An Exergy Method For Compressor Performance Analysis - 1995 - Importante
An Exergy Method For Compressor Performance Analysis - 1995 - Importante
421-433, 1995
[•IUTTERWORTH Copyright :C: 1995 Elsevier Science Limited and IIR
"~E I N E M AN N
Printed in Great Britain. All rights reserved
0140-7007/95/$10.00 + .00
An exergy method for compressor performance analysis is presented. The purpose of this is to identify and
quantify defects in the use of a compressor's shaft power. This information can be used as the basis for
compressor design improvements. The defects are attributed to friction, irreversible heat transfer, fluid
throttling, and irreversible fluid mixing. They are described, on a common basis, as exergy destruction rates
and their locations are identified. The method can be used with any type of positive displacement
compressor. It is most readily applied where a detailed computer simulation program is available for the
compressor. An analysis of an open reciprocating refrigeration compressor that used R12 refrigerant is
given as an example. The results that are presented consist of graphs of the instantaneous rates of exergy
destruction according to the mechanisms involved, a pie chart of the breakdown of the average shaft power
wastage by mechanism, and a pie chart with a breakdown by location.
(Keywords: performance analysis; compressor; exergy; simulation)
This paper describes an exergy analysis technique to valve, or with that due to heat transfer between the
quantify defects in the shaft power utilization of a compressor and the surroundings. Even leakage can be
compressor. The technique provides a breakdown of the characterized in terms of exergy destruction, as it involves
causes of shaft power wastage that is valuable to a design throttling and irreversible fluid mixing. The shaft power
engineer. When the main mechanisms of power wastage wastage due to leakage can thus be quantified.
have been located and quantified, appropriate modifica- The case study included in this paper is that of a
tions can be made to improve the performance of the reciprocating refrigeration compressor. A detailed simu-
compressor. It is shown that the new exergy method has lation program was used and experimental data were
several advantages when compared with conventional available to validate some of the main simulation results.
techniques that are used for the same purpose.
Shaft power wastage in compressors can be attributed
Literature review
to fluid throttling, irreversible fluid mixing, friction, and
irreversible heat transfer. All such defects can be Dossat I adopted a conventional approach and broke
described as exergy destruction rates. The locations down the overall efficiency of a refrigeration compressor
and mechanisms of the defects can be identified. For by defining the mechanical efficiency and the compres-
instance, the exergy destruction at the suction valve can sion efficiency. The mechanical efficiency was the ratio of
be compared with the exergy destruction at the discharge the indicated power to the shaft power input. It was
less than unity due to the effects of mechanical friction
*Present address: Ford Motor Company, Climate Control Division, within the compressor. The compression efficiency was
Dearborn, M1 48120, USA calculated by comparing the indicated power with the
421
422 J. A. McGovern and S. Harte
Nomenclature
b Specific flow exergy function (b = h - Tos ) 1) Specific volume (m 3 kg-l)
(Jkg -1) W Rate at which work is done on a system (W)
Cd Coefficient of discharge Compressor shaft power input (W)
cv Specific heat at constant volume (J kg- 1 K - 1) X Distance in x direction (m)
Cp Specific heat at constant pressure Y Distance in y direction (m)
(Jkg -I K -l) Z Distance in z direction (m)
h Specific enthalpy (Jkg 1 K l)
h' Specific enthalpy just downstream of an Greek letters
adiabatic throttling process (J kg -1 K -t) A Change in or increment of a quantity
] Irreversibility rate (exergy destruction rate) (5 Very small change in, or increment of, a
(w) quantity
m Mass (kg) ~,1 Rational efficiency defect
rh Mass flowrate (kg s- l) r/ Rational efficiency
or 0 Absolute temperature (K)
Rate of change of the mass of a system p Density (kgm -3)
(kgs 1) ~. Rate of density change (kg m 3 s l)
P. Absolute pressure (Pa) E Rate of exergy transfer or rate of exergy
Q Heat transfer rate to a system (W) ,.:.,,
change (W)
R Specific gas constant (Jkg -1 K 1) :c Rate of exergy transfer to the stream of fluid
Rate of change of entropy (J K - 1 s J) that passes through the compressor (W)
Scr Rate of entropy creation (JK -1 s 1)
