PROBLEM SOLVING

TECHNIQUES OF
PHYSICAL CHEMISTRY
FOR NEET

BY
JITENDRA HIRWANI

MOLE CONCEPT

ETOOSINDIA
INDIA’S NO. 1 ONLINE COACHING

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INDIA’S NO. 1 ONLINE COACHING J.H. SIR

Basic Exercise
1. Question Based on Moles
1. The volume of a gas in discharge tube is 1.12 × 10–7 ml. at STP. Then the number of molecule of gas in the tube is -
(1) 3.01 × 104 (2) 3.01 × 1015 (3) 3.01 × 1012 (4) 3.01 × 1016
Ans. (3)
2. Vapour density of gas is 11.2 volume occupied by 2.4 gms of this at STP will be -
(1) 11.2 lt (2) 2.24 lt. (3) 22.4 lt. (4) 2.4 lt.
Ans. (4)

A
3. Which of the following contains the least number of molecules ?

I
(1) 4.4 gm CO2 (2) 3.4 gm NH3 (3) 1.6 gm CH4 (4) 3.2 gm SO2
Ans. (4)

D
4. Elements A and B form two compounds B 2 A 3 and B 2A. 0.05 moles of B 2A 3 weight 9.0 gms and
0.10 mole of B2A weight 10 gms atomic weight of A and B are-
(1) 20 and 30 (2) 30 and 40 (3) 40 and 30 (4) 30 and 20
Ans.
5.
(3)
The number of molecule in 4.25 gms of NH3 is -

I N
S
(1) 1.505 × 1023 (2) 3.01 × 1023 (3) 6.02 × 1023 (4) None of these
Ans. (1)
6. 4.4 gm of an unknown gas occupies 2.24 litres of volume at STP. The gas may be :-

Ans.
7.
(4)

O O
(1) N2O (2) CO

Which contains least no. of molecules :–

(1) 1 gm. CO2 (2) 1 gm. N2
(3) CO2

(3) 1 gm. O2
(4) 1 & 3 both

(4) 1 gm. H2
Ans.

8.

Ans.
9.
(1)

(2)
T
If 3.01  1020 molecules are removed from 98 mg. of H2SO4, then the number of moles of H2SO4 left are :–

E
(1) 0.1  10–3 (2) 0.5  10–3 (3) 1.66  10–3 (4) 9.95  10–2

If V ml of the vapours of substance at NTP weight W g. Then molecular wt. of substance is:-

V W 1
(1) (W/V) × 22400 (2) × 22.4 (3) (W - V) × 22400 (4)
W V  2 2 4 00

Ans. (1)
10. Number of oxygen atoms in 8 gms of ozone is -

6.0 2  10 23 6.02  10 23 6.02  10 23

(1) 6.02 × 1023 (2) (3) (4)
2 3 6

Ans. (2)

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INDIA’S NO. 1 ONLINE COACHING J.H. SIR
11. 5.6 lt. of oxygen at STP contains -
(1) 6.02 × 1023 atoms (2) 3.01 × 1023 atoms (3) 1.505 × 1023 atoms (4) 0.7525 × 1023 atoms
Ans. (2)
12. Which of the following contains largest number of atoms ?
(1) 4 gm. of H2 (2) 16 gm. of O2 (3) 28 gm. of N2 (4) 18 gm. of H2O
Ans. (1)
13. The number of atoms present in 16 g of oxygen is
(1) 6.02 × 1011.5 (2) 3.01 × 1023 (3) 3.01 × 1011.5 (4) 6.02 × 1023
Ans. (4)

A
14. Which of the following contains greatest number of oxygen atoms ?

Ans.
15.
(1) 1 g of O
(3) 1 g of O3
(4)
(2) 1 g of O2
(4) all have the same number of atoms

D
The total number of ions persent in 1 ml of 0.1 M barium nitrate Ba(NO3)2 solution is -
I
N
(1) 6.02 × 1018 (2) 6.02 × 1019 (3) 3.0 × 6.02 × 1019 (4) 3.0 × 6.02 × 1018

I
Ans. (3)
16. A person adds 1.71 gram of sugar (C12H22O11) in order to sweeten his tea. The number of carbon atoms added are (mol.

S
mass of sugar = 342)
(1) 3.6 × 1022 (2) 7.2 × 1021 (3) 0.05 (4) 6.6 × 1022

O
Ans. (1)
17. The number of atoms in n mole of gas can be given by :-

O
n  Av.No. Av.No.  Atomicity
(1) n × Av. No. × atomicity (2) (3) (4) None
Atomicity n

T
Ans. (1)
12
C is :-

E
18. Sum of number of protons, electrons and neutrons in 12gm of 6

(1) 1.8 (2) 12.044 × 1023 (3) 1.084 × 1025 (4) 10.84 × 1023
Ans. (3)
19. The actual weight of a molecule of water is -
(1) 18 gm (2) 2.99 × 10–23 gm
(3) both (1) & (2) are correct (4) None of these
Ans. (2)
20. What is the mass of a molecule of CH4 :–

(1) 16 g (2) 26.6  1022 g (3) 2.66  10–23 g (4) 16 NA g

Ans. (3)

