Ryton

Ryton® PPS
Design Guide

SPECIALTY
POLYMERS
2 \ Ryton® PPS Design Guide
 Table of Contents

Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Assembly Methods . . . . . . . . . . . . . . . . . . . . . . 16

Ultrasonic Welding . . . . . . . . . . . . . . . . . . . . . . . . . 16
Compound Selection . . . . . . . . . . . . . . . . . . . . . 5 Ultrasonic Staking . . . . . . . . . . . . . . . . . . . . . . . . . . 17
The Fiberglass Reinforced Series . . . . . . . . . . . . . . . 5 Heat Staking . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
The Fiberglass and Mineral Reinforced Series . . . . . . 5 Snap Fit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Rivet Assembly . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Adhesives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Part Design . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Tapped Threads for Bolts . . . . . . . . . . . . . . . . . . . . 18
Wall Thickness . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Self-Tapping Screws . . . . . . . . . . . . . . . . . . . . . . . . 19
Weld Lines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Screw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Fiberglass Orientation . . . . . . . . . . . . . . . . . . . . . . . . 7 Ultrasonic Inserts . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Variable Wall Thickness . . . . . . . . . . . . . . . . . . . . . . . 7 Molded-In Threads . . . . . . . . . . . . . . . . . . . . . . . . . 21
Radii . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 Molded-In Inserts . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Ribs and Bosses . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 Interference Fit . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Drafts and Undercuts . . . . . . . . . . . . . . . . . . . . . . . . 8 Machining . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Typical Tolerances . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Computer Aided Engineering (CAE) . . . . . . . . 22
Mold Design . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Mold Temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Tool Steels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Coating Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Surface Treatments . . . . . . . . . . . . . . . . . . . . . . . . . 10
Sprue Design . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Runner Design . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Venting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Gate Geometries . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Gates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Center/sprue gate . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Pin gate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Fan gate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Diaphragm (disk) gate . . . . . . . . . . . . . . . . . . . . . . . . 13
Spoke gate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Flash gate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Edge gate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Tunnel (submarine) gate . . . . . . . . . . . . . . . . . . . . . . 13
Coring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Draft . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

Ryton® PPS Design Guide /3

4 \ Ryton® PPS Design Guide
 Introduction

Compound Selection The Fiberglass and Mineral Reinforced Series

There are two basic series of Ryton® PPS compounds This series includes Ryton® R-7, R-7-120, R10-110 and
from which to select. BR111. In addition to the 260 °C (500 °F) Heat Deflection
Temperature (HDT) at 1.8 MPa (264 psi) and excellent
The Fiberglass Reinforced Series mechanical strength, these compounds provide enhanced
This series includes Ryton® R-4, R-4-200, R-4-220 and electrical properties. This feature allows glass and mineral
R-4-230. The most common determining factors for filled Ryton® PPS compounds to be used in a wide range
selection between these compounds are flow length, of applications including electronic devices, switches, and
mechanical strength and hot water resistance. high density interconnection devices.

Typical glass-filled PPS applications include electronic Please refer to www.solvayspecialtypolymers.com for
connectors, under-hood automotive components, high specific mechanical, physical, electrical, chemical, and
heat appliance parts and a wide variety of industrial thermal data for all Ryton® PPS compounds.
products.

Ryton® PPS Design Guide /5

 Part Design

Part design is a critical aspect of any successful Wall sections must be thick enough to allow adequate
application. Matching end-use requirements of the part material flow into the tool. Figures 1 and 2 illustrate the
with a material’s capabilities is the first step. The designer effect of wall thickness and stock temperature on spiral
must take into consideration the strength of the part flow of Ryton® PPS. Since spiral flow is not packed at the
utilizing proper wall thickness and fiber orientation, and end, only 75 % of this length should be used for design
also consider the ability to fill the required mold. A well- purposes.
designed part will incorporate uniform wall thickness,
Figure 1: Spiral flow vs. wall thickness at 316 °C
adequate corner radii, ample draft, sufficient venting, and
(600 ˚F), maximum injection rate and 2 second fill
a gate location that minimizes the effects of weld lines.
1,016
Incorporating proper design elements will result in a part (40.0)
that can be economically manufactured and reproducible
762

Spiral flow [mm (inch)]

to very tight molding tolerances. (30.0)

Wall Thickness 508

Material cost and cycle time are directly related to wall (20.0)
thickness. Optimum part design balances minimum wall
254
thickness versus sufficient strength. The minimum wall
(10.0) R-4-230NA
section must be thick enough for the material to fill the R-4-200NA
mold under typical processing conditions. With Ryton® 0
R-7-120NA
PPS, as with all resins, it is important to strive for uniform 0.00 0.51 1.02 1.52 2.03 2.54
wall thickness. When this is impractical, parts should (0.02) (0.04) (0.06) (0.08) (0.10)
be designed to fill from thick to thin areas. Uniform wall Wall thickness [mm (inch)]
thickness is also desirable to minimize internal stresses.
Where wall thickness must vary, it should differ by no Figure 2: Spiral flow vs. stock temperature at 2.23
more than 40 % of the thickest wall. Likewise, intersections mm (0.090 inch) thickness with 2 second fill
should have a radius of 60 % of the thinner wall. 1,270
(50.0)
Wall thickness variations can affect the direction of
1,016
material flow and therefore shrinkage. Due to the
Spiral flow [mm (inch)]