S Specific entropy (J kg i K - I ) Subscripts
Rate of change of specific entropy 1~2, . . . Flow position
(Jkg I K - l s 1) bulk Refers to a characteristic or property of the
s' Specific entropy just downstream of an bulk fluid
adiabatic throttling process (J kg-1 K - 1) C Compressor
T Absolute temperature (K) cr Creation
T' Absolute temperature just downstream of an d Discharge
adiabatic throttling process (K) Identifier for exit flow stream
i/" Rate of change of absolute temperature f Associated with friction
(Ks -I ) i Identifier for inlet flow stream
To Absolute temperature of the environment J Identifier for a thermal mass
(K) k Identifier for a thermal mass
t Time (s) loc Local
U Internal energy (J) mx Associated with mixing
/.) Rate of change of the internal energy of a new New value calculated after a small time
system (J s- 1) interval in a finite difference calculation
u Specific internal energy (J kg- 1) rev Reversible
~i Rate of change of the specific internal energy S Suction
of a system (J kg 1 s-I) th Associated with throttling
V Volume (m 3) O Associated with heat transfer
I? Volume change rate (m 3 s i)
isentropic power required to produce the same refrigera- Exergy techniques have previously been suggested for
tion effect. The compression efficiency took account of application to compressors. Stecco 5 and McGovern 6
effects such as wire drawing (throttling), heat exchange both argued the case for using exergy analysis to measure
between the vapour and cylinder walls, and fluid friction. the efficiency of compressors. Both concluded that the
Dossat pointed out that the relationships between the exergy approach had the advantage that it could be
various factors that influenced the compression efficiency applied to all types of compressors, and that it could be
were difficult to evaluate mathematically. 4 integrated into an analysis of a whole plant or cycle.
FrancoDaCosta 2, Pandaya 3 and Sakaino described Townsend 7 applied exergy techniques to analyse a
the interrelationships between these factors. FrancoDa- multistage refrigeration system. He showed how exergy
Costa outlined a model suitable for use with a simulation techniques were quickly applied and how plant design
program, while Sakaino defined a model suitable for improvements were made due to the added insight the
use with experimental data. Estimations and simplifying exergy techniques gave. Xu 8 used exergy techniques to
assumptions that were somewhat arbitrary or subjective experimentally determine the thermodynamic losses in
had to be made. For example, Sakaino indirectly the components of refrigerators and freezers: in all cases
estimated the power wastage due to heat transfer by the largest exergy destruction rates occurred at the
subtracting the ideal power and the wastage by the other compressor.
mechanisms from the indicated power. However, it is believed that no other authors have
An exergy method for compressor performance analysis 423
1. Suction plenum
fluid system
A '°
Suction Discharge
plenum plenum
in a PhD thesis by M c G o v e r n 12 for the speed range
)
3 0 0 - 9 0 0 r e v m i n -I. All the experimental work was
Suction Discharge carried out before the completion of that PhD, and the
pipe pipe refrigerant used was R12.
The simulation model that was used to represent the
Compression compressor is outlined in this paper, as the particular
chamber exergy analysis results that follow depend on the
assumptions that were made in the simulation. A less
detailed model would have resulted in a less refined
Crankcase exergy analysis, while a more detailed and accurate
Figure 2 Flow paths between the fluid systems of the compressor. The model could have provided a more precise breakdown of
arrows indicate the normal flow directions, but in some cases reverse the causes of shaft power wastage.
flows also occur A major limitation of the ideal gas model with
Figure 2 Chemins d'&'oulement entre les circuits du compresseur. Les constant specific heats that was used was that it was
flbches indiquent lessens normaux d'&'oulement, mais dans certains cas il not possible to obtain simultaneous agreement between
peut se produirc un &'oulement inverse
simulated and experimental results for (1) the mass
flowrate and (2) the refrigerant temperatures. In an
industrially funded project, which cannot be reported on
described the use of exergy techniques to determine the at this time, the authors applied the same techniques to a
instantaneous and average rates of shaft power wastage, more complex rotary positive displacement compressor.
