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* Marked Questions are having more than one correct option.

Section (A) : Atoms, molecules, moles, avogadro's hypothesis

A-1. The charge on 1 gram ions of Al3+ is : (NA = Avogadro number, e = charge on one electron)
1 1 1
(A) N e coulomb (B) × NAe coulomb (C) × NAe coulomb (D) 3 × NAe coulomb
27 A 3 9

A-2. What is correct for 10 g of CaCO3 -

(A) It contains 1g-atom of carbon (B) It contains 0.3 g-atoms of oxygen
(C) It contains 12 g of calcium (D) None of these

A-3. Which of the following contains the largest number of atoms -

(A) 11g of CO2 (B) 4g of H2 (C) 5g of NH3 (D) 8g of SO2
i r
A-4. If the atomic mass of Sodium is 23, the number of moles in 46 g of sodium is :
(A) 1 (B) 2 (C) 2.3 (D) 4.6
S
A-5.

t a
Out of 1.0 g dioxygen, 1.0 g (atomic) oxygen and 1.0 g of ozone, the maximum number of oxygen
atoms are contained in -
(A) 1.0 g of atomic oxygen.
(C) 1.0 g of oxygen gas.
u p
(B) 1.0 g of ozone.
(D) All contain same number of atoms.

A-6. One mole of P4 molecules contains -

(A) 1 molecule G
(B) 4 molecules

A-7.
(C) 1/4 × 6.022 × 1023 atoms

a m (D) 24.088 × 1023 atoms

The number of sodium atoms in 2 moles of sodium ferrocyanide Na4[Fe(CN)6], is-

(A) 2

u p
(B) 6.023 × 1023 (C) 8 × 6.02 × 1023 (D) 4 × 6.02 × 1023

A-8.

A-9.
n
Which of the following will contain same number of atoms as 20g of calcium?

A
(A) 24g magnesium (B) 12g carbon (C) 8g oxygen gas (D) 16 g oxygen atom

The percentage by mole of NO2 in a mixture of NO2(g) and NO(g) having average molecular mass 34 is :
(A) 25% (B) 20% (C) 40% (D) 75%

A-10*. In which of the following pairs do 1 g of each have an equal number of molecules?
(A) N2O and CO (B) N2 and C3O2 (C) N2 and CO (D) N2O and CO2

Section (B) : Density and vapour density

B-1. 5.6 litre of a gas at N.T.P. weighs equal to 8 gm the vapour density of gas is -
(A) 32 (B) 16 (C) 8 (D) 40.

B-2. 2 moles of H2 at NTP occupy a volume of

(A) 11.2 litre (B) 44.8 litre (C) 2 litre (D) 22.4 litre
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B-3. 4.48 litres of methane at N.T.P. correspond to-

(A) 1.2 x 1022 molecules of methane (B) 0.5 mole of methane
(C) 3.2 gm of methane (D) 0.1 mole of methane

B-4. Mol. wt. = vapour density × 2, is valid for -

(A) metals (B) non metals (C) solids (D) gases

B-5. Number of moles of water in 488 gm of BaCl2.2H2O are - (Ba = 137)

(A) 2 moles (B* ) 4 moles (C) 3 moles (D) 5 moles

B-6. Density of ozone relative to methane under the same temperature & pressure conditions is :
(A) 1 (B) 3 (C) 1.5 (D) 2.5

B-7. Vapour density of a gas if its density is 0.178 g/L at NTP is :

B-8.
(A) 0.178 (B) 2 (C) 4 (D) 0.089

i r
A nugget of gold and quartz was found to contain x g of gold and y g of quartz and has density d. If the
densities of gold and quartz are d1 and d2 respectively then the correct relation is :
x y
(A) d + d =
xy
(B) xd1 + yd2 = (x + y) d
S
1

x y
2

(C) d + d =
d

xy
(D)
xy x x
+ d + d =0
t a
B-9.
2 1 d d

u p 1 2

The vapour density of a gas A is twice that of a gas B. If the molecular weight of B is M, the molecular
weight of A will be :

