Practise Question (Calculations) Answer
Practise Question (Calculations) Answer
Answer: 2.81N
𝑞2
𝐹=
4𝜋𝜀0 𝑟 2
= 2.81𝑁
2
Topic 2 – Bonding of Materials
Answer: 1.39m
𝑞2
𝐹=
4𝜋𝜀0 𝑟 2
1 𝑞 2
𝑟2 = ×
4𝜋𝜀0 𝐹
𝑁 ∙ 𝑚 2 (26.0 × 10−6 𝐶)(47.0 × 10−6 𝐶)
= (8.99 × 109 )
𝐶2 5.70𝑁
= 1.93𝑚2
𝑟= 1.93𝑚2 = 1.39𝑚
3
Topic 3 – Structure of Crystalline Solids &
Imperfection
1. If the atomic radius of lead is 0.175 nm, calculate the volume of its unit
cell in cubic meters. Lead has FCC structure.
Answer: 1.21 x 10-28 m3
a
4r
a
a
𝑎 = 8𝑟
2. Calculate the fraction of atom sites that are vacant for copper (Cu) at
its melting temperature of 1084 ºC (1357 K). Assume an energy for
vacancy formation of 0.90 eV/atom.
Given: Boltzmann's constant, (1.38 x 10-23 J/atom • K) or (8.62 x 10-5
eV/atom • K)
Answer: 4.55 x 10-4
𝑒𝑉
−0.90𝑎𝑡𝑜𝑚
𝑁𝑣 −𝑄𝑣 𝑒𝑉
(8.62×10−5 𝑎𝑡𝑜𝑚𝐾)(1357𝐾)
=𝑒 𝑘𝑇 =𝑒 = 4.55 × 10−4
𝑁
5
Topic 3 – Structure of Crystalline Solids &
Imperfection
3. Calculate the energy for vacancy formation in nickel (Ni), given that the
equilibrium number of vacancies at 850ºC (1123 K) is 4.7x1022 m-3.
The atomic weight and density (at 850ºC) for Ni are, respectively,
58.69 g/mol and 8.80 g/cm3.
Given:
Boltzmann's constant, (1.38 x 10-23 J/atom • K) or
(8.62 x 10-5 eV/atom • K)
Avogadro’s number, 6.02 x 1023 atoms / mol
Answer: 1.40 eV
6
Topic 3 – Structure of Crystalline Solids &
Imperfection
𝑁𝑣 −𝑄𝑣
= exp
𝑁 𝑘𝑇
4.7 × 1022 𝑚−3 −𝑄𝑣
= exp( )
9.026 × 1028 𝑎𝑡𝑜𝑚𝑠/𝑚3 (8.62 × 10−5 𝑒𝑉/𝑎𝑡𝑜𝑚)(1123𝐾)
−𝑄𝑣
ln(5.207 × 10−7 ) =
0.0968
−𝑄𝑣
−14.46 =
0.0968
𝑄𝑣 = 1.40𝑒𝑉
7
Topic 4 – Mechanical Properties of Materials