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21. Which of the following has the highest mass ?
(1) 1 g atom of C (2) ½ mole of CH4 (3) 10 ml of water (4) 3.011 × 1023 atoms of oxygen
Ans. (1)
22. The weight of 1 mole of a gas of density 0.1784 g/l at NTP is -
(1) 0.1784 g (2) 1 g (3) 4 g (4) Can not be Calculate
Ans. (3)
23. Given that one mole of N2 at NTP occupies 22.4 litre the density of N2 is -
(1) 1.25 g/litre (2) 0.80 g/litre (3) 2.5 g/litre (4) 1.60 g/litre
Ans. (1)

A
24. The number of gm molecules of oxygen in 6.02 × 1023 CO molecules is:-

Ans.
(1) 1 gm molecule
(2)
(2) 0.5 gm molecule

2. Question based on Percentage, Empirical Formula & Molecular Formula

(3) 5 gm molecule

D
(4) 10 gm molecule

I
N
25. Caffine has a molecular weight of 194. It contains 28.9% by mass of nitrogen Number of atoms of nitrogen in one

I
molecule of it -
(1) 2 (2) 3 (3) 4 (4) 5

S
Ans. (3)
26. A giant molecule contains 0.25% of a metal whose atomic weight is 59. Its molecule contains one atom of that metal. Its

O
minimum molecular weight is -

1 00  5 9
(1) 5900 (2) 23600 (3) 11800 (4)
0 .4

Ans.
27.
(2)

TO
Insulin contains 3.4% sulphur. The minimum mol. wt. of insulin is –
(1) 941.176 (2) 944 (3) 945.27 (4) None

E
Ans. (1)
28. A compound of X and Y has equal mass of them. If their atomic weights are 30 and 20 respectively. Molecular formula
of that compound
(its mol. wt. is 120) could be -
(1) X2Y2 (2) X3Y3 (3) X2Y3 (4) X3Y2
Ans. (3)
29. An oxide of sulphur contains 50% of sulphur in it. Its empirical formula is -
(1) SO2 (2) SO3 (3) SO (4) S2O
Ans. (1)
30. A hydrocarbon contains 80% of carbon, then the hydrocarbon is -
(1) CH4 (2) C2H4 (3) C2H6 (4) C2H2
Ans. (3)

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31. Emperical formula of glucose is -
(1) C6H12O6 (2) C3H6O3 (3) C2H4O2 (4) CH2O
Ans. (4)
32. An oxide of metal M has 40% by mass of oxygen. Metal M has atomic mass of 24. The emperical formula of the oxide
(1) M2O (2) M2O3 (3) MO (4) M3O4
Ans. (3)
33. The simplest formula of a compound containing 50% of element X(at wt. = 10) and 50% of element Y(at wt. = 20) is:-
(1) XY (2) X2Y (3) XY2 (4) X3Y
Ans. (2)

A
34. Which of the following compounds has same empirical formula as that of glucose:-

Ans.
35.
(1) CH3CHO
(2)

(1) N2O
(2) CH3COOH

(2) NO
(3) CH3OH

(3) N2O3

D
(4) C2H6

I
A gas is found to contain 2.34 gms of Nitrogen and 5.34 gms of oxygen. Simplest formula of the compound is -
(4) NO2

N
Ans. (4)

I
36. 2.2 gm of a compound of phosphorous and sulphur has 1.24 gms of 'P' in it. Its empirical formula is -
(1) P2S3 (2) P3S2 (3) P3S4 (4) P4S3

S
Ans. (4)
37. On analysis, a certain compound was found to contain iodine and oxygen in the ratio of 254:80. The formula of the

O
compound is :
(At mass I = 127, O = 16)
(1) IO (2) I2O (3) I5O2 (4) I2O5
Ans. (4)

TO
3. Question Based on Stoichiometry

E
38. In a gaseous reaction of the type

aA + bB  cC + dD,

which statement is wrong ?

(1) a litre of A combines with b litre of B to give C and D
(2) a mole of A combines with b moles of B to give C and D
(3) a gm of A combines with b gm of B to give C and D
(4) a molecules of A combines with b molecules of B to give C and D
Ans. (3)
39. Assuming that petrol is octane (C8H18) and has density 0.8 g/ml, 1.425 litre of petrol on complete combustion will
consume.
(1) 50 mole of O2 (2) 100 mole of O2 (3) 125 mole of O2 (4) 200 mole ofO2
Ans. (3)

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40. 9 gms of Al will react, with

3
2Al + O  Al2 O3
2 2

(1) 6 gms O2 (2) 8 gms O2 (3) 9 gms O2 (4) 4 gms O2

Ans. (2)
41. The equation :

3
2Al(S) + O (g)
2 2
 Al2O3(S) shows that :-

A
3 7

I
(1) 2 mole of Al reacts with mole of O2 to produce mole of Al2O3
2 2

D
3
(2) 2gm of Al reacts with g of O2 to produce one mole of Al2O3
2

N
3
(3) 2 gm mole of Al reacts with litre of O2 to produce 1 mole of Al2O3

I
2

S
(4) 2 mole of Al reacts with mole of O2 to produce 1 mole of Al2O3
2

Ans. (4)

42.

