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Safety Data Sheet: 1. Product & Company Identification BMW Antifreeze/Coolant (Afc)

This document is a safety data sheet for BMW Antifreeze/Coolant that contains ethylene glycol (60-100%), diethylene glycol (7-13%), ethylhexylic acid (5-10%), sodium hydroxide (5-10%). It lists the product identification, hazards, composition, and first aid measures. The product is harmful if swallowed and suspected of damaging fertility or the unborn child. First aid measures include not inducing vomiting if ingested, flushing eyes with water if in eyes, and removing contaminated clothing and washing skin if on skin.

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0% found this document useful (0 votes)
761 views6 pages

Safety Data Sheet: 1. Product & Company Identification BMW Antifreeze/Coolant (Afc)

This document is a safety data sheet for BMW Antifreeze/Coolant that contains ethylene glycol (60-100%), diethylene glycol (7-13%), ethylhexylic acid (5-10%), sodium hydroxide (5-10%). It lists the product identification, hazards, composition, and first aid measures. The product is harmful if swallowed and suspected of damaging fertility or the unborn child. First aid measures include not inducing vomiting if ingested, flushing eyes with water if in eyes, and removing contaminated clothing and washing skin if on skin.

Uploaded by

Orshanetz
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 6

Page 1 of 6

SAFETY DATA SHEET WP-126


Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 2.0 SDS Revision Date: 12/31/2013

1. PRODUCT & COMPANY IDENTIFICATION


1.1 Product Name:
BMW ANTIFREEZE/COOLANT (AFC)
1.2 Chemical Name: Ethylene Glycol Mixture
1.3 Synonyms: Ethanediol
1.4 Trade Names: BMW Antifreeze/Coolant (AFC)
1.5 Product Use: Engine Coolant
1.6 Distributor’s Name: Worldpac, Inc.
1.7 Distributor’s Address: 37137 Hickory Street, Newark, CA 94560 USA
1.8 Emergency Phone:
INFOTRAC: +1 (800) 535-5053 / +1 (352) 323-3500 (CONTRACT 84261)
1.9 Business Phone / Fax: +1 (510) 608-5525 / +1 (510) 742-9262

2. HAZARDS IDENTIFICATION
2.1 Hazard Identification: This product is classified as a hazardous substance but not as dangerous goods according to
the classification criteria of [NOHSC: 1088 (2004)] and ADG Code (Australia).
WARNING! HARMFUL IF SWALLOWED. SUSPECTED OF DAMAGING FERTILITY OR
THE UNBORN CHILD.
Hazard Statements (H): H302 – Harmful if swallowed. H361d – Suspected of damaging fertility
or the unborn child.
Precautionary Statements (P): P201 – Obtain special instructions before use. P202 – Do not
handle until all safety precautions have been read and understood. P264 – Wash hands and
exposed skin areas with soap and warm water thoroughly after handling. P270 – Do not eat,
drink or smoke when using this product. P280 – Wear protective gloves/eye protection. P281 –
Use personal protective equipment as required. P301+P312 – IF SWALLOWED: Call a
POISON CENTER or doctor/physician if you feel unwell. P330 – Rinse mouth.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. P308+P313 – IF exposed or
concerned: Get medical advice/attention. P405 – Store locked up. P501 - Dispose of
contents/container to licenses treatment, storage and disposal facility (TSDF).
2.2 Effects of Exposure: Eyes: This product can cause transient mild eye irritation with short-term contact with liquid sprays or
mists.
Skin: May cause mild skin irritation. Although rare, skin contact with ethylene glycol may cause an
allergic skin reaction (e.g., delayed skin rash which may be followed by blistering, scaling and
other skin effects). Passage through the skin may add to toxic effects from breathing or
swallowing.
Ingestion: If small amounts swallowed, no significant adverse health effects are anticipated. However,
ingestion of large amounts may cause serious damage to the target organs or death.
Inhalation: Breathing of vapor or mist is possible and may cause respiratory tract irritation. Possible adverse
effects on the nervous system and blood-forming system. Aspiration of liquid into the lungs can
cause severe lung damage or death.
2.3 Symptoms of Overexposure: Eyes: Stinging or burning sensation, Irritation, redness, and watering.
Skin: Possible irritation, defatting, or dermatitis (rash), characterized by dry, scaling, red, itching skin.
Ingestion: Laxative effects. Gastrointestinal discomfort, nausea, vomiting and headache.
Inhalation: Upper respiratory irritation, coughing, sneezing, staggering gait, giddiness, drowsiness, slurred
speech, involuntary eye movement, kidney damage, weakness, fatigue, nausea, and possible
nervous system depression. Overexposure to sprays or mists may cause chemical pneumonitis.
2.4 Acute Health Effects: Moderate irritation to eyes. Possible irritation to skin near affected areas or dermatitis (rash). Upper respiratory
irritation, possible nervous system depression. Harmful or fatal is swallowed.
2.5 Chronic Health Effects: Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying, cracking,
(dermatitis). Repeated or prolonged exposure to this material (or its components) has been suggested as a cause of
the following effects in laboratory animals, and may aggravate pre-existing disorders of the organs in humans:
kidneys, liver. May cause central nervous system effects, liver abnormalities, kidney damage or liver damage.
2.6 Target Organs: Kidneys, liver, central nervous system.

