2020irds BC
2020irds BC
ROADMAP
FOR
DEVICES AND SYSTEMS
2020 EDITION
BEYOND CMOS
THE IRDS IS DEVISED AND INTENDED FOR TECHNOLOGY ASSESSMENT ONLY AND IS WITHOUT REGARD TO ANY
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Table of Contents
Acknowledgments .............................................................................................................................. vi
1. Introduction .................................................................................................................................. 1
1.1. Scope of Beyond-CMOS Focus Team .............................................................................................. 1
1.2. Difficult Challenges ............................................................................................................................ 2
1.3. Nano-information Processing Taxonomy........................................................................................... 4
2. Emerging Memory Devices ........................................................................................................... 4
2.1. Memory Taxonomy ............................................................................................................................ 5
2.2. Emerging Memory Devices ................................................................................................................ 6
2.3. Memory Selector Device .................................................................................................................. 17
2.4. Storage Class Memory .................................................................................................................... 20
3. Emerging Logic and Alternative Information Processing Devices............................................... 27
3.1. Taxonomy ........................................................................................................................................ 27
3.2. Devices for CMOS Extension .......................................................................................................... 28
3.3. Beyond-CMOS Devices: Charge-Based.......................................................................................... 32
3.4. Beyond-CMOS Devices: Alternative Information Processing .......................................................... 36
4. Emerging Device-Architecture Interaction................................................................................... 41
4.1. Introduction ...................................................................................................................................... 41
4.2. Analog Computing ........................................................................................................................... 43
4.3. Probabilistic Circuits......................................................................................................................... 57
4.4. Reversible Computing...................................................................................................................... 59
4.5. Device-Architecture Interaction: Conclusions/Recommendations ................................................... 64
5. Beyond CMOS Devices for More-Than-Moore Applications ....................................................... 64
5.1. Emerging Devices for Security Applications .................................................................................... 64
6. Emerging Materials Integration ................................................................................................... 68
6.1. Introduction and Scope .................................................................................................................... 68
6.2. Challenges ....................................................................................................................................... 69
6.3. Technology Requirements and Potential Solutions ......................................................................... 70
6.4. Emerging/Disruptive Concepts and Technologies........................................................................... 73
6.5. Conclusions and Recommendations ............................................................................................... 74
7. Assessment ................................................................................................................................ 74
7.1. Introduction ...................................................................................................................................... 74
7.2. NRI Beyond-CMOS Benchmarking ................................................................................................. 75
7.3. Archive of ITRS ERD Survey-Based Assessment........................................................................... 77
8. Summary ................................................................................................................................ 80
9. Endnotes/References.................................................................................................................. 81
List of Figures
Figure BC1.1 Relationship of More Moore, Beyond CMOS, and Novel Computing Paradigms
and Applications (Courtesy of Japan beyond-CMOS group) .................................... 1
Figure BC2.1 Taxonomy of Emerging Memory Devices ................................................................. 6
Figure BC2.2. Taxonomy of Memory Select Devices .................................................................... 17
Figure BC2.3 Comparison of Performance of Different Memory Technologies ............................ 23
Figure BC3.1 Taxonomy of Options for Emerging Logic Devices ................................................ 27
Figure BC4.1. Conventional vs. Alternative Computing Paradigms .............................................. 42
Figure BC4.2 A Resistive Memory Crossbar 𝐴𝐴𝐴𝐴 = 𝑏𝑏 Solver is Illustrated ..................................... 45
Figure BC4.3 A Spiking CNN for Gesture Recognition with Local Learning ................................. 47
Figure BC4.4 One Generalized Instantiation of a Photonic MVM unit, with Wavelength
Multiplexed Inputs and Outputs and a Coupler-based Tunable Array.
Reproduced from931. ............................................................................................... 54
Figure BC4.5 Energy Dissipation per Stage vs. Frequency in an Adiabatic CMOS Shift
Register .................................................................................................................. 61
Figure BC4.6 Energy dissipation of RQFP and irreversible AQFP 1-b full adders ....................... 62
Figure EMI1 Emerging Material Integration Promotes the Advancement of Existing
Technologies .......................................................................................................... 69
Figure EMI2 An Example of the Role of Machine Learning in the Multiscale Simulation ............ 74
Figure BC7.1 (a) Energy versus Delay of a 32-bit ALU for a Variety of Charge- and Spin-
based Devices; (b) Energy versus Delay per Memory Association Operation
Using Cellular Neural Network (CNN) for a Variety of Charge- and Spin-based
Devices1156 .............................................................................................................. 76
Figure BC7.2 (a) Survey of Emerging Memory Devices and (b) Survey of Emerging Logic
Devices in 2014 ERD Emerging Logic Workshop (Albuquerque, NM) ................... 78
Figure BC7.3 Comparison of Emerging Memory Devices Based on 2013 Critical Review .......... 78
Figure BC7.4 Comparison of Emerging Logic Devices Based on 2013 ITRS ERD Critical
Review: (a) CMOS Extension Devices; (b) Charge-based Beyond-CMOS
Devices; (c) Non-charge-based Beyond-CMOS Devices ....................................... 79
List of Tables
Table BC1.1 Beyond CMOS Difficult Challenges .......................................................................... 3
Table BC2.1 Emerging Research Memory Devices—Demonstrated and Projected
Parameters ............................................................................................................... 5
Table BC2.2 Experimental Demonstrations of Vertical Transistors in Memory Arrays ............... 18
Table BC2.3 Benchmark Select Device Parameters ................................................................... 18
Table BC2.4a Experimentally Demonstrated Two-terminal Memory Select Devices .................... 20
Table BC2.4b Experimentally Demonstrated Self-selecting Memory Devices (self-rectifying) ..... 20
Table BC2.5 Target Device and System Specifications for SCM ................................................ 22
Table BC2.6 Potential of Current Prototypical and Emerging Research Memory Candidates
for SCM Applications .............................................................................................. 22
Table BC2.7. Likely Desirable Properties of M (Memory) Type and S (Storage) Type Storage
Class Memories ...................................................................................................... 26
Table BC3.1a MOSFETS: Extending MOSFETs to End of Roadmap .......................................... 27
Table BC3.1b Charge-based Beyond CMOS: Non-conventional FETs and Other Charge-
based Information Carrier Devices ......................................................................... 27
Table BC3.1c Alternative Information Processing Devices ........................................................... 28
Table BC4.1 Metrics for Analog Capacitive Vector-Matrix Multiply (VMM) ICs ........................... 54
Table BC4.2 Comparison of Some Electrical Oscillators for Computing ..................................... 56
Table EMI1 Near-term Difficult Challenges................................................................................ 69
Table EMI2 Long-term Difficult Challenges ............................................................................... 70
Table EMI3 Materials for Transistor Scaling and Integration ..................................................... 71
Table EMI4 Materials for Lithography and Patterning................................................................ 71
Table EMI5 Interconnect Materials ............................................................................................ 71
Table EMI6 Heterogeneous Integration, Assembly and Packaging Materials ........................... 72
Table EMI7 Emerging Research Materials Needs for Outside System Connectivity ................. 72
Table EMI8 Emerging Materials for Memory ............................................................................. 72
Table EMI9 Emerging Materials for Memory Select .................................................................. 72
Table EMI10 Emerging Materials for Advanced and Beyond-CMOS Logic Devices ................... 72
Table EMI11 Spin Devices versus Materials ............................................................................... 73
Table EMI12 Spin Material Requirements and Properties ........................................................... 73
Table EMI13 Metrology Needs and Challenges for Emerging Research Materials ..................... 73
Table EMI14 Modeling and Simulation ........................................................................................ 74
Table EMI15 Summary of Potentially Disruptive Emerging Research Materials Application
Opportunities .......................................................................................................... 74
ACKNOWLEDGMENTS
Sapan Agarwal Shy-Jay Lin
Brad Aimone Tsu-Jae King Liu
Hiro Akinaga Matthew Marinella
Otitoaleke Akinola Bicky A. Marque
Mustafa Badaroglu Rivu Midya
Gennadi Bersuker Yoshiyuki Miyamoto
Christian Binek Johannes Muller
Geoffrey Burr Azad Naeemi
Leonid Butov Mitchell A. Nahmias
Kerem Camsari Emre Neftci
Gert Cauwenberghs Mike Niemier
An Chen Dmitri Nikonov
Winston Chern Yutaka Ohno
Supriyo Datta Chenyun Pan
John Dallesasse Ferdinand Peper
Shamik Das Shriram Ramanathan
Erik DeBenedictis Mingyi Rao
Peter Dowben Shashi Paul
Tetsuo Endoh Paul R. Prucnal
Ben Feinberg Titash Rakshit
Thomas Ferreira de Lima Arijit Raychowdhury
Akira Fujiwara Sayeef Salahuddin
Elliot Fuller Shintaro Sato
Michael Frank Michael Schneider
Paul Franzon Bhavin J. Shastri
Michael Fuhrer Xia Sheng
Mike Garner Takahiro Shinada
Chakku Goplan Urmita Sikder
Bogdan Govoreanu Greg Snider
Cat Graves John-Paul Strachan
Kohei Hamaya Dimitri Strukov
Masami Hane Naoyuki Sugiyama
Jennifer Hasler Tarek Taha
Yoshihiro Hayashi Alexander N. Tait
Toshiro Hiramoto Shinichi Takagi
D. Scott Holmes Norikatsu Takaura
Sharon Hu Tsutomu Teduka
Francesca Iacopi Yasuhide Tomioka
Danielle Ilmeni Wilman Tsai
Jean Anne Incorvia Tohru Tsuruoka
Engin Ipek Zhongrui Wang
Satoshi Kamiyama R. Stanley Williams
Kiyoshi Kawabata Justin Wong
Asif Khan Dirk Wouters
Hajime Kobayashi Patrick Xiao
Suhas Kumar Kojiro Yagami
Ilya Krivorotov J. Joshua Yang
Xiuling Li Noboyuki Yoshikawa
Xiang (Shaun) Li Victor Zhirnov
BEYOND CMOS
1. INTRODUCTION
1.1. SCOPE OF BEYOND-CMOS FOCUS TEAM
Dimensional and functional scaling 1 of CMOS is driving information processing 2 technology into a broadening spectrum of new
applications. Scaling has enabled many of these applications through increased performance and complexity. As dimensional
scaling of CMOS will eventually approach fundamental limits, several new information processing devices and
microarchitectures for both existing and new functions are being explored to extend the historical integrated circuit scaling
cadence. This is driving interest in new devices for information processing and memory, new technologies for heterogeneous
integration of multiple functions, and new paradigms for system architecture. This chapter, therefore, provides an IRDS
perspective on emerging research device technologies and serves as a bridge between conventional CMOS and the realm of
nanoelectronics beyond the end of CMOS scaling.
An overarching goal of this chapter is to survey, assess, and catalog viable emerging devices and novel architectures for their
long-range potential and technological maturity and to identify the scientific/technological challenges gating their acceptance by
the semiconductor industry as having acceptable risk for further development. This chapter also surveys beyond-CMOS devices
for more than Moore (MtM) applications, e.g., hardware security.
This goal is accomplished by addressing two technology-defining domains: 1) extending the functionality of the CMOS platform
via heterogeneous integration of new technologies (“More Moore”), and 2) stimulating invention of new information processing
paradigms (“Beyond CMOS”). The relationship between these domains is schematically illustrated in Figure BC1.1. Novel
computing paradigms and application pulls (e.g., big data, IoT, artificial intelligence, autonomous systems, exascale computing)
introduce higher performance and efficiency requirements, which is increasingly difficult for the saturating More Moore
technologies to fulfill. Beyond-CMOS technologies may provide the required devices, processes, and architectures for the new
era of computing.
Figure BC1.1 Relationship of More Moore, Beyond CMOS, and Novel Computing Paradigms and
Applications (Courtesy of Japan beyond-CMOS group)
The chapter is intended to provide an objective, informative resource for the constituent nanoelectronics communities pursuing:
1) research, 2) tool development, 3) funding support, and 4) investment. These communities include universities, research
institutes, and industrial research laboratories; tool suppliers; research funding agencies; and the semiconductor industry. The
potential and maturity of each emerging research device and architecture technology are reviewed and assessed to identify the
1
Functional Scaling: Suppose that a system has been realized to execute a specific function in a given, currently available, technology. We say that system
has been functionally scaled if the system is realized in an alternate technology such that it performs the identical function as the original system and offers
improvements in at least one of size, power, speed, or cost, and does not degrade in any of the other metrics.
2 Information processing refers to the input, transmission, storage, manipulation or processing, and output of data. The scope of the BC Chapter is restricted to
most important scientific and technological challenges that must be overcome for a candidate device or architecture to become a
viable approach.
The chapter is divided into five sections: 1) emerging memory devices, 2) emerging logic and alternative information processing
devices, 3) emerging device-architecture interaction, 4) beyond-CMOS devices for More-than-Moore applications, and 5)
emerging materials integration. The former IRDS Emerging Research Materials (ERM) chapter is rolled into this chapter as
section 6 renamed to “emerging materials integration”. Some detail is provided for each entry regarding operation principles,
advantages, technical challenges, maturity, and current and projected performance. The chapter also discusses applications and
architectural focus combining emerging research devices offering specialized, unique functions as heterogeneous core processors
integrated with a CMOS platform technology. This represents the nearer term focus of the chapter, with the longer-term focus
remaining on discovery of an alternate information processing technology beyond digital CMOS.
1.2. DIFFICULT CHALLENGES
1.2.1. INTRODUCTION
The semiconductor industry is facing some difficult challenges related to extending integrated circuit technology to new
applications and to beyond the end of CMOS dimensional scaling. One class relates to propelling CMOS beyond its ultimate
density and functionality by integrating a new high-speed, high-density, and low-power memory technology onto the CMOS
platform. Another class is to extend CMOS scaling with alternative channel materials. The third class is information processing
technologies substantially beyond those attainable by CMOS using an innovative combination of new devices, interconnect, and
architectural approaches for extending CMOS and eventually inventing a new information processing platform technology. The
fourth class is to extend ultimately scaled CMOS as a platform technology into new domains of functionalities and application,
also known as “more than Moore”. The fifth class is to bridge the gap between novel devices and unconventional architectures
and computing paradigms. These difficult challenges are summarized in Table BC1.1.
1.2.2. DEVICE TECHNOLOGIES
Difficult challenges gating development of beyond-CMOS devices include those related to memory technologies, information
processing or logic devices, and heterogeneous integration of multi-functional components, a.k.a. More-than-Moore (MtM) or
Functional Diversification.
One challenge is the need of a new memory technology that combines the best features of current memories in a fabrication
technology compatible with CMOS process flow and that can be scaled beyond the present limits of SRAM and FLASH. This
would provide a memory device fabrication technology required for both stand-alone and embedded memory applications. The
ability of an MPU to execute programs is limited by interaction between the processor and the memory, and scaling does not
automatically solve this problem. The current evolutionary solution is to increase MPU cache memory, thereby increasing the
floor space that SRAM occupies on an MPU chip. This trend eventually leads to a decrease of the net information throughput. In
addition to auxiliary circuitry to maintain stored data, volatility of semiconductor memory requires external storage media with
slow access (e.g., magnetic hard drives, optical CD, etc.). Therefore, development of electrically accessible non-volatile memory
with high speed and high density would initiate a revolution in computer architecture. This development would provide a
significant increase in information throughput beyond the traditional benefits of scaling when fully realized for nanoscale CMOS
devices.
A related challenge is to sustain scaling of CMOS logic technology. One approach to continuing performance gains as CMOS
scaling matures in the next decade is to replace the strained silicon MOSFET channel (and the source/drain) with an alternate
material offering a higher potential quasi-ballistic-carrier velocity and higher mobility than strained silicon. Candidate materials
include strained Ge, SiGe, a variety of III-V compound semiconductors, and carbon materials. Introduction of non-silicon
materials into the channel and source/drain regions of an otherwise silicon MOSFET (i.e., onto a silicon substrate) is fraught with
several very difficult challenges. These challenges include heterogeneous fabrication of high-quality (i.e., defect free) channel
and source/drain materials on non-lattice matched silicon, minimization of band-to-band tunneling in narrow bandgap channel
materials, elimination of Fermi level pinning in the channel/gate dielectric interface, and fabrication of high-κ gate dielectrics on
the passivated channel materials. Additional challenges are to sustain the required reduction in leakage currents and power
dissipation in these ultimately scaled CMOS gates and to introduce these new materials into the MOSFET while simultaneously
minimizing the increasing variations in critical dimensions and statistical fluctuations in the channel (source/drain) doping
concentrations.
The industry is now addressing the increasing importance of a new trend of functional diversification, where added value to
devices is provided by incorporating functionalities that do not necessarily scale according to “Moore's Law”. In this chapter, an
“Beyond-CMOS devices for More-than-Moore Applications” section covers unconventional applications of existing and novel
technologies. The section currently covers emerging devices for hardware security and will be expanded in future update.
Discover and reduce to practice new device technologies and primitive-level architecture to
provide special purpose optimized functional cores (e.g., accelerator functions)
heterogeneously integrable with CMOS.
