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Ch5.3 (16 Marks) : 1. (1 Mark)

This document contains a chemistry test with 16 multiple choice questions related to bond enthalpies and reaction enthalpies. The questions assess understanding of concepts such as: - Bond enthalpy values for H-H, N-H, C=N and other bonds - Using bond enthalpy data to calculate enthalpy changes of reactions - Identifying exothermic and endothermic reactions from potential energy diagrams - Determining if reactants or products are more stable based on sign of enthalpy change

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74 views6 pages

Ch5.3 (16 Marks) : 1. (1 Mark)

This document contains a chemistry test with 16 multiple choice questions related to bond enthalpies and reaction enthalpies. The questions assess understanding of concepts such as: - Bond enthalpy values for H-H, N-H, C=N and other bonds - Using bond enthalpy data to calculate enthalpy changes of reactions - Identifying exothermic and endothermic reactions from potential energy diagrams - Determining if reactants or products are more stable based on sign of enthalpy change

Uploaded by

The LegendaryCarrotMaster
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Ch5.

3 [16 marks]
1. [1 mark]
What is the H−H bond enthalpy, in kJ mol−1 , in the H 2 molecule?
2 H 2 ( g ) +O2 ( g ) → 2 H 2 O ( g )

H f ( H 2 O )=xkJ mol−1

A.  x− y + 4 z
1
B.   ( x− y +4 z )
2
C.  x− y +2 z
1
D.   ( x− y +2 z )
2
2. [1 mark]
Which equation represents the N–H bond enthalpy in NH3?
A.  NH3 (g) → N (g) + 3H (g)
1 1
B.   NH3 (g) → N (g) + H (g)
3 3

1 3
C.  NH3 (g) → N2 (g) + H2 (g)
2 2

D.  NH3 (g) → •NH2 (g) + •H (g)


3. [1 mark]
Which is correct for the reaction?
2Al (s) + 6HCl (aq) → 2AlCl3 (aq) + 3H2 (g)         ΔH = −1049 kJ
A. Reactants are less stable than products and the reaction is endothermic.
B. Reactants are more stable than products and the reaction is endothermic.
C. Reactants are more stable than products and the reaction is exothermic.
D. Reactants are less stable than products and the reaction is exothermic.

4. [1 mark]
Methane undergoes incomplete combustion.
2CH4 (g) + 3O2 (g) → 2CO (g) + 4H2O (g)
What is the enthalpy change, in kJ, using the bond enthalpy data given below?

 
A. [2(1077) + 4(463)] − [2(414) + 3(498)]
B. [2(414) + 3(498)] − [2(1077) + 4(463)]
C. [8(414) + 3(498)] − [2(1077) + 8(463)]
D. [2(1077) + 8(463)] − [8(414) + 3(498)]
5. [1 mark]
Consider the following reaction:
N2 (g) + 3H2 (g) ⇌ 2NH3 (g)

    
Which calculation gives ΔHΘ, in kJ, for the forward reaction?
A.   2z − y − 3x
B.   y + 3x − 2z
C.   y + 3x − 6z
D.   6z − y − 3x
 
6. [1 mark]
Which statement is correct?
A.     In an exothermic reaction, the products have more energy than the reactants.
B.     In an exothermic reversible reaction, the activation energy of the forward reaction is
greater than that of the reverse reaction.
C.     In an endothermic reaction, the products are more stable than the reactants.
D.     In an endothermic reversible reaction, the activation energy of the forward reaction is
greater than that of the reverse reaction.
7. [1 mark]
Which describes the reaction shown in the potential energy profile?

A.     The reaction is endothermic and the products have greater enthalpy than the
reactants.
B.     The reaction is endothermic and the reactants have greater enthalpy than the
products.
C.     The reaction is exothermic and the products have greater enthalpy than the reactants.
D.     The reaction is exothermic and the reactants have greater enthalpy than the products.

8. [1 mark]
What is the enthalpy change, in kJ, of the following reaction?
3H2 (g) + N2 (g) ⇌ 2NH3 (g)

A. (6 × 391) − [(3 × 436) + 945]


B. (3 × 391) − (436 + 945)
C. −[(3 × 436) + 945] + (3 × 391)
D. −(6 × 391) + [(3 × 436) + 945]
9. [1 mark]
In which order does the oxygen–oxygen bond enthalpy increase?
A.     H2O2 < O2 < O3
B.     H2O2 < O3 < O2
C.     O2 < O3 < H2O2
D.     O3 < H2O2 < O2
10. [1 mark]
What can be deduced from this reaction profile?
A.     The reactants are less stable than the products and the reaction is exothermic.
B.     The reactants are less stable than the products and the reaction is endothermic.
C.     The reactants are more stable than the products and the reaction is exothermic.
D.     The reactants are more stable than the products and the reaction is endothermic.
11. [1 mark]
What can be deduced from the facts that ozone absorbs UV radiation in the region of 340
nm and molecular oxygen in the region of 242 nm?
A.     The bond between atoms in molecular oxygen is a double bond.
B.     The bonds in ozone are delocalized.
C.     The bonds between atoms in ozone are stronger than those in molecular oxygen.
D.     The bonds between atoms in molecular oxygen need more energy to break.
12. [1 mark]
The C=N bond has a bond length of 130 pm and an average bond enthalpy of 615kJmol -1.
Which values would be most likely for the C-N bond?
13. [1 mark]
In which reaction do the reactants have a lower potential energy than the products? 
A. CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)
B. HBr(g) → H(g) + Br(g) 
C. Na+(g) + Cl-(g) → NaCl(s) 
D. NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)
14. [1 mark]
Which equation represents the average bond enthalpy of the Si−H bond in SiH 4?
 
A.  SiH4(g)→SiH3(g)+H(g)
1 1
B.   SiH4 (g) →  Si(g) + H(g)
4 4
1
C.  SiH4(g) → SiH3(g) + H2(g)
2
D.  SiH4 (g) → Si(g) + 4H(g)
15. [1 mark]
Which equation corresponds to the bond enthalpy of the H–I bond?
1 1
A.     HI ( g)→ H 2 ( g)+ I 2 ( g)
2 2
1 1
B.     HI ( g) → H 2 (g)+ I 2 (s)
2 2
−¿(g) ¿

C.     HI ( g) → H +¿(g )+ I ¿

D.     HI ( g) → H ( g)+ I (g)
16. [1 mark]
Which enthalpy changes can be calculated using only bond enthalpy data?
I.     N 2 (g)+3 H 2(g)→2 N H 3 (g)

II.     C 2 H 5 OH (l)+ 3O 2 ( g) →2 C O 2 (g)+ 3 H 2 O( g)

III.     C H 4 ( g)+C l 2(g)→C H 3 Cl (g)+ HCl( g)


A.     I and II only
B.     I and III only
C.     II and III only
D.     I, II and III

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