(A) M (B) 2M G
(C) 3M (D)
M
2

B-10.
(A) 360.5 kg (B) 36.05 kg
a m
Mass of H2O in 1000 kg CuSO4.5H2O is - (Cu = 63.5)
(C) 3605 kg (D) 3.605 kg

B-11.

u p
The relative density of a gas A with respect to another gas B is 2. The vapour density of the gas B is 20, the
vapour density of the gas A is :

B-12.
(A) 30

A n (B) 40 (C) 50 (D) 60

The ratio of the weight of one litre of a gas to the weight of 1.0 L oxygen gas both measured at S.T.P. is
2.22. The molecular weight of the gas would be :
(A) 14.002 (B) 35.52 (C) 71.04 (D) 55.56

B-13. The molar mass of normal water is .......... as compared to heavy water.
(A) 10% less (B) 10% high (C) 2% less (D) zero% less

Section (C) : Percentage composition and molecular formula

C-1. The mass of carbon present in 0.5 mole of K4[Fe(CN)6] is -

(A) 1.8 gm (B) 18 gm (C) 3.6 gm (D) 36 gm

C-2. The percentage of nitrogen in urea is about-

(A) 38.4 (B) 46.6 (C) 59.1 (D) 61.3

C-3. The empirical formula of a compound of molecular mass 120 is CH2O. The molecular formula of the
compound is :
(A) C2H4O2 (B) C4H8O4 (C) C3H6O3 (D) all of these
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C-4. Insulin contains 3.4% sulphur by mass. What will be the minimum molecular weight of insulin -
(A) 94.117 (B) 1884 (C) 941 (D) 976

C-5. The percent of N in 66% pure (NH4)2 SO4 sample is -

(A) 32 (B) 28 (C) 14 (D) None of these

C-6. A compound was found to contain 5.37% nitrogen by mass. What is the minimum molecular weight
of compound-
(A) 26.07 (B) 2.607 (C) 260.7 (D) None

C-7. Calculate the molecular formula of compound which contains 20% Ca and 80% Br (by wt.) if molecular
weight of compound is 200. (Atomic wt. Ca = 40, Br = 80)
(A) Ca1/2Br (B) CaBr2 (C) CaBr (D) Ca2Br

C-8. The empirical formula of a compound is CH. Its molecular weight is 78. The molecular formula of the
compound will be -
(A) C2H2 (B) C3H3 (C) C4H4 (D) C6H6

i r
C-9.

(A) M2O (B) MO (C) M2O3 (D) M3O4

S
An oxide of a metal (M) contains 40% by mass of oxygen. Metal (M) has atomic mass of 24. The
empirical formula of the oxide is-

C-10.

t a
Two oxides of Metal contain 27.6% and 30% oxygen respectively. If the formula of first oxide is M3O4
then formula of second oxide is -

C-11.
(A) MO (B) M2O (C) M2O3

u p (D) MO2

The simplest formula of a compound containing 50% of element X (atomic mass = 10) and 50% of the
element Y (atomic mass = 20) by weight is
(A) XY (B) X2Y (C) XY2
G (D) X2Y3.

D-1. m
Section (D) : Balanced chemical equation analysis & Limiting Reagent

a
The mass of oxygen that would be required to produce enough CO, which completely reduces
1.6 kg Fe2O3 (at. mass Fe = 56) is :

D-2.
(A) 240 gm

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(B) 480 gm (C) 720 gm

The moles of O2 required for reacting with 6.8 gm of ammonia.

(D) 960 gm

D-3.
(A) 5

A n
(..... NH3 +..... O2  ..... NO + ..... H2O) is
(B) 2.5 (C) 1 (D) 0.5

What weight of CaCO3 must be decomposed to produce the sufficient quantity of carbon dioxide to convert
21.2 kg of Na2CO3 completely into NaHCO3. [Atomic mass Na = 23, Ca = 40]
CaCO3  CaO + CO2
Na2 CO3 + CO2 + H2O  2NaHCO3
(A) 100 Kg (B) 20 Kg (C) 120 Kg (D) 30 Kg