Extend ultimately scaled CMOS as a platform technology Provide added value by incorporating functionalities that do not necessarily scale according
into new domains of functionalities and application (“more to “Moore’s Law”.
than Moore, MtM”). Heterogeneous integration of digital and non-digital functionalities into compact systems
that will be the key driver for a wide variety of application fields, such as communication,
automotive, environmental control, healthcare, security, and entertainment.
A longer-term challenge is invention and reduction to practice of a manufacturable information processing technology addressing
“beyond CMOS” applications. For example, emerging research devices might be used to realize special purpose processor cores
that could be integrated with multiple CMOS CPU cores to obtain performance advantages. These new special purpose cores
may provide a particular system function much more efficiently than a digital CMOS block, or they may offer a uniquely new
function not available in a CMOS-based approach. Solutions to this challenge beyond the end of CMOS scaling may also lead to
new opportunities for such an emerging research device technology to eventually replace the CMOS gate as a new information
processing primitive element. A new information processing technology must also be compatible with a system architecture that
can fully utilize the new device. A non-binary data representation and non-Boolean logic may be required to employ a new device
for information processing. These requirements will drive the need for new system architectures. The requirements and
opportunities correlating emerging devices and architectures are discussed in the “Emerging Device-Architecture Interaction”
section.
3
Including a particular approach in this section does not in any way constitute advocacy or endorsement. Conversely, not including a particular concept in this
section does not in any way constitute rejection of that approach. This listing does point out that existing research efforts are exploring a variety of basic memory
mechanisms.
dimensional array, and it is essential to consider the performance of memory cells in the context of this array architecture. A
memory cell in such an array can be viewed as being composed of two fundamental components: the ‘storage node’ and the ‘select
device’, the latter of which allows a given memory cell in an array to be addressed for read or write. Both components impact
scaling limits for memory. For several emerging resistance-based memories, the storage node can, in principle, be scaled down
below 10 nm, 1 and the memory density will be limited by the select device. Planar transistors (e.g. FET or BJT) are typically used
as select devices. In a two-dimensional layout using in-plane select FETs the cell layout area is Acell=(6-8)F2. In order to reach
the highest possible 2-D memory density of 4F2, a vertical select transistor can be used. Table BC2.3 shows several examples of
vertical transistor approaches. Another approach to obtaining a select device with a small footprint is a two-terminal nonlinear
device, e.g. a diode. Table BC2.4 displays benchmark parameters required for a 2-terminal select device, and Table BC2.5
summarizes the operating parameters for several candidate 2-terminal select devices.
Storage-class memory (SCM) describes a device category that combines the benefits of solid-state memory, such as high
performance and robustness, with the archival capabilities and low cost per bit of conventional hard-disk magnetic storage. Such
a device requires a non-volatile memory technology that can be manufactured at a very low cost per bit. Table BC2.6 lists a
representative set of target specifications for SCM devices and systems, which are compared against benchmark parameters offered
by existing technologies (HDD, NAND Flash, and DRAM). Two columns are shown, one for the slower S-class Storage Class
Memory, and one for fast M-class SCM, as described in Section 2.4. These numbers describe the performance characteristics that
will likely be required from one or more emerging memory devices in order to enable the emerging application space of Storage
Class Memory. Table BC2.7 illustrates the potential for storage-class memory applications of a number of prototypical memory
technologies (Table BC2.1) and emerging research memory candidates (Table BC2.2). The table shows qualitative assessments
across a variety of device characteristics, based on the target system parameters from Table BC2.6. These tables are discussed in
more detail in Section 2.4.
with diameters above 10 nm, 9 whereas the use of shape-anisotropy induced PMA from elongated ferromagnetic pillars may
further the scaling of STT-MRAM below 10 nm diameter. 10 Lastly, STT-MRAM with higher density to replace DRAM is still
an open area for research. Stacking of STT-MRAM dies with logic or memory dies using through silicon vias, 11,12 and high
density 3D integration of STT-MRAM using selector-MTJ crossbar architecture 13 are two high potential approaches.
2.2.1.2. SPIN-ORBIT TORQUE
Spin-orbit torque (SOT)-driven magnetization switching recently emerges as an alternative write mechanism beyond STT for
SRAM-like cache-level applications. Though at rather early stage of research, sub-ns SOT writing has been demonstrated at
current density of 20-40 MA/cm2, 14,15 compared with 3-10 ns switching of STT-MRAM at a current density of 7 MA/cm2.5,16(see
Table BC2.1). A SOT-MRAM cell consists of a magnetic tunnel junction (MTJ) with its free layer (FL) sitting on top of a strip
of material with large spin-orbit coupling (SOC), such as heavy metal 17,18. When current flows through this long strip of SOT
material, spin-polarized current emerges and diffuses into the adjacent FL. Like the STT case, the spin-polarized current exerts a
damping-like spin torque on the ferromagnetic layer, thus switching the FL orientation. As the write path is separated from the
read path, a much larger read voltage can increase read speed. The major advantage of SOT over STT is that unlike STT where
the filtered spin-polarized current is smaller than the charge current, the SOT efficiency (spin-polarized current over charge
current) can be larger than one in the SOT case. 19 From a physics perspective, multiple mechanisms have been found to contribute
to this large damping-like SOT, including spin Hall effect (SHE)17, Rashba-Edelstein effect18, and spin-momentum locking from
topological protected electronic states19. Most experimental work has discovered a damping-like SOT in the in-plane transverse
direction with respect to the current flow direction. However, there also exists a field-like SOT in many of the experimental
works, which acts on the free layer like a static magnetic field with a fixed orientation.
There are three types of SOT-MRAM configurations, i.e., in-plane MTJ with easy axis oriented along the current direction (type
X), in-plane MTJ with easy axis oriented orthogonal to the current direction (type Y), and perpendicular MTJ (type Z). Note that
only type Y can achieve field-free switching, while both type X and Z require the breaking of symmetry for deterministic
switching. Experimentally, 0.5-ns switching with a current density of 40 MA/cm2 has been demonstrated in a 100 x 400 nm2 type
X MTJ, which will lead to 51-µA, 0.3-V, and 8-fJ write performance when scaled down to a channel width of 50 nm.14 Another
work shows 0.5-ns switching with a current density of 18 MA/cm2 in 30 x 190 cm2 type Y MTJ with a write error rate (WER) of
10-6.15 For perpendicular MTJ (type Z), research has shown 0.5-ns and 220-fJ write operation with a current density of 180
MA/cm2 of a 60 nm perpendicular MTJ with endurance up to 1011 and WER down to 10-5. Field-free switching is realized in this
work by using an elongated biasing ferromagnet deposited on top of the SOT-MTJ. 20
Lowering the write energy while maintaining sub-ns switching speed is the main challenge to push SOT-MRAM into cache-level
applications. A multitude of novel SOT materials beyond traditional heavy metal are being intensively investigated for higher
SOT efficiency. Several new research directions include heavy metal alloys 21 , topological insulator and semimetal 22 , 23 ,
antiferromagnets 24,25, and complex oxides 26,27. The need of high SOT efficiency is especially critical for type Z as it inherently
shows a larger switching current than type X and Y 28. Second, SOT-MRAM suffers from a large cell size due to the three-terminal
configuration needed to perform separate write and read functions. 29 A two-terminal perpendicular SOT-MRAM has been
demonstrated by increasing the density of the current flowing in-plane in the SOT underlayer while suppressing that of the current
flowing perpendicular in the MTJ 30. Meanwhile, the scheme of multiple SOT-MTJs sharing one single SOT write line can
partially alleviate the density disadvantage of SOT-MRAM. 31 Third, a tradeoff exists between writing speed and field-free
switching. For type Y, the FL aligning to the transverse direction does not experience any SOT; thus, an initial perturbation of
the FL away from the easy axis is required for fast switching. A large field-like SOT or Oersted field due to SOT current can
provide this perturbation. 32 For type X and Z, a maximal SOT exists as the FL is aligned perpendicular to the spin current direction,
thus enabling high-speed switching. There have been several approaches to break the symmetry for realizing field-free type X
and Z switching, such as lateral structural and shape-induced asymmetry28,33,34, use of interlayer exchange coupling 35, exchange
bias24, and dipolar external magnetic field 36. Meanwhile, new studies show field-free switching of type Z MTJ using a damping-
like SOT with perpendicular polarization arising from crystalline materials with broken in-plane symmetry 37 and interfaces with
SOC 38,39. Last, the scalability of all three SOT types remains an open question. Type X and Y scaling are challenging due to
variations in MTJ shape, while type X and Z scaling face obstacles in implementing field-free switching at scaled nodes.
2.2.1.3. VOLTAGE-CONTROLLED MAGNETIC ANISOTROPY
Contrary to current-driven writing mechanisms such as STT and SOT, voltage-assisted writing using electron-mediated voltage-
controlled magnetic anisotropy (VCMA) effect 40 enables lower write energy (~fJ) and smaller cell size due to reduced current,
and therefore joule heating and select transistor size.(see Table BC2.1) A VCMA-MTJ is almost the same as an STT-MTJ, except
that the tunnel barrier MgO thickness is increased to suppress the tunneling current and enhance the capacitive characteristics of
the tunnel barrier. 41 When a voltage is applied across the VCMA-MTJ, charge accumulation or depletion takes place at the
FL/barrier interface, leading to a change of electron occupancies among different Fe 3d orbitals. Because the interfacial
perpendicular magnetic anisotropy (PMA) originates from the Fe 3d and O 2p orbitals hybridization, this change of electron
occupancy results in the modulation of PMA and thus the energy barrier between the two FL stable states.40,42,43 The VCMA
effect is, therefore, a useful handle to reduce the energy barrier during the write operation, while the energy barrier is restored for
retention purposes after writing by simply removing the VCMA bias.
There are two main types of VCMA-assisted magnetization switching schemes. First, removal of the entire energy barrier by the
VCMA effect facilitates a precessional motion of the FL along an in-plane bias field direction (built-in or applied). By precise
timing of the VCMA pulse width, the FL can switch from one state to the other in half the precession period. 44 Research has
shown switching energy of 6 fJ/bit, switching speed of 0.5 ns, write voltage of 1.96 V, current density of 0.3 MA/cm2 with a WER
of 10-5 using perpendicular MTJs with a VCMA coefficient of 30 fJ/V-m. 45 Another recent work further shows 0.15 ns
precessional switching of 120 nm perpendicular VCMA-MTJ at a write voltage of 3.06 V, a current density of 0.3 MA/cm2 with
a WER of <10-6. 46 Second, the VCMA effect can be utilized to reduce the write energy in in-plane and perpendicular SOT-MTJs
further.31,47 Research has demonstrated VCMA-assisted (VCMA bias of 1 V) SOT writing of 30 x 80 nm2 to 50 x 120 nm2 in-
plane MTJ using 2-ns pulse with a current density of 12 MA/cm2 with a high endurance of 1013 write cycles. 48 Another work
shows 5-ns 62 𝜇𝜇A SOT current writing (VCMA bias of 1.2 V) of 30 x 80 nm2 in-plane MTJ with WER <10-8 and endurance over
1012 cycles, the VCMA coefficient in this device is about 100 fJ/V-m. 49
The major roadblock of VCMA in either precessional switching or assisting SOT switching is the rather small VCMA coefficient
of around 100 fJ/V-m, as defined by the interfacial PMA change under given electric field applied at the MgO barrier. 50 Though
~fJ-level write performance has already been demonstrated, further scaling of MTJs requires higher VCMA coefficient (>300
fJ/V-m) for advanced nodes cache or storage applications. 51 New materials research using Cr and Ir-based crystalline MTJs have
shown a high VCMA coefficient of up to 1000 fJ/V-m. 52,53 Meanwhile, detailed chemical and structural characterizations of
VCMA-MTJs recently reveal that metal-oxides at the FL/MgO interface lead to large VCMA effect. 54 Another challenge facing
VCMA is the longer read time because the thicker MTJ tunnel barrier leads to a much larger MTJ resistance. One way to resolve
this is using a large read voltage (VDD) which has reverse polarity compared with the write voltage to increase read speed and
reduce read disturbance. 55 In terms of the precessional switching scheme, another significant challenge is the non-deterministic
nature of the writing process, which results in large WER and narrow write pulse window. The use of pulse shape engineering
and reverse biasing can partially help 56,57, whereas combining VCMA with deterministic writing mechanisms such as type Y
SOT47 and STT 58 may solve this challenge.
2.2.2. OXIDE-BASED RESISTIVE MEMORY (OXRAM)
The redox-based nanoionic memory operation is based on a change in resistance of a MIM structure caused by ion (cation or
anion) migration combined with redox processes involving the electrode material or the insulator material, or both. 59,60,61 Three
classes of electrically induced phenomena have been identified that involve chemical effects, i.e., effects which relate to redox
processes in the MIM cell. In these three ReRAM classes, there is a competition between thermal and electrochemical driving
forces involved in the switching mechanism. Two major types of ReRAM exist: i) those based on metal oxide (OxRAM), which
involve oxygen ions/vacancies motion, and ii) conducting bridge-based RAM (CBRAM), which involves metal cation motion.
This section covers the three categories of OxRAM, and conducting bridge-based RAM (CBRAM) is covered in the following
section. Beyond CMOS has sub-categorized oxide ReRAM (OxRAM) based on the electrical switching type (bipolar versus
unipolar) and whether a conductive filament is formed in the device. Most of the literature fits into the three categories: bipolar
filamentary, unipolar filamentary, and nonfilamentary. 62
In most cases, the conduction is of a filamentary nature, and hence a one-time formation process is required before the bipolar
switching can be started. If this process can be controlled, memories based on this switching process can be scaled to very small
feature sizes. The switching speed is limited by the ion transport. If the active distance over which the anions or cations move is
small (in the <10 nm regime) the switching time can be below few nanoseconds, down to sub-nanoseconds range. 63,64 Many of
the finer details of the ReRAM switching mechanisms are still under investigation. Developing an understanding of the physical
mechanisms governing switching of the redox memory is a key challenge for this technology. Nevertheless, recent experimental
demonstrations of scalability, 65 retention, 66 and endurance 67 are encouraging.
2.2.2.1. BIPOLAR-FILAMENTARY OXRAM
Bipolar filamentary OxRAM is the most common form of oxide-based ReRAM. At any given defect density, the number of
current paths through the dielectric, in the virgin or fresh state, is proportional to the device area, and consequently the total
current is area dependent. In addition, the current magnitude tends to fluctuate from device to device due to randomness of the
initial distribution of vacancies/ions. However, cell area dependency is eliminated when the current is dominated by a single
conductive path, called conductive filament (CF)). The CF provides an ultimate scaling advantage since it is only limited to the
active filament size, which potentially may be as small as a few nm.
A one-time forming process is required for most types of OxRAM devices to create a conduction filament across the dielectric
layer linking the electrodes. A stable preferential conduction path is known to form through oxide films subjected to electrical
stress: under the applied voltage, a current abruptly increases at some point in time indicating the occurrence of a dielectric
breakdown (BD) resulting in the formation of a CF. During the forming process, electrons injected from the cathode electrode
may lead to their trapping at defect sites in the dielectric material inducing chemical bonds breakage and the generation of anion
vacancies (Oxygen or Nitrogen). 68 ,69
Post-forming switching events between high and low conductive states, which are operated at significantly smaller voltages, are
believed to modify the filament conductivity by rupturing/recovering a section of the filament (primarily in the vicinity of the
metal electrode) or changing the filament cross-section. The specific mechanisms in filament-type switching depend on the
materials (dielectric and metal electrodes) employed in the fabrication of the memory cell and may include more than one type
of a conduction mode.The operation of these devices involves redox reactions of the dielectrics sandwiched between two
electrodes. 70,71 , 72 The dielectrics are mostly comprised of one or a few layers of insulating materials 73 (e.g., oxide AlOx, HfOx,
TaOx, TiOx, WOx, ZrOx, oxynitrides AlOxNy, or nitrides including AlNx and CuNx). TaOx and HfOx are the leading candidates
among the aforementioned dielectrics, due to their superior performance (e.g. endurance) and CMOS compatibility.
Since the demonstration of a single crosspoint HfOx device with a 10 nm dimension in 2011 74, scaling to a smaller size has been
achieved by employing a sidewall electrode in a 1×3 nm2 cross-sectional HfOx-based OxRAM device with reasonable
performance in terms of both endurance and retention. 75 Up to 1012 cycles has been demonstrated with Zr:SiOx sandwiched by
graphene oxide layers. 76 Some of the filament-based metal-oxide RRAMs implemented with metal electrodes and a variety of
fab-friendly transition-metal-oxides (i.e., HfO2, ZrO2, TiO2, etc.) and nitride devices demonstrated sub-nanosecond, 77,78 switching
with high (up to 1012 cycles) endurance 79 and retention of more than 10 years. Extrapolated retention at 85°C by stressing TaOx
in the temperature range from 300°C to 360°C is estimated to be years with an activation energy of 1.6 eV. 80 Reliable switching
operations have been demonstrated at 340°C with devices based on 2D layered heterostructures (e.g., graphene/MoS2-
81
xOx/graphene).