NA = Not Available; ND = Not Determined; NE = Not Established; NF = Not Found; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: All WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2010 format.
Page 2 of 6
SAFETY DATA SHEET WP-126
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 2.0 SDS Revision Date: 12/31/2013

3. COMPOSITION & INGREDIENT INFORMATION


EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH NOHSC OSHA
ppm ppm ppm
ES- ES- ES-
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. % TLV STEL TWA STEL PEAK PEL STEL IDLH OTHER
107-21-1 KW2975000 203-473-3 60-100 (100) NA NF NF NF (50) NA NA
ETHYLENE GLYCOL
Acute Tox. 4 *; H302
111-46-6 NA 203-872-2 7-13 NA NA NF NF NF NA NA NA
DIETHYLENE GLYCOL
Acute Tox. 4; H302
149-57-5 NA 205-743-6 5-10 (5) NA NF NF NF NA NA NA
ETHYLHEXANOIC ACID
Acute Tox. (Dermal) 4; Acute Tox. (Oral) 5; Serious Eye. Dam. 1; Repr. 2; H303, H312, H318, H361d
1310-73-2 WB4900000 215-185-5 5-10 (2) NA NF NF NF (2) NA (10)
SODIUM HYDROXIDE
Skin Corr. 1A; H314

4. FIRST AID MEASURES


4.1 First Aid: Ingestion: Do NOT induce vomiting. Contact Infotrac +1 (800) 535-5053 or the nearest Poison Control Center
or local emergency telephone number for assistance and instructions. Seek immediate medical
attention. If vomiting occurs spontaneously, keep victim’s head lowered (forward) to reduce the risk
of aspiration.
Eyes: If product gets in the eyes, flush eyes thoroughly with copious amounts of water for at least 15
minutes, holding eyelid(s) open to ensure complete flushing. If the eyes or face become swollen
during or following use, consult a physician or emergency room immediately.
Skin: Remove contaminated clothing and wash affected areas with soap and water. If discomfort persists
and/or the skin reaction worsens, contact a physician immediately. Do not wear contaminated
clothing until after it has been properly cleaned.
Inhalation: Remove victim to fresh air at once. Under extreme conditions, if breathing stops, perform artificial
respiration. Seek immediate medical attention.
4.2 Medical Conditions Aggravated by Persons with pre-existing central nervous system (CNS) HEALTH
Exposure:
1
disease, neurological conditions, skin disorders, chronic
respiratory diseases, or impaired liver or kidney function should
FLAMMABILITY 0
avoid exposure. PHYSICAL HAZARDS 0
PROTECTIVE EQUIPMENT B
EYES SKIN

