Question 1: Choose the wrong statement: Cl – O bonding in ion series ClO -, ClO2-, ClO3-, ClO4- are

1.7, 1.64, 1.57 and 1.42 A0 respectively. This series is:

a) Increased of stability.
b) Increased of bonding energy.
c) Decreased of bond order.
d) Increased of bond order.
Question 2: Which statement is incorrect about ionic compounds?
a) Having high melting point.
b) Splitting to form ions when dissolving in water.
c) Being conductive in crystal phase.
d) Being conductive in liquid (melting) phase.
Question 3: Arrange following compounds VCl2, VCl3, VCl4 and VCl5 in the increasing order of
covalence bonding:
a) VCl3 < VCl4 < VCl2 < VCl5 b) VCl5 < VCl4 < VCl3 < VCl2
c) VCl2 < VCl3 < VCl4 < VCl5 d) VCl4 < VCl2 < VCl3 < VCl5
Question 4: Among below gases, the most difficult to evaporate is
a) H2O b) CO2 c) H2S d) HF
Question 5: Please calculate the equilibrium constant of below reaction:
2NaH2PO4(dd) + 3Ca(CH3COO)2(dd) Ca3(PO4)2(r) + 2NaCH3COO(dd) + 4CH3COOH(dd)
a) 1.10-9,51 b) 1.109,51 c) 1.109,98 d) 1.10-9,98
Knew pP of Ca3(PO4)2 is 29 (P is product solubility), pK 2 and pK3 of H3PO4 are 7,21 and 12,28.
pKa of CH3COOH is 4.75, Kw of water is 10-14.
Question 6 Based on the Bronsted-Lowry acid-base theory, what are the wrong statements?
1. The strength of acids and bases can only be determined in liquid state using acid-base
constants.
2. The strength of an acid is also depended on solvents. Stronger basic solvent is, stronger acid
substances would be.
3. The strength of the acid series HF, HCl, HBr, HI is decreased, respectively.
a.1, 2 b.1,3. c. 2,3 d. 1, 2, 3.
Question 7: According to Bronsted-Lawry’s theory, the conjugate acid – base pairs in water
solution are:
a. CH3COOH2+/CH3COOH, H2SO4/HSO4-, H2ClO4+/ClO4-, HCl/Cl-.
b. CH3COOH/CH3COO-, H3SO4+/SO4-2, HClO4/ClO4-, H2O/OH-.
c. CH3COOH2+/CH3COO-; H3SO4+/H2SO4; HClO4/ClO4-, [Al(H2O)6]3+/[Al(H2O)5OH]2+.
d. All are incorrect.
Question 8: Choose the correct answers (with solvent is water)
1. CH3NH2, CO32-, CH3COO-, Cl- are bases according to Bronsted-Lawry’s theory.
2. The strength of acids BF3, BCl3, BBr3 is decreased.
3. HCN, H3O+, Na+, C6H5OH, N2H5+ are acids according to Bronsted-Lawry’s theory.
4. The base strength is increased in series: anilin<3,5 dinitroanilin<2,6 dinitroanilin

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 5. pKa of an acid higher leads to weaker of its conjugated base.
a) 1,2,3,5 b) 1,5 c) 2,3,4 d) 3,5
Question 9: There are cations: (1) NH4+, (2) CH3NH3+, (3) (CH3)2NH2+, (4) CH3COOH2+.
Please arrange them in series of increasing the strength of acid:
a) (4) < (3) < (1) < (2) b) (3) < (4) < (1) < (2)
c) (4) < (3) < (2) < (1) d) No result above is correct
Question 10: There is the reaction: NH2-(k) + HBr(k) = NH3(k) + Br-(k)
Q ( KJ/ mol) 1689 1354
Choose the wrong statements:
1. Br- is stronger base than NH2- because of lower of Q value.
2. NH2- is stronger base than Br- because of higher of Q value.
3. When NH2- react with H+ will has ∆H higher than that of Br-
4. Conjugated acid of NH2- is weaker acid than that of Br-
a) 1,3 b) 2,3 c) 2,3,4 d) 2,4
Question 11: Choose the correct statement: What substances impulse the hydrolysis of NaNO3 in
water?
a. HCl, H2SO4 , KCl. b. NaOH, Ba(OH)2, NaCl.
c. NH4NO3, CH3COONa, HNO3. c. There is no.
Question 12: What are amphoteric substances base on Bronsted-Lawry’s theory:
a. HS- ,Ag+aq ,Fe2+aq , H2O, HCl, NH3
b. HS-, H2O, HCl, SO42-
c. HS-, H2O, HCl, HCO3-
d. F- , S2-, HS-, H2O, HCl, NH3
Question 13: There is difference from liquid and amorphous state in term of:
a) Structure b) Shape c) Isotropic d) a and b
Question 14: Which compounds have molecule lattice structures among below substances (in solid
state): COCl2, NO, NaNO3, BaO.
a) COCl2, NO b) COCl2, NO, NaNO3
c) COCl2 , BaO d) NO, NaNO3
Question 15: Which compounds have ion lattice structures among below substances (in solid
state): K3[Fe(CN)6], Fe(CO)5 , KCl, BaO, VCl5.
a) K3[Fe(CN)6], Fe(CO)5 b) KCl, BaO, VCl5.
c) VCl5, BaO, K3[Fe(CN)6] d) BaO, K3[Fe(CN)6], KCl.
Question 16: Which is strongest acid among these acids below?
a) HClO b) HBrO c) HIO d) HAtO
Question 17: Which substance has highest valence bonding among below substances?
a) Co(OH)3 b) FeCl3 c) C3H8 d) NiSO4
Question 18: Choose the right statement:
a.In Pauling’s rule for acids HaXOn(OH)m , value of m decides strenght of acid.