Unconventional electrodes such as graphene have been paired with HfOx dielectrics to yield a low power consumption, a
write/erase energy of 230 fJ per bit for a single programming transition. 82 Pt/BMO((Bi, Mn)Ox)/Pt structured OxRAM device
was used to demonstrate an even lower write/erase energy per transition, of the order of 3.8 pJ/bit for read and 20 pJ/bit for write
operation. 83
Large scale integration of OxRAM switching based on 1T1R schemes has been carried out by Toshiba, Panasonic and IMEC. In
2013, Toshiba announced the 32 Gb RRAM chip integrated with 24 nm CMOS. 84 In 2014, Panasonic and IMEC demonstrated
the encapsulated cell structure with an Ir/Ta2O5/TaOx/TaN stack on a 2-Mbit chip at the 40 nm node. In addition, passive
integration of 1S1R scheme has been reported by Crossbar on a 4-Mbit chip, but the material stack of the OxRAM switch has not
been revealed. 85 Ultra-fast (down to 100 ps), compliance-free, low power (< pJ) switching was demonstrated with 1R devices
using TiN/HfO2/TiN stack. 86
A number of technical challenges hampering the commercialization of OxRAM still remain despite the significant advancements
made in the field. One of the main challenges is the fact that the switching currents for devices based on the currently most mature
materials (e.g., HfOx and TaOx) are still too high (above tens of µA) for large arrays. Apart from that, the filament formation and
rupture processes are stochastic in nature, which leads to variation in switching parameters like the voltage and resistance
distribution of the switching. This is especially detrimental to certain applications such as multilevel cell memory.
2.2.2.2. BIPOLAR NON-FILAMENTARY OXRAM
The Bipolar Non-Filamentary OxRAM is a non-volatile bipolar resistive switching device composed of one or more oxide layers.
One layer is a conductive metal oxide (CMO), which is usually a perovskite such as PrCaMnO3 or Nb:SrTiO3. 87 In contrast to
Unipolar and Bipolar Filamentary OxRAM devices – typically based on binary oxides such as TiOx, NiOx, HfOx, TaOx or
combinations thereof—the resistance change effect of the Bipolar Non-Filamentary OxRAM is uniform. Depending on the
materials choice and structure the current is conducted across the entire electrode area, or at least across the majority of this area.
A forming step to create a conductive filament is not needed. Non-volatile memory functionality is achieved by the field-driven
redistribution of oxygen vacancies close to the contact resulting in a change of the electronic transport properties of the interface
(e.g. by modifying the Schottky barrier height). Oxygen can be exchanged between layers due to the exponential increase in ion
mobility at high fields. Low current densities, uniform conduction, and bipolar switching imply that substantial self-heating is
not involved. Typical ROFF to RON ratios are on the order of 10.
One class of the Bipolar Non-Filamentary OxRAM includes a deposited ion conductive tunnel layer (Tunnel ReRAM), e.g. ZrO2.
Here, a redistribution of oxygen vacancies causes a change of the electronic transport properties of the tunnel barrier. Low current
densities and area scaling of device currents enable ultra-high-density memory applications. Set, reset, and read currents scale
with device area. In addition, set, reset, and write currents are controlled by the tunnel oxide and hence, can be adjusted by
changing the tunnel barrier thickness. Both set and reset IV characteristics are highly nonlinear enabling true 1R cross-point
architectures without the need for an additional selector device for asymmetric arrays up to 512×4096 bit. No external circuitry
is needed for current control during set operation. A continuous transition between on and off states allow straightforward multi-
level programming without the need for precise current control.
The typical thickness of the CMO is greater than 5 nm and the tunnel barrier is typically 2–3 nm. If a tunnel barrier is present,
the adjacent electrode needs to be an inert metal such as Pt to prevent oxidation during operation. For the case of PCMO cell, low
deposition temperatures of less than 425°C of all layers enables back end integration schemes.
Currently the technology is in the research and development stage. Depending on material system and structure cycling endurance
over 10,000 cycles and up to a billion cycles as well as data retention from days to months at 70°C has been achieved on single
devices. 88 , 89 , 90 Within the Bipolar Non-Filamentary OxRAM device family the Tunnel OxRAM is probably the furthest
developed technology. Single device functionality is demonstrated down to 30 nm. Set, reset, and read currents scale with area
and tunnel oxide thickness facilitating sub µA switching currents with read currents in the order of a few nA to a few 100 nA.
BEOL integration schemes and CMOS/OxRAM functionality are verified for 200 nm devices on 200 mm CMOS wafers. True
cross-point array (1R) functionality utilizing the self-selecting non-linear device IV characteristics and transistor-less array
operation is demonstrated on fully decoded 4kb true cross-point arrays (1R) build on top of CMOS base wafers. SLC and MLC
operations are demonstrated within 4kb arrays.
Major challenges to be resolved towards the commercialization of Bipolar Non-filamentary OxRAM are, in order of priority,
a) improvement of data retention, b) the integration of conductive metal oxide layer (perosvkites) via ALD or the replacement of
CMO by more process-friendly materials, and c) the replacement of Pt electrodes by a non-reactive, more process-friendly
electrode material.
The most important issue is the improvement of retention and the “voltage-time dilemma.” This dilemma hypothesizes physical
reasons as to why it is difficult in a particular device and material system to simultaneously obtain a long retention, with short
low read voltages, and fast switching at moderate write voltages. 91 Even though the exact mechanism is still under investigation
there is a common agreement that oxygen vacancies are moved by the external electric field resulting in different resistance states
of the memory cell. Vacancy drift at room temperature is possible due to a field dependent mobility, which increases exponentially
with field at fields of 1 MV/cm and larger. However, current models based on a field-dependent mobility underestimate the
experimentally observed ratio between set/reset times and data retention indicating that the mechanism is only partly understood.
More theoretical work is needed to understand the kinetics of programming and retention mechanisms. Once understood,
materials need to be chosen to maximize the ratio between set/reset and retention times. The goal is to set/reset devices at low
temperatures and meet retention requirement of 10 years at 70°C, 85°C, and 125°C, depending on the application. A multi-layer
ReRAM structure (HfO2/A2O3) was shown to improve retention by suppressing tail bit failure due to decreased oxygen ion
diffusivity. 92
Memory cells using conductive perovskite material as an electrode have proven to show excellent device-to-device and wafer-
to-wafer reproducibility with yields close to 100%. One of the reasons might be that perovskites display high oxygen vacancy
mobilities and tolerate large variations in the oxygen content while maintaining its crystal structure. From an integration
perspective, ALD is the method of choice for advanced technology nodes and future 3D integration schemes. Key issues are the
control of the metals ratio (perovskites are ternary or quaternary oxides), the control of the oxygen stoichiometry in the cell,
oxygen loss in the presence of reducing atmospheres like H2, as well as high temperatures required for crystallization. Eventually
a migration to binary oxides with comparable properties might be required to resolve the integration challenges.
Platinum or other noble electrodes display superior device performance over fab-friendly electrodes like TiN. On the one hand it
was observed that the oxidation resistance of TiN is not sufficient to prevent oxidation and the formation of TiO2 during operation.
On the other hand, inert electrodes such as Pt or Pt-like metals are difficult to integrate. New oxidation-resistant electrodes and
Pt alternatives are required to reduce integration challenges and enable 3D integration schemes.
2.2.2.3. UNIPOLAR FILAMENTARY OXRAM
Note that unipolar filamentary OxRAM has been removed from the memory tracking tables, due to lack of research over the
period covered by this Beyond CMOS chapter. However, this text section has been maintained to provide background on earlier
unipolar OxRAM work, due to the close relationship and key differences with bipolar OxRAM.
Unipolar OxRAM is another resistive switching device, also referred to in the literature as thermochemical memory (TCM)59 due
to its primary switching mechanism. The device structure consists of a top electrode metal/insulator/bottom electrode metal
(MIM) structure. Typical insulator materials are metal-oxides such as NiOx, HfOx, etc., and common metal electrodes include
TiN, Pt, Ni, and W. In general, the device can be asymmetric (i.e. top electrode material differs from bottom electrode material),
but unlike other types of ReRAM, asymmetry is not required.
The first reported resistive switching in these MIM structures after 2000 was unipolar in nature (see reference 93 for the first
integrated device work that put metal oxide ReRAM in the spotlight). Unipolar is defined as switching where the same polarity
of voltage needs to be applied for changing the resistance from high to low (SET) or from low to high (RESET). Note that in the
general case, polarity is still important (e.g. repeatable SET/RESET switching only occurs for one polarity of voltage with respect
to one of the electrodes 94). Only in symmetric structures (e.g. Pt/HfO2/Pt), nonpolar behavior can be obtained, where SET and
RESET are occurring irrespective of voltage polarity. 95
The switching process is generally understood as being filamentary, where conduction is caused by a filamentary arrangement of
defects (e.g. oxygen vacancies) throughout the thickness of the insulator film. As with other filamentary OxRAM devices, an
initial high voltage “electroforming” step is required to form the conduction filament, while subsequent RESET/SET switching
is thought to occur through local breaking/restoration of this conduction path.
The unipolar character of the switching indicates that drift (of charged defects) in an electric field plays a less important role (than
it does in bipolar switching resistive memory), but that thermal effects probably dominate. 96,97 On the other hand, polarity effects
indicate anodic oxidation (e.g. at Ni or Pt electrodes) is responsible for RESET.94 These findings suggest a thermo-chemical
“fuse” model for describing this unipolar switching. It has been shown for different MIM structures that both unipolar and bipolar
switching mechanisms can be induced, depending on the operation conditions. 98,99,100,101 An interesting work reporting on the
Scaling Effect on Unipolar and Bipolar Resistive Switching of Metal Oxides was published. 102
A unipolar switching device is seen as advantageous for making scaled memory arrays, as it only requires a selector device as
simple as a diode that can be stacked vertically with the memory device in a dense crossbar array.93 In addition, the use of a single
program voltage polarity greatly simplifies the circuitry.
On the other hand, as has been exemplified in mixed mode (unipolar/bipolar) operation of memory cells, there are important
trade-offs between the unipolar and bipolar switching modes. On the positive side, unipolar switching mode typically shows a
higher ON/OFF resistance ratio. On the negative side, unipolar switching is typically obtained at higher switching power (higher
currents) than the bipolar mode, and also endurance is much more limited. As a result, major research and development work on
resistive memories has shifted towards bipolar switching mechanisms. Yet, some interesting recent development work has been
reported. 103,104,105,106,107,108 One paper103 shows an endurance of over 106 cycles with a resistive window of over 5 orders of
magnitude (and a reset current ~1mA). Others104,105,106 demonstrate how unipolar RRAM elements can be integrated in a very
simple way in an existing CMOS process (known as Contact ReRAM technology). This may provide a very inexpensive
embedded ReRAM technology. Recently, integration unipolar ReRAM with a 28 nm CMOS process was reported.106 The key
attributes were a small cell size (0.03 µm2), switching voltage of less than 3V, RESET current of less than 60 µA, endurance >
106 cycles, and short SET and RESET times of 500 ns and 100 µs, respectively. One paper107 shows 4Mb array data using this
same Contact-RRAM technology, fabricated using a 65 nm CMOS process. To accommodate the low logic VDD process, an on-
chip charge pump was applied. Set and reset voltages are less than 2V. Another paper108 reports on a novel approach using thermal
assisted switching to lower the switching current.
As stated above, large OFF to ON resistance ratio is an attribute of unipolar switching. The low resistance window and large
intrinsic variability of bipolar switching OxRAM may require complex and time-consuming switching operation schemes (e.g.
the so-called verify scheme). Further study of the stability and control of the large resistance window (at low current levels), are
required to determine if unipolar OxRAM variability can be improved, potentially even allowing for multi-level cell operation.
Major challenges to be resolved are the high switching current that seems inherent to the unipolar operation mode. Reset currents
less than 100 µA are achieved but need further reduction to less than 10 µA.104,105,106 Recently, a possible solution incorporating
thermally assisted switching has been presented.108
2.2.3. CONDUCTING BRIDGE MEMORY
Conductive Bridge RAM (CBRAM), also referred to as Programmable Metallization Cell (PMC), and electrochemical
metallization cells, is a device which utilizes electrochemical control of nano-scale quantities of metal in thin dielectric films or
solid electrolytes to perform the resistive switching operation. 109 The basic CBRAM cell is a metal–ion conductor–metal (MIM)
system consisting of an electrode made of an electrochemically active material such as Ag, Cu or Ni, an electrochemically inert
electrode such as W, Ta, or Pt, and a thin film of solid electrolyte sandwiched between both electrodes. 110 Large, non-volatile
resistance changes are caused by the oxidation and reduction of the metal ions by the application of low bias voltages. Key
attributes are low voltage, low current, rapid write and erase, good retention and endurance, and the ability for the storage cells
to be physically scaled to a few tens of nm. The material class for the dielectric film or the solid electrolyte is comprised of oxides,
higher chalcogenides (including glasses), semiconductors, as well as organic compounds including polymers.
CBRAM is a strong emerging memory candidate primarily due to scalability (~10 nm), 111 ultra-low energy operations due to fast
read, write and erase times, and low voltage requirements. 112 Maturity of the CBRAM technology development can be assessed
by the fact that many companies are either shipping products based on CBRAM or are in advanced stages of commercialization.
Recent publications show CBRAM technology application in various markets including SSDs, 113 embedded NVM, 114 and serial
interface non-volatile memory replacement. 115 In 2012, a CBRAM-based serial NVM replacement product became commercially
available. 116 In 2014, a 16 GB CBRAM array based on a CuTe CBRAM cell was demonstrated. 117,118 Such efforts are critical to
identify core technology challenges 119 and fundamental materials and mechanisms. 120 Novel applications such as reconfigurable
switch 121 and synaptic elements in Neuromorphic systems 122 based on CBRAM are also gaining prominence and are expected to
expand the application base for this technology. An atom-switch-based field-programmable gate array is also released using Cu
conduction bridge in a new polymer solid electrolyte. 123
As with other filamentary ReRAM technologies, CBRAM is challenged by bit level variability,119 the random nature of reliability
failure such as retention or endurance, and random telegraph noise potentially contributing to read disturbs. 124 Such issues require
large populations of bits to be studied, which suggests collaboration between universities and industry may be beneficial. Focus
on fundamental understanding and simultaneously addressing some mitigation path such as error correction schemes, redundancy
and algorithm development would enable closing the technology gap.
Engineering hurdles include the availability and integration of new materials used in CBRAM at advanced process nodes
especially when there could be issues with compatibility of thermal budgets and process tooling. The availability of integrated
array level information suggests that some of these challenges are being resolved in the recent years.115,121 Active participation
from semiconductor equipment vendors and material suppliers would assist in overcoming manufacturing hurdles rapidly.
2.2.4. MACROMOLECULAR (POLYMER) MEMORY
Macromolecular memory is a category of memory which focuses on structures incorporating a layer of polymer - the polymer
perhaps containing nano-particles, small molecules and nanoparticles - that is sandwiched between two metal electrodes. This
structure allows two different stable electrical states controlled through an external electrical voltage. These two stable electrical
states, which are often called ON and OFF states (or 0 and 1), exhibit resistive, ferroelectric or capacitive natures according to
the physical properties of the sandwich. The first fully-organic memory devices, based on nano-composite (a blend of poly-vinyl-
phenol (PVP) and Bucky-ball (C60)) was presented in Materials Research Society in 2005. 125 Around the same time, memory
devices using gold nano-particles and 8-hydroxyquinoline, dispersed in a polystyrene matrix, were also demonstrated. 126 Since
then, the interest to use an admixture of nano-particles, small molecules and polymers in the manufacture of electronic memory
devices, is on the rise. Non-volatile memory effects with a non-destructive read have been reported for a surprisingly large variety
of polymeric/organic materials and blends of polymers with nanoparticles and molecules. Unlike the other four categories, this
category is based on the material used in the switching layer(s) of the cell, but the mechanism is not specified. Both bipolar and
unipolar (all pulses of the same polarity) switching have been demonstrated. Macromolecular ReRAM may have a mechanism
placing it in one of the four main ReRAM categories listed above. However, the other mechanisms behind the electrical bistability,
such as capacitive and ferroelectric, have also been reported.
Depending on the structure of the polymer, a variety of mechanisms can be operative. For polymers supporting transport of
inorganic ions, formation of metallic filaments is reported. In semiconducting polymers supporting ion transport, dynamic doping
due to migration of inorganic ions occurs. Ferroelectric polymers in blends with semiconducting material give rise to a memory
effect-based modification of charge injection barriers by the ferroelectric polarization. However, for many polymeric materials,
the origin of the resistive switching is not well understood. To date no specific design criteria for the polymer are known, although
clear correlations between memory effect and electronic properties of the polymer have been demonstrated.