𝐶ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝐿𝑒𝑛𝑔𝑡ℎ
𝜎=( )𝐸
𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝐿𝑒𝑛𝑔𝑡ℎ
𝐶ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝐿𝑒𝑛𝑔𝑡ℎ
276 × 106 𝑃𝑎 = 110 × 109 𝑃𝑎
305𝑚𝑚
𝑆𝑡𝑟𝑒𝑠𝑠
𝐸=
𝑆𝑡𝑟𝑎𝑖𝑛
2500000000000𝑁
1015 𝑁/𝑚2 =
𝑆𝑡𝑟𝑎𝑖𝑛
𝑆𝑡𝑟𝑎𝑖𝑛 = 0.025
9
Topic 4 – Mechanical Properties of Materials
3. If a 5 m long steel wire extends by 2.5 mm, then the strain in it is:
a) 0.0005
b) 0.005
c) 0.0002 𝐶ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝐿𝑒𝑛𝑔𝑡ℎ
𝑆𝑡𝑟𝑎𝑖𝑛 =
d) 0.002 𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝐿𝑒𝑛𝑔𝑡ℎ
2.5 𝑚𝑚
𝑆𝑡𝑟𝑎𝑖𝑛 =
5𝑚
0.0025 𝑚
𝑆𝑡𝑟𝑎𝑖𝑛 =
5𝑚
𝑆𝑡𝑟𝑎𝑖𝑛 = 0.0005
10
Topic 4 – Mechanical Properties of Materials
𝐸
𝐾=
3(1 − 2𝑣)
300 𝐺𝑁/𝑚2
𝐾=
3(1 − 2(0))
𝐾 = 100 𝐺𝑁/𝑚2
11
Topic 4 – Mechanical Properties of Materials
12
Topic 4 – Mechanical Properties of Materials
𝐶ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝐿𝑒𝑛𝑔𝑡ℎ 𝐿𝑖
𝐸𝑛𝑔𝑖𝑛𝑒𝑒𝑟𝑖𝑛𝑔 𝑆𝑡𝑟𝑎𝑖𝑛 = 𝑇𝑟𝑢𝑒 𝑆𝑡𝑟𝑎𝑖𝑛 = ln
𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝐿𝑒𝑛𝑔𝑡ℎ 𝐿𝑜
2𝐿 − 𝐿
𝐸𝑛𝑔𝑖𝑛𝑒𝑒𝑟𝑖𝑛𝑔 𝑆𝑡𝑟𝑎𝑖𝑛 = 2𝐿
𝐿 𝑇𝑟𝑢𝑒 𝑆𝑡𝑟𝑎𝑖𝑛 = ln
𝐿
𝐿
𝐸𝑛𝑔𝑖𝑛𝑒𝑒𝑟𝑖𝑛𝑔 𝑆𝑡𝑟𝑎𝑖𝑛 = = 1 = 100% 𝑇𝑟𝑢𝑒 𝑆𝑡𝑟𝑎𝑖𝑛 = ln 2
𝐿
𝑇𝑟𝑢𝑒 𝑆𝑡𝑟𝑎𝑖𝑛 = 0.6931 = 69.31%
13
Topic 4 – Mechanical Properties of Materials
𝐹𝑜𝑟𝑐𝑒 45 𝑘𝑁 45 000𝑁
𝐸𝑛𝑔𝑖𝑛𝑒𝑒𝑟𝑖𝑛𝑔 𝑆𝑡𝑟𝑒𝑠𝑠 = = 2 = 2
𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝐴𝑟𝑒𝑎 6𝑚𝑚 0.006𝑚
𝜋 2 𝜋 2
= 159 𝑀𝑃𝑎
14
Topic 4 – Mechanical Properties of Materials
𝐶ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝐿𝑒𝑛𝑔𝑡ℎ 𝐿𝑖
𝐸𝑛𝑔𝑖𝑛𝑒𝑒𝑟𝑖𝑛𝑔 𝑆𝑡𝑟𝑎𝑖𝑛 = 𝑇𝑟𝑢𝑒 𝑆𝑡𝑟𝑎𝑖𝑛 = ln
𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝐿𝑒𝑛𝑔𝑡ℎ 𝐿𝑜
0.5𝐿 − 𝐿
𝐸𝑛𝑔𝑖𝑛𝑒𝑒𝑟𝑖𝑛𝑔 𝑆𝑡𝑟𝑎𝑖𝑛 = 0.5𝐿