apportioned to either specific mechanisms or specific In this case the refrigerant was R134a. Real gas
systems, within a positive displacement compressor. This equations 13 were used in the computer model and
paper supersedes a paper presented by the authors at the much better agreement between experimental results
1992 International Compressor Engineering Conference and simulation results was achieved.
at Purdue 9. Figure 1 is a schematic representation of the compres-
sor. There are four fluid systems within it, and four solid
masses. The flow paths between the fluid systems are
The compressor model
shown in Figure 2, while the heat transfer paths between
The compressor that was simulated and analysed has the fluid systems and solid masses are shown in Figure 3.
been described in two previous papers 1°'11. It was an A conventional first-law approach was used in
open-type air-cooled belt-driven compressor of relatively modelling the fluid systems within the compressor (see
straightforward design. It had two cylinders, but the Appendix 1). The simulation program was largely based
computer model was for one cylinder only. It had a on those published as Purdue short courses 14,15. Ideal gas
crank radius of 0.025 m, a piston diameter of 0.065 m, behaviour was assumed. In addition, the fluid systems
and a clearance volume of 4.51 ml per cylinder. Detailed were modelled in a special way to facilitate the exergy
experimental results for the compressor were included analysis. The method was fully consistent with the
424 J. A. McGovern and S. Harte
1.2
1
! E sTrg n°m ~ 340
350
Discharge plenum
1 1 Head partition
i
!
I
330 i
a. Suction plenum I
~ 320 Cylinder, crankcase, and piston
0.8
0.6
310 I
] Crankcase : 3O£ , 1
n
0.4 . . . . . .
45 90 135 180 225 270 315 360
Crank angle/[deg]
f
0.2
I Suction plenum j [
0
Temperatures of the fluid systems
0 45 90 135 180 225 270 315 360
Crank angle l ( d e g ]
Discharge plenum Crankcase
~' 36o
Valve lift "~ 340 I
~ , ! ~ Cylinder
& 320 ! ! ~\/.v---- . . . .
I I E
4 uconvave i
300 "4.. I ~t
~ - Suction plenum ] !
280 , h , ,
0 45 90 135 180 225 270 315 360
~, ~/ Discharge valve ~ I~
Crank angle/[deg]
r/- I~ (3)
Overall exergy analysis
Exergy analysis is based on the assumption that there is The difference between unity and the rational efficiency is
an infinite equilibrium environment that ultimately the total rational efficieno, defect. It is a decimal fraction
surrounds all systems that are to be analysed. The representing the rational inefficien O' of the compressor:
exergy (or available energy) of a system is the maximum
work that could be derived if the system were allowed to ~,/= 1 - r/ (4)
come to equilibrium with the environment. It is a
consequence of the second law of thermodynamics that
the combined exergy of all systems can only decrease or
Exergy analysis of a general fluid system
remain unchanged. Exergy can be destroyed, but not
created. Exergy can be exchanged between systems, but if For a general system as shown in Figure 6, which could
there are thermodynamic irreversibilities (such as friction correspond to one of the fluid systems within a
or heat transfer with finite temperature differences) some compressor, there are several types of change occurring
of the potential for the production of work is destroyed. simultaneously. There are unsteady flows of fluid in
In all real processes, therefore, the total exergy of all and out and there are unsteady heat transfer rates
systems decreases. For a specified system boundary a (which can be positive or negative). The mass, the
clear distinction can be made between exergy destruction volume, and all the thermodynamic properties of the
and exergy loss. Exergy loss is exergy that is passed on to system are changing.
some other system (often the environment) and which The rate of exergy destruction for the system can be
cannot be considered useful in the context of the purpose described as follows (Kotas TM, appendix B, Equation
of the plant. The term exergy destruction is used when the (B.14); Bejan 19, p 114):
potential for the production of work is destroyed within
the system boundary.