5. FIREFIGHTING MEASURES
5.1 Fire & Explosion Hazards: If involved in a fire, this product may decompose at high temperatures to form toxic gases
(e.g., CO, CO2, and NOx), smoke, hydrocarbons and their derivatives.
5.2 Extinguishing Methods: Water, Foam, CO2, Dry Chemical, low velocity water fog, Halon (if permitted),
5.3 Firefighting Procedures: As with any fire, firefighters should wear appropriate protective equipment including a
MSHA/NIOSH approved or equivalent self-contained breathing apparatus (SCBA) and
protective clothing. Treat as hot oil. Hazardous decomposition products may be released.
Thermal degradation may produce oxides of carbon, and/or nitrogen, hydrocarbons and/or
derivatives. Fire should be fought from a safe distance. Keep containers cool until well after
the fire is out. Use water spray to cool fire-exposed surfaces and to protect personal. Fight
fire upwind. Prevent runoff from fire control or dilution from entering sewers, drains, drinking
water supply, or any natural waterway.

6. ACCIDENTAL RELEASE MEASURES


6.1 Spills: Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective
Equipment (PPE). Use safety glasses or safety goggles and face shield; use gloves and other protective clothing
(e.g., apron, boots, etc.) to prevent skin contact.
Small Spills: Wear appropriate protective equipment including gloves and protective eyewear. Use a non-
combustible, inert material such as vermiculite or sand to soak up the product and place into a container for later
disposal.
Large Spills: Keep incompatible materials (e.g., oxidizers, strong acids, alkalis) away from spill. Stay upwind and
away from spill or release. Isolate immediate hazard area and keep unauthorized personnel out of area. Stop spill
or release if it can be done with minimal risk. Wear appropriate protective equipment including respiratory
protection as conditions warrant. Recover as much free liquid as possible and collect in acid-resistant container.
Use absorbent to pick up residue. Avoid discharging liquid directly into a sewer or surface waters.
Page 3 of 6
SAFETY DATA SHEET WP-126
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 2.0 SDS Revision Date: 12/31/2013

7. HANDLING & STORAGE INFORMATION


7.1 Work & Hygiene Practices: Avoid breathing mists or spray. Avoid eye and skin contact. Wear protective equipment when handling product.
Keep out of the reach of children. Do not eat, drink or smoke when handling this product. Wash thoroughly after
handling. Do not expose to heat and flame. Use only in ventilated areas. Immediately clean-up and decontaminate
any spills or residues.
7.2 Storage & Handling: Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans) away from heat and direct
sunlight. Store in closed containers. Avoid temperatures above 40°C (120°F). Keep away from incompatible
substances (see Section 10) and food/drink. Protect containers from physical damage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination.
7.3 Special Precautions: Empty containers may retain hazardous product residues.

8. EXPOSURE CONTROLS & PERSONAL PROTECTION


8.1 Ventilation & Engineering Controls: Use local or general exhaust ventilation to effectively remove and prevent buildup of vapors or mist generated from
the handling of this product. Ensure appropriate decontamination equipment is available (e.g., sink, safety shower,
eye-wash station).
8.2 Respiratory Protection: No special respiratory protection is required under typical circumstances of use or handling.
In instances where vapors or sprays of this product are generated, and respiratory protection
is needed, use only protection authorized by 29 CFR §1910.134, applicable U.S. State
regulations, or the Canadian CAS Standard Z94.4-93 and applicable standards of Canadian
Provinces, EC member States, or Australia.
8.3 Eye Protection: Avoid eye contact. Safety glasses with side shields must be used when handling or using this
product. A protective face shield is also recommended. Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166 (EU).
8.4 Hand Protection: Wear protective, chemical-resistant gloves (e.g., neoprene, nitrile) when using or handling this
product. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product.
8.5 Body Protection: Not required under normal conditions of use. A chemical resistant apron and/or protective
clothing are recommended when handling or using large quantities (e.g., > 5 gallons (18.9 L))
of this product. Protective working garments should meet EU Standard EN 344 or equivalent.