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 b. Base on Kartletch’s rule, the rate of q/r of center ion higher leads to weaker acidic of a
substance.
c. Cations that have pKtp lower then their acidic also weaker.
d. Alls are wrong.
Question 19: Choose the correct answer: Compare the strength of below bases:
1) F-> Cl- 2) O2-> OH- 3) Cl-> S2-
4) NH3> NF3 5) OH-> H2O 6) PH3> (CH3)3P
a. 1,2,4,5 b. 3,6 c. 1,2,3,5 d. 4,6
Question 20: Which oxides among below substaneces are easy reacted with water: PbO, SO 3, BaO,
CO2
a) BaO b) SO3, BaO
c) SO3, CO2 d) PbO, SO3, BaO
Question 21: In octahedral complex compounds, if numbers of electrons are higher than 3 and
lower than 8, then:
a) If ∆ > P is low spin complex compound. b) If ∆ > P is high spin complex compound.
c) If ∆ < P is high spin complex compound. d) Both a and c are correct
Question 22: Base on Latimer series of Chlorine in acid solution below:

1,201 1,181 1,701 1,630 1,358

ClO4- ClO3- HClO2 HClO Cl2 Cl-
Standard Redox Potential of ClO3-/ Cl2 is:
a) 1,83475 b) 1,4678 c) 1,5395 d) 1,898
Question 23: What electron configurations below can have both low and high spin structures:
1) d5 2) d7 3) d6 4) d8 5) d10
a) 1, 2, 3 b) 2, 3, 4 c) 1, 2, 5 d) 1, 2, 3, 4, 5
Question 24: In below reactions:
TiO2+ + 2H+ + e =Ti3+ + H2O, 0 = 0.1V; ZrO2+ + 2H+ + 4e = Zr +H2O, 0 = -1.5V
HfO2+ + 2H+ + 4e = Hf + H2O, 0 = -1.7V
Plsease choose correct answer for stable series of Ti(+4);Zr(+4); Hf(+4):
a) Ti <Hf < Zr b) Ti < Zr < Hf c) Zr < Ti < Hf d) Hf < Zr < Ti
Question 25: Please determine magnetic property and lattice stable energy of complex ion
hexaaquamaganat (II). Knew O= 101 kJ/mol and P = 304,2 kJ/mol.
a) Diamagnetic, 304,2 kJ/mol. b) Paramagnetic, 0 kJ/mol.
c) Paramagnetic, 304,2 kJ/mol. c) Diamagnetic, 0 kJ/mol.
Question 26: Please compare lattice stable energy of 2 complex ion: [MnCl 6]2+ (E1) and [FeCl6]3+
(E2)
a) Can not compare because we don’t know ∆, P b) E1=E2=0
c) E1<0<E2 d) E2>E1>0
Question 27: Choose the correct answer:
With the same ligand, which tetrahedral complex compound of Fe2+, Co2+, Ni2+ is the most stable:
a) Fe2+ b) Co2+ c) Ni2+ d) The same stability.

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Question 28: The lattice stable energy of complex ion [HgI4]2- (Hg has Z=80) and its color:
a) E = 0, orange b) E = -2∆T, colorless
c) E = 0, colorless d) E = -2∆T, blue.
Question 29: In acid environment, please arrange in series of stability of these compounds:
HClO4, HBrO4, HAtO4
a) HClO4 > HBrO4 > HAtO4 b) HAtO4 > HBrO4 > HClO4
c) HBrO4 < HAtO4 < HClO4 d) HBrO4 > HClO4 > HAtO4
Question 30: The Latimer’s diagram of Co at pH=1
2+ ¿−0.277 Co¿
3+¿1.92 C o →
¿
Co O2 1.416 C o →

What compound(s) of Cobalt cannot be stable in solution at pH = 1?

