Core Elements: OLI Flowsheet: ESP
Core Elements: OLI Flowsheet: ESP
OLI Flowsheet: ESP is an electrolyte-based, steady-state process simulator. It performs energy-, mass-, and
species-balance for industrial and research applications. The tool has thirty generalized units that can be
configured to over one-hundred units and unit operations. It is a one-of-a-kind software, developed by electrolyte
specialists to support fully electrolyte applications within a flowsheet environment. ESP is also the most complete
flowsheet implementation of OLI’s electrolyte thermodynamics technology.
Core Elements
The core elements of OLI Flowsheet:
ESP are the ESP Blocks and the OLI
Engine.
ESP Blocks
The simulation blocks within ESP are optimized for electrolytes. The block calculations, which are varied, are
designed to for efficient data input, review, and manipulation. Specialized blocks, such as membrane, crystallizer,
and mass-transfer limited towers, provide the user with first-principle predictions for these separation
technologies. A generalized list of ESP blocks are provided below.
OLI Engine
The OLI Engine is the product of a 45+ year applied research effort to predict the properties of multi-component
(ions & molecules), multi-phase systems. Such a goal requires accurate prediction of activity and fugacity
coefficients. Peer-reviewed, state-of-science theories that predict activities are the centerpiece of the OLI
Engine. OLI Engine features include.
• Supercritical phases
• pH and alkalinity reconcilation
• Solid Phase editing
• Activity coefficient models
o Strong Electrolyte (AQ) to 30 molal
o Mixed Solvent electrolyte (MSE) to fused-salt and miscible liquid limit
• Equation of State range: -0 to 1500+ atm and -50C to 90% of Critical T
Common Applications
ESP is used in a myriad of applications because of the chemistry breadth covered by the OLI Engine and because
of the ESP block versatility. Therefore, ESP is used in water-purification & processing, oil and gas production,
steam generation, power generation, and utility water. The list below are some example plant applications that
are commonly modeled with ESP.
• Wet/dry flue gas scrubbing and oxidation • Crude tower overhead desublimation
• Sour water stripping • Glycol regeneration
• Autoclaves • Chlor-alkali generation
• Claus plants • Forward osmosis
• Benfield Process • Potash processing
• Amine sweetening and regeneration • Pond evaporation and lithium isolation
• Seawater desalination • Urea production
• OTSG water purification and blowdown • Multiple Effect evaporation
Capabilities
✓ Flowsheet simulation with Streams are carried on a true-species basis and all speciation is considered
speciation for the range of conditions
✓ Comprehensive databank The complete OLI databank has coverage for the electrolyte chemistry of 80
elements, and several thousand aqueous organics, hydrocarbons, and solid
phases
✓ Sensitivity Analysis (2017) Scan the sensitivity of output variables on adjustable input parameters or
species.
✓ Controllers Simple to complex controllers, nested recycles, and flow/component
manipulate blocks are used to make converging on the steady-state solution
more quickly.
✓ Calculator (2017) Interface to Excel for user-supplied calculations
✓ Mass Transfer Limited The user has the ability to set the overall transfer efficiency, individual
tower species mass transfer coefficients, or utilize the list of four column and
sixteen packing types.
www.olisystems.com 240 Cedar Knolls Road, Suite 301, Cedar Knolls, NJ USA 07927
+1-973-998-0240 [email protected]