D-4. 12 g of alkaline earth metal gives 14.8 g of its nitride. Atomic weight of metal is -
(A) 12 (B) 20 (C) 40 (D) 14.8

D-5. NX is produced by the following step of reactions

M + X2  M X2
3MX2 + X2  M3X8
M3 X8 + N2CO3  NX + CO2 + M3O4
How much M (metal) is consumed to produce 206 gm of NX. (Take at wt of M = 56, N=23, X = 80)
14 7
(A) 42 gm (B) 56 gm (C) gm (D) gm
3 4
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D-6. How many mol Fe2+ ions are formed, when excess of iron is treated with 50mL of 4.0M HCl under
inert atmosphere ? Assume no change in volume -
(A) 0.4 (B) 0.1 (C) 0.2 (D) 0.8

D-7. A mixture containing 100 gm H2 and 100 gm O2 is ignited so that water is formed according to the reaction,
2H2 + O2  2H2O; How much water will be formed -
(A) 113 gm (B) 50 gm (C) 25 gm (D) 200 gm

D-8. 0.5 mole of H2SO4 is mixed with 0.2 mole of Ca (OH)2. The maximum number of moles of CaSO4
formed is -
(A) 0.2 (B) 0.5 (C) 0.4 (D) 1.5

D-9. For the reaction : A + 2B  C

5 mole of A and 8 mole of B will produce -
i r
D-10.
(A) 5 mole of C (B) 4 mole of C (C) 8 mole of C

S
(D) 13 mole of C

12 litre of H2 and 11.2 litre of Cl2 are mixed and exploded. The composition by volume of mixture
is -
(A) 24 litre of HCl
(C) 0.8 litre H2 & 22.4 litre HCl
a
(B) 0.8 litre Cl2 and 20.8 lit HCl.
(D) 22.4 litre HCl
t
D-11.

u p
How many mole of Zn(FeS2) can be made from 2 mole zinc, 3 mole iron and 5 mole sulphur.

D-12.
(A) 2 mole (B) 3 mole

G
(C) 4 mole

For the reaction 2P + Q  R, 8 mol of P and 5 mol of Q will produce

(A) 8 mol of R (B) 5 mol of R (C) 4 mol of R
(D) 5 mole

(D) 13 mol of R

D-13.
a m
Equal weight of 'X' (At. wt. = 36) and 'Y' (At. wt. = 24) are reacted to form the compound X2Y3. Then :

p
(A) X is the limiting reagent
(B) Y is the limiting reagent

u
(C) No reactant is left over and mass of X2Y3 formed is double the mass of ‘X’ taken

A n
(D) none of these

D-14*. A + B  A3B2 (unbalanced)

A3B2 + C  A3B2C2 (unbalanced)
Above two reactions are carried out by taking 3 moles each of A and B and one mole of C. Then which
option is/are correct ?
(A) 1 mole of A3B2C2 is formed (B) 1 2 mole of A3B2C2 is formed
(C) 1/2 mole of A3B2 is formed (D) 1 2 mole of A3B2 is left finally

D.15* If 27 g of Carbon is mixed with 88 g of Oxygen and is allowed to burn to produce CO2 , then :
(A) Oxygen is the limiting reagent. (B) Volume of CO2 gas produced at NTP is 50.4 L.
(C) C and O combine in mass ratio 3 : 8. (D) Volume of unreacted O2 at STP is 11.2 L.

D-16. Phosphine (PH3) decomposes to produce vapours of phosphorus and H2 gas. What will be the
change in volume when 100 mL of phosphine is decomposed ? PH3  P4 + H2
(A) + 50 mL (B) 500 mL (C) + 75 mL (D) – 500 mL

D-17. How many moles of potassium chlorate need to be heated to produce 11.2 litre oxygen at N.T.P.
1 1 1 2
(A) mol (B) mol (C) mol (D) mol
2 3 4 3
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D-18. The molar ratio of Fe++ to Fe+++ in a mixture of FeSO4 and Fe2(SO4)3 having equal number of sulphate ion
in both ferrous and ferric sulphate is
(A) 1 : 2 (B) 3 : 2 (C) 2 : 3 (D) can't be determined