The exergy of a system is a co-property of the system ' ' Z<
i 7"/.] (5)
and the environment. In exergy analysis of compressors
the environment consists of the local surroundings of the The term S is the rate of change of entropy of this system.
compressor. These local surroundings are modelled as Equation (5) is related to Equation (35) of Appendix 2 by
being in equilibrium and infinite. Given sufficient infor- the G u o y Stodola relation:
mation, the exergy of all the systems within a compressor
can be determined at any time. By determining ] = ToScr (6)
1. the rate of change of the exergy of each of the For a system that was in a steady state or in equilibrium,
systems that comprise a compressor, Equation (5) could be evaluated provided there was
2. the rates of exergy exchange between them, enough information to describe the density and the
3. the rates ofexergy exchange between the compressor specific entropy as continuous functions over the volume
and systems outside the compressor, (right to the boundary) and over time:
the rates of exergy destruction associated with the S = I][(~p+ sfl)dxdydz (7)
compressor can be calculated. This is the principle on
426 J. A. McGovern and S. Harte
between the stream of incoming fluid and the fluid already in the
system. Two different representations of the same model are shown in
(b) and (c). The model applies while a small quantity of fluid enters the --*0=~ Equilibrium
system
fluid system
& --, , th
Figure 7 Ces schemas montrent le modble utilis~ pour l'analyse U, V,T,p,m
exergOtique du mOlange d'un ~coulement entrant dans le systkme avec le
fluide dgjit prOsent dans celui-ci. Le processus irrkversible de mdlange dans
Ca) est remplac~ par le transfert irreversible de chaleur entre l~coulernent
de fluide entrant clans le systkme et le fluide dkja present dans celui-ci.
Deux representations diff&entes d'un mdme modble sent prdsentOes clans
(b) et (c). Le modkle est valable pour les cas olt une petite de fluide entre
dans le systkme
The basis of the exergy analysis model for a fluid system Figure 8 Schematic representation of the set of models for the
irreversibility mechanisms within a fluid system. The equilibrium fluid
When a system like that shown in Figure 6 is not in a system is included within the system
steady state and not in equilibrium, there will not be Figure 8 Reprksentation schdmatique des groupe de modbles pour les
enough information to evaluate the S term of Equation m~canismes d'irr~versibilit~ it l'int~rieur d'un circuit. Le circuit it
l'~quilibre est inclus clans le systkme
(7), or Equation (5). However, an exergy analysis model
is proposed whereby the o6 term can be estimated. This
involves specifying quasi-steady models for each of the Analysis boundary -7
mechanisms of irreversibility that are assumed to occur. ! ~,=-pv
Each of these irreversibility models involves entropy
creation, but no entropy change rate. The sum of the _
i i
; ....... -,
entropy creation rates can be represented by the t e r m Scr" __5_ q---
According to the assumptions that are made, when the ',, 0o,, ,, i
change rate, Srev, for the equilibrium system that is " (Z :'
complementary to the irreversibility models, and con-
sistent with the first law analysis of the original system,
can then be evaluated.
The exergy analysis model thus consists of separate
components that can be used to calculate the entropy Figure9 A fluid system in equilibrium. The intensive thermodynamic
creation rates for each mechanism of irreversibility and state of all inlet and outlet flows is the same as that of the system itself.
the entropy change rate of a complementary equilibrium All heat transfer rates to or from the system occur at the temperature of
the system
system; the sum of these entropy creation and entropy
Figure 9 Un circuit it l'~quilibre. L'~tat thermodynamique de tousles
change r a t e s (o6cr -4:"o6rev) equals the entropy change rate Ocoulernents aux entrdes et aux sorties est similaire it celui du systbme lui-
of the non-equilibrium system. Alternatively, it will be m~rne. Tous[es taux de transfert de chaleur vers ou en provenance du
shown that the irreversibility models are sufficient in systkme se produisent it la temp&ature du systbme
An exergy method for compressor performance analysis 427
3. Any heat transfer rate between a solid surface at the Table l Comparison of simulation results and experimental results
boundary and the equilibrium fluid system occurs, with a Tableau l Comparaison des r~sultats de la simulation avec ceux obtenus
finite temperature difference, across a boundary layer of lors des experiences
fluid that has negligible thickness and mass within the Experimental Simulation
system. The associated exergy destruction rate occurs in results results
the system but outside the equilibrium fluid system
Shaft power (W) 725 742
irrespective of the direction of heat flow. Indicated power (W) 674 694
4. The flow through any restriction is isentropic Mass flow rate (kg s -I) 0.013 0.0125
upstream of the throat. This is a standard assumption, Suction plenum exit temperature (K) 298 289
which underlies the orifice flow equation, in compressor Dsch. plenum exit temperature (K) 358 344
Crankcase temperature (K) 320 321
simulation. The irreversibility associated with throttling Energy to environment (W) 200 213
at a flow restriction therefore occurs downstream of the
restriction.
