful software for best results
• Comprehensive I/Os and serial interfaces for internal and
central interfacing
• Versatile networking possibilities for central maintenance and
3
secure data transfer
The MAXUM edition II is a universal process gas chromatograph • Many analytical possibilities as result of large application
for flexible process applications with a wide variety of analytical database
possibilities. The MAXUM edition II combines various functional
modules with a flexible oven concept and can therefore also • Large and experienced support team provides global support
optimally solve complex applications. Hardware and software features
The MAXUM edition II is used in all sectors of the chemical Simultaneous applications
industry, petrochemicals and refineries. It analyzes the chemical
composition of gases and liquids in all production phases. The Use one MAXUM edition II to provide the functionality of multiple
MAXUM edition II is suitable for installation in an analysis cabinet GCs.
close to the process or in a close laboratory. Thanks to the
flexible application possibilities, it can be used to analyze the Parallel chromatography
initial material, the end product and also secondary products. Separate complex analytical tasks into simple parallel tasks and
The MAXUM edition II can also be used for many applications shorten analysis times.
with environmental measurements.
Low operating costs
The MAXUM edition II has extremely rugged and specially
designed hardware and software. It automatically takes a Flexible oven concept results in low consumption of air and
sample from the process, and injects this onto the chromato- energy.
graphic columns.
With its powerful software and hardware, it satisfies the highest
demands for measurement repeatability, and can be operated
for a long time without manual interventions. Using powerful
communications tools, the MAXUM edition II can send its results
to process control systems. The comprehensive networking
facilities can be applied to use several MAXUM edition II
chromatographs together in large networks.

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© Siemens AG 2014

Process Gas Chromatographs


MAXUM edition II

Extension of functionality
■ Application
Network Access Unit (NAU)
Chemical industry
• A MAXUM edition II without analytical section
• Monitoring of benzene in styrene in the ppb range
• Available with or without HMI
• Traces of residual gases in ultra-pure gases
• Has 7 slots for optional I/O plug-in cards
• Determination of traces of hydrocarbons in air separation
• Offers central MODBUS connection of several chromato-
plants
graphs to the control system
• Fast analysis of CS2 and H2S in seconds
• Fast measurement of C6 to C8 aromatic compounds including
the measurement of C9+ aromatics
■ Function
• Monitoring of hydrogen in chlor-alkali plants Supply with carrier gas, combustion gas and auxiliary gases
• Measurement of sulfurous components A gas chromatograph must be supplied with carrier gas and,
if applicable, combustion gas and other auxiliary gases
• Measurement of C9 to C18 paraffins depending on the analytical configuration. The carrier gas is
• Determination of vinyl chloride in room air in a 60-second used to transport the sample through the analytical system.
cycle Auxiliary gases are used to operate valves, as combustion
3 • Gas analysis during manufacture of vinyl chloride monomer
(VCM)
gases for flame ionization detectors, and to purge the oven.
Injection system
Oil & gas The injection system is the link between the continuous process
• Crack gas analysis stream and the discrete analytical process. It is responsible for
• Natural gas: Trace analysis for components such as injecting an exactly defined portion of the sample in a repro-
mercaptans, H2S or COS ducible and pulsed manner (as far as possible) into the carrier
gas stream.
• Fast determination of benzene in naphtha
The injection can be carried out in the conventional manner
• Determination of high boiling aromatics in a distillation fraction using valves or by means of a live injection:
• Fast measurement of acetylene in ethylene • Gaseous samples (0.1 to 5 ml)
• Total sulfur in petrol and diesel • Completely vaporizable liquid samples (0.1 to 10 µl)
Water/waste water Gas injection valves
• Determination of halogenated hydrocarbons
Model 50 10-port valve:
• Simultaneous determination of chlorinated hydrocarbons,
aromatics and alcohols in water • Combined gas injection and backflushing valve
• Wastewater monitoring with PGC and stripper • Activation by pressure on the membrane without moving parts
• Can be used as gas injection valve or for column switching (6-
Power engineering port connection)
• Power generation in coal-fired power plant. • > 3 million switching cycles without maintenance
Automotive industry Model 11 6-port valve:
• Fast analytical measurement of methane in car exhausts • Can be used as gas injection valve, liquid injection valve or for
• High-speed chromatography for small molecules in propel- column switching
lants • Membrane controlled by tappet
• One million switching cycles without maintenance
■ Design
Chromatographic measuring equipment consists of a sampling
system matched to the application, sample preparation with
switchover to various sample streams if necessary, and the gas
chromatograph with the analytical and electronic hardware as
well as data processing, operation and communications
software.
The MAXUM edition II gas chromatograph is divided into three
sections depending on the version:
• The upper section contains the electronics with the power
supply, controllers and analog electronics
• The middle section contains the pneumatics and some of the
detectors (not with MAXUM edition II modular oven version)
• The bottom section contains the oven and the complete
analytical components responsible for the separation
The MAXUM edition II is available prepared for wall mounting or
for free mounting on a rack.

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Process Gas Chromatographs


MAXUM edition II

Liquid injection valve FDV Live injection add-on part


A constant quantity of a liquid sample can be automatically Flexible selection of the injection volume which is exactly
injected using the liquid injection valve, and subsequently matched to the analytical tasks and the requirements of the
vaporized rapidly and completely. The valve can also be used to columns is possible with the live injection add-on part.
inject small volumes of gas.
The liquid injection valve consists of three sections: Carrier gas
• Thermostatically-controlled vaporization system
• Sample passage section with seal PCG
• Pneumatic drive

NV- NV+

Air
SV1

3
Q+ Q-

Sample
DV

A Sample
Carrier gas

Heating
NV1 WLD
R
M

Split

NV Needle valve DV Injection valve


SV Solenoid valve A Live switching
PCG Pressure regulator

Live injection
Liquid injection valve FDV
Features:
• Vaporization temperature 60 to 350 °C
• Injection volume 0.1 to 9.5 l
• Sample temperature -20 to +150 °C
• Material of parts wetted by sample: Stainless steel, mat.
no. 1.4571, Hastelloy, Monel or special materials
• Control pressure 400 to 600 hPa
• Max. sample pressure 6 000 kPa, recommended 50 to
100 kPa
• Connections for pipe: 3.14 mm (1/8") outer diameter

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Process Gas Chromatographs


MAXUM edition II

Oven temperature is continuously increased according to a selectable


heating-up rate. This method (PTGC) is available with the
A further important factor for the separating performance is the MAXUM edition II.
temperature This has a very high influence on the vapor
pressure of the individual components, and thus on the diffusion The internal oven consists of a chamber with low thermal
and the distribution equilibrium between the mobile and capacity located within the standard oven. It contains the
stationary phases in the column. This influences the retention capillary column used for the separation.
times, and thus the identification of components. Therefore very
high demands are placed on the temperature stability and The ovens have separate, independent temperature control. The
repeatability of the oven and also on that of the injection temperature of the internal oven is freely-programmable. The
equipment and the detectors. temperature changes according to the time-dependent profile
assigned to the respective analysis. Up to three linear ramps
Two different types of oven are available: and four constant periods can be configured.
Airless oven for extremely stable isothermal oven temperatures It is then possible to determine components with low and high
(0.02 °C control accuracy) up to 80 °C (modular oven) or 280 °C boiling points in one analysis. Existing laboratory applications
depending on the version. can be opened up by PTGC for use in the process industry.
Airbath oven for "Simulated distillation" is an important application of PTGC in
• isothermal (5 to 225 °C) or refineries. The distillation range - a quality criterion for fuels - is

3 • temperature-programmed mode
chromatographically traced "online".
Columns
Both types of oven are available as
• single ovens or The columns are the central component of the chromatograph.
They resolve the gas mixture or the vaporized liquid into its
• dual ovens. individual components. The following distinction is made:
With the dual ovens, two separate heating circuits provide • Packed/micropacked columns with inner diameter of 0.75 to
independent oven temperatures. It is then possible to use two 3 mm
different temperatures for the respectively installed columns for • Capillary columns with inner diameter of 0.15 to 0.53 mm
one application or to carry out two or more applications in one
chromatograph with different temperatures for the separation. Packed columns are mechanically stable and simple to handle.
Capillary columns have a significantly higher separating perfor-
In order to measure sample components with highly different mance, often with a shorter analysis period and lower analysis
volatilities, a temperature program is frequently used for the temperature.
chromatographic separation. In this case the column

Packed columns Internal diameter 0.75 ... 3 mm


Geometry
Capillary columns Internal diameter 0.15 ... 0.53 mm
(narrow, normal and wide bore)

narrow-bore 0.15 mm

Packed column 3 mm
narrow-bore 0.32 mm

wide-bore 0.53 mm

Solid stationary phases Adsorptive change effect


Filling
Liquid stationary phases Distribution, solubility

Types of column

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Process Gas Chromatographs


MAXUM edition II

Column switching systems Model 11 6-port valve:


Process chromatographs are almost always equipped with • Can be used as gas injection valve, liquid injection valve or for
column switching functions. Column switching is understood to column switching
be the combination of several columns in the carrier gas path • Membrane controlled by tappet
which are arranged in succession or parallel. These columns • One million switching cycles without maintenance
usually have different separating performances, and are inter-
connected by valves for switching over the gas path. Valveless switching technique
A distinction is made between backflushing, cut and distribution.
The valveless live column switching is exactly controlled by
A wide range of techniques is available for column switching. electronic pressure regulators, and prevents falsification of
results since the sample does not come into contact with valves.
The techniques comprise highly stable membrane gas valves, A special pressure-controlled coupling element connects the
membrane piston valves, sliding vane rotary valves and also capillary columns.
valveless switching techniques.
This technique is optimally suitable for capillary columns, and
Valves offers the best long-term stability and reliability. Live column
Model 50 10-port valve: switching is a technique where backflushing, cut or distribution
• Combined gas injection and backflushing valve is carried out on two different columns without any switching of
valves or other moving components in the separation path.
• Activation by pressure on the membrane without moving parts
• Switches gas samples at an overpressure of 0 to 500 kPa
This is achieved using a unique coupling unit, the live T-piece. 3
Its function is based on pressure difference control regulated by
• Can be used as gas injection valve or for column switching the electronic precision pressure controllers of the MAXUM
(6-port connection) edition II. Because there is no dead volume whatsoever, it is
• > 3 million switching cycles without maintenance ideally suitable for the low flow rates used with capillary
columns. Maintenance of the column switching configuration is
then superfluous, the separating performance is improved, and
complicated separating procedures are simplified.

D D D D D D D

Straight forward Backflushing Backflushing Cut Distribution


summation
(one detector) (two detectors)

Column switching systems (examples)

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© Siemens AG 2014

Process Gas Chromatographs


MAXUM edition II

&RQWUROJDV

6DPSOHJDV

3
Live switching
Solenoid valve control module Detectors
• Contains all control elements in one module in order to reduce Thermal conductivity detectors (TCD) and flame ionization
downtimes during repairs to a minimum detectors (FID) are mainly used in process chromatography.
• Has 3-way and 4-way distributors for control of many different Specific detectors such as flame photometer detector (FPD),
types of valve electron capture detector (ECD), photo-ionization detector
• Uses separate, plug-on pipe connectors to permit implemen- (PID), or helium ionization detector (HID) are used to a lesser
tation of variable gas supplies extent.

Electronic pressure controller module (EPC) The detector modules described above can be combined
together in many different manners in the MAXUM edition II.
• Permits exact control of pressure without mechanical pressure
regulator. Shortens the setup time since the pressure is set by • A maximum of three detector modules can be used in the
an operator input. airbath oven.
• Permits programmable pressure changes for fast chromatog- • Up to three modules (depending on the type) can be used in
raphy and modern applications. the airless oven, the dual airless oven and the ovens with
temperature programming.
• Controls the supply of carrier gas and combustion gas. Avoids
drift and deviations which can occur with mechanical • Thermal conductivity detectors (TCD) are used in the modular
pressure control. oven system.
• In the case of multiple modules such as the TCD, the
measuring cells can be operated in parallel at offset times in
order e.g. to increase the number of analyses within a specific
time.
• Multiple modules can each be used with a column system for
one sample stream. This shortens the total cycle time with
multi-stream applications.
• Parallel use of two identical column systems provides
redundant measurements which can be compared with each
other, thus reducing the necessity for calibration.

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Process Gas Chromatographs


MAXUM edition II

Detector Measured value Selectivity Application example


dependent on:
Concentration Universal Main and subsidiary
components

Mass flow Thermally ionizable com- Hydrocarbons


ponents at < 1 000 °C

Mass flow Substances containing Traces of sulfur in HC matrices


S or P

Mass flow Universal Ultra-pure gas analysis


(except He and Ne)

3'+,'

Mass flow Molecules with Traces of halogenated


electronegative groups hydrocarbons

3'(&'

Mass flow Selective, dependent on Traces of aromatic compounds,


ionization potential amines

3'3,'

Suitable detectors for process gas chromatography

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© Siemens AG 2014

Process Gas Chromatographs


MAXUM edition II

Thermal conductivity detectors (TCD) Pulsed discharge detector (PDD)


The measuring principle of the TCD is based on the difference The detector can be used in three different versions: HID (helium
between the thermal conductivity of a pure carrier gas stream ionization detector), ECD (electron capture detector) and PID
and that of a gas mixture containing carrier gas and a (photo ionization detector). Installation in the Maxum GC is
component eluted from the column. Therefore all components possible without further modification, and the detector can only
whose thermal conductivity differs from that of the pure carrier be used in non-hazardous areas. The PDD uses stable, pulsed
gas can be detected by a TCD. DC discharges in helium as the ionization source. The detector's
performance data is equal to or better than that of detectors
TCDs always consist of one to three measuring cells and one or which use radioactive ionization sources. Since a radioactive
two reference cells which are electrically heated and contain source is not used, the complex directives for radiation
wire resistors or thermistors connected in a Wheatstone bridge. protection need not be observed by the customer.
The amount of heat transferred to the cells is the same as long • PDHID (helium ionization detector)
as pure carrier gas flows through the measuring and reference The PDHID works almost destruction-free with an ionization
cells. The resistances are therefore also very similar, and the rate of 0.01 to 0.1 %, and has a high sensitivity. The sensitivity
bridge resistors are balanced. If a mixture of carrier gas and for organic components is linear over five orders of
sample component flows through the sample chamber, the magnitude, and the detection limit is in the low ppb range. The
change in thermal conductivity of the gas mixture also changes PDHID can be used universally for organic and inorganic
the amount of heat transferred and thus the temperature and
3
components, with the exception of helium and neon.
resistance of the heating wires or thermistors in the sample
chamber. • PDECD (electron capture detector)
In electron capture mode, sample components with a high
The resulting offset in the bridge circuit is directly proportional to electron affinity can be selectively detected, such as haloge-
the current concentration of the sample component in the carrier nated hydrocarbons. The detector's properties and sensitivity
gas stream. are comparable with those of a 63Ni ECD. It is necessary to
use a supplementary gas in this mode (recommended:
Versions of TCDs: 3 % xenon in helium).
• Thermistor detector • PDPID (photo ionization detector)
• Filament detector A supplementary gas must also be used in this mode.
Both detectors are available for universal use, and the filament Addition of 1-3 vol% of argon, krypton or xenon to the auxiliary
detector can also be used at higher temperatures. The therm- gas leads to kinetic excitation of the added gas. The detector
istor detector is available as a block with 6 measuring detectors is used in this configuration for selective detection of aliphatic
and two reference detectors. The filament detector has a compounds, aromatic compounds and amines. The selec-
measuring cell and a reference cell. tivity or energy level can be determined through the choice of
added gas. The sensitivity in this mode is limited to sample
Flame ionization detector (FID) components whose ionization potential is below the kinetic
emission energy of the added gas.
With the flame ionization detector (FID), the gas leaving the
column is burnt in a constantly burning hydrogen flame. If this Accessories: Catalytic air purifier
gas mixture contains thermally ionizable components, e.g.
flammable organic compounds, ions are generated when the Instrument air is usually contaminated by traces of hydro-
compounds are burnt. These ions can transport charges which carbons. If this air is used as the combustion gas for a flame
change (increase) the conductivity of the gas in the vicinity of the ionization detector (FID), the impurities are evident as disturbing
flame. In order to measure the conductivity or the number of background noise.
ions, these can be collected at an electrode. The catalytic air purifier eliminates interfering impurities of hydro-
An electrode voltage is applied between the nozzle from which carbons in the combustion air for the FID detector. The products
the flame burns and the electron collector positioned above it. of the catalytic oxidation (H2O, CO2) have no influence on the
detector. Use of the catalytic air purifier significantly reduces the
The resulting current is amplified, and is the measured signal. background noise. It has a flameproof enclosure and is therefore
explosion-proof.
In contrast to the TCD (concentration-dependent signal), the
signal with the FID is proportional to the mass flow of the compo- The air within the purifier is passed through a spiral lined with
nents. palladium. This metal spiral is heated up to approx. 600 °C.
Palladium has a high activity at this temperature, and almost
The FID features a linear range of 6 to 7 powers of ten, and complete catalytic oxidation is achieved despite the short dwell
permits detection limits of less than 0.1 ppm (referred e.g. to the time. The air subsequently passes through a cooling loop, and
concentration of the hydrocarbon in the sample). Non- is output purified and cooled.
flammable components or those which only thermally ionize with
difficulty (e.g. inert gases and water), or components which do Parallel chromatography
not indicate thermal ionization at approx. 1 700 °C, cannot be
measured with the FID. This function divides a complex application into several simple
sub-applications which are analyzed in parallel. This reduces
In addition to the carrier gas, hydrogen and air are required as the cycle times.
the flame gases to operate this detector.
The hardware and software of the MAXUM edition II allows a
Flame photometer detector (FPD) complex chromatographic analysis to be divided into several
Further detector principles are used for determination of trace simple analyses. Each of these simple analyses can then be
concentrations of specific components. For example, the flame simultaneously executed in parallel. This not only simplifies the
photometer detector is used to determine traces of compounds complete analysis, it can also be carried out faster and with
containing sulfur or phosphor. The emission of light of character- greater reliability. In addition, maintenance of the simplified
istic wavelengths is measured when burning the substances in analyses is easier and faster.
a reducing hydrogen flame.

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Process Gas Chromatographs


MAXUM edition II

State-of-the-art communication Compatibility


TCP/IP communication and standard Ethernet hardware mean MAXUM edition II is compatible with all older types of chromato-
that MAXUM edition II is compatible with many networks. graph from Siemens: Advance Maxum.
Software Application
For simple operation and maintenance, MAXUM edition II offers Certain parameters must be observed during application and
an online software system with local operation over an HMI and subsequent operation of the MAXUM edition II. It can then be
a flexible GUI accessible using a computer workstation. determined qualitatively whether the task is fulfilled. The basic
The online software system is installed in every MAXUM edition II prerequisite for this is that all components can be detected and
or NAU and includes: clearly isolated from the interfering components. Important
parameters are: Analysis period, measuring ranges, detection
• Embedded EZChrom evaluation limits and repeatability of the results.
• Embedded MaxBasic in the runtime version
• Communications software, network software, I/O driver in
order to operate the gas chromatograph
The PC Workstation Software Gas Chromatograph Portal
comprises:
• MAXUM edition II workstation tools: 3
• NetworkView to provide an overview of the network
• Method builder
• MMI maintenance panel emulator
• Data logger
• Modbus utility
• Backup and restore utilities
• Online system download utilities
• Online help and documentation
and optional packages for individual ordering, e.g.:
• MaxBasic editor
• Simulated distillation method
• OPC communications server

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Process Gas Chromatographs


MAXUM edition II

■ Technical specifications
MAXUM edition II classic oven Configuration
General Oven options • Single isothermal oven or divided
oven with two independent isother-
Smallest measuring ranges • Thermal conductivity: mal zones
(depending on application) 0 ... 500 ppm • Single oven or two independent,
• Flame ionization: 0 ... 1 ppm airless ovens. The dual version has
Temperature range in oven Application-specific, depending on two separate oven areas with sep-
temperature class 5 ... 350 °C arate doors which operate com-
depending on oven version and pletely independently.
temperature class Detector modules for Thermal conductivity, flame ioniza-
Temperature control ± 0.02 °C tion, flame photometry, helium ion-
ization, photo-ionization and
EMI/RFI design • CE-compatible; certified accord- electron capture
ing to 2004/108/EC
(EMC directive) Number of detector modules • 1, 2 or 3 in any combination of
• CE-compatible; certified detector module types for airbath
according to 2006/95/EC ovens
(low-voltage directive) • 1, or 2 in any combination of detec-

3
• Tested according to tor module types for airless ovens,
EN 61010-1 / IEC 1010-1 up to 3 in special configurations

Calibration Comparison measurement with Sampling and column valves Diaphragm valves, diaphragm pis-
external standard ton valves, sliding vane rotary
• Type Manual or automatic valves, slider valves, or liquid injec-
tion valve
• Zero value Automatic baseline correction
• Span Standard sample cylinder (single or Valveless option Live switching
multipoint calibration possible) Columns Packed, micropacked or capillary
Design, enclosure columns

Mounting • Spacing on left: 460 mm from walls Regulation of gas supply Up to 8 electronic pressure regula-
and other devices tor channels and up to 6 mechanical
• Spacing on right: 460 mm in all pressure regulators
cases Electrical characteristics
• Spacing at front: 654 mm in all
cases Power supply • Single-phase AC, 100 ... 130 V
• Wall-mounted units or 195 ... 260 V (selectable),
• Center-to-center: 1 120 mm in all 47 … 63 Hz
cases • Single oven: max. 14 A
• Dual oven: 2 circuits,
Weight 77 kg max. 14 A each
Degree of protection IP54, Category 2 Gas inlet conditions
Danger class Standard configurations: Sample flow 5 ... 100 ml/min (depending on
• Certified according to ATEX with application)
air or nitrogen purging for Zones 1
and 2 (EEx pyedmib IIB + H2) Sample filter size 0.1 ... 5 µm with gaseous samples
• Suitable for use in non-hazardous depending on type of valve
areas and with non-dangerous Max. 0.3 µm with liquid samples
conditions
• Certified according to CSA C/US Minimum sample pressure 35 kPa, standard
for use in Class 1, Div. 1, Groups Maximum sample pressure 200 kPa standard, higher pressure
B, C, D with air or nitrogen purging as option
• Certified according to CSA C/US
for use in Class 1, Div. 2, Groups Maximum sample temperature 121 °C standard; higher tempera-
B, C, D. ture as option
Important note! Materials wetted by sample Stainless steel and Teflon; other
Use in non-hazardous areas materials as option
requires purging of the electronics Liquid injection (valve)
area with air or nitrogen.
PDD is not certified for hazardous Vaporization temperature 60 ... 350 °C depending on applica-
areas. tion and temperature class
Injection volume 0.1 ... 9.5 l
Sample temperature -20 ... +150 °C
Material of parts wetted by sample Stainless steel, mat. no. 1.4571,
Hastelloy, Monel or special materials
Control pressure 400 ... 600 kPa
Sample pressure Max. 6 000 kPa, recommended
50 ... 100 kPa
Connections for pipe 3.14 mm (1/8") outer diameter

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Process Gas Chromatographs


MAXUM edition II

Measuring response Climatic conditions


Sensitivity (depending on application) ± 0.5 % of span Ambient temperature -18 ... 50 °C
application-dependent
Linearity (depending on application) ± 2 % of span
Gas supply
Effects of vibrations Negligible
Instrument air • At least 350 kPa for units with
Repeatability in % of full span between 2 and 100 %: ± 0.5 %; valves Model 11 or Valco
0.05 and 2 %: ± 1 %; • At least 825 kPa for units with
50 and 500 ppm: ± 2 %; valves Model 50
• At least 175 kPa for airbath ovens;
5 and 50 ppm: ± 3 %; 85 l/min per oven
0.5 and 5 ppm: ± 5 % • No instrument air for fan-free ovens
Detection limits See detectors Carrier gas • Nitrogen or helium in compressed
gas cylinder, purity 99.998 %, or
Influencing variables hydrogen with a purity of 99.999 %
Effects of ambient temperature None with electronic pressure con- (depending on application).
trol • Typical consumption quantity:
5 100 l/month per detector module
Different effects with mechanical
pressure control (depending on Combustion gas • Hydrogen with a purity of 99.999 %

3
application) • Typical consumption quantity:
2 000 l/month per detector
Electrical inputs and outputs module
Standard input and output • 2 analog outputs; Combustion air • Reference air (< 1 ppm THC,
• 4 digital outputs (1 for output of O2 concentration 20 … 21 %).
system faults, 3 are user-configu- Supply through instrument air with
rable); catalytic purification (optional).
• 4 digital inputs; • Typical consumption quantity:
• 3 serial outputs 26 000 l/month
Card slots for optional inputs and 2 Corrosion protection • Purging with dry air to protect the
outputs via internal I2C bus electronics
• Air bath oven with stainless steel
Input and output cards A IO 8: 8 analog outputs, 8 analog
lining
inputs, 2 digital inputs
• Airless oven made of aluminum
D IO: 6 digital inputs and 8 digital • Steel lining painted on outside
outputs (epoxy powder coating)
AD I/O: 4 digital inputs and 4 digital Communication
outputs, 4 analog inputs and 4 ana-
log outputs Serial output RS 232, RS 485, e.g. Modbus
Digital inputs Optocoupler with internal power Ethernet Standard 10/100 BaseT Ethernet
supply (12 … 24 V DC); switchable with 4 RJ 45 connectors
by dry contacts. e.g. Modbus TCP IP or OPC
Alternative: switchable by external Optional
power supply 12 … 24 V DC (only ESBF board
dry relay contacts), external power
supply, negative connection linked Fiber-optic 100Base FX multimode
to ground, for a specific digital with ST connection
input. 3 x RJ45 and 1 x optical or
Digital outputs Dry changeover contacts, max. con- Scalance network components e.g.
tact rating: for redundant connections.
1 A with 30 V DC.
Diode bypass suppression should
be used for inductive loads.
Analog inputs -20 ... +20 mA into 50  or
-10 ... +10 V Rin = 0.1 M, alternate
insulation up to 100 V
Analog outputs 0/4 ... 20 mA into max. 750 , com-
mon negative pole, electrically iso-
lated from ground; freely-
connectable to ground
Termination Screw terminal for shielded or solid
cable with a maximum area of
18 AWG or 0.82 mm2

Siemens PA 01 · 2015 3/13


© Siemens AG 2014

Process Gas Chromatographs


MAXUM edition II

MAXUM edition II modular oven Configuration


General Oven options Single oven or two independent, air-
less ovens. Optionally small oven for
Smallest measuring ranges • Only for gaseous sample one small analytical module, large
(depending on application) • Thermal conductivity: oven for two small analytical mod-
0 ... 500 ppm ules or one large analytical module.
Temperature range in oven Application-specific, depending on Two small ovens, two large ovens or
temperature class 60 ... 80 °C any combination of 2 ovens is possi-
depending on application tempera- ble. Each dual oven version has two
ture class T4 separate oven areas with separate
doors which operate completely
Temperature control ± 0.02 °C independently.
EMI/RFI design • CE-compatible; certified Detector modules for Thermal conductivity
according to 2004/108/EC
(EMC directive) Detectors 1 4-cell TCD for small analytical
• CE-compatible; certified modules and 1- or 2 4-cell TCD for
according to 2006/95/EC large analytical modules
(low-voltage directive) Sampling and column valves Diaphragm valves Model 50
• Tested according to small analytical module with 1 x M50
EN 61010-1 / IEC 1010-1 large analytical module with

3 Calibration Comparison measurement with 1, 2 or 3 x M50


external standard Columns Packed, micropacked or metal
• Type Manual or automatic capillary columns
• Zero value Automatic baseline correction
Regulation of gas supply Up to 6 electronic pressure regula-
• Span Standard sample cylinder (single or tor channels and up to 4 mechanical
multipoint calibration possible) pressure regulators
Design, enclosure Electrical characteristics
Mounting • Spacing on left: 460 mm from walls Power supply • Single-phase AC, 85 ... 264 V,
and other devices 47 … 63 Hz
• Spacing on right: 460 mm in all • Max. 655 VA, nominal 280 VA
cases
• Spacing at front: 654 mm in all Optional:
cases 24 V DC ± 10 % 10 A with 32 V
• Wall-mounted units voltage limiting
• Center-to-center: 1 120 mm in all
cases Max. 100 mV residual ripple and
interferences minimum to maximum
Weight 60 kg at 20 MHz
Degree of protection IP54, Category 1 Fusing at max. 20 A
External 24 V supply must accept
Danger class Standard configurations:
minus to ground
• Certified according to ATEX with
air or nitrogen purging for Zones 1 Gas inlet conditions
and 2 (EEx pyedmib IIB + H2)
• Suitable for use in non-hazardous Sample flow 5 ... 100 ml/min
areas and with non-dangerous (depending on application)
conditions Sample filter size 0.1 µm with gaseous samples
• Certified according to CSA C/US
for use in Class 1, Div. 1, Groups Minimum sample pressure 35 kPa, standard
B, C, D with air or nitrogen purging
• Certified according to CSA C/US Maximum sample pressure 200 kPa standard, higher pressure
for use in Class 1, Div. 2, Groups as option
B, C, D. Maximum sample temperature 80 °C maximum
Important note! Materials wetted by sample Stainless steel, aluminum, Viton,
Use in non-hazardous areas polyimide and Teflon
requires purging of the electronics
area with air or nitrogen. Measuring response
Sensitivity (depending on application) ± 0.5 % of span
Linearity (depending on application) ± 2 % of span
Effects of vibrations Negligible
Repeatability in % of full span between 2 and 100 %: ± 0.5 %;
0.05 and 2 %: ± 1 %;
50 and 500 ppm: ± 2 %;
5 and 50 ppm: ± 3 %;
0.5 and 5 ppm: ± 5 %
Detection limits See detectors

3/14 Siemens PA 01 · 2015


© Siemens AG 2014

Process Gas Chromatographs


MAXUM edition II

Influencing variables Climatic conditions


Effects of ambient temperature None with electronic pressure Ambient temperature -18 ... 50 °C
control
Gas supply
Different effects with mechanical
pressure control (depending on Instrument air • At least 825 kPa for units with
application) valves Model 50
• No instrument air for fan-free ovens
Electrical inputs and outputs
Carrier gas • Nitrogen or helium in compressed
Standard input and output • 2 digital outputs (1 for output of gas cylinder, purity 99.998 %, or
system faults, 1 is user-configu- hydrogen with a purity of 99.999 %
rable); (depending on application).
• 2 serial outputs, 1 x RS 232/RS • Typical consumption quantity:
485, 1 x RS 485 5 100 l/month per detector
Card slots for optional inputs and 2 module
outputs via internal I2C bus Corrosion protection • Purging with dry air to protect the
Input and output cards A IO 8: 8 analog outputs, 8 analog electronics
inputs, 2 digital inputs • Air bath oven with stainless steel
lining
D IO: 6 digital inputs and 8 digital • Airless oven made of aluminum
outputs
3
• Steel lining painted on outside
AD I/O: 4 digital inputs and 4 digital (epoxy powder coating)
outputs, 4 analog inputs and 4 ana- Communication
log outputs
Serial output RS 232, RS 485, e.g. Modbus
Digital inputs Optocoupler with internal power
supply 24 V; switchable by dry con- Ethernet Standard 10/100 BaseT Ethernet
tacts. with 2 RJ 45 connectors
Alternative: switchable by external e.g. Modbus TCP IP or OPC
power supply 12 … 24 V DC (only Optional
dry relay contacts), external power ESBF board
supply, negative connection linked
to ground, for a specific digital Fiber-optic 100Base FX multimode
input. with ST connection
Digital outputs Dry changeover contacts, 3 x RJ45 and 1 x optical or
max. contact rating: Scalance network components e.g.
1 A with 30 V DC. for redundant connections.
Diode bypass suppression should
be used for inductive loads.
Analog inputs -20 ... +20 mA into 50  or
-10 ... +10 V Rin = 0.1 M, alternate
insulation up to 100 V
Analog outputs 0/4 ... 20 mA into max. 750 , com-
mon negative pole, electrically iso-
lated from ground; freely-
connectable to ground
Termination Screw terminal for shielded or solid
cable with a maximum area of
18 AWG or 0.82 mm2

Siemens PA 01 · 2015 3/15


© Siemens AG 2014

Process Gas Chromatographs


MAXUM edition II

■ Selection and ordering data


Please contact your Siemens sales partner to order a device.

■ Dimensional drawings





s 0$;80
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3











Notes: Only for airbath oven:


Left outlet for applications with one single oven
Left and right outlets for applications with divided oven
MAXUM edition II, dimensions in mm

3/16 Siemens PA 01 · 2015


© Siemens AG 2014

Process Gas Chromatographs


MAXUM edition II

788
711 411

th|t
Œ‹›–•Gpp
\[Y

683
3
51

38

Ø7

MAXUM edition II modular oven, dimensions in mm

Siemens PA 01 · 2015 3/17


© Siemens AG 2014

Process Gas Chromatographs


MicroSAM

■ Overview ■ Application
Chemical industry
• Analysis of ethylene in 1.2-dichloroethane (EDC) for process
control
• Fast determination of nitrogen in acetylene for process control
• Hydrocarbon analysis of starting product (LPG) of a cracker
• Safety measurement of ethylene oxide during unloading of
tankers
• Multicomponent analysis in ethylene oxide
• Analysis of methanol, water and dimethylether in a pilot plant
• Monitoring of coolant: Trace monitoring in chloromethane
• Analysis of nitrogen and hydrogen in pure gas of a chlor-alkali
plant
Oil & gas
3 • Hydrogen analysis in recycled gas and other process gases
• Analysis of inert gases and low-boiling paraffins/olefins in
combustion gas
• Analysis of hydrogen and low-boiling hydrocarbons in
The MicroSAM is a miniaturized process gas chromatograph reformer/platformer plant
(GC) in an Ex d enclosure. Through consistent use of micro- • Trace analysis of impurities in acetylene from a cracker
system technology (silicon wafer technology), all analytical
components are concentrated in the smallest possible area. • Analysis of ethane in ethylene from a cracker
The design particularly enables a distributed installation close to • Measurement of calorific value in exhaust gas for quality
the process. control in a power plant
• Analysis of ethylene in methane in an ethylene plant
■ Benefits • Analysis of propadiene and propine in the C2 splitter of a
• The distributed field installation reduces investment costs, steam cracker
and opens up new fields of application, e.g.: • Analysis of low-boiling hydrocarbons in an ethylene plant/
- Installation in plant areas where mounting within an analyzer visbreaker
shed is not possible
- Installation at remote locations without extended infra- • Analysis of exhaust gas in flares
structure • Analysis of gas loop in a propylene oxide plant
• Reduction in laboratory analyses through online measure- • Analysis of CO in crack gas in an LDPE
ments (low-density polyethylene) plant
• Low space requirements in analysis cabinets reduce • Analysis of refinery gas in a pilot plant
investment costs • Analysis of calorific value in natural gas preparation plants
• Low maintenance effort and gas/energy consumption reduce
operating costs Iron & steel
• High-resolution capillary columns permit fast analyses Analysis of exhaust gas in blast furnaces.
• Live injection permits representative sample injections Pharmaceutical industry
• Maintenance-free, valveless separating column switching • Analysis of O2, N2, CO2 and water in fermenting processes
with electronic pressure controllers • Analysis of alcohols in nitrogen for vacuum drying plants
• The use of several micro thermal conductivity detectors
(multidetection) provides exact measuring results and also Metals, aggregates, cement
validation possibilities Analysis of mine gas for inert gases and hydrocarbons.
• Versatile networking possibilities for central maintenance and
secure data transfer
• Remote monitoring with Windows-based software and
Ethernet communication
• Simplified servicing through replacement of modules

3/18 Siemens PA 01 · 2015


© Siemens AG 2014

Process Gas Chromatographs


MicroSAM

The column system


■ Design
The column system consists of two or three capillary columns
Enclosure connected in sequence. Micro TCDs or micro live circuits are
• EEx d version standard installed in sequence ("inline") upstream and downstream of the
individual columns. Three electronic pressure regulators supply
• Heating adjustable from 60 to 165 °C (isothermal)
the columns with carrier gas and carry out the switching
• Decentralized installation close to sampling point functions (injection, backflushing and cut).
Analytical module By using narrow-bore capillary columns, the separation at high
resolution is carried out within a much shorter time, approx.
The compact analytical module contains all the functional
factor 2 to 3 compared to standard capillary columns.
components of a chromatograph. The MicroSAM works with:
• Live injection Electronic pressure regulators
• Valveless live switching on microchip basis A high pressure stability together with rapid changing rates in
• Standardized analytical modules the hPa range are required for precise and fast switching. This is
achieved in the electronic pressure regulators by means of a
• Multidetection through use of up to 8 micro thermal piezo actuator.
conductivity detectors (TCDs) in the smallest possible area

3
(e.g. on all column/purging outputs and injection) Detector
The micro TCDs (based on silicon wafer technology) work on the
■ Function principle of continuous measurement of the different thermal
conductivities of the carrier gas and the components to be
Live injection measured.
The MicroSAM has a two-stage injection system. Using a micro The measurement can be carried out without falsification by
injection valve, a defined quantity of sample is first brought up to avoiding catalytic effects on the heating wires and maintaining a
the carrier gas pressure. This eliminates the pressure- constant flow velocity. This permits consistent in-line detection,
dependent error in the dosing quantity present with conventional i.e. without qualitative or quantitative losses of substances.
systems. In the second stage, the sample is transferred to the
column by a valveless micro injection system (live dosing). The Application modules
result is an "active" injection.
The application modules contain live injection and live switching.
The injection volume can be varied time-controlled, and exactly The modules D06, D08 and D11 have one separating column
matched to the column requirements. less than the modules D01, D02 and D09. The modules D06,
D08 and D11 have one detector less than the modules D01 and
Valveless live column switching D02. The application modules are suitable for separation of the
Because of the high dead volume of conventional valves, only components described below. However, when defining the
the valveless version can be considered for a miniaturized suitable application module for an actual, customer-specific
system. In this case, the generation of differences in flow using measuring task, technical evaluation by our Support Team is
several electronic pressure regulators at appropriate positions of required.
the column setup causes a change in the flow directions. D01, D02 and D08:
(The system operates according to the Wheatstone principle, These modules contain separating columns that can be
but pneumatically.) The functions "Cut" and "Backflushing" can impaired in their separating performance by humidity in the
then be implemented free of dead volume. carrier gas. For this reason, a carrier gas dry filter (filter set:
Article No. A5E00400116) is integrated for these modules on the
support bracket of the MicroSAM or supplied as a separate part
as standard.
The application modules are suitable for separation of the
components described below.
Detector Column 1 Detector Column 2 Detector Circuit Column 3 Detector
D01
Injection TCD Sil5 C3, C4, C5, TCD PoraPLOT/Porabond Q TCD Live Molecular filter TCD
C6+ CO2, C2, H2S, H2O H2, (Ar+O2), N2,
C1, CO
D02
Injection TCD Sil5 C5+ TCD SilicaPLOT TCD Live Molecular filter TCD
C2, C3, C4 (saturated, H2, (Ar+O2), N2,
unsaturated), C5+ C1, CO
D09
Injection - Sil5 TCD Sil5 TCD Live Porabond Q TCD
Non-polar aromatic Non-polar aromatic All components
and aliphatic hydro- and aliphatic except molecular
carbons hydrocarbons filter components

Application modules D01, D02 and D09

Siemens PA 01 · 2015 3/19


© Siemens AG 2014

Process Gas Chromatographs


MicroSAM

Detector Column 1 Detector Circuit Column 2 Detector


D06
Injection TCD Sil5 TCD Live Sil5 TCD
Non-polar aromatic and Non-polar aromatic and
aliphatic hydrocarbons aliphatic hydrocarbons
D08
Injection TCD Porabond Q TCD Live Molecular filter TCD
All components except H2, (Ar+O2), N2, C1, CO
molecular filter components
D11
Injection TCD RTX-5+ TCD Live SilicaPLOT TCD
RTX-200 C2, C3, C4, C5, C6
Non-polar aromatic and ali- (saturated, unsaturated)
phatic hydrocarbons and
medium-pole components
such as chlorosilane

3 Application modules D06, D08, and D11


Application
Various solution concepts are available:
• Adjustment without method development (on request)
- Run-out ex factory
The application modules are standardized. The functionality
of the MicroSAM is proven with a specified carrier gas, exact
setting of the oven temperature and the carrier gas inlet
pressures, and with a standard calibration gas.
The measured components and switching functions
(live injection, backflushing, cut) are saved.
- Commissioning on site
All application modules are standardized, i.e. the analytical
hardware is defined and cannot be changed. The specific
settings are carried out on site during commissioning.
• Adjustment with method development
Non-standardized applications require specific method
development:
An optimum solution is elaborated on the basis of an existing
specification and a selected calibration gas or with appli-
cation of a customer sample.

3/20 Siemens PA 01 · 2015


© Siemens AG 2014

Process Gas Chromatographs


MicroSAM

■ Technical specifications
Design, enclosure Sample and injection
Weight 15 kg Sample streams 3
Degree of protection IP65 (NEMA 4X) Calibration sample streams 1
Mounting Phase Gaseous
Installation on Post, pipe or wall Required filtration Degree of separation 99.99 % for
< 0.1 m particles
Distance from wall or next chromato- 300 mm (12")
graph Material with which the sample comes Stainless steel, fused silica,
into contact polyimide
Distance from ceiling or floor 200 mm (8")
Injection "Valveless" live injection
Explosion protection ATEX and IEC Ex: II 2 G Ex d IIC T4
Gb • Controller With multifunctional diaphragm
valve
Class I, Zone 1, Group IIB + H2 T4 • Injection volume adjustable using 2 ... 50 µl
Class I, Div 1, Groups B, C, D T4 switching times
Factory Sealed • Max. operating temperature 165 °C

3
Support bracket Oven
• Mounting part, dimensions (D x H) 380 x 110 mm Number/type 1/isothermal
• Gas connections 8
Purging with N2 Possible
• Bracket for gas connection, dimen- 146 x 110 mm
sions (D x H), bracket on right side, Dimensions (DxH) 160 x 10 mm
mounted at right angle
Heating capacity 20 W
Electrical characteristics
Temperature range 60 … 155 °C
Power supply 24 V DC (18.5 ... 30.2 V)
Temperature stability ± 0.1 K (60 ... 155 °C)
Power consumption
Temperature accuracy ± 3 K (60 ... 155 °C)
• Typical 18 W
• Maximum 60 W Retention time variations per 10 °C Approx. 0.3 %
• Electrical safety IEC 61010 / DIN VDE 0411 change in ambient temperature

EMC immunity According to IEC 60801/ Heating-up period from 30 ... 100 °C 10 minutes
DIN VDE 0843 Columns and gases
• Conducted interferences on AC
supply lines Column type Capillary columns 0.15 ... 0.25 mm/
internal
- According to Part 4 (burst) 2 kV
- According to Part 5 (ms pulses), 1 kV Separating column switching Multidimensional chromatography
line against line with backflushing and cut in live sys-
- According to Part 5 (ms pulses), 2 kV tem
line against ground Multifunctional diaphragm valve For injection and backflushing
• Conducted interferences on signal
lines Gas connections Swagelok 1/8"
- According to Part 4 (burst) 1 kV Pressure regulators Max. 4 single-channel electronic
• Immunity to static discharge pressure regulators
- According to Part 2 (ESD) 8 kV Solenoid valves for control of dia- 2 NC contacts, 2 NO contacts
• Immunity to fields phragm valve
- According to Part 3 and Part 6 10 V/m Carrier gas H2, N2, He, Ar
• Noise suppression According to CISPR 11 / EN 55011 / • Gas purity (minimum requirement) > 99.999 % (5.0)
DIN VDE 0875 Limit class B
• Solid components < 0.1 m
• Fuse T2.5 A
• Required filtration Degree of separation 99.99 % for
Gas inlet conditions < 0.1 m particles
Permissible sample pressure 10 … 60 kPa above atmosphere • Consumption 10 ... 60 ml/min
• Inlet pressure 500 …700 kPa (g)
Sample flow 20 … 100 ml/min 600 kPa (g) recommended
Max. sample temperature 120°C Important:
A continuous carrier gas supply is
Solid components < 0.1 mm required for error-free operation (fre-
Climatic conditions quent carrier gas failure has a nega-
tive effect on the life cycle of the
Permissible ambient temperature - 20 ... 50 °C (depending on oven detectors and the internal device
temperature) pressure regulator. In addition, an
external two-layer pressure regula-
Permissible storage/transport temper- - 30 ... 70 °C
tor for the carrier gas pressure is
ature
strongly recommended.
Permissible relative humidity Max. 90 %
Instrument air Not required

Siemens PA 01 · 2015 3/21


© Siemens AG 2014

Process Gas Chromatographs


MicroSAM

Detectors, calibration and performance data


Detector type TCD, max. 8 sensors
Ambient temperature Negligible
Vibrations Negligible
Cell volume 0.02 l
Calibration Manual or automatic, single-level or
multi-level
Smallest measuring range 1 000 ppm (application-dependent)
Linear range Typically > 104
Cycle time Typically 30 … 240 s
Electrical inputs and outputs
Basic equipment
• Digital outputs 4, freely usable (expandable by
(relay contact 0.4 A / 24 V DC) NAU or I/O Extender, see Communi-
cation in "General information")

3 • Digital inputs (24 V to optocoupler) 4, 3 freely usable (expandable by


NAU or I/O Extender, see Communi-
cation in "General information")
Interfaces
• Communication 1 x Ethernet 10BaseT / TCP/IP
• Control system coupling 1 x RS 485 or RS 232 /
Modbus RTU, OPC (ODPC) over
Ethernet
Electronics
Communication and analytical
controller (CAC)
• Microprocessor Intel 586 architecture
• Flash EPROM 128 MB
• Dynamic RAM 64 MB
• Operating system Windows CE 5.0
• Software Preinstalled. Modifications or
upgrades for operation PC down-
loadable via network or locally
Realtime signal processor (RSP)
• Microprocessor Motorola 68376, 20 MHz
• Flash EPROM 1 MB
• Static RAM 1 MB
• Operating system Forth
• Software Preinstalled. Modifications or
upgrades downloadable via inter-
nal service interface
Controller
• Sample streams 3
• Calibration sample streams 1
• Status LEDs for • Supply voltage
• Software sign-of-life
• Operational readiness
• Maintenance request alert
• Fault
• Sample flow
• LCD display for • Sample stream: S1, S2, S3, S4
• Sample components: e.g. CO2,
propane, etc.
• Measured value of sample as nu-
meric value
Recommended operator panel
• Personal computer Desktop or laptop
• Processor At least Pentium III
• Clock  800 MHz
• Interfaces 1 x Ethernet
• Operating system Windows XP or 7
• Software Gas chromatograph portal,
from version 1.02

3/22 Siemens PA 01 · 2015


© Siemens AG 2014

Process Gas Chromatographs


MicroSAM

Selection and ordering data Article No.


MicroSAM process gas chromatograph 7KQ3101- 7 7 0
Basic unit, mounted on holding bracket
For 3 sample streams + 1 calibration stream
For ambient temperatures from -20 to 50 °C
Explosion-proof, for Zone 1 and Class I Div.1
Power supply 24 V DC
For post, pipe or wall mounting
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Sample
For gaseous sample 0
For gaseous sample (standard UKOG) 8
Workstation operating software
(1 workstation operating software required per GC network)
Without operating software A
With workstation operating software B

Additional versions Order code 3


Add "-Z" to Article No. and specify Order codes.
Application modules D01, D02, D06, D08, D09, D11
See description at function of application modules
Standard applications with defined hardware
Method development in the application
Standard C01
Special application1) C04
Acceptance and customer information
(in agreement with application laboratory)
Remote acceptance J01
Factory acceptance, 1 day J02
Factory acceptance, 2 days J03
Factory acceptance, 3 days J04
Repeatability test
Standard (2 hours) E01
Up to 8 hours E02
Up to 24 hours E03
Up to 72 hours E04
Data transmission
Modbus mapping (during commissioning) F01
Inputs/outputs via I/O-Extender
Separate supply of the I/O Extender module K01
(without protective casing, not for hazardous areas)
4 digital inputs, 4 digital outputs, 2 analog inputs, 4 analog outputs
Analog values via external unit (standard package 1); Zones 1 and 2 K02
4 digital inputs, 4 digital outputs, 2 analog inputs, 4 analog outputs
Analog values via external unit (standard package 2); Zones 1 and 2 K03
12 digital inputs, 12 digital outputs, 6 analog inputs, 12 analog outputs
Analog values via external unit (standard package 3); Class I Div 2 K04
4 digital inputs, 4 digital outputs, 2 analog inputs, 4 analog outputs
Analog values via external unit (standard package 4); Class I Div 2 K05
12 digital inputs, 12 digital outputs, 6 analog inputs, 12 analog outputs
Miscellaneous calculations and functions
using BASIC interpreter integrated in the GC
MicroSAM Basic Editor H01
Application setup: Calculations in accordance with ISO 6976-95 H02
Application setup: Natural gas - calculations in accordance with GPA 2172-96 H03
Application setup: Natural gas - calculations in accordance with GOST 22667-82 H04
Application setup: Natural gas - customer-specific calculations H05
1)
On request

Siemens PA 01 · 2015 3/23


© Siemens AG 2014

Process Gas Chromatographs


MicroSAM

Support bracket F01 – Data transmission over Modbus


For easy mounting, incl. support for 8 gas connections Implementation and testing of a Modbus table for Modbus
consisting of: communication (RS 232 / RS 485 RTU).
• Mounting part: Dimensions: 380 mm x 110 mm (WxH) K0X – Inputs/outputs via I/O Extender
• Bracket for gas connection;
dimensions 146 mm x 110 mm (DxH) The MicroSAM basic unit provides four digital inputs and
Bracket on right side, mounted at right angle outputs. If more interfaces are required, these are provided by
the I/O Extender. It should be noted, however, that the I/O
The bracket is stipulated in the manual. Extender requires two device-internal digital inputs and outputs.
The I/O Extender solution can generate up to 12 additional
Exception analog outputs for the chromatograph (further inputs and
The bracket is not required if the MicroSAM is fitted in a outputs on request). The latest generation of NESSI components
protective casing approved by Siemens. In this case, however, for sample preparation can also be controlled. The max. cable
shipping of the unit is only permissible in this protective casing. length between MicroSAM (including master cable) and I/O-
Extender must not exceed 20 m. A 24 V DC power supply is
Sample streams required for the I/O Extender. This must be provided separately,
For up to 4 sample streams (including calibration stream); e.g. but can also be covered by the power supply of the MicroSAM.

3
3 sample streams + 1 calibration stream; controlled by 4 internal Note:
digital outputs (relay contact 0.4 A / 24 V DC)
If the delivery is to include a protective casing from the Set CV
Pos. 8_0: For gaseous sample range, please refer to this category in Catalog PA 01. There you
This position contains a basic unit prepared for integration of the can find more information on the I/O Extender and its specifi-
analyzer modules. cation within this total solution.

Pos. 8_8: Standard UKOG K02 or K04 standard packets 1/3

Individual customers standard. This position includes:


• Mounting rail
Pos. 9_B: Workstation operating software
• An I/O Extender module
The workstation operating software can only be ordered together • Protective casing, Ex e with standard cable glands and
with MicroSAM. Workstation operating software is required for terminal block; 170 x 227 x 131 mm (L x W x D)
each gas chromatograph network.
The delivery package of the I/O Extender solution for Class I
C01 – Method development and application Div 2 contains adapters (female thread 1", 3/4", 1/2" for fitting of
Comprehensive and specific development of the method is conduits) which are suitable for cable glands in accordance with
required for the tasks. this hazardous area.
The measured components and switching functions are entered K03 or K05 standard packets 2/4
completely using a customer sample (or a specially selected
calibration gas). Proof of repeatability is carried out in accor- This position includes:
dance with the customer specification. • Mounting rail
If a natural gas analyzer for calculation of the calorific value is • Three I/O Extender modules
ordered, the evaluation parameters are specifically optimized for • Protective casing, Ex e with standard cable glands and
the natural gas analysis. terminal block; 340 x 170 x 131 mm (L x W x D)
The required BASIC programs (H0X) are installed in the gas The delivery package of the I/O Extender solution for Class I
chromatograph. Div 2 contains adapters (female thread 1", 3/4", 1/2" for fitting of
The retention time window C6+ is set to the measured compo- conduits) which are suitable for cable glands in accordance with
nents n-C6 to C9. this hazardous area.