1
D-19. If 1 moles of oxygen combine with Al to form Al2O3, the weight of Al used in the reaction is : (Al = 27)
2
(A) 27g (B) 54g (C) 40.5g (D) 81 g

D-20. If 1 gm of HCl and 1 gm of MnO2 heated together the maximum weight of Cl2 gas evolved will be
[MnO2 + 4HCl  MnCl2 + Cl2 + 2H2O] [Atomic mass of Mn=55]
(A) 2gm (B) 0.975 gm (C) 0.486 gm (D) 0.972 gm

D-21. 0.5 mole of H2SO4 is mixed with 0.2 mole of Ca (OH)2. The maximum number of moles of CaSO4 formed
is

D-22.
(A) 0.2 (B) 0.5 (C) 0.4 (D) 1.5

A sample of ammonium phosphate (NH4)3PO4 contains 3.18 mol of H atoms. The number of mol of
i r
O atoms in the sample is :
(A) 0.265 (B) 0.795 (C) 1.06 (D) 3.18 S
Section (E) : Principle of Atom Conservation (POAC)
E-1.
t a
A sample of calcium carbonate is 80% pure. 25g of this sample is treated with excess of HCl. How much
volume of CO2 will be obtained at NTP.
(A) 4.48 litre (B) 5.6 litre (C) 11.2 litre

u p (D) 2.24 litre

E-2.

(A) 74.6g (B) 85.7g G

An ore contains 1.34% of the mineral argentite, Ag2S, by weight. How many grams of this ore would have
to be processed in order to obtain 1.00g of pure silver. (Ag) -
(C) 107.9g (D) 134.0g

E-3.
m
25.4 g of iodine and 14.2g of chlorine are made to react completely to yield a mixture of Cl and Cl3.

a
Calculate the number of moles of Cl and Cl3 formed.

E-4.
u p
(A) 0.1 mole, 0.1 mole (B) 0.1 mole, 0.2 mole (C) 0.5 mole, 0.5 mole (D) 0.2 mole, 0.2 mole

What weights of P4O6 and P4O10 will be produced by the combustion of 31g of P4 in 32g of oxygen leaving

E-5.
no P4 and O2.

A n
(A) 2.75g, 219.5g (B) 27.5g, 35.5g (C) 55g, 71g (D) 17.5g, 190.5g

21.6 g of silver coin is dissolved in HNO3. When NaCl is added to this solution, all silver is precipitated as
AgCl. The weight of AgCl is found to be 14.35 g then % of silver in coin is :
(A) 50% (B) 75% (C) 100% (D) 15%

Section (F) : Concentration terms

F-1. What volume of a 0.8 M solution contains 100 milli moles of the solute?
(A) 100 mL (B) 125 mL (C) 500 mL (D) 62.5 mL

F-2. If 500 ml of 1 M solution of glucose is mixed with 500 mlof 1 M solution of glucose final molarity of solution
will be :
(A) 1 M (B) 0.5 M (C) 2 M (D) 1.5 M

F-3. The volume of water that must be added to a mixture of 250 ml of 0.6 M HCl and 750 ml of
0.2 M HCl to obtain 0.25 M solution of HCl is :
(A) 750 ml (B) 100 ml (C) 200 m (D) 300 m

F-4. What volume of 0.10 M H2SO4 must be added to 50 mL of a 0.10 M NaOH solution to make a solution in
which the molarity of the H2SO4 is 0.050 M ?
(A) 400 mL (B) 50 mL (C) 100 mL (D) 150 mL
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F-5. 500 mL of a glucose solution contains 6.02 × 1022 molecules. The concentration of the solution is
(A) 0.1 M (B) 1.0 M (C) 0.2 M (D) 2.0 M

F-6. Mole fraction of A in H2O is 0.2. The molality of A in H2O is :

(A) 13.9 (B) 15.5 (C) 14.5 (D) 16.8

F-7. The molarity of the solution containing 2.8%( mass / volume) solution of KOH is : (Given atomic mass of
K = 39 ) is :
(A) 0.1 M (B) 0.5 M (C) 0.2 M (D) 1 M

F-8. What is the molarity of H2SO4 solution that has a density of 1.84 g/cc and contains 98% by mass of
H2SO4? (Given atomic mass of S = 32)
(A) 4.18 M (B) 8.14 M (C) 18.4 M (D) 18 M

i r
F-9.
S
The molality of a sulphuric acid solution is 0.2. Calculate the total weight of the solution having
1000 gm of solvent.