5. Any fluid that enters a system through a flow derived in Appendix 3:
restriction undergoes adiabatic throttling, followed by
irreversible heat transfer (as illustrated in Figure 7) with
the equilibrium fluid system. This irreversibility occurs (J T cpdO ( h T h i ) ) (10)
Jmx' = thiT° r; 0
within the system, but outside the equilibrium system.
1400
/ /
45C
1200 40C
356
1000
300
/
8OO 25C
6O0 200
150
400
>, 100
P 200
uJ 0
_J 50
0
0 45 90 135 180 225 270 315 360 45 90 135 180 225 270 315 360
Crank angle/[deg] Crankang~/[deg]
Exergy destruction rate due to friction Exergy destrn, rate due to condn.
/
250
200
150
100
50
/ ,v
0
0 45 90 135 180 225 270 315 360 45 90 135 180 225 270 315 360
Crank angle I[deg] Crank angle I[deg]
Exergy destruction rate due to mixing Exergy destrn, rate due to ext. conv.
5O 20
45
IRl'l _ I
18
40
^IVW~_I 16
35
30
Iv. " N 14
12
25 10
t
8
15 ~A 6
10 /I II ~1 4
5
~lV~l 2
0 - l 0
0 45 90 135 180 225 270 315 360 0 45 90 135 180 225 270 315 360
Crank angle I[deg] Crank angle/[deg]
Figure 10 Diagrams of the instantaneous rates of exergy destruction according to the mechanisms involved
Figure 10 Diagrammes des taux de destruction instantan~e d'exergie, selon les rnkcanismes coneern~s
Other exergy destruction rates friction work that is dissipated as heat transfer to a mass
Other causes of irreversibility that occur in the com- at temperature Ti is given as follows [e.g. see Kotas 18,
pressor are heat transfer between the lumped solid Equation (10)]:
masses, heat transfer to the environment, and friction.
Equations (14) and (15) respectively, which have /:f= ljVf(1 T/ -To
. .) (16)
the same form as Equation (8), are applicable for the
first two of these. The subscripts j and k refer to
solid masses.
The overall exergy destruction rate
Equations (5) and (8)-(16) can be used to evaluate the
•
mechanisms of shaft power wastage in detail. This would ConJerence at Purdue (Ed. J. F. Hamilton and R. Cohen) Purdue
include detailed data for temperatures, heat transfer University, W. Lafayette, IN, USA, (4 7 Aug 1986) 2 415 427
4 Sakaino, K. Some approaches towards a high efficiency rotary
rates, and mass flowrates within the compressor. A good compressor Proe 1984 International Compressor Engineering
practical solution is to use simulation techniques with Con/~'renee at Purdue (Ed. R. Cohen) Purdue University, W.
experimental verification of critical predictions such as Lafayette, IN, USA (11-13 Jul 1984) 315-322
the shaft power input, the mass flowrate and the 5 Stecco, S. S. Exergy analysis of compression and expansion pro-
discharge temperature. The irreversibility models pro- cesses Energy (1986) l l (6) 573 577
6 McGovern, J. A. Compressor rational efficiencies Developments
posed in this paper reduce to a practical minimum the in bMustrial Compressors, Proc lnst Mech Eng Conference 10
amount of data necessary for an exergy analysis that can (1989) 59-67
discriminate between different mechanisms and locations 7 Townsend, D. W. Second law analysis in practice The Chemical
of power wastage. Engineer (1980) Oct 628-633
8 Xu, X. Energy analysis on a vapor compression system using
R12, R134a and R290 as refrigerants Proc 1992 International
R¢f[rigeration Con/~'rence at Purdue (Ed. R. Tree and J. E.