(40.0)
fiberglass and molecular orientation, transverse shrinkage
762
is roughly double the flow direction shrinkage. For (30.0)
this reason, it is important that the wall thickness be
508
symmetrical through the cross section of the part. If thick (20.0)
sections are required to fill the part, the cross section R-4-230NA
254
should be as symmetrical as possible. R-4-200NA
(10.0)
R-7-120NA
Many Ryton® PPS part applications have wall thicknesses 0.0
as thin as 0.38 – 0.51 mm (0.015 – 0.020 inch). For example, 310 - 321 - 332 - 332
one battery pack cover measures 25.4 mm × 12.7 mm with (590) (600) (610) (620) (630) (640) (650)
0.38 mm walls (1 × 0.500 × 0.015 inch). There are various Stock temperature [°C (°F)]
connectors having 0.45 mm (0.018 inch) walls, and some
very small parts have walls as thin as 0.15 mm (0.006 inch). Weld Lines
Weld lines are formed when the melt front divides and
In very thick sections, the surface stops shrinking as it
then flows back together. Typically the weld line interface
solidifies while the interior bulk continues cooling and
is resin rich since glass fiber does not cross the interface.
shrinking. The difference in shrinkage can pull the material
This results in lower mechanical strength. If possible,
apart leaving sink marks and shrink voids which reduce
the weld line should be eliminated or located in an area
overall strength. Maximum allowable wall thickness
with lower load requirements. Gate location is critical in
depends on the Ryton® PPS compound selected. Most
determining weld line location. If weld lines must bear
Ryton® PPS parts should not have wall thickness greater
stress, the part design should compensate for typical
than 9.52 mm (0.375 inch).
strengths indicated in Figure 3. Weld line strength
depends heavily on processing, so the part and tool
design should allow for rapid injection, thorough packing
and adequate venting at the weld.

6 \ Ryton® PPS Design Guide

 Figure 3: Weld line strength for Ryton® PPS Figure 5: Wall thickness transitions
compounds

12
T
Flow
10
Tensile strength [Ksi]

Poor
8

6
T
4 Flow

2 Better
3T
0
R-4 R-4- R-4- R-7 R-7- BR111 T
230NA 200NA 120NA Flow

Fiberglass Orientation Best

3T
The orientation of the fiberglass reinforcement affects
strength. Ryton® PPS is stronger in the direction of flow Radii
as compared to the transverse direction. Fiberglass Ryton® PPS compounds, as is the case with other
orientation should be utilized to enhance the strength engineering thermoplastics, are notch sensitive. Therefore
requirements of the part. Part design and gate location sharp corners should be avoided in part designs. The
should minimize stress in the transverse direction. In some optimum fillet radius for Ryton® PPS compounds is 0.6T,
cases, wall thickness must be increased to compensate where T represents the wall (Figure 6) thickness.
for lower transverse strength. Refer to Figure 4 for
transverse versus flow direction strength information. Figure 6: Design for radii

Figure 4: Tensile strength vs. fiberglass orientation

Flow direction strength 0.6T 0.6T
Relative tensile strength

Transverse direction strength

Poor Better Best

Abrupt changes in part geometry, like sharp inside

corners, cause amplification of stress in the area of the
abrupt change. Quick geometry variations can promote
additional problems as well such as flow impedance,
40% glass filled glass/mineral filled molded-in stress and voids. Figure 7 shows the
relationship of stress concentration at a sharp corner as a
Variable Wall Thickness function of the radius to wall thickness ratio.
Some areas of a part may require more strength than
Figure 7: Typical stress concentration factor
others. However, wall thickness should be as uniform as
3.5
possible throughout the part. Radical variations in wall
thickness tend to concentrate stresses – both molded-in
Stress concentration factor

3.0
and externally applied. The shrinkage differential between
thick and thin sections causes molded-in stress at the
2.5
juncture. A uniform wall section creates an even flow that
has uniform shrinkage and minimal molded-in stress. R = 0.6T
2.0 Recommended
design standard
If wall thickness changes are unavoidable, they should be
gradual in order to minimize stress concentration. Figure 5 1.5
shows an example of the preferred method for achieving
a variable wall thickness. Coring the part in thick sections 1.0
is a good way to ensure uniform wall thickness. Coring will 0.00 0.25 0.50 0.75 1.00 1.25 1.50
also provide a means for cost savings in material usage. Radius/wall thickness ratio (R/T)
For further information on coring refer to the Mold Design
section.

Ryton® PPS Design Guide /7

 Ribs and Bosses Drafts and Undercuts
Proper rib design can increase part strength significantly. Ryton® PPS compounds replicate mold surfaces very well
Ribs are most effective in a thin area that must bear a load and flex little during ejection. Therefore, the part design
perpendicular to its plane. Figure 8 illustrates the optimum should avoid undercuts and provide sufficient draft to
relationship between wall thickness, rib thickness and eject the part without flexure. Short cores and shallow
radius. cavities of 4.76 mm (3/16 inch) or less should have at
least 1/4° draft per side. As cavity depth and core length
In addition to allowing reduced wall thickness and cooling
increase to one or two inches, the draft angle should
time, ribbing can improve flow paths to make the part
increase up to 2° per side. Polishing the core and cavity
easier to fill. However, ribs that are too thick can cause
will improve release so a surface finish of 0.0001 mm
sink marks, warpage and cracking. The part design must
(4 microinch) or better should be specified. Polish marks
incorporate a sufficient radius at the base of the rib.
should parallel the direction of part ejection.
Boss design should follow the same rules: avoid thick
In special cases, an undercut can be useful to retain
sections and provide sufficient radius at the base. Figure
parts on the core or cavity during mold opening. The
9 shows the recommended boss design for Ryton® PPS
interference should range from 0.0127 – 0.0254 mm
parts.
(0.0005 – 0.001 inch). Since Ryton® PPS compounds are
Figure 8: Recommended rib design very stiff, any undercut areas in a mold will experience
high wear rates.
H
Hmaximum = 3T Typical Tolerances
T t = 0.6T
Typically, Ryton® PPS exhibits very low shrinkage.
½° to 2°
Therefore, molded part tolerances are highly reproducible,
draft
but depend on the dimension. The larger the dimension,
the larger the tolerance needed. Generally for small
t to medium sized parts a tolerance of 0.1 % of a given
dimension can be held. Larger parts require tolerances
as high as 0.2 %. For an optimally gated small part,
tolerances as tight as 0.01 % can be achieved.
R = 0.6T