9. PHYSICAL & CHEMICAL PROPERTIES


9.1 Appearance: Clear liquid (possibly dyed)
9.2 Odor: Mild glycol odor
9.3 Odor Threshold: NA
9.4 pH: NA
9.5 Melting Point/Freezing Point: NA
9.6 Initial Boiling Point/Boiling Range: 165.5 °C (330 °F)
9.7 Flashpoint: 121 °C (250 °F)
9.8 Upper/Lower Flammability Limits: NA
9.9 Vapor Pressure: 1.10 mm Hg @ 20 °C (68 °F)
9.10 Vapor Density: NA
9.11 Relative Density: 1.127 @ 25 °C (77 °F)
9.12 Solubility: Soluble
9.13 Partition Coefficient (log Pow): NA
9.14 Autoignition Temperature: NA
9.15 Decomposition Temperature: NA
9.16 Viscosity: NA
9.17 Other Information: NA

10. STABILITY & REACTIVITY


10.1 Stability: This product is stable under normal storage and use conditions.
10.2 Hazardous Decomposition Products: Oxides of carbon (CO, CO2), sulfur (SOx), and nitrogen (NOx).
10.3 Hazardous Polymerization: Will not occur.
10.4 Conditions to Avoid: Open flames, high heat and direct sunlight.
10.5 Incompatible Substances: Strong oxidizing agents, acids or alkalis.
Page 4 of 6
SAFETY DATA SHEET WP-126
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 2.0 SDS Revision Date: 12/31/2013

11. TOXICOLOGICAL INFORMATION


11.1 Routes of Entry: Inhalation:
NO Absorption: YES Ingestion: YES
11.2 Toxicity Data: This product has not been tested on animals to obtain toxicological data. Toxicology data for some of the
components in this mixture, found in scientific literature, are presented below:
Sodium Hydroxide: LD50 (oral, rat): 500 mg/kg; Ethylene Glycol: LD50 (oral, rat): 4700 mg/kg;
Diethylene Glycol: LD50 (oral, rat): 12565 ppm; Ethylhexanoic Acid: LD50 (oral, rat): 1142 mg/kg
11.3 Acute Toxicity: See section 2.4
11.4 Chronic Toxicity: See section 2.5
11.5 Suspected Carcinogen: This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH,
NTP, or EPA classification.
11.6 Reproductive Toxicity: This product is not reported to cause reproductive toxicity in humans.
Mutagenicity: This product is not reported to produce mutagenicity effects in humans.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
11.7 Irritancy of Product: See Section 2.3
11.8 Biological Exposure Indices: NA
11.9 Physician Recommendations: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites.
Ethanol should be administered as soon possible in cases of sever poisoning since the elimination of the half-life of
ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce
“shots” of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole (4-methylpyrazole) is an
effective antagonist of alcohol dehydrogenase, and as such may be used as an antidote in the treatment off
ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body.
Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after
exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea,
vomiting and in severe cases, coma, convulsions, and possible death. The second stage lasts from 12-36 hours
after exposure and is initiated by the onset of coma. This phase is characterized by tachypnia, tachycardia, mild
hypertension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and
congestive failure. The final stage occurs 24-72 hours post exposure and is characterized by renal failure by a mild
increase in blood urine nitrogen and creatinine followed by recovery to complete anuria with acute tubular necrosis
that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol
intoxication is sever metabolic acidosis.

12. ECOLOGICAL INFORMATION


12.1 Environmental Stability: Do not allow product to reach ground water, water bodies or sewage system.
12.2 Effects on Plants & Animals: There is no specific data available for this product.
12.3 Effects on Aquatic Life: There is no specific data available for this product.

13. DISPOSAL CONSIDERATIONS


13.1 Waste Disposal: Dispose of in accordance with federal, state, provincial and local regulations.
13.2 Special Considerations: Used coolant may be recyclable. Contact the federal, state or provincial environmental authority to determine
suitability for recycling and or proper disposal requirements.