Conclusions Braun) Purdue University (14-17 Jul 1992) 1 231-240
9 McGovern, J. A., Harte, S. Computer simulation of exergy
A method has been proposed to break down and destruction within a reciprocating compressor Proe 1992 Inter-
quantify the shaft power wastage mechanisms in a national Compressor EngineerhTg Conference at Purdue (Ed.
compressor. It is particularly suitable for application in J, F. Hamilton) Purdue University, W. Lafayette, IN, USA
(14 17 Jul 1992) I 309-316
computer simulations of compressors, and provides a 10 McGovern, J, A. Performance characteristics of a reciprocating
sound basis for design optimization. The method also compressor over a range of speeds Proc 1988 International Com-
fills a gap in the literature by allowing for well-founded pressor Engbwering ConJi'rence at Purdue (Ed. W. Soedel) Pur-
quantification of defects in shaft power utilization or due University, W. Lafayette, IN, USA (18-21 Jul 1988) 1
146 153
rational efficiency. The technique was applied to a 11 McGovern, J. A. Performance testing of an open reciprocating
reciprocating refrigeration compressor, and graphs of refrigeration compressor over a range of speeds Proc 1986 Inter-
the instantaneous rates of exergy destruction (power national Compressor Engineering Conjerence at Purdue (Ed. J. F.
wastage) were generated. Added insight was gained into Hamilton and R. Cohen) Purdue University, W. Lafayette, IN,
how heat transfer mechanisms increase the power USA (4 7 Aug 1986) 1 242-253
12 McGovern, J. A. On refrigerant compressors PhD thesis Univer-
consumption of a compressor per unit of exergetic sity of Dublin, Trinity College (1988)
output rate. 13 Kabelac, S. A simple set of equations of state for process cal-
The main limitation of the approach is that very culations and its application to R134a and R152a lnt J Re/'r~g
detailed information is required about the functioning of (1991) 14 217-222
14 Soedel, W. Introduction to Computer Simulation of Positive
a compressor in order to be able to prepare a detailed Displacement Type Compressors Short Course Notes, Purdue
and accurate exergy analysis. However, there is no University, W. Lafayette, IN, USA (1972)
competing technique that can give the same type of 15 Hamilton, J. F. Extensions q[ Mathematical Modelling of
detailed results more easily. Positive Displaeenwnt Type Compressors Short Course Notes,
Exergy analysis techniques have several advantages Purdue University, W. Lafayette, IN, USA (1974)
16 Lin, Z. Modelling temperatures in high speed compressors for
compared with conventional techniques for the analysis the purpose of gas pulsation and valve loss modelling Proc
of shaft power use in compressors. Among the advan- 1992 hlternational Compressor Engineering Conference at Purdue
tages are: (Ed. J. F. Hamilton) Purdue University, W. Lafayette, IN, USA
(14 17Jul 1992) I 1375 1384
17 Reetenwald, G. W. Prediction of heat transfer in compressor
1. Efficiency defects due to heat transfer can be cylinders Proc 1986 International Compressor Engineering Con-
calculated on the same basis as other defects such as ,[erenee at Purdue (Ed. J. F. Hamilton and R. Cohen) Purdue
those due to friction or flow throttling. University, W. Lafayette, IN, USA (4 7 Aug 1986) 1 159 174
2. The efficiency defects are not defined according to 18 Kotas, T. J. The Exergy Method of Thermal Plant Anah'sis
some hypothetical or somewhat arbitrary measure of Butterworths, London (1985)
19 Bejan, A. Advanced Engineering Thermodynamies John Wiley &
what the ideal work of compression should be, such as Sons, New York (1988)
the isentropic, polytropic, or isothermal work. Instead 20 Szargut, J., Morris, D. R., Steward, F. R. Exergy Analysis of
they are defined in terms of the minimum theoretical Thermal, Chemical, and Metallurgical Processes Hemisphere
work necessary to bring the fluid being compressed from Publishing Corporation, New York (1988)
21 Bejan, A. Entropy Generation Through Heat and Fluid Flow John
the actual suction state to the actual discharge state. Wiley & Sons, New York (1982)
3. The exergy destruction rates within a compressor
can be incorporated readily into an analysis of the whole
system, whether this is a refrigeration plant or, for Appendix 1 First-law analysis and mass balance
instance, a pneumatic power installation.