J0X – Acceptance and customer information H0X - Various calculations and functions using
BASIC interpreter integrated in the GC
The scope of delivery is checked and the documentation and
operation of the device explained in detail during the factory The BASIC programs are either preset ex-works or can be
acceptance. created and modified by the customer.
This also comprises presentation of the analytical solution H01 – MicroSAM BASIC Editor
including communication, chromatograms, piping plan and gas The MicroSAM BASIC Editor allows individual programming of
path plan. If present, inspection of the sample preparation and calculations and functions by the user.
discussion of the documentation are carried out.
Please supplement the order for J02 to J04 by the desired option
from E0x.
Only experienced MicroSAM users should consider the option
for starting up the MicroSAM in the context of remote accep-
tance, e.g. using a telephone conference (on request).
E0x – Repeatability test
Proof of repeatability over a period of 2 h is included as
standard. Longer proof of repeatability for the unit can be
ordered using the supplements E02 to E04.

3/24 Siemens PA 01 · 2015


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Process Gas Chromatographs


MicroSAM

H02 - Application setup: Natural gas - calculation in Calibration Calibration Calibration


accordance with ISO 6976-95 gas I in gas II in gas III in
vol.% vol.% vol.%
The following physical variables must be calculated in accor-
dance with the standard: calorific value, heating value, Wobbe 1.2-butadiene – – 0.1
index, density, relative density. 1.3-butadiene – – 0.1
3 1-butene – – 0.1
The calorific value is calculated as standard in MJ/m on a molar
basis referred to the reference temperature 25 / 0 °C 2.2 dimethylpropane 0.3 0.3 –
(combustion/metering temperature). Calculation on the basis of
cis-2-butene – – 0.1
other reference variables or tables (in accordance with the
standard) requires unambiguous specification by the customer. Cyclopropane – – 0.1

The BASIC program is preset ex works; a customer modification Ethane 4 4 0.1


is only possible with the supplement H01. Ethene – – 0.1

H03 - Application setup: Natural gas - calculation in Ethine – – 0.1


accordance with GPA2172-96 Ethyl acetylene – – 0.1
The following physical variables must be calculated in accor- Helium – – Remainder

3
dance with the standard: calorific value, relative density and Isobutane 0.5 0.5 0.1
compressibility factor.
Isopentane 0.3 0.3 –
The calorific value is calculated as standard in BTU/ft3 (S) Isopentane – – 0.1
referred to the reference temperature 60 °F. Calculation on the
basis of other reference variables or tables (in accordance with Carbon dioxide 2 2 –
the standard) requires unambiguous specification by the Methane Approx. 85 Approx. 0.1
customer. 84.5

The BASIC program is preset ex works; a customer modification Methyl acetylene – – 0.1
is only possible with the supplement H01. n-butane 0.5 0.5 0.1

H04 - Application setup: Natural gas - calculation in n-heptane 0.05 0.05 –


accordance with GOST22667-82 n-hexane 0.05 0.05 0.1
The following physical variables must be calculated in accor- n-pentane 0.3 0.3 0.1
dance with the standard: calorific value, heating value, Wobbe Propadiene – – 0.1
index, relative density.
Propane 2 2 0.1
These parameters are calculated based on the physical Propene – – 0.1
properties of the pure components. As a special feature, the
methane concentration is defined as the residual value in this Oxygen 0.1 – –
operating mode. Nitrogen 5 5 –
The BASIC program is preset ex works; a customer modification trans-2-butene – – 0.1
is only possible with the supplement H01. Vinyl acetylene – – 0.1
H05 - Application setup: Customer-specific calculations and Hydrogen – 0.5 –
functions
Standard calibration gases for system test and run-out
An unambiguous description of the task is required in order to
guarantee correct functioning of the program.
The BASIC program is preset ex works; a customer modification
is only possible with the supplement H01.
The supplement H03 is only possible together with C0X.

Box with I/O Extender

Siemens PA 01 · 2015 3/25


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Process Gas Chromatographs


MicroSAM

■ Dimension drawings
156 200 70

12

300
3

20
40 34
85 306 20
L = 4 000 mm

1 5
40

220
40

4 8

D 10 (4x)

MicroSAM, dimensions in mm

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Process Gas Chromatographs


SITRANS CV

■ Overview ■ Design
Enclosure
• EEx-d version standard
• Heating adjustable from 60 to 165 °C (isothermal)
• Decentralized installation close to sampling point
Analytical modules
The compact analytical modules contain all the functional
components of a chromatograph. The SITRANS CV operates
with:
• Live injection
• Valveless live switching on microchip basis
• Standardized analytical modules
• Multidetection through use of up to 8 micro thermal

3
conductivity detectors in smallest possible areas
(e.g. on all column/purging outputs and injection)

The SITRANS CV gas chromatograph (GC), which is based on ■ Function


the innovative analytical technology of the MicroSAM, is an Live injection
analyzer that has been specially developed for natural gas
analysis. The device concept enables the higher and lower The SITRANS CV has a two-stage injection system. Using a
calorific value, standard density and Wobbe index (according to micro injection valve, a defined quantity of sample is first brought
ISO, AGA 8, Gost standard) to be determined in a way that is not up to the carrier gas pressure. This eliminates the pressure-
only cost-effective, but also quick, precise and reliable. dependent error in the dosing quantity present with conventional
systems. In the second stage, the sample is transferred to the
■ Benefits column by a valveless micro injection system (live dosing).
The result is an "active" injection.
Flexible installation: The rugged and compact design enables The injection volume can be varied time-controlled, and exactly
installation in even extreme areas of application, such as matched to the column requirements.
offshore exploration, or directly at the pipeline. The SITRANS CV
has the certification required (such as explosion protection or Valveless live column switching
splashwater protection) to meet the requirements of these appli-
cations. Because of the high dead volume of conventional valves, only
the valveless version can be considered for a miniaturized
Like the MicroSAM, the SITRANS CV consists of a basic unit and system. In this case, the generation of differences in flow using
an analysis module, which, if necessary, can be replaced in as several electronic pressure regulators at appropriate positions of
short a time as possible. Combined with low power and gas the column setup causes a change in the flow directions.
consumption, this keeps operating costs down. (The system operates according to the Wheatstone principle,
Notable features of the CVControl software, which has been but pneumatically.) The functions "Cut" and "Backflushing" can
specially developed for calibration-related applications, then be implemented free of dead volume.
includes its ease of operation and transparency. The column system
The automatic method optimization integrated in the software The separation system consists of up to three separation
increases the repeatability of the calorific value measurement columns connected in series. Micro TCDs or micro live circuits
and reduces the cost of ownership. are installed in sequence ("inline") upstream and downstream of
The serial RS 485/RS 232 and Ethernet interfaces enable the individual columns. Three electronic pressure regulators
communication with both the control system and a flow supply the columns with carrier gas and carry out the switching
computer. functions (injection, backflushing and cut).

Like the MicroSAM, the unit’s high analytical capability can be By using narrow-bore capillary columns, the separation at high
attributed to narrow-bore capillary columns, live injection, live resolution is carried out within a much shorter time, approx.
switching and in-line detection. factor 2 to 3 compared to standard capillary columns.
Electronic pressure regulators
■ Application A high pressure stability together with rapid changing rates in
• Analysis of natural gas in power plants: the hPa range are required for precise and fast switching. This is
- For quality control achieved in the electronic pressure regulators by means of a
- For turbine optimization piezo actuator.
- Pipeline monitoring
Detector
• Analysis of natural gas when opening up sea beds
(off-shore plants). The micro TCDs (silicon wafer technology) work on the principle
• Analysis of bio-natural gas in preprocessing plants of continuous measurement of the different thermal conductiv-
ities of the carrier gas and the components to be measured.
• Analysis of natural gas in liquefaction and regasification plants
(LNG Regasification and Storage) The measurement can be carried out without falsification by
avoiding catalytic effects on the heating wires and maintaining a
• Determination of calorific value in natural gas for power plants,
constant flow velocity. This permits consistent in-line detection,
in gas transfer stations, or during turbine optimization
i.e. without qualitative or quantitative losses of substances.
• Analysis of calorific value in natural gas preparation plants

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Process Gas Chromatographs


SITRANS CV

Modules
The standardized application modules generally feature live
injection and live switching functions, detectors and separation
columns.
Detector Column 1 Detector Column 2 Detector Circuit Column 3 Detector
C09 Sil5 TCD Sil5 TCD Live Porabond Q TCD
Injection Non-polar aromatic and Non-polar aromatic All components except
aliphatic hydrocarbons and aliphatic hydrocar- molecular filter compo-
bons nents
C01 TCD Sil5 TCD PoraPLOT/Porabond Q TCD Live Molecular filter TCD
Injection C3, C4, C5, C6+ CO2, C2, H2O H2, (Ar+O2), N2, C1,
CO
C13 TCD RTX-1 TCD HayeSepN TCD Live
Injection C3, i-C4, n-C4, neo-C5, N2, CH4, CO2, C2
i-C5, n-C5
Sum C6+ as sum peak

3
in the backflush

Application Component Possible working range (%)


The SITRANS CV is a storage product. Precalibration is carried Oxygen 0 ... 4
out at the factory, using helium and argon (as the carrier gas)
and a calibration gas. The measured components and switching Table 2: Measuring range of the additional measured component oxygen
of the extended calorific value analysis (see Article No. 7KQ3105-1)
functions (live injection, backflushing, cut) are saved in the GC.
The calibration process itself should be performed during The remark in footnote 1 about the detection of oxygen and
commissioning on-site. nitrogen is not valid in the case of an extended calorific value
analysis. In this case, all components from the Table 1
Measurements can be made within the following working
"Measured components and performance parameters for Pos.
ranges:
8_0 (master setup, standard calorific value analysis in accor-
Component Checked working range Possible working range dance with ISO 6976-1995)" plus oxygen are detected and
(%) (%) quantified.
Methane 57 ... 100 50 ... 100 For the analysis of biomethane the following components and
Nitrogen1) 0 ... 22 0 ... 25 their working ranges are measured (Table 3).
Carbon dioxide 0 ... 12 0 ... 20 Component Possible working range Calibration gas for bio-
Ethane 0 ... 14 0 ... 20 (%) methane measurement
(%)
Propane 0 ... 5 0 ... 15
Methane > 80 89
i-butane 0 ... 0.9 0 ... 10
Nitrogen <8 4
n-butane 0 ... 1.8 0 ... 10
Ethane <6 2.5
Neopentane 0 ... 0.1 0 ... 1
Carbon dioxide <4 2.5
i-pentane 0 ... 0.12 0 ... 1
Propane <5 1.0
n-pentane 0 ... 0.12 0 ... 1
Butane < 1.2 0.2
Hexane+2) 0 ... 0.08 0 ... 3
Oxygen <3 0.2
Hexane 0 ... 1
2-Methylpropane < 0.7 0.2
Heptane+3) 0 ... 1 (isobutane)
Octane 0 ... 1 Hydrogen <3 0.2
Nonane+4) 0 ... 1 Table 3: Measured components, working ranges and calibration gas for
Helium Concentration can be entered as a fixed value in the analysis of biomethane
the components list
H2S < 500 ppm No measured compo-
nent
High/low calorific value Calculated Calculated
Density and relative Calculated Calculated
density
Wobbe index Calculated Calculated
Compressibility factor Calculated Calculated
Normalisation factor Calculated Calculated

Table 1: Measured components and performance parameters for


Pos. 8_0 (master setup, standard calorific value analysis in accordance
with ISO 6976-1995)
1)
Any oxygen or carbon monoxide present in the sample will be detected
along with the nitrogen and, therefore, taken into account when the
nitrogen concentration is determined.
2)
Hexane+ = group(iso/n-hexane to iso/n-nonane)
3)
Heptane+ = group(iso/n-hexane) and group(iso/n-heptane to iso/n-nonane)
4)
Nonane+ = group(iso/n-hexane), group(iso/n-heptane), group(iso/n-octane),
group(iso/n-nonane)

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Process Gas Chromatographs


SITRANS CV

For analysis of natural gas with backflush summation, the Measurements within the scope of the possible working ranges
following components and working ranges are measured: (Table 1 "Measured components and performance parameters
Component Possible working range (%)
for Pos. 8_0 (Master setup, standard analysis of calorific value in
accordance with ISO 6976-1995)", right column, and Table 2
Methane 50 ... 100 "Measuring range of the additional measured component
Nitrogen 0 ... 25 oxygen of the extended analysis of calorific value (see Article
No. 7KQ3105-1)") are possible. However, checking of the
Carbon dioxide 0 ... 20
repeatability and correctness has not been carried out by the
Ethane 0 ... 20 official German body "Physikalisch technischer Bundesanstalt
Propane 0 ... 15 (PTB)".
i-butane 0 ... 10 Concentration range (mol.%) Repeatability according to ISO
n-butane 0 ... 10 6974-5 (2001); Mol fraction (%),
absolute
Neopentane*
50 < xi < 100 0.03 ... 0.035
i-pentane 0 ... 1
1 < xi < 50 0.011 ... 0.03
n-pentane 0 ... 1
0.1 < xi < 1 0.006 ... 0.011
Hexane+ 0 ... 3

3
xi < 0.1 < 0.006
Helium Concentration can be entered as a
fixed value in the component list Table 5: The repeatability of the measured components complies with
ISO 6974-5 (2001) – Annex B (Article No. 7KQ3105-0, 7KQ3105-1)
H2S No measured component
High/low calorific value Calculated The repeatability of the calorific value and standard density
achieve a relative standard deviation of < 0.01 %. SITRANS CV
Density and relative density Calculated
for the analysis of biomethane achieves a relative standard
Wobbe index Calculated deviation of < 0.05 %.
Compressibility factor Calculated The calibration gas is an extremely important factor for consid-
Normalization factor Calculated eration in terms of the MPE (maximum permissible error), and
has a significant effect on the accuracy of the overall measuring
Table 4: Component and measuring ranges for the analysis, including system. For this reason, SITRANS CV - based on a comparative
backflush summation measuring procedure - can never be more accurate than the
* Because the neopentane concentration is very small in practice, this calibration gas used. Other parameters besides the accuracy
component is not calibrated and is measured with the relative response data on the calibration gas certificate are important for the
factor of isopentane. For this reason, a possible working range is not
indicated. accuracy of a system. Examples of these include the optimum
gas composition, the ambient temperatures of the calibration
Analyses within the checked working range as well as the quality gas cylinders during transportation and operation, potential
parameters resulting from these (upper and lower calorific condensation of, for instance, higher hydrocarbons in a
values, density and relative density, Wobbe index, compression calibration gas cylinder, and the functionality of the sample
and normalization factors) correspond to the requirements listed preparation system.
below.
Under optimum conditions, the SITRANS CV achieves an MPE of
< 0.1 % for the calorific value and the standard density, whereby
the system for measuring biomethane produces an MPE of
< 0.5 %.
SITRANS CV is designed for measuring with various configura-
tions; the calibration gases required for this purpose are shown
below. (Table 6, Measurement and calibration gas components):

Siemens PA 01 · 2015 3/29


© Siemens AG 2014

Process Gas Chromatographs


SITRANS CV

SITRANS CV – Overview of possible configurations and the required calibration gases


Carrier gas He He Ar He
Analyzer module C09 C01 C01 C13
Calorific value analysis Calorific value analysis Basic Bio-CH4 Extended calorific C6+ backflush
C6+ C6+ with oxygen value analysis Bio-CH4
Calculation standard is ISO 6976, GOST and AGA 8 can be selected
Article No. 7KQ 3105-0 7KQ 3105-1 7KQ 3105-2 7KQ 3105-3
Hydrogen - - - M CR -
Oxygen - M CR M CR M CR -
Nitrogen M CR M CR M CR M CR M CR
Carbon dioxide M CR M CR M CR M CR M CR
Methane M CR M CR M CR M CR M CR
Ethane M CR M CR - M CR M CR

3 Propane
Isobutane
M CR
M CR
M CR
M CR
-
-
M CR
M CR
M CR
M CR
Butane M CR M CR - M CR M CR
Neopentane M*1 M*1 - - M*1
Isopentane M CR M CR - - M CR
Pentane M CR M CR - - M CR
Group C6+ M*2 CR M*2 CR - - -
Group C6+ backflush - - - - M*2 CR
Extended application 7KQ 3105- B02
Separate measure- M*3 CR*3 M*3 CR*3 - - -
ment of Group C6 and
Group C7+
Separate Groups C6, M*4 CR*4 M*4 CR*4 - - -
C7, C8, C9
Caution! Use of the SITRANS CV with a carrier gas different to that of the supplied solution can lead to faults and to the destruction
of the analysis module. Depending on the composition of the calibration gas, external heating for the calibration gas cylin-
der may be necessary.
M Measured
CR Required as calibration component; composition see catalog PA 01 – SITRANS CV - Function
M*1 Neopentane is measured with the response factor of isopentane;
for direct calibration of neopentane: see operating instructions
M*2 Group C6+ is measured with the relative response factor of n-hexane
M*3/CR*3 Groups C6 and C7+ are measured separately and calibrated with n-hexane and n-heptane, respectively
M*4/CR*4 Group C6, Group C7, Group C8, Group C9 are measured and calibrated separately
Table 6: Overview of device versions and available measurement configurations and the calibration gas compositions required for them

3/30 Siemens PA 01 · 2015


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Process Gas Chromatographs


SITRANS CV

■ Technical specifications
Climatic conditions
Permissible ambient temperature -20 ... +55 °C (depending on oven
temperature)
Permissible storage/transport -30 ... +70 °C
temperature
Permissible relative humidity Max. 90 %
Protection against dust and moisture
• According to EN 60529/IEC 60529 IP 65
• According to NEMA 250 NEMA 4X
Power supply
Power supply 24 V DC (18.5 ... 30.2 V)
External fuse T2.5 A
Power consumption, typical 18 W

3
Power consumption, maximum 60 W
SITRANS CV with SIMATIC Extension Unit Dimensions and weights
Width x depth x height 360 x 300 x 220 mm
(approx. 14" x 12" x 9")
Weight 15 kg (35 lb.)
Mounting
Installation on Post, pipe or wall
Distance from wall or next chromato- 300 mm (12")
graph
Distance from ceiling or floor 200 mm (8")
Electromagnetic compatibility
Noise suppression According to CISPR 11 / EN 55011 /
DIN VDE 0875 Limit class B
EMC immunity According to IEC 60801/
DIN VDE 0843
Conducted interferences on AC
supply lines
• According to Part 4 (burst) 2 kV
• According to Part 5 (ms pulses), 1 kV
line against line
• According to Part 5 (ms pulses), 2 kV
line against ground
Conducted interferences on signal
lines
• According to Part 4 (burst) 1 kV
Immunity to static discharge
• According to Part 2 (ESD) 8 kV
Immunity to fields
• According to Part 3 and Part 6 10 V/m
Safety
Electrical safety IEC 61010 / DIN VDE 0411
Explosion protection ATEX and IEC Ex:
II 2 G Ex d IIC T4 Gb
Class I, Zone 1, Group IIB + H2 T4
Class I, Div 1, Groups B, C, D T4
Factory Sealed
Oven
Number/type 1 / isothermal
Purging with N2 Possible
Dimensions (D x H) 160 x 10 mm
Max. heating power 35 VA
Temperature range 60 … 165 °C
Temperature stability ± 0.1 K (60 ... 165 °C)
Temperature accuracy ± 3 K (60 ... 165 °C)
Retention time variations per 10 °C Approx. 0.3 %
change in ambient temperature
Warm-up period from 30 … 100 °C 10 minutes

Siemens PA 01 · 2015 3/31


© Siemens AG 2014

Process Gas Chromatographs


SITRANS CV

Columns and gases Detectors, calibration and performance data


Separating column switching Multidimensional chromatography Detector type TCD, max. 8 sensors
with backflushing and cut in live
system Cell volume 0.02 µl

Multifunctional diaphragm valve For injection and backflushing Calibration Manual or automatic, single level

Gas connections Swagelok 1/8" Repeatability for calorific value and  0.01 % (for natural gas)
density
Pressure regulators Max. 4 single-channel electronic
pressure regulators Accuracy for calorific value and  0.1 % (for natural gas)
density
Solenoid valves for control of 2 NC contacts, 2 NO contacts
diaphragm valve Linear range Typically  104

Carrier gas He, Ar Cycle time Application-dependent


Notice: Ambient temperature influence Negligible
The carrier gas defined for the Mean Time to Repair/MTBF < 1 hour / 3 years
delivered state must be used. (without consumables)
Changing the carrier gas could Electronics: Communication and analytical controller (CAC)
destroy the thermal conductivity
detectors. Microprocessor Intel 586 architecture

3 • Gas purity (minimum requirement)


• Solid components
 99.999 % (5.0)
< 0.1 m
Flash EPROM 128 MB
Dynamic RAM 64 MB
• Required filtration Degree of separation 99.99 % for
0.1 m particles Operating system Windows CE 5.0
• Consumption < 35 ml/min
Software Preinstalled. Modifications or
• Inlet pressure 500 …700 kPa upgrades for operation PC down-
600 kPa (g) recommended loadable via network or locally
Important: Electronics: Realtime signal processor (RSP)
A continuous carrier gas supply is
required for error-free operation (fre- Microprocessor Motorola 68376, 20 MHz
quent carrier gas failure has a nega- Flash EPROM 1 MB
tive effect on the life cycle of the
detectors and the device-internal Static RAM 1 MB
pressure regulator). In addition, an
external two-layer pressure regula- Operating system Forth
tor for the carrier gas pressure is Software Preinstalled. Modifications or
strongly recommended. upgrades downloadable via internal
Instrument air Not required service interface

Sample and injection Interfaces

Sample streams 3 Communication 1 x Ethernet 10BaseT/TCP/IP

Calibration sample streams 1 Control system coupling 1 x Modbus RS 485/RS 232 RTU/
ASCII
Phase Gaseous
Inputs/outputs: Basic equipment
Permissible sample pressure 10 … 60 kPa above atmospheric
pressure Digital outputs 4, 3 x samples, 1 x calibration
NOTICE: Sample must not contain (relay contact 0.4 A/24 V DC)
ethine (acetylene).
Digital inputs (24 V to optocoupler) 4, for 1 = sample flow;
Sample flow 20 … 100 ml/min 2 = time synchronization;
3 = revision (results have no effect
Max. sample temperature 120 °C on average values);
Solid components < 0.1 m 4 = calibration

Required filtration Degree of separation 99.99 % Status indicator


for 0.1 m particles LEDs for • Supply voltage
Material with which the sample comes Stainless steel, fused silica, • Software Heartbeat
into contact polyimide • Ready
• Maintenance request alert
Injection "Valveless" live injection • Fault
• Controller With multifunctional diaphragm • Sample flow
valve LCD for • Sample stream: S1, S2, S3, S4
• Injection volume adjustable using From 2 ... 50 l • Sample components: e.g. CO2,
switching times propane, etc.
• Measured value of sample as
numeric value
Recommended operator panel
Personal computer Desktop or laptop
Processor At least Pentium III
Clock  800 MHz
Interfaces 1 x Ethernet
Operating system Windows XP, Windows 7
Software CV Control version 1.30.0.0 and
higher

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Process Gas Chromatographs


SITRANS CV

Selection and ordering data Article No. Notes on 7KQ3105-..


SITRANS CV process gas chromatograph 7KQ3105- 7 Support bracket
Basic unit (incl. application module)
mounted on mounting bracket For easy mounting, incl. support for 8 gas connections
Explosion-proof, for Zone 1 consisting of:
Power supply 24 V DC
For 3 sample streams + 1 calibration stream • Mounting part: Dimensions 380 x 110 mm (W x H)
For ambient temperatures from -20 ... +55 °C • Bracket for gas connection: Dimensions 146 x 110 mm
Stand-alone communication via 1 RS 485, RS 232
interface (MODBUS RTU, ASCII) (D x H), bracket on right side, mounted at right angle
For post, pipe or wall mounting Sample flow switchover
Includes CV Control operating software (English)
Click on the Article No. for the online configuration The chromatograph enables automatic selection and switchover
in the PIA Life Cycle Portal. of 3 sample flows and 1 calibration flow. The DO signal from the
gas chromatograph requires an external relay for the solenoid
Applications
valve. The sample preparation system can be ordered
For standard calorific value analysis 0 separately.
(N2, CO2, C1-C5, C6+)
Ambient temperatures
For extended calorific value analysis with oxygen 1

3
(N2, CO2, O2, C1-C5, C6+) Particularly in warmer zones, weather protection is necessary to
For calorific value analysis with biomethane 2 protect the SITRANS CV against direct solar radiation.
(N2, H2, CO2, O2, C1-C4) The chromatograph is designed as standard for temperatures
For calorific value analysis (N2, CO2, C1-C5, C6+) 3 from -20 to +55 °C. A version in a thermostatically-controlled
backflush summation casing is also available as an option for temperatures outside
these limits.
Additional versions Order code
Add "-Z" to Article No. and specify Order code Communication
Russian configuration SITRANS CV has a serial interface (RS 485/RS 232) for MODBUS
communication (RTU/ASCII). Modbus mapping can be flexibly
Russian configuration for extended calorific A01
value analysis used (see manual for more information).
Extended measuring range in combination The operator input is by means of another separate interface via
with position 8_0 and position 8_1 Ethernet (TCP/IP).
N2, C02, C1-C5, C6, C7 (+) B02 Other serial and analog (4 to 20 mA) interfaces are optionally
N2, C02, C1-C5, C6, C7, C8, C9 (+) possible using an external solution package (see Article No.
Acceptance and customer information 7KQ2160).
(in agreement with application laboratory)
Documentation
Factory acceptance, 1 day D01
The documentation includes a SITRANS CV Manual and
Factory acceptance (performance record), 1 day D02 CVControl Operating Manual in English and German. The
Factory acceptance, every additional day D03 documents can be found on the enclosed CD.
Proof of repeatability Safety manuals in all EU languages are also available on the CD.
Repeatability up to 8 h E01 CVControl operating software
Repeatability up to 24 h E02
The operating software (language: English or Russian) is
Repeatability up to 48 h E03 included in the scope of supply. Windows XP or Windows 7 must
be installed on the computer in order to install this software.
Selection and ordering data Article No.
Analog data transmission and serial interface 7KQ2160- 7 7 7 Application
External module for generation of analog and serial A general system check is made of the basic unit and the
interfaces
integrated application module. The module and basic unit are
Click on the Article No. for the online configuration in described in the manual. In addition to the standard configu-
the PIA Life Cycle Portal. ration, additional country-specific and user-specific sub-config-
Analog values via external unit (standard package) urations are available. The performance record ex works
contains the analysis check, including a repeatability record (4h
2 analog values 0
test).
4 analog values 1
The chromatograph is preconfigured; In addition, three
8 analog values 2 CD-ROMS are enclosed:
1)
16 analog values 3 • SITRANS CV Software (including manuals and CVControl
20 analog values1) 4 Operating Instructions)
MODBUS multiplexer • Country-specific sub-setups
Without multiplexer A • Parameter backup
Without CE certificate B
With CE certificate C
Enclosure
Without protective casing A
With protective casing B
1)
On request

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Process Gas Chromatographs


SITRANS CV

Article No. Pos. 8_0: Applications – Article No. Position 8_3: Applications – Calorific value analysis
Standard calorific value analysis with backflush summation
This application comprises the standard calorific value analysis. This position includes the analysis of the components listed in
The chromatograph's measurement method is set at the factory, Table 4, in which case the components starting from C6, includ-
using a synthetic natural gas mixture. The performance para- ing the isomers, are regarded as the sum peak. This variant is
meters specified in Table 5 and the criteria explained in the especially well suited for natural gases with very low content of
subsequent text apply to the individual components in Table 1 higher hydrocarbons, especially C6+.
and their physical variables.
However, this backflush summation can also be used to effec-
The calculation of the calorimetric variables is possible tively analyze natural gas with typical C6+ fractions. The compo-
according to the following standards: ISO 6976-95, GOST, nents up to and including C6+ can be analyzed within the
AGA 8, where the former is preset. The reference states for the possible concentration ranges according to Table 4.
combustion and for the gas volume that must be specified for
calculation purposes are preset to the standard state (Tb=25 °C, A01 – SITRANS CV for calorific value analysis Pos. 8_0, 8_1, 8_2
Tn = 0 °C) and can be easily changed to other reference states und 8_3 – Russian configuration
during commissioning using the operating software (Tb= This position includes the possibility for ordering SITRANS CV
operating temperature, Tn= standard temperature). with a Russian Ex certificate.
The CVControl software provides the energy units BTU/ft3, IMPORTANT: This Russian version results in a change in the
3 KWh/m3 and MJ/m3. nomenclature from SITRANS CV to MicroSAM.
Article No. Pos. 8_1: Applications – extended calorific value The following also applies to Pos. 8_3:
analysis with oxygen The limits listed in GOST Standard 31371.7-2008 are checked
This position includes the extended calorific value analysis of the during the inspection and supplied with the device documen-
components and possible working ranges from Table 1. Oxygen tation.
is measured in addition to the listed components (see Table 2). B02- SITRANS CV with extended measuring range in combi-
A carrier gas dry filter (Article No. filter set A5E00400116) on the nation with Pos. 8_0
mounting bracket of the SITRANS CV or enclosed separately is This position permits separate measurement of the group
used as standard for this measurement. isomers of the higher hydrocarbons C6 to C7(+) and C6 to C9
The remarks concerning oxygen and CO in footnote 1 of Table 1 (+). In accordance with the designation C7(+) and C9 (+), a
are no longer applicable to this position. The information detailed measurement is carried out up to and including n-C9.
concerning calculation and performance parameters are Important:
identical to Pos. 8_0.
Testing and certification of the SITRANS CV is carried out using
Important: the standard calorific value analysis in accordance with
For correct operation of SITRANS CV in accordance with Pos. Pos. 8_0. If Pos. D02 or D03 has been selected, this does not
8_0 and 8_1, all measured components must be present in the include repetition of the proof of repeatability (4 h test) of the unit
calibration gas. The calibration gases listed in the table "Recom- during the factory acceptance.
mended calibration gases for Pos. 8_0 and 8_1" are recom- The following calibration gases are essential for operation of the
mended (also see Table 6): SITRANS CV including these extended measuring ranges:
Component Pos. 8_0 (mol%) Pos. 8_1 (mol%) Required Calibration gas for C6 Calibration gas
components and C7(+) measurement for C6 and C9(+)
Oxygen 0.5
(mol%) measurement
Nitrogen 4 4 (mol%)
Carbon dioxide 1.5 1.5 Nitrogen 4.00 4.00
Methane 88.9 88.4 Carbon dioxide 1.50 1.50
Ethane 4 4 Methane 89,00 89,00
Propane 1 1 Ethane 4.00 4.00
Isobutane 0.2 0.2 Propane 1.00 1.00
n-butane 0.2 0.2 Isobutane 0.20 0.20
Neopentane 0.05 0.05 n-butane 0.20 0.20
Isopentane 0.05 0.05 Neopentane 0.10 0.10
n-pentane 0.05 0.05 Isopentane 0.05 0.05
n-hexane 0.05 0.05 n-pentane 0.05 0.05

Table 7: Recommended calibration gases for Pos. 8_0 and 8_1 n-hexane 0.05 0.05
n-heptane 0.05 0.05
A summary of the various country-specific setups, i.e. standard
settings including measured components and calibration gases, n-octane 0.05
can be found on the parameter backup CD in the "Readme.pdf" n-nonane 0.05
document.
Table 8: Components and concentrations of the calibration gases for the
Article No. Pos. 8_2: Applications – Calorific analysis with extended measuring ranges
biomethane
Further information regarding startup of SITRANS CV including
This position contains the analysis of the components and C7(+) and C9(+) measurement can be found in the manual and
working ranges of the biomethane listed in Table 3. Based on the on the enclosed document CD (country-specific setup
measured concentrations of the components, the quality param- "Readme.pdf" file)
eters – such as heating values – are determined in accordance
with the international standards ISO, GOST and AGA analo-
gously to positions 8_0 and 8_1.

3/34 Siemens PA 01 · 2015


© Siemens AG 2014

Process Gas Chromatographs


SITRANS CV

D01 - Acceptance and customer information - Factory Component Gas #1 (Mol.%) Gas #2 (Mol.%) Gas #3 (Mol.%)
acceptance, visual check, 1 day
Methane Residual Residual Residual
The scope of supply is checked and the documentation and (approx. 75) (approx. 85) (approx. 96.5)
operation of the unit explained as part of the factory acceptance Nitrogen 15.5 5 2.5
process. The factory acceptance does not include repetition of
Carbon dioxide 0.5 2 0.1
the proof of repeatability (4 h test) of the unit.
Oxygen 0.5 2 4
D02 - Acceptance and customer information - Factory
acceptance with performance record, 1 day Ethane 8 4 0.5
Propane 0.5 2 0.15
The scope of the tests to be carried out is described in Table 9
"Scope of tests during factory acceptance". When ordering D02, i-butane 0.15 0.5 0.03
please supplement the desired option from E0x. n-butane 0.15 0.5 0.03

Record of component isolation Through a final check of existing Neopentane 0.08 0.3 0.03
documentation and according to i-pentane 0.08 0.3 0.03
current chromatograms, 5 analyses
n-pentane 0.08 0.3 0.03
Stability test (repeatability) According to order E01 ... E03
Performance criteria according to Hexane 0.05 0.1 0.015

3
page 3/28 ff.
Table 10: Recommended calibration gases for linearity test during
Checking the Modbus connection Checking or simulation of Modbus acceptance
communication can be carried out
using a flow computer provided by The calibration gases have the following uncertainties:
the customer, for example.
Calculation test Comparison of the values calculated Proportions of Uncertainty (or smaller)
by CVControl with a customer com- component materials (Mol.%)
parison procedure (optional) 0.1 ... 0.25 ± 5.00 %
Auto-calibration function The two functions are explained the- 0.25 ... 1 ± 1.00 %
Auto-optimization of method oretically and practically during pre-
sentation of CVControl. 1 ... 10 ± 0.50 %
Alarm and event messages Simulation of alarm situations; 10 ... 100 ± 0.20 %
as per customer requirement
Table 11: Uncertainties of calibration gases
Table 8: Scope of test during factory acceptance
Notes on 7KQ2160-..
SITRANS CV is a standard product. Only in this manner is it
possible to guarantee short delivery times and attractive prices. Analog and serial data transmission
All performance records required retrospectively require higher SITRANS CV does not provide internal analog outputs. These
overhead. However, will will be happy to come to an agreement properties can be provided by the SIMATIC Extension Unit.
regarding implementation. This uses the Modbus output of the chromatograph in order to
D03 - Acceptance and customer information - Factory generate up to 8 active analog outputs (standard, more analog
acceptance, each additional day outputs on request).
Only in conjunction with D01 or D02 Modbus multiplexers are available in addition, and allow up to
2 Modbus masters to be connected to the SITRANS CV. The
E0x - Repeatability test distance from the SITRANS CV should not be more than
Proof of repeatability over a period of 4 h is included as 1 200 m. In the case of an installation without enclosure (without
standard. Longer repeatability records for the unit can be explosion protection), we deliver the components for generation
ordered by means of the supplementary item E0x. of analog outputs mounted on a rail, otherwise in the Ex d
enclosure.
E01 to E03 - Repeatability test, 8 h – 24 h – 48 h
Pos. 08_ 0 - 5 – Analog values via external unit
Only in conjunction with D02
This position includes:
Linearity tests can be carried out in the factory on request. The • Mounting rail
standard calibration gases required for this (Table 10: "Recom-
mended calibration gases for linearity test during acceptance") • Power supply
are provided free of charge. If the customer specifies other • SIMATIC S 7-300 and SIMATIC S7, Micro Memory Card 3.3 V
calibration gases with different compositions or higher uncer- NFLASH, 64 KB
tainty requirements, they must provide these gases for accep- • Analog output module with terminating connector
tance purposes. As an option, Siemens can procure these
special calibration gases (subject to a charge). • Protocol converter
On request, proof of the complete functionality of the Pos. 09_ A – C: Modbus multiplexer
SITRANS CV is possible within the certified temperature and (only applicable together with 0-4)
ambient conditions.
The Modbus signal can be routed using the Modbus multiplexer
and connected to two Modbus masters. B specifies supply of
the components without CE certificate.
Pos. 10_ A - B: Enclosure
This position includes the option for installation of the SIMATIC
extension unit in the hazardous area (Zone 1 and Zone 2). A
protective casing Ex d with standard cable glands including the
modules required for the analog outputs and the Modbus multi-
plexer (if applicable) are provided for this purpose.

Siemens PA 01 · 2015 3/35


© Siemens AG 2014

Process Gas Chromatographs


SITRANS CV

■ Dimensional drawings
156 200 70

12

300
3

20
40 34
85 306 20
L = 4 000 mm

1 5
40

220
40

4 8

D 10 (4x)

SITRANS CV, dimensions in mm

3/36 Siemens PA 01 · 2015


4
© Siemens AG 2014

Analytical Application Sets

4/2 Introduction

Continuous Emission Monitoring


4/3 Introduction
4/4 Set CEM CERT
4/8 Set CEM 1
4/17 Gasmet CEMS
4/30 HM-1400 TRX
Total mercury analyzer system
Dust and opacity measurement
4/32 - D-R 220 dust and opacity
measuring instrument
4/34 - D-R 290 dust concentration measuring
instrument
4/36 - D-R 320 dust measuring instrument
4/38 - D-RX 250 combination probe
Volume flow measurement
4/40 - D-FL 100 volume flow measuring system
4/42 - D-FL 220 volume flow measuring system
4/44 D-ISC 100 display and control unit for
dust and volume flow measuring instru-
ments
Environmental and process data
management systems
4/46 - D-EMS 2000
4/48 - D-EMS 2000 CS

Analysis of biogas
4/49 Set BGA

Continuous monitoring of hydrogen-


cooled generators
4/53 Set GGA

Determination of the quality of


natural gas
4/58 Set CV

Analyzer System Manager


4/68 Set ASM

Siemens PA 01 · 2015
© Siemens AG 2014

Analytical Application Sets


Introduction

■ Overview
Standardization and the supply of complete packages are two
trends that are currently on the up. This can be attributed to the
fact that the same application is frequently required in different
industrial sectors and overhead can be minimized in this case.
Furthermore, customers often want to purchase turnkey systems
to minimize the risk of any technical problems.
With its Analytical Application Set initiative, Siemens is making
use of its wealth of experience to offer standardized packages
that are designed with a single application in mind. Its range of
applications can cover a variety of industrial sectors.
It is now possible to simply configure and order complete appli-
cations straight from the catalog, thereby sharply reducing the
amount of time taken between the request and order. All Analyt-
ical Application Sets are tested in advance and provide a high
level of safety and reliability. The different versions cover a broad
spectrum of potential applications and ensure that the sets can
be configured for both minimum and maximum requirements.
The order structure makes it possible to choose from different
versions and module components, as well as configure the sys-
tem and order it directly.

4/2 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Introduction

■ Overview
The combustion of different fuels causes not only the develop- Siemens expertise in the area of products and solutions for
ment of carbon dioxide and water vapor but also other environ- process analysis helps you meet all requirements for continuous
mentally harmful exhaust gas substances (e.g. dust, nitrogen emission monitoring quickly and smoothly in accordance with
oxides and carbon monoxide, etc.) Emission limit values are de- regional law. This solution package even ensures a secure
termined for these substances according to the state of combus- investment in case of regulatory adjustments.
tion engineering. The compliance with these limits does not only
protect the environment from air pollutants but also ensures op- According to individual requirements, Siemens offers cold-ex-
timum combustion in the combustion plants. Emission measure- tractive, hot-extractive, and in-situ automated monitoring sys-
ments are a central element for complying with these limit val- tems.
ues. The portfolio is completed by emission evaluation systems for
These measurements are required to document whether legal data storage, visualization, remote transmission - permitted ac-
requirements relating to emission limits are complied with. Emis- cording to TA-Luft, 13., 17., 27., 30. and 31. BImSchV
sion measurements still serve as warranty from plant construc- Siemens does not only offer standard solutions but also com-
tors to operators that the plant runs in accordance with the spec- plete emission analysis systems, e.g. in turnkey analysis con-
ification and the law. tainers.
There are two reasons why the measuring and monitoring of flue
gases for emission components is one of the key topics in con-
tinuous gas analysis. First, because of the necessity to comply
with the legal regulations and directives. Second, because pro-
cess plant operators draw conclusions regarding process effi-
ciency from the gas analysis, for example, in boiler control.
So called Continuous Emission Monitoring Systems (CEMS) are
used for the determination of the exhaust gas components. In
Europe, they are usually called Automated Measurements Sys-
tems (AMS). DIN EN 15267 determines corresponding minimum
requirements and testing procedures for automated monitoring 4
systems for the measurement of gases and particulate sub-
stances in the exhaust gas of stationary sources as well as for
the measurement of the volume flow of the exhaust gas. It pro-
vides detailed procedures for the realization of the requirements
for the first quality assurance level (QAL1) of DIN EN 14181 and,
if required, the access data for the third quality assurance level
(QAL3).

Siemens PA01 · 2015 4/3


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM CERT

■ Overview ■ Design
Tested component design
The complete system consists of the following tested individual
components:
• Sampling probe: M&C, type: SP2000; Bühler/Siemens,
type: GAS222/7MB1943-2F
• Heated sample gas line: Winkler/Siemens, type: 7MB1943-2A
• Temperature controller: Siemens, type: SIRIUS
• Two-stage compressor gas cooler: M&C, type: CSS;
Bühler, type: EGK 2-19
• Sample gas pump: Bühler/Siemens, type: P2.3/7MB1943-3C
• NOX converter: M&C, type: CG-2; Bühler/Siemens,
type: BUENOX/7MB1943-2D
Performance-tested measuring ranges
Component Analyzer Smallest certi- Additional
module fied measur- measuring ranges
ing range
Set CEM CERT is a standardized and certified continuous emis-
sion monitoring system which is suitable for use in many plants CO (in test phase) U23-7MB2355 0 ... 150 mg/m³ 0 ... 750/
3 000 mg/m³
requiring European legislation (13. BImSchV, 27. BImSchV, TA
Luft, 2001/80/EC and IED 2010/75/EC, Annex V) approval. The (in test phase) U23-7MB2357 0 ... 150 mg/m³ 0 ... 750/
innovative CEMS meets the current quality standards of EU di- 3 000 mg/m³
rectives EN 14956, EN 15267 and EN 14181 (QAL1/2/3, AST). U23-7MB2358 0 ... 250 mg/m³ 0 ... 1 250 mg/m³

4 ■ Benefits
NO (in test phase) U23-7MB2355 0 ... 100 mg/m³ 0 ... 750/
2 000 mg/m³

• The tested measuring ranges can be selected for a variety of (in test phase) U23-7MB2357 0 ... 100 mg/m³ 0 ... 750/
2 000 mg/m³
ranges to ensure use in different areas of application for the
CEMS (TÜV approved). U23-7MB2358 0 ... 400 mg/m³ 0 ... 2 000 mg/m³
• The complete modular package allows the certified use of (in test phase) UV600 0 ... 50 mg/m³ 0 ... 100/
system components from different manufacturers (TÜV 1 000/2 000 mg/m³
approved). SO2 (in test phase) U23-7MB2355 0 ... 400 mg/m³ 0 ... 2 000 mg/m³
• Simple and fast to configure (in test phase) U23-7MB2357 0 ... 400 mg/m³ 0 ... 2 000 mg/m³
• Very low costs of procurement and operation U23-7MB2358 0 ... 400 mg/m³ 0 ... 2 000/7 000 (in
operation) mg/m³
Modular design
(in test phase) UV600 0 ... 75 mg/m³ 0 ... 130/1 500/
• Up to 2 analyzers with different measuring ranges can be 2 000 mg/m³
configured
NO2 (in test phase) UV600 0 ... 50 mg/m³ 0 ... 500 mg/m³
• Selection of versions for indoor or outdoor installation
O2, (paramag.) U23 0 ... 25 vol %
• Selection of sample gas cooler and NOX converter from
O2, (electrochem.) U23 0 ... 25 vol %
leading manufacturers
• Electric heaters and air conditioners can be configured to
extend the ambient temperature range ■ Function
• Selection of versions with appropriate sampling probes,
heated sample gas lines The complete tested modular measuring equipment is com-
posed of the sampling probe, the heated sample gas line, a two-
stage sample gas cooler, a gas pump and the multi-component
■ Application analyzers, ULTRAMAT 23 and SIPROCESS UV600.
• Emission monitoring of power plants fueled with solid, An electrochemical or a paramagnetic oxygen measuring cell
gaseous or liquid fuels can be used for the measurement of oxygen.
• Emission monitoring of so-called TA Luft plants (e.g. emission The gas path splits in parallel after the sample gas cooler. This
monitoring of glass melting furnaces or steel plants) separately supplies each analyzer with sample gas. One advan-
• Emission monitoring in crematorium facilities (27. BImSchV) tage for maintenance is that each analyzer can be individually
serviced without affecting the other. The sample gas coolers
used have a moisture alarm in case of malfunction. For addi-
tional protection, each analyzer is protected by a condensation
barrier, which stops the gas flow if moisture penetrates. This
guarantees optimum protection for gas analyzers.
For semi-automatic calibration of the zero and calibration gases,
a 3/2-way solenoid valve is installed between the first and sec-
ond cooling stages. The valve can also be used for AUTOCAL
calibration of the ULTRAMAT 23 (fully automatic timing) as well
as by the integrated PLC (LOGO module).

4/4 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM CERT

■ Technical specifications
Climatic conditions Power supply
Ambient temperature +5° ... +40 °C (standard) Supply 1 115 V AC, 50 … 60 Hz (-15 %, +10 %)
• With heater in sheet-steel Min. -5 °C Supply 2 230 V AC, 50 … 60 Hz (-15 %, +10 %)
cabinet
• With heating in GRP cabinet Min. -15 °C Supply 3 400 V AC, 50 … 60 Hz (-15 %, +10 %)
• With air-conditioning Max. +52 °C Power 4 000 VA max.
Relative humidity 75 % (annual average), non-condensing System design
Sample gas conditions Fusing of electronic consum- 1-pole or 2-pole (selectable)
Max. sample gas pressure at 500 hPa (mbar) ers
inlet to sample preparation Sample gas cooler 2-stage
system
Output signals 4 … 20 mA (corresponding to the analyzer
Max. moisture content in sam- 17 vol % (cooler type: CSS) information)
ple gas 25 vol % (cooler type: EGK 2-19)
Additional digital inputs and outputs via PLC
Sample gas temperature Max. 200 °C at cabinet entry (LOGO)
Sample gas flow Approx. 60 l/h per analyzer module Color RAL 7035
Sampling probe (standard) Dust load: < 2 g/m3 Weight Approx. 160 kg
Mounting flange: DN 65, PN 6, form B Sheet-steel cabinet/frame Indoor installation
Including temperature controller with Pt100 GRP cabinet Outdoor installation
With internal sampling tube, stainless steel, Explosion protection classifica- Installation outside the Ex zone
length: 1 m (can be shortened) tion
With filter in probe, to 600 °C Degree of protection IP 54 (avoid direct sunlight for outdoor instal-
Sampling probe for higher On request lation)
temperatures and in other
materials (optional)
Calibration Semi-automatic; AUTOCAL freely adjust-
able on U23 up to max. 24-hour interval 4
Sample gas line, electrically Max. 35 m, longer lengths on request Detailed information on the analyzers
heated
You can find detailed information on the analyzers:
Sample gas must not be flammable or explosive. • in the "Continuous Gas Analyzers, extractive" chapter
- ULTRAMAT 23
- SIPROCESS UV600
Dimensions
Sheet-steel cabinet (with base) 2 000 x 800 x 800 mm (H x W x D)
for indoor installation
GRP cabinet (with base) for 2 060 x 900 x 800 mm (H x W x D)
indoor installation
500 mm spacing on the right or left must be provided for the cable inlet and
connection of the heated sample gas line.

Siemens PA01 · 2015 4/5


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM CERT

■ Selection and ordering data


Product description Article number
Performance-tested emission measuring system (EN 15267) for the continuous emission 7MB1957- 7 7 7 7 7 - 7 7 7 0
measurement
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Rack
Sheet-steel cabinet (2 100 x 800 x 800 mm), hose/cable inlet left 0
Sheet-steel cabinet (2 100 x 800 x 800 mm), hose/cable inlet right 1
Control cabinet for outdoor installation (2 060 x 900 x 600 mm), GRP, hose/cable inlet left 4
Control cabinet for outdoor installation (2 060 x 900 x 600 mm), GRP, hose/cable inlet right 5
Sampling probe
Sampling probe type: SP2000; Manufacturer: M&C B
Sampling probe type: GAS 222; Manufacturer: Bühler C
Ventilation/cooling
Cabinet fan with outlet filter B
Cabinet air conditioner for sheet-steel cabinet C
Cabinet air-conditioner for GRP protective cabinet D
Heating
Without heating 0
Cabinet heating 1

4 Fuse protection
1-pole 0
2-pole 1
Sample gas cooler
Compressor gas cooler, type: CSS; Manufacturer: M&C 1
Compressor gas cooler, type: EGK 2-19, Manufacturer: Bühler 2
NO2/NO converter
Without NO2/NO converter A
NO2/NO converter, type: CG series; Manufacturer: M&C C
Power supply
115 V AC, -15 %, +10 %, 50 Hz A
230 V AC, -15 %, +10 %, 50 Hz B
400 V AC, -15 %, +10 %, 50 Hz (3-phase) C
Additional versions Order code
Add "-Z" to article number and then order code
Accessories
Preparation for data acquisition system, D-EMS (DURAG) A01
Preparation for dust measurement A02
Condensate tank with level monitoring A03
Acidification module (for measuring low concentrations of SO2) A04
Extractive analyzers, the analyzers must be ordered separately
Preparation for the installation of an ULTRAMAT23 C01
Preparation for the installation of two ULTRAMAT 23 C02
Preparation for the installation of a SIPROCESS UV600 C03
Preparation for the installation of two SIPROCESS UV600 C04
Preparation for the installation of an ULTRAMAT 23 and a SIPROCESS UV600 C05
Sample gas line, electrically heated (with temperature controller and circuit breaker)
Length: 5 m D01
Length: 10 m D02
Length: 15 m D03
Length: 20 m D04
Length: 25 m D05
Length: 30 m D06
Length: 35 m D07

4/6 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM CERT
Additional versions Order code
Electronic overcurrent protection for heated sample gas line
(only required when heated sample line is not selected from options D01 to D07)
Circuit breaker, 4 A, for lengths up to 5 meters D21
Circuit breaker, 6 A, for lengths up to 10 meters D22
Circuit breaker, 8 A, for lengths up to 15 meters D23
Circuit breaker, 10 A, for lengths up to 20 meters D24
Circuit breaker, 16 A, for lengths up to 30 meters D25
Circuit breaker, 20 A, for lengths up to 35 meters D26
Documentation
German N01
English N02
French N03

■ Dimensional drawings
Converter (option)

800
Option
130

200
Sample

4
gas outlet

Cable glands
VF1 ULTRAMAT 23 electrical input/output

VF2

Air conditioner
(option) SIPROCESS UV600

395
Calibration gas
2000

Air conditioner Zero gas U23


(option) Calibration gas inlets 1 to 3

Sample gas inlet

Sample gas
cooler
300

Heater
mounted on Condensate vent
the side Hinged frame 40HE
(option) right stop
100

Condensate Filter VF1 and VF2


Lateral view, right Frontal view tank (option) mounted on the back Lateral view, left
hinged frame open of the device

Figure contains options, dimensions in mm

Siemens PA01 · 2015 4/7


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1

■ Overview ■ Application
The monitoring of emission components in flue gases is one of
the most important topics for continuous gas analysis. This is a
result of legislation for monitoring emissions, e.g. for large com-
bustion plants, and also due to the requirements of companies
operating process plants who can draw conclusions on the pro-
cess efficiency from the gas analyses, e.g. with boiler control,
DENOX and DESOX plants.
The market requires a reliable complete system which is spe-
cially designed for the application. The Set CEM 1 (Continuous
Emission Monitoring) offered by Siemens is a system which reli-
ably covers all requirements associated with sampling, sample
preparation, and gas analysis.
It is possible to determine the concentrations of the gaseous
components CO, CO2, NO, NOx, SO2, O2, Ctotal, HCl, HF, NH3
and H2O.
The ULTRAMAT 23 and OXYMAT 6 are used for the extractive,
continuous gas analysis.
The Set CEM 1 is a standardized system specially for monitoring The standardized Set CEM 1 provides great clarity and simple
the emission components in flue gases. configuration facilities. Different versions mean that it is possible
to appropriately adapt the system to the requirements. Stan-
dardization also means that not all imaginable versions can be
■ Benefits included, and that it may not be possible to implement special
Standardized complete system requirements such as armored cables, varying gas composi-
tions, customer-specific documentation or specific conductor la-
4 • Highly exact and reliable monitoring of emission components
in flue gases. System-specific certificate according to
beling without an extra charge.
DIN EN ISO 14956 and QAL 1, according to EN 14181.
• Modular complete package with gas sampling system,
■ Design
sample gas preparation system and gas analyzers from one Starting with a mounting frame with sample preparation system,
source it is possible to add additional units as options. These include:
• Simple and fast to configure • Sampling probe with weather protection hood
• Tried and tested, harmonized and reliable set • Heated sample gas line (for details see catalog PA11)
• Low purchase price and economic operation • Analyzers
Proven, suitability-tested technologies • Air-conditioning unit
• Continuous determination of up to eight measured compo- • NO2/NO converter
nents • Sample preparation extension for an additional ULTRAMAT 23
• In-situ measurements without sampling and preparation, analyzer
using LDS 6 laser diode spectrometer • Single and dual (electrically isolated, not electrically isolated)
• Use of ULTRAMAT 23 with cleanable cells and automatic analog signal processing
calibration with ambient air as well as optional electrochemical • Power supply modules (115 V, 230 V, 400 V)
oxygen measurement • Outer panels with steel-plate door or with window
Optional: • Single-pole and double-pole fusing
• Paramagnetic oxygen measurement with OXYMAT 6 • Condensation bottle
Simple operation • Coalescence filter
• Intuitive operation Sampling probe
• Configuration on large displays using plain text, in several The standard probe is fitted with a DIN flange DN 65, PN 6. The
languages probe is provided with a regulated heater, and has a power con-
Simple maintenance sumption of 400 VA. It is supplied with a weather protection hood
and 2 µm filter. The maximum dust concentration at the sampling
• Maintenance-friendly cabinet design with hinged frame and point should not exceed 2 g/m³. The sampling pipe is 1 000 mm
uniform design long, is made of stainless steel, and has dimensions of 20 x
• Digital display of maintenance requests on LOGO modules 1.5 mm. The sample gas temperature must not exceed 600 °C.
It is also possible to purchase the Set CEM 1 without sample
probe.