Ans. (4)

O O
26 CC of CO2 are passed over red hot coke. The volume of CO evolved is :–
(1) 15 CC (2) 10 CC (3) 32 CC (4) None of these

T
43. If 1/2 moles of oxygen combine with Aluminum to form Al2O3 then weight of Aluminum metal used in the reaction is (Al=
27) –

E
(1) 27 gm (2) 18 gm (3) 54 gm (4) 40.5 gm
Ans. (2)
44. If 8 ml. of uncombined O2 remain after exploding O2 with 4 ml. of hydrogen, the number of ml. of O2 originally were -
(1) 12 (2) 2 (3) 10 (4) 4
Ans. (3)
45. For the reaction A + 2B  C,
5 mole of A and 8 mole of B will produce
(1) 5 mole of C (2) 4 mole of C (3) 8 mole of C (4) 13 mole of C
Ans. (2)

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46. If 1.6 gms of SO2 1.5 × 1022 molecules of H2S are mixed and allowed to remain in contact in a closed vessel until the
reaction
2H2S + SO2  3S + 2H2O,
proceeds to completion. Which of the following statement is true ?
(1) Only 'S' and 'H2O' remain in the reaction vessel. (2) 'H2S' will remain in excess
(3) 'SO2' will remain in excess (4) None
Ans. (2)
47. If 0.5 mol of BaCl2 is mixed with 0.1 mole of Na3PO4, the maximum number of mole of Ba3(PO4)2 that can be formed is:-
(1) 0.7 (2) 0.05 (3) 0.30 (4) 0.10
Ans. (2)
48. 12 lit. of H2 and 11.2 lit. of Cl2 are mixed and exploded. The composition by volume of mixture is–
(1) 24 lit. of HCl (g)
(3) 0.8 lit. H2 and 22.4 lit. HCl (g)
(2) 0.8 lit. Cl2 and 20.8 lit. HCl (g)
(4) 22.4 lit. HCl (g)

I A
D
Ans. (3)
49. 10 ml of gaseous hydrocarbon on combustion give 40 ml of CO2(g) and 50 ml of H2O (vap.). The hydrocarbon is -

N
(1) C4H5 (2) C8H10 (3) C4H8 (4) C4H10

I
Ans. (4)
50. 500 ml. of a gaseous hydrocarbon when burnt in excess of O2 gave 2.5 lt. of CO2 and 3.0 lt. of water vapours under same

S
conditions. Molecular formula of the hydrocarbon is -
(1) C4H8 (2) C4H10 (3) C5H10 (4) C5H12
Ans. (4)
4.
51.

(1) O
Question Based on Equivalent Weight
Molecular weight of tribasic acid is W. Its equivalent weight will be :

O
W
2
(2)
W
3
(3) W (4) 3W

T
Ans. (2)
52. A, E, M and n are the atomic weight, equivalent weight, molecular weight and valency of an element. The correct

E
relation is :

M M
(1) A = E × n (2) A  (3) A  (4) M = A × n
E n

Ans. (1)
53. Sulphur forms two chlorides S2Cl2 and SCl2. The equivalent mass of sulphur in SCl2 is 16. The equivalent weight of
sulphur in S2Cl2 is -
(1) 8 (2) 16 (3) 32 (4) 64
Ans. (3)
54. If equivalent weight of S in SO2 is 8 then equivalent weight of S in SO3 is -

8 2 8 3 2 3
(1) (2) (3) 8 × 2 × 3 (4)
3 2 8

Ans. (1)

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INDIA’S NO. 1 ONLINE COACHING J.H. SIR
55. Which property of an element is not variable :
(1) Valency (2) Atomic Weight (3) Equivalent Weight (4) None
Ans. (2)
56. One gm equivalent of a substance is present in -
(1) 0.25 mole of O2 (2) 0.5 mole of O2 (3) 1.00 mole of O2 (4) 8.00 mole of O2
Ans. (1)
57. In a compound AxBy ,
(1) Mole of A = mole of B = mole of Ax By
(2) eq. of A = eq of B = eq. of AxBy
(3) yx mole of A = yx mole of B = (x + y) × mole of AxBy

A
(4) y × mole of A = y × mole of B
Ans.
58.

Ans.
(2)

(1) 1
(2)
(2) 2 (3) 3 (4) 4
I
0.45 gm of acid (molecular wt. = 90) was exactly neutralised by 20 ml. of 0.5 N NaOH. Basicity of the acid is -

D
N
59. 0.126 g of an acid requires 20 ml of 0.1 N NaOH for complete neutralisation. Eq. wt. of the acid is –

I
(1) 45 (2) 53 (3) 40 (4) 63
Ans. (4)

S
60. 2g of a base whose eq. wt. is 40 reacts with 3 g of an acid. The eq. wt. of the acid is
(1) 40 (2) 60 (3) 10 (4) 80
Ans. (2)

O
61. Equivalent weight of a divalent metal is 24. The volume of hydrogen liberated at STP by 12 gms of the same metal when
added to excess of an acid solution is -
(1) 2.8 litres (2) 5.6 litres (3) 11.2 litres (4) 22.4 litres
Ans.
62.

Ans.
(2)

TO
0.84 gm of a metal carbonate react's exactly with 40 ml of N/2 H2SO4. The equivalent weight of the metal carbonate is -
(1) 84
(3)
(2) 64 (3) 42 (4) 32

63.

