SPM Chemistry set 9 paper 3 1

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Answer all questions For
Examiner’
The time suggested to complete Question 1 and Question 2 is 45 minutes s Use

1 An experiment is carried out to study the rate of reaction. A 250 cm 3 conical flask
contained 45 cm3 of sodium thiosulphate solution, Na2S2O3 0.2 mol dm-3 is placed
on a white paper marked with the ‘X’ sign as shown in the figure below.

eye

Sodium thiosulphate
+ sulphuric acid

White paper

“X” sign

5 cm3 sulphuric acid of l.0 mol dm-3 was added to the sodium thiosulphate solution and the
mixture swirled. At the same time the stopwatch was started. The time is taken
as soon as the ‘X’ sign is no longer visible.

The experiment is repeated using the different concentration of sodium thiosulphate.

The table below shows the results of experiment with the different concentration of sodium
thiosulphate solution.

Experiment Concentration of sodium Time(s) 1/time

thiosulphate (mol dm-3) (s-1)
1 0.04 55
2 0.08 48
3 012 42
4 0.16 37
5 0.20 33

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SPM Chemistry set 9 paper 3 2
For
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Examiner’s
Use
(a) (i) Complete the table above and draw the graph of concentration against 1/time on the
graph paper next page. 1(a)(i)

[3 marks]
(ii) Based on the graph in (a)(i), state the relationship between rate of reaction with
concentration.

……………………………………………………………………………………………. 1(a)(ii)
[3 marks]

(b) Predict the time when the ‘X’ sign no longer visible if the same experiment is
repeated by using 0.1 mol dm-3 of sodium thiosulphate. 1(b)

…………………………………………………………………………........………………
[3 marks]

(c) Complete the table below based on the experiment

Name of variables Action to be taken

(i) Manipulated variable: (i) The way to manipulate variable

………………………………………
…………………………………
……………………………………….

(ii) What to observe in the responding

(ii) Responding variable: variable

……………………………………
………………………………
……………………………………

(iii) Controlled variable (iii) The way to maintain the controlled

variable 1(c)
………………………………. ………………………………..

…………………………………

[3 marks] 1(d)

(d) State the hypothesis for the experiment.

…...………..……………………………..............…………………………………………
Total
……….. …………….………………………………………………………………………

[3 marks]

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SPM Chemistry set 9 paper 3 3
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SPM Chemistry set 9 paper 3 4
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2 A student carried out an experiment to investigate the effect of heat on lead(II) nitrate
and zinc carbonate salt. The released gas is passed through into the lime water. For
Examiner’s
Figure 2 below shows the set-up of apparatus for heating lead(II) nitratee and zinc Use
nitrate.

Lead(II) carbonate Zinc carbonate

(white solid)
(white solid)

Earlier experiment Lime water

Heat Heat

Residue (brown solid) Residue (yellow solid)

Final experiment

Heat Heat

a) Complete the following table by stating the observations and related inferences
For
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SPM Chemistry set 9 paper 3 5
4541/3
for heating of lead(II) carbonate salt.

Observations Inferences

i) ……………………………………... i) ………………………………………...

……………………………………... ………………………………………..

ii) …………………………………….. ii) ……………………………………….

…………………………………….. ……………………………………….. 2(a)

[3 marks]

b) State the hypothesis for the experiment.

2(b)
…………………………………………………………………………………………..
[3 marks]

c) Write the chemical equation for the effect of heat on lead(II) carbonate.
2(c)
……………………………………………………………………………………….…
[3 marks]

d) The residue of heating lead(II) carbonate salt is dissolved in the dilute nitric acid.
After that, the solution is added with the excess sodium hydroxide solution.
State the observation.

…………………………………………………………………………………………… 2(d)
……………………………………………………………………………………………
[3 marks]

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SPM Chemistry set 9 paper 3 6
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e) 2.67 g of lead(II) carbonate decomposed completely when it is heated. For
Calculate the number of moles of gas released. Examiner’s
[ Relative molecular mass of lead(II) carbonate, 267] Use

2(e)

[3 marks]
2(f)
f) Name the products when zinc carbonate is heated.

……………………………………………………………………………………………
[3 marks] Total

3
A student is given an ionic compound X and covalent compound Y.

Using the suitable materials and apparatus, plan a labotary experiment to compare
the electrical conductivity between the compounds of X and Y.
Your explaination should include all the followings:

(a) Statement of the problem

(b) All the variables
(c) List of materials and apparatus
(d) Procedure
(e) Tabulation of data
[ 17 marks ]

END OF QUESTION PAPER

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SPM Chemistry set 9 paper 3 7
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SPM Chemistry set 9 paper 3 8
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SPM Chemistry set 9 paper 3 9
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