4/8 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1
Heated sample gas line Frost protection heater
The temperature of the heated line is regulated at 200 °C by a The power consumption of the optional cabinet heater is 500 VA.
temperature controller. The power consumption is 100 VA per The delivery includes a thermostat with a power consumption of
meter. The internal core is made of PTFE 4/6. The heated line can 25 VA for controlling the frost protection heater.
be up to 35 m in length. Lengths greater than 35 m can be pro-
vided upon special request. If desired, the system can also be Fusing of the analog signals
supplied without a heated sample gas line. In addition to single-pole fusing of the electronic consumers, it is
Mounting frame possible to provide double-pole fusing.

The basis of each CEM 1 set is the mounting frame with hinged The double-pole fuse is mainly required in Benelux countries.
frame (40 HU) for installation of up to five 19" rack units. The Removal of condensation
mounting frame includes a standardized sample preparation
system designed for an ULTRAMAT 23. A 19 liter condensation bottle can be provided as an option. It is
also possible to order the system without a condensation bottle
The sample preparation system includes a 3/2-way solenoid if the condensation can be removed on-site.
valve, 3-way switchover ball valve, regulating valve, corrosion-
resistant sample gas pump (power consumption 60 VA), con- NO2/NO converter
densation trap, room air suction filter with filter element, LOGO The mounting frame and cabinets can be optionally extended by
for digital display of individual signals in the cabinet, 24 V DC a 19" rack unit with NO2/NO converter with carbon cartridge. The
power supply unit (power consumption 70 VA). Also included power consumption is 520 VA. The flow rate is 90 l/h. An NO2/
are a sample gas cooler (power consumption 200 VA) with inte- NO converter is required if the share of NO2 in the total NOx is
gral heat exchanger, hose pump, moisture sensor with flow cell greater than 5% and/or if total NOx is to be always determined.
and Teflon filter. Teflon tubes connect the components.
The external dimensions without plinth are 2 000 x 800 x 800 mm Power supply
(H x W x D). A cabinet depth of 600 mm is also optionally avail- The system can be designed either for 115 V AC, 230 V AC or
able (not suitable for LDS 6). Hoses and cables can be con- 400 V AC (-15 %, +10 %) with 50 or 60 Hz.
nected from the left or right. A distance of 500 mm must be pro-
Three phases, neutral and ground must be provided by the cus-
vided on the left or right at the installation site for introduction of
the hoses and cables. tomer at 400 V AC. 4
In addition to the sheet-steel mounting frames for indoor installa- Analog signal processing
tion, an FRP version is also available for outdoor use. The FRP As standard, the analog signals are simply connected to isolat-
cabinet is always provided complete with side panels and plinth. ing terminals. As an option, the analog signals can be pro-
The external dimensions are 2 080 x 800 x 600 mm (H x W x D). cessed twice without electrical isolation by a diode module, or
The GRP cabinet cannot be combined with the LDS 6. twice with electrical isolation.
Preparation of sample preparation system for second Analyzers
ULTRAMAT 23
The standardized set is prepared for an ULTRAMAT 23. The sys-
The standard system with sample preparation system and elec- tem can be supplemented by a second ULTRAMAT 23,
tronics is prepared for one ULTRAMAT 23. If a second OXYMAT 6 and/or LDS 6. Various measured components and
ULTRAMAT 23 is to be fitted, this option must be selected so that measuring ranges can be selected. Other combinations of mea-
the sample preparation system and electronics are extended ac- sured components and measuring ranges are available on re-
cordingly. quest, but you must check that the desired certificates and ap-
Additional filter provals are available. The analyzers, measured components
and measuring ranges used are described briefly below.
In addition to the fine filter and moisture filter which are always
present, a coalescence filter can be optionally fitted in the sam- Details on the analyzers, alternative components and ranges
ple preparation system. can be found under the topics "Continuous gas analyzers, ex-
tractive" and "Continuous gas analyzers, in-situ".
Side panels with doors
ULTRAMAT 23: CO, NO
Optional outer panels can be selected for the sheet-steel mount-
ing frames. This possibility allows use of the CEM 1 set in analy- For measuring two infrared components.
sis cabinets as a rack design on one hand, or on the other as a
Component Smallest tested measuring Switchable to
cabinet design in halls requiring degree of protection IP54. Ei- range
ther a sheet-steel door without window or a glass door can be
selected. CO 0 ... 150 mg/Nm³ 0 ... 750 mg/Nm³
NO 0 ... 100 mg/Nm³ 0 ... 500 mg/Nm³
Base
Plinths with a height of 100 and 200 mm are additionally avail- One or two measuring ranges can be freely set within the limits.
able. The ULTRAMAT 23 carries out automatic self-calibration with
ambient air. The power consumption is 60 VA.
Cabinet cooling and ventilation
Optionally available are a fan with outlet filter, an air-conditioning
unit for indoor installation, and an air-conditioning unit for out-
door installation. The system can be ordered without a fan or air-
conditioning unit if the side panels and the door with window are
omitted.
The fan with outlet filter has a power consumption of 60 VA, and
is fitted in the cabinet wall. The delivery also includes a thermo-
stat with a power consumption of 25 VA.
The air-conditioning unit has a cooling power of 820 VA.

Siemens PA01 · 2015 4/9


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1
ULTRAMAT 23: CO, NO, SO2 LDS 6: HCl / H2O
For measuring three infrared components. Component Smallest tested measuring range

Component Smallest tested measuring Switchable to HCl 0 ... 15 mg/Nm³


range H2O 0 ... 30 %
CO 0 ... 250 mg/Nm³ 0 ... 1 250 mg/Nm³
Application for channel 1: Emission monitoring
NO 0 ... 400 mg/Nm³ 0 ... 2 000 mg/Nm³
The power consumption is 50 VA. Suitable for connection of non-
SO2 0 ... 400 mg/Nm³ 0 ... 2 000 mg/Nm³
Ex sensors, including non-Ex-protected sensor electronics.
One or two measuring ranges can be freely set within the limits. The delivery includes a pair of sensors for instrument air or N2 on
The ULTRAMAT 23 carries out automatic self-calibration with the process side. The pair of sensors is designed for a moderate
ambient air. The power consumption is 60 VA. flow rate of 0 to 120 l/min. The 400 mm long purging tubes are
ULTRAMAT 23: CO, NO, CO2 made of stainless steel. The process connection is DN 65, PN 6.
The power consumption is 2 VA.
For measuring three infrared components.
Limitation:
Component Smallest tested measuring Switchable to Applies to measurement paths > 2 000 mm, applies to gases
range with a methane content < 15 mg/m³. Necessary gas temperature
CO 0 ... 250 mg/Nm³ 0 ... 1 250 mg/Nm³ between 120 and 210 °C.
NO 0 ... 400 mg/Nm³ 0 ... 2 000 mg/Nm³ LDS 6: HF
CO2 0 ... 5 % 0 ... 25 % HF: Smallest possible measuring range depends on the gas
One or two measuring ranges can be freely set within the limits. composition.
The ULTRAMAT 23 carries out automatic self-calibration with Application for channel 1: Emission monitoring
ambient air. The power consumption is 60 VA.
The power consumption is 50 VA. Suitable for connection of non-
The component CO2 has not been type approved by the TÜV. Ex sensors, including non-Ex-protected sensor electronics.
4 ULTRAMAT 23: CO2 The delivery includes a pair of sensors for instrument air or N2 on
the process side. The pair of sensors is designed for a moderate
For measuring one infrared component.
flow rate of 0 to 120 l/min. The 400 mm long purging tubes are
Component Smallest measuring range Largest measuring range made of stainless steel. The process connection is DN 65, PN 6.
The power consumption is 2 VA. The HF measurement has not
CO2 0 ... 5 % 0 ... 25 %
been type approved by the TÜV.
One or two limits can be freely set within the limits. The ULTRA- Limitation:
MAT 23 carries out automatic self-calibration with ambient air. Component has not been type approved by TÜV. Necessary gas
The power consumption is 60 VA. temperature between 0 and 150 °C.
The component CO2 has not been type approved by the TÜV. LDS 6: HF/H2O
The ULTRAMAT 23 analyzers can be optionally equipped with an HF: Smallest possible measuring range depends on the gas
electrochemical oxygen sensor. composition.
O2: Tested measuring ranges 0 to 10/25% H2O: Smallest tested measuring range 0 to 30%
OXYMAT 6: O2 Application for channel 1: Emission monitoring
For paramagnetic measurement of oxygen. Instead of The power consumption is 50 VA. Suitable for connection of non-
ULTRAMAT 23 with electrochemical cell. Ex sensors, including non-Ex-protected sensor electronics.
O2: Tested measuring ranges 0 to 10/0 to 25% The delivery includes a pair of sensors for instrument air or N2 on
Sample chamber without flow-type compensation branch, made the process side. The pair of sensors is designed for a moderate
of stainless steel 1.4571. flow rate of 0 to 120 l/min. The 400 mm long purging tubes are
made of stainless steel. The process connection is DN 65, PN 6.
LDS 6: HCl The power consumption is 2 VA. The HF measurement has not
been type approved by the TÜV.
Component Smallest tested measuring range
HCl 0 ... 15 mg/Nm³ Limitation:
Component has not been type approved by TÜV. Necessary gas
Application for channel 1: Emission monitoring temperature between 0 and 150 °C.
The power consumption is 50 VA. Suitable for connection of non-
Ex sensors, including non-Ex-protected sensor electronics.
The delivery includes a pair of sensors for instrument air or N2 on
the process side. The pair of sensors is designed for a moderate
flow rate of 0 to 120 l/min. The 400 mm long purging tubes are
made of stainless steel. The process connection is DN 65, PN 6.
The power consumption is 2 VA.
Limitation:
Applies to measurement paths > 2 000 mm, applies to gases
with a methane content < 15 mg/m³. Necessary gas temperature
between 120 and 210 °C.

4/10 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1
LDS 6: NH3 Additional LOGO for four or more 19" rack units
Component Smallest tested measuring range Sets with more than three 19" rack units integrated require a
LOGO extension module. The delivery also includes connection
NH3 0 ... 20 mg/Nm³
and programming.
Application for channel 1: Emission monitoring Core end labeling
The power consumption is 50 VA. Suitable for connection of non- It is optionally possible to order core end labeling according to
Ex sensors, including non-Ex-protected sensor electronics. the Siemens standard (VDE 0100 Part 200).
The delivery includes a pair of sensors for instrument air or N2 on
Documentation
the process side. The pair of sensors is designed for a moderate
flow rate of 0 to 120 l/min. The 400 mm long purging tubes are The Siemens standard documentation is available in German or
made of stainless steel. The process connection is DN 65, PN 6. English.
The power consumption is 2 VA.
The documentation includes gas path diagram, circuit diagram,
Limitation: terminal diagram, installation diagram, consumable materials
Applies to measurement paths > 1 250 mm. Necessary gas tem- list, signal list, cable list, and parts list. Also included are techni-
perature between 0 and 150 °C. cal data sheets and Operating Instructions for the components
LDS 6: NH3/ H2O and devices used. The documentation language for parts pro-
vided by other suppliers may deviate. Plant description, LOGO
Component Smallest tested measuring range program and test certificates are also included in the documen-
tation.
NH3 0 ... 20 mg/Nm³
H2O 0 ... 15 %
The documentation contains no customer-specific/project-spe-
cific drawings, and consists of two folders and one CD per set.
Application for channel 1: Emission monitoring
The power consumption is 50 VA. Suitable for connection of non-
Ex sensors, including non-Ex-protected sensor electronics.
The delivery includes a pair of sensors for instrument air or N2 on
the process side. The pair of sensors is designed for a moderate
4
flow rate of 0 to 120 l/min. The 400 mm long purging tubes are
made of stainless steel. The process connection is DN 65, PN 6.
The power consumption is 2 VA.
Limitation:
Applies to measurement paths > 1 250 mm. Necessary gas tem-
perature between 0 and 150 °C.
Hybrid cable
A hybrid cable is required to connect a central unit to one pair of
sensors. Versions for 5, 10, 25, 40 and 50 m are available. Cable
lengths cannot be combined. Lengths greater than 50 m can be
ordered on request.
Sensor cable
A sensor cable is required to connect one pair of sensors. Ver-
sions for 5, 10 and 25 m are available. Cable lengths cannot be
combined. Lengths greater than 25 m can be ordered on re-
quest.
Electrical preparation for dust measurement
Electrical preparation for connection of an external dust mea-
surement to the system (contains a switch amplifier).
Electrical preparation for flow measurement
Electrical preparation for connection of an external flow mea-
surement to the system (contains a switch amplifier).
Electrical preparation for pressure measurement
Electrical preparation for connection of an external pressure
measurement to the system (contains a switch amplifier).
Electrical preparation for temperature measurement
Electrical preparation for connection of an external temperature
measurement to the system (contains a switch amplifier).
Electrical preparation for emission data memory on rail
module
On request.
Electrical preparation for emission data memory in 19" rack
unit
On request.

Siemens PA01 · 2015 4/11


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1

Measuring equipment

LOGO TD

L = max. 35 m
CLF
Option NO CO/NO
Sample gas
Option Water trap
outlet
Converter U23
Option Option

Sample gas inlet SO2

U23
2nd ULTRAMAT 23 (option)

O2
LDS 6

HCL,
H2 O O6E

Option OXYMAT 6E (option)

LDS 6

4
LDS 6 (option)

19 liters
Cabinet heating
Option (option)

Calibration gas inlet Cabinet ventilation (option)


Optional
Fan/outlet filter
or air-conditioning unit

Set CEM 1, gas flow chart, figure contains options

4/12 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1

■ Function Connections
Hose material Teflon
A sample is extracted via the heated sample gas probe. The
dust concentration may be up to 2 g/m³, the sample gas temper- Cables Not armored, not halogen-free
ature up to 600 °C. The gas is transported to the analysis cabinet Electrical design According to IEC
via a heated sample gas line. The heating prevents condensate. Cable ID Individual core labeling as option
The gas cooler cools and dries the sample in the analysis cabi-
net. Condensate is drained. The level in the condensate trap is Fusing of electronic consumers 1-pole; 2-pole as option
monitored. For safety purposes, a coalescence filter can be pro- Duplication of analog signals • Not electrically isolated as option
vided in addition to the fine filter and moisture filter which are al- • Electrically isolated as option
ways present. The sample gas is analyzed by analyzers such as Installation
the ULTRAMAT 23, OXYMAT 6 and LDS 6. The ULTRAMAT 23
Site
operates on the basis of molecular-specific absorption of infra-
• In sheet-steel cabinet/frame Indoor installation
red radiation or with an electrochemical oxygen measuring cell.
• In GRP cabinet Outdoor installation
The OXYMAT 6 is an analyzer for paramagnetic oxygen mea-
surements. The in-situ LDS 6 laser diode spectrometer operates Ex zone Non-Ex area
according to the molecular-specific absorption of near-IR radia- System design
tion. The delivery may also include an NO2/NO converter which
permits measurement of total nitrogen oxides. In order to qualify Type Mounting frame or cabinet
the set for low or high temperature ranges (-5, +45 °C), it is pos- Cabinet degree of protection IP54
sible to use a cabinet heater or air-conditioning unit. Power sup- Automatic calibration Yes, with ULTRAMAT 23
ply versions are available for 115, 230 or 400 V AC. Electronic
consumers can be provided with single-pole or double-pole fus- Detailed information on the analyzers
ing. The components of the sample preparation system and the You can find detailed information on the analyzers:
analyzers are connected to LOGO modules via a binary signal, • In the "Continuous Gas Analyzers, extractive" chapter
- ULTRAMAT 23
and transmit maintenance requirements. The analog signals can - OXYMAT 6
be processed either singly or twice. Electrical isolation is addi- • In the "Continuous Gas Analyzers, in-situ" Chapter
tionally possible for the double processing. - LDS 6

■ Technical specifications
Dimensions (without plinth) 4
Depth of sheet-steel frame
• 800 mm (without plinth) 2 000 x 800 x 800 mm (H x W x D)
Climatic conditions
• 600 mm (without plinth) 2 000 x 800 x 600 mm (H x W x D)
Ambient temperature 0 ... 35 °C
GRP cabinet (with plinth) 2 080 x 900 x 600 mm (H x W x D)
• With heater in sheet-steel cabinet Min. -5 °C
• With heating in GRP cabinet Min. -15 °C It is necessary to provide a 500 mm gap to the right or left for the
• With air-conditioning Max. 52 °C tube or cable inlet.
Relative humidity 70 %, non-condensing Use of the LDS 6 requires a cabinet with a depth of 800 mm.
1)
Corrosive atmosphere No Higher performance sample gas coolers can be offered upon request (not
TÜV suitability-tested). A higher performance cooler is generally required
Gas inlet conditions for high sulfide content in fuels (e.g. heavy oil).
Max. sample gas pressure at inlet to 500 hPa (mbar)
sample preparation system
Max. moisture content in sample gas 17 vol-% 1)
Max. water dew point 60 ?
Min. sample gas pressure at inlet to 180 °C
sample preparation system
Dust content at inlet to sample prepa- Dust-free
ration system
Sampling probe Sampling tube 20 x 1.5,
1 000 mm long, stainless steel,
flange: DN 65, PN 6
Max. sample gas pressure at sam- 500 hPa (mbar)
pling probe
Max. sample gas temperature at sam- 600 °C
pling probe
Max. dust content at sampling probe 2 g/Nm³
Sample gas must not be flammable or explosive.
Power supply
Supply 1 115 V AC (-15 %, +10 %)
Supply 2 230 V AC (-15 %, +10 %)
Supply 3 400 V AC (-15 %, +10 %)

Siemens PA01 · 2015 4/13


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1
Selection and ordering data Article No.
Set CEM 1 – Continuous Emission Monitoring 7MB1953- 7 7 7 7 7 - 77 7 7 Cannot be combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Rack
Rack 1: 2 000 x 800 x 800 mm (H x W x D), with sample preparation device, 0 A03, A04, B02, B04
with hinged frame 40 HU, hose/cable inlet on left side, with lighting, prepared
for 1 x ULTRAMAT 23, max. five 19" rack units possible
Rack 2: 2 000 x 800 x 800 mm (H x W x D), with sample preparation device, 1 A03, A04, B02, B04
with hinged frame 40 HU, hose/cable inlet on right side, with lighting, prepared
for 1 x ULTRAMAT 23, max. five 19" rack units possible
Rack 3: 2 000 x 800 x 600 mm (H x W x D), with sample preparation device, 2 A01, A02, B01, B03,
with hinged frame 40 HU, hose/cable inlet on left side, with lighting, prepared E01 ... E06,
for 1 x ULTRAMAT 23, max. five 19" rack units possible, not suitable for LDS 6 F01 ... F06,
G01 ... G04
Rack 4: 2 000 x 800 x 600 mm (H x W x D), with sample preparation device, 3 A01, A02, B01, B03,
with hinged frame 40 HU, hose/cable inlet on right side, with lighting, prepared E01 ... E06,
for 1 x ULTRAMAT 23, max. five 19" rack units possible, not suitable for LDS 6 F01 ... F06,
G01 ... G04
Rack 5: 2 060 x 900 x 600 mm (H x W x D), GRP, base 80 mm, with sample prepara- 4 A01 ... A04,
tion device, with hinged frame 40 HU, hose/cable inlet on left side, with lighting, pre- B01 ... B04,
pared for 1 x ULTRAMAT 23, with side panels, incl. door with window, max. five 19" E01 ... E06,
rack units possible, not suitable for LDS 6 F01 ... F06,
G01 ... G04
Rack 6: 2 060 x 900 x 600 mm (H x W x D), GRP, base 80 mm, with sample prepara- 5 A01 ... A04,
tion device, with hinged frame 40 HU, hose/cable inlet on right side, with lighting, B01 ... B04,
prepared for 1 x ULTRAMAT 23, with side panels, incl. door with window, max. five E01 ... E06,

4 19" rack units possible, not suitable for LDS 6 F01 ... F06,
G01 ... G04
Sampling probe
Without A
Standard sampling probe B
Ventilation/cooling
Without A
Fan with outlet filter B
Cabinet air-conditioning unit C
Cabinet air-conditioning unit for GRP rack D
Heating
Without 0
Cabinet heating 1
Fuse protection
1-pole 0
2-pole 1
Removal of condensation
Without 0
19 l container with level monitoring 1
NO2/NO converter
Without A
NO2/NO converter B
Power supply
115 V AC, -15 %, +10 %, 50 or 60 Hz A
230 V AC, -15 %, +10 %, 50 or 60 Hz B
400 V AC, -15 %, +10 %, 50 or 60 Hz (3 phases, neutral, ground provided C
by customer)
Connection set for heated line
Without controller 0
Standard controller (max. 35 m heated line can be connected) 1
Note:
The heated sample gas line must be ordered separately using Catalog PA 11.

4/14 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1

Additional versions Order code


Add "-Z" to Article No. and specify Order code
Bases
Base for rack 1, 2, height 100 mm A01
Base for rack 1, 2, height 200 mm A02
Base for rack 3, 4, height 100 mm A03
Base for rack 3, 4, height 200 mm A04
Rack accessories
Outer panel painted, for rack 1 and 2, viewing door B01
Outer panel painted, for rack 3 and 4, viewing door B02
Outer panel painted, for rack 1 and 2, sheet steel door B03
Outer panel painted, for rack 3 and 4, sheet steel door B04
ULTRAMAT 23, OXYMAT 6 extractive analyzers
ULTRAMAT 23: CO, NO C01
ULTRAMAT 23: CO, NO, SO2 C02
ULTRAMAT 23: CO, NO, CO2 C03
ULTRAMAT 23: CO2 C04
ULTRAMAT 23: Electrochemical O2 sensor for ULTRAMAT 23 expansion C05
OXYMAT 6: OXYMAT paramagnetic O2 analyzer C06
Preperation for free choice ULTRAMAT 23 analyzer C07
Additional sample preparation components 4
Coalescence filter D02
LDS 6 in-situ analyzers
HCl including sensor pair E01
HCl/H2O including sensor pair E02
HF including sensor pair, not suitability-tested E03
HF/H2O including sensor pair, not suitability-tested E04
NH3 including sensor pair E05
NH3/H2O including sensor pair E06
LDS 6 hybrid cable per LDS 6
5m F01
10 m F02
25 m F03
40 m F04
50 m F05
Customer-specific > 50 m F06
LDS 6 connecting cable per LDS 6
5m G01
10 m G02
25 m G03
Customer-specific > 25 m G04
Electrical preparation
Preparation for dust measurement J01
Preparation for flow measurement J02
Preparation for pressure measurement J03
Preparation for temperature measurement J04
Preparation for emission data memory – DIN rail module (on request) J05
Preparation for emission data memory – 19" rack unit (on request) J06
Additional LOGO
LOGO for a third and fourth 19" rack unit K01

Siemens PA01 · 2015 4/15


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Set CEM 1
Additional versions Order code
Core end labeling
Single-core labeling Siemens standard L01
Analog signal processing
Double, galvanically connected, 1 x per analog signal M01
Double, galvanically isolated, 1 x per analog signal M02
Documentation
German N01
English N02
French (on request) N03

■ Dimensional drawings

Option:
Control cabinet ventilation (when using side walls) **
Standard: voltage 230 V/50 Hz, 1-pole fusing
Either fan and outlet filter
Option:
or air-conditioning unit Option:
voltage 115 V/50 Hz / 400 V/50 Hz, 2-pole fusing
Mounting on left or right Electronic and pneumatic
Spare location inputs and outputs
800 for converter either on left or right
(option)

4 Outlet filter

SIEMENS

LOGO Electrical
0.00
0.00

Optionally extendable input/output


Option: ULTRAMAT 23 ULTRAMAT 23
Depends on number
Analog signal + -
duplication SIEMENS
s LOGO! TD
of analyzers.
with electrical 2. ULTRAMAT 23 (option)
isolation SIEMENS

0.00
0.00

Spare location ULTRAMAT 23 ULTRAMAT 23

OXYMAT 6E (option)
Sample gas outlet
2000

Siemens

OXYMAT 6E
Spare
-RV3 Calibration
LDS 6E (option)
Siemens gas inlet

Option: LDS 6E
Sample gas inlet
Coalescence filter

Fan

Condensation outlet
350

Hinged frame 40 HU
100

Option:
Side view from right Front view condensation bottle Side view from left
Hinged frame open with level monitoring
19 liters

Standard: without plinth Sample gas cooler Option: Available cabinet sizes:
Option: Cabinet heater Metal: W x H x D: 800 x 2 000 x 600
with plinth 100 or 200 mm high Metal: W x H x D: 800 x 2 000 x 800
FRP: W x H x D: 900 x 2 140 x 600
** FRP cabinet is always with side walls and 80 mm plinth

Design of the Set CEM 1, figure contains options, dimensions in mm

4/16 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS

■ Overview ■ Application
The measurement and monitoring of emission components in
flue gases is one of the most important topics for continuous gas
analysis. This is a result of legislation for monitoring emissions,
e.g. for waste incinerators, and also due to the requirements of
companies operating process plants who can draw conclusions
on process efficiency from the gas analyses, e.g. with boiler and
oven controls, DeNOx and DeSOx plants.
The market requires a reliable complete system which is spe-
cially designed for the application. The Gasmet CEMS (Continu-
ous Emission Monitoring System) offered by Siemens is an ex-
tractive and continuous gas probe measuring system based on
established FTIR spectroscopy method. It reliably covers all re-
quirements associated with sampling, sample processing, and
gas analysis.
The concentration of the following gas components can be de-
termined on the basis of FTIR: CO, CO2, HCl, HF, H2O, NH3, NO,
NO2, N2O, SO2, CH4, C2H4, C2H6, C3H8, C6H14and HCOH. The
Gasmet CEMS is another FTIR-based, standardized complete FTIR measurement can also be used to derive additional values
system for continuous, simultaneous measurement of a large for total organic carbon and NOx. In addition, the Gasmet CEMS
number of emission components in flue gases from power sta- offers space for an optional ZrO2 oxygen analyzer as well as a
tions and waste incinerators. FIDAMAT 6 for determining total organic carbon levels (also
QAL1 certified, if required).
■ Benefits The standardized Gasmet CEMS provides great clarity and sim-
ple configuration facilities. Different versions facilitate individual
Standardized complete system
• Highly accurate and reliable monitoring of emission compo-
nents in flue gases
adaptation to the system requirements in hand. Standardization,
however, also means that not all imaginable versions can be in- 4
cluded, and that it may not always be possible to implement par-
• Modular complete package with gas sampling system, hot ticular requirements such as armored cables, customer-specific
sample processing, measurement at 180 °C, data processing documentation or special conductor labeling without an extra
and analysis charge.
• Numerous analog and digital signal I/Os
• Simultaneous multicomponent analysis of 16 gas components
as standard:
CO, CO2, HCl, HF, H2O, NH3, NO, NO2, N2O, SO2, CH4, C2H4,
C2H6, C3H8, C6H14, HCOH
• Additionally calculated from the FTIR measurement: NOx and
total carbon values
• Approval for FTIR-based emission measurements (QAL 1 in
accordance with EN 14181) possible for ten measured
components
• Can be expanded with one or two additional analyzers for
measuring oxygen and for FID-based total carbon
measurement (also with QAL 1 approval, if required)
• Simple and fast to configure
• Tried and tested, harmonized and reliable set
• Low purchase price and economic operation
Proven, performance-tested technologies
• Continuous determination of up to eleven measured compo-
nents
• Simultaneous FTIR measurement for CO, CO2, HCl, H2O, NH3,
NO, NO2, N2O and SO2
• Optionally: Use of a QAL1 certified ZrO2 oxygen analyzer with
hot sample feed
• Optionally: FID-based total organic carbon measurement with
FIDAMAT 6
Simple operation
• Intuitive operation
• Configuration on a large TFT display using keyboard
Easy maintenance
• Maintenance-friendly cabinet design with 19'' telescopic rails
• Digital display of maintenance requirements

Siemens PA01 · 2015 4/17


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS
Heated sample gas line
■ Design
The Gasmet CEMS is supplied as standard with heated sample
The Gasmet CEMS is a fully equipped FTIR analysis system gas lines between the sampling unit in the Gasmet CEMS anal-
comprising several 19'' rack units: ysis cabinet and the FTIR analyzer.
• A sampling unit with sample gas pump and controller for the
Further internal sample gas lines to the optional ZrO2 and/or FID
heated sample gas lines,
analyzers can be ordered additionally.
- internally, from the sampling unit to the analyzer (included in
the scope of supply) The external sample gas line from the sampling probe to the
- externally, from the sampling probe to the analysis cabinet sampling unit in the analysis cabinet of the Gasmet CEMS is not
(optional) included in the standard scope of delivery of the system.
• The actual FTIR spectrometry system with gas cuvette All heated sample gas lines (external and internal) are regulated
• An industrial PC as analysis and operator input unit, including to 180 °C in the temperature controller integrated into the Gas-
keyboard and TFT display met CEMS sampling unit.
Options for expanding the system include: The external sample gas line can be heated as required and
• A sampling probe must therefore be designed for approx. 200 °C. It must have a
power consumption of 120 VA per meter, and it must use K-type
• A heated sample gas line (from the sampling probe to the temperature sensors (Ni-Cr-Ni). The length of the heated line
analysis cabinet) must not exceed 30 m.
• Additional analyzers (maximum 2)
Lengths greater than 30 m can be provided on special request,
- ZrO2 oxygen analyzer
or they can be implemented via an additional temperature con-
- FIDAMAT 6 for total carbon measurement
trol unit.
Sampling probe For the external, heated sample gas line, a replaceable inner lin-
The Gasmet CEMS is supplied as standard without a sampling ing made from PTFE with a 4 mm inner diameter and 6 mm outer
probe. diameter is recommended. The connections must be Swagelok
6 mm. For steric reasons, the outer diameter of the sample gas

4
A suitable stainless steel (SS 316) probe with DN 65 PN 6 flange line including preassembly on the side of the connection to the
that can be heated to 180 °C is recommended as a sampling Gasmet CEMS sampling unit must be less than 43 mm.
probe for the Gasmet CEMS. This can be offered separately on
request. Gasmet CEMS sampling unit
Since particles of dust can usually be expected in sample gas, The sampling unit is designed for hot-extractive sampling of wet,
you are strongly recommended to use a sampling probe with a corrosive gas streams, and is integrated into the Gasmet CEMS
suitable (pre-)filter element and/or backflushing facility, espe- as a 19" rack unit.
cially with dust concentrations > 2 g/m3.
It encompasses all valves, flow meters, sample gas pumps and
The sample gas temperature should usually not exceed 600 °C; filters required for the measuring task. The temperature of all
the sample gas pressure must be between 400 and 6 000 hPa. parts coming into contact with the sample gas (pumps, filters
and lines) is stabilized to 180 ºC.
For performance-tested applications, a sampling probe
matched to the Gasmet CEMS must be used (e.g. M&C The sample gas does not have to be diluted and does not have
SP2000H or comparable). This can be offered separately on re- to be dried beforehand either. The gas flow and the pressure of
quest. the instrument air supply can be monitored via the Gasmet
CEMS sampling unit by means of an alarm.
The sampling unit is connected to the control PC and is con-
trolled using the Calcmet software, like the FTIR and the other
(optional) analyzers.

Gasmet CEMS sampling unit with removed filter insert

4/18 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS

Gas line connection to


Heated sampling line
oxygen analyzer
Purge in Computer connector connections
IO connector
Gas line connection for the
Oxygen reference in Span to probe
FTIR analyzer

Instrument air
in

Zero gas in

Span gas in

Power connector 24 V DC connector


Gas line connection to from
sample line 4
Rear with connections of the Gasmet CEMS sampling unit
Analysis cabinet
The analysis cabinet of the Gasmet CEMS contains all the es- 2 000
sential components in the form of 19'' rack units, including ca-
bling and tubing:
Rear door
• The Gasmet CEMS sampling unit
with mounted
• The Gasmet CEMS FTIR spectrometry module with gas air-conditioning unit
cuvette
• An industrial PC, including TFT display and keyboard, for
controlling the analysis systems and for processing data
2 400

• An optional oxygen analyzer


• An additional, optional FIDAMAT 6 analyzer
The external dimensions of the analysis cabinet with socket, in-
cluding the air-conditioning unit mounted on the rear door, are:
2 100 x 600 x (800 + 250) mm (H x W x D). Front door

Hose and cable inlets are possible from the top, below, left and
right.
At the installation location, sufficient space must be provided to
the front, the right and the rear of the analysis cabinet to allow Minimum space requirements for a Gasmet CEMS for facilitating instal-
opening of the front and rear doors, and facilitate access to the lation and maintenance work
rear door. The air-conditioning unit mounted on the rear also re-
quires sufficient space for air circulation.
To be able to pull out the 19'' rack units to the front on the tele-
scopic extensions, the electrical cables and sample gas lines in
the cabinet must be sufficiently long and flexible. The same ap-
plies to the lines to the CEMS analysis cabinet if it has to be
moved on optional rollers for service and maintenance pur-
poses, for example.

Siemens PA01 · 2015 4/19


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS
External panels and doors Analog signal processing
The side panels and the rear door of the Gasmet CEMS analysis The analog signals are connected as single wires on isolating
cabinet are designed in steel plate, and the front door in glass. terminals as standard.
Base Analyzers
The analysis cabinet of the Gasmet CEMS is offered optionally The analysis cabinet is prepared for accommodating one to
on a plinth or four rollers (two with immobilizing brakes). three analyzers with hot sample feed. As well as the standard
Gasmet CEMS FTIR spectrometry unit, the system can also be
Air-conditioning unit supplemented with a ZrO2 oxygen analyzer, as well as a
To prevent overheating of the electronic components inside the FIDAMAT 6. Different measured components and measuring
cabinet, the analysis cabinet is supplied as standard with an air- ranges are available for selection. Other combinations of mea-
conditioning unit. The air-conditioning unit is attached to the rear sured components and measuring ranges are available on re-
door and has a cooling capacity of 1 100 W. quest, but you must check that the desired certificates and ap-
provals are available. The analyzers, measured components
Condensation removal and measuring ranges used are described briefly below.
The Gasmet CEMS analysis system is offered as standard with a GASMET FTIR spectrometer
plastic tube for removal and disposal of condensation by the
customer. For measuring 16 infrared active components as standard. A
calibrated measuring range is stored as standard per gas com-
Power supply ponent. Further calibrated measuring ranges per gas compo-
nent are available upon request for an additional charge.
The system can be designed either for three phases 115 V AC
at 60 Hz, 32 A or 400 V AC, or three phases 230 V AC at 50 Hz,
16 A.
Three phases, neutral and ground must always be provided by
the customer.

4
Component Smallest measuring Typical measuring Maximum measuring Unit
range range range
Water H2O 0 ... 25 0 ... 25 0 ... 40 Vol.%
Carbon dioxide CO2 0 ... 10 0 ... 20 0 ... 30 Vol.%
Carbon monoxide CO 0 ... 70 0 ... 500 0 ... 10 000 ppm
Nitrous oxide N2O 0 ... 50 0 ... 100 0 ... 500 ppm
Nitrogen monoxide NO 0 ... 100* 0 ... 200 0 ... 2 000 ppm
Nitrogen dioxide NO2 0 ... 100 0 ... 200 0 ... 500 ppm
Sulfur dioxide SO2 0 ... 30* 0 ... 100 0 ... 2 000 ppm
Ammonia NH3 0 ... 20* 0 ... 50 0 ... 500 ppm
Hydrogen chloride HCl 0 ... 10* 0 ... 50 0 ... 500 ppm
Hydrogen fluoride HF 0 ... 17* 0 ... 50 0 ... 100 ppm
Methane CH4 0 ... 50 0 ... 100 0 ... 1 000 ppm
Ethane C2H6 ** 0 ... 100 ppm
Ethylene (ethene) C2H4 ** 0 ... 100 ppm
n-propane C3H8 ** 0 ... 100 ppm
n-hexane C6H14 ** 0 ... 100 ppm
Formaldehyde HCOH ** 0 ... 50 ppm
Total carbon Ctotal, or THC, TOC 0 ... 15 0 ... 40 0 ... 40 mgC/m3
(via FTIR measurement)
Nitrogen oxide NOx Calculated from N2O, NO and NO2
(via FTIR measurement)
* Smallest measuring range only possible at maximum 30 vol.% water concentration
** Dependent on the application

Standard components and measuring ranges Gasmet CEMS

4/20 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS

Purge gas in Sample gas in Sample gas out

Power Serial connector


connector

Gasmet CEMS FTIR rack unit, front and rear


ZrO2 oxygen analyzer
Component Typical measur- Unit
ing range
Oxygen O2 0 … 25 Vol.%

Power
connector
Reference
air Sample in
4

0 to 10 V Sample out

Electrical and gas connections of the ZrO2 analyzer


FIDAMAT 6
The FIDAMAT 6 is used for FID-based measurement of the total
carbon content (Ctotal, THC, TOC value).
Component Typical measur- Unit
ing range
Total carbon Ctotal, or THC, 0 ... 40 mgC/m3
TOC

You can find details of the optional FIDAMAT 6 analyzer in the


"Continuous gas analyzers, extractive" chapter of this catalog.

Siemens PA01 · 2015 4/21


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS
Component Performance-tested Additional performance-tested measuring ranges*) Units
measuring ranges*)
Range 1*) Range 2*)
Water H2O 0 ... 30 0 ... 40 Vol%
Carbon dioxide CO2 0 ... 25 Vol%
Carbon monoxide CO 0 ... 75 0 ... 300 0 ... 1500 mg/m3
Nitrous oxide N2O 0 ... 100 0 ... 500 mg/m3
Nitrogen monoxide NO 0 ... 200 0 ... 600 0 ... 2000 mg/m3
Nitrogen dioxide NO2 0 ... 200 0 ... 500 mg/m3
Sulfur dioxide SO2 0 ... 75 0 ... 300 0 ... 1500 mg/m3
Ammonia NH3 0 ... 15 0 ... 50 mg/m3
Hydrogen chloride HCl 0 ... 15 0 ... 90 mg/m3
Oxygen O21) 0 ... 25 Vol%
Total carbon THC, TOC2) 0 ... 15 mgC/m3
3)
Hydrogen fluoride HF 0 ... 3 0 ... 10 mg/m3
* A calibrated measuring range is stored in the software of a Gasmet CEMS per measured component as standard. Additional suitability-tested measuring
range available, either alternatively or for an additional charge.
1)
Using an optionally available, performance-tested ZrO2 oxygen analyzer
2)
Using an optionally available, performance-tested FID analyzer
3)
For performance-tested applications, the following must be checked for each case:
a) Only HF has to be measured in harmony with European Directive 2000/76/EU and 2001/80/EU.
=> QAL1 Certificate available
b) HF must be measured with only one FTIR spectrometer unit simultaneously with one or more other performance-tested IR-sensitive gas components.

4
=> No QAL1 certificate formally available for HF, but FTIR unit can be configured on request in such a way that the extended measuring uncertainties as
required by European Directive 2000/76/EU and 2001/80/EU are observed with regard to HF measurement. A manufacturer declaration in this regard and
calculation of the extended measuring uncertainties can be offered on request.
=> Possibly lower-cost solution compared to the use of 2 FTIR spectrometer units (see c)), if accepted by authority/test institute.
c) HF and one or more of the other above-listed IR-sensitive gas components are measured with two FTIR spectrometer units.
=> QAL1 certificate available

Performance-tested measuring ranges of the Gasmet CEMS analysis system


Other combinations of measured components and measuring
ranges are available on request, as well as other sample gas
components. In this case, you must check that the desired cer-
tificates and approvals are available.
Control and analysis unit

Operator interface of the Calcmet software of the Gasmet CEMS analysis


system
An industrial PC with Windows operating system and RAID hard The standard configuration enables control and monitoring of
drives is used in the Gasmet CEMS analysis system for control- the analyzers via the serial interface, watchdog support, as well
ling the sampling unit and the analyzers, as well as for data anal- as remote monitoring and maintenance options for the service
ysis and forwarding of the analysis data to the process control and maintenance personnel.
system. The GASMET Calcmet software is used as the control
and analysis software. Siemens provides automation and drive products with industrial
security functions that support the secure operation of plants or
machines. They are an important component in a holistic indus-
trial security concept. With this in mind, our products undergo
continuous development. We therefore recommend that you
keep yourself informed with respect to our product updates.
Please find further information and newsletters on this subject at:
http://support.automation.siemens.com

4/22 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS
To ensure the secure operation of a plant or machine it is also All internal gas routes of the Gasmet CEMS upstream of the FTIR
necessary to take suitable preventive action (e.g. cell protection spectrometer must be kept free of all contamination using clean
concept) and to integrate the automation and drive components purge gas before switching on the analyzer with sample gas in-
into a state-of-the-art holistic industrial security concept for the feed, or in good time before switching off temperature stabiliza-
entire plant or machine. Any third-party products that may be in tion of the sample gas lines and the analyzer. This prevents con-
use must also be taken into account. Please find further informa- densation of sample gas components, airborne pollutants, and
tion at: http://www.siemens.com/industrialsecurity atmospheric humidity, and/or the accumulation of particles in-
side the FTIR spectrometer. This prevents irreversible damage to
Zero gas and calibration gas supply the internal gas cuvette.
The Gasmet CEMS analysis system is equipped as standard Either nitrogen (quality: at least 5.0) or completely oil-free and
with two solenoid valves for the automatic infeed of zero gas and particle-free instrument air is used as the purge gas.
calibration gas.
To enable a "safety purge" of the internal gas routes in particular,
Either nitrogen (quality: at least 5.0) or purified instrument air is the instrument air must always be available at a pressure of ap-
used as the zero gas for the FTIR analyzer, which must be fed in prox. 6 bar.
at a pressure of 2 000 hPa.
Options/expansions (on request)
The span gas must contain one or more of the gas components
to monitored, depending on requirements and/or official regula- • Second/further calibrated measuring range(s) per sample gas
tions. The span gas must also be fed in at a pressure of approx. component
2 000 hPa. • Expansion set with solenoid valves for automatic span gas
infeed of up to four further span gases
Instrument air supply
• Instrument air/combustion air processing
The FTIR interferometer of the Gasmet CEMS is purged continu-
ously with instrument air at an even flow rate of approx. 0.5 l/min. • Calibration unit for the recommended annual test with wet
gases to adjust the H2O, NH3, HCl and HF calibration (can be
made available on loan within the scope of a service contract)

■ Function
Sample gas (max. 600 °C) is continuously taken via a heated FTIR spectroscopy is outstandingly suitable for multicomponent 4
sample gas probe, and transported via a heated sample line to analysis of numerous gas components. However, the oxygen
the sample pump of the heated sampling unit in the air-condi- concentration important for emission measurements, and the
tioned analysis cabinet. Heating to 180 °C prevents condensa- concentrations of other non-infrared-active gases such as inert
tion in the analysis system. From the sampling unit, the sample gases or hydrogen, cannot be determined in this way.
gas flows via further heated sample gas lines continuously
through the gas cuvette of the actual FTIR analyzer, as well as, For measuring O2, the system can be optionally equipped with
through the gas cuvette of the optional ZrO2 oxygen analyzer. a ZrO2 oxygen analyzer that can be integrated into the Gasmet
CEMS as a further 19" rack unit, and controlled using the Calc-
In the FTIR analyzer, spectra of the gas mix in the infrared spec- met software.
trum range are recorded at intervals of a few seconds. The gen-
erated interferograms are added together and converted to in- The FTIR method offers the possibility of calculating a "total or-
frared spectra using mathematical Fourier transform routines. ganic carbon value" from the individual concentrations of several
The result is the absorption spectrum of the sample gas, aver- hydrocarbons stored in the Gasmet CEMS standard calibration
aged over 60 seconds. The concentrations of the individual library. If direct total organic carbon measurement using the FID
components are calculated using multivariate-multicomponent method is required, a further free 19'' slot of the Gasmet CEMS
analysis. can be optionally equipped with a FIDAMAT 6.

A connected industrial PC, equipped with the special Calcmet The cabinet of the Gasmet CEMS analysis system is equipped
software, handles control of the measurements, analysis of the as standard with an air-conditioning unit mounted on the rear.
measured spectra, control of other programmable sequences, Power supply versions are available for 115 V AC or 400 V AC.
and output of the analog and status signals.

Siemens PA01 · 2015 4/23


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS
Gas flow charts and electrical connections

Delivery limit

Gasmet Computer
2- K-Bus
5° RS-232C Ethernet
Analog
Sample Probe
DN65 PN6-B
Sampling Unit
HEATED LINE 2
P1
Heated zone F1 FLA1
Ø6/4 mm OD/ID

HEATED LINE 1 CEM Signal Interface


Temp alarm Ø 6/4 mm OD/ID Filter A
Pump Flow alarm 1 HEATED LINE 3
Shuttlevalve Ø4 mm ID
FLA2 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

A C A C A C A C A C A C A C A C A C A C A C A C A C A C A C A C A C A C A C
B D B D B D B D B D B D B D B D B D B D B D B D B D B D B D B D B D B D B D

1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2

Orifice
SPAN TO PROBE LINE Checkvalve1 Checkvalve2 A
3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4 3 4

Ø 6/4 mm OD/ID Flow alarm 2


5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6 5 6

7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8 7 8

KL9186 KL1408 KL2408 KL9187 KL9186 KL1408 KL9186 KL1408 KL2408 KL9187 KL2408 KL9187 KL3054 KL3054 KL4428 KL9187 KL4428 KL9187 KL9010

V1 V2 V3 V4 V5 Signals to
Control room
and Field devices

Gas inlets (6/4 mm OD/ID) connector Delivery limit


6 mm Swagelok

Gas Pressure Consumption

Span Gas 1.5 bar 0 l/min / 5 l/min


FIC1

FIC2

FIC3

FIC4

FIC5

Zero Gas 1.5 bar 0 l/min / 5 l/min PA1


Instrument Air 5 ... 8 bar 1 / 15 l/min PA
* ( 50 / 65 l/min
with waste gas
dilution option )

Zr Oxygen Analyzer Reference air

4 Sample in
Sample out

Gasmet Ft-ir Analyzer Purge


Sample in
Outlet
Sample out dilution 32 mm OD drain pipe

Dilution air 50l/min


(Instrument air) Delivery limit

Delivery limit

Gasmet CEMS: Gas flow chart including options

Cabinet Heated line Sample probe IEC Wall


cooler sockets
X3 HL1 PR1 X4
B4:3 X2:5 L X2:10 L 3 L
A1 L X2:9 N X1:11 N
X1:8 X2:4 N 2
X1:7 X2:3 PE X2:8 PE A1 X2:6 B3:1 X1:1 PE
N TcK+ X2:1 1 7
B5:3 A2 X2:7 B4:1
A2 PE X1:2 TcK- X2:2 8

2 4
K1
50 A
1 3
Delivery limit

Devices L
X1:13

F1 F2 F3 F4 F5 Potential PE
N
C10 C10 C16 C6 C6 X1:7 rail X1:1

T 1 3 5 N 1 1 1 1 1
Q1 1 3 5 N F0
63 A 63 A
2 4 6 N ∆n0.03 A
2 4 6 N 2 2 2 2 2
X2:
L1
SUPPLY
L2
TN-S
L3
230 V/400 V
N
min. 25 A
PE
max. 63 A
Delivery limit

Gasmet CEMS: Electrical connections, including options

4/24 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS

■ Technical specifications
General data Sampling unit
Measuring principle • Fourier transform infrared (FTIR) Temperature controller for heated 0 … 180 °C
spectroscopy sample gas lines
• for oxygen: ZrO2 measuring cell
(optional) Type of temperature sensor in sample K type (Ni-Cr-Ni element)
• for total carbon (Ctotal, THC, TOC) gas lines
- FTIR, not performance-tested Gas inlet conditions
(standard) • Max. sample gas pressure at inlet to 1 500 hPa
- FID analyzer, also performance- sample preparation system
tested in accordance with
EN 14181 if required (option) • Sample gas temperature at inlet to 180 … 200 °C, non-condensing
sample preparation system
Performance capability Simultaneous analysis of up to 50 gas • Dust content at inlet to sample prep- Dust-free
components aration system
Standard: 16 components
• Instrument air Oil-free and dust-free instrument air,
T90 time < 180 s, with 20 m sample gas line dew point < -40 °C
• Flow rates • Sample gas: 2 ... 5 l/min
Climatic conditions
• Zero gas: Approx. 0.5 l/min
• Ambient temperature during opera- 0 ... 40 °C, non-condensing • Span gas: Approx. 0.5 l/min
tion • Reference air for optional O2 mea-
• Ambient conditions during storage -20 ... 60 °C, 0 ... 95% relative humid- surement: Approx. 0.7 l/min
and transportation ity, no condensation! • Instrument air to rinse the FTIR
• Site Indoors, dust-free, clean ambient air, spectrometer:
no external vibrations - Normal mode: Approx. 0.5 l/min
- Safety purging: Approx. 4 l/min
Ex zone Non-Ex area (IEC General Purpose) • Reference air for optional O2 mea-
System design surement: Approx. 0.7 l/min
• Type Cabinet configuration • Gas inlets Sample gas (heated to 180 °C), span
gas, zero gas, instrument air
• Cabinet degree of protection IP54
Electrical connections
• Supply voltage (alternative 1) 3 phases 115 V AC (-15%, +10%)/
• Gas outlets FTIR analyzer (heated), O2 analyzer
(heated), span gas for sample probe,
interferometer purging, reference air
4
60 Hz, 32 A + neutral + ground for O2 analyzer
(TN-S) • Gas connections Swagelok 6 mm, for sample gas lines
• Supply voltage (alternative 2) 400 V AC (-15 %, +10%) /50 Hz, with 4/6 mm internal/external diame-
3 phases 230 V AC (-15%, +10%)/ ters of the Teflon core. The external
50 Hz, 16 A + neutral + ground diameter of the sample gas line
(TN-S) including preassembly on the side of
the connection to the sampling unit
• Power consumption Gasmet CEMS with 20 m heated
must be no more than 43 mm.
sample gas line: approx. 7.5 kW
Sample gas pump
Dimensions (with plinth) 2100 x 600 x (800 + 250) mm
(H x W x D) • Material Stainless steel 316
• Diaphragm PTFE
Weight Gasmet CEMS with FTIR and O2 ana-
lyzers: Approx. 320 kg *) • Maximum flow rate 4 l/min
• Heated filter For particles > 2 µm
Electrical inputs/outputs
Valves
Analog inputs/outputs • Solenoid valves Sample gas / backflushing, span gas
• Analog outputs 16 channels, 4 … 20 mA, isolated, via sample outlet, span gas via sam-
freely programmable ple probe, zero gas, instrument air
• Analog inputs 8 channels, 4 … 20 mA, isolated, (safety circuit)
freely programmable • Shut-off valves Sample gas/backflushing, gas infeed
Digital inputs/outputs for maintenance purposes
• Digital outputs 16 channels, 24 V DC, freely pro- FTIR spectrometer unit
grammable
Measuring principle Fourier transform infrared (FTIR)
System alarm, maintenance require- spectroscopy
ment, maintenance, measured value
overshoot, valid measured value Spectral resolution Standard: 8 cm-1
• Digital inputs 16 channels, floating contacts Scan rate 10 scans/s
Temperature alarm sampling probe, Detector Peltier cooled MCT
temperature alarm analysis cabinet,
alarm air-conditioning unit on the Infrared light source SiC, 1 550 K
analysis cabinet, alarm zero gas Beam splitter and window material ZnSe
pressure, alarm O2 analyzer, acti-
vated scan gas infeed via sampling Spectral range 4 200 … 900 cm-1 (2.4 … 11 µm)
probe, activated system standby FTIR gas cuvette Multiple path gas cell with fixed opti-
Optional expansions Up to 255 terminal strips cal path length: 5.0 m
• Material Standard: 100% rhodium-coated alu-
Interfaces (optional) RS 232, RS 422/485, Modbus, minum
PROFIBUS
• Mirror Gold coating
• Cuvette volume 0.4 liters
• Seals Standard: Viton O rings, others: On
request
Window material BaF2
Interferometer purging • Oil-free and particle-free instrument
air, dew point < -40 °C, 0.5 l/min
• Nitrogen (at least 5.0)

Siemens PA01 · 2015 4/25


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS
Measuring performance
• Zero point checking: Recommendation: Automatic "zero
point calibration" with nitrogen every
24 hours
(Quality of the nitrogen: 5.0 or higher)
• Zero point drift: < 2% of the measuring range of the
"zero point calibration"
• Linearity error < 2% of the measuring range
• Temperature impact < 2% of the measuring range per
10 K temperature change
• Pressure influence 1 % of the measured value at 1%
sample gas pressure change. Ambi-
ent pressure fluctuations are mea-
sured and compensated for
Oxygen analyzer (optional)
Measuring principle ZrO2 measuring cell
Detection limit < 1 ppm O2
Reference gas • Oil-free and particle-free instrument
air, dew point < -40 °C
• Span gas
Sensor material Stainless steel 316 (1.4571)
Gas flow Minimum 0.1 l/min
Measuring ranges Min. 0 … 2 vol.% O2
Type 0 … 25 vol.% O2
Accuracy ± 0.2% of the measuring range
FIDAMAT 6 (optional) See "Continuous gas analysis, extrac-

4
tive"
Measuring principle FID analyzer

*) The system is supplied partially disassembled in several packages:


Analyzer rack units, sampling unit, industrial PC, air conditioning unit and
preconfigured analysis cabinet.