Figure 9: Recommended boss design

2.5 to 3D

Hmaximum = 3T 0.6T

R = 0.6T
H

0.6T T

8 \ Ryton® PPS Design Guide

 Mold Design

Mold design is as critical as part design. The best Shrinkage

mold designs optimize the performance properties of Shrinkage is affected by part weight and thickness,
Ryton® PPS. For example, to produce crystalline parts, compound type, fiber orientation, mold temperature,
the mold must be designed to operate at 135 °C (275 °F) amount of coring in the mold and any post-molding
or hotter. It must compensate for material shrinkage annealing. Figure 11 shows the expected shrinkage for a
within the required level of dimensional precision. A well highly cored part.
designed mold will control the effects of gate location and
melt flow paths on shrinkage, wargape, and part strength. Figure 11: Flow and transverse shrinkage for highly
The tool steel used is also a consideration since it will cored parts
determine the length of time the mold will be in service. Flow direction shrinkage

0.006
Mold Temperature

Shrinkage [mm/mm or inch/inch]

Mold temperature significantly affects crystallinity and thus 0.005
the dimensional stability of the part when it is exposed to
0.004
temperatures above the glass transition (Tg) (Figure 10)
temperature. 0.003

Figure 10: Effect of mold temperature on cyrstallinity 0.002

90
0.001
80
70 0.000
Cyrstallinity index

60 1.27 1.78 2.29 2.79 3.30

(0.05) (0.07) (0.09) (0.11) (0.13)
50
Wall thickness [mm (in)]
40
30
Transverse shrinkage
20
0.007
10
Shrinkage [mm/mm or inch/inch]

0
0.006
37 60 82 104 127 149 171 193
(100) (140) (180) (200) (220) (300) (340) (380)
Mold temperature [°C (°F)] 0.005

NOTE: It is very important to keep the mold temperature 0.004

either above 135 °C (275 °F) or below 82 °C (180 °F).

To operate between these temperatures will produce 0.003
40% glass filled
varying resultant dimensions. Parts that are used at high 65% glass/mineral filled
0.002
temperatures should be molded using a mold temperature
at or above 135 °C (275 °F). 1.27 1.78 2.29 2.79 3.30
(0.05) (0.07) (0.09) (0.11) (0.13)
Please refer to the Ryton® PPS Processing Guide for Wall thickness [mm (in)]
specific information regarding mold heating/cooling
equipment and their manufacturers.

Ryton® PPS Design Guide /9

 For any given part, mold shrinkage decreases with Surface Treatments
increasing part weight, as fully packing out the part Successfully used surface treatments are:
decreases shrinkage. Thicker wall sections generally
• Borofuse®
exhibit higher shrinkage than thinner ones since they
hold heat longer. Mold shrinkage increases somewhat • LSR-1®
with increasing mold temperature due to increased • Nitride®
crystallization. Parts restrained during molding by coring • Diamond Black®
will exhibit lower shrinkage than unrestrained parts.
Annealing also affects shrinkage in Ryton® PPS parts. Please consult trade publications such as the “Thomas
Cold-molded parts will develop substantial crystallinity Register for Metal Treating Companies.” Figures 12 and 13
and shrink considerably if held above 204 °C (400 °F) for show tool wear of different steels and surface treatments.
extended periods. Figure 12: Wear resistance of tool steels
Conversely, hot-molded parts already have a high level of 10
crystallinity and exposure to temperatures above 204 °C 9
(400 °F) result in very little additional shrinkage. 8
7

Weight loss [%]

Tool Steels 6
soft
hard
Because of the abrasive nature of the glass and mineral 5
fillers used in Ryton® PPS compounds, hard tool steels are 4
required. For long run production molds, A-2, D-2 or D-7 3
tool steels hardened to Rockwell C-60+ is recommended. 2
Of these, A-2 is commonly used since it is a little more 1
flexible and forgiving. Many times cavity blocks of these 0
harder tool steels can be inserted into a mold base of P-20 A-2 D-2 FERRO-TIC
softer steel to minimize cost and make machining easier.
Because especially high rates of wear are typically Figure 13: Wear resistance of surface treatments
encountered at gates, removable (replaceable) gate blocks 0.20
of D-2 steel are often used. For low volume runs, S-7 and 0.18
H-13 are acceptable softer steels. For complex electrical 0.16
connector molds, S7 is a good choice for core pins to 0.14
Weight loss (%)

minimize breakage because of the increased ductility. 0.12

Coatings and surface treatments are two methods for 0.10
achieving higher wear resistance in long run production 0.08
molds built from softer tool steels. 0.06
0.04
Coating Methods
0.02
Recommended mold coating methods are slow 0.00
deposition Dense Chrome and Electroless Nickel. These Borofuse® Nitride® LSR-1®
coatings provide good mold release characteristics and
fairly long life. It is important to note that steels with a Prototype tooling is often an excellent way to produce
surface finish of 0.0001 mm (4 microinches) or better a short production run of parts and discover the unique
experience extended service life. facets of producing particular parts. Prototype tools can
be made from a variety of softer steels and aluminum.
The ease of machining the softer metals makes them
economical to use during prototyping. Care must be
taken, however, with aluminum tools since they are more
difficult to heat uniformly and cannot withstand high
injection and clamping pressure as well as steel tools.

10 \ Ryton® PPS Design Guide

Sprue Design Multi-cavity molds should have balanced runner systems.
Standard sprue designs are quite acceptable with nominal On multi-cavity molds with primary and secondary
values of 2° of draft and reverse taper or Z-cut sprue puller runners, the primary runner should carry on beyond the
systems. Keep the runner as short and highly polished as intersection of the secondary runner in order to provide
possible to ease part removal from the stationary half of a cold slug well for the runner flow front. Runner length,
the mold. Figure 14 shows a standard sprue design. however, should be kept at a minimum (Figure 16).

