Paul C. Painter Michael M. Coleman Physical Properties of Polymers
Paul C. Painter Michael M. Coleman Physical Properties of Polymers
Designation : Compulsory
Pre-requisites : Chemistry
Credit and
: 3(L) - 0(T) – 2(P) – 4(Cr)
Contact hrs
Theory Examination: (Scheme) End Semester Exam: 60 marks
Assessment Mid Semester Exam: 20 marks
:
Methods Internal Assessment: (Scheme) 20 marks (5 marks for attendance + 15 marks for assignment
submission, Surprise Tests, Term paper etc)
After completion of the course, students will be able to:
1. Understand polymerization process and techniques
Course 2. Explain the structure-property relations and flow behaviour of polymers
:
Outcomes 3. Demonstrate characterization and testing of polymers and composites
4. Understand the manufacturing process of composites
5. Choose an appropriate polymer material for various applications.
Modes of
: Talk and chalk, Power point presentations, and practical etc.
Delivery
Mapping of course outcomes with program outcomes
Course
PO1 PO2 PO3 PO4 PO5 PO6 PO7 PO8 PO9 PO10
outcome
CO1 √ √ √ √
CO2 √ √
CO3
Syllabus
Chemistry of Polymers: Polymerization methods and kinetics, copolymerization, different copolymers,
polymerization techniques, molecular weight of polymers, glass transition temperature and crystallinity in polymers.
Synthesis and properties of thermoplastics, Thermosetting polymers, Natural and synthetic rubbers, Thermoplastic
Elastomer.
Polymer Characterization: Solubility and swelling, determination of molecular weights, polydispersity, analysis of
polymers using IR, XRD, thermal (DSC, DMTA, TGA), microscopic (optical and electronic) techniques.
Polymer Rheology: Flow of Newtonian and non-Newtonian fluids, parameters influencing the polymer rheology,
types of rheometer, viscoelasticity mechanical models, rubber curing.
Polymer Blends: blend miscibility-miscible and immiscible blends, thermodynamics and phase morphology.
Compounding ingredients, cross-linking and vulcanization.
Polymer Processing: Compression molding, transfer molding, injection molding, blow molding, reaction injection
molding, extrusion, calendaring, rotational molding, thermoforming, two-roll mill and internal mixer.
Polymer Testing: Mechanical tests, Conductivity-thermal and electrical, dielectric constant, electric resistance, surface
and volume resistivity, swelling, ageing resistance, environmental stress cracking resistance. ASTM codes for polymer
testing.
Polymer composites: Fiber and matrix materials, fiber architecture. Manufacturing techniques- Hand layup, bag
moulding process, compression molding, liquid composite moulding, Filament winding, Pultrusion, reactive polymer
composites, Thermal and mechanical properties, Testing of composites, advantages and applications.
List of Experiments:
1. Identification of various polymers.
2. Bulk photo-polymerization of Methyl Methacrylate
3. Preparation of Polystyrene by the free radical polymerization process
4. Preparation of Nylon by interfacial polymerization
5. Preparation of cured epoxy resin by room temperature reaction
6. Molecular weight determination by viscometry and end-group analysis
7. Mechanical testing of plastic and rubbers
8. Preparation and mechanical testing of fiber reinforced plastics.
References books
1. Polymer Science, Vasant R. Gowariker, N. V. Viswanathan & Jayadev Sreedhar.
2. Encyclopedia of Polymer Science and Technology, Herman F. Mark.
3. Essentials of Polymer Science and Engineering, Paul C. Painter and Michael M. Coleman.
4. Physical Properties of Polymers, James Mark, Kia Ngai, William Graessley, Leo Mandelkern, Edward
Samulski, Jack Koenig, George Wignall.
5. Plastics Engineering, R. J. Crawford, Pergamon Press.
6. Text Book of Polymer Science, Billmeyer, John Wiley & Sons.
7. Principles of Polymerization, Odian G, 4th ed., John Wiley & Sons.
8. Processing of Polymer Matrix Composites, P.K. Mallick, CRC Press.
Designation : Compulsory
Pre-requisites :
Credit and
: 3(L) - 0(T) – 2(P) – 4(Cr)
Contact hrs
Theory Examination: (Scheme) End Semester Exam: 60 marks
Mid Semester Exam: 20 marks
Assessment
:
Methods Internal Assessment: (Scheme) 20 marks (5 marks for attendance + 15 marks for assignment
submission, Surprise Tests, Term paper etc)
Semester-VII