4/26 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS

■ Selection and ordering data Article No.


Gasmet CEMS FTIR analysis system for continuous emissions 7MB1956 - 7 7 7 7 7 - 7 7 7 7
monitoring
Incl. GASMET FTIR analyzer, Gasmet CEMS sampling unit,
industrial PC, TFT screen, keyboard
Standard analog and digital inputs/outputs
Click on the Article No. for the online configuration in the PIA Life
Cycle Portal.
Cabinet configuration
Cabinet configuration 1 with plinth, 2 100 x 600 x (800 + 250) mm 0
(H x W x D), air-conditioning unit on rear
Cabinet configuration 1 on rollers, 2 100 x 600 x (800 + 250) mm 1
(H x W x D), air-conditioning unit on rear
Sample gas probe
Without sample gas probe A
Heated sample gas line
Without heated sample gas line A
FTIR measurement
Standard CEMS FTIR unit 1 0
Oxygen measurement
No O2 measurement 0
Prepared for accommodating a suitable ZrO2 O2 analyzer 1
(19" rack unit)
Including ZrO2 analyzer 2
4
Total carbon measurement
FTIR-based total carbon measurement (not performance-tested) 1
Prepared for accommodating an additional total carbon (FID) analyzer 2
(19" rack unit)
Software version
Calcmet software version 12.x A
Fieldbus version
Modbus via RS 232 A
Power supply
400 V AC/50 Hz, on customer side: 3 phases (230 V/16 A), neutral, 0
ground
115 V AC/60 Hz, on customer side: 3 phases (115 V/32 A), neutral, 1
ground

Additional versions Order Code


Please add "-Z" to Article No. and specify Order code.
Calibration certificate (certificate of the gas cylinder A01
with which the calibration has been made)
Accessories Article No.
Portable GASMET calibration gas generator for H2O and liquid calibra- KHZ-GM-CAL-301
tions; including heated probe line as well as 5 ml and 1 ml injectors
Rollers for housing cabinet, supplied separately KHZ-GM-CAB-OPT-120

Recommended spare parts schedule


Description Annually Every Every Item no.
2 years 3 years
Filter set for housing fan (10 units) X KHZ-GM-COW-FIL-003
O-ring filter element X KHZ-GM-SAM-FIL-004
Heated filter element 0.1 µm, stainless steel X KHZ-GM-SAM-FIL-009
Set of diaphragms for sample gas pump X KHZ-GM-SAM-FLOW-100
IR light source unit X KHZ-GM-OPE-IRS-620
Laser unit X KHZ-GM-OPE-LAS-630
Temperature fuse 229 °C, with crimp connections X KHZ-GM-SMP-HEAT-002
Set of Viton gaskets (standard) for gas cuvette X KHZ-GM-SMP-GASK-738

Siemens PA01 · 2015 4/27


© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS

■ Dimensional drawings

3
2 100

4 9

600 50
10 800 + 2

1 Industrial PC 6 TFT display


2 Keyboard and touchpad 7 Rear door with mounted air-conditioning unit
3 Gasmet sampling preparation unit 8 Cabinet IP54
4 ZrO2 oxygen analyzer (optional) 9 Space for optional FID analyzer
5 Gasmet FTIR analyzer 10 Drawer for accessories

Design of the Gasmet CEMS analysis system

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© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
Gasmet CEMS

■ More information
Preventive maintenance
The table below offers a general overview of the recommended can be carried out by the operating personnel are described in
tasks for preventive maintenance for a Gasmet CEMS analysis detail in the documentation supplied with each system. For more
system. The actual requirements depend heavily on the individ- comprehensive work, special training courses or service con-
ual conditions of the application and installation. The tasks that tracts are offered.
Maintenance interval Task(s) To be carried out by
Daily Zero gas infeed Automated
1 week Visual inspection of the system and the included analyzers Operating personnel
1 week Visual inspection of the sampling unit Operating personnel
Approx. 30 days Zero gas and span gas infeed Automated
2 to 6 months Inspection and replacement of the filters of the sample probe and the Specially trained operating personnel
sampling unit (included in the annual service with the service contract)
Approx. 3 months Inspection of the oxygen calibration of the ZrO2 oxygen analyzer Automated
(included in the annual service with the service contract)
Approx. 12 months Inspection of the gas cell of the FTIR analyzer Trained service engineer
(included in the annual service with the service contract)
Approx. 12 months If required: Replacement of the diaphragm of the sample pump Trained service engineer
Approx. 12 months Infeed of wet span gases (for NH3, HCl, HF measurement), adjustment Specially trained service engineer
of the "water calibration" (included in the annual service with the service contract,
including provision of the calibration unit required for this
purpose)
18 to 60 months If required: Replacement of optoelectronic components (e.g. laser and Trained service engineer
infrared light source) of the FTIR analyzer

Suggestion for preventive maintenance of a Gasmet CEMS analysis system


4
Automated maintenance
Zero gas infeed
The Gasmet CEMS carries out automatic "zero gas calibration"
daily at definable times. With the help of controllable solenoid
valves, the FTIR gas cuvette is flushed for several minutes with
"zero gas", usually nitrogen, instead of sample gas.
Zero gas and span gas infeed
An infeed of span gas using dry span gases is recommended at
regular intervals, such as every 30 days, before infeed of the
zero gas. Span gas infeed can also be automated via controlla-
ble solenoid valves.
Annual inspection of wet span gases
Recording of a new water spectrum using the FTIR unit of the
Gasmet CEMS analysis system is recommended once a year.
Wet span gases for adjusting the system should also be sup-
plied once a year for the gas components ammonia, hydrogen
The Gasmet CEMS calibration unit for water
chloride and hydrogen fluoride.
These tasks must be carried out by a specially trained service Step motor
engineer, e.g. within the scope of a service contract.
Calibration gas
Span gases and nitrogen are required for these inspections as
well as a special calibration unit. That accessory can be be pro-
vided on loan within the scope of a service contract. max. 180 °C

N2

Functional principle of the Gasmet CEMS calibration unit for water

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© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
HM-1400 TRX Total mercury analyzer system

■ Overview ■ Application
The HM-1400 TRX monitors not only the performance of the mer-
cury separators by measuring the total mercury concentration,
but also reports and registers (also online) any violation of the
high limits. As a result it is often possible to intervene directly in
the process of the plant to be monitored and thus ensure reliable
compliance with the specified limit values.
Areas of application
• Waste incineration plants (municipal waste, industrial waste,
hospital waste)
• Sewage sludge and hazardous waste incineration
• Steel plants with scrap metal preparation
• Contaminated soil burning plants (thermal cleanup of soil)
• Crematoriums
• Mercury mines and refineries
• Fluorescent light bulb recycling
Approvals
The HM-1400 TRX is a total mercury monitor for fully automatic
and continuous measurement of emissions of mercury in flue • Suitability-tested by the TÜV North, test report 109 GMT007/
gas ducts. 8000632287 dated 30 June 2011
• Certified according to DIN EN 15267-3
■ Benefits • Itemized in the list of suitable measuring devices for
continuous emission measuring
4
• Extractive measuring procedure
• MCERTS
• Low maintenance dry reactor
• High operational reliability
• Easy maintenance, easy replacement of components
• Low cross sensitivities
• Easy to read LC display

■ Design
Heated
sample probe

Pump
Thermocatalytic
reactor Hg-photometer
Zero gas
filter Liquid
watchdog

Calibration
Gas/liquid
reactor
separator

Option
Stack

Reference
Condensate
standard

System components HM-1400 TRX


Sampling system Gas patch switchover
The sampling system consists of a sampling probe and a sam- The sample gas is extracted condensate-free from the exhaust
pling line. Both components are heated to 180 °C. With flue gas stack with approx. 100 Nl/h and fed via a three-way ball valve to
temperatures < 200 °C, the sampling tube must also be in the thermocatalytic reactor. The path switchover is also heated
heated tube design to prevent faulty measurements (lower find- and is operated as component of the measuring device by
ings for the mercury concentration measurement due to the ab- means of the device control. You can select between sample
sorption properties of HgCl2). gas connection, reference connection or zero gas connection.

4/30 Siemens PA01 · 2015


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Analytical Application Sets


Continuous emission monitoring
HM-1400 TRX Total mercury analyzer system
Thermocatalytic reactor
■ Technical specifications
The total mercury analysis measures not only the elementary
metallic mercury that is stored freely in the sample gas or depos- Measured variable Total mercury
ited in the materials, but also measures the chemically bonded Measuring ranges 0 ... 45, 0 ... 75 to 0 ... 500 g/Nm3
mercury that is found in the flue gas. The ionic mercury must also
be converted into elementary, atomic mercury so that the detec- Measuring principle UV absorption
tor can acquire and evaluate the total mercury. The thermocata- Sample gas temperature 0 ... 250 °C
lytic reactor carries out this function at a pre-set operating tem- Sample gas pressure -50 ... +50 hPa
perature.
Duct diameter > 0.5 m
Gas drying Ambient temperature 5 °C ... 40 °C
Before the mercury content is determined, the now created sam- Degree of protection IP40 (IP54)
ple gas containing Hg0 is dried while flowing through a Peltier
Measured value outputs 2 x 0/4 ... 20 mA, 500 
cooler. At the same time the system pressure and the measured
gas temperature are continuously recorded. Relative expanded uncertainty 5.5% CR
Digital outputs 4 relay outputs,
Prefilter permissible load 250 V, 100 VA
Before the prepared and dried sample gas flows through the Digital inputs 1 isolated input
photometer, it passes through an additional filter with hygro-
Detection limit < 0.1 g/Nm3
scopic effect to eliminate even lower residual humidity compo-
nents. This is important first for recording the gas volume flow in Reference point drift < 2% ZRE
dry form and, second, pollution and deposits are avoided in the Zero point drift < 0.5% ZRE
photometer and the maintenance-free service life increased. automatic zero offset

2-beam UV photometer Supply voltage 230/400 V AC, 50 Hz, 3 x L, N, PE


• Measuring instrument 1200 VA
The sample gas enters the measuring cuvette and is then routed • Sampling probe 650 VA
over a selective filter in which the mercury is absorbed. The sam-
4
• Sampling line 100 VA/m
ple gas thus freed from the mercury then flows through the refer- • Heated sample pipe 0.6 m, 1.0 m, 600 VA/800 VA/1200 VA
ence cuvette. The advantage of this cuvette switching is that the 1.5 m
entire gas matrix flows through both the measuring cuvette and Dimensions (H x W x D) control cabi- 1700 x 800 x 500 mm
the reference cuvette and most of the mercury is selectively fil- net
tered out before it reaches the reference cuvette. This principle
of differential measurement means that the measurement is less Weight 220 kg
sensitive to spectrometric interference components than the sin- Purge air supply, compressed air 6 ... 8 bar (for reference gas genera-
gle-beam photometer that has only one cuvette. With the cuvette tor only)
switching of the two-beam device this cross sensitivity for SO2,
for example, only becomes effective after 1000 mg/m³. The mea-
sured signal from the photometer is taken over by the internal ■ More information
PLC.
A HM-1400 TRX total mercury analyzer consists of, for example:
Gas volume flow generation • 1 sampling pipe, heated and temperature-controlled, with
When the sample gas volume flow leaves the 2-beam UV pho- connecting cable
tometer, it passes through the vacuum pump which generates • 1 sampling probe, heated and temperature-controlled, with
the gas flow. The volume flow of approx. 100 Nl/h is set manually connecting cable
with the fine regulating valve. The system pressure and sample • 1 sampling line, heated and temperature-controlled
gas temperature parameters are measured after the gas drying
at the photometer, where the mercury is also measured, and are • 1 measuring device
used ultimately to convert the gas volume flow to standard con- • Operating instructions, service manual, maintenance manual
ditions. The mercury concentration as result of a measurement
is output as 4 to 20 mA current signal to match the set measuring Please consult your Siemens sales partner for information on
range of 0 to X µg/Nm3 (dry). how to correctly configure and order a HM-1400 TRX total mer-
cury analyzer for a Siemens CEMS project.
Optional:
• Larger measuring range with dilution device
• Side-mounted cooling device
• Integrated system to generate reference gas
• Heated sample pipe 0.6 m, 1.0 m, 1.5 m

■ Function
In the HM 1400 TRX total mercury analyzer the sample gas is
converted into mercury vapor by a combination of thermal and
chemical treatment. It is then continuously measured in a pho-
tometer. The sample gas flow is measured after a sample game
cooler at 2 °C. The concentration is calculated and displayed as
"dry flue gas".

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© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
D-R 220 dust and opacity measuring instrument
Measuring head
■ Overview
The transmitter and receiver optics are integrated together with
the electronics in a sturdy but compact polyamide housing. The
measuring head is mounted on the weld-in flange.
Reflector
The reflector is installed in a sturdy polyamide housing. The re-
flector is mounted on the weld-in flange directly opposite the
The D-R 220 is a scattered light dust and opacity measurement measuring head.
device for monitoring dust emissions in smaller plants and pro- Supply box with purge air unit
cess applications.
A hose connects the measuring head and the reflector with the
■ Benefits supply box. The filtered air is used to keep clean the scattered
light interfaces of the measuring head and the reflector. A cable
• In-situ measurement directly in the flue gas flow connects the measuring head to the supply box.
• Digital operation with microprocessor Optional:
• Adjustable limit value
Quick-closing shutters
• 2 contact switch outputs
• Measuring value integral 4/15/60 seconds The quick-closing shutters are mounted on the measuring head
and the reflector side between the weld-in flanges and the con-
• Internal event memory with real-time clock nected devices (measuring head, reflector). In the event of a
• Modbus RTU interface fault (failure of the power supply or purge air) they automatically
• Measurement results shown as opacity or extinction close the path between the exhaust gas duct and the measuring
equipment.
• No weather protection covers needed
Electronics for quick-closing shutter
■ Application
4 The D-R 220 monitors not only the efficiency of the filter plants
A control electronics is required for each quick-closing shutter.
Universal control unit D-ISC 100
by registering the residual dust content, but also reports instan-
taneously when permissible levels of dust or flue gas emissions The connected equipment can be operated and configured con-
are exceeded. As a result it is often possible to intervene directly veniently using the D-ISC 100. The display provides an immedi-
in the process of the plant to be monitored and thus ensure reli- ate overview of the current measured values and the status of
able compliance with the specified limit values. the measuring instruments.

Areas of application Measured-value acquisition


• Compact device for smaller plants In the simplest case a recorder is used to record the measured
• Heating plants, power plants values and the reference values. The measured values and sta-
tus signals that are output can also be fed into systems that will
• Boiler plants in industry, barracks, hospitals, schools process these further.
• Dust extraction and filter plants
Weather protection covers
• Process monitoring
Weather protection covers are available to protect the measur-
ing head and the reflector when the measuring system is in-
■ Design stalled outdoors.
Additional options:
Optical Reflector • Neutral density filters for linearity check
measuring unit
• Sighting scope for easy alignment

■ Function
The device operates using the double-pass method according
to the auto-collimation principle. The light beam traverses the
Supply box measuring distance twice. The attenuation of the light beam by
the dust content in the measuring section is measured and eval-
uated.
The universal control unit D-ISC 100 can be connected for the
measured value display, which allows up to eight dust and flow-
rate measurement instruments.
The connected equipment can be operated and configured con-
veniently using the D-ISC 100. The display provides an immedi-
ate overview of the current measured values and the status of
the measuring instruments.

System components D-R 220

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Analytical Application Sets


Continuous emission monitoring
D-R 220 dust and opacity measuring instrument

■ Technical specifications
Measuring instrument D-R 220
Measurements • Opacity
• Extinction
Measuring ranges
• Opacity 0 ... 25/50/100 %
• Extinction 0 ... 0.2/0.4 ... 1.6
• Dust1) • 0 ... 160 mg/m3
• 0 ... 4000 mg/m3
Measuring principle Transmission
Sample gas temperature Above dew point up to 200 °C,
optional up to 500 °C
Sample gas pressure -50 ... +10 hPa, optional higher
Duct diameter 0.4 ... 10 m
Ambient temperature -20 ... +50 °C
Degree of protection IP65
Measured value output 0/4 ... 20 mA, 400 
Digital outputs 2 relay outputs, 30 VA,
max. 48 V/0.5 A
Digital inputs None
Accuracy < 2% of the measuring range
Detection limit < 2% of the measuring range

4
Supply voltage 24 V DC, 0.4 A from the supply unit
Dimensions (H x W x D) measuring 160 x 150 x 314 mm
head
Weight
• Measuring head 2.7 kg
• Reflector 1.6 kg
Supply box
Purge air supply From the supply box
Supply voltage 85 ... 264 V AC, 46 ... 63 Hz, 50 VA
Dimensions (H x W x D) 210 x 300 x 380 mm
Weight 13 kg
Degree of protection IP65
1)
with reference to one meter of path length after gravimetric calibration

■ More information
In general, a dust concentration measuring instrument D-R 220
consists of:
• 1 measuring head D-R 220 M
• 1 zero point reflector
• 1 reflector
• 2 welded tubes with adjustment flange
• 2 purge air adapters with clips
• 1 operating unit (for up to 8 sensors)
• Parameterization software with stick and USB cable
• 1 supply box (incl. purge air blower) 115/230 V, 50/60 Hz
• Operating instructions
• Weather protection covers for measuring head, reflector,
blower, control unit, etc.
Please consult your Siemens sales partner for information on
how to correctly configure and order a D-R 220 measuring in-
strument for a Siemens CEMS project.

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© Siemens AG 2014

Analytical Application Sets


Continuous emission monitoring
D-R 290 dust concentration measuring instrument

■ Overview ■ Design

Optical
measuring unit Reflector

The D-R 290 is an optical opacity/dust monitor for plants with Purge air unit
small to medium dust concentrations.

■ Benefits
• In-situ measuring procedure, continuous measurement Control and
display unit
• Semiconductor source with long service life
• Super-wide band diodes (SWBD), which provides more stable
measuring results in comparison to devices with conventional
LEDs

4 • Powerful microprocessor technology


• Measured value display on LC display in opacity, extinction or
System components D-R 290
Measuring head
in mg/m3
The transmitter and receiver optics are integrated together with
• Automatic function tests with correction of measured values in
the electronics in a rugged and robust aluminum housing. The
relation to soiling
measuring head is mounted on the weld-in flange.
• Optics and electronics in a hermetically sealed unit - no
smoke gas can enter device Reflector
• Easy adjustment without additional equipment The reflector is installed in a rugged and robust aluminum hous-
• Low-maintenance thanks to optimal purge air conduction ing. The reflector is mounted on the weld-in flange directly oppo-
site the measuring head.
• Heated end plate
Evaluation unit
■ Application The D-R 290 measuring system is connected to and operating
The D-R 290 monitors not only the efficiency of the filter plants on the evaluation unit. The evaluation unit is connected to the
by registering the residual dust content, but also reports instan- measuring head by means of an approx. 2 m long cable.
taneously when permissible levels of dust or flue gas emissions Purge air unit
are exceeded. As a result it is often possible to intervene directly
in the process of the plant to be monitored and thus ensure reli- A hose connects the measuring head and the reflector with the
able compliance with the specified limit values. purge air unit. The filtered air is used to keep clean the scattered
light interfaces of the measuring head and the reflector.
Areas of application
Optional:
• Furnace plants with semi-anthracite coal, brown coal, fuel oil
and combined heating Quick-closing shutters
• Converter plants, asphalt mixing plants The quick-closing shutters are mounted on the measuring head
• Cement manufacturing plants and the reflector side between the weld-in flanges and the con-
nected devices (measuring head, reflector). In the event of a
Approvals fault (failure of the power supply or purge air) they automatically
• Suitability-tested by the TÜV Cologne, test report 936/801017 close the path between the exhaust gas duct and the measuring
• Certified according to DIN EN 15267-3 equipment.
• Itemized in the list of suitable measuring devices for Electronics for quick-closing shutter
continuous emission measuring
A control electronics is required for each quick-closing shutter.
• MCERTS
Measured-value acquisition
In the simplest case a recorder is used to record the measured
values and the reference values. The measured values and sta-
tus signals that are output can also be fed into an emission cal-
culator system for further processing.
Weather protection covers
Weather protection covers are available to protect the measur-
ing head, the reflector, the purge air unit and the terminal boxes
when the measuring system is installed outdoors.

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Analytical Application Sets


Continuous emission monitoring
D-R 290 dust concentration measuring instrument
Additional options:
• Bus interface, for example, Modbus or similar
■ More information
• Explosion proof design for EEx p, Zone 1 or Zone 2 Please consult your Siemens sales partner for information on
how to correctly configure and order a D-R 290 measuring in-
• With an additional display unit at the measuring location, the strument for a Siemens CEMS project.
control and display unit can be installed at a distance of up to
1000 m away
• Temperature compensation through additional analog input
• Special model for measuring distances up to 18 m with
2 purge air units
• Filter set for sensitivity and linearity control

■ Function
The device operates using the double-pass method according
to the auto-collimation principle. The light beam traverses the
measuring distance twice. The attenuation of the light beam by
the dust content in the measuring section is measured and eval-
uated.

■ Technical specifications
Measuring instrument D-R 290
Measurements • Opacity
• Extinction
Measuring ranges
• Opacity
• Extinction
0 ... 20 to 0 ... 100 %
0 ... 0.1 to 0 ... 1.6 4
• Dust1) 0 ... 80 mg/m3 to 0 ... 4 000 mg/m3
Measuring principle Transmission
Sample gas temperature Above dew point up to 250 °C,
optional up to 1 000 °C, depending
on application
Sample gas pressure -50 ... +20 hPa, optional higher
Duct diameter 1 ... 12 m, optional up to 18 m
Ambient temperature -20 ... 50 °C, optional higher
Degree of protection IP65, Ex optional
Measured value outputs 2 x 0/4 ... 20 mA, 500 
Manual or automatic measurement
range switching
optional Modbus RTU, PROFIBUS DP
Digital outputs 6 programmable relay outputs,
permissible load 48 V/0.5 A
Digital inputs 6 programmable isolated inputs
Accuracy < 1 % of measuring range
Detection limit 0.75 % at extinction 0 ... 0.1
Reference point drift < 0.4% of measuring range / month
Zero point drift < 0.4% of measuring range / month
Auxiliary power 95 ... 264 V AC, 47 ... 63 Hz, 30 VA
Dimensions (H x W x D) measuring 363 x 185 x 398 mm
head
Weight 17 kg
Purge air supply
Purge air quantity Approx. 80 m3/h
Auxiliary power 115/230 V AC, 50/60 Hz,
0.37/0.43 kW
Dimensions (H x W x D) 350 x 550 x 500 mm
Weight 12 kg
Degree of protection IP55
1)
with reference to one meter of path length after gravimetric calibration

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Analytical Application Sets


Continuous emission monitoring
D-R 320 dust measuring instrument

■ Overview ■ Design
Measuring head Universal control Supply unit with inte-
Mounting flange unit D-ISC 100 grated purge air supply

The D-R 320 is an optical dust monitor for the smallest to medium
dust concentrations in dry emissions and process gas.

■ Benefits
• Continuous measurement of dust concentration
• Easy installation on standard flanges
• Easy setup without manual adjustment
• Automatic background light compensation, no light trap
• Convenient operation, remote access option System components D-R 320
• Automatic control functions Transmitter / receiver unit D-R 320 M

4 •

Integrated purge air regulation and purge air control
Long maintenance intervals
The transmitter and receiver optics are integrated together with
the electronics in a compact unit in a rugged housing. The trans-
• Certified to EN 15267-3 mission-reception unit consists of the measuring head, the
swivel adapter, the process connection and the field facing
• Data transmission via Modbus, in compliance with VDI 4201-3 panel. This measuring unit is installed directly above the waste
gas duct, on a DIN 100 PN 6 or ANSI 4" 150 lbs flange. No ad-
■ Application justment is required.
The D-R 320 monitors not only the efficiency of the filter plants Supply unit D-TB 200
by registering the residual dust content, but also reports instan- The supply unit of the dust concentration measuring instrument
taneously when permissible levels of dust or flue gas emissions D-R 320 is used to supply electricity and purge air and provides
are exceeded. As a result it is often possible to intervene directly the connection for the transfer of the measured data. The regu-
in the process of the plant to be monitored and thus ensure reli- lated purge air is used to keep clean the optical interfaces of the
able compliance with the specified limit values. transmission and reception optics of the D-R 320. The device
Areas of application automatically reports any failure of the purging air.
Continuous emission monitoring, for example, on: Optional:
• Incineration plants in general Universal control unit D-ISC 100
• Plants according to IED 2010/75/EU/17. BImschV The connected equipment can be operated and configured con-
• Plants according to 2001/80/EG LCPD/13. BImschV/German veniently using the D-ISC 100. The display provides an immedi-
TA-Luft ate overview of the current measured values and the status of
• Waste, hazardous waste and sewage sludge incineration the measuring instruments.
plants Measured-value acquisition
• Cement manufacturing plants
In the simplest case the measured values and reference values
• Power plants with gas, oil, coal or co-firing are transferred to the plant's control system. The measured val-
• Plants for the incineration of biomass ues and status signals that are sent can also be fed to an emis-
sion calculator system for further processing, either via discrete
Monitoring of: signals (4 to 20 mA and configurable relay contacts) or via
• Ventilation units Modbus according to VDI 4201-3.
• Filter units Quick-closing shutter
Approvals The swivel adapter can be optionally replaced with an adapter
• Suitability-tested by the TÜV Cologne, test report with a fully integrated quick-closing shutter. By using this quick-
936/21217455/A closing shutter the path between the measuring device and the
• Certified according to DIN EN 15267-3 waste gas is closed mechanically, but not airtight in the event of
a fault (failure of power supply or purge air); the measuring de-
vice is temporarily protected against overheating in such cases.
The measuring head takes over the control of the quick-closing
shutter.
Weather protection covers
A weather protection cover is available to protect the measuring
system when it is installed outdoors.

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Analytical Application Sets


Continuous emission monitoring
D-R 320 dust measuring instrument
Explosion proof design
An explosion proof design with pressurized enclosure according
to EEx p, Zone 1 or Zone 2 is available for use in hazardous ar-
eas.

■ Function
The device operates according to the backscattering principle.
The light of a laser diode illuminates the dust particles in the
measuring volume of the flue gas duct. The light reflected by the
particles is measured and evaluated.
The D-R 320 does not require a light trap. The background light
in the stack is detected by means of a special optical system
with an integrated dual detector and automatically compen-
sated without manual adjustment.
The universal control unit D-ISC 100 can be connected for the
measured value display, which allows up to eight dust and flow-
rate measurement instruments.
The connected equipment can be operated and configured con-
veniently using the D-ISC 100. The display provides an immedi-
ate overview of the current measured values and the status of
the measuring instruments.
Control functions
The D-R 320 automatically performs zero and span check as
well as contamination check at regular intervals and on demand.
The device features an automatic contamination correction.
Need for maintenance is immediately indicated by the electron-
4
ics.

■ Technical specifications
Measuring head
Measured variable Dust concentration
Measuring ranges 0 ... 5 mg/m3 to 0 ... 200 mg/m3
Measuring principle Backscattering
Sample gas temperature 0 ... 600 °C
Sample gas pressure -50 ... +50 hPa, optional higher
Duct diameter 0.7 ... 20 m
Ambient temperature -40 ... +60 °C
Degree of protection IP65
Measured value outputs 0/4 ... 20 mA, 400 
Modbus RTU bi-directional
Digital outputs 2 relay outputs, permissible load
60 V DC, 30 V AC/0.5 A
Digital inputs None
Auxiliary power 24 V DC/0.5 A
Dimensions (H x W x D) 200 x 190 x 260/410 mm
Weight 15 kg
Supply box
Purge air supply Integrated blower
Supply voltage 115/230 V AC, 50/60 Hz,
0.37/0.43 kW
Dimensions (H x W x D) 480 x 450 x 320 mm
Weight 12 kg
Degree of protection IP65

■ More information
Please consult your Siemens sales partner for information on
how to correctly configure and order a D-R 320 measuring in-
strument for a Siemens CEMS project.

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Analytical Application Sets


Continuous emission monitoring
D-RX 250 combination probe

■ Overview ■ Application
By combining four selected measuring functions in a single de-
vice it is possible to automatically calculate the pollutant mass
flow for the preparation of the emission declaration in addition to
monitoring the pollutant dust.
Areas of application
• For measurements in accordance with TIA Air (Technical
Instructions for Maintaining Air Purity) 13., 17. and 27.
BlmSchV
The combined probe sensor D-RX 250 is a single rod measure- • Not suitable for use behind electrostatic precipitators
ment probe for simultaneous measurement of dust concentra-
tion, volume flow, temperature and absolute pressure. Approvals
• Suitability-tested by the TÜV Cologne,
■ Benefits test report 936/800006/A
• Itemized in the list of suitable measuring devices for
• Only one probe/installation opening in the exhaust gas continuous emission measuring
channel
• MCERTS
• Compact design, no moving parts, no consumable parts
• Continuous conversion to normalized dust concentration in
mg/Nm3 and to normalized volume flow in Nm3/h
• LCD display in mg/Nm3, Nm3/h, °C and hPa, one analog
output for each measurement value
• Parameterization at the control unit without the need of a PC or
other tools

4 • Remote connection of control and evaluation unit via two-wire


bus interface up to 1000 m

■ Design

Probe Transmitter Differential Control and


pressure unit evaluation unit

Max. 1 000 m

System components D-RX 250


Probe Differential pressure transducer
The probe consists of the probe measuring rod and the mea- The differential pressure transducer converts the differential
sured value processing by the electronics in the measuring pressure, created by the gas flowing in the probe measuring rod,
head. The probe measuring rod is a probe section that protrudes into a gas velocity variable.
into the dust duct and is fastened with a flange in the duct. The
probe measuring rod is insulated in design because of the tribo- Transmitter
electric measurement and has two chambers for differential The transmitter provides the supply voltages for the probe and
pressure measurement. The two chambers for pressure mea- the measuring transducer for absolute pressure and differential
surement are connected to a differential pressure transmitter. pressure, reads in the raw measured values of these modules
One of the two chambers is also connected to the absolute pres- and transfer the measured values via the RS 485 interface to the
sure transducer in the transmitter. The gas temperature is mea- evaluation unit. Through the RS 485 interface the transmitter
sured via a measurement resistance in a third chamber in the reads the probe values of the triboelectric measured signal and
center of the probe section. The electronic measured value pro- the temperature.
cessing is performed in the probe housing. The temperature of
the measurement resistance and the triboelectric raw value are The differential pressure transducer is connected to the transmit-
determined here. The two raw values of temperature and tribo ter by means of a two-wire cable. The absolute pressure trans-
signal are transferred digitally to the transmitter. ducer is located inside the transmitter housing. It receives the
pressure from the chamber via a special rod.

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Analytical Application Sets


Continuous emission monitoring
D-RX 250 combination probe
Control and evaluation unit
■ Technical specifications
The control and evaluation unit reads out the raw measured val-
ues from the transmitter. The measured values for normalized D-RX 250 combined probe sensor
dust concentration and normalized volume flow are calculated in Measurements • Dust concentration
the unit. • Volume flow
• Pressure
It is possible to output all analog values via Modbus or 4/20 mA • Temperature
signals and all status signals via isolated contacts.
Measuring ranges • 0 ... 10 to 0 ... 500 mg/Nm3
Measured-value acquisition • 0 ... 9 999 999 Nm3/h1)
• 800 ... 1300 hPa
In the simplest case a recorder is used to record the measured • 0 ... 200 °C, optional 0 ... 350 °C
values and the reference values. The measured values and sta- Measuring principle
tus signals that are output can also be fed into an emission cal- • Dust Tribo electric
culator system for further processing. • Volume Differential pressure
Optional: Sample gas temperature Above dew point up to 200 °C,
optional up to 350 °C
• Weather protection cover
Sample gas humidity < 80%
• Change-over cock for back purging/zero point control
Sample gas pressure -200 ... +200 hPa
• Automatic cyclical probe back purging for high dust concen-
trations Duct diameter 0.3 ... 5 m
• Hastelloy probes for corrosive gases Ambient temperature -20 ... +50 °C
• Purge air connection at flange Degree of protection IP65
Measured value outputs 4 x 0/4 ... 20 mA, 500 
■ Function Modbus RTU (RS 485)
Digital outputs 7 relay outputs, permissible load
Dust concentration 48 V/0.5 A
The dust concentration is calculated according to the triboelec-
tric measuring principle. The tribo probe measures the electrical
Digital inputs
Accuracy
6 isolated inputs
< 2% of the measuring range
4
charge of the incident particles.
Detection limit < 2% of the measuring range
Volume flow Reference point drift < 1% of measuring range / month
The measurement of the volume flow is based on the mechanical Zero point drift < 1% of measuring range / month
action principle. The probe has two separate chambers, be- Auxiliary power 115/230 V AC, 50/60 Hz, 50 VA
tween which a differential pressure builds up under flow.
Dimensions
Absolute pressure • Probes 180 x 180 x (340 + probe length) mm
• Probe length 250/400/700/1000 mm
The absolute pressure in the flue gas is measured by a pressure
transmitter in one chamber of the probe. Weight
• Probe 9.5 kg
Temperature • Electronics 22 kg
The temperature is measured directly in the center of the flue Options
gas in a separate chamber within the probe with a temperature Probe back purging, purge air supply 3 bar
sensor.
Isolator purging, continuous purge air Approx. 2 m3/h
supply
1)
Flue gas velocity > 5 m/s concentration after gravimetric calibration

■ More information
Please consult your Siemens sales partner for information on
how to correctly configure and order a D-RX 250 combined
probe sensor for a Siemens CEMS project.

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Analytical Application Sets


Continuous emission monitoring
D-FL 100 volume flow measuring system

■ Overview ■ Application
As in-situ measuring system, the measuring equipment deter-
mines the measured values without sampling directly in the duct
through which gas is flowing.
Areas of application
• Volume flow measurement at high temperatures
• Plants with small or large flue cross-sections
• Volume flow measurement at high pressure
Approvals
The D-FL 100 volume flow measuring system measures the flow • Suitability-tested by the TÜV Cologne,
rate in dry emissions with a probe using the differential pressure test report 936/800006/A
principle. • Itemized in the list of suitable measuring devices for
continuous emission measuring
■ Benefits • MCERTS
• Measuring of emission speed
• Adjustable parameters
• Versions with or without counter-support and for point
measurement
• Calculation of volume flow at standard conditions with evalu-
ation unit D-FL 100-20
• Maintenance interval 6 months

4 • Automatic backpurging device (optional)

■ Design
Differential pressure
transducer

Flow 4 ... 20 mA
Evaluation unit
4 ... 20 mA
4 ... 20 mA

Cross over cock


Absolute Temperature
pressure transducer
transducer (optional)
(optional)

Flow probe

Flow direction

System components D-FL 100


Dynamic pressure probe • System 1: 22 x 24 mm2 for 0.4 to 2 m length, with one-sided
(max. 1 m) or two-sided mounting
Each dynamic pressure probe of type D-FL 100 is a customized
product for the respective measuring location. Three different • System 2: 50 x 53 mm2 for 0.4 to 4 m length, with one-sided
sizes are available depending on the length of the planned mea- (max. 1.5 m) or two-sided mounting
surement path: • System 3: 90 x 100 mm2 for 0.4 to 8 m length, two-sided
mounting

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Analytical Application Sets


Continuous emission monitoring
D-FL 100 volume flow measuring system
Adapter Additional options:
The cross-over cock is either connected by an adapter to the dif- • Absolute pressure transducer
ferential pressure transducer directly on the probe (not for sys- • Temperature transducer
tem 3) or via a hose or tube connection. • Special designs in other materials for applications with partic-
Cross-over cock ularly aggressive exhaust gases or higher gas temperatures:
Standard material for probe stainless steel 1.4571, depending
Cross-over device for the backpurging of the dynamic pressure on measurement task also Hastelloy, Inconel or other materials
probe
• dP transducer in Ex-version
Differential pressure transducer
The transducer is delivered with factory set defaults for the or- ■ Function
der-specific configuration. The zero point should be calibrated The D-FL 100 measuring system operates according to the me-
after the installation. chanical action principle. The probe has two separate cham-
Counter-support bers, between which the flow builds up a differential pressure.
Taking account of the other flow parameters such as absolute
A counter-support is required for a probe mounted on two sides. pressure and temperature, for example, the volume flow can be
The counter-support supports the probe not only mechanically, converted from operating to standard conditions with the help of
but also enables the compensation of the temperature-depen- the D-FL 100-20 evaluation unit.
dent longitudinal expansion of the probe.
Mounting tubes with flange ■ Technical specifications
Mounting tubes made of stainless steel 1.4571, adapted to the Measuring system D-FL 100
plant conditions, are available in various lengths. A single flange
Measurements • Flue gas velocity
is required for a one-sided probe; otherwise two flanges are al- • Volume flow1)
ways required.
Measuring ranges • 2 ... 50 m/s
Optional: • 0 ... 3 000 000 m3/h

Evaluation unit Measuring principle


Sample gas temperature
Differential pressure
Above dew point up to 450 °C,
4
The evaluation unit D-FL 100-20 evaluates the measured signal optional up to 850 °C
from the differential pressure transducer. A 4 to 20 mA current
signal is available as measured value output. A Modbus inter- Sample gas pressure -200 ... +200 hPa, optional higher
face according to VDI 4201 for the connection of an emission Duct diameter 0.4 ... 8 m
evaluation calculator with digital interface is available in addition Ambient temperature -20 ... +50 °C
to the 4 to 40 mA current signal output. The front panel contains
five LEDs and one USB port. The LEDs signal the system's cur- Degree of protection IP65
rent status/operating state. Measured value output 0/4 ... 20 mA, 500 
The various parameters, such as standard density, substitute Digital outputs 2 relay outputs,
values for pressure and temperature in the exhaust gas duct, permissible load 48 V/0.5 A
k-factor and measuring ranges are input via the USB port with Digital inputs None
the help of a PC or the associated software D-ESI 100. Accuracy < 2% of the measuring range
Software D-ESI 100 Detection limit < 3 m/s
Software for assigning parameters, visualizing the measured Reference point drift < 0.5% of measuring range / month
data, and carrying out AST, QAL2 and QAL3 for D-FL 100-20. Zero point drift < 0.5% of measuring range / month
The D-ESI 100 can be parameterized, maintained and (when Auxiliary power 18 ... 32 V DC/1 A, 90 ... 264 V AC,
faults occur) analyzed via the USB port with the help of a PC and 48 ... 62 Hz, 100 VA
the associated software. Dimensions
• Probes 380 x 160 x (300 + probe length) mm
Universal control unit D-ISC 100 with evaluation unit
• Probe length 0.4 ... 2/0.4 ... 4/0.4 ... 8 m
D-FL 100-20
Weight 32 kg + 6.8 kg/m probe length
The connected equipment can be operated and configured con-
veniently using the D-ISC 100. The display provides an immedi- Purge-air supply (optional) 6 ... 8 bar for back purging
ate overview of the current measured values and the status of 1) Optional pressure and temperature correction
the measuring instruments.
Automatic back purging unit ■ More information
An automatic back purging device to keep the measuring open- Please consult your Siemens sales partner for information on
ings clean is available for applications with high dust loads. how to correctly configure and order a D-FL 100 measuring sys-
tem for a Siemens CEMS project.
Weather protection covers
A weather protection cover is available to protect the probe head
and the back purging control when the measuring system is in-
stalled outdoors.

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Analytical Application Sets


Continuous emission monitoring
D-FL 220 volume flow measuring system
Measuring heads
■ Overview
Two identically designed measuring heads, set for type A and
type B, are used. Depending on the application data, different
depth-of-penetration lengths are required, for example, from 100
to 1100 mm.
Stainless steel 1.4571 is used as probe material. The housing is
made of impact-proof polyamide.
A 4 mA to 20 mA current signal is available as measured value
output which measures the velocity and/or the volume flow and
can be connected, for example, to a emission evaluation calcu-
lator or a recorder. Two relay contacts are available for signaling.
The D-FL 220 is a volume flow measuring system for ultra-sonic Also available is a Modbus interface according to VDI 4201-3 for
measuring of flow and volume flow, especially for wet and ag- the connection of an emission evaluation calculator with digital
gressive smoke emissions. interface. The various parameters are entered during the instal-
lation on site. The USB port is on the rear.
■ Benefits Purge flanges
• In-situ measuring method The purge air which cools the ultra-sonic transducer and keeps
• Measurement possible below dew point and for high dust it clean is supplied via purge flange (one for each measuring
concentrations head). A toggle-type fastener connects the purge flange to the
• Continuous measurement of normal volume flow and gas measuring head.
velocity Mounting tubes with flange
• Automatic zero point and reference point control
Mounting tubes made of stainless steel 1.4571 or of glass-fiber
• Digital signal processing reinforced plastic, adapted to the plant conditions, are available.
• Remote access possible, digital interface according to
4
Purge air unit
VDI 4201-3
• Operation with or without control unit A hose connects the two measuring heads to the purge air unit.
The filtered air is used to cool the measuring heads and to keep
• Very low maintenance the transducers clean.

■ Application Terminal box


Terminal box to output the data with connecting cable for the two
As in-situ measuring system, the measuring equipment deter-
sensors and customer terminal strip.
mines the measured values without sampling directly in the duct
through which gas is flowing. Software D-ESI 100
Areas of application Software to assign parameters, to visualize the measured data,
• Volume flow measuring at low speeds and to carry out AST, QAL2 and QAL3.
• Plants with damp and/or aggressive exhaust gas, for example, The D-ESI 100 can be parameterized, maintained and (when
in waste incineration plants faults occur) analyzed via the USB port with the help of a PC and
• Volume flow measurement at high dust content the associated software.

Approvals Optional:
• Suitability-tested by the TÜV Cologne, test report Universal control unit D-ISC 100
936/21218490/A
The connected equipment can be operated and configured con-
• Itemized in the list of suitable measuring devices for veniently using the D-ISC 100. The display provides an immedi-
continuous emission measuring ate overview of the current measured values and the status of
the measuring instruments.
■ Design Weather protection covers
Weather protection covers are available to protect the measur-
Duct Measuring head ing heads when the measuring system is installed outdoors.
Additional options:
• Absolute pressure transducer
• Temperature transducer
Purge air

Purge air

System components D-FL 220

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Analytical Application Sets


Continuous emission monitoring
D-FL 220 volume flow measuring system

■ Function
The D-FL 220 measuring system operates according to the
acoustic transit time differential method.
Two identical sensors transmit and receive ultra-sonic pulses re-
ciprocally. The system calculates precisely the gas velocity and
the gas temperature from the transit time difference dependent
on the direction. The volume flow is calculated taking into con-
sideration the cross-section, the sample gas temperature and
the absolute pressure. The D-FL 220 performs internal self-mon-
itoring routines and is very low maintenance.

■ Technical specifications
Measuring system D-FL 220
Measurements • Flue gas velocity
• Volume flow1)
• Temperature
Measuring ranges • 0 ... 40 m/s
• 0 ... 3 000 000 m3/h
• 0 ... 400 °C
Measuring principle Ultrasonic transit-time differential
Sample gas temperature 0 ... 300 °C, optional higher
Sample gas pressure -50 ... +20 hPa, optional higher
Duct diameter 0.5 ... 13 m, temperature-dependent
Ambient temperature -20 ... +50 °C,
measuring head: -40 ... +70 °C 4
Degree of protection IP65
Measured value output 0/4 ... 20 mA, 400 
Modbus RTU bi-directional
Digital outputs 2 relay outputs,
permissible load 48 V/0.5 A
Digital inputs None
Accuracy <2%
Detection limit < 0.3% of measuring range
Reference point drift < 0.3% of measuring range / month
Zero point drift < 0.2% of measuring range / month
Auxiliary power 24 V DC/0.5 A
Dimensions standard measuring head Ø 190 x 570 mm
Weight 17 kg
Purge air supply
Purge air quantity Approx. 80 m3/h
Auxiliary power 115/230 V, 50/60 Hz, 0.37/0.43 kW
Dimensions (H x W x D) 350 x 550 x 500 mm
Weight 12 kg
Degree of protection IP55
1)
Optional pressure and temperature correction

■ More information
Please consult your Siemens sales partner for information on
how to correctly configure and order a D-FL 220 measuring sys-
tem for a Siemens CEMS project.

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Analytical Application Sets


Continuous emission monitoring
D-ISC 100 display and control unit for dust and volume flow measuring instruments

■ Overview ■ Application
The control unit can supply a single sensor or a system consist-
ing of two sensors with power. Several sensors that are con-
nected via a network can also be connected to the D-ISC 100. In
this case each of the sensors must be supplied with power by
means of a separate terminal box, supply unit or evaluation unit.
Modbus links the sensors to each other and to the D-ISC 100.
The display provides an immediate overview of the status of the
connected devices. The current measured values can be dis-
played without the necessity of direct access to the sensors. It is
also possible to visualize the measured values with bar chart
display.
The connected sensors can be queried, controlled and param-
eterized with the control unit. Operation takes place directly via
the membrane keyboard of the control unit. Alternatively, you
can connect a PC via the integrated USB port. In conjunction
with the Web server technology software D-ESI 100, remote sup-
port is possible via the Internet.
The D-ISC 100 universal control unit permits the connection of
The control unit features four slots for extension modules, for ex-
up to 8 sensors combining dust and volume flow measurements
ample, Modbus RTU or analog / digital input and output mod-
on one display.
ules.

■ Benefits You also have the option of including an external converter (e.g.
PROFIBUS DP) inside the unit. This eliminates the need for an
• Connection of up to 8 sensors additional housing in equivalent degree of protection.

4
• Large liquid crystal display (LCD) for display of the measured
values Approvals
• Automatic detection of connected sensors Type-tested according to European directive EN 15267 for con-
tinuous emission measurements in connection with the test re-
• Easy parameter assignment of connected sensors ports no. 936/21217455, 936/21218492 and 936/21218490 of
• Operation locally via membrane keyboard or USB port, or the Technical Inspectorate of the Rhineland region (TÜV Rhein-
remote control via the RS 485 interface land)
• Modular design, four slots available for extension modules
• Slot for external converter ■ Design
• No maintenance costs The following functions can be added to the D-ISC 100 control
• Easy to update via SD card unit by means of plug-in modules:
• Modbus RTU module
• Analog input module with four analog inputs: 0 to 20 mA with
2/4 mA live zero, burden 50 
• Analog output module with four analog outputs: 0 to 20 mA
with 4 mA live zero, max. burden 400 
• Digital input module with eight digital inputs
• Digital output module with eight digital outputs

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Analytical Application Sets


Continuous emission monitoring
D-ISC 100 display and control unit for dust and volume flow measuring instruments

■ Technical specifications
Basic unit
Output signal 0 ... 20 mA, zero point 4 mA
Maximum burden 400 
Relay outputs 3 x status, isolated (limit value, fault,
control cycle, etc.)
Maximum switching power 48 V/0.5 A
Inputs 1 x function, isolated
Ambient temperature -20 ... +50 °C, optional -40 ... +60 °C
Electrical data
Line voltage 90 ... 264 V, 48 ... 62 Hz
Power Approx. 100 W
Auxiliary power for sensors 24 V DC/2 A
Mechanical specifications
Material Stainless steel 1.4301
Color RAL 5017
Degree of protection IP65
Weight 5 kg
Dimensions (H x W x D) 130 x 330 x 220 mm

Expansion options
Modbus RTU module
Interface RS 485, serial
4
Baud rate 9600 ... 57 600 Bd
Analog input module
Output signal 0 ... 20 mA, zero point 0/2/4 mA
adjustable
Load 50 
Analog output module
Output signal 0 ... 20 mA, zero point 4 mA
Maximum burden 400 
Digital input module
Inputs 8 x function, isolated
Digital output module
Relay outputs 8 x status, isolated (limit value, fault,
control cycle, etc.)
Converter module
Type PROFIBUS DP

■ More information
Please consult your Siemens sales partner for information on
how to correctly configure and order a D-ISC 100 control unit for
a Siemens CEMS project.

