1-235 CHEMISTRY 2018
Time : 3 Hours J Class: 12th .JM.M.:75
Instructions :
(i) Attempt all questions.
(ii) Question Nos.1 to 4 are objective type. Canies total 20 marks.
(iii) Question Nos. 5 tc_> 8. each question carries 2 marks. (word
limit 30 words)
(w) Question Nos. 9 to 12, each question carries 3 marks. (word
limit 75 words)
(v) Question Nos. 13 to 17, each question carries 4 marks. (word
limit 120 words)
{VI) Question Nos. 18 to 20, each question �rries 5 marks. (word
limit 150 �ords)
(vii) Internal options are given:in Question Nos. 5 to 20.
Q.J Choose the correct option : 1 x 5= 5
(a) The defect in which the crystal lattice have the vacancy of
one cation and one anion is :
(i) Ionic defect (ii)Atomic defect
(iii) Frankel defect (iv) Schottky defect
( b) Fe, Co, Ni are �hich type of magnetic substance?
(i) Paramagnetic (ii) Ferromagnetic
(iii) Diamagnetic· (iv)Anti-ferromagnetic
(c) Which of the following is not an organometallic compound?
(i) Ethyl magnesium bromide(ii) T�tra ethyl lead
(iii) Sodium ethoxide (iv) Tetra methyl aluminium
(d) Which is not a g lyceride?
(i) Fat (ii)Oil
(iii) Phospbolipid (iv) Soap
(e) Which hydride is found in liquid state?
(i) HF (ii) HCI
(iii) HBr (iv) HI
Q2 Fill in the blanks : l x5=5
(a) The process of adding minute amount of impurity in an element
or compound is called ___
(b ) Arrhenius equation is represented by ____
(c) In lead storage cell ____ works as electrolyte.
( d) Carbylamine test gives only ____ amine.
(e) Protein is a polymer of _____
QJ · Write.ziswers in orie word of each : 1 x5=5
. (a) F-centers give colour to crystal due to whose presence?
· (b) Wlµc� noble gas is used_ in elec�ic bulbs with nitrogen?
(c) CoJloidal ·solution of liquid in.liquid is known as ___
(d) Write the name of organometallic compound used as an anti-
. knock.
.. . . .
._ (e) .�ich protein is responsible for the cJothing of blood?
Q.4 Match the pair correctly : 1 x5=5
"A" "B"
(a) Diazonium salt (i) Explosive
(b)Gasmask (il)C6HSN2Cl
(c) Philosopher wool (iii) Radioactive halogen
( d) Astatine (iv)ZnO .
(e)T.N.B. (v) Adsol)'tion of poisonous gases
Q.5 What is Electrophoresis? 2
(Or) What are catalytic promoters? Give one example..
Q. 6 · Sea divers for breathing inside sea uses the mixture of Helium and
Oxygen. Why? 2
(Or) All Halogens are strong oxidising agents. Why?
Q.7 What are chelates? Give one example. 2
(Or) Write chemical fonnula of the following coordinate compounds
(i) Hexaaquachromium (IIQ chloride
(u) Potassfom tetraiodomercurate (II) ·
Q.8 Write the simple and chemical name of vitamins; whose deficiency
causes the following diseases : 2
( i) Sterility
(ii) Non-clotting of blood
(Or) What is peptide bond?
Q.9 On dissolving 4 gm urea in 100 gm water, 1.24 � depression in freezing
point of the solution is obtained. Calculate molecular mass of urea.
(Kr= 1.86 Kmol· 1) 2
(Or) -Calculate osmotic pressure of the solution.which contains 68.4 gram
sucrose in 1000 ml of solution at 293 K.
�,,,;, 0.082 litre attn. K·1 mol·1)
Q.10 Define the following 1+1+1=3
(i) Azeotropic mixtures
· · (u) Isotonic solution
(m} · Semipermeable membrane
...
(Or) Define the following :
. (i) Osmotic pressure ·
(ii) Van'tHofffactor
(ili) Molal freezing depression .constant
Q.11 Write the electronic configuration ofFe2• and Fe3• (Atomic No. ofFe
= 26). Which one is more paramagnetic? 3
(Or) Ionic radii ofFe2•is less than ionic radii ofMn 2•. Why?
Q.12 How is �Cr207 prepared from chromite ore? Write with equation. 3
(Or) ·What is lanthanide contraction? How·is it caused?
Q.13 ·write four differences between molecularity and order reaction.
1+1+1+1=4
(Or) Write four differences between rate of reaction and rate constant.
Q.i4 Write the concentration ofBauxite ore byHall's process with equation.
4
(Or) Describe with diagram the Siemens Martin process of manufacturing
of steel.
'
Q.15 Explain the following reactions ofchlorofonn: 4
(i) Effect ofAir and Sunlight
· (i.J) Reimer-Tiemann Reaction
(Or) · Explain the following reactions ofchlorobenzene :
(�) Reaction with chlorine in the presence ofFeCl 3 in dark
(ii) Fitting reaction. http://www.mpboardonline.com
·
Q.16 Give the reasons : 2 + 2=4
(i) Boiling points of alcoh1'ls are higher than ethers.
(i.J) Pure phenol is a colourless solid but it converted into pink
· after some time by placing open in the. air. Give chemical
reaction. .I
(Or) What do you understand by dehydration of alcohol? Explain it�
mechanism. ,
Q.17 How wiJl you obtain following from acetic a�id? (Give equations only)
.1+1+1+1=4
(i) Acetic anhydride
(it) · Ethyl acetate
(ili) Trichloroacetic acid
· (iv) Acetyl chloride
(Or) How will you obtain following compounds from benzaldehyde?
(Give equations only) ·
(i) · Cinnamaldehyde
(it) Benzoin-
(fu) Cinnamic acid
(iv) Benzoyl chloride
Q.18 Define the following and write the formula and unit of each
I l
(i) Equivalent conductivity 2-+2-=5
2 2
(ii) Molar co�ductivity
(Or) Draw a labelled cljagram of Galvanic cell and explain cell reaction.
Q.19 Explain the hydrides of Nitrogen family under the following
(i)
points: .. 3+ 2=5
(a) Basic property
. (b) Reducing property
( c) Melting and Boiling point.
(ii) PC15 exists but NC1 5 does not, why?
(Or) (i) Explain the hydrides of Oxygen family under the following.
points:
(a) Reducing property
(b) Acidic property •
( c) Thennal stability
(ii) Oxygen exhibits oxidation states -2 to+2 while other elements
of this group exhibit oxidation states +2, +4 and +6, why?
Q20 Define the followi�g and give examples 1+1+1+1+1 = 5
(i) Antifertility
(ii) Antacids
(iii) Hypnotics
(iv) Non-hypnotic
(v) Antibiotics
(Or) (i) What are artificial sweetners? Write any four names.3 + 2 =5
(ii) Write note on insect repellent.