Figure 14: Standard sprue design Figure 16: Balanced runner and cavity

Machine Locating
nozzle ring

Sprue D
bushing
Fixed
half

Moving
half Cold slug well
Runner length should be kept at a minimum with runner
“Z” puller diameter optimized for the compound to be used.
Ejector pin Suggested minimum runner diameters are listed in
Table 1. The diameters listed in the table are suggested
sizes starting at the gate and moving toward the sprue.
Runner Design
The diameter should be increased 20 % at each 90˚
It is very important that the runner system be designed runner turn. Where two secondary runners converge
so that the mold cavities fill uniformly and in a balanced to form a larger secondary runner or main runner, the
fashion. diameter should be increased 40 %. In addition, for eight
Runners of many types can be used successfully with cavity or higher molds, the use of a melt flipper should
Ryton® PPS compounds. Full round and trapezoidal be considered. For specific details about the melt flipper
runners are preferred (Figure 15). Runners should be technology, please contact your Solvay representative
designed with cold slug wells. or contact the manufacturer, Beaumont Runner
Technologies, Inc. (www.meltflipper.com)
Figure 15: Trapezoidal runner profiles
Table 1: Minimum runner diameter, mm (inch)
15°
R-4 R-4 XT, BR111
W R-4-230 R-4-200 R-7-120
L = 127 (5) 3.175 (0.125) 4.775 (0.188) 4.775 (0.188)
L = 254 (10) 4.775 (0.188) 6.350 (0.250) 6.350 (0.250)
D L = 381 (15) 6.350 (0.250) 7.950 (0.313) 7.950 (0.313)

Generally, it is good practice with engineering

Equivalent runner diameter “D”
thermoplastics to not use family mold layouts because
of differences in filling patterns. These differences are
Width [W] Depth [D]
“W” “D” sometimes difficult to control and may produce parts with
mm in inch mm mm
in mm inch differing physical and mechanical properties. However,
1/4 3/16
6.4 1/4 6.4 4.8 4.8 3⁄16 if a family mold must be used, a rotating runner shut-off
5/4 1/4
7.9 6.4
7.9 7/165/16 11.1 56.4 1⁄4 should be incorporated into the runner design in order to
/16 7.9
11.1 1/2
7/16 12.7 3/8
7.9 9.5 5⁄16 allow individual cavity molding.

12.7 1/2 9.5 3⁄8

Ryton® PPS Design Guide / 11

 Venting Gate Geometries
To successfully mold Ryton PPS compounds, proper
®
The illustration in Figure 18 points out some of the pitfalls
venting is essential. Poor or improper venting results of less than optimal gating methods and offers design
in hard to fill parts and burning of the part in areas solutions.
where gas is trapped. In addition, trapped gas leads to
Part distortion is caused by differential shrinkage. As
accelerated mold wear.
the molded part shrinks, internal stresses are developed
Venting can be accomplished with 0.0076 – 0.0127 mm which distort the part. The greater the difference in part
(0.0003 – 0.0005 inch) deep by 6.4 mm (0.25 inch) wide cross sections, the greater the chance of distortion.
channels cut on the parting line (Figure 17). Flattened
To avoid distortion, the designer should strive to maintain
ejector pins can also be used as vents. Stationary vent
uniformity throughout the part and minimize weld lines.
pins are not recommended as various substances can
Since Ryton® PPS compounds are filled compounds,
clog them over long part runs. Vacuum venting has been
they behave anisotropically. For typical Ryton® PPS
used successfully in areas where a blind pocket exists.
compounds, this means parts will shrink about half
The vacuum is turned on after the mold closes and prior
as much in the flow direction as perpendicular to the
to the start of the injection cycle. Vented runners are
direction of flow.
recommended.
Figure 18: Gate geometries
Figure 17: Parting line vent detail

A A

6.4 mm
( 0.25 in)

Weld lines

0.8 - 1.6 mm
(0.06 - 0.09 in Land )
Parting line

Depth
a b c d
Edge 3-pin Spoke Diaphragm
gate gates gate gate
Section A - A
For larger parts, direct gating into the top surface using
multiple gates has shown to be effective in reducing
warpage.

12 \ Ryton® PPS Design Guide

 Gates The following list represents the majority of gating choices
A variety of different gating methods is suitable for available. Where it is applicable, the gate land length
molding Ryton® PPS compounds. The graph of minimum should be kept as short as possible or 0.030 in maximum.
gate diameter or thickness versus overall part volume
Center/sprue gate
shown in Figure 19 depicts the relative need for increasing
Efficient and works well on parts where concentricity is
the gate diameter or thickness as overall part volume
important or parts with dome shapes (Figure 20).
increases. The remove quotes for round gates shown
in Figure 19 may also be considered the minimum gate Pin gate
thickness for typical rectangular gates having a width of
Used much like a sprue gate, this gate can be used with
two times the gate thickness. A good guideline for larger
multi-cavity tooling and provides automatic separations of
parts is for the gate diameter or thickness to be about
part from runner (Figure 21).
60 % to 75 % of the maximum wall thickness of the part.
Success has been shown with center, sprue, tab, flash, Fan gate
round, disk, submarine, and spoke gates. The placement
Good for uniform polymer flow front into a part similar to a
of the gate is essential in determining the potential
flash gate (Figure 22).
strength and dimensional stability of the part. Small parts
can usually be gated in a single location to prevent weld Diaphragm (disk) gate
lines. If the part cannot be molded without weld line(s), the Ideal for producing highly concentric cylindrical parts
weld line(s) should be placed in the thickest section of the without weld lines (Figure 23).
part or in areas where there is minimal stress.
Spoke gate
Figure 19: Minimum Gate Diameter
Can be used in parts which are too large for a diaphragm
0.160 4.00
gate. Odd number of spokes should be used so that gates
0.140 3.50
Minimum gate diameter [inch]

are not opposite one another. In addition, gates should

Minimum gate diameter [mm]

0.120 3.00 be positioned such that weld lines form in the areas of
0.100 2.50 thickest cross section (Figure 24).
0.080 2.00
Flash gate
0.060 1.50
Good for parts with large flat surfaces requiring minimum
0.040 1.00 warpage (Figure 25).
0.020 0.50
Edge gate
0.000 0.00
Most commonly used; allows high degree of fiber
0.1 1 10 100 1,000
orientation and is generally seen on multi-cavity molds
Part volume [cc]
requiring moderate precision in tolerances (Figure 26).