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Analytical Application Sets


Continuous emission monitoring
D-EMS 2000 Environmental and process data management system

■ Overview

4-20 mA,
Ring memory Modbus,
6 years int, day PROFIBUS, Ring memory
+ protocols OPC, ELAN > 32 days
30 days 1 min + 1 s

1 ... 8
Ring memory
> 32 days

4-20 mA, D-EMS 4-20 mA, D-MS D-EMS 2000 D-EMS 2000 D-EMS 2000
2000 CS 500 KE Client Client Client
Modbus, Modbus,
PROFIBUS, PROFIBUS,
OPC, ELAN OPC, ELAN

TCP/IP TCP/IP

Authority Internet
Ring memory
> 5 years
Individual values
Protocols

4 System
Raid 1

Backup on DCF77
HD/SSD GPS
System Workstation D-EMS 2000

The D-EMS 2000 environmental and process data management system is a modular system for the continuous acquisition, long-term
storage, calculation and visualization of environmental and process data.

■ Benefits ■ Application
• Instrument for monitoring legally prescribed limit values and The D-EMS 2000 standard system is designed for small to me-
recording their observance dium sized industrial sites whose emission data, immission data
• Emission monitoring and remote data transmission to the or process data must be recorded in line with government regu-
authorities lations for measured data logging.
• Corresponds to EU directives 2000/76/EU, 2001/80/EU and Approvals
2010/75/EU
• Suitability-tested by TÜV in accordance with German TA-Luft,
• Adjustable to any plant size through to complete assessment 1., 2., 13., 17., 27., 30. and 31. BImSchV
of complex industrial sites
• Itemized in the list of suitable systems for evaluation of
• Continuous monitoring of 1 to 320 components per system continuous emission measuring
workstation
• Certified according to DIN EN 15267-2
• Interconnection of any number of components via data
networks • MCERTS certified
• Visualization available in 19 languages
■ Design
Measured data acquisition:
• Analog/digital inputs as
- 19" rack with ring memory
- Local DIN rail modules
• Data communication via bus systems, Modbus RTU/ TCP,
PROFIBUS, Elan, OPC UA

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Analytical Application Sets


Continuous emission monitoring
D-EMS 2000 Environmental and process data management system

■ Function
Data sources
• Emission data
• Immission data
• Meteorological data
• Water data
• Process data
Data export
• Data interface to MS-Excel with option of further measured
data evaluation, e.g. for fulfillment of environmental protection
officer’s reporting duties
• Measured data can be transferred to authorities via standard
remote communication or via Internet
• Merging of measured data e.g. for greenhouse emission
trading
• Remote service interface for fast and cost effective service
Data security
• Industrial type evaluation PC with vibration-proof hard disks in
RAID 1 array and special air cooling with filter system
• Paperless data storage to replace recorders and printers is
possible through integrated data security, which is
guaranteed on several levels in the system
• Intermediate storage of the raw input values at minute
intervals in data communication unit D-MS 500 KE
4
• Storage of raw input values in one-second intervals
• Data backup on external redundant drive
Internet/intranet connection
• Data transmission to an Internet server with HTML standard
masks via standard software (MS Internet Explorer)
• Password protected control of daily emission values including
the classification records
Visualization
• Measured data logging according to official regulations
• Classification tables, daily, monthly and annual records
• Representation of current, prognostic and historic measured
data in bar/linear form
• Pollutant compensation, characteristics curve and correlation
• Automatic alarm and information system
Annual emission declaration
• Automatic preparation of annual emission declaration, from
the individual values stored in the system, according to
11. BlmSchV
• Compatible with official software, import/export module
• Automatic filling in of forms
• Reading in of historical emission declarations

■ More information
Please consult your Siemens sales partner for information on
how to correctly configure and order a D-EMS 2000 environmen-
tal and process data management system for a Siemens CEMS
project.

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Analytical Application Sets


Continuous emission monitoring
D-EMS 2000 CS Environmental and process data management system

■ Overview

D-EMS 2000 D-EMS 2000 D-EMS 2000


Client Client Client

4-20 mA, Modbus, PROFIBUS, OPC, ELAN TCP/IP

Ring memory
Authority Internet
6 years int, day
+ protocols 30 days
1 min + 1 s

Backup on DCF77
HD/SSD GPS

4
The D-EMS 2000 CS environmental and process data management system is an affordable compact system for small to medium
plants.

■ Benefits ■ Technical specifications


• Independently operating module for the acquisition, long-term Device versions • Compact system in 19", 3HU rack
storage, calculation and visualization of environmental and
• Desktop version with monitor/
process data keyboard/mouse
• Instrument for monitoring legally prescribed limit values with • 19" slide-in assembly
automatic recording
PC Intel based dual-core PC with
• Continuous monitoring of 1 to 12 components, connected via Windows 7 Pro & 8, 2 GB RAM and
bus communication or hard-wired 120 GB SDD
• Compact system, no additional evaluation PC required Inputs / outputs Max. 3 cards:
• Combination card
• Windows-based and certified D-EMS 2000 software 4 AI, 8 DI, 2 AO, 4 DO
• All modules of the D-EMS 2000 system can be used • Input card 8 AI, 15 DI
• Output card 8 AO
• Visualization available in 19 languages • Output card 16 DO
Connection of bus systems • Modbus RTU/ TCP, PROFIBUS,
■ Application Elan, OPC UA
• Analog/digital inputs: 12/24
The D-EMS 2000 CS compact system is designed for small to • Analog/digital outputs: 12/24
medium sized industrial plants whose emission data, immission Interfaces • 1 x VGA
data or process data must be recorded in line with public author- • 2 x USB
ity regulations for measured data logging. • 1 x RJ 45
• 3 x serial (RS 232 or RS 485)
Approvals • BNC for DCF77 - radio clock
• Suitability-tested by TÜV in accordance with German TA-Luft, Ambient temperature 5 ... 40 °C
1., 2., 13., 17., 27., 30. and 31. BImSchV Degree of protection IP20
• Itemized in the list of suitable systems for evaluation of Operating voltage 115/230 V AC, 50/60 Hz, 100 VA
continuous emission measuring
• Certified according to DIN EN 15267-2
• MCERTS certified ■ More information
Please consult your Siemens sales partner for information on
■ Design how to correctly configure and order a D-EMS 2000 CS compact
system for a Siemens CEMS project.
Three available device types:
• Compact system in 19", 3HU rack
• Desktop version with monitor / keyboard / mouse
• 19", 1HU slide-in unit with extendable keyboard and hinged
monitor

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Analytical Application Sets


Analysis of biogas
Set BGA

■ Overview ■ Application
The efficiency of biogenic production processes and optimum
operation of the plant largely depends on continuous monitoring
of the biogas composition. The basic version of the Set BGA an-
alyzes CH4 and CO2 using the proven ULTRAMAT 23 IR ana-
lyzer. The concentrations of O2 and H2S are optionally measured
using electrochemical sensors and also converted into output
signals of 4 to 20 mA. In this manner, the Set BGA contributes to
operational safety and explosion protection in addition to pro-
cess optimization.
The modular design of the system takes into account the physi-
cal conditions of the gas with regard to temperature and mois-
ture in that various gas preparation components for heating or
drying the sample gas can be configured as required.
The gas mixture can be explosive at critical concentration ratios
between methane and oxygen. Even if such critical gas compo-
sitions occur extremely rarely, the danger of ignition must never-
theless be avoided. For this reason, the Set BGA is designed
with a high safety standard and even the basic version is
The Set BGA (biogas analyzer) is a standardized system for sta- equipped with flow monitoring and detonation protection in ac-
tionary, continuous operation for the analysis of landfill gas, sew- cordance with EN 12874 in the sample gas path. To increase
age gas or biogas. safety even further, a gas sensor for monitoring the ambient air
can be connected as an option.
■ Benefits It is also possible to monitoring up to four measuring points us-
ing an optional sample switching cabinet. In this case the sam-
Standardized complete system
The standardized complete system has a modular configuration
ple flows are sucked in continuously using a powerful pump in
order to achieve fast measuring times. 4
and can thus be used at various measuring locations for different
measuring tasks.
• Simple and fast to configure
• Field-tested and matched Set in rugged industrial design
• Extremely high long-term stability
• The Set BGA is based on the proven ULTRAMAT 23
Field-proven, reliable technologies
• Autocalibration function with ambient air reduces the mainte-
nance requirements
• Detonation protection in accordance with EN 12874
• Modular system design based on long-term tested compo-
nents
• LEL sensor for cabinet monitoring (optional)
Simple operation
• Intuitive menu guidance
• Configuration on large displays with plain text
• Two freely-configurable limits per measured component

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Analytical Application Sets


Analysis of biogas
Set BGA

■ Design ■ Technical specifications


The Set BGA consists of the following components: Technical data of Set BGA
• ULTRAMAT 23 analyzer with four measured components max. Installation
• Analyzer cabinet with modularly configurable gas preparation Ambient temperature 5 … 38 °C, with cabinet heating ± 0 °C
components
Site Indoor/outdoor installation (configurable)
• Cabinet for measuring point switchover (option)
Gas inlet conditions
• Heated line (option)
Sample gas pressure • With pump, depressurized suction mode, se-
The ULTRAMAT 23 is selectable with two IR components (CO2 lectable with internal or external pump
and CH4). Furthermore, the configuration can be equipped with • Provision must be made for a pressure re-
duction for pressures greater than
an electrochemical oxygen sensor and/or an electrochemical 1 200 mbar absolute
hydrogen sulfide sensor. The corresponding measuring ranges
are listed in the table below. Pump performance Adjustable to 60 … 80 Nl/h
Sample gas temperature Max. 45 °C, with moisture saturation
Measured component Smallest measuring Largest measuring
range range Power supply
CO2 0 … 20 % 0 … 100 % Supply 1 200 … 240 V AC, 47 … 63 Hz
CH4 0 … 20 % 0 … 100 % Supply 2 100 … 120 V AC, 47 … 63 Hz
O2 0…5% 0 … 25 % Power consumption Approx. 180 VA (without cooler and sample
preparation)
H2S (high) 0 … 500 ppm 0 … 5 000 ppm
Connection systems
H2S (low) 0 … 5 ppm 0 … 50 ppm
Teflon hose With PVDF screwed glands
The ULTRAMAT 23 calibrates the IR components and the elec- Connection systems Metric (6 mm) or imperial (1/4") selectable
tromechanical oxygen sensor automatically with ambient air.
Calibration with calibration gas is recommended once a year or Dimensions

4 after oxygen sensor replacement. In order to comply with the


technical specification data, the hydrogen sulfide sensor must
Set BGA measuring system
(W x H x D)
600 x 781 x 600 mm

be calibrated every three months. An appropriate calibration Sample preparation 600 x 600 x 220 mm
gas is therefore required. It is supplied to the analyzer through a (W x H x D)
manually switchable ball valve. Weight
Set BGA measuring system Approx. 50 kg
Sample preparation Approx. 22 kg
System design

System housing 3-part sheet-steel housing with window


Degree of protection IP54
Cabinet conditioning Fan
Cooling system Peltier cyclone cooler (optional)
Sample preparation Max. six sample streams can be controlled
using Logo module with fast loop pump in
separate housing
Analog outputs Per component 0/2/4 … 20 mA; NAMUR,
floating, max. load 750 
Measured components / measuring ranges
CH4 0 … 100 vol% to 0 … 20 vol% (NDIR)
CO2 0 … 100 vol% to 0 … 20 vol% (NDIR)

Set BGA measuring system O2 0 … 25 vol% to 0 … 5 vol% (electrochemical


or paramagnetic optionally selectable)
H2S 0 … 5 000 ppm (electrochemical); optional
0 … 5 ppm to 0 … 50 ppm (electrochemical);
optional
Safety assemblies
Assembly 1 Detonation protection F501
Assembly 2 Flow measurement with limit monitoring at the
output
Assembly 3 LEL monitoring (optional)
Comment • The system concept of the Set BGA is based
on the preconfigured ULTRAMAT 23 solu-
tions (7MB2335-…, 7MB2337-…)
• The technical performance data concerning
the measuring response correspond to the
catalog data of the ULTRAMAT 23. The pre-
configured version does not contain any
ULTRAMAT 23 add-ons or retrofitting sets.

2-stream sample preparation

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Analytical Application Sets


Analysis of biogas
Set BGA

■ Selection and ordering data Article No.


Set BGA basic configuration, including flame arrestor 7MB1955- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
Click on the Article No. for the online configuration in the
PIA Life Cycle Portal.
Gas connections, external
6 mm 0
¼ inch 1
Sample conditioning
Without gas cooling A
Passive cooling (supplied separately) B
Peltier cooler, integrated in Set BGA enclosure C
Enclosure design
Not heated A
Electrically heated B
Pump design
Without pump 0
Internal pump in analyzer 1
External pump, fitted in Set BGA enclosure 2
Power supply
AC 120 V, 60 Hz 0
AC 230 V, 50 Hz 1
AC 110 V, 50 Hz
AC 220 V, 60 Hz
2
3
4
Infrared measured components
Version with one measured component 0
Highly selective ULTRAMAT 23 single-beam infrared gas
analyzer for measuring methane; mounted in 19-inch rack unit
for installation in wall cabinet
Specification:
• ·Measured component CH4
- Smallest measuring range: 0 ... 20 %
- Largest measuring range: 0 … 100 %
Version for two measured components 1
Highly selective ULTRAMAT 23 single-beam infrared gas ana-
lyzer for measuring carbon dioxide and methane; mounted in
19-inch rack unit for installation in wall cabinet
Specification:
• 1. Measured component CO2
- Smallest measuring range: 0 ... 20 %
- Largest measuring range: 0 … 100 %
• 2. Measured component CH4
- Smallest measuring range: 0 ... 20 %
- Largest measuring range: 0 … 100 %
Version with one measured component 2
Highly selective ULTRAMAT 23 single-beam infrared gas ana-
lyzer for measuring carbon dioxide; mounted in 19-inch rack
unit for installation in wall cabinet.
Specification:
• Measured component CO2
- Smallest measuring range: 0 ... 0.5%
- Largest measuring range: 0 … 2.5%
Oxygen measurement
Gas analyzer without oxygen sensor A
Electrochemical oxygen sensor; sensitive to CO2 B
Specification:
• Smallest measuring range: 0 ... 5 %
• Largest measuring range: 0 ... 25 %
• Repeatability: approx. 0.05% O2
Paramagnetic oxygen measuring cell; no sensor wear C C
Specification:
• Smallest measuring range: 0 ... 2%
• Largest measuring range: 0 ... 100%
• Repeatability: < 1% of smallest measuring range

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Analytical Application Sets


Analysis of biogas
Set BGA
Set BGA basic configuration, including flame arrestor 7MB1955- 7 7 7 7 7 - 7 7 7 7 Cannot be combined
H2S measurement
Without H2S sensor A
With H2S sensor, 0 … 5 000 ppm B B
With H2S sensor, 0 … 5 ppm to 0 … 50 ppm D D
Documentation
German, 1 set (paper and CD) 0
English, 1 set (paper and CD) 1
French, 1 set (paper and CD) 2

Further versions (add-ons)


Add "-Z" to Article No. and specify Order code
Heated sample gas line, self-regulating, Ex-proof
Length: 5 m, supplied separately A01
Length: 10 m, supplied separately A02
Length: 15 m, supplied separately A03
Length: 20 m, supplied separately A04
Length: 25 m, supplied separately A05
Length: 30 m, supplied separately A06
Length: 35 m, supplied separately A07
Communication
4 PROFIBUS PA interface A12
PROFIBUS DP interface A13
Fast loop design and sample switching
2-stream sample switching with Logo and external pump B02
3-stream sample switching with Logo and external pump B03
4-stream sample switching with Logo and external pump B04
5-stream sample switching with Logo and external pump B05
6-stream sample switching with Logo and external pump B06
Gas sensor for leak monitoring of the Set BGA system
Alarm monitoring: 20 % LEL methane C01

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Analytical Application Sets


Continuous monitoring of hydrogen-cooled generators
Set GGA
In addition, contamination of the hydrogen cooling gas reduces
■ Overview the efficiency of the turbo generator, as it leads to considerably
higher friction loss. For a 970 MW generator, a difference of 4%
is equivalent to a 0.8 MW difference in power. There are also
good reasons related to cost-effectiveness why the cooling gas
should be continuously monitored for contamination.
The Set GGA is a complete solution for monitoring hydrogen-
cooled turbo generators, with the dual benefit of being simple to
handle and having low initial investment costs.

■ Design
The Set GGA is available in the following versions:
• Generator Gas Analyzer (GGA)
• GGA with test gas skid
• GGA with test gas skid and installation frame
Analyzers
The GGA contains two CALOMAT 6E analyzers (19" rack unit
versions). From the gas sampling system right through to the gas
The standardized Set GGA (Generator Gas Analyzer) has been outlet, these are completely separate from one another, thereby
specially designed for monitoring hydrogen-cooled turbo gener- ensuring full redundancy.
ators.
The CALOMAT 6E is a continuous gas analyzer for determining
H2 and He in binary or quasi-binary gas mixtures.
■ Benefits
To measure the hydrogen and inert gases continuously, the ex-
Standardized complete system
• Simple and fast to configure
act thermal conductivity of the sample gas mixture is measured
and the concentration calculated from this. Only binary gas mix- 4
tures can be directly measured.
• Field-proven, harmonized and reliable set
• Low purchase price and economic operation The CALOMAT 6E is used to measure 0 to 100 % CO2/Ar in air,
0 to 100 % H2 in CO2/Ar or 80 to 100 % H2 in air, in the context
• Suitable for optimizing the efficiency of H2-cooled turbo of monitoring hydrogen-cooled turbo generators, on account of
generators its high measuring range dynamics.
Field-proven, reliable technologies The units are approved for use in ATEX Zone 2. Gas mixtures
• High-precision and reliable purity monitoring of hydrogen may also be fed in according to the definition of Zone 1. In terms
of tightness and compressive strength, the measuring cell and
• Microchip-based thermal conductivity measurement
entire physical structure of the gas path, from inlet to outlet, are
• Redundant measuring system certified up to 55 000 hPa . This is much higher than the pressure
• SIL 1 certificate for the analysis hardware that arises when oxyhydrogen gas is ignited.
Simple operation A flame arrestor at the sample gas inlet provides additional
safety.
• Intuitive menu prompting
• Configuration on large displays with plaintext The integrated LCD display shows the measured values, status
bar and measuring ranges simultaneously.
• Use of CO2 and AR as inert gas possible
The T90 time is less than 5 s. This means that the delay between
the measurement and displaying the result is very short.
■ Application
Tests carried out under harsh field conditions have indicated that
This set is used in power generation applications. the 3-week drift of the measurement results is less than 0.1 %.
Turbo generators in power plants are cooled with gas in order to Combined with a repeatability value of 0.1 %, this ensures that
increase their efficiency. In spite of the strict safety requirements the measurement results gathered will be both accurate and
hydrogen is used as a cooling gas. This offers huge advantages precise.
over air. These include considerably better cooling properties,
lower friction loss on rotating parts, and a higher electrical
breakdown strength. These features enable hydrogen to satisfy
the requirements for the turbo generator to reach an optimum
level of efficiency.
However, mixtures of hydrogen and air with a hydrogen content
of anything from 4 to 77 % are explosive. For safety reasons, it is
imperative that this is prevented during operation filling and
emptying of the turbo generators. International standards
(EN 60034-3 and IEC 842) state that redundant safety monitor-
ing with two independent operating systems must be used for
this.

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Analytical Application Sets


Continuous monitoring of hydrogen-cooled generators
Set GGA
Analyzer cabinet
■ Function
Another feature of the GGA is a protective cabinet for the analyz-
ers. This provides a compact location where the system can be There are three distinct processes in monitoring hydrogen-
easily installed, and offers protection against dust and water. cooled turbo generators: normal operation, filling and emptying.
The system is approved in accordance with IP54 degree of pro- The measuring task entails preventing a gas mixture of hydrogen
tection. and air outside the specified limits, or detecting the risk of this
happening in good time, as well as monitoring the hydrogen pu-
The cabinet measures 616 x 615 x 600 mm (H x D x W) and is rity.
made from painted sheet steel.
During normal operation, the purity of the generator cooling gas
A key advantage of this type of construction is that it eliminates is monitored. If the purity falls below a specific limit (e.g. < 95 %
the need for a restricted breathing enclosure, allowing mainte- H2), a message is output. The monitored range is 80 to 100 %
nance to be carried out without any difficulty. If a restricted H2 in air.
breathing enclosure is required, it must be ensured that the sys-
tem is operated in an airtight room. Restoring the restricted Filling the generator is a two-stage procedure: first, the air in the
breathing enclosure once maintenance procedures have been generator is replaced by inert gas (argon or CO2), and then this
performed is a costly and time-consuming process. is replaced by hydrogen. During this, the concentration trends of
the gases are measured and the replacement processes moni-
To keep operating and maintenance costs low, the GGA set sup- tored. To prevent explosive mixtures from being formed, it is nec-
ports natural cabinet ventilation and a filter element provides essary to monitor the measuring range of 0 to 100 % inert gas in
protection against particles of dirt. Purging with instrument air is air in the first step and 0 to 100 % H2 in inert gas in the second
not necessary. step.
Test gas skid The procedure is performed in reverse when emptying the gen-
erator: The hydrogen is first replaced with inert gas and the gen-
The analyzers and analyzer cabinet are supplied as part of the
erator is then filled with air. The measuring tasks remain un-
basic configuration of the set. As an option, however, it is also
changed in this case. Here it is necessary to monitor the
possible to obtain a suitable test gas skid on a mounting plate.
measuring ranges of 0 to 100 % H2 in inert gas first, and then 0
The test gas skid is responsible for preparing the extracted sam- to 100 % inert gas in air.
4 ple ready for analysis. This ensures that the sample, calibration
and inert gases are fed into the analyzers at the right pressure
and flow rate, and without having been mixed with other gases.
The skid is fully equipped with a flame arrestor, stopcock ball
valve, stainless steel overflow regulator, single-stage pressure
reducer, stainless steel 5-way transfer ball valve, all-metal flow
meter for air, 1-channel isolating switch amplifier and installation
material. The flowmeters are designed to transmit a limit monitor-
ing signal. The connection is made on-site.
The test gas skid guarantees that all the requirements in terms
of safety, quality and simplicity are satisfied when connecting
sample, calibration and inert gases.
Installation frame
The installation frame is a supplementary feature of the set. It en-
ables free-standing installation of the analyzer cabinet and test
gas skid.
The installation frame is supplied in a fully assembled state (in-
cluding feet). Its overall height is 2 000 mm.

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Analytical Application Sets


Continuous monitoring of hydrogen-cooled generators
Set GGA

■ Technical specifications
Climatic conditions Measuring response (relating to sample gas pressure 1 013 hPa absolute,
0.5 l/min sample gas flow and 25 °C ambient temperature)
Ambient temperature 5 ... 50 °C
Output signal fluctuation < ± 0.75% of the smallest possible
Relative humidity 70 %, non-condensing measuring range according to rating
Corrosive atmosphere No plate, with electronic damping con-
stant of 1 s ( = 0.25%)
Gas inlet conditions
• Calomat 6E Zero point drift < 1%/week of the smallest possible
span according to rating plate
- Sample gas pressure 800 ... 1 100 hPa (absolute)
Measured-value drift < 0.5%/of the smallest possible span
- Sample gas flow 30 ... 90 l/h (0.5 … 1.5 l/min) according to rating plate
• Test gas skid
Repeatability < 1% of the current measuring range
- Sample gas pressure 55 000 hPa (absolute)
Detection limit 1 % of the current measuring range
- Sample gas flow 30 … 90 l/h (0.5 … 1.5 l/min)
Linearity error < ± 1 % of the current measuring
Power supply
range
• Supply 1 200 ... 240 V AC, 47 ... 63 Hz
• Supply 2 100 ... 120 V AC, 47 ... 63 Hz Influencing variable (relating to sample gas pressure 1 013 hPa absolute,
0.5 l/min sample gas flow and 25 °C ambient temperature)
• Supply 3 24 V DC for switch amplifiers
Ambient temperature < 1%/10 K referred to smallest possi-
Type of connections ble span according to label
Pipe material Stainless steel
Accompanying gases Deviation from zero point
Connections/components • Metric (6 mm) Sample gas flow < 0.1% of the smallest possible span
• Imperial (¼") according to rating plate with a
Cabling change in flow of 0.1 l/h within the
permissible flow range
Electrical design According to IEC
Sample gas pressure < 1 % of the current measuring range
Type of cables
Cable ID
Non-armored cables
No single core labeling Power supply
with a pressure change of 100 hPa
< 0.1 % of the current measuring
4
Installation range with rated voltage ± 10 %

Site Interior
Ex-zone analyzer ATEX II, 3G
System design
Version Cabinet
Degree of protection IP54
Automatic calibration No
Signal outputs 4 ... 20 mA/isolated contact
Max. 24 V AC/DC 1 A
With sample gas return flow On request

Generator gas analyzer


Analysis Measuring point designation Generator gas analyzer
Concentration Unit Measured Measuring range
component
Component Min. Typical Max. Small Large
Ar/CO2 in air 0 100 vol. % Yes 0 100
H2 in Ar/CO2 0 100 vol. % Yes 0 100
H2 in air 80 100 vol. % Yes 80 100
Sample temperature 50 °C
Dust content 0 mg/m3
H2O dew point -50 °C
Aggregate state, sample1) Gaseous
1) Standard state at 20 °C, 101.3 kPa

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Analytical Application Sets


Continuous monitoring of hydrogen-cooled generators
Set GGA

Selection and ordering data Article No.


Set GGA 7MB1950- 7 7 7 0 7 - 7 7 7 7 Cannot be combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Gas connections
6 mm pipe 0
1/4" pipe 1
Version
H2 monitoring (turbo generators) GA
Add-on electronics
Without 0
Auxiliary power
100 ... 120 V AC, 47 ... 63 Hz 0
200 ... 240 V AC, 47 ... 63 Hz 1
Variants
Set GGA, cable glands M20x1.5 power supply with cable diameter of 6 ... 12 mm A
(e.g. in accordance with EMT674-057, EMT674-059)
Set GGA, with test gas skid, cable glands M20x1.5 power supply with cable diame- B
ter of 6 ... 12 mm (sampling unit on stainless steel plate), delivery batch in 2 parts
Set GGA, cable glands M25x1.5 power supply with cable diameter of 14 ... 18 mm C
(e.g. in accordance with EMT674-070, EMT674-071)
Set GGA, with test gas skid factory-assembled on mounting frame, cable glands E

4
M20x1.5 power supply with test gas skid (PA on stainless steel plate), ready mounted
on frame, delivery batch 1 part
Explosion protection
Certificate: ATEX II 3G, flammable and non-flammable gases B
Documentation
German 0
English 1
French 2
Spanish 3

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Analytical Application Sets


Continuous monitoring of hydrogen-cooled generators
Set GGA

■ Dimensional drawings

685 615

CALOMAT
Siemens

MKG31 CQ001

612
Siemens

MKG32 CQ001

Line
pressure
-FA1 -FA2
regulator
Protective casing 110
130
2000

5-way
1900

ball valve -PF1


Flame
-QR1
-RB4 arrestor
-PF2
-QR2 -FA3 Mounting rack
630

-RB5
(screwed)
4
Stopcock
1300

ball valve

Flow meter
Test gas skid Test gas skid
-SV1 -SV2
-RB1 -RB2 -RB3

40
Low-pressure
910
overflow regulator

Test gas skid, fully piped with VA pipe 6 x 1


Weight: 115 kg

Set GGA, dimensions in mm, figure corresponds to 7MB1950-0GA00-1EB0

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Analytical Application Sets


Determination of the quality of natural gas
Set CV
Such a system can be used wherever the quality of natural gas
■ Overview has to be determined. For example, during the conditioning of
natural gas and feeding into the pipeline network, during trans-
portation and distribution in the network, and when extracting it
for supply purposes.

■ Design
Standardization of systems means good clarity and simple facil-
ities for configuration. Different versions mean that it is possible
to appropriately adapt the system to the requirements. The mod-
ules can be combined as desired. Standardization also means
that not all imaginable versions are included, and that special re-
quirements such as armored cables, customer-specific docu-
mentation, specific conductor labeling, or certificates such as
CE or 31B cannot be implemented at all, or not without an extra
charge.
The design is divided into the following standard modules: sam-
pling, pressure reduction, sample preparation system,
SITRANS CV, gas supply, calibration gases.
The Set CV (Calorific Value) is a standardized system for deter-
mining the quality of natural gas with SITRANS CV and
MicroSAM.
Gas supply
station
■ Benefits
Standardized complete system
4 • Easily and quickly configured, from sampling to the gas
supply
• Field-proven, harmonized and reliable set
• Suitable for determining the natural gas quality with high Sampling Sample SITRANS CV Flow
accuracy probe preparation computer
CV Control SW
Field-proven, reliable technologies
• Version with German Federal Testing Authority certification
(without mass memory, without DSfG) available for fiscal
metering
• GC MEMS technology with low consumption levels, high
linearity/accuracy over the entire measuring range, and short
cycle times
General information
Easy installation
The set can be dimensioned for a 230 V AC or 115 V AC power
• Installation in EEx Zone 1 possible supply. It is not possible to switch between supplies.
• Compact and rugged design for erecting indoors and
The gas connections can be supplied with either metric or impe-
outdoors
rial dimensions.
• Minimum space requirements
On the metric line, the gas connections are in the form of metric
clamping ring glands with a diameter of 3 mm. The imperial line
■ Application contains gas connections in the form of imperial clamping ring
For the chromatography industry, the natural gas market is one glands with a diameter of 1/8 inch. The pipes between the sam-
of the fastest growing in the world. There are a variety of reasons pling probe, pressure reduction, sample preparation device,
for this. While global energy requirements are increasing, there and SITRANS CV are optionally available. The system is gener-
is a parallel trend of fossil fuel reserves being depleted. Natural ally designed for temperatures between -20 and +55 °C in areas
gas is one type of fossil fuel that can still be found in vast, un- with a risk of explosions. When provided with heating, the sys-
tapped reserves. In addition to this, the market is becoming in- tem can also be used down to -30 °C. The natural gas to be mea-
creasingly liberalized, and the number of participants has risen sured should be in a stable gaseous form, dry and clean.
considerably as a result - from the production stage, across the Sampling probe
entire distribution network, right through to the end customer. In
turn, this has generated more transfer points at which the quality The basic components of a sampling probe are a lance, process
and quantity of natural gas need to be determined for account- connection, process isolation and, if necessary, pressure reduc-
ing purposes. tion. The high-pressure version is not supplied pre-assembled.
The market requires a reliable complete system which is spe- Lance
cially designed for natural gas. With the Set CV, Siemens offers A representative sample should be taken from the central third
a system that covers all the requirements of such applications, of the pipeline. With a lance length of 1 m it is therefore possible
from sampling to pressure reduction, sample preparation and to extract a sample from a pipeline with a diameter of up to
determination of quality, supplying carrier and calibration gases, 1 600 mm. In addition, two versions with different types of lance
right through to expansion of the communication interfaces. diameter are available. On the one hand, a pipe whose outer di-
The set offers various modules to cover market requirements. ameter is 6 mm and inner diameter is 2 mm. And on the other, a
Using the different versions, the set can be adapted, and the pipe whose outer diameter is 12 mm and inner diameter is 8 mm.
modules can be freely-combined. The lance can be supplied in a permanently installed or remov-
able state (not for 12 mm).

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Analytical Application Sets


Determination of the quality of natural gas
Set CV
Process connection
There are four versions for the flange connection to the pipeline.
Flange DN 65 PN16 Form C for pressures up to 1 600 kPa,
flange ANSI 2" for pressures up to 300 lbs RF as well as flange
DN 65 PN160 Form E for pressures up to 16 000 kPa and flange
ANSI 2" for pressures up to 2 500 lbs RF.
Process isolation
It may be necessary to isolate the natural gas line from the sys-
tem for maintenance and repair work. To do this, you can select
either a simple stopcock or a double block and bleed structure.
While the stopcock is a cost-effective solution for minimum re-
quirements, the double block and bleed structure stands for en-
hanced safety, as it has two valves that prevent any gas from be-
ing transferred further.
High-pressure reduction on the primary side
Pressure can be reduced in three ways: directly at the probe
(primary side), in an external casing with a pressure reduction
unit (primary side), or in the sample preparation system (sec- Sample preparation
ondary side).
The permissible sample and calibration gas pressure is 10 to
If the sample preparation system and the natural gas chromato- 60 kPa above atmospheric pressure. Notice: Sample must not
graph are installed directly next to the sampling point, the high- contain ethine!
pressure reduction can be implemented in the sample prepara-
tion system. The pressure should always be reduced as close to The incoming carrier gas pressure must range from 500 to
the sampling point as possible in order to keep the dead volume 700 kPa (g). 600 kPa (g) is recommended. Important: A contin-
as small as possible. The permissible sample and calibration uous carrier gas supply is required for error-free operation (fre-
gas pressure is 10 to 60 kPa above atmospheric pressure. No-
tice: Sample must not contain ethine!
quent carrier gas failure has a negative effect on the durability of
the detectors and the device-internal pressure settings). In ad- 4
dition, an external two-step pressure regulator for the carrier gas
The incoming carrier gas pressure must range from 500 to pressure is strongly recommended.
700 kPa (g). 600 kPa (g) is recommended. Important: A contin-
uous carrier gas supply is required for error-free operation (fre- The basic configuration of the sample preparation system for a
quent carrier gas failure has a negative effect on the durability of stream includes a stopcock, 0.5 µm filter, flowmeter for the fast
the detectors and the device-internal pressure settings). In ad- loop, pressure-relief valve, 3/2-way solenoid valve with sealed
dition, an external two-step pressure regulator for the carrier gas cable for automatic switching between calibration gas and sam-
pressure is strongly recommended. ple gas, and a terminal box for connecting the solenoid valve.
This solenoid valve must either be protected by the customer at
Heated and unheated pressure reduction units are available in 0.5 A, or a ready-assembled terminal box with power supply and
the external casing for high-pressure reduction on the primary fuses can be ordered from the list of supplementary items.
side. Pressure reduction in the external casing is suitable for
combination with the permanently installed and retractable stan- There are also a number of other options for modifying the basic
dard probe. The heated pressure regulators have a power con- configuration.
sumption of 150 W, and reliably maintain the sample in a gas- Secondary pressure adjustment
eous state.
The pressure adjustment unit with unheated pressure regulators
Special probe with high-pressure reduction can be ordered for one, two and three sample flows. This type of
A third option offers an alternative to the two standard probes: a structure meets the minimum secondary pressure adjustment
permanently installed probe with integrated separation of aero- requirements. Please note that a reduction in pressure cools the
sols (so-called BTU diaphragm) in the pipeline and a pressure sample down considerably, which can cause moisture to con-
reduction unit. The lance is integrated in this at a depth of dense if the dew point is fallen below.
228 mm. The protection pipe has an outer diameter of 22.8 mm. Another alternative, however, is pressure adjustment with a
The lance and pressure reduction do not need to be separately heated pressure regulator (150 W) for one, two or three sample
defined. streams. Heating the sample ensures that it remains in a gas-
Heated pipeline eous state. The Joule-Thomson effect is thus compensated. The
regulators can reduce pressures from 16 to 100/170 kPa.
To ensure that the sample is maintained in a gaseous state, it is
recommendable to use a heated sample gas line – for example, If the pressure is to be reduced directly at the sampling probe or
between the sampling point and the sample preparation system. in an external casing outside the sample preparation system, no
The pipeline is encased in a PE corrugated hose with an outer further pressure reduction is required during sample prepara-
diameter of 43 mm. The self-regulating maintenance tempera- tion.
ture remains at approximately 80 °C. The electrical connection is
in the terminal box.
The power consumption is approx. 38 W/m.
Pipe base for enclosure attachment
A hot-dip galvanized 2" pipe base, 1 700 mm high, with mount-
ing brackets and joining sheet enables free-standing mounting
of the protective casing.

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Analytical Application Sets


Determination of the quality of natural gas
Set CV
Sample injection Protective top cover
Where sample injection is concerned, straightforward and safety Another option is a protective top cover made from fiber glass-
versions are available for between one and three streams. reinforced plastic and supplied with mounting brackets, for pro-
tection against solar radiation and storms. It must be mounted to
Considered simply, sample injection is carried out for one, two or a pipe base.
three streams using one solenoid valve per sample stream (cas-
cade connection). Its job is to block any gas flows that are not Heated sample gas line
required without preventing the desired gas from flowing. A
0.5 A fuse is required per solenoid valve and flowmeter. These To prevent condensation of the sample, it may be necessary to
are available in the ready-assembled terminal box. use a heated prepared pipeline – for example, between the sam-
ple preparation device and SITRANS CV/MicroSAM. The pipe-
The safety version of the sample injection system for one, two or line is encased in a PE corrugated hose with an outer diameter
three streams with double block and bleed technology enables of 43 mm. The self-regulating maintenance temperature is
the sample to be switched over, which in turn allows clean sep- around 80 °C.
aration between gas streams by partially closing and venting the
line. Since two valves are used to prevent the flow of gas that is
not to be measured, rather than just one, the functional safety of
the system remains at an optimum level for a long time. In addi-
tion, 0.5 A fuses are required for the sample valves and calibra-
tion valve. These are included in the electrical connection (sup-
plementary item).
Monitoring the sample gas monitoring chromatograph (GC)
The sample flow to the GC can also be monitored electronically
as an option. An alarm signal is output when necessary. A switch
disconnector for the power supply is also required; this can be
ordered along with the ready-assembled terminal box.
Protective casing/mounting plate for sample preparation system
4 The sample preparation system is available mounted either on a
plate, in the protective casing, or in the heated protective casing.
The stainless steel mounting plate, measuring 682 x 482 x 3 mm
(H x W x D), is suitable for wall mounting. The system compo-
nents selected are mounted on the plate and supplied with all Example of single-stream sample preparation system: may deviate from
pipes and wires installed. the supplied system
The unheated protective transmitter box, made from fiber glass- SITRANS CV/MicroSAM
reinforced plastic and suitable for wall mounting measures
800 x 600 x 480 mm (H x W x D) and is fitted with stainless steel The core component of the Set CV is the GC SITRANS CV/
hinges, quick-release locks, safety glass windows and a stain- MicroSAM (for more detailed information see catalog PA 01,
less steel mounting plate. section 3).

The system components selected are mounted and supplied SITRANS CV/MicroSAM system components
with all pipes and wires installed in the protective casing. Protective casing/plate for SITRANS CV/MicroSAM
It is also possible to provide a heater in the protective transmitter The SITRANS CV/MicroSAM is available mounted either on a
box which can be controlled between 10 and 40 °C in steps of plate, in the protective casing, or in the heated protective casing.
5 degrees. The system components selected are mounted and
supplied with all pipes and wires installed in the protective cas- The stainless steel mounting plate, measuring 682 x 482 x 3 mm
ing. The heating has a power of 400 W. (H x W x D), is suitable for wall mounting.
Aerosol filter/glycol filter The unheated protective transmitter box, made from fiber glass-
reinforced plastic and suitable for wall mounting measures
These filters have the task of removing any impurities that may 800 x 600 x 480 mm (H x W x D) and is fitted with stainless steel
have been introduced into the natural gases by aerosols or gly- hinges, quick-release locks, safety glass windows and a stain-
cols, thus providing an additional level of safety for the less steel mounting plate.
SITRANS CV and, therefore, the system functionality. The aero-
sol filter is supplied with 5 replacement diaphragms and the gly- The protective casing can also be supplied with heating as an
col filter with 10 replacement cartridges. option. The heating can be adjusted between 10 and 40 °C, in
increments of 5. The system components selected are mounted
Manual laboratory sampling and supplied with all pipes and wires installed in the protective
An additional control valve permits manual laboratory sampling casing. The heating has a power of 400 W.
as an option. When not in use, it is fitted with a blanking plug on
the output end.
Pipe base for enclosure attachment
A hot-dip galvanized 2" pipe base, 1 700 mm high, with mount-
ing brackets and joining sheet enables free-standing mounting
of the protective casing or the mounting plate as an alternative
to wall mounting.

4/60 Siemens PA01 · 2015


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Analytical Application Sets


Determination of the quality of natural gas
Set CV
Terminal box Automatic cylinder changeover switch with separate coils
There are five connection options in total to choose from: The stainless steel automatic cylinder changeover switch, sup-
plied on a mounting plate, is designed for back pressures of be-
The simplest option is the interface in accordance with tween 50 and 1 000 kPa and contains two coiled pipes for he-
SITRANS CV/MicroSAM (open cable end). lium that conform to DIN 477. The maximum permissible
The terminal box with the dimension of 340 x 170 x 91 mm cylinder pressure is 20 000 kPa. This version also includes a
(H x W x D) is made from polyester resin. The scope of delivery gauge for measuring primary and back pressure. A contact
includes terminals, isolating terminals, cable glands and a PE gauge cannot be fitted when supplied separately.
rail. If ordered with the pipe base add-on part, the terminal box Simple supply unit
is supplied attached to the base, and the scope of supply in-
cludes 2.5 mm² terminals for connection by the customer and This simple supply unit consists of a hot-dip galvanized 2-inch
M16/M20 cable glands. The power supply is 24 V DC. The ter- pipe base, 2 200 mm high, with a fiber glass-reinforced plastic
minal box is not suitable for connecting a heater, flow meter with protective top cover as well as two cylinder holders and a cylin-
limit value transmitter, and Double Block and Bleed (DB&B). der changeover switch. The gas cylinders are not included in the
basic scope of supply.
The terminal box with the dimension of 360 x 360 x 190 mm
(H x W x D) is made from painted sheet steel. The scope of de- Painted sheet steel gas cylinder cabinet
livery includes switch amplifiers, terminals, and cable glands. If
ordered with the pipe base add-on part, the terminal box is sup- This version is supplied with the automatic cylinder changeover
plied attached to the base, and the scope of supply includes switch and coils, as well as the stainless steel calibration gas
2.5 mm² terminals for connection by the customer and M16/M20 cylinder pressure reducer in a sheet metal cabinet.
cable glands. The power supply is 24 V DC. The terminal box is The gas cylinder cabinet has room for two 50 l cylinders and one
not suitable for connecting a heater and DB&B. 10 l calibration gas cylinder. The dimensions are 2 050 x 1 250 x
The terminal box, including switch amplifier and a power supply 400 mm (H x W x D). It contains the cylinder station, a stopcock
(115 V AC or 230 V AC, not switchable), with the dimension of for carrier gas, cylinder holder and pipe coils for the gas cylin-
360 x 360 x 190 mm (H x W x D), is made from painted sheet ders. The cabinet pipes are fully installed and the cabinet is
steel. The scope of delivery includes terminals, 0.5 A fuses, ter- equipped with bulkhead fittings for carrier gas, calibration gas
and exhaust gas from the pressure relief valves.
4
minals, cable glands and a PE rail. If ordered with the pipe base
add-on part, the terminal box is supplied attached to the base, As an option, this gas cylinder cabinet can also be supplied with
and the scope of supply includes 2.5 mm² terminals for connec- heating from a heating sleeve for a 10 l calibration gas cylinder
tion by the customer and M16/M20 cable glands. The terminal at 20 °C retaining temperature. The cylinder head is heated sep-
box is not suitable for using DB&B. arately, in a fiber glass-reinforced plastic enclosure. The cylinder
The terminal box, including switch amplifiers and a power sup- pressure reducer is also located here. The heating sleeve pre-
ply (115 V AC or 230 V AC, not switchable), with the dimension vents condensation from building up in the gas cylinder. To en-
of 360 x 360 x 190 mm (H x W x D), is made from painted sheet sure seamless gas heating, a heated line for accepting the cali-
steel. The scope of delivery includes isolating terminals, 0.5 A bration gas is recommended.
fuses, terminals, cable glands, relays and a PE rail. If ordered
with the pipe base add-on part, the terminal box is supplied at-
tached to the base, and the scope of supply includes 2.5 mm²
terminals for connection by the customer and M16/M20 cable
glands.
Gas supply
A gas chromatograph requires calibration and carrier gases.
Therefore the set offers various options with regard to gas con-
nection, gas cylinder design, and calibration gases. Either indi-
vidual components or complete systems can be ordered.
Cylinder pressure reducer, separate
The cylinder pressure reducer for calibration gases is supplied
separately. It is made from stainless steel and has a cylinder
connection conforming to DIN 477 No. 14 (calibration gas). The
cylinder pressure reducer is also fitted with a gauge for primary
and back pressure.
Contact gauge for supply gases
Two gauges with a 50 mm diameter and mounted on the battery
pressure reduction station can also be ordered. The intrinsically-
safe slot initiators in accordance with NAMUR must be operated
via a switch amplifier. This is not included in the delivery. The line
is in the terminal box on the station panel.
Heated line
A heated prepared line is available for heating the calibration
gas line from the cylinder cabinet to the sample preparation de-
vice. The power consumption is 38 W/m with an outer diameter
of 43 mm on the corrugated hose. The integrated heating system
is self-regulating with a maintenance temperature of approxi-
mately 80 °C.

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Analytical Application Sets


Determination of the quality of natural gas
Set CV
Calibration gases
■ Function
Six different calibration gases are available as standard.
It is the job of the sampling probes to take a representative sam-
Compo- C6+ with C6+ with- C6+ with- C7+ with- C6, C7, Bio- ple from the pipeline. It is important to ensure that this sample is
nent O2 out O2 out O2 out O2 C8, C9 methane extracted from the central third of the pipeline. One advantage
groups without with H2 of the retractable probes is that there is no risk of damage being
O2
caused to them when pigging is taking place in the pipeline.
Special Certified There is also the option of reducing pressure directly at the sam-
feature in acc. pling probe. This is especially advisable if sample preparation
with PTB-
A 7.63 and gas analysis are not carried out directly next to the sampling
point.
(mol %) (mol %) (mol %) (mol %) (mol %) (mol %)
As a general rule, implementing a reduction in pressure reduces
Hydrogen 0.20
the sample pressure to between 10 kPa and 500 kPa. Heated
Nitrogen 4.00 4.00 4.00 4.00 4.00 4.00 pressure regulators must be used if the dew point could be fallen
Carbon below in the process.
monoxide
In the sample preparation system, pressure reducers and flow-
Carbon 1.50 1.50 1.50 1.50 1.50 2.50 meters can be used to set the sample flow and pressure that will
dioxide ultimately be required. Electronic monitoring of the sample flow
Oxygen 0.50 0.40 transmits an alarm signal to the SITRANS CV/MicroSAM if nec-
Methane 88.40 88.90 88.90 88.80 88.86 88.40
essary. The filters ensure that the sample is appropriately clean.
An optional double block and bleed (DB&B) arrangement of the
Ethane 4.00 4.00 4.00 4.00 4.00 2.50 solenoid valves can ensure extremely safe isolation between the
Ethene sample streams and the calibration gas. All versions of the sam-
Propane 1.00 1.00 1.00 1.00 1.00 1.00
ple preparation system are available for one, two or three flows
plus the calibration flow.
Isobutane 0.20 0.20 0.20 0.20 0.20 0.50
The prepared sample is then analyzed in the natural gas ana-
4
n-butane 0.20 0.20 0.20 0.20 0.20 0.50
lyzer and the calorific value, standard density and Wobbe index
Neopen- 0.05 0.05 0.05 0.1 0.1 are calculated. Connecting the SITRANS CV/MicroSAM to a flow
tane computer enables an energy value to be calculated from the
Isopen- 0.05 0.05 0.05 0.05 0.05 measured quality and quantity with consideration of the pres-
tane sure, temperature and flow measurement. SITRANS CV is pref-
n-pentane 0.05 0.05 0.05 0.05 0.05 erably used in connection with flow computers. For the use of
MicroSAM, please consult the parent company.
n-hexane 0.05 0.05 0.05 0.05 0.01
n-heptane 0.05 0.01
In order to regularly carry out calibration and supply carrier gas
to the SITRANS CV/MicroSAM, gases that are typically found in
n-octane 0.01 shelving or cabinet structures must be made available. Heating
n-nonane 0.01 the gas cylinders prevents condensation from building up in
them. The gas cylinder transfer station enables the cylinders to
be exchanged during operation. Individual cylinders can be
connected and disconnected by means of valves.
The communication functionalities of the SITRANS CV can be
extended using a SIMATIC Extension Unit. It is then possible to
connect a further Modbus master and/or up to 16 AO. For the
generation of analog outputs in combination with MicroSAM, we
recommend the I/O Extender solution (see catalog PA 01, sec-
tion 3)

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Analytical Application Sets


Determination of the quality of natural gas
Set CV

■ Technical specifications
General information System components
Ambient temperature -30 ... 55 °C (with heating) On mounting plate 682 x 482 x 3 mm
Explosion protection ATEX Category II 2G, T3 In protective casing 800 x 600 x 480 mm
Supply voltage 230 V AC, 115 V AC or 24 V DC Protective casing heating Power consumption 400 W
Max. permissible pressure at 16 000 kPa Adjustable between 10 and 40 °C, in incre-
input of high-pressure reduc- ments of 5.
tion Terminal box 340 x 170 x 91 mm
Max. permissible pressure at 16 000 kPa Pipe base 2-inch pipe base, 1700 mm high
input of sample preparation
system with pressure regula- Heated line Heating power is 38 W per meter
tor
Self-regulating heating up to approximately
Max. permissible pressure at 10 ... 60 kPa above atmospheric pressure 80 °C
output of sample preparation Notice: Sample must not contain ethine!
Outer material is PE
system
corrugated hose with 43 mm outer diameter
Sampling
Gas supply
Lance Outer diameter 6 mm and inner diameter
2 mm Transfer station Max. cylinder pressure 20 000 kPa
or outer diameter 12 mm and inner diameter Output pressure 50 ... 1 000 kPa
8 mm Pipe base 2-inch pipe base, mounted
Length 1 000 mm8 Height 2 200 mm
Special probe with BTU dia- Immersion depth approx. 380 mm Gas cylinder cabinet Gas cylinder cabinet for two 50 l carrier gas
phragm and pressure reduc- Protection pipe outer diameter 25.4 mm cylinders and one 10 l calibration gas cylin-
tion, non-retractable der. Dimensions are 1 250 x 400 x 2 050 mm
Process connection At flange DN65 PN16 Form C, Cylinder heating The cylinder heating system is dimensioned

4
max. 1 600 kPa gas pressure for 10 l calibration gas cylinders and ensures
At flange DN65 PN160 Form E, that no condensation occurs within the gas
max. 16 000 kPa gas pressure cylinder.
At flange ANSI, 2-inch, 300 lbs RF Cylinder pressure reducer Cylinder pressure reducer for reducing pri-
At flange ANSI, 2-inch, 2 500 lbs RF mary pressure of max. 30 000 kPa to back
pressure 0 … 400 kPa
High-pressure reduction in Casing with dimensions 385 x 485 x 380 mm
casing with pressure regula- Primary pressure 16 000 kPa, output pres- Heated line Heating power is 38 W per meter
tors, optional heating Self-regulating heating up to approximately
sure 100/170 kPa (power consumption 150 W) 80 °C
Pipe base 2-inch pipe base for free-standing transmitter Outer material is PE
box, 1 700 mm high corrugated hose with 43 mm outer diameter
Heated line Heating power is 38 W per meter Calibration gas
Self-regulating heating up to approx. 80 °C
Outer material is PE corrugated hose with Gas mixture 1 ... 6 The gas mixture is stable for 36 months.
43 mm outer diameter

Sample preparation for 1 to 3 sample gas flow, plus calibration gas flow
Basic configuration 0.5 µm filter, 3/2-way solenoid valve, flowme-
ter, overflow valve and stopcock
Pressure regulator, optional Primary pressure 16 000 kPa, output pres-
heating sure 100/170 kPa (power consumption 150 W)
Simple sample injection One 3/2-way solenoid valve per sample gas
stream
DB&B sample injection Two 3/2-way solenoid valves per sample gas
flow
On mounting plate 652 x 422 x 3 mm
In protective casing 750 x 520 x 430 mm
Protective casing heating Power consumption 300 W
Adjustable between 10 and 40 °C, in incre-
ments of 5
Pipe base 2-inch pipe base, 1 700 mm high
Additional filters Aerosol, glycol

Siemens PA01 · 2015 4/63


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Analytical Application Sets


Determination of the quality of natural gas
Set CV

Selection and ordering data Article No.