Stability of the memory states at high temperatures (85°C, 2 × 104 s) has been demonstrated. 127,128 Programming at very low
power (70 nW) has been realized.128 Assuming a 15 ns switching time for the same system, one might achieve a write energy of
6 × 10-15 J/bit. Furthermore, low programming voltages have been realized: +1.4 and -1.3 V for the two states with good retention
time (>104 s). 129 Downscaling of polymer resistive memory cell to the 100 nm length scale has been reported. 130 At this length
scale, integration of memory cells into an 8 × 8 array could be shown. Polymer memory cells on a flexible substrate have been
shown. 131 For amorphous carbon, downscaling to nanometer sized cells has been published (1 × 103 nm2). 132 Using carbon
nanotubes as macromolecular electrodes and aluminum oxide as interlayer, isolated, non-volatile, rewriteable memory cells with
an active area of essentially 36 nm2 have been achieved, requiring a switching power less than 100 nW, with estimated switching
energies below 10 fJ per bit. 133 With regards to the mechanism of operation, extensive work on the class of polyimide polymers
has shown clear correlations between electronic structure of the polymer and memory effects, although a comprehensive picture
for the operation has not yet emerged. A number of studies have indicated an active role of the interface between macromolecular
material and (native) oxide layers in the operation of the memory involving charge trapping. 134,135 The recent and past studies
show resistive, 136 capacitive (charge storage, based on electric dipole formation) 137, 138 and ferroelectric behavior 139 of such
devices. Thus, there is a need to open up a further discussion on the right pathway to realize such memory.
In macromolecular memory, a large variety of operation mechanisms can be operative. A key research question concerns
distinguishing different mechanisms and evaluating the potential and possibilities of each mechanism. A second subsequent step
would be to identify model systems for each mechanism. Having such a model system then provides a possibility to benchmark
the operation of the macromolecular materials. These research steps would be crucial for establishing and securing the
collaboration of the chemical industry; for design, synthesis and development of the next generation macromolecular materials
for memory applications, clear guidelines on the required structural and electronic properties of the macromolecular material are
needed. For instance, memory effect originating for metallization and formation of metallic filaments requires macromolecular
materials that support transport of ions and have appropriate internal free volume for ion conduction. Here the field could benefit
from interaction with the field of polymer batteries. Ferroelectric polymers have been shown to give rise to resistive memory 140
and could benefit enormously from development of new macromolecular polymeric materials with combined ferroelectric
switching and semiconducting structural units. Finally, a number of macromolecular memories involve oxide layers. Here
mutually beneficial interaction with the (research) community on metal oxide ReRAM switching could spring, because at the
macromolecular / oxide interface trap states can be engineered by tuning the electron levels of the macromolecular material.
In a nutshell, this area certainly needs an attention from theoretical physicists, materials scientists, chemists and device engineers.
There are a number of issues that need to be addressed before we can embark on extending these devices to the real world. Such
issues involve understanding of the electrical bistability mechanism in nano-composite (there are a number of contradicting
theories), maintaining the difference between low and high conduction states for a longer period time by ensuring the stability of
the high and low states, selecting environmentally friendly materials required for fabrication of nano-composite/polymer
materials, and developing a cost-effective methodology for the fabrication of devices.
It is not possible to replace silicon-based memory devices with polymers in the foreseeable future. However, there are a number
of other applications where “cheap” electronic memory devices can play a vital role. For example, nano-composite based
memory devices can be directly printed on medicine bottles/packages and the information about the patient and schedule of taking
medicine can be stored on the printed device.
2.2.5. FERROELECTRIC MEMORY
Coding digital memory states by the electrically alterable polarization direction of ferroelectrics has been successfully
implemented and commercialized in capacitor-based Ferroelectric Random Access Memory (covered in Table BC2.1). However,
in this technology the identification of the memory state requires a destructive read operation and largely depends on the total
polarization charge on a ferroelectric capacitor, which in terms of lateral dimensions is expected to shrink with every new
technology node. In contrast to that, alternative device concepts, such as the ferroelectric field effect transistor (FeFET) and the
ferroelectric tunnel junction (FTJ), allow for a non-destructive detection of the memory state and promise improved scalability
of the memory cell. The current status of and key challenges for these emerging ferroelectric memories will be assessed within
this section.
2.2.5.1. FERROELECTRIC FET
The FeFET is best described as a conventional MISFET that contains a ferroelectric oxide in addition to or instead of the
commonly utilized SiOx, SiON or HfO2 insulators. The former case requires the direct and preferably epitaxial contact of the
ferroelectric to the semiconductor channel (metal-ferroelectric-semiconductor-FET, MFSFET), whereas the latter and commonly
applied case maintains a buffer layer between the channel material and the ferroelectric (metal-ferroelectric-insulator-
semiconductor-FET, MFISFET). When additionally introducing a floating gate in-between the buffer layer and the ferroelectric,
a metal-ferroelectric-metal-insulator-semiconductor structure (MFMISFET) may be obtained that shares its equivalent circuit
representation with the MFISFET approach. By applying a sufficiently high voltage pulse to the gate of the FeFET (i.e. voltage
drop across the ferroelectric layer larger than its coercive voltage Vc), the polarization direction of the ferroelectric can be set to
either assist in the inversion of the channel or to enhance its accumulation state. This results in a polarization dependent shift of
the threshold voltage VT, which allows for a non-destructive read operation and a 1T memory operation comparable to that of
FLASH devices.
In order to assess the material and device requirements for a reliable and scalable FeFET technology the following two intrinsic
relations in a ferroelectric gate stack need to be considered. First it is important to note that the extent of the aforementioned VT-
shift (memory window) in FeFET devices is primarily determined by the VC of the implemented ferroelectric rather than by its
remnant polarization Pr . 141 This results in a scaling versus memory window trade-off as Vc is proportional to the coercive field
Ec and thickness dFE of the ferroelectric. The inability of the commonly utilized perovskite-based FeFETs to laterally scale beyond
the 180 nm node is therewith not solely based on the insufficient thickness scaling of perovskite ferroelectrics, 142,143 but rather
due to their low Ec (SBT: 10-100 kV/cm, PZT: ~50 kV/cm, summarized in 144) that in order to maintain a reasonable memory
window requires compensation by a large dFE. A solution to this scaling retardation is provided by the high coercive field (1-2
MV/cm) and thickness-scalable FE-HfO2. 145 This CMOS-compatible material innovation enabled the demonstration of a FeFET
technology scaled to the 28 nm node utilizing a conventional HKMG technology and is already used in high volume production. 146
The close resemblance of the HKMG transistor and the FE-HfO2-based memory transistor proves especially useful for the
realization of an embedded memory solution with greatly reduced mask counts as compared to embedded FLASH.
The second noteworthy and important characteristic of the FeFET gate stack is related to its intrinsic capacitive voltage divider,
which causes a significant gate voltage drop and buildup of electric field not only across the ferroelectric, but also across the non-
ferroelectric insulator in the gate stack. When additionally considering the incapability of the linear insulator to fully compensate
the polarization charge of the ferroelectric layer, it becomes apparent that even in the case of no external biasing the capacitive
voltage divider leads to a buildup of a permanent electric field. The so-called depolarization field building up in the ferroelectric
is opposed to the polarization direction of the ferroelectric and to the electric field induced in the insulator 147. The capacitive
voltage divider is therefore directly responsible for the retention loss during stand-by as well as for the gate voltage distribution
and the corresponding charge injection during write operations. This retention- and endurance-critical distribution of the electric
field within the gate stack may be optimized by choosing the insulator capacitance as high as possible and the ferroelectric
capacitance as low as possible. In the perovskite-based FeFET this is achieved by utilizing high-k buffer layers and is additionally
fostered by the unavoidably large physical thickness of the perovskite ferroelectrics. 4, 148. In the case of the aggressively scaled
FE-HfO2-based FeFET, the small thickness of the ferroelectric is compensated by the comparably low permittivity of HfO2, the
possibility to use ultra-thin interfacial layers, and by the depolarization resilience of the high Ec.144,149 This leads to the situation
that despite the markedly different stack dimensions and materials used, the electrically obtained characteristics are quite similar.
Fast switching speed (≤100 ns), switching voltages in the range of 4-6 V, and 10-year data retention and endurance in the range
of 1012 switching cycles have been demonstrated for FE-HfO2-145,146,150,151 as well as for perovskite-based FeFETs.141,152,153 In the
case of cycling endurance, however, the high Ec of FE-HfO2 and the correspondingly large electric field in the insulator facilitates
charge trapping during write operation, which was identified as the root cause for the limited endurance of 105 cycles observed
in FE-HfO2-based FeFETs with ultra-thin interfacial layer enabling excellent data retention. 154 Nevertheless, in an alternative
approach utilizing a thicker insulator and sub-loop operation it was demonstrated that at the cost of retention a cycling endurance
>1012 may still be obtained.150 In the current stage of development this endurance versus retention trade-off may be tailored,
spanning the application range from embedded NOR-FLASH replacement with high retention requirements to low refresh rate
1T DRAM requiring high cycling endurance.
Entirely overcoming this endurance versus retention trade-off will require an improved stack design that may include a tailored
polarization hysteresis (low Pr and high Pr/Ps ratio)141, a reduced trap density at the interfaces,154 an optimized capacitive voltage
divider by area scaling in the MFMISFET approach 155 or the realization of a MFSFET device by implementing recent
breakthroughs in the epitaxial growth of FE-HfO2. 156 Despite promising results obtained for perovskite-based FeFET devices
implemented into 64Kb NAND-Arrays at a feature size of 5 µm153, little is known about the variability and array characteristics
of FeFET devices scaled to technology nodes approaching the grain or domain size of the implemented ferroelectrics. Initial
investigations on phase and grain distribution in doped HfO2 based ferroelectric thin films and the effects of such granularity on
device level characteristics of scaled FeFETs (such as on the statistical nature of switching) have recently been reported in Refs.
157,158,159
. Recently, 64 kb and 32 Mb FeFET arrays were demonstrated in the 28 nm 160 and the 22 nm FD-SOI CMOS platform, 161
respectively—in each case, a clear low and high VT separation at the array level was demonstrated. Nevertheless, in order to fully
judge the variability of ferroelectric phase stability at the nanoscale and to guide material optimization and fundamental
understanding of the phenomenon, larger array statistics in the kB to Mb range and high-resolution PFM data will be required.
Besides, recent demonstration of non-volatile memory operation based on antiferroelectricity—a phenomenon closely related to
ferroelectricity—in work-function engineered ZrO2 thin film capacitors may allude to new way of addressing and potentially
solving some of these challenges in FeFETs. 162
2.2.5.2. FERROELECTRIC TUNNEL JUNCTION
The ferroelectric tunnel junction, a ferroelectric ultra-thin film commonly sandwiched by asymmetric electrodes and/or interfaces,
exhibits ferroelectric polarization induced resistive switching by a non-volatile modulation of barrier height. With the tunneling
current depending exponentially on the barrier height, the ferroelectric dipole orientation either codes for a high or a low resistance
state in the FTJ, which can be read out non-destructively. The resulting tunneling electroresistance (TER) effect of FTJs, the ratio
between HRS and LRS, is usually in the range of 10 to 100 ( 163 and references therein). However, giant TER of > 104 has most
recently been reported in a super-tetragonal BiFeO3 based FTJ by Yamada et al. 164 A similarly high TER was demonstrated by
Wen and co-workers 165 for a BaTiO3 tunnel barrier by replacing one metal electrode of the FTJ with a semiconducting electrode.
With this new junction design, the modulation of tunneling current does not only rely on barrier height, but due to a variable
space charge region in the semiconductor, also on a barrier width modification. With these most recent findings, two strategies
to achieve giant TER have been identified: either use a ferroelectric barrier with a large polarization such as BiFeO3 or use a
semiconductor as electrode material to modulate the barrier width by field-induced carrier depletion.
The MFM-based structure of FTJs may be able to enable a retention time (> 10 years) and very high cycling endurance (> 1014)
properties of conventional FRAM. Nonetheless, in order to have a significant tunneling current, ferroelectric films in FTJs usually
have a thickness ranging from several unit cells to ~5 nm, which is much thinner than in commercialized 1T-1C FRAM (> 50
nm). Due to larger interface contributions and increased leakage currents at reduced thickness, experimental data of these material
systems might strongly deviate from their thick film behavior and need to be assessed separately. 166 However, even though only
limited data are available up to this point, promising single cell characteristics have already been demonstrated, such as the most
recent demonstration of 4x106 endurance cycles and extrapolated data retention of 10 years at room temperature for a BiFeO3-
based FTJ. 167 In the context of retention, it should be noted that despite improved TER, the newly proposed MFS-FTJ structure
will give rise to a depolarization field, which will most likely degrade memory retention in a similar manner as described for the
FeFET in Section 2.2.5.1. The highly energy efficient electric field switching, common to all ferroelectric memories, enables fast
(10 ns 168) and low voltage (1.4 V167) switching in FTJ devices and results in a minimal power consumption during write operation
(1.4 fJ/bit, calculation based on the device characteristics given 169). Due to the availability of non-destructive read-out and the
further reduced ferroelectric thickness in FTJ devices as compared to conventional FRAM, improved voltage scaling and total
energy consumption may be expected from this technology.
Similar to most other two-terminal resistor-based memories with insufficient self-rectification, the elimination of sneak currents
in large crossbar arrays is most efficiently suppressed utilizing 1T-1R or 1D-1R cell architecture. In terms of scaling, this two-
element memory cell, as well as the scalability of the selector device itself, has to be considered. 170 Simply based on the lateral
dimensions of the FTJ element (assuming unlimited scalability of the selector), scaling below 50 nm2,169based on PFM data, 171
most likely appears possible. However, with further scaling a simultaneous enhancement of the LRS current density is required
to maintain readability in massively parallel memory architectures. A recent breakthrough of 1.4x105 A/cm² current density at
300 nm feature size has been achieved by Bruno et al. 172 utilizing low resistivity nickelate electrodes. Based on these results
maintaining 10 µA read current for feature sizes <100 nm appears possible. New FTJ concepts are also emerging; for example,
engineered domain walls within the ferroelectric layer in an FTJ structure can lead to exotic quantum phenomenon such as
resonant electron tunneling and quantum oscillations in the electrical conductance albeit at low temperatures. 173
FTJ based memories are currently at a very early development stage, and most of the research activity is focused on perovskite-
based ferroelectrics. Further investigations reaching beyond single device characterization will be needed to fully judge the
scalability of FTJ as well as its MLC capability suggested in Ref. 174. So far, no conclusions can be drawn on retention and
statistical distribution of the polarization induced resistance states in large arrays. However, when considering the collective
phenomenon of ferroelectricity with multiple dipoles contributing to a resistance change as opposed to filament-type resistive
switching, advanced scalability may be expected. First results have shown that the FTJ is very similar to ReRAM in terms of
electrical behavior and memory design, albeit distinct physical mechanisms. It should be noted that current prototypes could
actually have both FTJ and ReRAM traits, as resistive switching is common among oxides including ferroelectric perovskites ( 175
and references therein). For future development, the ferroelectric film in an ideal FTJ should be as thin as possible to allow
scalability (while maintaining sufficient read current) and much less defective than that in ReRAM (e.g., with fewer oxygen
vacancies), so that the mechanism of ferroelectric switching can dominate electrical behavior with little influence from
mechanisms related to conducting filaments. The manufacturability of the rather complex electrode-perovskite ferroelectric-
system of the FTJ concept will largely rely on the availability of high throughput and CMOS-compatible epitaxial growth
techniques for large substrates or alternatively on the unrestricted feasibility demonstration of a polycrystalline FTJ. In this
context it is worth noting that the CMOS-compatibility and advanced thickness scalability of ferroelectrics based on HfO2 and its
doped variant151 as well as recent breakthroughs in its epitaxial growth156 might yield great potential for the manufacturability of
competitive FTJs. Experimental demonstrations of FTJs based on doped variant of HfO2 were recently reported in Refs. 176,177,178.
2.2.6. MASSIVE STORAGE DEVICES
Device scaling has become a matter of strategic importance for modern and future information storage technologies, which
motivates an exploration of unconventional materials with competitive performance attributes. By 2040 the conservative estimate
the worldwide amount of stored data is 10^24 bits, and the high estimate is ~10^29 bits 179 (these estimates are based on research
by Hilbert and Lopez 180). In nature, much of the data about the structure and operation of a living cell is stored in the molecule
of deoxyribonucleic acid (DNA) and using nucleic acids molecules, such as DNA, for memory storage has been proposed. DNA
has an information storage density that is several orders of magnitude higher than any other known storage technology: 1 kg of
DNA stores 10^24 bits, for which >109 kg of silicon Flash memory would be needed.179 Thus, a few tens of kilograms of DNA
could meet all of the world’s storage needs for centuries to come.
A number of recent studies have shown that DNA can support scalable, random-access and error-free information
storage. 181,182,183 A state-of-the-art operating system developed at the University of Washington with an industry partner is a
DNA-based archival storage framework that supports random access from a DNA key-value store. 184 The DNA-stored files are
compatible with mainstream digital format, and large-scale DNA storage up to 200 MB has been demonstrated. 185 There are still
many unknowns regarding both DNA operations in cell and with regard to the potential of DNA technology for massive storage
applications. DNA volumetric memory density far exceeds (103–107×) projected ultimate electronic memory densities. Also, in
the living cell, the memory read/write operations occur at high speed (<100 µs/bit) and require very low energy of ~10-17 J/bit or
10-11 W/GB. 186 DNA can store information stably at room temperature for hundreds of years with zero power requirements,
making it an excellent candidate for large-scale archival storage.186 Also, DNA is an extremely abundant and totally recyclable
material. Recently, a method for efficient encoding of information—including a full computer operating system—into DNA was
presented, which approaches the theoretical maximum for information stored per nucleotide. 187 One of the goals for research
efforts is to demonstrate miniaturized, on-chip integrated DNA storage. New methods for DNA synthesis and sequencing are key
components for these developments.