a)CoO2 b) Co3+ c) Co2+ d) Co3+ & Co2+
Question 31: Use the same Latimer’s diagram of Co at pH=1, choose the correct statement/s:
1) Oxidation property of compounds/ions of cobalt is increased from the left to the right.
2) Co3+ can be disproportionated to form CoO2 and Co2+
3) Co2+ is stable in acidic solution.
4) The reduction potential values will be decreased when pH is increased.
a) 1,2,3,4 b) 2,3,4 c) 2,3 d) 1,4
Question 32: Choose the wrong statement:
a) In tetrahedral complex compounds orbital dxy, dyz, dxz have higher energy than that of dx2-
y2 and d z2. In octahedral complex compounds orbital dx2-y2 & dz2 have higher energy than that of dxy,
dyz, dxz.
b) Complex compounds that have no π bonding if they have higher Δ lead to low spin
complex compound and more stable.
c) Complex compounds that are π donor lead to decreasing of Δ and have low spin value
and more unstable.
d) Crystal Field Theory can explain why complex compounds of d and f elements have
many case of color.
Question 33: Knew standard reduction potential of the semi-reaction Fe3+(aq) + e− → Fe2+(aq) is
+0,77V. Please determine changing of its potential when CN- is added into solution, where stable
constant of Fe(CN)63- is 1031 and Fe(CN)64- is 1024.
a. Increase b. No change c. Decrease d. Cannot determine.
Question 34: The complex ion hexacyanidoferate(III) (CN- is strong field ligand) has:
a) Octahedral structure, paramagnetic, low spin b) Formula is [Fe(CN)6]3-
c) Lattice stable energy is E= -2+2P d) Alls are correct.
Question 35: Knew:
Au3+ + 3e  Au φ = 1,50 V
Where overall unstable constant of [AuCl4-] is Kus = 2.10-21,3
Please calculate the standard reduction potential at 250C of below semi-reaction :
AuCl4- + 3e  Au + 4Cl-
a) 0.98 V b) 1.08 V c) 1.2 V d) 1.15 V
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Question 36: Which main compound will be obtained when S is burned in oxygen?
a) SO b) SO2 c) SO3 d) S2O3
Question 37: What are stable oxidation numbers of sulfur among below values:
1) -2 2) +2 3) +6 4) +4
a) 3 b) 3 & 4 c) 1 , 3 & 4 d) 2 & 3
Question 38: Sulfurous gas will has reduction property in which below reaction(s)?
1) SO2 + H2O  2) SO2 + H2S + H2O 
3) SO2 + H2O2 + H2O  4) SO2 + Cl2 + H2O 
a) 3 & 4 b) 2 , 3 & 4 c) 1 & 3 d) 2 & 4
Question 39: Choose the correct answers:
1) Specific property of cid sulfurous is oxidation.
2) Hydro sulfide gas is stable in atmospheric.
3) Acid sulfuric 2M solution has strong acidic.
4) Trioxide Sulfur gas (Sulfur (VI) oxide) can not be destroyed below 10000C.
a) 4 b) 2 c) 3 d) Alls are wrong.
Question 40: The solution of potasium permanganate (in acid solution) will become colorless in
what below substances?
1) FeSO4 2)H2O2 3) (NH4)2SO4 4) CO2
a) 1 b) 1 & 3 c) 1 & 2 d) 1 & 4
Question 41: Oxidation property of Ag+ will be increased if what substance below is added in its
solution:
1/ NH3 2/ CN- 3/ HCl 4/ H2SO4
a. 1,2 b. 2,3 c. 3,4 d. There is no.
Use below Frost’s diagram for questions from 42 to 45 ( pH=14):
4
A
3 3.12
B
2.37
2 C
1.78

1
D
Cl2 0.42
0 0
-2 -1 0 1 2 3 4 5 6 7 8

-1
E -1.36

-2

Question 42: Base on this diagram, the unstable compounds are:

a)Cl2, A, C b)Cl2, D, B c)E, B, D d)A, C, E

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Question 43: Complete the positions from A to E:
A  B  C  D  Cl2  E ( pH  14)
   
a. (A) ClO4 , ( B) ClO3 , (C ) ClO2 , ( D) HClO, ( E ) Cl
 
b. (A) HClO4 , ( B) HClO3 , (C ) HClO2 , ( D) ClO , ( E ) Cl
    
c. (A) ClO4 , ( B)ClO3 , (C ) ClO2 , ( D) ClO , ( E ) Cl
d. Can’t complete.
Question 44: Calculate the reduction potential at positions 1,2,3,4,5:
A 
(1)
 B 
(2)
 C 
(3)
 D 
(4)
 Cl2 
(5)
 E ( pH  14)
a. (1) 0.374 V, (2) -0.481V, (3) 1.071V, (4) 0.295, (5) -1.358V
b. (1) 0.374, (2) 0.295V, (3) 0.681V, (4) 0.421, (5) 1.358V
c. (1) 0.295 V, (2) 0.295V, (3) 0.890, (4) 0.295, (5) 1.358V
d. (1) 0.374 V, (2) 0.295V, (3) 0.421V, (4) 0.295, (5) -1.358V
Question 45: What product can be collected when KClO4 reacted with a reduction substance in pH
= 14 aqueous solution:
a) HClO3, Cl-, HClO b) ClO3-, Cl-, HClO
c) ClO3-, Cl-, ClO- d) Can’t determine.