CV set, probe (supplied separately) and high-pressure reduction 7KQ2150- 7 7 7 7 7 - 7 7 7 Cannot be combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Explosion-proof version, in accordance with ATEX 0
Supply voltage
Without A A A A B03,
230 V AC B C03
115 V AC C
Pneumatic connections
Metric A
Imperial B
Lance (length always 1 m)
Without 0
OD/ID 6 mm/2 mm 1
OD/ID 12 mm/8 mm 2
Process connection
Without 0
Flange DN 65 PN16 Form C 1
Flange DN 65 PN160 Form E 2
Flange ANSI, 2", 300 lbs RF 3

4 Flange ANSI, 2", 2 500 lbs RF 4


Analysis isolation
Without 0
Stopcock 1
DB&B 2 2
Probe installation
Without A
Standard (without pressure reduction) B
Removable (without pressure reduction) C
Special installation (with pressure reduction) D
High pressure reduction
Without A
Separate high-pressure reduction box with mech. pressure regulators B
Separate high-pressure reduction box with evaporation pressure regulator C C
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Base for high-pressure reduction device B01
Protective top cover GRP B02
Preparation of heated line B03
Heated line from the high-pressure reduction box to the sample preparation device C03
(C03 + C03 = 2 m)
Separate stainless steel pipe 3 x 0.5 mm in 5 m intervals for connection to the sample C04
preparation device (example: C04 + C04 = 10 m)

4/64 Siemens PA01 · 2015


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Analytical Application Sets


Determination of the quality of natural gas
Set CV

Selection and ordering data Article No.


Sample preparation device, basic configuration 7KQ2151- 7 7 7 7 7 - 77 Cannot be combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Explosion-proof version, in accordance with ATEX 0
Supply voltage
Without A A A A
230 V AC B
115 V AC C
Pneumatic connections
Metric A
Imperial B
Pressure adjustment
Without 0
Pressure regulator unheated for 1 sample flow 1
Pressure regulator unheated for 2 sample flows 2
Pressure regulator unheated for 3 sample flows 3
Pressure regulator heated for 1 sample flow 4 4
Pressure regulator heated for 2 sample flows 5 5
Pressure regulator heated for 3 sample flows 6 6
Sample gas pump (Ex) für 1 sample flow 7
Sample injection 4
Without 0
Standard for 1 sample flow (automatic) 1
Standard for 2 sample flows (automatic) 2
Standard for 3 sample flows (automatic) 3
For 1 sample flow in DB&B technology (automatic) 4 4
For 2 sample flows in DB&B technology (automatic) 5 5
For 3 sample flows in DB&B technology (automatic) 6 6
Monitoring the sample gas flow to the gas chromatograph
Visual, mechanical monitoring 0
With electrical monitoring 1
Plate/enclosure
Without A
Mounting plate for wall mounting B
GRP protective casing (unheated) for wall mounting C
GRP protective casing (heated) for wall mounting D D
GRP protective casing (unheated) mounted on base E
GRP protective casing (heated) mounted on base F F
Mounting plate mounted on base G
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Aerosol filter per sample flow with 5 replacement diaphragms A01
Glycol filter per sample flow with 10 replacement cartridges A02
Manual lab sampling per sample flow A03
Connection of second calibration gas through solenoid valve A04
Protective top cover GRP B01
Replacement filter element for sample flow filter (5 units) E01

Siemens PA01 · 2015 4/65


© Siemens AG 2014

Analytical Application Sets


Determination of the quality of natural gas
Set CV

Selection and ordering data Article No.


System components 7KQ2152- 7 7 7 7 7 Cannot be combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Explosion-proof version, in accordance with ATEX 0
Supply voltage
230 V AC A
115 V AC B
24 V DC C C C C B03, C01
Pneumatic connections
Metric A
Imperial B
Plate/enclosure SITRANS CV
Without 0
On plate, with stopcock and connection pieces 1
In the GRP protective casing, unheated 2
In the GRP protective casing, heated 3 3
Electrical connection
Interface in accordance with technical data of SITRANS CV (free cable end) 0
Ex terminal box with standard terminals; 24 V DC connection 1
Ex terminal box with electrical sample gas monitoring; 24 V DC connection 2

4 Ex terminal box with electrical sample gas monitoring and standard sample injection;
115/230 V AC connection
3 3

Ex terminal box with electrical sample gas monitoring and DB&B sample injection; 4 4
115/230 V AC connection
Additional versions Order code
Add "-Z" to Article No. and specify Order code
Pipe bases for securing the enclosure without mounting plate/box B01
Protective top cover GRP B02
Preparation of heated line B03
Heated line for sample preparation device/SITRANS CV (C01 + C01 = 2 m) C01
Installation kit (pipe/glands/cable) for connecting to the sample preparation device C02
Separate stainless steel pipe 3.0 x 0.5 mm or 3.18 x 0.56 mm (continuous) C03
at 5 m intervals (example: C03 + C03 + C03 = 15 m)

4/66 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Determination of the quality of natural gas
Set CV

Selection and ordering data Article No.


Gas supply 7KQ2153- 7 7 7 7 7 Cannot be combined
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Explosion-proof version, in accordance with ATEX 0
Supply voltage
Without A A C01
230 V AC B
115 V AC C
Pneumatic connections
Metric A
Imperial B
Automatic transfer station (stainless steel) with coils
Without 0
Installed on the mounting panel 1
Installed on the base 2
Installed in the metal cabinet 3
Installed in the metal cabinet with calibration gas cylinder heating 4
Cylinder pressure reducer for calibration gas
Without 0
Separate 1
Installed (base/metal cabinet) 2 4
Additional versions Order code
Add "-Z" to Article No. and specify Order code
2 contact pressure gauges for transfer station A01
Preparation of heated line B03
Heated line for calibration gas from the cylinder cabinet to the sample preparation C01
device (only with 115 V/230 V); length per meter (C01+C01 = 2 m)
Separate stainless steel pipe 3.0 x 0.5 mm or 3.18 x 0.56 mm (continuous) at 5 m C02
intervals (example: C02+C02+C02=15 m)

Selection and ordering data Article No.


Calibration gas for SITRANS CV 7KQ2158- 0 A 7 0 0
Calibration gas in 10 liter cylinder
Mixture 1 B
Mixture 2 C
Mixture 3 D
Mixture 4 E
Mixture 5 F
Mixture 6 G

Siemens PA01 · 2015 4/67


© Siemens AG 2014

Analytical Application Sets


Analyzer System Manager
Set ASM

■ Overview ■ Application
The ASM is a PC-based HMI system for monitoring, testing and The ASM is ideal for all systems and plants where high reliability
administration of analyzers in subsystems or in the complete of the measured values and documentation of the analyzer per-
plant. The relevant information of the analyzers is collected over formances are required. Using the communications network, re-
a uniform communications network and saved in a central data- mote analyzers can also be monitored from a central worksta-
base. By means of the PC's user-friendly operator interface it is tion.
possible to access measured-value trends, device statuses and
statistical evaluations, among others, or to start test routines for The ASM is particularly suitable for use in the oil & gas, petro-
validation of the results. A comprehensive reporting module is chemical, and chemical industries, and can be applied in new
available to document the evaluations. plants or also in existing plants to optimize the analyzer land-
scape.
■ Benefits ■ Design
• Monitoring, testing and administration of many different types
of analyzers using one system System design
• Visualization and operation using a single-user system up to • PC-based HMI system
distributed multiuser systems with redundant servers • Visualization and operation possible using a single-user
• Assessment of the measured-value reliability through system up to distributed multi-user systems with redundant
checking of the analyzers using various validation routines, servers
e.g. based on the industry standard ASTM D 3764 • Logging and archiving of process and system data in a central
• Increase in analyzer online time through use of the line sample database
method • Integration of different analyzers in a uniform communications
• Statistical evaluation of operating statuses and determination network
of key performance indicators (KPI) such as availability, error
rate and maintenance frequency System software
• Siemens SIMATIC WinCC for the HMI functions
4 • Reduction in maintenance costs through device-specific
planning, implementation and checking of maintenance work • Microsoft SQL Server for archiving and data collection
• Documentation of the performance of individual analyzers up • Microsoft Windows/ Windows Server as operating system
to the complete plant using the reporting module. The reports
can be saved in the ASM or exported for further use. Communication
• An Ethernet network is the basis for communication
• Integration of analyzers using PROFINET, ModbusTCP or OPC
data exchange
• Analyzes without a communication interface can be
integrated by connecting the signals to Siemens SIMATIC
components
• Data exchange with other systems possible using OPC
Networking
• Siemens Scalance Ethernet switches for design of electrical
and optical Industrial Ethernet in line and star structures;
design in ring structures is possible to increase the fail-safety
of the network
• Integration of the ASM in an existing Ethernet network may be
possible

View of the process module

4/68 Siemens PA01 · 2015


© Siemens AG 2014

Analytical Application Sets


Analyzer System Manager
Set ASM

■ Function
General information
The information of the analyzers is collected over the communi-
cations network and saved in the central ASM database for fur-
ther analysis. The ASM is accessed using a Windows worksta-
tion, and it is possible to navigate between overview displays,
device-specific displays, and general functions.

View of the maintenance module

Report: AnalyserPerformance
From: 02/02/2010 01:19:00 PM Until: 04/02/2010 11:19:00 AM

4
Shelter: AH-101
Analyser: 10-AT-105001

Key Performance Indicators:


Time Absolute Relative Rate Value

Online (TPRO) 41.33 h 93.71 % Availability 99.19 %

Checking 5.48 %
Checking (TCHK) 2.42 h 5.48 %
Breakdown 0.81 %
Breakdown (TBRK) 0.36 h 0.81 %

Overview of analyzers in a plant Reproducibility 96.3 %


Report: ValidationHistory
From: 02/02/2010 04:19:00 PM Until: 04/02/2010 11:19:00 AM

Shelter: AH-101
Analyser: 10-AT-105001

The ASM has the following function modules for each analyzer Calibrations:
Stream

Validation_20

Validation_20
Date / Time

04/02/2010 10:00:31 AM

04/02/2010 08:54:31 AM
Validation Procedure

Reference Sample Validation

Reference Sample Validation


Reference Bottle

Bottle4Anlz001

Bottle4Anlz001
Result

Valid

Valid

for carrying out the HMI tasks:


Validation_20 04/02/2010 07:51:41 AM Reference Sample Validation Bottle4Anlz001 Valid
Start Finish State
Validation_20 04/02/2010 06:45:41 AM Reference Sample Validation Bottle4Anlz001 Valid
03/02/2010 10:09:30 AM 03/02/2010 10:12:40 AM finished
Validation_20 04/02/2010 05:39:51 AM Reference Sample Validation Bottle4Anlz001 Valid
03/02/2010 11:14:30 AM 03/02/2010 11:15:00 AM finished
Validation_20 04/02/2010 04:36:51 AM Reference Sample Validation Bottle4Anlz001 Valid
03/02/2010 11:39:30 AM 03/02/2010 11:46:00 AM finished
Validation_20 04/02/2010 03:31:01 AM Reference Sample Validation Bottle4Anlz001 Valid

Validation_20 04/02/2010 02:25:11 AM Reference Sample Validation Bottle4Anlz001 Valid

Validation_20 04/02/2010 01:19:22 AM Reference Sample Validation Bottle4Anlz001 Valid

Module Task Validation_20

Validation_20

Validation_20
04/02/2010 12:16:02 AM

03/02/2010 11:10:11 PM

03/02/2010 10:07:11 PM
Reference Sample Validation

Reference Sample Validation

Reference Sample Validation


Bottle4Anlz001

Bottle4Anlz001

Bottle4Anlz001
Valid

Valid

Valid

Validation_20 03/02/2010 09:01:21 PM Reference Sample Validation Bottle4Anlz001 Valid

Validation_20 03/02/2010 07:55:31 PM Reference Sample Validation Bottle4Anlz001 Valid

Process Provides a detailed overview of the selected analyzer. The cur- Validation_20

Validation_20

Validation_20
03/02/2010 06:49:41 PM

03/02/2010 05:46:51 PM

03/02/2010 04:41:02 PM
Reference Sample Validation

Reference Sample Validation

Reference Sample Validation


Bottle4Anlz001

Bottle4Anlz001

Bottle4Anlz001
Valid

Valid

Warning

rent analyzer status, planned maintenance work, and configura- Validation_20

Validation_20

Validation_20
03/02/2010 03:35:11 PM

03/02/2010 03:29:22 PM

03/02/2010 09:31:01 AM
Reference Sample Validation

Reference Sample Validation

Reference Sample Validation


Bottle4Anlz001

Bottle4Anlz001

Bottle4Anlz001
Warning

Warning

Failed

tion data are displayed. The current measured values are Validation_20

Validation_20

Validation_20
03/02/2010 08:25:41 AM

03/02/2010 07:20:22 AM

03/02/2010 06:15:11 AM
Reference Sample Validation

Reference Sample Validation

Reference Sample Validation


Bottle4Anlz001

Bottle4Anlz001

Bottle4Anlz001
Warning

Warning

Warning

displayed in a table, historical values can be analyzed with the Validation_20

Validation_20

Validation_20
03/02/2010 05:09:52 AM

03/02/2010 04:07:31 AM

03/02/2010 02:59:11 AM
Reference Sample Validation

Reference Sample Validation

Reference Sample Validation


Bottle4Anlz001

Bottle4Anlz001

Bottle4Anlz001
Warning

Valid

Valid

trend display using selectable time windows.


Validation_20 03/02/2010 01:56:41 AM Reference Sample Validation Bottle4Anlz001 Valid

Validation_20 03/02/2010 12:51:12 AM Reference Sample Validation Bottle4Anlz001 Valid


Page: 1 / 1 Generating Date: 04/02/2010 05:36:49 PM Validation_20 02/02/2010 11:46:02 PM Reference Sample Validation Bottle4Anlz001 Valid

Validation_20 02/02/2010 10:40:41 PM Reference Sample Validation Bottle4Anlz001 Valid

Validation_20 02/02/2010 09:35:21 PM Reference Sample Validation Bottle4Anlz001 Valid

Validation Checking the reliability of the measured values of analyzers Validation_20

Validation_20

Validation_20
02/02/2010 08:30:01 PM

02/02/2010 07:24:41 PM

02/02/2010 06:25:02 PM
Reference Sample Validation

Reference Sample Validation

Reference Sample Validation


Bottle4Anlz001

Bottle4Anlz001

Bottle4Anlz001
Valid

Valid

Valid

using various routines and methods. This test can be started


Validation_20 02/02/2010 05:14:21 PM Reference Sample Validation Bottle4Anlz001 Warning

Page: 1 / 1 Generating Date: 04/02/2010 05:39:56 PM

automatically at specific intervals or manually by the ASM.


Calibration Carries out a calibration on the analyzer and monitors the
results (this module is only available for analyzers which sup-
port remote calibration, e.g. Siemens Maxum Ed. II, Siemens Examples of generated reports
MicroSAM, …).
Mainte- Device-specific maintenance tasks can be specified here, their
nance timing defined, and checked. Documentation such as mainte-
nance procedures or manuals can be opened to support the
maintenance work. The view of key performance indicators
(KPI) provides a fast overview of the analyzer's performance
such as availability, error rate and maintenance frequency
Reporting This is a comprehensive function for producing customized
reports. The module permits analysis of current and historical
data in selectable time periods for documentation of the perfor-
mance of individual analyzers up to the complete plant using
the reporting module. The reports can be saved in the ASM or
exported for further use.

Siemens PA01 · 2015 4/69


© Siemens AG 2014

Analytical Application Sets


Analyzer System Manager
Set ASM
Further functions are:
Function Task
SCADA The ASM provides all typical SCADA functions such
as:
Password protection and different access privileges
User administration
Signaling, acknowledgment and archiving of alarms
and events
Network screen Status display of the network devices. This overview
displays the statuses of the Ethernet switches
(online/uncertain/fault). The analyzer alarms are
integrated in the ASM signaling system.
Reference bottle man- Management and assignment of reference gas cyl-
agement inders. This information serves as reference values
for the validation using the reference sampling
method.
Equipment engineering For configuring the analyzers. Among others, the
analyzer-specific data is entered here, the type of
validation is defined, and the number of measured
values and units is entered.
Maxum software Direct calling of the comprehensive Siemens config-
uration and operation software for Siemens Maxum
edition II and MicroSAM. It is then possible to View of the validation module
access the connected analyzers for maintenance,
configuration, or viewing of chromatograms. ■ Technical specifications
Validation Operating system • Windows XP Professional SP2/SP3

4 One of the core functions of the ASM is checking the analyzers for client
for reliability of the measured values. Two different methods of • Windows 2003 Server SP2
measurement are available for recording the values, namely the PC hardware requirements
reference sample method and the line sample method. The re- • Processor type (recommended) • Server: dual core, 3 GHz
sulting values can be checked using different evaluation meth- • Client: Client: dual core, 2 GHz
ods (based on ASTM D3764 or deviation). The objective of the • RAM (recommended) • Server: 4 GB
validation is to recognize fluctuations and deviations with re- • Client: 2 GB1)
spect to a comparison value, and to thus permit a statement to • Graphics card (recommended) 32 MB, 1280 x 10241)
be made on the reliability and drift of the measurement. • Hard disk (recommended) • Server: 2 x 160 GB (Raid 1)
• Client: 80 GB
Method of measurement: reference sample method • Hard disk (free space for installation, • Server: > 40 GB
recommended) • Client: > 1.5 GB
The analyzer is disconnected from the process gas, and a refer-
• DVD-ROM/ USB port For software installation
ence gas connected for measurement. The composition of this
reference gas has previously been specified in the "Reference 1)
Hardware requirement when using Microsoft XP Professional
bottle management" of the ASM. Using these values, the ASM
determines the deviation between the measurement and the ref-
erence data.
■ More information
Method of measurement: line sample method Please contact your Siemens sales partner for further informa-
tion and for ordering.
With this method, a gas sample is extracted from the stream of
sample gas to the analyzer, and analyzed in the laboratory. The
resulting values are passed on to the ASM and compared with
the analyzer's measured values. With this method, the analyzer
need not be disconnected from the process gas, and perma-
nently remains available for the process measurement.
Evaluation based on ASTM D3764
Based on the international standard ASTM D3764, the results
are checked using various statistical methods, including stan-
dard deviation, Dixon freak value test, and systematic error.
Evaluation using deviation method
Limit values are defined for this evaluation: the warning limit and
the control limit. Simple rules are used to define how the reliabil-
ity of the measurement is to be assessed when these limits are
violated. For example, it can be defined that a single violation of
the limit can be tolerated, but that repeated violation is an imper-
missible condition.

4/70 Siemens PA01 · 2015


5
© Siemens AG 2014

General information

5/2 Communication
5/2 Continuous gas analysis
5/7 Gas analysis library for SIMATIC PCS 7
5/8 Process gas chromatography

5/11 Operator functions of Series 6

5/12 FAT & factory certificates

5/13 Ex versions
5/13 Continuous gas analysis, extractive
5/21 Continuous gas analysis, extractive
ATEX II 2G control unit
5/22 Continuous gas analysis, extractive
ATEX II 2G control unit,
leakage compensation
5/24 Continuous gas analysis, extractive
ATEX II 2G/3G control unit,
continuous purging
5/26 Continuous gas analysis, extractive
Purging unit FM (Class I Div 2)
5/27 Continuous gas analysis, extractive
Additional units
5/29 Continuous gas analysis, in-situ
LDS 6
5/31 Continuous gas analysis, in-situ
LDS 6, EEx barrier
5/32 Continuous gas analysis, in-situ
SITRANS SL
5/33 Process gas chromatography

5/34 Tables
5/34 Conversion tables
5/35 Dew point/saturation table
5/37 International standards

5/39 Definitions

Siemens PA 01 · 2015
© Siemens AG 2014

General information
Communication
Continuous gas analysis

■ Overview
Reliable functioning of analyzers is of decisive importance for Networking over ELAN
process control. It is necessary to record, correct and transmit
measured values, to set and modify parameters, to check func- ELAN communication is used e.g. for the correction of cross-in-
tions, to update calibrations, and to scan status signals e.g. for terference. Direct connection is only possible between Siemens
preventive maintenance. Communication between the operator gas analyzers.
and device is therefore an important part of process analysis, Specification for the interface cable
and the offered facilities have become a decisive performance Surge impedance 100 ... 300 , with a measuring
feature of analyzers. frequency of > 100 kHz
Extractive Cable capacitance Typ. < 60 pF/m
The gas analyzers of Series 6 (ULTRAMAT 6, Core cross-section > 0.22 mm2, corresponds to
ULTRAMAT/OXYMAT 6, OXYMAT 6, OXYMAT 61, FIDAMAT 6 AWG 23
and CALOMAT 6) as well as the ULTRAMAT 23 offer the following Cable type Twisted pair, 1 x 2 conductors of
communications facilities in addition to data transmission over cable section
analog and binary outputs:
Signal attenuation Max. 9 dB over the whole length
• RS 485 interface
Shielding Copper braided shield or braided
• SIPROM GA shield and foil shield
• PROFIBUS DP/PA Connection Pin 3 and pin 8
• Generic communications interface (only OXYMAT 6,
ULTRAMAT 6 and ULTRAMAT/OXYMAT 6).
RS 485 interface
The serial interface integrated as standard permits communica-
tion between several analyzers over the internal bus (ELAN). Pa-
rameterization is carried out using the analyzer’s menu.

0 
*1' 
 9-pin connector

 (RS 485)

5
9  (device 1)


0 

0 
*1' 
 9-pin connector

 (RS 485)
9  (device 2)


0 

0 
*1' 
 9-pin connector

 (RS 485)
9  (device 3)


0 

Bus cable with plug connections, ELAN networking

5/2 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Communication
Continuous gas analysis
Bus terminating resistors Hardware requirements
Pins 3-7 and 8-9 of the first connector of a bus cable must be The following hardware and system requirements must be
bridged (ELAN networking). provided for the PC/laptop configuration in order to use
SIPROM GA:
Note
• Windows computer with Pentium 133 MHz and 32 MB RAM:
It is advisable to install a repeater on the device side in the case Recommendation: Pentium II 266 MHz and 64 MB RAM
of a cable length of more than 500 m or with high interferences.
• CD-ROM drive (for installation)
Networking with SIPROM GA • Vacant hard disk capacity of at least 10 MB
When used externally, the RS 485 interface requires software • VGA graphics card (Windows-supported);
matched to the analyzers, e.g. SIPROM GA. resolution: 1024 x 768
SIPROM GA is a software program for communication between • Printer (Windows-supported)
PC/laptop and analyzers. A maximum of 12 devices (electronics • MS-Windows 95, ME; NT 4, Windows 98, Windows 2000 or
modules) with up to four channels/measured components of the Windows XP operating system
following type can be connected, displayed and remote-con-
trolled per COM interface: • Vacant COM port (COM 1, 2 ...)
- The RS 485 / RS 232 interface converter is required for
• OXYMAT 6/61 coupling to the RS 485 ELAN network
• OXYMAT 64 - A standard 10-Mbit or 100-Mbit network (RJ45 connection)
• ULTRAMAT 6 with TCP/ IP is required for connecting the Ethernet / RS 485
interface converter
• CALOMAT 6
Accessories for the network
• CALOMAT 62
• FIDAMAT 6 For cables, connectors, repeaters etc., see Catalog IK PI or
CA 01 on the Mall under SIMATIC NET communications sys-
• ULTRAMAT 23 tems/PROFIBUS/network components.
SIPROM GA allows access to device parameters, right up to the Networking with SIPROM GA via converter
configuration of devices. All analyzer functions (except factory
default functions) can be remote-controlled and monitored in this Up to 12 analyzers with max. four components each can be net-
manner. SIPROM GA is therefore an ideal servicing and mainte- worked.
nance tool for Siemens gas analyzers. The functional principle is shown in the following illustration.
In addition to remote control of all operator functions,
SIPROM GA offers complete access to all diagnostics data.
SIPROM GA therefore permits preventive maintenance as well
as fast responses when maintenance becomes necessary or
when the production sequence is changed. up to 12 analyzers

SIPROM GA ensures: 5
• High operational reliability
• High availability
• Central, comprehensive information
• Fast response time
• Flexibility
• Economical system integration
In addition to output of TAG No., components, current measured
values, comprehensive diagnostics information (status) and pa-
rameter settings on the analyzer display, SIPROM GA also offers
the following features: RS 485/RS 232
• Bargraph display converter
• Recorder display of one or more measured values with printer
output Typical design of an RS 485 network with SIPROM GA
• Calibration functions (adjustment of all setpoints for calibra- The gas analyzers can be installed at distances up to 500 m.
tion, remote calibration) One network can be connected to each COM port.
• Saving of all device data
• Remote control of all device functions
• Remote calibration
• Online help
• Downloading of new device firmware
• Cyclic saving of measured values on hard disk
• Writing user data to the device’s EEPROM, or downloading
data from it.
Access to the analyzers using SIPROM GA is carried out either:
• Directly from the PC over an RS 485 interface or
• Over an Ethernet gateway

Siemens PA 01 · 2015 5/3


© Siemens AG 2014

General information
Communication
Continuous gas analysis
Networking with SIPROM GA via Ethernet COM port, and thus the possibility for monitoring and operating
several widely distributed or separately installed analyzers/sys-
When networking with Ethernet, there are no limitations for the tems from one station.
distance between PC and gateway. In addition, communication
over Ethernet permits connection of several gateways to one

up to 12 analyzers

Ethernet Gateway

Ethernet Gateway

Typical design of an RS 485 Ethernet network with SIPROM GA

5/4 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Communication
Continuous gas analysis
PROFIBUS are PROFIBUS-compatible when using an optional plug-in card
(retrofitting also possible) and therefore comply with the "Device
The usual transmission of measured values and fault messages profile for analyzers" defined as binding by PI (PROFIBUS Inter-
via analog and binary outputs requires complex cabling. On the national).
other hand, when using PROFIBUS DP and PROFIBUS PA, one
single two-wire conductor is sufficient for digital transmission Customer benefits include an enormous savings potential in all
e.g. of all measured values (also from several channels), status plant areas, covering configuration and commissioning, opera-
information or diagnostics functions for preventive maintenance. tion and maintenance, up to subsequent plant expansions.
The PROFIBUS DP version with its high transmission rate for rel- Operation of the gas analyzers from a control system or a sepa-
atively small data quantities per device is widely used in produc- rate PC is possible using the SIMATIC PDM (Process Device
tion automation, whereas PROFIBUS PA takes into account the Manager); this is software which executes under Windows and
features important for process engineering, e.g. large data which can also be integrated into the SIMATIC PCS 7 process
quantities and use in hazardous areas. control system. This permits a clear presentation for integration
of the analyzers in the system as well as for the complex param-
The limited dynamic performance of 4 to 20 mA mA signals can eter structure of the analyzers.
be replaced, the laborious configuring of measuring ranges can
be omitted. By using simulated measured values without media, Direct connection of the analyzers to a control system is also
increased safety can be provided for the plant configuration, possible without PDM, e.g. using STEP7, but this necessitates
and configuration errors can be avoided. Parameter sets can be additional programming and offers less user friendliness. In
generated offline (from your desk) and subsequently down- most cases, this direct connection is therefore only applicable if
loaded and saved in the device. Local operations can thus be acyclic (device operation) data are not used.
reduced to a minimum.
A differentiation is made between cyclic and acyclic services.
The Siemens gas analyzers Cyclic services are used to transmit time-critical data such as
• OXYMAT 6/61 measured values and statuses. Acyclic services permit scan-
ning or modification of device parameters during operation.
• OXYMAT 64
• ULTRAMAT 23 Both graphic displays and values can be output on a PC. Signal-
ing of maintenance, fault and diagnostics information is also cy-
• ULTRAMAT 6 clic. These data are displayed in plain text when using
• CALOMAT 6 SIMATIC PDM.
• CALOMAT 62 The binary outputs can also be switched using cyclic services,
• FIDAMAT 6 thus also permitting triggering of relays over PROFIBUS (e.g. for
measuring point switchover, calibration etc.).

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Schematic structure of a PROFIBUS system

Siemens PA 01 · 2015 5/5


© Siemens AG 2014

General information
Communication
Continuous gas analysis
The following acyclic device parameters and configurations Generic communications interface
can be used in PROFIBUS DP and PROFIBUS PA by means of (only OXYMAT 6, ULTRAMAT 6 and ULTRAMAT/OXYMAT 6)
SIMATIC PDM:
User benefits are offered thanks to numerous functions which
• Factory data are mainly required in the automotive industry, for example to
• Diagnostics values carry out repeated linearization. In contrast to PROFIBUS and
• Logbook ELAN, communication is only possible between one device and
one PC, and takes place according to the master/slave princi-
• Display measuring ranges ple. The device only transmits data when requested by a com-
• Zero calibration mand telegram, where only one command can be processed
• Sensitivity calibration and replied to at a time.
• Setpoints for zero/sensitivity The generic communications menu can be called using
Function88, and the parameters adjusted.
• Total/single calibration and AUTOCAL
• Select measuring ranges Continuous gas analysis/in-situ
• Define measuring ranges LDS 6 can send and receive data over an Ethernet connection
• Electric time constants together with the LDScom software. This installation and service
tool is able to check and adapt device status and calibration pa-
• On/off functions rameters from a remote location. If necessary, even a complete
• Chopper frequency system check can be carried out over the remote connection. If
• Magnetic field frequency servicing is necessary, the required information can be sent to
the Siemens service engineer by modem, and he can then carry
• Date/time out the appropriate measures from the remote location.
• Measuring point switchover
This facility for remote maintenance and diagnostics is imple-
• Logbook settings mented using a standard LAN modem.
• Relay assignment
• Binary inputs
• Reset
• Save/load data
• Suppression of short noise signals Public telephone network
• Calibration tolerances Modem
Ethernet
• Switch valves
• PROFIBUS configuration LDS 6

5 Use of PROFIBUS offers the following customer benefits:


• Cost reductions for planning, installation and operation
• Use of (distributed) device intelligence
• Replaceability of devices Preset IP address in network
• Only one cable for everything, no complex cabling 192.168.XXX.XXX
• No limited 4 to 20 mA resolution
• No laborious parameterization of measuring ranges
• Simulation of measured values LDS 6 additionally possible
• Simplification of commissioning LDS 6 additionally possible
• Testing of network/AS LDS 6 additionally possible
• Avoidance of errors during startup
• Online diagnostics
External connection of LDS 6 via a modem for implementing remote
• Offline parameterization maintenance measures

5/6 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Communication
Gas analysis library for SIMATIC PCS 7

■ Overview ■ Function
Driver blocks
PCS 7 Add-on fit for SIMATIC PCS 7 V7 The gas analyzers are integrated into the hardware configuration
of the SIMATIC PCS 7 process control system using their GSD
files. Parameterization of the driver blocks is subsequently car-
ried out corresponding to the device configuration. The driver
blocks provide the following functions:
• Reading of analyzer values
• Starting of autocalibration
• Evaluation of device-specific diagnostics
• Standard diagnostics
• Alarms for analyzer values (alarm limits adjustable on the
block)
• Simulation
Symbols and faceplates
The symbols are automatically created and connected using the
wizard "Create block symbols". The faceplates can be displayed
in various views:
• Standard
• Maintenance
• Configuration
• Limits
• Trend
• Alarm

■ More information
The driver blocks from the gas analysis library permit integration Please contact your Siemens sales partner for further informa-
of the following gas analyzers into the SIMATIC PCS 7 process tion and for ordering.
control system over PROFIBUS DP:
• ULTRAMAT 6 and ULTRAMAT 23
• CALOMAT 5
• OXYMAT
The driver blocks permit access to the measured values and to
the calibration functions of these devices. They can also be used
to evaluate and display diagnostics information, and to trigger
alarms if necessary.
Note:
The gas analysis library can be used together with
SIMATIC PCS 7 V6 and V7.

Siemens PA 01 · 2015 5/7


© Siemens AG 2014

General information
Communication
Process gas chromatography

■ Overview
The MAXUM edition II and MicroSAM gas chromatographs can Memory division
transfer measured results and status information to process con-
trol systems, operator panels or printers during operation. To ensure that the meaning of the registers is known to each net-
work station, this must be defined in the configuration. The re-
Interfaces sults of each component in each sample must be written into de-
fined positions in the PCS memory. These address declarations
Chromatograph, operator panel, printer and control system use depend on the number of chromatographs, samples and com-
special electronic interfaces: ponents. The same applies to status, sample sequence and
• Electrical connection sample release. Standard addresses are also defined in these
The device interfaces are connected by electric cables. cases.
The electrical properties of the interfaces are standardized.
OPC server (OLE for Process Control)
• Control of communication and language
Rules must be observed to control the communication. It must OPC is a vendor-independent software interface. It allows stan-
be clearly defined in networks who is the "sender" and who is dardized access from Windows applications to chromatograph
the "receiver" of the data. Both communication partners must data. OPC corresponds to a typical client/server architecture.
use the same protocol. OPC allows a universal connection between any Windows appli-
MODBUS cation which supports an OPC client interface and the MAXUM
edition II / MicroSam.
MODBUS is a rule for controlling data transfer between two com-
puter systems - a transmission protocol. MODBUS is the "de The OPC server is usually installed on a separate PC.
facto" industry standard for connecting measuring and control OPC is a modern alternative to MODBUS. MAXUM edition II and
devices to process control systems (PCS). Most process control MicroSAM do not require an additional interface, they use the
systems can be equipped with serial interfaces and MODBUS. existing Ethernet connection (TCP/IP).
Using the MODBUS coupling, information can be sent interfer- OPC standardizes the access to measured values, status func-
ence-proof via just one data line. Information can be read from tions, control functions and analytical data in a manner similar to
process gas chromatographs (PGC), and certain functions of MODBUS.
the PGC can also be parameterized.
Advantages with OPC applications:
Advantages:
• Reduced maintenance costs
• Information on the PGC status during operation
• Simple GUI for configuration
• Supply of protected data in numerical form without falsification
by interfering pulses • Reduced system integration costs
• Reduced cabling overhead • Reduced test costs
• Reduced maintenance costs
The MODBUS coupling can:
5 • Transmit measured values
• Transmit status information
• Output information on the current analysis
• Trigger control functions
The MODBUS uses a master/slave transmission procedure.
The control system is always the master, the process gas chro-
matograph is the slave.
The representation of data in the message frames is based on
the compact RTU format.

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OPC server

5/8 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Communication
Process gas chromatography
Hardware components Software
NAU - Network Access Unit Modern chromatographs are controlled by microprocessors.
We differentiate between software in the device and software on
An NAU expands and supplements a GC network, and has three a PC operator panel.
fundamental functions:
• Enclosure for 7 additional I/O plug-in cards Software in the chromatograph
• Connection of serial ASCII printers and external host PCs The chromatograph can carry out analyses independently, with-
(control system) out an operator panel being connected. It then requires its own
• Central operation of a GC network from one point control software and local operating software (HMI).

The Network Access Unit (NAU) is an input/output station for the Software in the operator panel (PC)
Siemens process chromatographs. It can be used to centrally Siemens gas chromatographs can be operated over Ethernet
call, process and pass on data. It is used if it is not possible to and a PC, by using the built-in control panel (HMI), or with a Net-
connect the electronics close to the analyzer, if the number of Mi- work Extension Unit (NAU).
croSam inputs/outputs is insufficient, or if installation in a central
control room is required. This significantly reduces the required Workstation software
wiring to the control room. The most important programs this contains are the MAXUM Sys-
The NAU can also be used as a central control unit for function tem Manager, the MAXUM EZChrom and the HMI-Emulation. In
testing, data output and parameterization of the MicroSam. It addition, it contains useful MAXUM utilities and loadable exten-
permits access to the MicroSam to which it is connected, as well sions such as:
as to all other Siemens gas chromatographs and further NAUs of MaxBasic
the system which are networked over the system bus.
For modification of MaxBasic programs in the gas chromato-
The NAU is connected to the Ethernet or DataNet and has a total graphs or the NAU.
of 7 slots to accommodate a wide range of electronics cards.
These comprise cards for analog and digital signal processing MAXUM OPC Server
as well as interfaces for host computers and process control For coupling of the MAXUM e.g. to control systems.
systems. An NAU can be expanded by a further 10 slots using a
CAN Extension Unit. Simulated Distillation
A total of 7 different electronics cards are available: For import/export of methods for simulated distillation.
MAXUM System Tools
• Input/output module 8 analog outputs For data logging, for firmware updating, or for operation of dis-
• Input/output module 4 digital outputs, continued OptiCHROMs (APC 8.0).
4 digital inputs Different levels of operation
• Input/output module 2 digital outputs,
5
2 digital inputs, Operation of the PC is in three levels:
2 analog outputs, • System Manager - network monitoring and configuration of the
2 analog inputs chromatograph
• Communication module 10 Base FO Ethernet • EZChrom - method development and control of analysis
(fiber-optic coupling)
• MMI emulation - operator control and monitoring
• Communication module DataNET Copper
(redundant system bus) System Manager:
Configuration of database and applications
• Communication module DataNET Fiber Optic
• Communication module Advanced Data Highway
The System Manager provides the connection to the chromato-
(OptiCHROMe Advance graph as well as an overview of the network.
coupling) It is additionally used for configuration and high-level monitoring
CEU - CAN Extension Unit (only MAXUM edition II) of the chromatograph, and additionally branches to the MMI em-
ulation, EZ Chrom and Basic editor.
• Increases the I/O capacity of the GC or NAU
• 10 additional I/O plug-in cards The System Manager almost exclusively outputs static displays,
i.e. it fetches a table from the chromatograph’s database, and
• Has its own power supply saves it again there later. Only results and alarms are displayed
• Also for zone 1 dynamically.
ANG - Advance Network Gateway The System Manager presents the hardware in tables, e.g. the
system table contains all hardware components of the chromato-
Connects OptiCHROMs to the Ethernet network. graph: detectors, valves, ovens, digital outputs, etc.
DNH - DataNET Hub In addition, the System Manager can:
Communications router completely redundant in the network: • Save databases of a chromatograph as a file on the PC, or
has 2 own TCP/IP addresses, dual electronics and power load them from the PC into the chromatograph.
supply. • Upgrade the chromatograph software.
ANCB - Advance Network Communication Board • Call EZChrom, MMI emulation, Datalogger or the MaxBasic
Converts the communications protocols in the device editor.

Two versions:
• MAXUM directly to DataNET
• MAXUM directly to OptiCHROM data highway

Siemens PA 01 · 2015 5/9


© Siemens AG 2014

General information
Communication
Process gas chromatography
EZChrom: APC 8.0
Generate methods and sample sequences
This is an interface to the OptiCHROM Advance gas chromato-
The EZChrom software is installed on the PC and is also in- graphs. It is started from the MAXUM System Manager. It permits
cluded in the operator software in the chromatograph, e.g. it operation of older types of chromatograph via a PCI card.
integrates the detector signals there, calculates the results, or
switches time-controlled events. The following can be executed with APC 8.0:
• Service panel emulation on the PC
EZChrom on the PC is responsible for the following tasks:
• Data logging
• Generate or modify methods
• Viewing of chromatograms
• Carry out re-integration
• Editing of tables in OptiCHROM.
• Calibrate a method
• Display and print saved and real-time chromatograms GC-Tools operating software
• Archive chromatograms GC-Tools is the Windows-based operating software for discon-
tinued Siemens gas chromatographs of Series 202 and 302. This
• Generate and modify sample flow sequences software expands the BEDI operating software, which is based
• View analysis clock on MS-DOS.
• Switch the chromatograph to Run or Hold. The Network Explorer shows all information at the device level,
MMI emulation: Operator control and monitoring e.g.:
This is identical to operation on the built-in control panel of a • Chromatogram display
MAXUM or an NAU. It is used for operator control and monitor- • Manual control of all parameters
ing. For example, it is possible to display results, switch valves • Drivers for the four serial interfaces of the chromatograph
or modify temperatures. However, there are only minimum pos-
sibilities for editing the configuration and tables. The MMI is al-
ways a dynamic display.

5/10 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Operator functions of Series 6

Main menu No. Function designation Manual SIPROM PA/DP PA/DP


GA V1.6.0 V2.0.0
Diagnostics 1 Factory data X X X X
2 Diagnostic values X X — X
3 Log book X X — X
4 Display measuring ranges X X — X
Calibration 20 Zero calibration X X — X
21 Sensitivity calibration X X — X
22 Zero point/sensitivity setpoints X X — X
23 Total/individual calibration X X — X
24 AUTOCAL X X X X
25 Drift values X X — —
26 Calibration with air (OXYMAT 64 only) X — — —
Measuring ranges 40 Select measuring ranges X X — X
(Code 1) 41 Define measuring ranges X X — X
Parameter 50 Electrical time constants X X — X
(Code 1) 51 Limit values X X — —
52 On/off functions X — — X
53 Status messages X X — —
54 Graphical measured value representation X X — —
55 Measured-value display X X — —
56 LCD contrast X — — —
57 Chopper frequency (ULTRAMAT 6 only) X X — X
Magnetic field frequency (OXYMAT 6 only)
Flame ignition (FIDAMAT 6 only)
58 Date/time X X — X
59 Measuring point switchover X X — —
60 Log book settings X — — X
61 Vibration compensation (OXYMAT 6 only) X X — X
Switch internal valves (FIDAMAT 6 only)

Configuration
62
70
Switch external pressures (FIDAMAT 6 "without pump" only)
Analog output
X
X
X
X

— —
X
5
(Code 2) 71 Relay assignment X X — X
72 Binary inputs X X — X
73 ELAN configuration X X — —
74 Reset X X — X
75 Save, load data X X — X
76 Suppression of short noise signals X X — X
77 Measured value memory (analog output) X X — —
78 Calibration tolerances X X — X
79 Change codes X X — —
80 Unit test X X — —
81 Language selection X X — —
82 Pressure correction (ULTRAMAT 6, OXYMAT 6, OXYMAT 64 X X — —
and CALOMAT 62 only)
83 Correction of cross-interference X X — —
84 Phase calibration (ULTRAMAT 6 and OXYMAT 6 only) X — — —
85 Switch valves X — — —
86 Linear temperature compensation X X — —
87 Fault on/off X — — —
88 AK configuration (ULTRAMAT 6 and OXYMAT 6 only) X — — —
89 Sample chamber heating (ULTRAMAT 6, OXYMAT 6 and X X — —
CALOMAT 62 only)
90 PROFIBUS configuration X X X X
91 Startup state (FIDAMAT 6 only) X X — —
92 Pressure values (FIDAMAT 6 only) X X — —
93 Units (FIDAMAT 6 only) X — — —

— Control of external valves — — — X


— Software download — X — —

Siemens PA 01 · 2015 5/11


© Siemens AG 2014

General information
FAT & factory certificates

Selection and ordering data Article No.


FAT & factory certificates for extractive gas analyzers 7MB8100- 7 7 7 7 7 - 7 7 7 7 not applicable for
of Series 6 and ULTRAMAT 23
Click on the Article No. for the online configuration in the PIA Life Cycle Portal.
Factory acceptance (FAT) with customer
Visual inspection and basic settings
None 0
Visual acceptance, 1 to 8 devices, incl. function test and calibration 1
Visual acceptance, 9 devices and more, incl. function test and calibration 2
Measured signal response
None A
Noise, drift B
Noise, drift, linearity, T90 time C
Compensation, cross-interference
None A
Pressure compensation B FIDAMAT
1 interfering gas C
2 ... 3 interfering gases D
Pressure compensation and 1 interfering gas E FIDAMAT
Pressure compensation and 2 or 3 interfering gases F FIDAMAT
Factory acceptance, explosion protection
None 0
Pressurized enclosure for explosion-proof units (functionality) 1 19" rack units
Relay test 2
Pressurized enclosure for explosion-proof units and relay test 3 19" rack units
Number of test channels
None 0
1 ... 3 2
4 ... 6 3
7+ 4
Certificates
General certificates
Factory certificate DIN EN 10204 2.1 (quality test certificate)1) 0
Adjustment certificate DIN EN 10204 3.1 (with calibration gas) 1
Certificate of origin1) 2

5 Certificate of origin and adjustment certificate


Certificate of origin and factory certificate DIN EN 10204 2.11)
Certificate of origin, adjustment certificate and factory certificate
3
4
5
DIN EN 10204 2.1
Adjustment certificate and factory certificate EN 10204 2.1 6
Factory certificate EN 10204 2.1 following repair 7
Parameter sheets (only with suffix Y22) 8
Factory certificate DIN EN 10204 2.2
None A
Noise, drift, linearity B
Noise, drift, linearity, pressure compensation C FIDAMAT
Noise, drift, linearity, pressure and temperature compensation D FIDAMAT
Factory certificate DIN EN 10204 2.2, extended
none A
Cross-interference of residual gases (H2O and 2 other gases) B
T90 time C
Influence of atmosphere containing CO2 D
Cross-interference of residual gases2) and T90 time E
Cross-interference of residual gases2) and influence of atmosphere containing F
CO2
T90 time and influence of atmosphere containing CO2 G
Cross-interference of residual gases2), T90 time and influence of atmosphere H
containing CO2
Factory certificate DIN EN 10204 2.2, language
German 0
English 1
French 2
Required analyzer information Order code
Add "-Z" to Article No. and specify Order codes.
Information on product/order with order item and contact partner Y22
(Sales Region, region or distributor)

1)
Can also be ordered following delivery
2)
H2O and 2 other gases

5/12 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive

■ Overview
Use of Series 6 in hazardous areas • Pressurized enclosure with continuous purging
The principle of this type of protection is based on having con-
Dependent on the application, the measuring equipment tinuous purging of the EEx p enclosure after the pre-purge. It
can include the following parts: prevents ingress of the surrounding atmosphere and ensures
• Analyzer that, for example, sample gas released through leaks is
• EEx p safety equipment (purging unit) thinned to the extent that a combustible mixture cannot be cre-
ated. The volume flow of the protective gas is fixed at 1 l/min
• Flame arrestors and exceeds the maximum release volume by a factor of more
• Ex i isolation amplifier than 100.
• Isolating relay Protective gas flows continuously through the enclosure with a
volume flow of at least 1 l/min; in addition, the flow ensures that
Gas analyzers the enclosure pressure is increased to at least 50 Pa higher
Suitability-tested field analyzers of Series 6 must be used to than the surrounding pressure.
measure gases in hazardous areas. The max. permissible purging gas pressure is 25 hPa.
The max. permissible sample gas pressure is equivalent to the
The Series 6 analyzers are approved in accordance with Ex type permissible analyzer sample gas pressure.
of protection "Pressurized enclosure EEx p" for Zone 1 and Zone Test certification TÜV 01 ATEX 1708 X
2. In addition, these analyzers must be connected to monitoring Device identification: II 2 G EEx p [ia] ia IIC T4.
equipment which must also be suitability-tested.
The fundamental safety requirements of both versions are satis-
Exception: a pressurized enclosure is not required in zone 2 for fied by compliance with the European standards
the measurement of gases whose composition always remains EN 50014:1997, EN 50016:1995, EN 50020:1994 and
below the lower explosive limit (LEL); in this case, it is sufficient EN 954:1996.
for the field housing to be gas fume-proof (type of protection
EEx n R). The purging gas is monitored using EEx p monitoring equip-
ment: This is a stand-alone unit which is connected electrically
Following pre-purging of 5 minutes, the monitoring equipment and pneumatically to the analyzer. Explosion protection is only
ensures that no gas fumes can enter the enclosure, and accu- provided when both devices are combined (analyzer and purg-
mulation of the sample gas in the enclosure is prevented. The ing unit, and possibly further measures) (see below).
volume flow during the pre-purging phase is > 50 l/min. The pro-
tective gas is usually fed into the analyzer enclosure from a sup- Category ATEX II 3G (Ex zone 2)
ply network via the monitoring equipment. The principle of the type of protection "Pressurized enclosure for
Category ATEX II 2G (Ex zone 1) devices of Category 3" is based on preventing the ingress of any
hazardous atmosphere into the gas analyzer.
Two versions of pressurized enclosure EEx p complying with the
directive 94/9/EC are available for use in zone 1: Two versions complying with Directive 94/9/EC are available for
use in Zone 2. In both cases, the standard devices of Series 6
• Pressurized enclosure with compensation of losses resulting
from leaks
(field version, not Ex) can be used. 5
The principle of this type of protection is based on prevention • Explosion protection due to gas-fumes-proof enclosure
of ingress of the surrounding atmosphere or of the sample gas The enclosure of the Series 6 gas analyzers (standard, field
into the enclosure of the electrical equipment. version) is sealed sufficiently to prevent gas fumes from pen-
Only that volume of protective gas is fed into the enclosure etrating. With this type of protection, only sample gases may
that is required to maintain an overpressure of at least 50 Pa be fed in which are below the LEL.
compared to the sample gas pressure and atmospheric pres- Test certificate: TÜV 01 ATEX 1686 X
sure. The maximum purging gas pressure is 165 hPa; this re- Device identification: II 3 G EEx n R II T6
sults in a maximum permissible sample gas pressure of It is not necessary to install a purging unit here.
164 hPa; • Pressurized enclosure with continuous purging
If the sample gas is combustible or occasionally flammable, Protective gas continuously flows through the enclosure with a
the analyzer enclosure must be additionally purged with inert volume flow of at least 1 l/min; furthermore, the flow results in
gas (e.g. nitrogen). In these cases, you must additionally en- an overpressure in the enclosure of at least 50 Pa compared
sure that the internal enclosure pressure is at least 5 mbar to atmospheric pressure.
higher than the fail-safe-regulated sample gas pressure. The max. permissible purging gas pressure is 25 hPa. The
If the pressure control of the sample gas is not fail-safe max. permissible sample gas pressure is equivalent to the
(= "double fault safety"), but only operationally safe (="single permissible analyzer sample gas pressure.
fault safety"), a differential pressure switch of the EEx p safety Test certification TÜV 01 ATEX 1697 X
equipment must be used to signal if the sample gas pressure Device identification: II 2/3 G EEx n P II T4
exceeds the purging gas pressure. This measure trips a safety The purging gas is monitored using E Ex p monitoring equip-
shutdown. ment. This is a stand-alone unit which is connected electrically
With occasionally flammable sample gas mixtures, flame ar- and pneumatically to the analyzer. Explosion protection is only
restors must be additionally mounted externally at the sample provided when these two units (analyzer and purging unit) are
gas inlet and outlet. combined. (see below, purging unit)
Both the differential pressure switch and the flame arrestors
come into contact with the sample gas and must therefore be The fundamental safety requirements of both versions are satis-
made of corrosion-proof material, if applicable. fied by compliance with the European standards
Test certification: PTB 00 ATEX 2022 X EN 50014:1997, EN 50016:1995, EN 50020:1994 and
Device identification: II 2 G Eex p [ia] ia IIC T4 EN 954:1996.
The EEx p monitoring equipment is a stand-alone unit which is
connected electrically and pneumatically to the analyzer. Explo-
sion protection is only provided when these two units are com-
bined.