Two major categories of technical challenges remain:
• Physical Media: Improving scale, speed, cost of synthesis and sequencing technologies.
• Operating System: Creating scalable indexing, random access and search capabilities.
The key technological and scientific challenges are in improving performances beyond the life sciences industry. In the life
science industry applications require perfect synthesis and perfect sequencing, while scale, throughput and cost are secondary
considerations. For data storage, high read and write error rates can be tolerated, and information encoding schemes can be used.
In this application, scale and throughput and cost are primary considerations. Current DNA storage workflows can take several
days to write and then read data, due to reliance on life sciences technologies that were not designed for use in the same system.
The demonstrated DNA write-read cycle is too slow and costly to support exascale archival data storage. Solving this problem
will require: 1) Substantial reductions in the cost of DNA synthesis and sequencing, and 2) Deployment of these technologies in
a fully automated end-to-end workflow.
2.2.7. MOTT MEMORY
Mott memory is a metal/insulator/metal capacitor structure consisting of a correlated electron insulator (or Mott insulator).
Correlated electron insulators often show the electronic phase transition accompanied by a drastic change in their resistivity under
external stimuli such as temperature, magnetic field, electric field, and light. Mott memory exploits this electronic phase transition
(called Mott metal-to-insulator transition or Mott transition 188) induced by an electric field. A mechanism of the Mott memory
has been theoretically proposed in terms of the interfacial Mott transition induced by the carrier accumulation at a Schottky-like
interface between a metal electrode and a correlated electron insulator. 189 The theory also predicted that the resistive switching
due to the interfacial Mott transition has a non-volatile-memory functionality, because the Mott transition is a first-order phase
transition due to its nature.188 In addition, Mott memory based on the Mott transition involving a large number of carriers (more
than 1022 cm-3) has in principle an advantage in device scaling, because there are a sufficient number of carries for the Mott
transition even in a nanoscale device. In an ideal Mott transition, the electrons localized due to the strong electron-electron
correlation come to be itinerant, via the stimuli, such as application of an electric field, and so forth. It needs no dopants, and the
mechanism withstands the miniaturization of the (silicon) devices.
The Mott transition induced by an electric field or carrier injection has been experimentally demonstrated in a correlated electron
material of Pr1-xCaxMnO3. 190 After this demonstration, two-terminal devices such as switches and memories have been intensively
studied using such correlated electron oxides as Pr1-xCaxMnO3, 191, 192 VO2, 193, 194, 195 SmNiO3, 196 NiO, 197, 198 Ca2RuO4, 199 and
NbO2, 200,201 and using Mott-insulator chalcogenides of AM4X8 (A=Ga, Ge; M=V, Nb, Ta; X=S, Se). 202,203,204,205 In addition to
these inorganic materials, reversible and non-volatile resistive switching based on the electronic phase change between charge-
crystalline state and quenched charge glass has recently been demonstrated in the organic correlated materials of θ-(BEDT-
TTF)2X (where X denotes an anion). 206
SmNiO3 exhibits a colossal (8 orders in magnitude) resistance jump by hydrogenation. The SmNiO3 channel with the solid state
proton gate has demonstrated the electric base gated large ON/OFF switching.196 The trigger for switching is based on the proton
intercalation by electric field, and the DFT calculation explains the large gap opening by additional electron doping via
protonation and is the origin for colossal resistance jump phenomena. 207 These results indicate that the device using the metal –
insulator (Mott) transition driven by the strong electron-electron correlation is powerful as well as appropriate for the switching
devices.
Scalability has been demonstrated down 110 × 110 nm2 in Mott memristors consisting of NbO2 that shows the temperature-driven
Mott transition from a low-temperature insulator phase to a high-temperature metal phase. The switching speed, energies, and
endurance of the NbO2-Mott memristors have been evaluated to be less than 2.3 ns, of the order of 100 fJ, and >109,
respectively.200,201 The programing and read voltages reported so far are <2 V and <0.2 V, respectively.198 The non-volatile
resistive switching of AM4X8 single crystals was induced by the electric field of less than 10 kV/cm.202,203,204,205 This suggests
that if the device consisting of a 10-nm-thick AM4X8 film is fabricated, the switching voltage will be less than 0.01 V.
Although non-volatile switching has been reported in the devices based on AM4X8 and θ-(BEDT-TTF)2X, their retention
characteristics are not elucidated in detail.202,203,204,205,206 In addition, the NbO2-Mott memristors and VO2-based devices are
volatile switch.193,194,195,200,201 The retention is thus a major concern of Mott memory. In principle, the Mott transition can be
driven even by a small amount of carrier doping to the integer-filling or half-filling valence states of the transition element.188
However, because of disorders, defects, and spatial variation of chemical composition, a rather large amount of carriers of more
than 1022 cm-3 are required to drive the Mott transition in actual correlated electron materials, resulting in a relatively large
switching voltage required in the Mott memory. Therefore, one of the key challenges is the control of crystallinity and chemical-
composition in the thin films of correlated electron materials, including the integration of the correlated electron materials onto
Si platform. There are some theoretical mechanisms proposed for Mott memories such as the interfacial Mott transition189 and
the formation of conductive filament generated by local Mott transition.202,204,205 However, a thorough understanding of the
mechanism has not been achieved yet. Therefore, the elucidation of detailed mechanism is also a major research challenge.
2.3. MEMORY SELECTOR DEVICE
The capacity (or density) is one of the most important parameters for memory systems. In a typical memory system, memory
devices (cells) are connected to form an array. A memory cell in an array can be viewed as being composed of two components:
the ‘storage node’, which is usually characterized by an element with switchable states, and the ‘selector’, which allows the
storage node to be selectively addressed for read and write. Both components impact scaling limits of memory. It should be noted
that for several advanced concepts of resistance-based memories, the storage node could in principle be scaled down below 10
nm, 208 and the memory density is often limited by the selector devices. Thus, the selector device represents a serious bottleneck
for emerging memory scaling to 10 nm and beyond.
The most commonly used memory selector devices are transistors (e.g., FET or BJT), as in DRAM, FRAM, etc. Flash memory
is an example of a storage node (floating gate) and a selector (transistor) combined in one device. Planar transistors typically have
the footprint around (6-8)F2. In order to reach the highest possible 2D memory density of 4F2, a vertical transistor selector needs
to be used. However, transistors as selector devices are generally unsuitable for 3D memory architectures. Two-terminal memory
selector devices are preferred for scalability and can be used in crossbar memory arrays to achieve 4F2 footprint. 209,210 The
function of selector devices is essentially to minimize leakage through unselected paths (“sneak paths”). Two-terminal selector
devices can achieve this through asymmetry (e.g., rectifying diodes) or nonlinearity (e.g., nonlinear devices). 211 Volatile switches
can also be used as selector devices. Figure BC2.2 shows a taxonomy of memory selector devices. In addition to external selector
devices, some storage elements may have inherent self-selecting properties (e.g., intrinsic nonlinearity or self-rectification), which
may enable functional crossbar arrays without external selectors.
Vertical Oxide/oxide
heterojunctions Mott switch MIEC
Reverse-conduction Intrinsic
diodes nonlinearity
Self-rectification
The simplest realization of diode selectors uses semiconductor diodes, such as a pn-junction diode, Schottky diode, or
heterojunction diode. Such devices are suitable for a unipolar memory cell. For bipolar memory cells, selectors with bi-directional
switching are needed. Proposed examples include Zener diodes, 215 BARITT diodes, 216 and reverse breakdown Schottky
diodes. 217
2.3.2.1. SI DIODE SELECTOR DEVICES
Both single-crystal Si 218 and poly-Si219,220,221 diodes have been developed as selector devices for PCM arrays. To provide high
ON current, the contact resistivity needs to be reduced to <10-7 Ω cm2, which was achieved by engineering the metal electrodes
and electrode-Si interface. 219 A short-time annealing technique helps to reduce the OFF current and enlarge the ON/OFF ratio.
Poly-Si technology can achieve ON current density of 107 A/cm2 (at ~ 1.8V) and an ON/OFF ratio of 108. It is believed that Si
diodes can be scaled beyond 20 nm or 10 nm. Poly-Si diode selector devices have been integrated in PCM crossbar arrays, 3D
vertical chain-cell type PCM, 220 and a 1 Gb PCM test chip. 221 A major challenge of Si diodes is the high processing temperature
(above 1000°C) required to crystallize Si to reduce contact resistivity and OFF current.
2.3.2.2. OXIDE DIODE SELECTOR DEVICES
Oxide-based heterojunction222,223,224,225 or Schottky junction228,229,230,231 diodes may be fabricated at lower temperatures and used
as selector devices. They are particularly suitable for oxide-based RRAM devices. A p-NiOx/n-TiOx diode has demonstrated a
rectification ratio of 105 at ±3V and ON current density of 5×103 A/cm2 (at ~ 2.5V) 222. A p-CuOx/n-InZnOx diode achieved higher
ON current density of 104 A/cm2 (at ~ 1.3V) and was integrated with NiOx RRAM in a 2-layer 8×8 crossbar array 223,224 and with
Al2O3 antifuse in a one-time-programmable (OTP) memory. 225 Si substrates can be used as a part of heterojunction diodes as
demonstrated in n-ZnO/p-Si 226 and n-Ge-nanowire/p-Si diodes. 227 In TiOx-based diodes with Pt electrodes, temperature-
dependent current-voltage (I-V) characteristics confirm a Schottky barrier of ~0.55 eV at the TiOx/Pt interface. 228 The
rectification ratio is ~ 1.6×104 at ±1V but ON current density is low (~ 13A/cm2) due to large size. A Pt/TiO2/Ti diode with Pt as
the Schottky contact and Ti the ohmic contact achieved higher rectification ratio of 107 – 109 at ±1V. 229 Another demonstration
of Pt/TiO2/Ti Schottky diodes improved ON current density to ~ 3×105 A/cm2 at 2 V on a 4 µm2 area. 230 Measurement showed
that current is not uniform across the diode area, probably due to edge leakage. Therefore, current density is higher at smaller
diode size. An Ag/n-ZnO Schottky diode with non-alloyed Ti/Au ohmic contact demonstrated a rectification ratio of 105 and
forward current density over 104 A/cm2 at 2 V. 231 In addition to oxide Schottky diodes, Si Schottky diodes are also utilized as
selector devices, e.g., Al/p-Si. 232 The ON current of oxide-based heterojunction diodes is often limited by both contact resistance
and density of states of the oxide materials.
current density (> tens of MA/cm2). 248 Endurance above 108 cycles has been demonstrated on MIEC devices in small arrays. 249
The MIEC selector devices were also integrated with PCM in a 512 kb testing array using 180nm CMOS process. 250 The
scalability of MIEC select devices was tested to below 30nm in diameter and below 12nm in thickness. 251
2.3.4.3. COMPLEMENTARY RESISTIVE SWITCHES
A complementary resistive switch (CRS) provides a self-selecting memory by connecting two bipolar RRAM devices anti-
serially. 252 It may be considered as “constructed nonlinearity”. Both states “0” and “1” have high resistance in CRS, which helps
to minimize leakage through sneak paths. In either state, one of the two RRAMs is in LRS and the other in HRS. When reading
a “1” state, the HRS device is switched to LRS and both devices end up in LRS. When reading a “0” state, no switching occurs
and CRS remains in HRS. Notice that the reading operation is destructive, although non-destructive readout method was also
proposed. 253 CRS has been demonstrated in different resistive switching devices, e.g., Cu/SiO2/Pt bipolar resistive switches, 254
amorphous carbon-based RRAM, 255 TaOx–based RRAM, 256 multi-layer TiOx device, 257 HfOx RRAM, 258 ZrOx/HfOx bi-layer
RRAM, 259 Cu/TaO2 atomic switch, 260 Nb2O5−x/NbOy RRAM, 261 etc.
Table BC2.5a summarizes experimentally demonstrated parameters of some two-terminal select devices, including diodes,
volatile switches, and nonlinear devices. Table BC2.5b summarizes the parameters of some reported self-rectifying memories. It
should be emphasized that these summary tables can only capture a snapshot of selector device characteristics; however, the
functionality of these devices depends on their actual voltage in arrays with random data patterns and the balance between
selectors and storage elements. Therefore, these parameter tables should only be used for illustration purpose, not for rigorous
benchmark or assessment.
It remains a great challenge for the demonstrated selector devices to meet all the requirements in Table BC2.4. For scaled two-
terminal select devices, two fundamental challenges are contact resistance219 and lateral depletion effects. 262,263 Very high doping
concentration is needed to minimize both effects. However, high doping concentrations result in increased reverse bias currents
in classical diode structures and therefore reduced Ion/Ioff ratio. For switch-type selector devices the main challenges are
identifying the right material and the switching mechanism to achieve the required drive current density, Ion/Ioff ratio, and
reliability.
Although Flash memory technology continues to project for further density scaling, inherent performance characteristics such as
read, write and erase latencies have been nearly constant for more than a decade. 266 While the introduction of multi-level cell
(MLC) Flash devices extended Flash memory capacities by a small integral factor (2–4), the combination of scaling and MLC
have resulted in the degradation of both retention time and endurance, two parameters critical for storage applications. The
migration of NAND Flash into the vertical dimension above the silicon has continued this trend of improving bit density (and
thus cost-per-bit) while maintaining or in some cases, even slightly degrading the latency, retention, and endurance characteristics
of present-day NAND Flash.
This outlook for existing technologies has opened interesting opportunities for prototypical and emerging research memory
technologies to enter the non-volatile solid-state-memory space.
2.4.1.2. WHAT IS STORAGE CLASS MEMORY?
Storage-class memory (SCM) describes a device category that combines the benefits of solid-state memory, such as high
performance and robustness, with the archival capabilities and low cost of conventional hard-disk magnetic storage. 267,268 Such a
device requires a non-volatile memory (NVM) technology that could be manufactured at a very low cost per bit.
A number of suitable NVM candidate technologies have long received research attention, originally under the motivation of
readying a “replacement” for NAND Flash, should that prove necessary. Yet the scaling roadmap for NAND Flash has progressed
steadily so far, without needing any replacement by such technologies. So long as the established commodity continues to scale
successfully, there would seem to be little need to gamble on implementing an unproven replacement technology instead.
However, while these NVM candidate technologies are still relatively unproven compared to Flash, there is a strong opportunity
for one or more of them to find success in applications that do not involve simply “replacing” NAND Flash. Storage Class
Memory can be thought of as the realization that many of these emerging alternative non-volatile memory technologies can
potentially offer significantly more than Flash, in terms of higher endurance, significantly faster performance, and direct-byte
access capabilities. In principle, Storage Class Memory could engender two entirely new and distinct levels within the memory
and storage hierarchy. These levels would be differentiated from each other by access time, with both levels located within more
than two orders of magnitude between the latencies of off-chip DRAM (~80 ns) and NAND Flash (20 µs).
2.4.1.2.1. STORAGE-TYPE SCM
The first new level, identified as S-type storage-class memory (S-SCM), serves as a high-performance solid-state drive, accessed
by the system I/O controller much like an HDD. S-SCM must provide at least the same data retention as Flash, allowing S-SCM
modules to be stored offline, while offering new direct overwrite and random-access capabilities (which can lead to improved
performance and simpler systems) that NAND Flash devices cannot provide. However, because of the modest (perhaps 10x)
advantage in read latency over NAND Flash, it is critical that the eventual cost-per-bit for S-SCM be no worse than 3-10x higher
than NAND Flash. While such costs need not be realized immediately at first introduction, it would need to be very clear early
on that costs could steadily approach such a level relative to Flash.
Note however that such system cost reduction can come from other sources than the raw cost of the device technology: a slightly-
higher-cost NVM technology that enabled a simple, low-cost SSD by eliminating or simplifying costly and /or performance-
degrading overhead components would achieve the same overall goal. If the cost per bit could be driven low enough through
ultrahigh memory density, ultimately such an S-SCM device could potentially replace magnetic hard-disk drives in enterprise
storage server systems as well as in mobile computers (subject to the same issues mentioned above in terms of needing numerous
IC fabs to ship the many petabytes of HDD delivered to those markets264).
2.4.1.2.2. MEMORY-TYPE SCM
The second new level within the memory and storage hierarchy, termed M-type storage-class memory (M-SCM), should offer a
read/write latency of less than ~200 ns. These specifications would allow it to remain synchronous with a memory system,
allowing direct connection from a memory controller and bypassing the inefficiencies of access through the I/O controller. The
role of M-SCM would be to augment a small amount of DRAM to provide the same overall system performance as a DRAM-
only system, while providing moderate retention, lower power-per-GB and lower cost-per-GB than DRAM. Again, as with S-
SCM, the cost target is critical. It would be desirable to have cross-use of the same technology in either embedded applications
or as a standalone S-SCM, in order to spread out the development risk of an M-SCM technology. The retention requirements for
M-SCM are less stringent, since the role of non-volatility might be primarily to provide full recovery from crashes or short-term
power outages, requiring non-volatility over a period of perhaps 7–21 days.