Tunnel (submarine) gate

Submarine gates have been used successfully with
Ryton® PPS compounds; however, special consideration
must be given to the design. The tunnel included angle
should be 30 – 35° and the center line of the tunnel
should be 25 – 30° from a line drawn perpendicular to the
mold parting line. Figure 27 presents a recommended
submarine gate design. The tunnel must be well polished
with no undercuts.

Ryton® PPS Design Guide / 13

 Figure 20: Sprue gate Figure 24: Spoke gate
Sprue Polish to a A
spherical radius
A
Part Mold
parting
line
Spoke
gate
Part wall

Figure 21: Pin gate

Runner
plate T Secton A - A Ejector pin

R = 0.6 T
Cavity
retainer Draft
plate 1° - 3°
Land length Figure 25: Flash gate
Gate
size Gate
A A
Figure 22: Fan gate
A Runner A

Gate Runner
Runner
Secton A - A

Section A - A Figure 26: Edge gate

Figure 23: Diaphragm gate 0.51 mm

( 0.020 in)
A A

See minimum
Ejector pin gate size
Part
wall
Gate

Figure 27: Tunnel gate

Diaphragm Gate angle 30° - 35°

Gate
Sprue Centerline
angle
Secton A - A
25° - 30°
D

Knockout pin

1 - 1½ D

14 \ Ryton® PPS Design Guide

Coring Draft
Thick part sections should be cored to provide uniform Ryton® PPS compounds flex very little during ejection;
wall thickness. This design practice will avoid sink marks therefore, the part design should provide sufficient
and voids, reduce stress and cycle time, and offer material draft to eject the part without flexure. Short cores and
savings. Cores that extend into the cavity will be subject shallow cavities of 4.76 mm (3/16 inch) or less should
to high pressure; therefore, these cores should generally have at least 1/4° draft per side. As cavity depth and
have a minimum diameter of D = 1.27 mm (0.05 inch) and core length increases to one or two inches, draft angle
should not extend more than 2D unless they pass entirely should increase up to 2° per side. Polishing the core and
through the cavity (Figure 28). cavity will improve release so specify a surface finish of
0.0001 mm (4 microinch) or better. Polish marks should
Figure 28: Coring problems and solutions
parallel the direction of part ejection. This is typically
Before coring Redesign referred to as draw polishing.

Core equally
from both sides
Sinks

Sinks

T 0.6T

Sink

Ryton® PPS Design Guide / 15

 Assembly Methods

Most products incorporate several functions that require Figure 29: Shear joint for ultrasonic welding
different levels of performance or dimensional precision. In
Before weld
many cases, Ryton® PPS compounds can meet all these
requirements, allowing the designer to combine these
functions into a single molding. When part geometry or
functional needs necessitate more than one molding or R = 0.6 W
material, the components should be designed to minimize W = 1.3 mm W
the cost and complexity of assembly procedures. (0.050 in)
minimum Pilot
Ryton® PPS parts may be assembled using a variety of
techniques, each requiring certain design considerations. Depth
Procedural details are presented in other Ryton® PPS of weld 0.4 - 0.8 mm
literature. ( 0.015 - 0.03 in)
Interference =
Ultrasonic Welding 0.3 - 0.4 mm
Ryton® PPS compounds are relatively easy to weld ( 0.012 - 0.015 in)
Clearance =
together. Joint design is, however, critical to the finished 0.05 - 0.13 mm
part strength. A shear joint is the best overall, although the ( 0.002 - 0.005 in)
step joint has been used successfully with Ryton® R-4. After weld

The shear joint will generally be six times stronger than the
step joint. There are many types of joint designs. Typical
designs for shear and step joints are shown in Figures 29
and 30.

When welding shear joints, use high power with a high

amplitude booster, low pressure, and slow horn speed.
When welding the parts, caution should be used since too
high of an amplitude and/or too long of an application time
could destroy the part (Figure 29).
Figure 30: Step joint for ultrasonic welding
Shear joints are usually not recommended for parts with
a maximum dimension of 89 mm (3.5 inch) or greater, Before weld
sharp 90˚ turns, or irregular shapes, due to the difficulty W
of holding the required molding tolerances. Ryton® PPS
may extend these limits, however, since it can hold tight
molding tolerances.

Some of the more common joint design mistakes to avoid W/3 H

are: W/3
1. Joints that are too tight or too close together which
prevents adequate vibration
2. Section transmitting the ultrasonics is too thin as it may
crack under the high amplitude level C

3. Too large of a step, requiring a high instant power that C = 0.05 - 0.13 mm ( 0.002 - 0.005 in)
may destroy the part H = 0.2 - 0.6 mm (0.008 - 0.025 in)