Siemens PA 01 · 2015 5/13


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive
Category ATEX II 3D (Ex zone 22) The following additional safety mechanisms are recommended
for continuous gas analyzers for measuring explosive gases (in-
Ex zone 22 concerns the so-called dust protection. This is the ternal explosion protection). These requirements are based on
European successor to the previous German zone 11. Zone 22 the European ATEX approvals for analyzers, but can also be
concerns the area in which during normal operation it is not ex- used as directives in the USA since no other specific definition
pected that potentially explosive atmospheres occur in the form exists there.
of a cloud of flammable dust in the air. Should such a cloud oc-
cur, however, then only briefly. Purging requirements
Considering the more stringent conditions for zone assignment, The continuous analyzers from Siemens with approvals for
it can be expected that there will be increased demand for dust- Class I, Div. 2 never require purging in a hazardous area in ac-
protected analyzers. cordance with Class I, Div. 2 / Zone 2 under the aspect of area
The field versions of CALOMAT 6, OXYMAT 6 and ULTRAMAT 6 classification. All electronic and mechanical components are
can be used in this zone according to the conformity statement classified as “non-explosive” and can be used in environments
TÜV 03 ATEX 2278 X. in accordance with Class I, Div. 2 / Zone 2. However, purging
may be necessary for a specific application, depending on the
They are assigned the Ex identification II 3 D IP65 T60 °C or type of sample gas and the respective analyzer model in order
T65 °C or T85 °C or T135 °C. to comply with the NEC and NFPA standards and to guarantee
However, this only concerns the so-called external explosion maximum possible safety as well as protection of the system.
protection. With respect to the measurement of flammable NFPA 496 requirements for continuous gas analyzers and sys-
gases, the additional measures applicable to gas explosion pro- tems from Siemens
tection apply in addition, such as flame inhibitors. These sepa-
rate certificates apply here. The NFPA 496 "Standard for Purged and Pressurized Enclosures
for Electrical Equipment" describes in great detail and clarity the
FM/CSA Class I Div 2 requirements for purging and for the pressurized enclosure for
The field versions of the standard analysis units can be used. electric systems depending on 1) the external hazardous area
Explosion protection is only provided when combined with the classification, 2) the classification/grading of the system, 3) the
suitable equipment. type of gas in the gas path, and 4) the expected discharge of
gas (none/limited/unlimited).
Definitions
It is assumed for the internal gas path of a continuous gas ana-
Non-flammable Gas or gas compositions with concentrations below the lyzer that it exhibits only low losses under normal conditions and
gas lower explosion limit (LEL). Non-explosive, even in con- uncontrolled losses in the case of a mechanical failure (abnor-
tact with air. mal conditions).
Example: CH4 < 4.4 %; H2 < 4 %; C2H2 < 2.3 %
When connecting gases with flammable components (> LEL) to
Flammable gas Gas or gas composition with concentrations above the the gas path of an analyzer with a hermetically sealed enclosure,
LEL. Explosive, but additionally requires air and ignition the flammable component can become enriched in the inside of
energy. the analyzer enclosure – even under normal conditions – beyond

5 Explosive gas
Example: CH4 > 4.4 %; H2 > 4 %; C2H2 > 2.3 %

Mixture of flammable gas and a gas matrix containing


a limit for continuous explosiveness and change the area classi-
fication (inside the analyzer enclosure) from "General Purpose"
(Universal) or Class I, Div. 2 / Zone 2 to Class I, Div. 1 / Zone 0.
oxygen; between the LEL and the UEL (upper explosion This can also occur under abnormal conditions in any type of an-
limit). Already contains O2 and is explosive without
additional air. alyzer enclosure (including NEMA 1).
Example: 4,4 % ... 16.5 % CH4 in air Analyzers for installation in the field – O6F, U6F and C6F – have
a gas-tight enclosure (IP65 / NEMA 4 equivalent in accordance
Note: Very little data is available on the existing LEL and
UEL for oxygen concentrations other than ambient air with IEC/EN 60529 and NEMA Standards Publication 250). Only
(20.95 % O2) or for sample pressures other than atmo- a small natural exchange of air takes place with the environment.
spheric pressure. In accordance with NFPA 496, a limited discharge of gas is to be
expected under normal conditions, and an unlimited discharge
Although the IEC and EN directives IEC 60079-10, EN 60079-10 under abnormal conditions.
(gas) and IEC 61241-10, EN 50281 (dust) do not specifically de-
fine the terms seldom, occasional, frequent, and permanent, the Analyzers for 19" rack mounting – O6E, U6E, U/O6, C6E, U23,
following interpretation is customary: O61, FID5 and FID6 – have an "open" enclosure (IP20 in accor-
dance with IEC/EN 60529, no exact NEMA equivalent to IP20
• Frequent or permanent: > 1 000 hours per year
available). A high natural exchange of air takes place with the
 a frequent explosive atmosphere corresponds to Zone 0 or
environment unless the exchange is restricted. In accordance
Class I, Div. 1
with NFPA 496, no discharge of gas is to be expected under nor-
• Occasional: 10 to 1 000 hours per year mal conditions, but an unlimited discharge under abnormal con-
 an occasional explosive atmosphere corresponds to Zone ditions.
1 or Class I, Div. 1
In the case of analyzers designed for general applications, it is
• Seldom: < 10 hours per year assumed that they can ignite an explosive gas mixture at any
 a seldom explosive atmosphere corresponds to Zone 2 or time, and therefore no type of explosive atmosphere whatsoever
Class I, Div. 2 may be present in the vicinity of these analyzers or within the en-
closure at any time.

5/14 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive
In the case of analyzers designed for Class I, Div. 2 / Zone 2 it is Purging rate / applied pressure
assumed that they cannot ignite an explosive gas mixture under
normal conditions (single fault safety), and these analyzers can Purging with air: The air throughput for purging an analyzer for
therefore be used in an occasionally explosive atmosphere in field installation must be sufficient such that the concentration of
the environment or within the enclosure in accordance with the flammable gases is less than 25 % of the LEL (see NFPA 496,
definition of Class I, Div. 2 / Zone 2. However, a frequent or per- Section 8.3). An air throughput of 1 l/min is recommended.
manent explosive atmosphere must be avoided since a simulta- Purging with inert gas: The inert gas throughput for purging an
neous fault occurring on the electrical components of the ana- analyzer for field installation must be sufficient such that the ox-
lyzer could constitute an ignition source. ygen level is less than 5 % of the volume or, at a maximum, less
When purging a continuous gas analyzer or when purging/vent- than 50 % of the oxygen required to form an explosive mixture
ing a continuous gas analyzer system suitable for Class I, Div. 2 (see NFPA 496, Section 8.3). An inert gas throughput of 1 l/min
/ Zone 2 with instrument air or ambient air, and if failure of the is recommended.
safety vessel is not obvious, a leak detector (measurement in % Applied pressure with inert gas: The purging and holding pres-
of LEL) or similar equipment should be used in order to detect sure applied to an analyzer for field installation must be sufficient
the unlimited discharge under abnormal conditions and to avoid such that the oxygen level is less than 5 % of the volume or, at a
a frequent or permanent explosive atmosphere inside the ana- maximum, less than 50 % of the oxygen required to form an ex-
lyzer or in its environment. The leak detector must be fitted at a plosive mixture (see NFPA 496, Section 8.3). A pressure of 25 Pa
location where the escaping sample gas can be measured be- (0.1 inch water column) in accordance with NFPA 496 is recom-
fore becoming too greatly diluted. The alarm limit of the leak de- mended. It should be taken into consideration when applying a
tector must be set to a level which enables detection of a dan- pressure to an analyzer, that instead of continuous purging,
gerous state with consideration of the fact that the discharged flammable gas can collect within the analyzer if the sample gas
sample gas has most probably already been diluted before it pressure is higher than the purging pressure. It is recommend-
reaches the sensor. able to appropriately adapt the purging pressure within the per-
Further important information missible pressure range of the field device enclosure.

Gas paths material Exceptions: Inert gas should not be used as the purging gas for
certain applications. This particularly applies to safety-related
It is strongly recommended that you use gas paths made of measurements of oxygen (LEL proof) where the sample gas has
metal for applications with flammable gases since such gas a slight overpressure and the inert gas used for purging could
paths offer the greatest safety. This particularly applies to ana- dilute the sample under abnormal conditions. Such applications
lyzers or systems which are purged with instrument air or ambi- require individual assessment of the purging equipment re-
ent air since an explosive atmosphere can be produced under quired and the mode of operation.
abnormal conditions. This immediate danger does not exist in
the case of analyzers or systems purged with inert gas. Integrated systems and analyzer containers: Purging or the ap-
plication of pressure to continuous gas analyzer systems must
It should be mentioned that, with an integrated system, all parts be designed such that the requirements of NFPA 496 are com-
containing flammable gas (pumps, gas coolers, filters etc.) must plied with.
be assessed in the same manner.
5
Leak detector
Purging of left-hand analyzer side (electronics side) of
continuous gas analyzers for field installation When purging a continuous gas analyzer or when purging/vent-
ing a continuous gas analyzer system suitable for Class I, Div. 2
Since the left electronics side and the right measurement side of / Zone 2 with instrument air or ambient air, and if failure of the
continuous gas analyzers are separated gas-tight from each safety vessel is not obvious, a leak detector (measurement in %
other, it is unnecessary to purge the electronics side in most of LEL) or similar equipment should be used in order to detect
cases – purging of the (right-hand) measurement side is suffi- unlimited discharges under abnormal conditions and to avoid a
cient. frequent or permanent explosive atmosphere inside the analyzer
or in its environment. The leak detector must be fitted at a loca-
However, if doubt exists that flammable gas could penetrate the tion where the escaping sample gas can be measured before
left-hand electronics side and become enriched there, it is ad- becoming too greatly diluted. The alarm limit of the leak detector
visable to purge both sides. must be set to a level which enables detection of a dangerous
Further reasons for purging analyzers state with consideration of the fact that the discharged sample
• Corrosive sample gases: Purging with air or inert gas is nec- gas has most probably already been diluted before it reaches
essary to prevent the enrichment of corrosive gas inside the the sensor.
analyzer, whereby operators or servicing personnel could be
injured or the analyzer unit could be damaged. The dis-
charged purging gas should be released at a non-critical
point (collective vent etc.)
• Toxic gases: Purging with air or inert gas is necessary to pre-
vent the enrichment of toxic gas inside the analyzer, whereby
operators or servicing personnel could be injured. The dis-
charged purging gas should be released at a non-critical
point (collective vent etc.). Further information can be found in
the OSHA directives for handling toxic materials.

Siemens PA 01 · 2015 5/15


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive

■ Application
Differentiation of cases: Ex zones/danger through flammable sample gas
Gas type Sample gas non-flammable Sample gas is flammable Sample gas is flammable
below the lower explosive and/or is rarely, and then and/or is occasionally
limit (LEL) only briefly, above the LEL above the LEL

Zone
Category ATEX II 1G Individual acceptance test Individual acceptance test Individual acceptance test
(zone 0) (on request) (on request) (on request)
Category ATEX II 2G Analyzer Ex analyzer EEx p Ex analyzer EEx p Ex analyzer EEx p
(zone 1) (certificate ATEX 2022X) (certificate ATEX 2022X) (certificate ATEX 2022X)
Operating mode "Leakage
compensation"
Gas path Pipe gas path Pipe gas path Pipe gas path
Flame arrester — — Flame arrester in sample gas
inlet and outlet
Monitoring EEx p control device EEx p control device sample EEx p control device sample
(certificate ATEX E 082) gas pressure < 165 hPa, fail- gas pressure < 165 hPa, fail-
safe (certificate ATEX E 082) safe (certificate ATEX E 082)
Pressure switch — Differential pressure switch Differential pressure switch
(when sample gas pressure is (when sample gas pressure is
not controlled fail-safely) not controlled fail-safely)
Category ATEX II 2G Analyzer Ex analyzer EEx p Ex analyzer EEx p Ex analyzer EEx p
(zone 1) (certificate ATEX 1708X) (certificate ATEX 1708X) (certificate ATEX 1708X)
Operating mode
"Continuous purging"
Gas path Pipe gas path Pipe gas path Pipe gas path
Flame arrester — — Flame arrester in sample gas
inlet and outlet
Monitoring EEx p control device (certifi- EEx p control device (certifi- EEx p control device (certifi-
cate DMT 99 ATEX E 082) cate DMT 99 ATEX E 082) cate DMT 99 ATEX E 082)
Pressure switch — — —

5
Category ATEX II 3G Analyzer Standard analyzer in field Standard analyzer in field Standard analyzer in field
(zone 2) housing (addition E11: housing (addition E12: housing (addition E12:
certificate ATEX 1686X) certificate ATEX 1697X) certificate ATEX 1697X)
Gas path Pipe or hose gas path Pipe gas path Pipe gas path
Flame arrester — — Flame arrester in sample gas
inlet and outlet
Monitoring — EEx p control device (certifi- EEx p control device (certifi-
cate DMT 99 ATEX E 082) cate DMT 99 ATEX E 082)
Non-hazardous zone Analyzer Analyzer as rack unit or in Analyzer as rack unit or in Analyzer as rack unit or in
field housing field housing field housing
Gas path Pipe or hose gas path Pipe gas path, recommended Pipe gas path, recommended
Enclosure purging with inert Enclosure purging with inert
gas (N2) recommended gas (N2) recommended
Flame arrester — — Flame arrester in sample gas
inlet and outlet
Monitoring — — Simplified monitoring of
purging recommended

Ex configurations – principle selection criteria

Signal line routing


Within zone 1 From zone 1 to zone 2 From zone 1 to non-hazardous zone
Ex i isolation amplifier Required Conditional use Conditional use
(when energy feedback cannot be (when energy feedback cannot be
excluded) excluded)
Isolating relay Required Conditional use Conditional use
(when energy feedback cannot be (when energy feedback cannot be
excluded) excluded)

Additional units, selection criteria (ATEX 2G)

5/16 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive
Use of OXYMAT 6 in hazardous area and/or for measurement of flammable gases
Article No. Certification Additional unit
(short codes)
Gas Dust Purging Flame Pressure Ex i isolation Ex i isolat-
unit arrestor switch amplifier ing relay
Category Operating mode Ex Ex 7MB8000- 7MB8000- 7MB8000- 7MB8000- 7MB8000-
zone zone
ATEX II 2G Leakage 7MB2011-***0*-2*** X — 2BB 6BA/6BB1) 5AA1) 3AB1) 4AB1)
(zone 1) compensation
7MB2011-***0*-3*** X — 2BA 6BA/6BB1) 5AA1) 3AB1) 4AA1)
Continuous 7MB2011-***0*-6*** X — 2CB 6BA/6BB1) o 3AB1) 4AB1)
purging
7MB2011-***0*-7*** X — 2CA 6BA/6BB1) o 3AB1) 4AA1)
ATEX II 3G Flammable gases 7MB2011-***0*-0*** E12 — 2CB 6BA/6BB1) o o o
(zone 2)
7MB2011-***0*-1*** E12 — 2CA 6BA/6BB1) o o o
7MB2011-***0*-0*** E42 — 6BA/6BB1) o o o
7MB2011-***0*-1*** E42 — 6BA/6BB1) o o o
Non-flammable 7MB2011-***0*-0*** E11 — o o o o o
gases
7MB2011-***0*-1*** E11 — o o o o o
7MB2011-***0*-0*** E41 — o o o o
7MB2011-***0*-1*** E41 — o o o o
Non-haz- Non-hazardous 7MB2011-***0*-0*** E40 — o o o o
ardous gas zone
zone 7MB2011-***0*-1*** E40 — o o o o
7MB2011-***0*-0*** — — o o o o o
7MB2011-***0*-1*** — — o o o o o
7MB2021-****0-**** X — o o o o o

CLASS 1 Flammable and 7MB2011-***0*-0*** E20 — 1AA 6BA/6BB o o o


Div 2 non-flammable
gases 7MB2011-***0*-1*** E20 — 1AA 6BA/6BB o o o
7MB2021-*****-****2) E20 — 1AA 6BA/6BB o o o
— Combination not allowed
X Possible combination, no additional data required
5
o Not required
Ex configurations, possible combinations
1) Conditionally required: see table of Ex configurations, selection criteria
2) Installation in additional enclosure required

Siemens PA 01 · 2015 5/17


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive
Use of ULTRAMAT 6 in hazardous area and/or for measurement of flammable gases
Article No. Certification and Additional unit
short codes
Gas Dust Purging unit Flame Pressure switch Ex i isolation Ex i isolating
arrestor amplifier relay
Category Operating mode 7MB2111- Ex Ex zone 7MB8000- 7MB8000- 7MB8000- 7MB8000- 7MB8000-
7MB2112- zone
ATEX II 2G Leakage *****-2*A* X — 2BB 6BA/6BB1) 5AA1) 3AB1) 4AB1)
(zone 1) compensation
*****-3*A* X — 2BA 6BA/6BB1) 5AA1) 3AB1) 4AA1)
Continuous *****-6*A* X — 2CB 6BA/6BB1) o 3AB1) 4AB1)
purging
*****-7*A* X — 2CA 6BA/6BB1) o 3AB1) 4AA1)
ATEX II 3G Flammable *****-0*A* E42 — 6BA/6BB1) o o o
(zone 2) gases
*****-1*A* E42 — 6BA/6BB1) o o o
*****-0*A* E12 — 2CB o o o o
*****-1*A* E12 — 2CA o o o o
Non-flammable *****-0*A* E41 — o o o o
gases
*****-1*A* E41 — o o o o
*****-0*A* E11 — o o o o o
*****-1*A* E11 — o o o o o
Non-hazard- Non-hazardous *****-0*A* X E40 — o o o o
ous zone gas zone
*****-1*A* X E40 — o o o o

CLASS 1 Flammable and 7MB2111- E20 — 1AA 6BA/6BB o o o


Div 2 non-flammable *****-0*A*,
gases
7MB2111- E20 — 1AA 6BA/6BB o o o
*****-1*A*
7MB212*- E20 — 1AA 6BA/6BB o o o
*****-****2)
— Combination not allowed

5 X Possible combination, no additional data required


o Not required
1)
Conditionally required; see table of Ex configurations, selection criteria.
2)
Installation in additional enclosure required

5/18 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive
Use of CALOMAT 6 in hazardous area and/or for measurement of flammable gases
Article No. Certification Additional unit
Gas Dust Purging unit Flame arrester Pressure Ex i isolation Ex i isolat-
switch amplifier ing relay
Category Operating 7MB8000- 7MB8000- 7MB8000- 7MB8000- 7MB8000-
mode
ATEX II 2G Leakage 7MB2511- X — 2BB 6BA/6BB1) 5AA1) 3AB1) 4AB1)
(zone 1) compensation ***0*-0AE*
7MB2511- X — 2BA 6BA/6BB1) 5AA1) 3AB1) 4AA1)
***0*-1AE*
Continuous 7MB2511- X — 2CB 6BA/6BB1) o 3AB1) 4AB1)
purging ***0*-0AF*
7MB2511- X — 2CA 6BA/6BB1) o 3AB1) 4AA1)
***0*-1AF*
ATEX II 3G Flammable 7MB2511- X X — 6BA/6BB1) o o o
(Zone 2) gases ***0*-*AJ*
7MB2511- X — 2CA/2CB 6BA/6BB1) o o o
***0*-*AC*
7MB2521- X — acc. to 6BA/6BB1) o o o
***0*-*AB*2) Certificate
Non-flammable 7MB2511- X X — o o o o
gases ***0*-*AH*
7MB2511- X — o o o o o
***0*-*AB*
7MB2521- X — o o o o o
***0*-*AB*
Non-haz- Non-hazardous 7MB2511- — X — o o o o
ardous gas zone ***0*-*AG*
zone

CLASS 1 Flammable and 7MB2511- X — 1AA 6BA/6BB o o o


Div 2 non-flammable ***0*-*AD*
gases
7MB2521-
***0*-*AD*2)
X — 1AA 6BA/6BB o o o
5
X Possible combination, no additional data required
— Combination not allowed
o Not required
Ex configurations, possible combinations
1)
Required under certain conditions; see table of Ex configurations, selection criteria
2)
Installation in additional housing required

Use of ULTRAMAT 23 in hazardous area and/or for measurement of flammable gases


Article No. Certification and Additional unit
short codes
Gas Dust Purging Flame Pressure switch Ex i isolation Ex i isolat-
unit arrestor amplifier ing relay
Category Operating mode 7MB233*- Ex zone Ex zone 7MB8000- 7MB8000- 7MB8000- 7MB8000- 7MB8000-
ATEX II 3G Flammable *****-**** E20 — o o1) o o o
(zone 2) gases2)
Non-flammable *****-**** E20 — o o o o o
gases2)
Class 1 Flammable and *****-**** E20 — 1AA o1) o o o
Div 2 non-flammable
gases2)
— Combination not allowed
o Not required/not defined
1)
Required under certain conditions
2)
Installation in additional housing required

Siemens PA 01 · 2015 5/19


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive

Ex approval
ATEX CLASS I Div 2 ATEX
2G - LC 2G - CP 3G burn. 3G nbrn. FM CSA 3D (dust)
see basic MLFB Z + E12 Z + E11 Z + E20 Z + E20 Z + E4X
except CALOMAT except
CALOMAT
Field device
U6F ATEX 2022 X ATEX 1708 X ATEX 1697 X ATEX 1686 X 3016050 1526657 ATEX 2278 X
U6F-S ATEX 2022 X ATEX 1708 X ATEX 1697 X ATEX 1686 X 3016050 — —

O6F ATEX 2022 X ATEX 1708 X ATEX 1697 X ATEX 1686 X 3016050 1526657 ATEX 2278 X
O6F-S ATEX 2022 X ATEX 1708 X ATEX 1697 X ATEX 1686 X 3016050 — —

C6F ATEX 2022 X ATEX 1708 X ATEX 1697 X ATEX 1697 X 3018862 1526660 ATEX 2278 X
C6F-S ATEX 2022 X ATEX 1708 X ATEX 1697 X ATEX 1697 X 3018862 o —
C62F ATEX 2022 X ATEX 1708 X — — — — —
C62F-S ATEX 2022 X ATEX 1708 X — — — — —

19" rack unit


U6E — — — 3016050 1526657 —
U6E-S — — — 3016050 — —

O6E — — — 3016050 1526657 —


O6E-S — — — 3016050 - —
OU6E — — — 3016050 1526657 —
OU6E-S — — — 3016050 - —

5 C6E
C6E-S




ATEX 1873 X
ATEX 1873 X
3018862
3018862
1526660



C62E — — — — — —
C62E-S — — — — — —

O61 — — — — — —
O64 — — — — — —
F6 — — — (SET) — —
U23 — — ATEX 0027 x 3035269 2133209 —
U23 O2p — — ATEX 0027 x 3035269 2133209 —
U23 H2S — — ATEX 0027 x 3035269 2133209 —
CP = Continuous Purging
LC = Leakage compensation
… -S = Special application
burn. = Flammable gases
nbrn. = Non-flammable gases
o = In progress

Possible combinations of PROFIBUS with Ex applications


ATEX 2022 X PROFIBUS PA Ex-i FM/CSA PROFIBUS PA or DP
ATEX 1708 X PROFIBUS PA Ex-i
ATEX 1697 X PROFIBUS PA Ex-i ATEX 2278 X PROFIBUS DP - Non-hazardous gas installation (Z + E40)
ATEX 1686 X PROFIBUS DP ATEX 2278 X PROFIBUS DP in combination ATEX 1686 X (Z + E41)
ATEX 1873 X PROFIBUS DP ATEX 2278 X PROFIBUS PA Ex-i in combination with ATEX 1697 X (Z + E42)

5/20 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive - ATEX II 2G control unit

■ Overview
EEx p safety equipment (purging unit) Additional function
The EEx p safety equipment to be connected to the analyzer By connecting additional pressure sensors, the internal pressure
must have at least the following features: of the enclosure is maintained at a pressure higher than that of
• Adjustable pre-purging phase; purging gas flow must be the sample gas by means of a proportional valve. During the pre-
approximately 50 l/min purging phase the purging gas flow is max. 4 100 Nl/h with an
internal enclosure pressure of 50 hPa.
• Limitation of purging gas pressure during the pre-purging
phase: < 165 hPa 4 programmable relay inputs (8 relay contacts) are available to
• "Leakage compensation" or "Continuous purging" separate the data lines.
• Connection for purging gas lines with Ø 10 mm or Ø 3/8" from During the operating phase, the pressure inside the enclosure
and to the analyzer must be maintained at a level at least 50 Pa higher than that of
the surrounding atmosphere. If the internal pressure drops be-
• Pressure after pressure reducer low the defined minimum value, safety equipment must shut
- 0.2 to 0.4 MPa (leakage compensation) down the entire electical supply to the EEx-p enclosure autono-
- 0.2 to 0.3 MPa (continuous purging) mously (including the possible data lines) .
• Max. permissible input pressure 0.6 MPa
Enclosures frequently contain accessories to which flammable
• Relay contacts for all-pole isolation of the analyzer supply volt- gases or sometimes also flammable gas mixtures are fed via a
age separate gas path. This is the case with gas analyzers, for exam-
• Connection option for a key-operated switch and a pressure ple. In this case, it must be ensured that the pressure of the pro-
switch (intrinsically-safe circuits) tective gas is always more than 50 Pa higher than the pressure
• Device version "Leakage compensation": Connection option of the sample gas.
for a pressure switch with intrinsically-safe scan After mounting the control device APEX 2003.SI/B on the EEx-p
The Bartec control unit APEX 2003.SI/B meets the requirements enclosure, and after connecting the mains power and the pro-
for "Pressured enclosure with leakage compensation or continu- tective gas, the control module regulates and monitors the flow
ous purging" in accordance with EN 50016 or ATEX guidelines, of purging gas automatically during the pre-purging phase, and
and can be used as explosion-proof equipment in Zones 1 the internal enclosure pressure during the operating phase.
and 2. If the minimum operating pressure of the enclosure is exceeded
The purging unit ensures that in a closed enclosure, any explo- and if flow through the pressure monitoring module is sufficient,
sive gases will be purged and then a pressure higher than the the pressure sensors forward the sensor module signals to the
surrounding atmosphere will be generated and maintained. control module.

A non-hazardous area is thus created in the enclosure in which


electrical devices can be installed that are not themselves explo-
sion-proof. After commissioning, a distinction is made between
the pre-purging phase and the operating phase: 5
The pre-purging phase is necessary to ensure that any explo-
sive atmposphere entering during the standstill time does not
become a hazard; the enclosure must therefore be purged with
protective gas (air from a non-hazardous area or inert gas) be-
fore commissioning.

Siemens PA 01 · 2015 5/21


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive - ATEX II 2G control unit, leakage compensation

■ Overview Pressure sensors MIN A = 0 … 300 hPa,


MIN B = 0 … 300 hPa,
BARTEC EEx p control unit "Leakage compensation" MAX = 0 … 300 hPa,
MAX 1 = 0 … 300 hPa,
The APEX 2003.SI/A2 control unit controls and monitors the pre- DIFF A = 0 … 25 hPa,
purging and operating phases of gas analyzers with contain- DIFF B = 0 … 25 hPa
ment systems in hazardous zone 1. Prepurging time 0 … 99 min; 5 sec dropout
delayed
The control unit redundantly monitors the set overpressure of the
purging gas. When the overpressure decreases, it is corrected Weight 11 kg
to the adjustable setpoint (max. purging gas pressure 165 hPa). Electrical data
Supply voltage 230 V AC (115 V AC)  10 %,
■ Technical specifications 48 … 62 Hz
Control unit ATEX IIG, compensa- Power consumption 21 W /230 V
tion of losses through leaks
NO contacts K2/3; max. 250 V, 5 A
Guidelines EC EMC directive 89/336/EEC, with cos  = 1,
EC low voltage, RL 73/23/EEC, K4/K5; supply voltage or floating,
Ex directive 94/9/EC max. 250 V, 5 A with cos  = 1
Design Explosion-protected enclosure Communication RS 485 interface
(EEx e) with viewing window in
the cover Temperature switching value 0 … +40 °C
(option)
Enclosure material Glass fiber-reinforced polyester
Explosion protection
Degree of protection IP65
Marking EEx e d ib [ia p] IIC T4/T6
Terminals 2.5 mm, finely stranded
Test certification DMT 99 ATEX E 082
Ambient temperature -20 … +40 °C

■ Dimensional drawings

 

5


BARTEC control unit, dimensions in mm

5/22 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive - ATEX II 2G control unit, leakage compensation

■ Schematics

$QDO\]HU (([SFRQWUROXQLW

,QHUWJDVRXWOHW

2XWOHW
3UHVVXUHVHQVRU
',))&
6DPSOH
6DPSOHJDV
FHOO

,QOHW

3UHVVXUHVZLWFK ,QHUWJDVLQOHW
UHGXQGDQW 'T
YHUVLRQ

03D

BARTEC control unit, leakage compensation, gas connection diagram

([WFXUUHQW ([WFXUUHQW
6HQVRU VRXUFLQJ 7HPSHUDWXUH .H\ 212)) VRXUFLQJ %ULGJHIRU
PRGXOH VZLWFK VHQVRU VZLWFK VZLWFK VZLWFK FDOLEUDWLRQ

EEx i
1-12 5 8 13 14 15 16 17 18 19 20 21 22 23 24

&RQWUROPRGXOH K2/K3

K1 K4/K5

25 26 27 28 29 31 32 39 41 43 45 46 44 42 40 35 34 47 48
+ - + -

L1
N
2XWSXW ,QSXW 'DWDFDEOH 3RZHUVXSSO\
PE
YDOYH YDOYH
(([S
DQDO\]HU
'DWD
FDEOH

BARTEC control unit, leakage compensation, electric connection diagram

Siemens PA 01 · 2015 5/23


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive - ATEX II 2G/3G control unit, continuous purging

■ Overview Terminals 2.5 mm, finely stranded


Pressure sensors MIN A = 0 … 25 hPa,
BARTEC EEx p control unit "Continuous purging" MIN B = 0 … 25 hPa,
MAX = 0 … 25 hPa,
The APEX 2003.SI/A4 control unit controls and monitors the pre- MAX 1 = 0 … 25 hPa,
purging and operating phases of gas analyzers with contain- DIFF A = 0 … 25 hPa,
ment systems in Ex zone 1 and Ex zone 2. DIFF B = 0 … 25 hPa
The control unit redundantly monitors the continuous flow of pro- Prepurging time 0 … 99 min; 5 sec dropout delayed
tective gas through the connected analyzer and thereby dilutes Weight 10 kg
any escaping sample gas to below the lower explosive limit
(max. purging gas pressure 25 hPa). Electrical data

At the same time, a higher pressure is maintained inside the Supply voltage 230 V AC (115 V AC)  10 %,
48 … 62 Hz
EEx-p enclosure than in the surrounding atmosphere. If the flow
of purging gas or the internal pressure falls below a determined Power consumption 21 W /230 V
minimum value, the supply voltage to the equipment in the pres- NO contacts K2/3; max. 250 V, 5 A with cos  = 1,
surized enclosure is shut down.
K4/K5; supply voltage or floating,
4 programmable relay inputs (8 relay contacts) are available to max. 250 V, 5 A with cos  = 1
separate the data lines. Communication RS 485 interface
Temperature switching value 0 … +40 °C
■ Technical specifications (option)
Control unit ATEX II 2G, Explosion protection
continuous purging
Marking EEx e d ib [ia p] IIC T4/T6
Guidelines EC EMC directive 89/336/EEC,
EC low voltage, RL 73/23/EEC, Test certification DMT 99 ATEX E 082
Ex directive 94/9/EC Ambient temperature -20 … +40 °C
Design Explosion-protected enclosure (EEx e)
with viewing window in the cover
Degree of protection IP65

■ Dimensional drawings
 
5


BARTEC control unit, dimensions in mm

5/24 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive - ATEX II 2G/3G control unit, continuous purging

■ Schematics

$QDO\]HU (([SFRQWUROXQLW
2SHUDWLQJIORZQR]]OH

3XUJLQJJDV
RXWOHW
2XWOHW

6DPSOH 6DPSOHJDV
FHOO

,QOHW

3UHSXUJLQJ21
Dq 3XUJLQJJDV
LQOHW
PD[03D
6HWWLQJRSHUDWLQJIORZ

BARTEC control unit, continuous purging, gas connection diagram

Sensor Temperature Key Jumper for


module switch switch adjustment

5
T

EEx i
1-12 5 8 15 16 17 18 19 20 23 24

Control module K2/K3

K1 K4/K5

25 26 27 28 29 39 41 43 45 46 44 42 40 35 34 47 48
Purging valve -
+

L1
N
Data line Supply voltage
PE
EEx p
Data analyzer
line

BARTEC control unit, continuous purging, electric connection diagram

Siemens PA 01 · 2015 5/25


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive - Purging unit FM (Class I Div 2)

■ Application Switching contact Via SPCO switch approved for


Class 1 Division 2
The Ex purging unit MiniPurge FM is used to monitor the pres- Settings Lower response limit 0.5 hPa set
sure during continuous purging of an analyzer with purging or relative to purging gas flow of
inert gas. If the pressure falls below the set value, an optical 1 … 2 l/min
display is triggered and the relay is activated. This monitoring Prepurging time Is defined by operator, and con-
unit is driven by the purging gas pressure and therefore does not trolled manually
require an additional power supply.
Enclosure pressure limitation By means of stainless steel with
integrated flame arrestor; opens
■ Technical specifications at 10 hPa  10 %

Classification Class I Division 2


Enclosure dimensions (in mm) 444 x 438 x 275 ■ Dimensional drawings
Enclosure volume (I) Approx. 50 l
 
Enclosure pressure (normal) 1 hPa  
FM certificate Certificate of compliance
1X8A4.AE / 0B3A3.AE


Reaction upon failure of pressure Opening of switching contact,
and alarm via signal indicator
(red display)



System type MiniPurge complete system
Operating mode Continuous purging
Type of enclosure Reinforced polycarbonate
Enclosure surface RAL 7035 gray with transparent
cover
Pressure supply Dry, oil-free air or inert gas with
regulated pressure of approx.
2000 hPa (30 psi) at inlet of
MiniPurge
Supply connections Pressure via ¼ BSPP connection,

pressure hose at least ½" or
12 mm 


5 Display (signal indicator) Pneumatically driven color sig- 



nal: green/red

MiniPurge, dimensions in mm

■ Schematics

Analyzer Purging gas


inlet

Sample Cable connection


cell Sample gas Purging gas

MiniPurge, purging unit, Class I, Div 2, gas connection diagram

5/26 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive - Additional units

■ Overview
Installation of Ex isolation modules / Ex i isolation amplifiers Isolating relay (signal outputs with external voltage supply)
7MB8000-4AA/-4AB
The mounting rail in the analyzer has a length of approximately
250 mm, with the number of installable components being If the device has to be opened, it must be isolated at all poles
limited. from the mains cable, the binary inputs, relay outputs, analog in-
puts/ outputs, RS 485 interface cable, and the PROFIBUS PA ca-
The maximum installation height is approximately 95 mm; how- bles (not Ex i). For this purpose, isolating relays must be in-
ever, it is less in the area of the display (88 mm). The width must serted. Intrinsically-safe circuits are excepted from this.
not exceed 80 mm.
An isolating relay must be explosion-proof if it is to be set up in
The add-on devices must be approved for an ambient tempera- an area subject to explosion hazard.
ture of up to 60 °C; this temperature can be reached under ex-
treme marginal conditions. Protective gas
The label of the analyzer shows all types of explosion protection • The fed-in gases are not flammable. Air from an area not sub-
that the device itself and the components can have. ject to explosion hazard can be used as the protective gas
(purging gas).
Installation must always be discussed with the competent ex-
perts. • Flammable gases or gas mixtures that are rarely or only briefly
ignitable are fed in. The enclosure must be flooded with inert
Slots in the analyzer and the purging unit. gas.
Ex i isolation Ex isolating Comment • Gas mixtures that are occasionally ignitable are introduced.
amplifier relay 8S As with b), the enclosure must be flooded with inert gas; in ad-
Analyzers 2 2 Max. 2 dition, the sample gas inlet and outlet must be equipped with
flame arrestors.
Bartec purging 0 1 Max. 1
unit • Explosive gas mixtures that are present in the long term or per-
manently must not be connected!
Ex i isolation amplifier, 7MB8000-3AB
Flame arrestors
The analog inputs and outputs of the analyzers are not intrinsi-
cally safe in the basic version. If the gas mixture to be measured sometimes has an explosive
composition, flame arrestors must be installed in the sample gas
The analog output can be supplemented later with an intrinsi- inlet and, in certain circumstances, also in the sample gas outlet,
cally-safe analog output (explosion protection type EEx ib II C or in addition to the application already described with flammable
EEx ia II C). For this purpose, a suitable commercially available sample gases.
isolating transformer can be mounted on a rail in the device.
The material of the flame arrestors must be resistant to the flow-
Technical data: type sample gas mixture. For this reason, they are available in

5
• Intrinsically-safe analog output two different versions:
• mA isolating transformer without power supply • The detonation protection (Ex designation Ex IIG IIC) is used
to prevent flashover in the case of unstable detonations and
• For installing in the analyzer deflagrations of explosive gas or vapor/air mixtures of explo-
Isolation amplifier, rail mounting sion group IIC.
• Intrinsically-safe output EEx ia IIC • The flame arrestor consists essentially of a detonation-proof
enclosure with gas connections and a ceramic sinter cartridge
• Galvanic isolation built into the housing (max. pore width: 80 µm) to prevent
Technical data flashover.
Input voltage 8.4 V + 0.02 x load x (V/) It may be heated up to 150 °C and subjected to a pressure up to
3 bar (abs.).
Linearity < 0.1 V
Temperature impact < 0.1 %/10 K Technical data
Power supply 8.4 ... -30 V DC from the current Length 83.5 mm
loop Diameter 32 mm
Weight 160 g External thread M 30 x 1.5; 30 mm long
Ambient temperature -20 °C … +60 °C Gas connections G 1/4"
Relative humidity < 95 %, no condensation Material Stainless steel or Hastelloy C
Explosion protection Max. gas operating pressure 3 bar (abs.)
Type of protection II (1) G D [Eex ia] IIC Max. operating temperature 150 °C (200 °C on request)
EC type-examination certificate TÜV 98 ATEX 1338 Explosion group IIC
Safety limits U0  12.6 V
I0  95 mA

Siemens PA 01 · 2015 5/27


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, extractive - Additional units
Differential pressure switch: 7MB8000-5AA
There must be a fail-safe guarantee that the sample gas pres-
sure will never exceed 5 hPa under the purging gas pressure.
If this cannot be guaranteed on the plant side, a differential pres-
sure switch must be mounted between the sample gas line and
the purging gas line and connected electrically with the purging
unit.
The differential pressure switch always has contact with the sam-
ple gas.
Technical data
• Differential pressure switch with magnetic spring contact
• Type 821.1
• Materials coming into contact with the sample gas:
Stainless steel, mat. no. 1.4571
• Measuring range: -20 ... +20 hPa
• Trigger point: adjustable

5/28 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, in-situ - LDS 6

■ Overview
Sensors and cables for applications of the LDS 6 in "Intrinsic safety" is limited to circuits with relatively small capac-
hazardous areas ity. To prevent sparks during closing or opening, the capacitance
and inductance of an intrinsically-safe circuit are also limited de-
Intrinsic safety and intrinsically-safe circuit pending on the maximum current and voltage values. No sparks
Principles or thermal effects which could lead to ignition of an explosive at-
mosphere occur either in normal operation or in the process up-
The physical principle for the degree of protection "Intrinsic set. Therefore intrinsically-safe circuits may also be connected
safety" is that a certain minimum ignition energy is required to ig- or disconnected during operation when live, since the safety is
nite an explosive atmosphere. In an intrinsically-safe circuit, this also guaranteed in the event of a short-circuit or interruption. The
minimum ignition energy is not present in the hazardous area, following figure shows the block diagram for the type of protec-
neither during normal operation nor in the event of an incident. tion "Intrinsic safety".
The intrinsic safety of a circuit is achieved by limiting the current,
voltage, power and temperature. Therefore the type of protection

Hazardous area Safe area


Ra La Li Ri F

Limited temperature
rise Ca Ci
U0
Limited
spark
energy

PA

U0 Max. output voltage PA Potential compensation


Ri Internal resistor Ra External resistor
Li Internal inductivity La External inductivity
Ci
F
Internal capacitance
Fuse
Ca External capacitance
5
Block diagram for voltage/current limiting with type of protection "Intrinsic safety"
Intrinsically-safe electrical equipment and intrinsically-safe com- The standard refers to so-called "countable faults" instead of pro-
ponents of associated equipment are divided into two catego- tective measures. These refer to protective measures, such as
ries ("Protection levels"). A differentiation is made between the current limiting resistors, Zener diodes for voltage limiting, fuses,
protection levels "ia" and "ib". Protection level "ib" also provides safe distances etc., i.e. all components or measures which im-
protection should one protective measure fail (fault redundancy plement an exactly defined safety function for the associated
1). Protection level "ia" provides protection even if two protective equipment.
measures should fail (fault redundancy 2).

Protection level Description according to EN 50020 Installation


ia The intrinsically-safe electrical equipment must not cause an ignition: Up to zone 0
• During normal operation or with the existence of non-countable safety-related faults which result in
the most unfavorable condition.
• During normal operation or with the existence of countable faults plus non-countable faults which
result in the most unfavorable condition.
• During normal operation or with the existence of two countable faults plus non-countable faults
which result in the most unfavorable condition.
ib The intrinsically-safe electrical equipment must not cause an ignition: Zone 2
• During normal operation or with the existence of non-countable faults which result in the most un- Zone 1
favorable condition.
• During normal operation or with the existence of countable faults plus non-countable faults which
result in the most unfavorable condition.
Protection levels of electrical equipment and intrinsically-safe components

Siemens PA 01 · 2015 5/29


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, in-situ - LDS 6
Minimum ignition curves Typical setup of an LDS 6 system in a hazardous area
The "minimum ignition curves" are used to evaluate an intrinsi- LDS 6 is capable of measuring gases in EEx environments, pro-
cally- safe circuit and to determine the maximum capacitance vided all safety-relevant points are particularly observed. The
and inductance values. They are included in the valid intrinsi- central unit of LDS 6 must always be located outside of hazard-
cally-safe standards (EN 50020 or DIN EN 50020 and ous areas.
IEC 60079-11 or EN 60079-11). Minimum ignition curves exist for
resistive, capacitive and inductive circuits. Different minimum ig- Special EEx-type sensors (see explosion protection tag),
nition curves are applied depending on the gas group for which certified according to
an intrinsically-safe circuit is to be designed, and take into ac- • ATEX II 1G Ex ia IIC T4 and
count the minimum ignition energies of the gas groups. • ATEX II 1 D Ex iaD 20 IP65 T135 °C
Associated electrical equipment allow operation inside almost any EEx-classified area.
Associated electrical equipment is a reference to equipment For the intrinsically-safe version, an EEx barrier must be pro-
which contains one or more intrinsically-safe circuits, but in vided between the sensors and central unit. A typical version is
which not all circuits are intrinsically-safe. Associated electrical shown in the following figure for intrinsically safe EEx ia sensors.
equipment usually has an isolating function, i.e. separating in-
trinsically-safe equipment from non-intrinsically-safe equipment
within a signal circuit. Such devices include, for example: safety CD6 Ex
barriers, switch amplifiers, power supply units etc. Transmitter Receiver
Associated electrical equipment is not explosion-proof and must
therefore not be installed in hazardous areas. It only contains in-
trinsically-safe circuits which may be routed into the hazardous
area. Associated electrical equipment is identified by a square
bracket enclosing "EEx" and the symbol for the type of protec-
tion, as well as absence of the temperature class

Hybrid
(e.g. [EEx ia] IIC).

cable
Sensor connecting cable
Cables
DIN/EN 60079-14 (VDE 165, Part 1) must be observed when se-
lecting and routing the cables. Particular attention must be paid Ex zone
to the characteristic values, such as electric strength and mini-
mum cross-section. In the case of intrinsically-safe circuits, the
cable capacitance and inductance must be observed in addi- Ex barrier
tion, and must not exceed the values specified for the intrinsi-
cally-safe or associated equipment used (Co, Lo). The connec-
tion points and cables of intrinsically-safe circuits must be
Hybrid cable

5
identified, e.g. in light blue, and be separated from the other
connection points and cables of non-intrinsically-safe circuits. LDS 6

Typical setup of LDS 6 in a hazardous area

5/30 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, in-situ - LDS 6, EEx barrier

■ Overview ■ Technical specifications


The EEx barrier is included in the scope of delivery of the CD 6 EEx barrier
sensors in EEx ia version. It is meant for wall mounting close to Hazardous area output
the location of the LDS 6 central unit within an EEx-safe environ-
ment. • Minimum output voltage 12.5 V at 45 mA

The EEx barrier defines the interface between the analyzer cen- • Maximum output voltage 24 V at 170 
tral unit and the intrinsically-safe sensor heads and ensures un- • Current limitation 45 mA
der all circumstances that the total electrical energy transferred Max. power consumption 90 mA at 24 V,
via the hybrid cable to the sensors is always less that than (45 mA output) 110 mA at 20 ... 35 V DC
needed to ignite combustible gas mixtures.
Safety description 25 V, 170 , 147 mA,
Um = 250 Vrms or DC

■ Dimensional drawings

250

146
350

EEx barrier, dimensions in mm

Siemens PA 01 · 2015 5/31


© Siemens AG 2014

General information
Ex versions
Continuous gas analysis, in-situ - SITRANS SL

■ Overview
The SITRANS SL consists of a flameproof transmitter, a flame-
proof receiver, and optionally a specially certified junction box of
increased safety. The complete analytical system is accommo-
dated in the two flameproof enclosures which are connected to-
gether by a cable. A further cable is connected to the receiver,
and serves as the power supply and customer interface. Both
cables have a fixed connection to the flameproof enclosure.
They must be connected in a suitable junction box if applicable.
The receiver also has a local display.
SITRANS SL can be operated by Ex-certified infrared remote
control.
The laser has a radiated power of 0.8 mW. The irradiance is ap-
prox. 10.9 . 10 - 3 mW/mm2. This is below the values permitted in
EN 60079-28.
The SITRANS SL is available with ATEX or FM certificates.
An Ex concept with type of explosion protection "Pressurized en-
closure d" is used for the SITRANS SL. The enclosure used re-
sists an explosion caused by an explosive gas mixture in the an-
alyzer. Ignition of an explosive atmosphere produced outside the
enclosure is therefore reliably prevented.

Connection cable Connection cable


Analog-I/O, Modbus PROFIBUS DP

Transmitter unit Receiver unit


Connection
cable
ATEX cable
gland

5 Remote control

ATEX cable
Mounting bracket for gland
junction box

Cable gland for


Ethernet cable
aP /PD[ P aP
Ex-e junction box Ex-e junction box

Special conditions Connection conditions


Repairing of the flameproof gaps must only be carried out in ac- • Unused openings must be closed in accordance with
cordance with the manufacturer’s design directives. EN 60079-1 Section 11.9.
• A fixed cable must be used for the SITRANS SL gas analyzer,
and routed such that it is sufficiently protected against dam-
age.
• If the temperature on the entry components is higher than
70 °C, appropriate temperature-resistant cables must be
used.
• The SITRANS SL gas analyzer must be included in the local
equipotential bonding.
• The end of the SITRANS SL gas analyzer cable must be con-
nected in an enclosure which complies with the requirements
of a recognized type of explosion protection in accordance
with EN 60079-0, Section 1, if the connection is made in the
hazardous area.

5/32 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Ex versions
Process gas chromatography

■ Overview
Safety is extremely important during the storage, manufacture, Basic design with MAXUM edition II
processing and transportation of flammable materials, espe-
cially in the chemical and petrochemical industries, and in oil The electronic components are accommodated in a pressurized
and gas production. area. If the overpressure falls below a certain value, a control de-
vice switches off the power supply when a defined threshold is
Gas chromatographs and the sample preparation carried out in reached.
these plants must be designed such that no explosive mixtures
can be ignited when applied. National directives and guidelines The MAXUM edition II is available with certificates according to
as well as international standards regulate the equipment pre- CSA/US, or ATEX certificates according to Cenelec for the EU
requisites. market.

The MAXUM edition II and MicroSAM chromatographs can be


used in hazardous areas according to ATEX II 2G (zone 1) and
ATEX II 3G (zone 2).
The following individual protective measures apply:
Type of protection: pressurized enclosure "p"
The ignition source is enclosed by a protective gas with over-
pressure (at least 0.5 hPa). Air is used in most cases. The sur-
rounding explosive atmosphere cannot penetrate.
No flammable sample or flammable carrier gas may be passed
into this pressurized area. Switching valves for the carrier gas H2
must therefore be mounted outside this area.
The strength of the enclosure is at least 1.5 times the resistance
to operating pressure.
An alarm is generated in the event of failure of the purging gas
or the overpressure.
The electronics area must be purged prior to starting up the MAXUM edition II
equipment.
Basic design with MicroSAM
This purging also provides additional protection in corrosive en-
vironments. The MicroSAM is designed such that all components (electronic
and analytical) are accommodated in a flameproof enclosure.
Type of protection: flameproof enclosure "d" The advantage of this version is that no additional purging gases
This type of protection is used for most of our detectors. The de-
tector is fitted in an enclosure which is resistant to the explosion
or safety monitoring systems are required.
The MicroSAM is available with ATEX or FM/CSA certificates for
5
of an explosive atmosphere within it. This means that the me- the US market.
chanical stability of the enclosure must withstand this internal ex-
plosion pressure.
Joints must also be so tight that hot gas escaping between two
parts of the enclosure is not explosive.
Ignition of an explosive atmosphere produced outside the enclo-
sure is therefore reliably prevented. This is known as resistance
to transmission of internal ignition.
The FID, TCD and FPD detectors are available with this degree
of protection.
The maximum demands with regard to the joint parameters
(width/length) are placed on enclosures of explosion group II C.
MicroSAM is an example of this.