Ans.
64.
E
H3PO4 is a tribasic acid and one of its salt is NaH2PO4 What volume of 1M NaOH solution should be added to 12 g
NaH2PO4 to convert it into Na3PO4 ? (at.wt of P=31)
(1) 100 ml
(2)
(2) 200 ml (3) 80 ml (4) 300 ml

The ratio of amount of H2S needed to precipitate all the metal ions from 100 ml of 1M AgNO3 and 100 ml of 1 M CuSO4
is
(1) 1 : 2 (2) 2 : 1 (3) Zero (4) Infinite
Ans. (1)
65. A1 g of an element give A2 g of its oxide. The equivalent mass of the element is –

A2  A1 A2  A1 A1
(1) 8 (2) 8 (3) A  A  8 (4) (A2 – A1) × 8
A1 A2 2 1

Ans. (3)

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66. When an element forms an oxide in which oxygen is 20% of the oxide by mass, the equivalent mass of the element will
be –
(1) 32 (2) 40 (3) 60 (4) 128
Ans. (1)
67. If 1.2 g of a metal displaces 1.12 litre of hydrogen at NTP, equivalent mass of the metal would be –
(1) 1.2 × 11.2 (2) 12 (3) 24 (4) 1.2 + 11.2
Ans. (2)
68. One gm of hydrogen is found to combine with 80 gm of bromine. One gm of calcium (valency = 2) combines with 4 gm
of bromine. The equivalent weight of calcium is –
(1) 10 (2) 20 (3) 40 (4) 80

A
Ans. (2)

I
69. 2.8 gm of iron displaces 3.2 gm of copper from a solution of copper suphate solution. If the equivalent mass of iron is
28, then equivalent mass of copper will be –

D
(1) 16 (2) 32 (3) 48 (4) 64
Ans. (2)

N
70. A metal oxide is reduced by heating it in a stream of hydrogen. It is found that after compete reduction 3.15 gm of the
oxide have yielded 1.05 gm of the metal. We may conclude that.

Ans.
71.
(1) Atomic weight of the metal is 4
(3) Equivalent weight of the metal is 4
(3)

S I(2) Equivalent weight of the metal is 8

(4) Atonic weight of the metal is 8

If m1 gm of a metal A displaces m2g of another metal B from its salt solution and if their equivalent weights are E2 and E1

O
respectively then the equivalent weight of A can be expressed by:-

m1 m2 m1 m2
(1) m × E2 (2) m × E2 (3) m × E1 (4) m × E1

O
2 1 2 1

Ans. (3)

T
72. 14 g of element X combines with 16 g of oxygen. On the basis of this information, which of the following is a correct
statement:-

E
(1) The element X could have an atomic wt. of 7 and its oxide is XO
(2) The element X could have an atomic weight of 14 and its oxide is X2O
(3) The element X could have an atomic weight of 7 and its oxide is X2O
(4) The element X could have an atomic weight of 14 and its oxide is XO2
Ans. (3)
73. 45 gm of acid of mol. wt. 90 neutralised by 200 mL of 5N caustic potash. The basicity of acid is:-
(1) 1 (2) 2 (3) 3 (4) None
Ans. (2)
74. 1.6 gm of Ca and 2.60 gm of Zn when treated with an acid in excess separately, produced the same amount of hydrogen. If
the equivalent weight of Zn is 32.6, what is the equivalent weight of Ca:-
(1) 10 (2) 20 (3) 40 (4) 5
Ans. (2)

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75. 74.5 g of a metallic chloride contains 35.5 g of chlorine. The equivalent mas of the metal is –
(1) 19.5 (2) 35.5 (3) 39.0 (4) 78.0
Ans. (3)

5. Question Based on Calculation of Atomic Weight and Molecular Weight

76. The equivalent weight of an element is 4. It's chloride has a V.D. 59.25. Then the valency of the element is –
(1) 4 (2) 3 (3) 2 (4) 1
Ans. (2)
77. The specific heat of an element is 0.214 cal/gm°C. The approximate atomic weight is -
(1) 0.6 (2) 12 (3) 30 (4) 65
Ans.
78.
(3)

I A
A metal M forms a sulphate which is isomorphous with MgSO4 7H2O. If 0.6538 gm of metals M displaced 2.16 gm of
silver from silver nitrate solution, then the atomic weight of the metal M is

D
(1) 32.61 (2) 56.82 (3) 65.38 (4) 74.58
Ans. (3)

N
79. The carbonate of a metal is isomorphous with MgCO3 and contains 6.091% of carbon. Atomic weight of the metal is

I
nearly -
(1) 48 (2) 68.5 (3) 137 (4) 120

S
Ans. (3)
80. 71 gm of chlorine combines with a metal giving 111 gm of its chloride. The chloride is isomorphous with MgCl2. 6H2O. The atomic
mass of the metal is:-

O
(1) 20 (2) 30 (3) 40 (4) 69
Ans. (3)

O
81. The atomic weight of a metal (M) is 27 and its equivalent weight is 9, the formula of its chloride will be:-
(1) MCl (2) MCl2 (3) M3Cl (4) None

T
Ans. (4)
82. The chloride of a metal contains 71% chlorine by weight and the vapour density of its is 50, the atomic weight of the metal
will be:-

Ans.
83.