4. Assembly in which the highest part does not vibrate

After weld
5. Energy director design that prevents a homogenous
weld

16 \ Ryton® PPS Design Guide

Ultrasonic Staking The optimal process conditions for a typical 3.18 mm
Ultrasonic staking is an assembly method that uses (1/8 inch) diameter post might be, for an amorphous part,
the controlled melting and reforming of a plastic stud a tip temperature of 310 °C (590 °F). For a crystalline part,
or boss to capture or lock another component of the use a tip temperature of 327 °C (620 °F). The downward
assembly. The plastic stud protrudes through a hole in force is typically 68 kg (150 lbs.) applied for 40 seconds.
the component, then the high frequency vibrations of Since the staked area will be amorphous after the melt/
the ultrasonic horn are imparted to the top of the stud. deformation, the assembly should be annealed at 204 °C
The stud melts and fills the volume of the horn cavity to (400 °F) for 2 hours if the application requires a fully
produce a head, locking the component in place. The crystalline part.
progressive melting of plastic under continuous but The heat staking tip is designed in the same manner as
generally light pressure forms the head. Ultrasonic staking the horn head for an ultrasonic staking unit. However,
causes some reduction in tensile strength of the reformed since all glass reinforced compounds can be abrasive, we
stud. recommend that the staking tip be made of a hardened
The advantages of ultrasonic staking include short steel with a Rockwell C rating of 60 or greater.
cycle time, tight assemblies with virtually no tendency
Snap Fit
for recovery, ability to perform multiple stakes with one
horn, repeatability and control over the process, design The most convenient method of assembling plastic
simplicity, and the elimination of consumables such as parts is the snap fit. The savings in assembly costs more
screws. than offset the increase in tooling costs required by this
technique. Studies have shown that the high strength
There are two head-forms that will satisfy the and ridgity of Ryton® PPS compounds provide good
requirements of a majority of applications (Figure 31). holding strength with a minimum of flex and interference.
The first, generally considered standard, produces a Figure 32 details the guidelines for the design of snap fit
head having twice the diameter of the original stud, with members for different Ryton® PPS compounds. Typically,
a height 1/2 the stud diameter. The second, referred to Ryton® PPS snap fit applications involve only one time
as a low-profile, has a head diameter 1 – 1/2 times the assembly.
stud diameter, with a head height 1/4 the size of the head
diameter. Figure 32: Snap fit design parameters

Figure 31: Ultrasonic staking methods

t
d d

Δ
D D

H H
L

Calculate maximum deflection by:

εL 2
2D ∆ =
1.5D 3C
½D ¼D where:

∆ = Calculate maximum
Deflection at break*deflection by:
L = Length
Heat Staking C = t/2 εL2
Δ=
Heat staking is very similar to ultrasonic staking and has t = Thickness sC
many of the same advantages plus greater strength. ε = 0.018 for R-4XT, R-4-200
Testing has demonstrated that amorphous parts (cold 0.014 for R-4, R-4-230
Where:
molded) stake more easily and exhibit more strength than Δ 0.010 for R-7,atR-7-120,
= deflection break* BR111
crystalline (hot molded) parts. The rate of heat transfer is L = length
controlled by adjusting the interdependent variables of * Use
C= 75 %
t/2 for one time assembly
Uset =50 %
thickness
for multiple assemblies
the tip temperature and downward pressure. Too much
ε = 0.015 for R-4XT, R-4-200
pressure and/or too low of a temperature will crack the 0.014 for R-4, R-4-230
post before melt-deformation can occur. 0.010 for R-7, R-7-120, BR111

*Use 75% for one time assembly

Use 50% for multiple assemblies

Ryton® PPS Design Guide / 17

 Rivet Assembly Tapped Threads for Bolts
Ryton PPS can be successfully assembled using semi-
®
It is often desirable to assemble plastic components to
tubular style rivets. each other or to different materials using bolts. In most
applications where repeated assembly and disassembly
The definition of a semi-tubular rivet is a rivet whose mean
is not required, Ryton® PPS moldings with tapped threads
hole depth, measured on the wall, does not exceed 112 %
work very well.
of its mean body diameter. This design will put less stress
on the molded parts, especially if the distance between To characterize the bolt holding strength of Ryton®
the hole and the underside of the head is the same as PPS compounds, holes were drilled in injection molded
the combined material thickness. In order to ensure that 15.9 mm (0.625 inch) thick Ryton® PPS R-4 and R-10
minimum stress is placed on the molded parts during 7006A slabs. Three hole sizes were tapped for a variety
riveting operations, it is essential that the rivet setter be of common threads, ranging from 4-40 to 1/4-20 bolts.
adjusted to exert the minimum impact required to clinch The three hole sizes chosen were, one hole size smaller,
the rivet. Even more successful are the (Tommel) rivet one hole size larger, and the recommended hole size for
setting machines that round over the metal on the bottom steel threads, as shown in the “Machinery’s Handbook”
of the rivet. This places even less stress on the part for each bolt. The bolts were then screwed into the hole to
(Figure 33). three depths, four bolt diameters (except the 1/4-20), two
bolt diameters, and three turns. Samples were then pulled
Figure 33: Example rivets
in an Instron to measure the force required either to pull
the bolt from the hole, or to break the bolt.

The data in Table II demonstrates that tapped holes in

Ryton® PPS glass mineral filled compounds have excellent
bolt holding power. Bolts screwed in to a depth of four
bolt diameters equaled or exceeded the tensile strength
of brass and mild steel bolts. Bolts screwed in three
Solid Hollow Semi-tubular turns and those at two bolt diameters also had excellent
strength.
Adhesives
Adhesive bonding is a versatile method of joining like or
dissimilar materials. Holes, rivets, clamps, and screws
have a tendency to cause stress points in concentrated
areas. Adhesives tend to distribute the load over the
entire area, thus virtually eliminating localized stress
areas. There are many adhesives that will bond Ryton®
PPS compounds, provided the surface is properly
prepared to allow the adhesive to wet the surface. The
adhesive should be selected to best meet the need for the
application in which the product will ultimately be used.

In each adhesive application, the following criteria must be

considered:
1. Characteristics of the materials to be joined
2. Surface preparation
3. Joint design
4. Adhesive selection and handling
5. Application
6. Cure of the adhesive/adhered couple
7. Ultimate strength and environmental performance of
the “adhesively joined” fabricated part or structure.

Surface preparation and adhesive selection is discussed

in our technical bulletin entitled, “Bonding Adhesives and
Paints to Ryton® PPS.”