Particularly critical for M-SCM will be device endurance, since the time available for wear-leveling, error-correction, and other
similar techniques is limited. The volatile portion of the memory hierarchy will have effectively infinite endurance compared to
any of the non-volatile memory candidates that could become an M-SCM. Even if device endurance can be pushed well over 109
cycles, it is quite likely that the role of M-SCM will need to be carefully engineered within a cascaded-cache or other Hybrid
Memory approach. 269 That said, M-SCM offers a host of new opportunities to system designers, opening up the possibility of
programming with truly persistent data, committing critical transactions to M-SCM rather than to HDD, and performing commit-
in-place database operations.
2.4.1.3. TARGET SPECIFICATIONS FOR SCM
Since the density and cost requirements of SCM transcend the straightforward scaling application of Moore’s Law, additional
techniques will be needed to achieve the ultrahigh memory densities and extremely low cost demanded by SCM, such as 1) 3-D
integration of multiple layers of memory, currently implemented commercially for write-once solid-state memory, 270 and/or 2)
Multiple level cell (MLC) techniques.
Table BC2.6 lists a representative set of target specifications for SCM devices and systems compared with benchmark parameters
of existing technologies (HDD and NAND Flash). As described above, SCM applications can be expected to naturally separate
based on latency. Although S-class SCM is the slower of these two targeted specifications, read and write latencies should be in
the 1–5 μsec regime in order to provide sufficient performance advantage over NAND Flash. Similarly, endurance of S-class
SCM should offer at least 1 million program-erase cycles, offering a distinct advantage over NAND Flash. In order to support
off-line storage, 10-year retention at 85°C should be available.
In order to make overall system power usage (as shown in Table BC2.6) competitive with NAND Flash and HDD, and since
faster I/O interfaces can be expected to consume considerable power, the device-level power requirements must be extremely
minimal. This is particularly important since low latency is necessary but not sufficient for enabling high bandwidth – high
parallelism is also required. This in turn mandates a sufficiently low power per bit access, both in terms of peripheral circuitry
and device-level write and read power requirements. Finally, standby power should be made extremely low, offering opportunities
for significant system power savings without loss of performance through rapid switching between active and standby states.
In order to achieve the desired cost target of within 3–10x of the cost of NAND Flash, the effective areal density will similarly
need to be quite similar to 1X-node planar NAND Flash. This low cost structure would then need to be maintained by subsequent
SCM generations, through some combination of further scaling in lateral dimension, by increasing the number of multiple layers,
or by increasing the number of bits per cell.
Also shown in Table BC2.6 are the target specifications for M-type SCM devices. Given the faster latency target (which enables
coherent access through a memory controller), the program-erase cycle endurance must be higher, so that the overall non-volatile
memory system can offer a sufficiently large lifetime before needing replacement or upgrade. Although some studies have shown
that a device endurance of 107 cycles is sufficient to enable device lifetimes on the order of 3–10 years, 271 we anticipate that the
need for sufficient engineering margin would suggest a minimum cycle endurance of 109 cycles. While such endurance levels
support the use of M-class SCM in memory support roles, significantly higher endurance values (e.g., 1e12 or 1e14 cycles) would
allow M-class SCM to be used in more varied memory applications, where the total number of memory accesses may become
very large.
Table BC2.6 Potential of Current Prototypical and Emerging Research Memory Candidates for SCM
Applications
While the details of the devices involved may still be uncertain, the projected array specifications and the target applications are,
for all intents and purposes, indistinguishable from those described above for S-type Storage Class Memory. Thus we can consider
3D-Xpoint as the first commercial implementation of the Storage Class Memory concept first described in 2008.267,268
Furthermore, in a later presentation, a second, “Performance-focused” form of 3D-Xpoint memory was described as being under
active development. 277 Compared to the initial “Cost-focused” form of 3D-Xpoint memory, this variant is said to offer even faster
latencies and higher endurance (Figure BC2.3). Thus, this second variant of 3D-Xpoint is somewhat similar to M-type SCM as
described above, both in terms of its specifications and in terms of potential applications. The only major difference, as observed
in Figure BC2.3, is the strong similarity between the expected volatility of Performance-focused 3D-Xpoint and the known
volatility of DRAM. In contrast, one of the benefits of M-type SCM was supposed to be its non-volatility. Ideally, retention of
data for perhaps 1-3 weeks would permit successful recovery of server data, even after a power outage due to a natural disaster
or other major event.
Historically, roughly one-third of the power in a large computer system is consumed in the memory sub-system. 278 Some portion
of this is refresh power, required by the volatile nature of DRAM. As a result, modern data servers consume considerable power
even when operating at low utilization rates. For example, Google 279 has reported that servers are typically operating at over 50%
of their peak power consumption even at very low utilization rates. The requirement for rapid transition to full operation precludes
using a hibernate mode. As a result, a persistent memory that did not require constant refresh would be valuable.
Many computer systems are not running at peak load continuously. Such systems (including mobile or data analytics) become
much more efficient if power can be turned off rapidly while maintaining persistent stored data, since power usage can then
become proportional to the instantaneous computational load. This provides additional incentive for the non-volatile storage
aspect of SCM.
Some applications such as data analytics and ASIC systems can benefit from having associative memories or content
addressability, while other applications might gain little. Mobile systems can become even more compact if many different
memory tiers can be combined on the same chip or package, including non-volatile M-class or even S-class Storage Class
Memory.
Total cost of ownership is influenced by cost-to-purchase, cost-to-maintain, and system lifetime. Current cost-to-purchase trends
are that Hard Disk Drives (HDD) cost roughly an order of magnitude less per bit than Flash memory, which in turn costs almost
an order of magnitude less per bit than DRAM. However, cost-to-purchase is not the only consideration. It is anticipated that S-
class SCM will consume considerably less power than HDD (both directly and in terms of required cooling), and will take up
considerably less floorspace. One early projection what that by 2020, if the main storage system of a data center is still built
solely from HDD, the target performance of 8.4 G-SIO/s could consume as much as 93 MW and require 98,568 square feet of
floor space. 280 In contrast, the improved performance of emerging memories could supply this performance with only 4 kW and
12 square feet. Given the cost of energy, this differential can easily shift the total cost advantage to emerging memory, away from
HDD, even if a cost per bit differential still exists.
These requirements have led to considerable early investigation into new memory architectures, exploiting emerging memory
devices, often in conjunction with DRAM and HDDs in novel architectures. These new Storage Class Memories (SCM) are
differentiated as whether they are intended to be close to the CPU (M-class) or to largely supplement the hard-drives and SSDs
(S-class).
The emergence of SCM leads to the need to resolve issues beyond the device level, including software organization, wear leveling
management, and error management. Because of the inherent speed in SCMs, software can easily limit the system performance.
Some of these changes have already been initiated by the advent of SSDs. All types of IO software – from the filesystem, through
the operating system and up to applications – had to be redesigned in order to best leverage both SSDs and then SCMs. The
number of software interactions was reduced, and disk-centric features were removed. Inefficiencies buried deep within
conventional software were accounting for anywhere from 70% to 94% of the total IO latency. 281 It is likely to be valuable to
give application software direct access to the SCM interface, although this can then require additional considerations to protect
the SCM device from malicious software. This direct access has not occurred for SSDs, with manufacturers applying numerous
undocumented operations between the input data and the raw storage. (One example is the inversion of entire data blocks, based
on the number of 0s or 1s to be stored.) However, this approach is not typically used in current operating systems that use some
form of File Address Table as an intermediate index mechanism.
Access patterns in data-intensive computing can vary substantially. While some companies continue to use relational databases,
others have switched to flat databases that must be separately indexed to create connections amongst entries. In general, database
accesses tend to be fairly atomic (as small as a few bytes) and can be widely distributed across the entire database. This is true
for both reads and writes, and since the relative ratio of reads and writes varies widely by application, the optimality of any one
design can depend strongly on the particular workload.
A specific issue that arises with SCMs is wear leveling. While DRAMs and HDDs can support a large number of writes to the
same location without failure, most of the emerging non-volatile memory device technologies cannot. Thus, there is a need for
low-overhead mechanisms to “spread” the writes around uniformly, generally referred to as “wear leveling”. An important issue
in any file system is that certain data (such as metadata) is written to quite frequently. It is important to make sure that such
storage locations are not subject to fast wear out, e.g. by using a more robust technology for such portions of the file system.
Error management is a broader problem than just wear leveling. While DRAM has traditionally benefited from simple methods
such as ECC and EDCs, Flash with its large page sizes and slow accesses can afford more sophisticated algorithms such as LDPC.
Unfortunately, SCM will need more error correction than DRAM but will need faster error correction than Flash, especially for
M-class SCMs. This is an open area for research. Some possible options include exploring codes that exploit specifics of error
patterns, such as Tensor codes, and the use of in-situ scrub, 282 where accumulated errors are periodically eliminated so that one
or two-bit error correction can remain sufficient.
2.4.2.3. EMERGING MEMORY ARCHITECTURES FOR M-CLASS SCM
Storage Class Memory architectures that are intended to replace, merge with, or support DRAM, and be close to the CPU, are
referred to as M-type or Memory-type SCM (M-SCM). The required properties of this memory have many similarities to DRAM,
including its interfaces, architecture, endurance, and read and write speed. Since write endurance of an emerging research memory
is likely to be inferior to DRAM, considerable scope exists for architectural innovation. It will be necessary to choose how to
integrate multiple memory technologies to optimize performance and power while maximizing lifetime. In addition, advanced
load leveling that preserves the word level interface and suitable error correction will be needed.
The interface is likely to be a word-addressable bus, treating the entire memory system as one flat address space. Since the cost
of adapting to new memory interfaces is sizeable, an interface standard that could support multiple generations of M-SCM devices
would be highly preferred. Many systems (such as in automobiles) might be deployed for a long time, so any new standard should
be backward-compatible. Such a standard should compatible to DRAM interfaces (though with simpler control commands) and
should reuse existing controllers and PHY (physical layers), as well as power supplies, as much as possible. It should be power
efficient, e.g. supporting small page sizes, and should support future directions, such as 3D Master/slave configurations. The M-
SCM device should indicate when writes have been completed successfully. Finally, an M-SCM standard should support multiple
data rates, such as a DDR-like speed for the DRAM and a slower rate for the NVRAM. 283
While wear-leveling in a block-based architecture requires significant overhead to track the number of writes to each block,
simple techniques such as “Start-Gap” Wear-Leveling are available for direct-byte-access memories such as PCM (Phase Change
Memory). 284 In this technique, a pair of registers are used to identify the location of the start point and an empty gap within a
region of memory. After some threshold number of write accesses, the gap register is moved through the region, with the start
register incrementing each time the gap register passes through the entire region. Additional considerations can be added to defend
against detrimental attacks intended to intentionally wear out the memory.
With such techniques, even an M-class SCM that is markedly slower than DRAM can offer improved performance by increasing
available capacity and by reducing the occurrence of costly cache misses. 285 With proper caching, a carefully-designed M-SCM
system could potentially even match DRAM performance despite its lower device latency. 286 The presence of a small DRAM
cache helps keep the slower speed of the M-class SCM from affecting overall system performance in many common workloads.
Even with an endurance of 1e7 cycles, the system lifetime has been shown to be on the order of 3 years. Techniques for reducing
the write traffic back to the SCM device can help improve this by as much as a factor of 3 under realistic workloads.
Direct replacement of DRAM with a slightly slower M-class SCM has also been considered, for the particular example of STT-
MRAM. 287 Since individual byte-level writes to STT-MRAM consume more power than in DRAM, a direct replacement is not
competitive in terms of energy or performance. However, by re-architecting the interaction between the output buffer and the
STT-MRAM, unnecessary writes back to the NVM can be eliminated, producing a sizeable energy improvement at almost no
loss in performance. However, the use of write buffers means that the device must be able to complete all writes back to non-
volatile memory in the event of power loss. Integrating PCM into the mobile environment, together with a redesigned memory
management controller, is predicted to deliver a six times improvement in speed and also extends the memory lifetime six times. 288
Caches are intended to ensure that frequently-needed data is located near to the processor, in nearby, low-latency memory. In
storage architectures, “hot” or frequently-accessed data is identified and then moved to faster tiers of storage. However, as the
number of tiers or caches increases, a significant amount of time and energy is being spent moving data. An alternative approach
is to completely rethink the hardware/software interface. By organizing the computational system around the data, data is not
brought to the processor but instead processing is performed in proximity to the stored data. One such emerging data-centric chip
architectures termed “Nanostores” 289 was predicted to offer 10–60x improvements in energy efficiency. 290
Given the slower than expected deployment of scaled emerging devices for M-class SCM, several projects have employed large
amounts of DRAM as a surrogate for and M-class SCM. Though Bresniker et.al. describe a computer enabled by a large non-
volatile “Universal memory,” 291 press reports indicate that early commercial machines will be built with large amounts of DRAM.
They point out that an NVM version allows “occasionally-on computing” but could have the downside that new types of bugs
might appear as OSs and programs effectively run indefinitely and cannot “re-create their memory state representations each time
they start”. New applications and algorithms might emerge as a result of keeping data in perpetuity, or at least for long periods
of time.
2.4.2.4. EMERGING MEMORY ARCHITECTURES FOR S-CLASS SCM
S (Storage) type SCMs are intended to replace or supplement hard-disk drives as main storage, much like current Flash-based
SSDs, but with even more IOPs (I/O operations per second). Their main advantage will be speed, avoiding the seek time penalty
of main drives. However, to succeed, their total cost of ownership needs to approach that of HDDs. Research issues include
whether the SCM serves as a disk cache or is directly managed, how load leveling is implemented while retaining a sufficiently
fast and flexible interface, how error correction is implemented, and identifying the optimal mix of fast-yet-expensive and slow-
yet-inexpensive storage technologies. The effective performance of Flash SSD, itself slower than S-SCM, has been strongly
affected by interface performance. For instance, the SATA (Serial Advanced Technology Attachment) interface was originally
designed for HDD, and was commonly used for early SSD devices despite not being optimized for Flash SSD. 292
One possible introduction of these new memory devices to the market would be as hybrid solid-state discs, where the new memory
technology complements the traditional Flash memory to boost the SSD performance. Experimental implementations of
FeRAM/Flash 293and PCRAM/Flash 294 have been explored. It was shown that the PCRAM/Flash hybrid improves SSD operations
by decreasing the energy consumption and increasing the lifetime of Flash memory.
Additional open questions for S-SCM include storage management, interface, and architectural integration, such as whether such
a system should be treated like a fast disk drive or as a managed extension of main memory. To date, disk-like systems built using
non-volatile memories have had disk-like interfaces, with fixed-sized blocks and a translation layer used to obtain block addresses.
However, since the file system also performs a table lookup, some portion of SCM performance is sacrificed. In addition, non-
NAND-Flash SCMs have randomly accessible bits and do not need to be organized as fixed-size blocks. 295
While preserving this two-table structure means that no changes to the operating system are required to use or to switch between
new S-SCM technologies, the full advantages of such fast storage devices cannot be realized. There are two alternative approaches
to eliminate one of these lookup tables. In the Direct Access mode, the translation table is removed, so that the operating system
must then understand how to address the SCM devices. However, any change in how table entries are calculated (such as
improvements in garbage collection or wearleveling) would then require changes in the operating system.
In contrast, in an Object-Based access model, the file system is organized as a series of (key, value) objects. While this requires
a one-time change to operating systems, all specific details of the SCM could be implemented at a low level. This model leads to
greater efficiency in terms of both speed and effective “file” density and also offers the potential for enhanced reliability.
Another issue for SCM-based systems will be addressing the asymmetry between read and write in devices such as PCM or other
emerging non-volatile memories. 296 Such asymmetry can affect the ordering and atomicity of writes and needs to considered in
system or algorithm design. 297 Atomicity is critical for operations such as database transactions properties, so that either all of a
series of related database operations occur, or none of them occur.
Longer write latencies, in technologies such as PCM, can be compensated by techniques such as data comparison writes, 298 partial
writes, 299 or specialized algorithms/structures that trade writes for reads. 300,301 (These last set of techniques can also help reduce
endurance problems.) Write ordering and atomicity problems can be finessed by hardware primitives. These can either be existing
hardware primitives – cache modes (e.g., write-back, write-combining), memory barriers, cache line flush 302,303,304 – or newly-
proposed hardware primitives, such as atomic 8-byte writes and epoch barriers. 305,306
Even first-generation PCM chips, although implemented without a DRAM cache, compare favorably with state-of-the-art SSDs
implemented with NAND Flash, particularly for small (<2 KB) writes and for reads of all sizes. 307 The CPU overhead per input-
output operation is also greatly reduced. Another observation for even first-generation PCM chips is that while the average read
latency is similar to NAND Flash, the worst-case latency outliers for NAND Flash can be many orders of magnitude slower than
the worst-case PCM access. This is particularly important considering that such S-class SCM systems will typically be used to
increase system performance by improving the delivery of urgently-needed “hot” data.