F-10.
(A) 1000 g (B) 1098.6 g (C) 980.4 g

a
(D) 1019.6g

t
Suppose you want an acidic solution to carry out a chemical reaction with 2 moles of NaOH. Which sample
of acid is the best choice for you. (At. wt. : S = 32, Cl = 35.5)
(A) 1 M H2SO4 (50 Rs per lt.)
(C) 1 M HCl (30 Rs per lt.)
p
(B) 1 M H2SO4 (56 Rs per lt.)

u
(D) 1 M HCl (27 Rs per lt.)

F-11. G
2M of 100 ml Na2 SO4 is mixed with 3M of 100 ml NaCl solution and 1M of 200 ml CaCl2 solution. Then the

(A) 1/2 (B) 2

m
ratio of the concentration of cation and anion.

a (C) 1.5 (D) 1

F-12.
(A) 18 M

u p
H3PO4 (98 g mol–1) is 98% by mass of solution. If the density is 1.8 g/ml, the molarity is
(B) 36 M (C) 54 M (D) 0.18 M

F-13.

A n
50 mL solution of BaCl2 (20.8% w/v) and 100 mL solution of H2SO4 (9.8% w/v) are mixed
(Ba = 137, Cl = 35.5, S = 32)

BaCl2 + H2SO4  BaSO4  + 2HCl

BaSO4 formed is :
(A) 23.3 g (B) 46.6 g (C) 29.8 g (D) 11.65 g

F-14. A solution of glucose received from some research laboratory has been marked mole fraction x and molality
(m) at 10ºC. When you will calculate its molality and mole fraction in your laboratory at 24ºC you will find
(A) mole fraction (x) and molality (m) (B) mole fraction (2x) and molality (2m)
(C) mole fraction (x/2) and molality (m/2) (D) mole fraction (x) and (m ± dm) molality

F-15. The volume of water is required to make 0.20 M solution from 16 mL of 0.5 M solution is
(A) 40 ml (B) 16 ml (C) 50 ml (D) 24ml

M
F-16. A solution of FeCl3 is its molarity for Cl– ion will be
30

M M M M
(A) (B) (C) (D)
90 30 10 5
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A-1. (D) A-2. (B) A-3. (B) A-4. (B) A-5. (D) A-6. (D) A-7. (C)

A-8. (C) A-9. (A) A-10*. (CD) B-1. (B) B-2. (B) B-3. (C) B-4. (D)

B-5. (B) B-6. (B) B-7. (B) B-8. (A) B-9. (B) B-10. (B) B-11. (B)

B-12. (C) B-13. (A) C-1. (D) C-2. (B) C-3. (B) C-4. (C) C-5. (C)

C-6. (C) C-7. (B) C-8. (D) C-9. (B) C-10. (C) C-11. (B) D-1. (B)

D-2. (D) D-3. (B) D-4. (C) D-5. (A) D-6. (B) D-7. (A) D-8. (A)

D-9. (B) D-10. (C) D-11. (A) D-12. (C) D-13. (C) D-14*. (BD)

i r
D.15*

D-22.
(BCD) D-16.

(C) E-1.
(C)

(A)
D-17.

E-2.
(B)

(B)
D-18.

E-3.
(B)

(A)
D-19.

E-4.
(B)

(B)
D-20.

E-5.
(C)

(A)
S
D-21.

F-1.
(A)

(B)

F-2. (A) F-3. (C) F-4. (C) F-5. (C) F-6.

t
(A) a F-7. (B) F-8. (C)

F-9.

F-16.
(D)

(C)
F-10. (A) F-11. (D) F-12. (A)
p
F-13.

u
(D) F-14. (A) F-15. (D)

G
a m
u p
A n