MicroSAM

Siemens PA 01 · 2015 5/33


© Siemens AG 2014

General information
Tables
Conversion tables

■ Overview
 


JP   JP











0
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0

0
0
0
$U
  
0
 
2


&O
$LU


 

62
1

 0 
2 +&O
& 
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 6 1H  


0
+

+ 1
+&
&

2
 
+ &2
&
 

0 
 
+
& + + 2 1+ 
&
 

0 
 
&+ 
 

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0 
5 
           

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00ROHFXODUZHLJKW
([DPSOHIRU62JPFRUUHVSRQGVWR9RO

Conversion from g/m3 to vol. % (at 293 K and 1013 hPa)


Conversion tables
Component Molecular mass 1 ppm in mg/m3 1 mg/m3 in ppm hPa psia
CO 28 1.250 0.800 420 6.091
NO 30 1.339 0.747 500 7.251
SO2 64 2.857 0.350 600 8.202
CO2 44 1.964 0.509 800 11.603
CH4 16 0.714 1.400 1 000 14.503
C2H4 28 1.250 0.800 1 160 16.824
C2H6 30 1.339 0.747 1 200 17.404
C4H10 58 2.589 0.386 1 300 18.854
C3H8 44 1.964 0.509 1 485 21.538
C3H6 42 1.875 0.533 1 500 21.755
Conversion ppm  mg/m3 (1 atm; 0 °C), examples 2 000 29.007

atm bar hPa psia 3 000 43.511


atm 1.01325 1013.25 14.69595 3 500 50.763

bar 0.9869 1000 14.50377 4 000 58.015

hPa 0.0009869 0.001 0.0145038 Conversion hPa  psia


psia 0.0680 0.06894 68.94
Conversion of pressure units

5/34 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Tables
Dew point/saturation table

Dew point Water content Dew point Water content


°C °F ppm (vol.) g/m3 1) °C °F ppm (vol.) g/m3 1)
-100 -148.0 0.014 0.0000103 0 +32.0 6 020 4.84
-90 -130.0 0.008 0.000119 +1 +33.8 6 480 5.2
-80 -112.0 0.54 0.000565 +2 +36.8 6 850 5.6
-70 -94.0 2.57 0.00269 +3 +37.4 7 487 6.0
-60 -78.0 10.7 0.011 +4 +39.2 8 022 6.4
-55 -67.0 20.8 0.021 +5 +41 8 595 6.8
-50 -58.0 38.4 0.038 +6 +42.8 9 216 7.3
-48 -54.4 49.6 0.049 +7 +44.6 9 875 7.8
-46 -50.8 63.0 0.061 +8 +46.4 10 584 8.3
-45 -49.0 68.5 0.067 +9 +48.2 11 318 8.8
-44 -47.2 80.1 0.076 +10 +50 12 114 9.4
-42 -43.6 101.5 0.097 +11 +51.8 12 935 10.0
-40 -40.0 126.9 0.11 +12 +53.6 13 806 10.7
-39 -38.2 137.0 0.12 +13 +55.4 14 800 11.4
-38 -36.4 158.0 0.14 +14 +57.2 15 796 12.1
-37 -34.6 174.1 0.16 +15 +59 16 791 12.8
-36 -32.8 197.8 0.17 +16 +60.8 17 885 13.6
-35 -31.0 224.0 0.19 +17 +62.6 19 030 14.5
-34 -29.2 245.0 0.22 +18 +64.4 20 396 15.4
-33 -27.4 274.0 0.24 +19 +66.2 21 641 16.3
-32 -25.6 303.4 0.26 +20 +68 23 020 17.3
-31 -23.8 336.0 0.30 +21 +69.8 24 502 18.3
-30 -22.0 374 0.33 +22 +71.6 26 120 19.4
-29 -20.2 411 0.37 +23 +73.4 27 736 20.6
-28 -18.4 461 0.40 +24 +75.2 29 477 21.8
-27 -16.8 511 0.45 +25 +77 31 219 23.0
-26 -14.3 563 0.49 +26 +78.8 33 209 24.4
-25
-24
-13.0
-11.2
623
689
0.55
0.59
+27
+28
+80.6
+82.4
35 200
37 312
25.8
27.2
5
-23 -9.4 759 0.66 +29 +84.2 39 551 28.7
-22 -7.3 840 0.72 +30 +86 41 791 30.3
-21 -5.8 922 0.80 +31 +87.8 44 322 32.0
-20 -4.0 1 015 0.88 +32 +89.6 46 936 33.5
-19 -2.2 1 118 0.96 +33 +91.4 49 675 35.6
-18 -0.4 1 231 1.05 +34 +93.2 52 539 37.2
-17 +1.4 1 358 1.15 +35 +95 55 472 39.6
-16 +3.2 1 480 1.26 +36 +96.8 58 639 41.3
-15 +5.0 1 630 1.38 +37 +98.6 62 001 43.8
-14 +6.8 1 779 1.51 +38 +100.4 65 487 45.8
-13 +8.8 1 953 1.65 +39 +102.2 68 973 48.4
-12 +10.4 2 140 1.79 +40 +104 71 761 50.7
-11 +12.2 2 338 1.96 +42 +107.6 81 049 56.5
-10 +14.0 2 562 2.14 +44 +111.2 89 889 62.3
-9 +15.8 2 798 2.33 +45 +113 94 527 65.3
-8 +17.6 3 047 2.54 +46 +114.8 99 600 68.7
-7 +19.4 3 333 2.76 +48 +118.4 110 681 75.5
-6 +21.2 3 632 2.99 +50 +122 120 398 82.3
-5 +23.0 3 955 3.20 +55 +131 155 472 104.0
-4 +24.8 4 303 3.51 +60 +140 196 517 129.5
-3 +26.6 4 690 3.81 +70 +158 307 212 196.5
-2 +28.4 5 100 4.13 +80 +176 467 662 290.5
-1 +30.2 5 547 4.47 +90 +194 691 542 418.0
+100 +212 1 000 980 558.0
1)
Reference temperature = dew point temperature.

Siemens PA 01 · 2015 5/35


© Siemens AG 2014

General information
Tables
Dew point/saturation table
Guide values for dead time (sec) per meter of sample gas line
d 4 mm 6 mm 8 mm 10 mm 12 mm 14 mm 16 mm 18 mm 20 mm
Q
30 l/h 1.5 3.4 6 9.4 13.5 18.4 24 30.5 37.6
60 l/h 0.8 1.7 3 4.7 6.8 9.2 12 15.3 18.8
90 l/h 0.5 1.1 2 3.1 4.5 6.1 8 10.2 12.5
120 l/h 0.4 0.9 1.5 2.4 3.4 4.6 6 7.6 9.4
150 l/h 0.3 0.7 1.2 1.9 2.7 3.7 4.8 6.1 7.5
180 l/h 0.3 0.6 1 1.6 2.3 3.1 4 5.1 6.3
210 l/h 0.2 0.5 0.9 1.3 1.9 2.6 3.4 4.3 5.4
240 l/h 0.2 0.5 0.8 1.2 1.7 2.3 3 3.8 4.7
270 l/h 0.2 0.4 0.7 1 1.5 2 2.7 3.4 4.2
300 l/h 0.15 0.34 0.6 0.9 1.4 1.8 2.4 3.1 3.8

d = Inner diameter of sample gas lines


Q = Flow rate

5/36 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Tables
International standards
National standards also exist in most EU member states, and However, extensive harmonization has already been carried out
may be used in these countries in addition to the valid EN stan- in the explosion protection sector, and most standards now also
dards. In the Federal Republic of Germany, these are the DIN exist as "DIN EN ...." versions, which have also been incorpo-
standards and the VDE regulations. rated into the VDE regulations. DIN EN standards are identical to
the corresponding EN standards, were special national features,
e.g. concerning areas of validity etc., are formulated in a national
foreword.

Topic International Europe/Germany USA Canada


FM UL ANSI/ISA Ex zone Ex Class Miscella-
model Div. model neous
Ex: General IEC 60079-0 EN 50014/ FM 3600 ANSI/ISA- CSA 79-0-95
regulations VDE 0170/0171 Part 1 S12.0.01
Oil immersion IEC 60079-6 EN 50015/ UL2279, Pt.6 ANSI/ISA- CSA-E79-6
"o" DIN EN 50015, S12.26. 01
VDE 0170/0171 Part 2
Pressurized IEC 60079-2 EN 50016/ FM 3620 (NFPA4 96) CSA-E79-2 CSA TIL. E
enclosure "p" DIN EN 50016, 13 A
VDE 0170/0171 Part 3
Powder filling IEC 60079-5 EN 50017/ UL2279, Pt.5 ANSI/ISA- CSA-E79-5
"q" DIN EN 50017, S12.25. 01
VDE 0170/0171 Part 4
Flameproof IEC 60079-1 EN 50018/ FM 3615 UL2279, Pt.1 ANSI/ISA- CSA-E79-1 CSA C22.2
enclosure "d" DIN EN 50018, UL1203 S12.22. 01 No. 30
VDE 0170/0171 Part 5
Increased IEC 60079-7 EN 50019/ UL2279, Pt.7 ANSI/ISA- CSA-E79-7
safety "e" DIN EN 50019, S12.16. 01
VDE 0170/0171 Part 6
Intrinsic safety IEC 60079-11 EN 50020/ FM 3610 UL2279, Pt.11 pr CSA-E79-11 CSA C22.2
"i" DIN EN 50020, UL 913 ANSI/ISA- No. 157
VDE 0170/0171 Part 7 S12.02. 01
Degree of IEC 60079-15 EN 50021/ FM 3611 UL2279, Pt.15 pr ANSI/ISA CSA-E79-15 CSA C22.2
protection "n" DIN EN 50021, S12.12. 01 No. 213
VDE 0170/0171 Part 8
Encapsulation IEC 60079-18 EN 50028/ UL2279, Pt.18 ANSI/ISA- CSA-E79-18
"m" DIN EN 50028,
VDE 0170/0171 Part 9
S12.23. 01
5
Zone 0 IEC 60079-26 EN 50284/
DIN EN 50284,
VDE 0170/0171 Part 12
Electrical IEC 61010 EN 61010-1/ ANSI/ISA- CAN/CSA-
safety DIN EN 61010-1, 82. 02.01 C22.2 No.
VDE 0411 Part 1 1010.1

Comparison of international and European standards

Siemens PA 01 · 2015 5/37


© Siemens AG 2014

General information
Tables
International standards

European standard German standard German title


EN 1127 DIN EN 1127-1 Explosive atmospheres - Explosion protection - Part 1: Fundamentals and method
EN 50039 DIN EN 50039, Electrical equipment for hazardous areas; intrinsically-safe electrical systems "i"
VDE 0170/0171 Part 10
EN 13463-1 DIN EN 13 463-1 Non-electrical equipment for use in hazardous areas, Part 1: Fundamental method and
requirements
EN 50281-1-1 DIN EN 50281-1-1, Electrical equipment for use in areas with combustible dust,
VDE 0170/0171 Part 15-1-1 Part 1-1: Electrical equipment with protection by enclosure

EN 60079-10 DIN EN 60079-10, Electrical equipment for potentially explosive gas atmospheres,
VDE 165 Part 101 Part 10: Division of potentially explosive areas

EN 60079-14 DIN EN 60079-14, Electrical equipment for hazardous areas, Part 14: Electrical installations in potentially
VDE 165 Part 1 explosive areas (except underground excavation)

EN 60079-17 DIN EN 60079-17, Electrical equipment for potentially explosive gas atmospheres, Part 17: Testing and main-
VDE 0165 Part 10 tenance of electrical installations in hazardous areas (except underground excavation)

EN 60950 DIN EN 60950, Safety of information technology equipment, including electrical office machines
VDE 0805
Harmonized European standards for explosion protection

T 1 > 450 °C T 2 > 300 °C T 3 > 200 °C T 4 > 135 °C T 5 > 100 °C T 6 > 85 °C
I Methane
II A Acetone Ethyl alcohol Petrol Acetyl aldehyde
Ethane i-amyl acetate Diesel fuel Ethyl ether
Ethyl acetate n-butane Aviation gasoline
Ammonia n-butyl alcohol Fuel oil
Benzene (pure) n-hexane
Acetic acid
Carbon monox-
ide
Methane
Methanol
Propane
Toluene

5 II B Town gas
(Illuminating
Ethylene

gas)
II C Hydrogen Acetylene Carbon disulfide
Classification of gases and vapors into explosion groups and temperature classes

5/38 Siemens PA 01 · 2015


© Siemens AG 2014

General information
Definitions

■ Overview
Definitions Units of measurement
Calibration gas Vol%
Gas used for adjusting the sensitivity (deflection) of the detected Volume proportion in % of measured component, based on the
gas. It is a gas mixture of known composition (measured compo- sample gas.
nent and suitable residual gas).
ppm (vpm)
Sensitivity
Parts per million, i.e. one proportion of the measured component
Ratio between a change in output variable observed on the mea- per 106 proportions of the sample gas (corresponds to 10-4 %).
suring instrument and the change in input variable required for
this. In gas analysis technology, ppm is usually understood as vol-
ume concentrations. The dimension unit vpm is frequently used
Linearity error of devices with linear characteristics for unequivocal identification:
Deviation of measured characteristic from a linear reference 1 vpm = 1 cm³ / m³
characteristic.
Example: 1 000 vpm = 0.1 vol.% = 1 dm³ / m³
The linearity is an important variable particularly for instruments
which use a measuring effect with nonlinear characteristic and mg/m³
where the measured characteristic is linearized electronically. Mass of measured component in mg referred to 1 m³ of sample
Cross-sensitivity gas at 1 013 hPa and 20 °C.

Measure for the selectivity of a gas analyzer with regard to inter- Example: 1 vpm = 1 cm³ / m³ corresponds to:
fering components. (molecular weight of component / molecular volume of compo-
It is the ratio between the displayed value of the interfering com- nent)  (mg / m³)
ponent and the displayed value of the measured component; Weight concentration
both have the same concentration.
Specification of measured values in weight concentrations is not
In the case of analyzers where the total concentration of different common with gas analysis. Weight concentrations can only be
materials is measured (e.g. total hydrocarbon concentration) determined in exceptional cases. The dimension unit mg/m³
and where the individual components are weighted differently in does not mean weight concentration.
the measuring result, these factors are specified in equivalents
of a master component (e.g. CH4 equivalents for the total hydro-
carbon measurement) and not as cross-sensitivity.
Dynamic response
The dynamic response of an analyzer is characterized by its re-
sponse time and dead time. The response time is the time which 5
passes until the output variable remains constantly within de-
fined limits following an abrupt change in the input variable. The
response time is usually understood as the time required to
reach 90 (T90) or 95 % of the expected display.

Siemens PA 01 · 2015 5/39


© Siemens AG 2014

General information

Notes

5/40 Siemens PA 01 · 2015


6
© Siemens AG 2014

Appendix

6/2 Siemens Industry Training

6/3 PIA Life Cycle Portal


6/3 Engineering, Ordering, Installation and
Operation tool

6/4 Partner at Industry


Technical Training
Consulting Tec
pport Sup hnical 6/5 Siemens Automation Cooperates with
e Su port
Onlin
Education
r ts
Fie vice

Pa

Service Engineering
Se
ld

Programs Support
6/5 Applicable practical know-how
are
r

Sp

6/7 Online Services


Modernization Optimization
Services Services
6/7 Information and Ordering in the Internet
and on DVD
6/8 Information and Download Center
Social Media, Mobile Media

6/9 Industry Services


6/9 Your machines and plants can do more -
with Industry Services.
6/10 Industry Services for the entire life cycle

6/14 Software Licenses

6/16 Conditions of sale and delivery

Siemens PA 01 · 2015
© Siemens AG 2014

Appendix
Siemens Industry Training

■ Faster and more applicable know-how: ■ Highlights Siemens Industry Training


Hands-on training from the manufacturer
Top trainers
Siemens Industry Training provides you with comprehensive
support in solving your tasks. Our trainers are skilled teachers with direct practical experience.
Course developers have close contact with product develop-
Training by the market leader in the industry enables you to ment, and directly pass on their knowledge to the trainers.
make independent decisions with confidence. Especially where
the optimum and efficient use of products and plants are con- Practical experience
cerned. You can eliminate deficiencies in existing plants, and The practical experience of our trainers enables them to teach
exclude expensive faulty planning right from the beginning. theory effectively. But since theory can be pretty drab, we attach
great importance to practical exercises which can comprise up
to half of of the course time. You can therefore immediately im-
plement your new knowledge in practice. We train you on state-
of-the-art methodically/didactically designed training equip-
ment. This training approach will give you all the confidence you
need.
Wide variety
With a total of about 300 local attendance courses, we train
the complete range of Siemens Industry products as well as
interaction of the products in systems.
Tailor-made training
We are only a short distance away. You can find us at more than
50 locations in Germany, and in 62 countries worldwide. You
wish to have individual training instead of one of our
300 courses? Our solution: We will provide a program tailored
exactly to your personal requirements. Training can be carried
out in our Training Centers or at your company.
The right mixture: Blended learning
First-class know-how directly pays for itself: In shorter startup
times, high-quality end products, faster troubleshooting and re- "Blended learning" is a combination of various training media
duced downtimes. In other words, increased profits and lower and sequences. For example, a local attendance course in a
costs. Training Center can be optimally supplemented by a teach-your-
self program as preparation or follow-up. Additional effect:
Achieve more with Siemens Industry Training Reduced traveling costs and periods of absence.
• Shorter times for startup, maintenance and servicing
• Optimized production operations
• Reliable configuration and startup
• Minimization of plant downtimes
• Flexible plant adaptation to market requirements
• Compliance with quality standards in production
• Increased employee satisfaction and motivation

6 • Shorter familiarization times following changes in technology


and staff

■ Contact
Visit our site on the Internet at:
www.siemens.com/sitrain
or let us advise you personally.
Siemens Industry Training Customer Support Germany:
Phone: +49 911 895-7575
Fax: +49 911 895-7576
E-Mail: [email protected]

6/2 Siemens PA 01 · 2015


© Siemens AG 2014

Appendix
PIA Life Cycle Portal
Engineering, Ordering, Installation and Operation Tool

■ Overview
The PIA Life Cycle Portal provides the appropriate functionality
in all stages of the Product Life Cycle for products of Process In-
strumentation, Process Analytics and Weighing Technology.
The application guides you through Engineering & Selection,
supports you at the Order and provides tools and information for
Installation and Operation.

• Phase 1: Selection & Planning


• Phase 2: Ordering
• Phase 3: Installation & Operation
• Additional features: e. g. PIA Mobile

Phase 1: Selection & Planning Phase 3: Installation & Operation


Selection Spare parts
Achieve product solutions that meet Find appropriate spare parts for selected
your requirements by specifying rel- products or corresponding product fami-
evant parameters according to the lies.
measuring point by using the
guided selection or select the prod-
uct directly in the product and ac- After sales support
cessories tree. Go to the Service and Support Portal to ac-
cess manuals, certificates and further infor-
mation concerning service & support.
Configuration
Configure a selected product step by step Device information and history
and use the integrated configuration knowl-
edge to avoid errors. Serial number specific product information
for installed devices

Sizing & calculation


Sizing & calculation tools for Gas Analyzers, Additional features
Weighing and Batching Systems and Flow
measurement instruments. Personalize
Register in order to customize the applica-
tion to your personal needs.
Phase 2: Ordering 6
Bulk upload
PIA Mobile
Verify several part numbers in one step by
uploading a simple text file. Use the product selection, configuration
and device information and history with the
version optimized for mobile devices.
Watchlist & projects www.siemens.com/piamobile

Collect products in a watch list and save it


as a project for later use. Product details
Find all relevant product information at a
Interface to the Industry Mall single glance: commercial and technical
data, certificates, images and documents,
Order the selected products with the order- etc.
ing system for Siemens' automation and
drive solutions.

■ More information
PIA Life Cycle Portal
Ostliche Rheinbrückenstraße 50
76187 Karlsruhe, Germany
Tel.: +49 (721) 595 2114
E-Mail: [email protected]
www.siemens.com/pia-portal

Siemens PA 01 · 2015 6/3


© Siemens AG 2014

Appendix
Partner at Industry

At Siemens Industry we are resolutely pursuing the same goal:


long-term improvement of your competitive ability.
We are committed to this goal. Thanks to our commitment, we
continue to set new standards in automation and drive tech-
nology. In all industries – worldwide.
At your service locally, around the globe for consulting, sales,
training, service, support, spare parts ... on the entire Industry
Automation and Drive Technologies range.
Your personal contact can be found in our Contacts Database at:
www.siemens.com/automation/partner
You start by selecting a
• Product group,
• Country,
• City,
• Service.

6/4 Siemens PA 01 · 2015


© Siemens AG 2014

Appendix
Siemens Automation Cooperates with Education
Applicable practical know-how

■ Comprehensive teaching support for educational institutions


• The new TIA Portal training materials for SIMATIC S7-1200 are
available in English, German, French, Italian, Spanish and
Chinese for download.
www.siemens.com/sce/documents
Trainer packages for hands-on learning

Siemens Automation Cooperates with Education (SCE)


offers a global system for sustained support of technical skills.
SCE supports educational institutions in their teaching assign-
ment in the industrial automation sector and offers added value
in the form of partnerships, technical expertise, and know-how.
As the technological leader, our comprehensive range of
services can support you in the knowledge transfer for Industry
4.0.
Our services at a glance
• Training curriculums for your lessons
• Trainer packages for hands-on learning
• Courses convey up-to-date, specialist knowledge Our SCE trainer packages offer a specific combination of
• Support for your projects/textbooks original industrial components which are perfectly matched to
your requirements and can be conveniently used in your course.
• Complete didactic solutions from our partners These price reduced bundles available exclusively to schools
• Personal contact for individual support include innovative and flexible hardware and software
packages. SCE can currently offers more than 90 SCE trainer
Training curriculums for your lessons packages including related equipment. These cover both the
factory and process automation sectors. You can use them to
impart the complete course contents on industrial automation at
a very low cost.
Trainer packages are available for:
• Introduction to automation technology with LOGO! logic
module and SIMATIC S7-1200 compact controller
• PLC engineering with SIMATIC S7 hardware and STEP 7
software (S7-300, S7-1500 and TIA Portal)
• Operator control and monitoring with SIMATIC HMI
• Industrial networking over bus systems with SIMATIC NET
(PROFINET, PROFIBUS, IO-Link)
• Sensor systems with VISION, RFID and SIWAREX
6
• Process automation with SIMATIC PCS 7
• Power Monitoring Devices SENTRON PAC 4200
• Motor Management SIMOCODE
• Networked drive and motion technologies with SINAMICS/
SIMOTION
Use our profound industrial know-how for practice-oriented and • CNC programming with SinuTrain
individual design of your course. We offer you more than 100
didactically prepared training curriculums on the topics of Important ordering notes:
automation and drives technology free of charge. These
Only the following institutions are authorized to obtain trainer
materials are perfectly matched to your curricula and sylla-
packages: vocational schools, Colleges and Universities,
buses, and optimally suited for use with our trainer packages.
in-house vocational training departments, non commercial
This takes into account all aspects of a modern industrial
research institutions and non commercial training departments.
solution: installation, configuration, programming, and commis-
sioning. All documents, including projects, can be individually To purchase a trainer package, you require a specific end-use
matched to your specific requirements. certificate, which you can obtain from your regional sales office.
Particular highlights: www.siemens.com/sce/tp
• With the new SIMATIC PCS 7 curriculums and trainer
packages, you can pass on basic, practice-oriented PCS 7
knowledge at universities within about 60 hours (= 1
semester), using plant simulation.

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Appendix
Siemens Automation Cooperates with Education
Applicable practical know-how

■ Comprehensive teaching support for educational institutions (continued)


Courses convey up-to-date specialist knowledge We can provide you with consulting for selected projects and
support from your personal SCE contact as well as our web
based and regional Customer Support.
As a particular service, SCE supports technical authors with our
know-how as well as with intensive technical consulting.
Siemens library of special textbooks covering the industrial
automation sector provides an additional resource for you and
your students. These can be found at the SCE web site.
www.siemens.com/sce/contact
www.siemens.com/sce/books
Complete didactic solutions

Profit from our excellent know-how as the leader in industrial


technologies. We offer you specific courses for automation and
drive technology worldwide. These support you in the practice-
oriented transferring of product and system know-how, are in
conformance with curriculums, and derived from the training
fields. Compact technical courses especially for use at univer-
sities are also available.
Our range of courses comprises a wide variety of training
modules based on the principle of Totally Integrated Automation
(TIA). The focus is on the same subject areas as with the SCE
trainer packages.
Every PLC and drive course is oriented on state-of-the-art Our partners for learning systems offer a wide range of training
technology. Your graduates can thus be prepared optimally for systems and solutions for use in your courses or laboratory.
their future professional life. These models have been designed based on our trainer
In some countries we are offering classes based on our training packages and thus save you the time and cost of self-
curriculums. Please inquire with your SCE contact partner. construction of individual components. The Partner systems
provide you with simple and effective help in the fulfillment of
www.siemens.com/sce/contact your teaching assignment.
Support for your projects/textbooks www.siemens.com/sce/partner
Contact for individual support
You can find your personal SCE contact on our Internet site. Your
6 local SCE Promoter will answer all your questions concerning the
complete SCE offering, and provide you with timely and
competent information about innovations. When you encounter
challenges, you can profit from our global team of excellence.
If a direct SCE contact is not listed for your country, please
contact your local Siemens office.
www.siemens.com/sce/contact
SCE Support Finder for your Internet request
You are an educator and need support on the topic of industry
automation? Send us your request:
www.siemens.com/sce/supportfinder

Automation and drive technology is characterized by continuous


and rapid developments. Service and Support therefore play an
important role. 6FDQWKH45
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LQIRUPDWLRQ
6&(KRPHSDJH

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Appendix
Online Services
Information and Ordering in the Internet and on DVD

■ Siemens Industry Automation and Drive Technologies in the WWW


A detailed knowledge of the range of products and services
available is essential when planning and configuring automation
systems. It goes without saying that this information must always
be fully up-to-date.
Siemens Industry Automation and Drive Technologies has
therefore built up a comprehensive range of information in the
World Wide Web, which offers quick and easy access to all data
required.
Under the address
www.siemens.com/industry
you will find everything you need to know about products, sys-
tems and services.

■ Product Selection Using the Interactive Catalog CA 01 of Industry


Detailed information together with convenient interactive
functions:
The interactive catalog CA 01 covers more than 80 000 products
and thus provides a full summary of the Siemens Industry Auto-
mation and Drive Technologies product base.
Here you will find everything that you need to solve tasks in the
fields of automation, switchgear, installation and drives.
All information is linked into a user interface which is easy to
work with and intuitive.
After selecting the product of your choice you can order at the
press of a button, by fax or by online link.
Information on the interactive catalog CA 01 can be found in the
Internet under
www.siemens.com/automation/ca01
or on DVD.

6
■ Easy Shopping with the Industry Mall
The Industry Mall is the electronic ordering platform of
Siemens AG on the Internet. Here you have online access
to a huge range of products presented in an informative and
attractive way.
Data transfer via EDIFACT allows the whole procedure from
selection through ordering to tracking and tracing of the order to
be carried out. Availability checks, customer-specific discounts
and preparation of quotes are also possible.
Numerous additional functions are available to support you.
For example, powerful search functions make it easy to select
the required products. Configurators enable you to configure
complex product and system components quickly and easily.
CAx data types are also provided here.
Please visit the Industry Mall on the Internet under:
www.siemens.com/industrymall

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Appendix
Online Services
Information and Download Center, Social Media, Mobile Media

■ Downloading Catalogs
In addition to numerous other useful documents, you can also
find the catalogs listed on the back inside cover of this catalog
in the Information and Download Center. Without having to reg-
ister, you can download these catalogs in PDF format or increas-
ingly as digital page-turning e-books.
The filter dialog box above the first catalog displayed makes it
possible to carry out targeted searches. If you enter “MD 3” for
example, you will find both the MD 30.1 and MD 31.1 catalogs.
If you enter “ST 70” both the ST 70 catalog and the associated
news or add-ons are displayed.
Visit us on the web at:
www.siemens.com/industry/infocenter

■ Social Media
Connect with Siemens through social media: visit our social net-
working sites for a wealth of useful information, demos on prod-
ucts and services, the opportunity to provide feedback, to ex-
change information and ideas with customers and other
Siemens employees, and much, much more. Stay in the know
and follow us on the ever-expanding global network of social
media.
Connect with Siemens Industry at our central access point:
www.siemens.com/industry/socialmedia
Or via our product pages at:
www.siemens.com/automation
or
www.siemens.com/drives
6 To find out more about Siemens' current social media activities
visit us at:
www.siemens.com/socialmedia

■ Mobile Media
Discover the world of Siemens.
We are also constantly expanding our offering of cross-platform
apps for smartphones and tablets. You will find the current Sie-
mens apps at the app store (iOS) or at Google Play (Android).
The Siemens app, for example, tells you all about the history, lat-
est developments and future plans of the company – with infor-
mative pictures, fascinating reports and the most recent press
releases.

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Appendix
Industry Services
Your machines and plant can do more – with Industry Services.
Whether it is production or process industry - in view of rising
cost pressure, growing energy costs, and increasingly stringent
environmental regulations, services for industry are a crucial
competitive factor in manufacturing as well as in process indus-
tries.
All over the world Siemens supports its customers with product,
system, and application-related services throughout the entire
life cycle of a plant. Right from the earliest stages of planning,
engineering, and building, all the way to operation and modern-
ization. These services enable customers to benefit from the
Siemens experts’ unique technological and product knowledge
and industry expertise.
Thus downtimes are reduced and the utilization of resources is
optimized. The bottom line: increased plant productivity, flexibil-
ity, and efficiency, plus reduced overall costs.
Discover all advantages of our service portfolio:
www.siemens.com/industry-services

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(QJLQHHULQJ6XSSRUW Technical Support (QJLQHHULQJ6XSSRUW
Spare Parts
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Modernization Repair Services
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Field Services &
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2SWLPL]DWLRQ6HUYLFHV

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Siemens supports its clients with technology based Services across a plants entire life cycle.

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Appendix
Industry Services
Industry Services for the entire life cycle
Online Support
Online support is a comprehensive information system for all
questions relating to products, systems, and solutions that
Siemens has developed for industry over time. With more than
300,000 documents, examples and tools, it offers users of auto-
mation and drive technology a way to quickly find up-to-date in-
formation. The 24-hour service enables direct, central access to
detailed product information as well as numerous solution exam-
ples for programming, configuration and application.
The content, in six languages, is increasingly multimediabased
– and now also available as a mobile app. Online support’s
“Technical Forum” offers users the opportunity to share informa-
tion with each other. The “Support Request” option can be used
to contact Siemens’ technical support experts. The latest con-
tent, software updates, and news via newsletters and Twitter en-
sure that industry users are always up to date.
www.siemens.com/industry/onlinesupport

Online Support App

Using the Online Support app, you can access over 300,000 “mySupport”. You also receive selected news on new functions,
documents covering all Siemens industrial products - anywhere, important articles or events in the News section.
any time. Regardless of whether you need help implementing
your project, fault-finding, expanding your system or are plan-
ning a new machine.
You have access to FAQs, manuals, certificates, characteristics
curves, application examples, product notices (e.g. announce- Scan the QR code
ments of new products) and information on successor products for information on
in the event that a product is discontinued. our Online Support
Just scan the product code printed on the product directly using app.
the camera of your mobile device to immediately see all techni-
cal information available on this product at a glance. The graph- The app is available free of charge from the Apple App Store
ical CAx information (3D model, circuit diagrams or EPLAN mac- (iOS) or from Google Play (Android).
ros) is also displayed. You can forward this information to your
workplace using the e-mail function. www.siemens.com/industry/onlinesupportapp

The search function retrieves product information and articles


and supports you with a personalized suggestion list. You can
6 find your favorite pages – articles you need frequently – under

Technical Support
The ability to quickly analyze system and error messages and
take appropriate action are key factors in ensuring that plants
run safely and efficiently. Questions can arise at any time and in
any industry, whether it’s an individual product or a complete au-
tomation solution. Siemens technical support offers individual
technical assistance in matters related to functionality, how to
operate, applications, and fault clearance in industrial products
and systems – at any time and globally, over the phone, by e-
mail, or via remote access. Experienced experts from Siemens
answer incoming questions promptly. Depending on the require-
ments, they first consult specialists in the areas of development,
on-site services, and sales. Technical support is also available
for discontinued products that are no longer available. Using the
support request number, any inquiry can be clearly identified
and systematically tracked.

http://support.automation.siemens.com/WW/view/en/16605032

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Appendix
Industry Services
Industry Services for the entire life cycle
Spare Parts
Drive and automation systems must be available at all times.
Even a single missing spare part can bring the entire plant to a
standstill – and result in substantial financial losses for the oper-
ator. The spare parts services from Siemens protects against
such losses – with the aid of quickly available, original spare
parts that ensure smooth interaction with all other system com-
ponents. Spare parts are kept on hand for up to ten years; de-
fective parts can be returned. For many products and solutions,
individual spare parts packages ensure a preventive stock of
spare parts on-site. The spare parts services is available around
the world and around the clock. Optimum supply chain logistics
ensure that replacement components reach their destination as
quickly as possible. Siemens’ logistics experts take care of plan-
ning and management as well as procurement, transportation,
customs handling, warehousing, and complete order manage-
ment for spare parts.
http://support.automation.siemens.com/WW/view/en/43502238

Repair Services
Reliable electrical and electronic equipment is crucial for oper-
ating continuous processes. That is why it is essential that mo-
tors and converters always undergo highly specialized repair
and maintenance. Siemens offers complete customer and repair
services – on site and in repair centers – as well as technical
emergency services worldwide. The repair services include all
measures necessary to quickly restore the functionality of defec-
tive units. In addition, services such as spare parts logistics,
spare parts storage and rapid manufacturing are available to
plant operators in all verticals. With a global network of certified
repair shops operated by Siemens as well as third parties, Sie-
mens handles the maintenance and overhaul of motors, convert-
ers, and other devices as an authorized service partner.

http://support.automation.siemens.com/WW/view/en/43512848

6
Field Services
It’s a top priority in all industries: the availability of plants and
equipment. Siemens offers specialized maintenance services
such as inspection and upkeep as well as rapid fault clearance
in industrial plants – worldwide, continuously, and even with
emergency services as needed. The services include startup as
well as maintenance and fault clearance during operation. The
startup service includes checking the installation, function tests,
parameterization, integration tests for machines and plants, trial
operation, final acceptance, and employee training. All services,
including remote maintenance of drives, are also available as el-
ements of customized service contracts.

http://support.automation.siemens.com/WW/view/en/66012486

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Appendix
Industry Services
Industry Services for the entire life cycle
Training
Increasingly, up-to-date knowledge is becoming a determining
factor in success. One of the key resources of any company is
well-trained staff that can make the right decision at the right mo-
ment and take full advantage of the potential. With SITRAIN –
Training for Industry, Siemens offers comprehensive advanced
training programs. The technical training courses convey exper-
tise and practical knowledge directly from the manufacturer.
SITRAIN covers Siemens’ entire product and system portfolio in
the field of automation and drives. Together with the customer,
Siemens determines the company’s individual training needs
and then develops an advanced training program tailored to the
desired requirements. Additional services guarantee that the
knowledge of all Siemens partners and their employees is al-
ways up-to-date.

http://support.automation.siemens.com/WW/view/en/43514324

Technical Consulting & Engineering Support


The efficiency of plants and processes leads to sustainable eco-
nomic success. Individual services from Siemens help save sub-
stantial time and money while also guaranteeing maximum
safety. Technical consulting covers the selection of products and
systems for efficient industrial plants. The services include plan-
ning, consulting, and conceptual design as well as product
training, application support, and configuration verification – in
all phases of a plant’s lifecycle and in all questions related to
product safety. Engineering support offers competent assis-
tance throughout the entire project, from developing a precise
structure for startup to product-specific preparation for imple-
mentation as well as support services in areas such as prototype
development, testing and acceptance.

http://support.automation.siemens.com/WW/view/en/16605680

6
Energy & Environmental Services
Efficient energy use and resource conservation – these top sus-
tainability concerns pay off – both for the environment and for
companies. Siemens offers integrated solutions that unlock all
technical and organizational potential for successful environ-
mental management. Customized consulting services are aimed
at sustainably lowering the cost of energy and environmental
protection and thus increasing plant efficiency and availability.
The experts provide support in the conceptual design and im-
plementation of systematic solutions in energy and environmen-
tal management, enabling maximum energy efficiency and opti-
mized water consumption throughout the entire company.
Improved data transparency makes it possible to identify sav-
ings potential, reduce emissions, optimize production pro-
cesses, and thereby noticeably cut costs.

http://support.automation.siemens.com/WW/view/en/42350774

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Appendix
Industry Services
Industry Services for the entire life cycle
Modernization & Optimization Services
High machine availability, expanded functionality and selective
energy savings – in all industries, these are decisive factors for
increasing productivity and lowering costs. Whether a company
wants to modernize individual machines, optimize drive sys-
tems, or upgrade entire plants, Siemens’ experts support the
projects from planning to commissioning.
Expert consulting and project management with solution respon-
sibility lead to security and make it possible to specifically iden-
tify savings potential in production. This secures investments
over the long term and increases economic efficiency in opera-
tion.

http://support.automation.siemens.com/WW/view/en/66005532

Plant Maintenance & Condition Monitoring


Modern industrial plants are complex and highly automated.
They must operate efficiently in order to ensure the company’s
competitive strength. In addition, the steadily increasing net-
working of machines and plants require consistent security con-
cepts. Maintenance and status monitoring as well as the imple-
mentation of integrated security concepts by Siemens’ experts
support optimum plant use and avoid downtime. The services in-
clude maintenance management as well as consulting on main-
tenance concepts, including the complete handling and execu-
tion of the necessary measures. Complete solutions also cover
remote services, including analysis, remote diagnosis, and re-
mote monitoring. These are based on the Siemens Remote Ser-
vices platform with certified IT security.

http://support.automation.siemens.com/WW/view/en/59456862

6
Service Contracts
Making maintenance costs calculable, reducing interfaces,
speeding up response times, and unburdening the company’s
resources – the reduced downtimes that these measures
achieve increase the productivity of a plant. Service contracts
from Siemens make maintenance and repairs more cost-effec-
tive and efficient. The service packages include local and re-
mote maintenance for a system or product group in automation
and drive technology. Whether you need extended service peri-
ods, defined response times, or special maintenance intervals,
the services are compiled individually and according to need.
They can be adjusted flexibly at any time and used indepen-
dently of each other. The expertise of Siemens’ specialists and
the capabilities of remote maintenance thus ensure reliable and
fast maintenance processes throughout a plant’s entire lifecycle.

http://support.automation.siemens.com/WW/view/en/65961857

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Appendix
Software Licenses

■ Overview
Software types Rental floating license
Software requiring a license is categorized into types. The rental floating license corresponds to the rental license,
The following software types have been defined: except that a license is not required for each installation of the
• Engineering software software. Rather, one license is required per object (for example,
user or device).
• Runtime software
Trial license
Engineering software
A trial license supports "short-term use" of the software in a non-
This includes all software products for creating (engineering) productive context, e.g. for testing and evaluation purposes.
user software, e.g. for configuring, programming, parameteriz- It can be transferred to another license.
ing, testing, commissioning or servicing.
Data generated with engineering software and executable Demo license
programs can be duplicated for your own use or for use by third- The demo license support the "sporadic use" of engineering soft-
parties free-of-charge. ware in a non-productive context, for example, use for testing
and evaluation purposes. It can be transferred to another
Runtime software license. After the installation of the license key, the software can
This includes all software products required for plant/machine be operated for a specific period of time, whereby usage can be
operation, e.g. operating system, basic system, system expan- interrupted as often as required.
sions, drivers, etc. One license is required per installation of the software.
The duplication of the runtime software and executable pro-
grams created with the runtime software for your own use or for Demo floating license
use by third-parties is subject to a charge. The demo floating license corresponds to the demo license,
You can find information about license fees according to use in except that a license is not required for each installation of the
the ordering data (e.g. in the catalog). Examples of categories of software. Rather, one license is required per object (for example,
use include per CPU, per installation, per channel, per instance, user or device).
per axis, per control loop, per variable, etc. Certificate of license (CoL)
Information about extended rights of use for parameteriza- The CoL is the licensee's proof that the use of the software has
tion/configuration tools supplied as integral components of the been licensed by Siemens. A CoL is required for every type of
scope of delivery can be found in the readme file supplied with use and must be kept in a safe place.
the relevant product(s).
Downgrading
License types
The licensee is permitted to use the software or an earlier ver-
Siemens Industry Automation & Drive Technologies offers vari- sion/release of the software, provided that the licensee owns
ous types of software license: such a version/release and its use is technically feasible.
• Floating license
Delivery versions
• Single license
Software is constantly being updated.
• Rental license The following delivery versions
• Rental floating license • PowerPack
• Trial license • Upgrade
• Demo license can be used to access updates.
• Demo floating license Existing bug fixes are supplied with the ServicePack version.
6 Floating license
The software may be installed for internal use on any number of
PowerPack
PowerPacks can be used to upgrade to more powerful software.
devices by the licensee. Only the concurrent user is licensed. The licensee receives a new license agreement and CoL
The concurrent user is the person using the program. Use (Certificate of License) with the PowerPack. This CoL, together
begins when the software is started. with the CoL for the original product, proves that the new soft-
A license is required for each concurrent user. ware is licensed.
Single license A separate PowerPack must be purchased for each original
license of the software to be replaced.
Unlike the floating license, a single license permits only one
installation of the software per license. Upgrade
The type of use licensed is specified in the ordering data and An upgrade permits the use of a new version of the software on
in the Certificate of License (CoL). Types of use include for the condition that a license for a previous version of the product
example per instance, per axis, per channel, etc. is already held.
One single license is required for each type of use defined. The licensee receives a new license agreement and CoL with
the upgrade. This CoL, together with the CoL for the previous
Rental license product, proves that the new version is licensed.
A rental license supports the "sporadic use" of engineering A separate upgrade must be purchased for each original license
software. Once the license key has been installed, the software of the software to be upgraded.
can be used for a specific period of time (the operating hours do
not have to be consecutive).
One license is required for each installation of the software.

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Appendix
Software Licenses

■ Overview
ServicePack Software Update Service (SUS)
ServicePacks are used to debug existing products. As part of the SUS contract, all software updates for the respec-
ServicePacks may be duplicated for use as prescribed accord- tive product are made available to you free of charge for a period
ing to the number of existing original licenses. of one year from the invoice date. The contract will automatically
be extended for one year if it is not canceled three months
License key before it expires.
Siemens Industry Automation & Drive Technologies supplies The possession of the current version of the respective software
software products with and without license keys. is a basic condition for entering into an SUS contract.
The license key serves as an electronic license stamp and
is also the "switch" for activating the software (floating license, You can download explanations concerning license conditions from
rental license, etc.). www.siemens.com/automation/salesmaterial-as/catalog/en/
The complete installation of software products requiring license terms_of_trade_en.pdf
keys includes the program to be licensed (the software) and the
license key (which represents the license).

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© Siemens AG 2014

Appendix
Conditions of sale and delivery

■ 1. General Provisions ■ 3. Additional Terms and Conditions


By using this catalog you can acquire hardware and software The dimensions are in mm. In Germany, according to the
products described therein from Siemens AG subject to the German law on units in measuring technology, data in inches
following Terms and Conditions of Sale and Delivery (hereinafter apply only to devices for export.
referred to as "T&C"). Please note that the scope, the quality and Illustrations are not binding.
the conditions for supplies and services, including software
products, by any Siemens entity having a registered office Insofar as there are no remarks on the individual pages of this
outside Germany, shall be subject exclusively to the General catalog - especially with regard to data, dimensions and weights
Terms and Conditions of the respective Siemens entity. The given - these are subject to change without prior notice.
following T&C apply exclusively for orders placed with Siemens
Aktiengesellschaft, Germany. ■ 4. Export regulations
1.1 For customers with a seat or registered office in We shall not be obligated to fulfill any agreement if such
Germany fulfillment is prevented by any impediments arising out of
national or international foreign trade or customs requirements
For customers with a seat or registered office in Germany, the
or any embargoes and/or other sanctions.
following applies subordinate to the T&C:
Export of goods listed in this catalog may be subject to licensing
• the "General Terms of Payment"1) and,
requirements. We will indicate in the delivery details whether
• for software products, the "General License Conditions for licenses are required under German, European and US export
Software Products for Automation and Drives for Customers lists. Goods labeled with "AL" not equal to "N" are subject to
with a Seat or Registered Office in Germany"1) and, European or German export authorization when being exported
• for other supplies and services, the "General Conditions for out of the EU. Goods labeled with "ECCN" not equal to "N" are
the Supply of Products and Services of the Electrical and subject to US re-export authorization.
Electronics Industry"1). The export indications can be viewed in advance in the
description of the respective goods on the Industry Mall, our
1.2 For customers with a seat or registered office outside
online catalog system. Only the export labels "AL" and "ECCN"
Germany
indicated on order confirmations, delivery notes and invoices
For customers with a seat or registered office outside Germany, are authoritative.
the following applies subordinate to the T&C:
Even without a label, or with label "AL:N" or "ECCN:N", authori-
• the "General Terms of Payment"1) and, zation may be required i .a. due to the final disposition and
• for software products, the "General License Conditions for intended use of goods.
Software Products for Automation and Drives for Customers If you transfer goods (hardware and/or software and/or
with a Seat or Registered Office outside of Germany"1) and technology as well as corresponding documentation, regardless
• for other supplies and/or services, the "General Conditions for of the mode of provision) delivered by us or works and services
Supplies of Siemens Industry for Customers with a Seat or (including all kinds of technical support) performed by us to a
Registered Office outside of Germany"1). third party worldwide, you must comply with all applicable
national and international (re-)export control regulations.
■ 2. Prices If required for the purpose of conducting export control checks,
you (upon request by us) shall promptly provide us with all infor-
The prices are in € (Euro) ex point of delivery, exclusive of mation pertaining to the particular end customer, final dispo-
packaging. sition and intended use of goods delivered by us respectively
The sales tax (value added tax) is not included in the prices. It works and services provided by us, as well as to any export
shall be charged separately at the respective rate according to control restrictions existing in this relation.
the applicable statutory legal regulations. The products listed in this catalog may be subject to
Prices are subject to change without prior notice. We will charget European/German and/or US export regulations. Any export
6 the prices valid at the time of delivery.
To compensate for variations in the price of raw materials (e.g.
requiring approval is therefore subject to authorization by the
relevant authorities.
silver, copper, aluminum, lead, gold, dysprosium and neodym), Errors excepted and subject to change without prior notice.
surcharges are calculated on a daily basis using the so-called
metal factor for products containing these raw materials. A
surcharge for the respective raw material is calculated as a
1) The text of the Terms and Conditions of Siemens AG can be
supplement to the price of a product if the basic official price of downloaded at
the raw material in question is exceeded. www.siemens.com/automation/salesmaterial-as/catalog/en/
The metal factor of a product indicates the basic official price terms_of_trade_en.pdf
(for those raw materials concerned) as of which the surcharges
on the price of the product are applied, and with what method of
calculation.
An exact explanation of the metal factor can be downloaded at:
www.siemens.com/automation/salesmaterial-as/catalog/en/
terms_of_trade_en.pdf
To calculate the surcharge (except in the cases of dysprosium
and neodym), the official price from the day prior to that on which
the order was received or the release order was effected is used.
To calculate the surcharge applicable to dysprosium and
neodym ("rare earths"), the corresponding three-month basic
average price in the quarter prior to that in which the order was
received or the release order was effected is used with a one-
month buffer (details on the calculation can be found in the
explanation of the metal factor).

6/16 Siemens PA 01 · 2015


© Siemens AG 2014

Catalogs
Industry Automation, Drive Technologies and Low-Voltage Power Distribution
Further information can be obtained from our branch offices listed at www.siemens.com/automation/partner

System Solutions for Industry Catalog Low-Voltage Power Distribution and Catalog
Interactive Catalog on DVD Electrical Installation Technology
Products for Automation and Drives, Low-Voltage Power CA 01 SENTRON · SIVACON · ALPHA LV 10
Distribution and Electrical Installation Technology Protection, Switching, Measuring and Monitoring
Devices, Switchboards and Distribution Systems
Building Control Standards-Compliant Components for LV 11
GAMMA Building Control ET G1 Photovoltaic Plants
3WT Air Circuit Breakers up to 4000 A LV 35
Drive Systems 3VT Molded Case Circuit Breakers up to 1600 A LV 36
Digital: SIVACON System Cubicles, System Lighting LV 50
SINAMICS G130 Drive Converter Chassis Units D 11
and System Air-Conditioning
SINAMICS G150 Drive Converter Cabinet Units
SINAMICS GM150, SINAMICS SM150 D 12 Digital: ALPHA Distribution Systems LV 51
Medium-Voltage Converters ALPHA FIX Terminal Blocks LV 52
SINAMICS PERFECT HARMONY GH180 D 15.1 SIVACON S4 Power Distribution Boards LV 56
Medium-Voltage Air-Cooled Drives Digital: SIVACON 8PS Busbar Trunking Systems LV 70
Germany Edition Digital: DELTA Switches and Socket Outlets ET D1
SINAMICS G180 D 18.1
Converters – Compact Units, Cabinet Systems,
Cabinet Units Air-Cooled and Liquid-Cooled Motion Control
SINAMICS S120 Chassis Format Units and D 21.3 SINUMERIK & SIMODRIVE NC 60
Cabinet Modules Automation Systems for Machine Tools
SINAMICS S150 Converter Cabinet Units SINUMERIK & SINAMICS NC 61
SINAMICS DCM DC Converter, Control Module D 23.1 Equipment for Machine Tools
SINAMICS DCM Cabinet D 23.2 SINUMERIK 840D sl Type 1B NC 62
SINAMICS and Motors for Single-Axis Drives D 31 Equipment for Machine Tools
SINAMICS G120P and SINAMICS G120P Cabinet D 35 SINUMERIK 808 NC 81.1
pump, fan, compressor converters Equipment for Machine Tools
Three-Phase Induction Motors SIMOTICS HV, D 84.1 SINUMERIK 828 NC 82
SIMOTICS TN Equipment for Machine Tools
• Series H-compact SIMOTION, SINAMICS S120 & SIMOTICS PM 21
• Series H-compact PLUS Equipment for Production Machines
Asynchronous Motors Standardline D 86.1 Drive and Control Components for Cranes CR 1
Synchronous Motors with Permanent-Magnet D 86.2
Technology, HT-direct Power Supply
DC Motors DA 12 Power supply SITOP KT 10.1
SIMOREG DC MASTER 6RA70 Digital Chassis DA 21.1
Converters
Safety Integrated
SIMOREG K 6RA22 Analog Chassis Converters DA 21.2
Digital: SIMOREG DC MASTER 6RM70 Digital DA 22 Safety Technology for Factory Automation SI 10
Converter Cabinet Units
SIMOVERT PM Modular Converter Systems DA 45 SIMATIC HMI/PC-based Automation
SIEMOSYN Motors DA 48 Human Machine Interface Systems/ ST 80/
MICROMASTER 420/430/440 Inverters DA 51.2 PC-based Automation ST PC
MICROMASTER 411/COMBIMASTER 411 DA 51.3
SIMODRIVE 611 universal and POSMO DA 65.4 SIMATIC Ident
Note: Additional catalogs on SIMODRIVE or SINAMICS Industrial Identification Systems ID 10
drive systems and SIMOTICS motors with SINUMERIK
and SIMOTION can be found under Motion Control
SIMATIC Industrial Automation Systems
Low-Voltage Three-Phase-Motors Products for Totally Integrated Automation ST 70
SIMOTICS Low-Voltage Motors D 81.1 SIMATIC PCS 7 Process Control System ST PCS 7
SIMOTICS FD Flexible Duty Motors D 81.8 System components
LOHER Low-Voltage Motors D 83.1 SIMATIC PCS 7 Process Control System ST PCS 7 T
MOTOX Geared Motors D 87.1 Technology components
SIMOGEAR Geared Motors MD 50.1 Add-ons for the SIMATIC PCS 7 ST PCS 7 AO
SIMOGEAR Gearboxes with adapter MD 50.11 Process Control System
Mechanical Driving Machines
FLENDER Standard Couplings MD 10.1 SIMATIC NET
FLENDER High Performance Couplings MD 10.2 Industrial Communication IK PI
FLENDER SIG Standard industrial gear unit MD 30.1
FLENDER SIP Standard industrial planetary gear units MD 31.1 SIRIUS Industrial Controls
SIRIUS Industrial Controls IC 10
Process Instrumentation and Analytics
Field Instruments for Process Automation FI 01
Digital: SIPART Controllers and Software MP 31
Products for Weighing Technology WT 10 Information and Download Center
Digital: Process Analytical Instruments PA 01 Digital versions of the catalogs are available on the Internet at:
Digital: Process Analytics, PA 11 www.siemens.com/industry/infocenter
Components for the System Integration There you’ll find additional catalogs in other languages.
Please note the section “Downloading catalogs” on page
Digital: These catalogs are only available as a PDF. “Online services” in the appendix of this catalog.
© Siemens AG 2014

Security information
Siemens provides products and solutions with
industrial security functions that support the
secure operation of plants, solutions, machines,
equipment and/or networks. They are important
components in a holistic industrial security
concept. With this in mind, Siemens’ products
and solutions undergo continuous development.
Siemens recommends strongly that you regularly
check for product updates.

For the secure operation of Siemens products


and solutions, it is necessary to take suitable
preventive action (e.g. cell protection concept)
and integrate each component into a holistic,
state-of-the-art industrial security concept. Third-
party products that may be in use should also be
considered. For more information about industrial
security, visit
http://www.siemens.com/industrialsecurity.
Get more information
To stay informed about product updates as they
All the latest information on process analytical instruments occur, sign up for a product-specific newsletter.
can be found on the internet at For more information, visit
www.siemens.com/processanalytics http://support.automation.siemens.com.

Siemens AG Subject to change without prior notice The information provided in this catalog contains merely general
Process Industries and Drives Division PDF (E86060-K3501-A101-B1-7600) descriptions or characteristics of performance which in case of
actual use do not always apply as described or which may change
Process Automation KG 1214 PDF 482 En
as a result of further development of the products. An obligation to
76181 KARLSRUHE Produced in Germany provide the respective characteristics shall only exist if expressly
GERMANY © Siemens AG 2014 agreed in the terms of contract. Availability and technical
specifications are subject to change without notice.
All product designations may be trademarks or product names
of Siemens AG or supplier companies whose use by third parties
for their own purposes could violate the rights of the owners.

www.siemens.com/automation

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