18 \ Ryton® PPS Design Guide

Table 2: Bolt holding strength in Ryton® PPS glass mineral filled compounds
Drill Size Pull Out Strength
Bolt Size [mm (inch)] Bolt Depth [N (lbf)]
4-40, Mild steel No. 43 3 Turns 818 (184)
2.84 (0.112) 2.26 (0.089) 5.69 (0.224) 413 (1837)
11.38 (0.448) 1744 (3921)
6-32, Brass No. 36 3 Turns 1085 (244)
3.51 (0.138) 2.69 (0.106) 7.01 (0.276) 2544 (5721)
13.26 (0.522) 2664 (5991)
8-32, Brass No. 29 3 Turns 1050 (236)
4.17 (0.164) 3.45 (0.136) 8.33 (0.328) 3385 (7611)
15.88 (0.625) 3385 (7611)
10-24, Mild steel No. 25 3 Turns 1628 (366)
4.83 (0.190) 3.78 (0.149) 9.65 (0.380) 5040 (11332)
15.88 (0.625) 6263 (14081)
10-32, Brass No. 21 3 Turns 1219 (274)
4.83 (0.190) 4.04 (0.159) 8.08 (0.318) 4092 (9202)
15.88 (0.625) 6094 (13701)
1/4-20, Mild steel No. 7 3 Turns 2491 (560)
6.35 (0.250) 5.33 (0.210) 13.97 (0.550) 10942 (24602)
15.88 (0.625) 11640 (26171)

1= Bolts Broke, 2= Stripped Threads

Self-Tapping Screws
The excellent creep resistance of Ryton® PPS makes it Tables 3, 4 and 5 show the holding power and torque
well suited for assembly with self-tapping screws. Due to retention of self-tapping screws in Ryton® PPS 40 % glass
the hardness of Ryton® PPS compounds, thread cutting filled and 65 % glass/mineral filled compounds. This data
types, rather than thread forming types, perform best. The indicates that Ryton® PPS is an excellent choice for screw
hole size recommended by the “Machinery’s Handbook” assembly techniques.
for phenolformaldehyde thermosets should be used.

Table 3: Self-tapping (thread cutting) screw holding power in Ryton® PPS 40 % glass filled compound

Thread Driving Undriving Stripping Avg. Holding Suggested

Screw Type and Engagement Torque Torque Torque Load Tensile Drill Size
Size Mild Steel [mm (inch)] [Nm (inch · lbf)] [Nm (inch · lbf)] [Nm (inch · lbf)] [N (lbf)] [mm (inch)]
Type F
#4-40 4.76 (3⁄16) 0.2 (2) 0.1 (1) 1.0 (9) 729 (164) #40 2.49 (0.0980)
4-40 7.94 (5⁄16) 0.5 (4) 0.2 (2) 1.7 (15) 2122 (477) 40 2.49 (0.0980)
6-32 6.35 (1⁄4) 1.0 (9) 0.7 (6) 2.1 (19) 1597 (359) 32 2.95 (0.1160)
6-32 7.94 (5⁄16) 1.2 (11) 1.0 (9) 3.7 (33) 2420 (544) 32 2.95 (0.1160)
8-32 7.94 (5⁄16) 1.1 (10) 1.1 (10) >5.6 (>50) 2722 (612) 27 3.66 (0.1440)
8-32 12.7 (1⁄2) 2.4 (21) 2.4 (21) >5.6 (>50) 6049 (1360) 27 3.66 (0.1440)
10-24 7.94 (5⁄16) 2.0 (18) 1.7 (15) 5.1 (45) 2188 (492) 20 4.09 (0.1610)
10-24 12.7 (1⁄2) 2.7 (24) 2.7 (24) >5.6 (>50) 4906 (1103) 20 4.09 (0.1610)
10-32 7.94 (5⁄16) 3.2 (28) 3.2 (28) >5.6 (>50) 3314 (745) 20 4.09 (0.1610)
10-32 12.7 (1⁄2) 5.6 (50) 5.6 (50) >5.6 (>50) 5035 (1132) 20 4.09 (0.1610)

Ryton® PPS Design Guide / 19

 Table 4: Self-tapping screw holding power in Ryton® PPS 65 % glass filled compound

Thread Driving Undriving Stripping Pull Out

Screw Size Drill Size Engagement Torque Torque Torque Strength
[mm (inch)] [mm (inch)] [mm (inch)] [Nm (inch · lbf)] [Nm (inch · lbf)] [Nm (inch · lbf)] [N (lbf)]
4-40, No. 40 4.76 (3⁄16) 0.2 (2) 0.1 (1) 0.1 (9) 983 (2212)
2.84 (0.112) 2.49 (0.0980) 7.94 (5⁄16) 0.5 (4) 0.3 (3) 1.6 (14) 1993 (448)
6-32 No. 32 6.35 (1⁄4) 0.9 (8) 0.7 (6) 2.0 (18) 1672 (3762)
3.51 (0.138) 2.95 (0.1160) 7.94 (5⁄16) 1.0 (9) 0.8 (7) 2.7 (24) 2638 (593)
1
8-32 No. 27 7.94 (5⁄16) 1.1 (10) 0.9 (8) >5.6 (>50) 2464 (5542)
4.17 (0.164) 3.66 (0.1440) 12.7 (1⁄2) 1.8 (16) 1.7 (15) >5.61 (>50) 5618 (1263)
1
10-24 No. 20 7.94 (5⁄16) 1.8 (16) 1.2 (11) >5.6 (>50) 2233 (5022)
1
4.83 (0.190) 4.09 (0.1610) 12.7 (1⁄2) 3.1 (35) 2.7 (24) >5.6 (>50) 5769 (1297)
10-32 No. 20 7.94 (5⁄16) 3.2 (28) 2.8 (25) >5.61 (>50) 3389 (7622)
1
4.83 (0.190) 4.09 (0.1610) 12.7 (1⁄2) >5.6 (>50) 4.6 (41) >5.6 (>50) 5983 (1345)
1
Accurate readings could not be obtained above 5.6 Nm (50 inch · lbf) of torque.
2
Failures resulted from brittle fracture of Ryton® PPS.

