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ChE 122 LE1 Notes

This document summarizes equations for closed and open systems involving work, properties of substances like gases and liquids, and various thermodynamic processes. Key equations given are for work done in expansion/contraction and shaft work, properties as functions of temperature and pressure, and equations of state for ideal gases and polytropic processes. The summary also outlines the application of these equations according to the type of system, substance, and process, such as reversible processes in closed systems involving ideal gases.

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52 views

ChE 122 LE1 Notes

This document summarizes equations for closed and open systems involving work, properties of substances like gases and liquids, and various thermodynamic processes. Key equations given are for work done in expansion/contraction and shaft work, properties as functions of temperature and pressure, and equations of state for ideal gases and polytropic processes. The summary also outlines the application of these equations according to the type of system, substance, and process, such as reversible processes in closed systems involving ideal gases.

Uploaded by

googley71
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SUMMARY OF EQUATIONS

Closed system: Per mole n of a substance:


( ) Expansion or contraction work:
Stationary, closed system:
Mechanical reversibility:
( )

Work may be: Adiabatic:


(1) expansion or contraction work ( ), and/or
(2) shaft work Properties:

Per mole n of a substance: ( ) ( )

For liquids or gases:


Stationary, open system:
( ) ( )
( ̇)
( ) ( ) ( )
*( ) ̇+ ̇ ̇

Work may be:


(1) expansion or contraction work ( ̇ ), and/or Ideal gas:
(2) shaft work ( ̇ )

At steady-state:
( ̇) For any process:

( )
*( ) ̇+ ̇ ̇
Mechanically reversible process in a closed system:
Work is in the form of shaft work only

Flow rates: Adiabatic, reversible process:


̇
̇ ̇ ( ) ;
( ) ( ) ( )

Polytropic process:
APPLICATION OF EQUATIONS according to:
1. Type of system: open/closed
2. Substance: any substance/ideal gas
3. Process: general process/mechanically reversible process

Closed system:
( )

Stationary, closed system:

( )

Material: any substance Material: ideal gas

Per mole n of a substance: Per mole n of a substance:

{ {

Processes Processes
Constant volume: Any process
Or if :
∫

Constant pressure:
Or if :
∫ Constant temperature:
Or if :

Adiabatic: Adiabatic:

For constant heat capacities:


( ) ( )
Polytropic:

Mechanically reversible processes Mechanically reversible processes


( ) ( )
( ) ( ) ( )

Constant volume, mechanically reversible: Constant volume, mechanically reversible:

Constant pressure, mechanically reversible: Constant pressure, mechanically reversible

Constant temperature, mechanically reversible:

Adiabatic, mechanically reversible Adiabatic, mechanically reversible:

For constant heat capacities

( ) ( ) ( )

( ) ( )

Polytropic, mechanically reversible:

( ) ( )
*( ) + *( ) +
( )
Stationary, open system:
( ̇)
( )
*( ) ̇+ ̇ ̇

̇ {
̇

At steady-state:
( ̇)
( )
*( ) ̇+ ̇ ̇

Flow rates:
̇
̇ ̇ ( )

For ideal gases:

( ) ( ) ( )

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