𝐿 𝑇𝑟𝑢𝑒 𝑆𝑡𝑟𝑎𝑖𝑛 = ln
𝐿
−0.5𝐿
𝐸𝑛𝑔𝑖𝑛𝑒𝑒𝑟𝑖𝑛𝑔 𝑆𝑡𝑟𝑎𝑖𝑛 = = −0.5 𝑇𝑟𝑢𝑒 𝑆𝑡𝑟𝑎𝑖𝑛 = ln 0.5
𝐿
𝑇𝑟𝑢𝑒 𝑆𝑡𝑟𝑎𝑖𝑛 = −0.69
15
Topic 4 – Mechanical Properties of Materials
16
Topic 4 – Mechanical Properties of Materials
9. ∆𝑑 −2.5 × 10−3 𝑚𝑚
𝜖𝑙𝑎𝑡𝑒𝑟𝑎𝑙 = = = −2.5 × 10−4
𝑑𝑜 10𝑚𝑚
𝜖𝑙𝑎𝑡𝑒𝑟𝑎𝑙
𝑃𝑜𝑖𝑠𝑠𝑜𝑛′ 𝑠 𝑅𝑎𝑡𝑖𝑜𝑛, 𝜈 =
𝜖𝑙𝑜𝑛𝑔𝑖𝑡𝑢𝑑𝑖𝑛𝑎𝑙
−2.5 × 10−4
0.34 =
𝜖𝑙𝑜𝑛𝑔𝑖𝑡𝑢𝑑𝑖𝑛𝑎𝑙
𝜖𝑙𝑜𝑛𝑔𝑖𝑡𝑢𝑑𝑖𝑛𝑎𝑙 = 7.35 × 10−4
𝜎 = 𝜖𝐸
𝜎 = 7.35 × 10−4 97𝐺𝑃𝑎 = 71.3𝑀𝑃𝑎
𝐹
𝜎=
𝐴
𝐹
71.3𝑀𝑃𝑎 = 𝐹 = 5600𝑁
10 × 10−3 𝑚 2
𝜋( )
2
17
Topic 4 – Mechanical Properties of Materials
18
Topic 4 – Mechanical Properties of Materials
10.
12.8𝑚𝑚 2 10.7𝑚𝑚 2
𝜋 − 𝜋
%𝑅𝐴 = 2 2 × 100 = 30%
12.8𝑚𝑚 2
𝜋 2
106 𝑁 1𝑚2
𝐹 = 𝜎𝑓 𝐴𝑜 = 460 × 128.7𝑚𝑚2 = 59,200𝑁
𝑚2 106 𝑚𝑚2
𝐹 59,200𝑁
𝜎𝑓 = = = 660𝑀𝑃𝑎
𝐴𝑓 1𝑚2
128.7𝑚𝑚2
106 𝑚𝑚2
19
Topic 5 – Dislocation and Strengthening
Mechanism
20
Topic 5 – Dislocation and Strengthening
Mechanism
21
Topic 6 – Polymer Structure and Ceramics
𝑀𝑛 21,150 𝑔/𝑚𝑜𝑙
𝐷𝑃 = = = 338
𝑚 62.50 𝑔/𝑚𝑜𝑙
23
Topic 6 – Polymer Structure and Ceramics
24
Topic 6 – Polymer Structure and Ceramics
25
Topic 6 – Polymer Structure and Ceramics
2.
Molecular Weight Mean Mi
xi xiMi wi wiMi
Range (g/mol) (g/mol)
10000 - 20000 15000 0.03 450 0.01 150
20000 - 30000 25000 0.09 2250 0.04 1000
30000 - 40000 35000 0.15 5250 0.11 3850
40000 - 50000 45000 0.25 11250 0.23 10350 Repeating unit of PVC
50000 - 60000 55000 0.22 12100 0.24 13200
60000 - 70000 65000 0.14 9100 0.18 11700
70000 - 80000 75000 0.08 6000 0.12 9000
80000 - 90000 85000 0.04 3400 0.07 5950
Average Average
49800 55200
Mn Mw
m = 2 (12.01 g/mol) + 4 (19 g/mol) = 100.02 g/mol
𝑀𝑛 49,800 𝑔/𝑚𝑜𝑙
𝐷𝑃 = = = 498
𝑚 100.02 𝑔/𝑚𝑜𝑙
26