14. TRANSPORTATION INFORMATION


The basic description (ID Number, proper shipping name, hazard class & division, packing group) is shown for each mode of transportation. Additional descriptive information
may be required by 49 CFR, IATA/ICAO, IMDG, SCT, ADGT, ADR and the CTDGR.
14.1 49 CFR (GND): NOT REGULATED
14.2 IATA (AIR): NOT REGULATED
14.3 IMDG (OCN): NOT REGULATED
14.4 TDGR (Canadian GND): NOT REGULATED
14.5 ADR/RID (EU): NOT REGULATED
14.6 SCT (MEXICO): NOT REGULATED
14.7 ADGR (AUS): NOT REGULATED
Page 5 of 6
SAFETY DATA SHEET WP-126
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 2.0 SDS Revision Date: 12/31/2013

15. REGULATORY INFORMATION


15.1 SARA Reporting Requirements: This product contains Ethylene Glycol, a substance subject to SARA Title III, section 313 reporting requirements.
15.2 SARA Threshold Planning Quantity: NA
15.3 TSCA Inventory Status: All components of this product are listed in the TSCA Inventory or are exempt.
15.4 CERCLA Reportable Quantity (RQ): Ethylene Glycol: 5000 lbs (2270 kg)
15.5 Other Federal Requirements: NA
15.6 Other Canadian Regulations: This product has been classified according to the hazard criteria of the Controlled Products
Regulations (CPR) and the SDS contains all of the information required by the CPR. The
components of this product are listed on the DSL/NDSL. None of the components of this
product are listed on the Priorities Substances List. WHMIS D2B (Other Toxic Effects).
15.7 State Regulatory Information: Ethylene Glycol is found on the following state criteria lists: Florida Toxic Substances List (FL), Massachusetts
Hazardous Substances List (MA), Minnesota Hazardous Substances List (MN), New Jersey Right-to-Know List
(NJ), Pennsylvania Right-to-Know List (PA), and Washington Permissible Exposures List (WA).
Diethylene Glycol is found on the following state criteria lists: MN, PA.
Sodium Hydroxide is found on the following state criteria lists: FL, MA, MN, NJ, PA, and WA.
No ingredients in this product, present in a concentration of 1.0% or greater, are listed on any of the following state
criteria lists: California Proposition 65 (CA), Florida Toxic Substances List (FL), Massachusetts Hazardous
Substances List (MA), Michigan Critical Substances List (MI), Minnesota Hazardous Substances List (MN), New
Jersey Right-to-Know List (NJ), New York Hazardous Substances List (NY), Pennsylvania Right-to-Know List (PA),
Washington Permissible Exposures List (WA), Wisconsin Hazardous Substances List (WI).
15.8 Other Requirements: The primary component of this product is listed in Annex I of EU Directive 67/548/EEC:
Ethylene Glycol: Harmful (Xn).
Risk Phrases (R): R22-63 – Harmful if swallowed. Possible risk of harm to the unborn child.
Safety Phrases (S): S(2)-46 - Keep out of the reach of children. If swallowed, seek medical
advice immediately and show this container or label where possible.

16. OTHER INFORMATION


16.1 Other Information: WARNING! HARMFUL IF SWALLOWED. Wash hands and exposed skin areas with soap and warm water
thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/eye
protection. If ingested, call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If in eyes,
rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
KEEP OUT OF REACH OF CHILDREN.
16.2 Terms & Definitions: See last page of this Safety Data Sheet.
16.3 Disclaimer: This Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR §1910.1200.
Other government regulations must be reviewed for applicability to this product. To the best of ShipMate's &
Worldpac’s knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy,
suitability or completeness is not guaranteed and no warranties of any type, either expressed or implied, are
provided. The information contained herein relates only to the specific product(s). If this product(s) is combined
with other materials, all component properties must be considered. Data may be changed from time to time. Be
sure to consult the latest edition.
16.4 Prepared for: Worldpac, Inc.
37137 Hickory Street
Newark, CA 94560 USA
Tel: +1 (510) 608-5525
Fax: +1 (510) 742-9262
http://www.worldpac.com
16.5 Prepared by: ShipMate, Inc.
P.O. Box 787
Sisters, OR 97759-0787 USA
Tel: +1 (310) 370-3600
Fax: +1 (310) 370-5700
http://www.shipmate.com
Page 6 of 6
SAFETY DATA SHEET WP-126
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 2.0 SDS Revision Date: 12/31/2013

DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a SDS. Some of these that are commonly used include the following:
GENERAL INFORMATION:
HAZARD RATINGS:
CAS No. Chemical Abstract Service Number
0 Minimal Hazard
EXPOSURE LIMITS IN AIR: 1 Slight Hazard
2 Moderate Hazard
ACGIH American Conference on Governmental Industrial Hygienists 3 Severe Hazard
TLV Threshold Limit Value 4 Extreme Hazard
OSHA U.S. Occupational Safety and Health Administration ACD Acidic
PEL Permissible Exposure Limit ALK Alkaline
IDLH Immediately Dangerous to Life and Health COR Corrosive
W Use No Water
FIRST AID MEASURES:
OX Oxidizer
CPR Cardiopulmonary resuscitation - method in which a person whose heart has TREFOIL Radioactive
stopped receives manual chest compressions and breathing to circulate blood
and provide oxygen to the body. TOXICOLOGICAL INFORMATION:

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: HMIS LD50 Lethal Dose (solids & liquids) which kills 50% of the exposed animals
s
HEALTH, FLAMMABILITY & REACTIVITY RATINGS: LC50 Lethal concentration (gases) which kills 50% of the exposed animal
ppm Concentration expressed in parts of material per million parts
0 Minimal Hazard HEALTH TDlo Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
1 Slight Hazard FLAMMABILITY TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or toxic effects
2 Moderate Hazard PHYSICAL HAZARDS TC, TCo, LClo, & LCo
IARC International Agency for Research on Cancer
3 Severe Hazard PERSONAL PROTECTION NTP National Toxicology Program
4 Extreme Hazard RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
PERSONAL PROTECTION RATINGS: TLm Median threshold limit
log KOW or log KOC Coefficient of Oil/Water Distribution
A G
REGULATORY INFORMATION:

B H WHMIS Canadian Workplace Hazardous Material Information System


DOT U.S. Department of Transportation
TC Transport Canada
C I EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
D J NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
TSCA U.S. Toxic Substance Control Act
E K EU European Union (European Union Directive 67/548/EEC)
WGK Wassergefährdungsklassen (German Water Hazard Class)
Consult your supervisor or SOPs
F X for special handling directions. WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION (WHMIS) SYSTEM:

Face Shield &


Safety Glasses Splash Goggles Gloves
Protective Eyewear
Class A Class B Class C Class D1 Class D2 Class D3 Class E Class F

Compressed Flammable Oxidizing Toxic Irritation Infectious Corrosive Reactive


Protective Clothing
Boots Synthetic Apron Dust Respirator
& Full Suit
EC (67/548/EEC) INFORMATION:

Dust & Vapor Half- Full Face Airline Hood/Mask


Full Face Respirator
Mask Respirator Respirator or SCBA

OTHER STANDARD ABBREVIATIONS:

NA Not Available C E F N O T Xi Xn

NR No Results
Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
NE Not Established
ND Not Determined
CLP/GHS (1272/2008/EC) PICTOGRAMS:
ML Maximum Limit
SCBA Self-Contained Breathing Apparatus

NATIONAL FIRE PROTECTION ASSOCIATION: NFPA

FLAMMABILITY LIMITS IN AIR:


Autoignition Minimum temperature required to initiate combustion in air with no other
Temperature source of ignition GHS01 GHS02 GHS03 GHS04 GHS05 GHS06 GHS07 GHS08 GHS09

LEL Lower Explosive Limit - lowest percent of vapor in air, by volume, that will
Harmful Health
explode or ignite in the presence of an ignition source Explosive Flammable Oxidizer Pressurized Corrosive Toxic Environment
Irritating Hazard
UEL Upper Explosive Limit - highest percent of vapor in air, by volume, that will
explode or ignite in the presence of an ignition source

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