Ans.
84.
E
(1) 29
(1)

(1) 25.6
(3)
(2) 58

(2) 36
(3) 35.5

The specific heat of a metal M is 0.25. Its eq. wt. is 12. What is it's correct at wt. :–
(3) 24
(4) 71

(4) 12

Vapour density of a gas is 16. The ratio of specific heat at constant pressure to specific heat at constant volume is 1.4,
then its atomic weight is -
(1) 8 (2) 16 (3) 24 (4) 32
Ans. (2)
85. The weight of substance that displace 22.4 litre air at NTP is :
(1) Molecular Weight (2) Atomic Weight (3) Equivalent Weight (4) All
Ans. (1)

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86. 0.39 gm of a liquid on vapourisation gave 112 ml. of vapour at STP. Its molecular weight is -
(1) 39 (2) 18.5 (3) 78 (4) 112
Ans. (3)
87. In Victor Mayer's method 0.2 gms of a volatile compound on volatilisation gave 56 ml. of vapour at STP. Its molecular
weight is -
(1) 40 (2) 60 (3) 80 (4) 120
Ans. (3)
88. 510 mg of a liquid on vapourisation in Victor Mayer's apparatus displaces 67.2 CCs of dry air (at NTP). The molecular
weight of liquid is -
(1) 130 (2) 17 (3) 1700 (4) 170

A
Ans. (4)

I
89. 0.44 gms of a colourless oxide of nitrogen occupies 224 ml. at STP. The compound is -
(1) N2O (2) NO (3) N2O4 (4) NO2

D
Ans. (1)
90. One litre of a certain gas weighs 1.16 gm at STP. The gas may posibly be -

N
(1) C2H2 (2) CO (3) O2 (4) NH3

I
Ans. (1)
91. The oxide of an element possess the molecular formula M2O3. If the equivalent mass of the metal is 9, the molecular mass

S
of the oxide will be –
(1) 27 (2) 75 (3) 102 (4) 18
Ans. (3)

6.
92.
O
Question Based on Law of Chemical Combination

O
Which one of the following pairs of compounds illustrate the law of multiple proportions ?
(1) H2 O, Na2O (2) MgO, Na2O (3) Na2O, BaO (4) SnCl2, SnCl4

T
Ans. (4)
93. In the reaction N2 + 3H2 2 NH3, ratio by volume of N2, H2 and NH3 is 1 : 3 : 2. This illustrates law of -

E
(1) Definite proportion (2) Multiple proportion (3) Reciprocal proportion (4) Gaseous volumes
Ans. (4)
94. Different proportions of oxygen in the various oxides of nitrogen prove the law of -
(1) Equivalent proportion (2) Multiple proportion (3) Constant proportion (4) Conservation of matter
Ans. (2)
95. Oxygen combines with two isotopes of carbon 12C and 14C to form two sample of carbon dioxide. The data illustrates-
(1) Law of conservation of mass (2) Law of multiple proportions
(3) Law of reciprocal proportions (4) None of these
Ans. (4)
96. The law of conservation of mass holds good for all of the following except -
(1) All chemical reactions (2) Nuclear reactions
(3) Endothermic reactions (4) Exothermic reactions
Ans. (2)
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97. Number of molecules in 100 ml of each of O2, NH3 and CO2 at STP are –
(1) in the order CO2 < O2 < NH3 (2) in the order NH3 < O2 < CO2
(3) the same (4) NH3 = CO2 < O2
Ans. (3)
98. The empirical formula of an organic compound containing carbon and hydrogen is CH2. The mass of one litre of this
organic gas is exactly equal to that of one litre of N2 at same temperature and pressure. Therefore, the molecular formula
of the organic gas is –
(1) C2H4 (2) C3H6 (3) C6H12 (4) C4H8
Ans. (1)
99. Four one litre flasks are seperately filled with the gases hydrogen, helium oxygen and ozone at same room temp. and

A
pressure. The ratio of total number of atoms of these gases present in the different flasks would be -

I
(1) 1 : 1 : 1 : 1 (2) 1 : 2 : 2 : 3 (3) 2 : 1 : 2 : 3 (4) 2 : 1 : 3 : 2
Ans. (3)

D
100. A container of volume V, contains 0.28 gm of N2 gas. If same volume of an unknown gas under similar condition of
temperature and pressure weighs, 0.44 gm, the molecular mass of the gas is

N
(1) 22 (2) 44 (3) 66 (4) 88

I
Ans. (2)
101. A and B are two identical vessels. A contains 15 gm ethane at 1 atm and 298 K. The vessel B contains 75 gm of a gas

S
X2 at same tamperature and pressure. The vapour density of X2 is –
(1) 75 (2) 150 (3) 37.5 (4) 45

O
Ans. (1)
102. Hydrogen combines with chlorine to form HCl. It also combines with sodium to form NaH. If sodium and chlorine also
combine with each other, they will do so in the ratio of their masses as:-

O
(1) 23 : 35.5 (2) 35.5 : 23 (3) 1: 1 (4) 23 : 1
Ans. (1)