Another new software consideration for both S- and M-class SCM is the increased importance of avoiding memory corruption,
either through memory leaks, pointer errors, or other issues related to memory allocation and deallocation. 308 Since part of the
memory system is now non-volatile, such issues are now pervasive and may be difficult to detect and remove without affecting
stored user data.
General libraries and programming interfaces – such as NV-heaps, 309 Mnemosyne, 310 NVMalloc, 311 and recovery and durable
structures 312 – have been proposed to expose SCM as a persistent heap and thus ease its adoption. Schemes for filesystem support
have been developed to transparently utilize as byte-addressable persistent storage, including Intel’s PMFS, 313 BPFS, FRASH, 314
ConquestFS, 315 and SCMFS. 316
Table BC2.7. Likely Desirable Properties of M (Memory) Type and S (Storage) Type Storage Class Memories
Table BC3.1b Charge-based Beyond CMOS: Non-conventional FETs and Other Charge-based Information
Carrier Devices
vertical InAs transistors that showed cut-off frequency of 2 GHz, 341 and extended, programmable arrays (“tiles”) of non-volatile
nanowire-based Flash memory that are used to build circuits such as full-adder, full-subtractor, multiplexer, demultiplexer,
clocked D-latch and finite state machines. 342,343 Planar VLS III-As nanowires perfectly aligned in-plane have enabled multigate
HEMTs to enhance high frequency performance. 344,345
Despite the promising results that are mostly obtained from academic research labs, bottom-up nanowire transistors still face
significant challenges before commercialization is feasible. There is an urgent need to improve device yield and uniformity, as
well as position registry if the nanowires are to be transferred to a different substrate. 346 On the other hand, the potential of bottom-
up nanowire transistors for monolithic core-shell architecture and the inherently relaxed lattice matching requirements for
heterogeneous integration have not been completely exploited for low power and high speed applications. 347 For top-down
fabricated nanowires, with the demonstration of standalone transistors, CMOS integration, and a functional ring oscillator,
vertically stacked planar Si nanowires hold enormous potential to succeed FinFETs in sub-5nm technology nodes. 348,349,350.
3.2.3. 2D MATERIAL CHANNEL FETS
Two-dimensional (2D) materials transition metal dichalcogenides (TMDCs), including graphene, are promising candidates for
future channel materials in LSIs. Since they are layered materials, they can be as thin as one-layer (one-atom) thick without
degrading their properties, which cannot be realized with conventional three-dimensional materials. Electrostatic control of such
a thin channel is easier than a conventional bulk channel, suppressing “short channel effects” often encountered by scaled
transistors. Carrier mobility of such 2D materials can be very high. Furthermore, novel devices based on principles different from
that of CMOS can be realized using 2D materials, as discussed later.
Graphene has especially attracted attention as a channel material due to its extremely high mobility since the year of 2004, when
a report on monolayer graphene prepared by exfoliation of graphite crystals was published. 351 The report showed that the field-
effect mobility of graphene on SiO2 was as high as ~10,000 cm2/Vs. It was then predicted that the room-temperature mobility of
graphene on SiO2 would be limited to ~40,000 cm2/Vs due to scattering by surface phonons of the SiO2 substrate. 352 In fact, much
higher field effect mobility was obtained using suspended graphene. Values as high as 120,000 cm2/Vs and 1,000,000 cm2/Vs at
240 K and liquid-helium temperature were obtained. 353, 354 Recently, hexagonal boron nitride (hBN), an inert and flat material,
has been used as a substrate for graphene-channel transistors, and it has been shown that the field effect mobility of such devices
can exceed 100,000 cm2/Vs at room temperature near the charge neutrality point. 355, 356 Furthermore, a device in which graphene
was sandwiched between two hBN flakes and edge-contacted with two metal electrodes exhibited mobility even higher than the
above. 357 The results indicate that hBN can be excellent passivation film for graphene devices.
Graphene can also be obtained on SiC surface by annealing a SiC crystal at high temperatures (often called “epitaxial graphene”).
The annealing temperatures range from 1200⁰C to 2000⁰C depending on the annealing environment. 358 , 359 Chemical vapor
deposition of graphene on metal foil or film has also been demonstrated. 360, 361, 362, 363 Typical growth temperatures are around
1000⁰C. It has been shown that monolayer graphene is preferentially formed on Cu foil or film,360,362, 364 while multi-layer
graphene can be formed on Ni, Co, and Fe catalyst.361,363, 365 The quality of epitaxial graphene and CVD graphene is now as good
as that of exfoliated graphene. 366, 367
Efforts have been made to fabricate graphene-channel transistors, where fabrication processes such as doping and contacting to
graphene channels have been developed. 368 However, since graphene does not have a bandgap, such transistors cannot have an
ON/OFF ratio high enough for digital applications. Several approaches have been proposed to open a bandgap of graphene. One
of the two major approaches is to apply an electric field perpendicular to AB-stacked bilayer graphene. 369 , 370 , 371 , 372 , 373
Experimentally, a transport gap of 130 meV was obtained at an electrical displacement of 2.2 V/nm, providing an ON/OFF ratio
of ~100 at room temperature.372 This ON/OFF ratio is probably the largest for this approach so far, which is, however, not high
enough for logic applications. In fact, it has been pointed out that a small stacking fault of AB-stacked bilayer graphene can
increase the off current, 374 which is a serious problem.
A promising approach to form a bandgap in graphene is to make it narrow, that is, to form a graphene nanoribbon
(GNR). 375, 376, 377, 378, 379, 380, 381, 382 In fact, simulations using a first-principles many-electron Green’s function approach within the
GW approximation have predicted that bandgaps can be as large as ~5 eV depending on their widths for armchair-edged GNRs
(AGNRs).382, 383 Formation of GNRs was first attempted by using electron beam lithography and etching.376 Carrier transport
through such a GNR was also investigated. An energy gap of ~200 meV was obtained for a GNR with a width of 15 nm. Devices
with multiple GNRs with a sub-10 nm half-pitch were fabricated using patterning with directed self-assembly of block
copolymers. 384 The transport characteristics of such top-down GNRs were poor, however. This is mainly because the edges of
such GNRs were not well controlled, probably with a lot of defects. 385, 386 Recently, however, attempts to form GNRs with
controlled edges have been made using bottom-up approaches. In fact, Cai et al. demonstrated the growth of armchair-edged
GNRs (AGNRs) from 10,10’-dibromo-9,9’-bianthryl precursors. 387 In their approach, precursor molecules are deposited onto a
clean Au(111) surface by vacuum evaporation in ultra-high vacuum. The substrate is then heated to 200⁰C to remove Br from the
precursors and to connect them with each other at the Br-removed points, forming polymers. By further heating the substrate to
400⁰C, the polymers were cyclodehydrogenated to form AGNRs with a uniform width. The AGNR formed is referred to as
7AGNR, because it has seven dimer lines in the width direction. The band gap of 7AGNR is 3.7-3.8 eV according to the
simulations above382,383 and agrees with an experimentally obtained bandgap (~2.3 eV) considering image-charge corrections by
Au substrate. 388 Now several types of GNRs have been formed using similar approaches with different precursors. 389 As for
AGNRs with a smaller bandgap, 9AGRs with a theoretical bandgap of about 2.2-2.3 eV have been obtained.353 Formation of
13AGNRs with a theoretical bandgap of about 2.3-2.5 eV was also demonstrated although the GNRs were rather short, typically
less than 10 nm in this case. The successful formation of atomically precise AGNRs paves a way for their application to transistor
channels.
Performance of GNR-channel transistors have been predicted by numerical simulations. 390, 391, 392 It was shown that a transistor
with multiple-GNR channels (width: 1.47 nm, pitch: 3.47 nm) with a channel length of 15 nm exhibited an on-current exceeding
1 mA/μm with ON/OFF ratio larger than 105 and a subthreshold swing of 64 mV at a drain voltage of 0.1 V40. Transistors using
7AGNRs as channels were fabricated and evaluated experimentally. The performance of transistors was, however, poor with a
very low on-current and an ON/OFF ratio of 3.6 x 103 at a drain voltage of 1V. 393 The small on-current was attributed to large
Schottky barriers at the source and drain contacts caused by the large bandgap of 7AGNR. Use of 9AGNRs and 13AGNRs with
smaller bandgaps actually improved the transistor performance. In fact, transistors using 9GNRs as channel exhibited ON/OFF
ratios as high as 105 and on-current of 1 μA at a drain voltage of 1V, although the number of GNRs in each transistor is unclear. 394
The performance is not yet as good as a counterpart using carbon nanotubes (CNTs) 395 but expected to improve further by, for
example, covering GNRs with hBN and realizing better contacts between GNRs and source/drain electrodes.
New principle devices using GNRs have also been proposed. One is a tunneling field-effect transistor (TFET). A higher on-
current than that of Si TFET has been predicted. 396 Use of strained graphene as a channel can also realize tunneling-like transport,
according to simulations. 397 A Klein-tunneling-based device has also been proposed. 398 Graphene can offer possibilities for
employing novel switching mechanism for future electronics.
Transition metal dichalcogenides (TMDCs) are another 2D material attracting attention. TMDCs have the chemical formula of
MX2, where M is a transition metal element and X is a chalcogen. They can be metallic, half-metallic, semiconducting, or
superconducting depending on their compositions. Molybdenum disulfide, MoS2, is probably the most popular semiconducting
TMDC, whose single layer was isolated for electrical measurements in 2005. 399 Electrical properties of semiconducting TMDCs
depend on the number of layers due to quantum confinement effects and changes in symmetry. For example, single-layer MoS2
has a direct band gap of 1.9 eV, while bulk MoS2 has an indirect bandgap of 1.2 eV. 400 The bandgaps also vary with the
compositions. For example, first principles calculations performed using the Heyd-Scuseria-Ernzerhof (HSE06) hybrid functional
show that MoS2, MoSe2, MoTe2, WS2, WSe2, and WTe2 have bandgaps of 2.02 eV, 1,72 eV, 1.28 eV, 1.98 eV, 1.63 eV, and 1.03
eV, respectively. 401
Transistors with TMDCs as a channel material have been demonstrated. Kis et al. fabricated a top-gate MoS2-channel transistor,
demonstrating a large ON/OFF ratio (~108) and good subthreshold swing (74 mV/decade). 402 Exfoliated single-layer MoS2 was
used in this experiment. However, field-effect mobility was relatively low (60-70 cm2/Vs). 403 In fact, transport in single-layer
TMDC is severely affected by the environment, often degrading its electrical property. It has actually been demonstrated that
mobility of TMDC increases with thickness. 404, 405 This is because influences of charged impurities in substrate decrease as the
thickness increases. As for MoS2, field-effect mobility as high as 480 cm2/Vs was obtained for a 47-nm thick MoS2 channel. 406
MoS2 is naturally electron-doped, which is possibly caused by chalcogen vacancies, while WSe2 is hole-doped. 407 It is actually
still difficult to control doping level of TMDCs, which is a major challenge to realize TMDC-based electronics. Incidentally,
Desai et al. fabricated MoS2-channel transistor with 1-nm gate lengths by using a CNT as a gate. 408 The ON/OFF ratio and
subthreshold swing were ~106 and 65 mV/decade, respectively. This is probably the shortest channel transistor ever made.
New principles devices using TMDCs have also been demonstrated. Sarkar et al. fabricated a tunneling FET (TFET) by placing
n-type MoS2 on top of p-type Ge, forming a p-n junction. 409 The TFET was gated by using a solid polymer electrolyte. The
subthreshold swing had an average of 31.1mV/decade for four decades of drain current at room temperature. Britnell et al.
prepared stacking structures consisting of graphene/MoS2/graphene and graphene/hBN/graphene, demonstrating a switching
device based on tunneling phenomena. 410 Although the tunneling devices introduced here can offer steep-slope switching
properties, on-current is relatively low, which is an important issue to address for real-world applications. Fabrication of a lateral
heterojunction of TMDCs, such as MoSe2 and WSe2, have also been demonstrated, 411 , 412 and a p-n junction by such a
heterojunction has been made. 413, 414 Valleytronics based on carriers located in two inequivalent valleys in the wave number space
also attract attention. 415, 416 New principles devices using TMDCs, as introduced here, may have good opportunities in future
electronics.
Growth technology of TMDCs is also in progress. In fact, the synthesis of TMDC film dates back to the 1980’s, when the growth
was performed with van der Waals epitaxy. 417 More recently, Lee et al. demonstrated CVD growth of MoS2 using MoO3 and S
powder as precursors. 418 , 419 The growth temperature was 650˚C. Single-crystal monolayer MoS2 flakes were successfully
obtained. This method was further improved and single-crystal MoS2 flakes as large as 120 μm in lateral size were obtained. 420
There have been a quite a few reports using similar methods for synthesizing TMDCs, including MoSe2, 421 WS2,418, 422 and
WSe2. 423 However, uniform growth over a large area is not easy using this powder-based CVD technique. In 2015, Kang et al.
succeeded in large area growth of MoS2 by MOCVD using Mo(CO)6 and (C2H5)2S as precursors. 424 The electron mobility of
MoS2 in this case was 30 cm2/Vs at room temperature. In general, mobility of CVD MoS2 is lower than that of exfoliated MoS2,
which is still an important issue to address. Furthermore, MoS2 deposition by using sputtering is also in progress. 425, 426, 427 The
sputtering method is scalable, but it is still difficult to obtain film with a quality as high as that by MOCVD.
3.2.4. TUNNEL FETS
Tunneling Field Effect Transistors (TFETs) have the potential to achieve a low operating voltage by overcoming the thermally
limited subthreshold swing voltage of 60 mV/decade by utilizing tunneling as a switching mechanism. 428,429,430 In its simplest
form, a TFET is a gated, reverse-biased p-i-n diode with a gate controlled intrinsic channel. There are two mechanisms that can
be used to achieve a low voltage turn on. The gate voltage can be used to modulate the thickness of the tunneling barrier at the
source channel junction and thus modulate the tunneling probability. 431 , 432 , 433 , 434 The thickness of the tunneling barrier is
controlled by changing the electric field in the tunneling junction. Alternatively, it is possible use energy filtering or density of
states switching. If the conduction and valence band do not overlap at the tunneling junction, no current can flow. Once they do
overlap, current can flow. Simulations have predicted arbitrarily steep subthreshold swings when relying on density of states
switching as the current is abruptly cutoff when the conduction band and valence band no longer overlap.430 If phonons or short
channel lengths are accounted for, simulated subthreshold swings on the order of 20–30 mV/decade are typical. 435 It is possible
to use the tunneling switching mechanisms in series with the standard MOSFET thermal switching mechanism to get an overall
subthreshold swing that is steeper than 60 mV/decade when no individual mechanism is steeper than 60 mV/decade. 436 The best
experimental results to date have relied on a combination of thermal switching and density of states switching. 437.So far, the
experimental results are far worse than simulated device characteristics. The review by Lu and Seabaugh428 shows a
comprehensive benchmarking of published experimental results prior to 2014. The benchmarking shows two problems with
TFETs as a MOSFET replacement: 1) Devices are unable to achieve SS <60 mV/decade over a large range or at useful current
levels and 2) The on-state current is too low for reasonable performance.
The review shows 14 reports of subthreshold swings below 60 mV/decade, and a few additional results have been published
since. Most of the results are for group-IV materials such as Si,433,438,439,440,441,442 strained SiGe, 443 Si/Ge, 444 and strained Ge. 445
Nanowire III-V TFETs have shown even steeper swings. An InP/GaAs heterojunction 446 has shown 30 mV/decade at 1 pA/μm.
The steepest result ever reported is in a Si/InAs heterojunction 447 of approximately 20 mV/decade at 0.1 pA/μm. However, there
are only a few data points defining this result. Even for low power applications, at least 1–10 μA/μm is needed. 448 Recently, a
promising InAs/GaAsSb/GaSb nanowire heterostructure TFET with a 48 mV/decade SS at 67 nA/μm and an I60 (current at
60 mV/decade) of 0.31 μA/μm was demonstrated.437
Researchers attempting to achieve higher on-current TFETs have traditionally relied on reducing the effective mass by using III-
V’s and reducing effective bandgap by using a heterostructure. While this has increased the current, the subthreshold swings and
off currents have gotten worse. The increase in off-state current and subthreshold swing needs to be decoupled from the increase
in on-state current. Unfortunately, this is a fundamental tradeoff when modulating the thickness of the tunneling barrier:429 barrier
thickness modulation only gives a step subthreshold swing at low current densities.