Table 5: Torque retention of self-tapping screws in Ryton® PPS 40 % glass-filled compound
Unscrewing Torque Unscrewing Torque
Application Torque after 24 h at Room Temp., after 24 h at 71 °C (160 °F),
[Nm (inch · oz)] [Nm (inch · oz)] [Nm (inch · oz)]
0.092 (13) 0.087 (12.3) 0.083 (11.7)
0.113 (16) 0.101 (14.3) 0.085 (12.0)
0.141 (20) 0.125 (17.7) 0.118 (16.7)

Screw Data
• Screw length: 4.98 mm (0.196 inch)
• Screw diameter: 1.85 mm (0.073 inch)
• Drilled hole size: 1.50 mm (0.059 inch)
• Height of head: 1.80 mm (0.071 inch)
• Head diameter: 3.00 mm (0.118 inch)
• Contact area of head: 4.50 mm2 (0.007 inch2)

20 \ Ryton® PPS Design Guide

Ultrasonic Inserts Table 6: Specifications for ultrasonic inserts
Like other thermoplastics, Ryton PPS can be
®

conveniently assembled using ultrasonic inserts. Table Size Insert Length D Max. E Max.
6 shows how a 15.9 mm (0.625 inch) Ryton® PPS, No. 0 & No. 2 0.115 0.121 0.126
65 % glass/mineral filled compound slab was used to 0.188 0.110 0.126
develop pull data on three common sizes of inserts. No. 4 0.135 0.156 0.162
Inserts of these types are recommended when repeated 0.219 0.144 0.162
disassembly is required, and good pull-out strength is No. 6 0.150 0.202 0.209
desirable. Figure 34 shows design recommendations for 0.250 0.188 0.209
other common inserts. No. 8 0.185 0.229 0.237
The tapered hole is specified for the following reasons: 0.312 0.211 0.237

1. Positioning of the insert is faster, more accurate and No. 10 0.225 0.270 0.280
ensures proper alignment every time 0.375 0.249 0.280

2. Places the insert in a “partially installed” position in 1/4 inch 0.300 0.352 0.366

the hole, permitting more rapid installation because 0.500 0.324 0.366
the volume of plastic which must be displaced is 5/16 inch 0.335 0.434 0.451
decreased 0.562 0.404 0.451
3. Provides the best release of the plastic part from the 3/8 inch 0.375 0.526 0.543
mold 0.625 0.491 0.543

(All dimensions in inches)

Figure 34: Design recommendations for
ultrasonic inserts

8°

Emax

Minimum depth =
insert length +
0.762 mm ( 0.030 in)

Dmax

Molded-In Threads
Because of the excellent processability of Ryton® PPS, molded-in threads can be designed into most parts. This will
eliminate the need for expensive secondary machining operations. Molding in the threads should also provide superior
performance, as compared to machined threads, due to the normal skin effect on injection molded parts. Table 7 has the
pull-out values for molded-in threads.

Table 7: Holding power of various fastening methods in Ryton® PPS 65 % glass mineral filled compounds

Fastening Fastener Thread Size Drill Size Engagement Pull Out Strength
Method Type [mm (inch)] [mm (inch)] [mm (inch)] [N (lbf)]
Ultrasonic Dodge® 6-32 4.78 (0.188) 6.35 (0.250) 1704 (383)
insert Ultrasert II* 3.51 (0.138)
Ultrasonic Dodge® 10-32 6.32 (0.249) 9.53 (0.375) 3492 (785)
insert Ultrasert II* 4.09 (0.161)
Molded 1/4-20 12.7 (0.500) 7264 (1633)
threads 6.35 (0.250)
Molded Yardley® (Brass) 1/4-20 12.7 (0.500) 13731 (3087)
inserts standardized 6.35 (0.250)

Ryton® PPS Design Guide / 21

 Molded-In Inserts Computer Aided Engineering (CAE)
Because of the excellent processability of Ryton PPS,
®
Our Computer Aided Engineering services include a full
molded-in inserts can be designed into many parts. complement of analysis programs prepared to assist
Molded-in inserts may be used when repeated assembly at any stage of the development cycle. From design to
and disassembly of parts is required. Since Ryton® PPS testing, you can be assured that your product is being
easily molds around inserts, excellent pull-out strengths evaluated with state-of-the-art programming by material
should be expected. Inserts are recommended when and processing experts.
an appreciable amount of preload is desired. The insert • Computer Aided Design
should be designed such that the load is carried through
• Material selection
the metal insert and not the plastic. Flanged type inserts
work well for highly loaded applications. • Flow analysis
• Shrink evaluation
Interference Fit • Molding optimization
The strength and modulus of Ryton® PPS compounds
• Finite Element Analysis
makes them suitable for retention of interference fit
components; however, molded-in inserts are generally
perferred especially for larger components such as
Conclusion
hubs or bearings. To prevent cracking, the degree of These design guidelines are intended to help designers
interference should typically not induce more than about maximize the versatility of Ryton® PPS engineering
0.5 % hoop strain. Tests have shown that increasing depth thermoplastics in their products. Our suggestions are the
of insertion (or increasing the area of surface contact) result of direct experimentation and our Technical Service
can be more effective at improving pull out strength than staff’s experiences in helping customers. For more
increasing interference. detailed information, contact Solvay Specialty Polymers.

Machining
Because of its exceptional mechanical properties, Ryton®
PPS can be readily machined with conventional metal
working tools. A high degree of precision can be obtained
with Ryton® PPS while using moderate cutting speeds
and fast feed rates. It is recommended that carbide tipped
tools be used for machining all Ryton® PPS compounds.

In general, the best surface speed will be in the range of

1.5 to 3.5 m/s (300 to 700 SFM) for turning operations, 0.5
to 1.0 m/s (100 to 200 SFM) for milling operations, and 1.0
to 1.5 m/s (200 to 300 SFM) for drilling and reaming.

The rate of travel should be relatively fast. A slow feed

results in excess abrasion by the tool and will tend to give
poor surface appearance. If a coolant is desired, ethylene
glycol (antifreeze) works well.

Although fairly deep cuts of up to 3.17 mm (1/8 inch)

can be made, finish cuts should take off no more than
0.127 mm (0.005 inch) of material.

22 \ Ryton® PPS Design Guide

Ryton® PPS Design Guide / 23
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