T
103. When 100 g of ethylene polymerizes to polythylene according to equation
nCH2 = CH2 -(- CH2 - CH2 -)n-. The weight of polyethylene produced will be:-

Ans.
104.
E
(1)

(2)
n
2
gm (2) 100 gm (3)
1 00
n
gm (4) 100ngm

If law of conservation of mass was to hold true, then 20.8 gm. of BaCl2 on reaction with 9.8 gm. of H2SO4 will produce
7.3 gm. of HCl and BaSO4 equal to :–
(1) 11.65 gm. (2) 23.3 gm. (3) 25.5 gm. (4) 30.6 gm.
Ans. (2)
105. A chemical equation is balanced according to the law of –
(1) Multiple proportions (2) Constant proportions
(3) Reciprocal proportions (4) Conservation of mass
Ans. (4)

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106. Two flask A & B of equal capacity of volume contain NH3 and SO2 gas respectively under similar conditions which flask
has more no. of moles –
(1) A (2) B
(3) Both have same moles (4) None
Ans. (3)

I A
N D
S I
O O
E T

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Analytical Exercise
1. An organic compound having molecular mass 60 is found to contain C=20% , H=6.67% and N=46.67% while rest
is oxygen. On heating it gives NH3 along with a solid residue. The solid residue give violet colour with alkaline
copper sulphate solution. The compound is -
(1) (NH2)2CO (2) CH3CH2CONH2 (3) CH3NCO (4) CH3CONH2
Ans. (1)

2. How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms?
(1) 2.5 × 10–2 (2) 0.02 (3) 3.125 × 10–2 (4) 1.25 × 10–2
Ans. (3)

A
3. Percentage composition of an organic compound is as follows :

C=10.06, H=0.84 , Cl=89.10

(1) CH2 Cl2 (2) CHCl3 (3) CH3Cl

D
Which of the following corresponds to its molecular formula if the vapour density is 60.0

(4) None I
N
Ans. (2)

I
4. A litre of air containing 1% Ar is repetedly passed over hot Cu and hot Mg till no reduction of volume takes place.
The final volume of Ar shall be :

S
(1) 0 ml (2) 230 ml (3) 770 ml (4) 10 ml
Ans. (4)

O
5. The total number of electrons in 4.2 g of N3– ion is (NA is the Avogadro’s number)
(1) 2.1 NA (2) 4.2 NA (3) 3 NA (4) 3.2 NA
Ans. (3)

O
6. The number of mole of nitrogen in one litre of air containing 10% nitrogen by volume, under standard conditions, is
(1) 0.03 mole (2) 2.10 mole (3) 0.186 mole (4) 4.46 × 10–3 mole

T
Ans. (4)
7. Liquid benzene (C6H6) burns in oxygen according to 2C2H6 (l) + 15O2(g)  12CO2 (g) + 6H2O(g)

E
How many litres of O2 at STP are needed to complete the combustion of 39 g of liquid benzene ?
(1) 74 L (2) 11.2 L (3) 22.4 L (4) 84 L
Ans. (4)
8. 1 mol of KClO3 is thermally decomposed and excess of aluminum is burnt in the gaseous product. How many moles of
Al2O3 are formed ?
(1) 1 (2) 2 (3) 1.5 (4) 3
Ans. (1)
9. The amount of zinc required to produce 1.12 ml of H2 at STP on treatment with dilute HCl will be :
(1) 65 g (2) 0.065 g (3) 32.5 × 10–4 g (4) 6.5 g
Ans. (3)
10. Volume of CO2 obtained at STP by the complete decomposition of 9.85 g Na2CO3 is
(1) 2.24 litre (2) Zero (3) 0.85 litre (4) 0.56 litre
Ans. (2)

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11. One litre of CO2 is passed through red hot coke. The volume becomes 1.4 litres at same temperature and pressure. The
composition of products is
(1) 0.8 litre of CO2 and 0.6 litre of CO (2) 0.7 litre of CO2 and 0.7 litre of CO
(3) 0.6 litre of CO2 and 0.8 litre of CO (4) 0.4 litre of CO2 and 1.0 litre of CO
Ans. (3)

M M
12. When 100 ml of H2SO4 is mixed with 500 ml of NaOH then nature of resulting solution and normality of excess
10 10
of reactant left is

N N N N
(1) Acidic, (2) Basic, (3) Basic, (4) Acidic,
5 5 20 10

A
Ans. (3)

I
13. Mole fraction of solvent in aqueous solution of NaOH having molality of 3 is
(1) 0.3 (2) 0.05 (3) 0.7 (4) 0.95

D
Ans. (4)
–1
14. Concentrated aqueous sulphuric acid is 98% H2SO4 by mass and has a density of 1.80 gmL . Volume of acid required
to make one litre of 0.1 M H2SO4 solution is

N
(1) 16.65 mL (2) 22.20 mL (3) 5.55 mL (4) 11.10 mL

I
Ans. (3)
15. Number of significant figures in 6.62 × 10–34.