A first-law analysis and a mass balance is carried out on a
system, as shown in Figure 6, to determine how the
energy and the mass change over a small time interval.
References
The analysis is subject to the assumptions listed in the
1 Dossat, R. J. Principles of Refrigeration 2nd edn, SI Version, following section.
John Wiley & Sons, New York (1981)
2 FrancoDaCosta, C. M. Use of a simulation model for theoretical
optimisation analysis of a rolling-piston type compressor Proc
1986 International Compressor Engineering Conference at Purdue Assumptions
(Ed. J. F. Hamilton and R. Cohen) Purdue University, W.
Lafayette, IN, USA (4 7 Aug 1986) 3 824 839
1. It is recognized that the processes occurring within
3 Pandaya, P. N. A simplified procedure for designing hermetic the system can be highly irreversible, involving fluid
compressors Proe 1986 International Compressor Engineering throttling, mixing of incoming streams with the bulk
An exergy method for compressor performance analysis 431
fluid, and heat transfer with significant temperature The new specific internal energy of the bulk fluid in the
differences. The system is not in thermodynamic system after a short time interval is thus given by
equilibrium. For the first-law analysis a temperature Equation (23) and the new mass by Equation (24):
and a pressure of the bulk fluid, Tb~lk and Pbulk
//bulkne,~ =//bulk "4- /)bulk A / (23)
respectively, are defined as the temperature and pressure
of a corresponding equilibrium system having the same mnew = m + t h a t (24)
values of U, V and m.
The new system volume is given by
2. It is assumed that a quasi-equilibrium state exists
over each portion of the system boundary where a fluid Vnew = V + VAt (25)
stream crosses. and the new specific volume of the bulk fluid can be
3. The gravitational potential energy and the kinetic determined as
energy of the fluid streams and the fluid in the system are
assumed negligible. ]/new
Vbulk.... -- (26)
4. It is assumed that there is good mixing of the fluid renew
within the system and that therefore all exit streams can The new bulk fluid temperature, Tbulk,0~, is the equili-
be assumed to have specific internal energy values and brium temperature of fluid that would have the new bulk
other thermodynamic properties that equal the bulk fluid fluid values for the specific internal energy and the
values. specific volume. By using the equation of state of the
5. It is assumed that the bulk fluid pressure is an fluid, an estimate of the new pressure of the bulk fluid
adequate estimate of the pressure on the local boundary can be made:
for evaluating the displacement work. Owing to the inlet
flow restrictions, there can be significant differences Pbulk .... = J'('l~bulk ...... Tbulkn~w) (27)
between the pressures at which the inlet fluid streams
cross the system boundary and the bulk fluid pressure.
6. Owing to the heat transfer resistance of the fluid Comments
boundary layer, there can be significant temperature According to the assumptions underlying the analysis,
differences between the surface of the containment and the new specific internal energy, specific volume,
the bulk fluid. temperature and pressure of the bulk fluid are predicted
7. It is assumed that the bulk fluid temperature is after a short time interval. These data also define the
an adequate estimate of the fluid temperature for thermodynamic state of the fluid in the exit streams.
evaluating the heat transfer rates between the fluid and However, the first-law analysis and mass balance do not
its containment. uniquely define a final equilibrium state of the system.
Because a state of equilibrium does not exist, the
Derivation of equations pressure, temperature, and other properties of the bulk
fluid cannot be regarded as equilibrium state properties
The energy balance takes the following form: of the system. The new mass, internal energy and volume
of the system are uniquely defined, but the entropy is not
v = + O, + w (l+) (see Appendix 2).
i C .]
Therefore
/)bulk = [ Z rhi(cp ri - GTbulk)- Z rh,,(RTbulk)
Z rhi( hi -- '/hulk) -- Z t~le( he -- "bulk) q- ~ O/ -- Pbulk ~ k~
i e j
in
(22)
432 J. A. McGovern and S. Harte
1--(~i QI"}"ZQmx*)
i = S+ ZrrteS-
e i (51)
=7" 1 e !
(50)