S
(1) Two (2) Three (3) Four (4) One
Ans. (2)
Ammonia gas is passed into water, yielding a solution of density 0.93 g/cm3 and containing 18.6% NH3 by weight. The

O
16.
mass of NH3 per cc of the solution is
(1) 0.17 g/cm3 (2) 0.34 g/cm3 (3) 0.51 g/cm3 (4) 0.68 g/cm3

O
Ans. (1)
17. A certain amount of a metal whose equivalent mass is 28 displaces 0.7 L of H2 at S.T.P. from an acid hence mass of the

T
element is
(1) 1.75 g (2) 0.875 g (3) 3.50 g (4) 7.00 g
Ans. (1)

E
18. Number of Fe atoms in 100 g Haemoglobin if it contains 0.33% Fe. (Atomic mass of Fe = 56)
(1) 0.035 × 1023 (2) 35 (3) 3.5 × 1023 (4) 7 × 108
Ans. (1)
19. An organic compound containing C and H gave the following analysis C = 40%, H = 6.7%. Its empirical formula would
be
(1) CH4 (2) CH2O (3) C2H4O2 (4) C2H4
Ans. (2)
20. The number of electrons in 1.6 g of CH4 is approximately
(1) 25 × 1024 (2) 1.5 × 1024 (3) 6 × 1023 (4) 3.0 × 1024
Ans. (3)
21. 6.025 × 1020 molecules of acetic acid are present in 500 ml of its solution. The concentration of solution is
(1) 0.002 M (2) 10.2 M (3) 0.012 M (4) 0.001 M
Ans. (1)

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22. How many litre of oxygen at STP is required to burn 60 g C2H6
(1) 22.4 L (2) 11.2 L (3) 22.4 × 7 L (4) 8.5 L
Ans. (3)
23. For the formation of 3.65 g of HCl gas, what volume of hydrogen gas and chlorine gas are required at NTP conditions?
(1) 1 L, 1 L (2) 1.12 L, 2.24 L (3) 3.65 L, 1.83 L (4) 1.12 L, 1.12 L
Ans. (4)
24. Specific volume of cylindrical virus particle is 6.02 × 10–2 cc/gm whose radius and length are 7 Å and 10 Å respectively.
If NA = 6.02 × 1023, find molecular weight of virus.
(1) 15.4 kg/mol (2) 1.54 × 104 kg/mol (3) 3.08 × 104 kg/mol (4) 3.08 × 103 kg/mol
Ans. (1)
25. The crystalline salt Na2SO4.xH2O on hearting loses 55.9% of its mass and becomes anhydrous. The formula of crystal-

A
line salt is

I
(1) Na2SO4.5H2O (2) Na2SO4.7H2O (3) Na2SO4.2H2O (4) Na2SO4.10H2O
Ans. (4)
26. The atomic mass of an element is 27. If valency is 3, the vapour density of the volatile chloride will be:-

D
(1) 66.75 (2) 6.675 (3) 667.5 (4) 81
Ans. (1)

N
27. Two elements X (at-mass 16) and Y (at-mass 14) combine to form compounds A, B and C. The ratio of different masses

I
of Y which combines with a fixed mass of X in A, B and C is 1 : 3 : 5. If 32 parts by mass of X combines with 84 parts by
mass of Y in B, then in C 16 parts by mass of X will combine with :
(1) 14 parts by mass of Y (2) 42 parts by mass of Y

S
(3) 70 parts by mass of Y (4) 84 parts by mass of Y
Ans. (3)
28. 1 L of a hydrocarbon weighs as much as one litre of CO2 Under similar conditions. Then the molecular formula of the

O
hydrocarbon is -
(1) C3H8 (2) C2H6 (3) C2H4 (4) C3H6
Ans. (1)

O
29. There are two oxides of sulphur. They contain 50% and 60% of oxygen respectively by weights. The weights of
sulphur which combine with 1 gm of oxygen in the ratio of -

T
(1) 1 : 1 (2) 2 : 1 (3) 2 : 3 (4) 3 : 2
Ans. (4)

E
30. Number of HCl molecules present in 10 ml of 0.1 M solution is :
(1) 6.022 × 1023 (2) 6.023 × 1022 (3) 6.022 × 1021 (4) 6.022 × 1020
Ans. (4)
31. The volume of a gas at 00C and 700 mm pressure is 760 CC. The no. of molecules present in this volume is
(1) 1.88 × 1022 (2) 6.022 × 1023 (3) 18.8 × 1023 (4) 18.8 × 1022
Ans. (1)
32. Rearrange the following (I to IV) in the order of increasing masses and choose the correct answer. (Atomic masses : N = 14,
O = 16, Cu = 63)
I 1 molecule of oxygen II 1 atom of Nitrogen III 1 × 10-10 × (gm molecular weight of oxygen)
IV 1 × 10-10 × (gm atomic weight of copper)
(1) II < I < III < IV (2) IV < III < II < I (3) II < III < I < IV (4) III < IV < I < II
Ans. (1)
33. The number of moles of carbon dioxide which contain 8 gm of oxygen is –
(1) 0.5 moles (2) 0.20 moles (3) 0.40 moles (4) 0.25 moles
Ans. (4)
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34. If 224 ml of a triatomic gas has a mass of 1g at 273 K and 1 atm pressure, then the mass of one atom is –
(1) 8.30 × 10–23 gm (2) 2.08 × 10–23 gm (3) 5.53 × 10–23 gm (4) 6.24 × 10–23 gm
Ans. (3)
35. 22.4 litre of water vapour at NTP, When condensed to water occupies an approximate volume of -
(1) 18 litre (2) 1 litre (3) 1 ml (4) 18 ml
Ans. (4)
36. 0.01 mole of iodoform (CHI3) reacts with Ag to produce a gas whose volume at NTP is
2CHI3 + 6Ag  C2H2 + 6Ag I(s)
(1) 224 ml (2) 112 ml (3) 336 ml (4) None of these
Ans. (2)

A
37. The minimum quantity in grams of H2S needed to precipitate 63.5 g of Cu2+ will be nearly :

I
Cu+2 + H2S  CuS + H2
(1) 63.5 g (2) 31.75 g (3) 34 g (4) 20 g
Ans. (3)

D
38. 2.76 g of silver carbonate on being strongly heated yields a residue weighing –
Ag2 CO3 2Ag + CO2 + ½ O2

N
(1) 2.16 g (2) 2.48 g (3) 2.32 g (4) 2.64 g

I
Ans. (1)
39. The volume of gas at NTP produced by 100 gm of CaC2 with water:-

S
CaC2 + 2H2O  Ca(OH)2 + C2H2
(1) 70 litre (2) 35 litre (3) 17.5 litre (4) 22.4 litre
Ans. (2)
40.

Ans. O
90 ml. of pure dry O2 is subjected to silent electric discharge. If only 10% of it is converted to O3, volume of the mixture
of gases (O2 and O3) after the reaction will be ------ and after passing through turpentine oil will be .......

O
(1) 84 ml and 78 ml
(4)
(2) 81 ml and 87 ml (3) 78 ml and 84 ml (4) 87 ml and 81 ml

T
41. Element 'A' reacts with oxygen to form a compound A 2 O 3 . If 0.359 gram of 'A' react to give
0.559 gram of the compound, atomic weight of 'A' will be :–
(1) 51 (2) 43.08 (3) 49.7 (4) 47.9

E
Ans. (2)
42. 1.12 mL of a gas is produced at STP by the action of 4.12 mg of alcohol ROH with methyl magnesium iodide. The
molecular mass of alcohol is –
R – OH + CH3MgI  CH4 + Mg(OR)I
(1) 16 (2) 41.2 (3) 82.4 (4) 156.0
Ans. (3)
43. CaCO3 is 90% pure. Volume of CO2 collected at STP when 10 gms of CaCO3 is decomposed is -
(1) 2.016 litres (2) 1.008 litres (3) 10.08 litres (4) 20.16 litres
Ans. (1)
44. 50 gm CaCO3 will react with ...... gms of 20% HCl by weight .
(1) 36.5 gm (2) 73 gm (3) 109.5 gm (4) 182.5 gm
Ans. (4)

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ASSERTION & REASON EXERCISE

These questions consist of two statements each, printed as Assertion and Reason. While answering these Questions
you are required to choose any one of the following four responses.
A. If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.
B. If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.
C. If Assertion is True but the Reason is False.
D. If both Assertion & Reason are False.
NA NA
1. Assertion :– 16 gm each of O2 and O3 contains and atoms respectively
2 3

A
Reason :– 16 gm O2 and O3 contains same no. of molecules.

I
Ans. (D)
2. Assertion :– Carbon and oxygen combined together only in one fixed ratio.

D
Reason :– In a chemical compound the elements are combined together in a fixed ratio.
Ans. (D)
3. Assertion :– The mass of the products formed in a reaction depends upon the limiting reactant.

N
Reason :– Limiting reactant reacts completely in the reaction.

I
Ans. (A)
4. Assertion :– Volume occupied by 1mol H2O(l) is equals to 22400 cc. at NTP.
Reason :– 1 mol of any substance occupies 22.4 lit volume at N.T.P.

S
Ans. (D)
5. Assertion :– At same temp & pressure 1lit O2 and 1lit SO2 contains equal no. of molecules.
Reason :– Acc. to avogadros hypothesis equal volume of all gases under similar condition of temp and pressure

O
contains equal no. of molecules.
Ans. (A)
6. Assertion :– 44 gm of CO2 28 gm of CO have same volume at STP.

O
Reason :– Both CO2 and CO are formed by C and oxygen.
Ans. (B)
7. Assertion :– Equivalent wt. of Cu in both CuO and Cu2O is 31.75

T
Reason :– Equivalent wt. of an element is constant.
Ans. (D)

E
8. Assertion :– On compressing a gas to half the volume, the number of moles is halved.
Reason :– Number of moles present decreases with decrease is volume.
Ans. (D)
9. Assertion :– Law of conservation of mass hold good for nuclear reaction.
Reason :– Law states that mass can be neither created nor destroyed in a chemical reaction.
Ans. (D)
10. Assertion :– The balancing of chemical equations is based on law of conservation of mass.
Reason :– Total mass of reactants is equal to total mass of products.
Ans. (A)
11. Assertion :– Pure water obtained from different sources such as, river, well, spring, sea etc. always contains hydrogen
and oxygen combined in the ratio 1 : 8 by mass
Reason :– A chemical compound always contains elements combined together in same proportion by mass, it was
discovered by French chemist, Joseph Proust (1799).
Ans. (A)

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