An ideal density of states (DOS) switch would switch abruptly from zero-conductance to the desired on-conductance thus
displaying zero subthreshold swing voltage. 449 Practically, the band edges are not perfectly sharp, so there is a finite density of
states extending into the band gap. Optical measurements of intrinsic GaAs imply a band edge steepness of 17 meV/decade. 450
However, the electrically measured joint DOS in diodes has generally indicated a steepness >90 mV/decade. 451 This broadening
is likely due to the spatial inhomogeneity and on heavy doping that appears in real devices. Effectively, there are many distinct
channel thresholds in a macroscopic device, leading to threshold broadening. Fortunately, it has been experimentally
demonstrated that a band edge worse than 60 mV/decade can be combined with a thermal switching mechanism to give an overall
subthreshold swing better than 60 mV/decade.436
TFETs are reverse-biased diodes hence are subject to generation in the depletion region. These generation events include but are
not limited to bulk and interface trap-assisted Shockley-Read-Hall (SRH) 452,453,454 and spontaneous and Auger generation. 455
Calculations based upon these mechanisms show that these significantly degrade the subthreshold swing and increase the leakage
currents but do not prevent TFETs from achieving sub-60 mV/decade subthreshold swing. Material defects and gate interface
traps make these effects worse and result in worse band edges.
To overcome these challenges, better material perfection than ever before is needed. Every defect or dangling bond can create a
trap that ruins the band edge or creates a parallel conduction path. The defects due to doping can be eliminated by electrostatically
inducing carriers. Proof of concept devices can be made by making the device a few nanometers large so that there is a low
probability of having a trap within the device. 2D transition metal dichalcogenides (TMD) heterostructures potentially have better
electrostatic control and lower defects as there are ideally no dangling bonds at the semiconductor oxide interface.
3.3. BEYOND-CMOS DEVICES: CHARGE-BASED
3.3.1. SPIN FET AND SPIN MOSFET TRANSISTORS
Spin-transistors are classified as “non-conventional charge-based extended CMOS devices,” 456 and can be further divided into
two categories: the spin-FETs proposed by Datta and Das 457 and spin-MOSFETs proposed by Sugahara and Tanaka. 458 The
structures of both types of spin transistors consist of a ferromagnetic source and a ferromagnetic drain which act as a spin injector
and a detector, respectively. Although the devices have similar structures, they have quite different operating principles.456,459 In
spin-MOSFETs, the gate has the same current switching function as in ordinary transistors, whereas in the spin-FETs, the gate
acts to control the spin direction via the Rashba spin-orbit interaction. Both types of devices behave as a transistor and function
as a magnetoresistive device. The important features of spin transistors are that they allow a variable current to be controlled by
the magnetization configuration of the ferromagnetic electrodes (spin-MOSFETs) or the spin direction of the carriers (spin-FETs),
and they offer the capability for non-volatile information storage using the magnetization configurations. These features are very
useful for energy-efficient, low-power circuit architectures that cannot be achieved by ordinary CMOS circuits. Non-volatile
logic and reconfigurable logic circuits have been proposed using the spin-MOSFET and the pseudo-spin-MOSFETs, which are
suitable for power-gating systems with low static energy.459,460,461,462,463,464,465
The full operation suggested for spin-FETs459,466 and spin-MOSFETs459,467,468,469,470 have not yet been experimentally verified.
For realizing fully functional spin transistors, some important progress in the underlying technologies such as electrical spin
injection, spin detection, and spin manipulation in semiconductors (SCs) should be required. 471,472,473 Lots of theories 474,475, 476,477
have predicted that the insertion of a tunnel barrier between the ferromagnet (FM) and SC is a promising method for highly
efficient electrical spin injection and detection.
Recently, large spin signals induced by the efficient spin injection and detection were observed in Si-based lateral spin-valve
devices with FM/MgO tunnel-barrier contacts even at room temperature. 478,479,480,481 Also, by using a back-gated device structure
with FM/MgO tunnel-barrier contacts,468,469,470 a basic read operation of Si-spin-MOSFETs was demonstrated at room
temperature. These are important developments for Si-based spin-MOSFETs. However, if an insulator tunnel barrier such as
MgO was utilized, the large parasitic resistance can cause the obstacle for the development of source and drain structures in the
spin transistors. Another key development for highly efficient spin injection/detection in SCs is half-metallic FM contacts. In
particular, electrical spin injection, transport, and detection in SCs without using insulator tunnel barriers have been demonstrated
in lateral spin-valve devices with Heusler alloy/SC Schottky-tunnel-barrier contacts. 482,483,484,485,486To reduce the value of RA at
the source and drain structures in spin-MOSFETs, the delta-doping of dopant impurities near the Heusler alloy/Ge Schottky-
tunnel-barrier 487 has been demonstrated, leading to the room-temperature spin transport 488 including local magnetoresistance
effect in Ge-based lateral devices with RA values of less than 0.2 kΩµm2. 489 Unfortunately, the MR ratio at room temperature in
the Ge-based lateral devices is still much low (< 0.001%) because of an imperfection of the Heusler alloy/Ge quality.489 For
enhancing the MR ratio in spin-MOSFET structures, it is essential to optimize the formation of high-quality Heusler alloy/SC
Schottky-tunnel contacts and to reduce the channel length between source and drain contacts.
Alternative approaches for realizing spin-MOSFETs have been proposed.459,464,467,490,491 Pseudo-spin-MOSFETs are circuits that
reproduce the functions of spin-MOSFETs using an ordinary MOSFET and a magnetic tunnel junction (MTJ) which is connected
to the MOSFET in a negative feedback configuration. Although pseudo-spin-MOSFETs offer the same functionality as spin
transistors, such as the ability to drive variable current, pseudo-spin-MOSFETs have larger resistance than spin-FETs or spin-
MOSFETs.
For spin manipulation in SCs, channel materials with a strong spin-orbit interaction, such as InGaAs, InAs and InSb, are
required459 in order to sufficiently induce the Rashba spin-orbit interaction by an electric gate voltage. Using InAs 492 and
InGaAs 493 2DEG heterostructures with and without FM spin injector and detector, respectively, the spin manipulation was
demonstrated by the electric field, meaning the operation of a spin-FET. However, the operation temperature was limited to the
low temperature less than 40 K. The experimental proof of electrical spin injection, detection and manipulation in SCs with the
strong spin-orbit interaction above room temperature is needed to create spin-FETs.
3.3.2. NEGATIVE GATE CAPACITANCE FET
Salahuddin and Datta originally proposed 494 that, based upon the energy landscape of ferroelectric capacitors, it should be
possible to implement a step-up voltage transformer that will amplify the gate voltage of a MOSFET. This would be accomplished
by replacing the standard insulator in the gate stack with a ferroelectric insulator of appropriate thickness. The resulting device is
called a negative gate capacitance FET or NCFET. The gate operation in this device would lead to subthreshold swing (STS)
lower than 60 mV/decade and might enable low voltage/low power operation. The main advantage of such a device 495 is that it
is a relatively straightforward replacement of conventional FETs. Thus, high Ion levels similar to advanced CMOS would be
achievable with lower voltages. An early experimental attempt to demonstrate a low-STS NCFET, based on a P(VDF-TrFE)/SiO2
organic ferroelectric gate stack, was reported 496 in 2008, and subsequently 497 in a more controlled structure in 2010. These
experiments established the proof of concept of sub-60 mV/decade operation using the principle of negative capacitance.
In addition to these experiments using polymer-based ferroelectrics, negative differential capacitance was demonstrated in a
crystalline capacitor stack. 498 Essentially, it was demonstrated that in a bi-layer of dielectric Strontium Titanate (SrTiO3: STO)
and Lead Zirconate Titanate (PbxZr1-xTiO3: PZT), the total capacitance is larger than what it would be for just the STO of the
same thickness as used in the bi-layer. This necessarily demonstrates the stabilization of PZT at a state of negative differential
capacitance. More recently, in a single PZT capacitor, a direct measurement of negative capacitance was demonstrated. 499 That
work determined that when a ferroelectric capacitor is pulsed with an input voltage, it shows an ‘inductance-like’ discharging in
addition to a capacitive charging.
As a recent significant result, it is now possible to grow ferroelectric materials using the atomic layer deposition process (ALD)
by doping the frequently used gate dielectric HfO2 by constituents such as Zr, Al or Si. 500 Using this doped Hf based ALD
ferroelectric, a number of experiments have demonstrated the negative capacitance effect. 501,502,503 For example, by using HfZrO2
as a gate dielectric, sub-60 mV/decade STS was demonstrated503 in finFETs with Lg=30 nm for both nFET and pFET structures.
In the last two years, multiple papers have reported this effect for various material systems and channel lengths. Significant among
them is the demonstration by GlobalFoundries of NCFETs in their 14 nm finFET technology, with improved subthreshold swing,
lower OFF current and lower active power and ring oscillators running at GHz speed. 504
3.3.3. NEMS SWITCH
Nano-Electro-Mechanical (NEM) switches use electrostatic force to mechanically actuate a movable structure to make or break
physical contact between current-conducting source and drain electrodes. When the electrodes are separated physically by an air
gap, no current flows across the gap, resulting in zero OFF-state current. The NEM switch undergoes an abrupt change in
current conduction ability between non-contacting and contacting states, with nearly zero subthreshold swing. 505 While zero
OFF-state current provides for zero standby power dissipation, zero subthreshold swing enables very low operating voltages for
low dynamic power dissipation as well. Moreover, a NEM switch can be operated with either positive or negative voltage polarity
due to the ambipolar nature of the electrostatic force, so that an electrostatically actuated NEM relay can be configured to turn on
either with increasing control (gate) voltage or with decreasing gate voltage and can serve as either a pull-down device (passing
a low voltage – ground – from the source to the drain, i.e. discharging the voltage at the drain) or a pull-up device (passing a
high voltage – VDD – from the source to the drain, i.e. charging the voltage at the drain). 506 Additional advantages of mechanical
devices include robust operation across a wide temperature range, down to cryogenic temperatures, 507 and immunity to ionizing
radiation. NEM switches can be monolithically integrated with CMOS circuitry by a modular post-CMOS fabrication process
with relatively low thermal budget. Since state-of-the-art CMOS technology incorporates air-gapped interconnects, 508 NEM
switches can be implemented using multiple interconnect layers formed in the back-end-of-line (BEOL) process. 509 Potential
applications for hybrid NEMS-CMOS technology include CMOS power gating, 510 configuration of FPGAs, 511 non-volatile back-
up storage of information in SRAM and CAM cells,509 and energy-efficient, fast and reconfigurable look-up tables. 512
Conventional planar processing techniques (i.e., thin-film deposition, lithography and etch processes) can be employed to
fabricate the conducting electrodes of a mechanical switch. The air-gaps between electrodes are formed with a final “release”
etch step in which a sacrificial material such as silicon dioxide, photoresist, polyimide or silicon is selectively removed. The
switching delay and operating voltage of a NEM switch can be reduced by scaling down the size of these air-gaps. The smallest
air-gap demonstrated to date for a functional NEM structure fabricated using a top-down approach is 4 nm, resulting in an
actuation voltage of approximately 0.4 V. 513 As expected, it exhibited very low OFF-state current and sub-threshold swing;
however, it is only a 2-terminal device, not suitable for logic switch application. SiC nanowires have been used as the movable
structure for NEM switches that are suitable for high-temperature operation. Functioning 2-terminal SiC switches with air-gaps
as small as 10 nm and switching voltage as low as 1V have been demonstrated. 514 3-terminal devices and corresponding logic
gates also were demonstrated. 515 Piezoelectric materials have been incorporated in NEM devices to enable sub-1V switching 516.
The operating speed of a NEM switch is much slower than that of a transistor because it is dominated by mechanical delay related
to the physical motion of the movable structure rather than the electrical (charging/discharging) delay; therefore an optimized
relay-based IC design should arrange for all mechanical movements to happen simultaneously, so that the delay per operation is
essentially one mechanical delay.506 For a pass-gate circuit topology, multiple switches are connected together in series to drive
the output signal. This means that the source voltage can vary between the reference voltage (ground) and the supply voltage
(VDD). For proper pass-gate circuit operation, the state of the switch cannot be dependent on the source voltage; therefore a fourth
electrode is necessary to provide a constant reference voltage, such that the voltage applied between the control (gate) electrode
and the reference (body) electrode determines the state of the switch, i.e. whether a current path is established between the source
and drain electrodes. 517 The contact and actuation air-gaps can be reduced by biasing the body electrode to reduce the magnitude
of the gate voltage required to switch the device ON/OFF. Moreover, a constant-field scaling methodology can be applied to
miniaturize NEM switches for reduced footprint, switching delay and switching energy. 518 With the aid of body biasing, the
minimum switching energy for a nanoscale relay is anticipated to be on the order of 10 aJ, which compares well against the
switching energy for an ultimately scaled MOSFET. 519, 520 Piezoelectric NEM devices have demonstrated 10 mV switching
operation using body bias, providing for very low energy dissipation per switching cycle (23 aJ), and an extremely small
subthreshold slope (0.013 mV/decade)516. A variety of relay-based computational and memory building blocks have been
experimentally demonstrated to date. 521,522
The prospective system-level benefits of mechanical logic have been analyzed by performing simulation-based assessments of
VLSI circuit blocks implemented with NEM switches. These indicate that relays can provide for more than 10x reduction in
energy per operation as compared with MOSFETs, and can reach clock speeds in the GHz regime. 523 Thus, a major potential
advantage of NEM switch technology is improved energy efficiency. Moreover, the contact adhesive force and structural
stiffness can be engineered to achieve bi-stable operation, which makes mechanical switches attractive for embedded non-volatile
memory applications. 524 Recently hybrid CMOS-NEMS circuits have been demonstrated, with non-volatile NEM switches
operating at the same VDD as for the CMOS circuitry. 525 The BEOL metallic layers used to form interconnects in a conventional
CMOS process can be leveraged to implement compact NV-NEM switches for dynamically reconfigurable circuit functionality 526.
For all of the aforementioned applications, the NEM switches need to operate reliably and consistently for at least 109 cycles.
Due to the extremely small mass of the movable electrode (less than 1 ng), neither gravitational acceleration nor mechanical
vibration substantially affects their operation. Structural fatigue or creep can be easily avoided by designing the movable
structure/anchor such that the maximum induced strain is well below the yield strength. However, permanent stiction can be a
mode of device failure: for soft electrode materials such as gold and platinum, Joule heating at the contacting asperities can lead
to atomic diffusion (welding). This issue can be mitigated by using a refractory electrode material such as tungsten to minimize
contact wear and by reducing the peak voltage difference between the source and drain electrodes (VDD) when they are in contact.
NEM switches with tungsten electrodes have been demonstrated to have endurance up to 1 billion ON/OFF cycles at 2.5 Volts
for a relatively large load capacitance of 300 pF (i.e. exaggerated electrical delay), and endurance exceeding 1016 ON/OFF cycles
is projected for voltages below 1 Volt and load capacitance below 1 pF. 527 The remaining reliability challenge for NEM logic
switches is degradation (dramatic increase) of on-state resistance due to electrode surface oxidation or the formation of friction
polymers during the course of device operation. Alternative contacting electrode materials such as Ru/RuO2 and/or hermetic
packaging are potential solutions to this issue.
Adhesive force between the contacting electrodes dictates the minimum required stiffness of the movable structure, which in turn
determines the minimum gate-to-body voltage required to switch the NEM relay. The adhesion energy is determined by metallic
bonding (at the contacting asperities) and by van der Waals force (in the non-contacting regions of the electrodes). Self-assembled
molecular (SAM) coating of hydrophobic materials has been demonstrated to reduce the adhesive force and thereby enable
switching operation at lower gate voltage. 528 Sub-50 mV operation of relay integrated circuits demonstrating OR, AND, and
XOR gate functionality have been demonstrated with body-biased SAM-coated NEM switches. 529 Most recently, operation of
NEM switches and integrated circuits at temperatures down to 4K were demonstrated for the first time. 530 Due to reduced
adhesion energy and elimination of contact oxidation, relays can be operated reliably with voltages as low as 25 mV for more
than 108 cycles at cryogenic temperatures, showing promise for monolithic integration of multiplexing control circuitry with
qubits.
In conclusion, the negligible OFF-state current and ultra-low-voltage operation capability of NEM switches make them
compelling for ultra-low-power digital computing applications such as the Internet of Things, particularly where resilience to
extreme temperatures and/or immunity to radiation are required. Furthermore, hybrid CMOS-NEM technology shows promise
for enhanced chip functionality, e.g. with dynamically reconfigurable interconnects. Remaining challenges to realizing the
promise of mechanical computing include materials and process optimization to achieve stably low contact resistance with
minimal contact adhesive force.
3.3.4. MOTT FET
Mott field-effect transistor (Mott FET) utilizes a phase change in a correlated electron system induced by a gate as the fundamental
switching paradigm. 531,532 Mott FETs could have a similar structure as conventional semiconductor FET, with the semiconductor
channel materials being replaced by correlated electron materials. Correlated electron materials can undergo Mott insulator-to-
metal phase transitions under an applied electric field due to electrostatically doped carriers. 533,534 Besides electric field excitation,
the Mott phase transition can also be triggered by photo- and thermal-excitations for optical and thermal switches. Defects created
by environmental exposure to chemicals or electrochemical reactions can also induce Mott transition via carrier doping. The
critical threshold for inducing phase change can be tuned via stress.
Mott FET structure has been explored with different oxide channel materials.532 Among several correlated materials that could
be explored as channel materials for Mott FET, vanadium dioxide (VO2) has attracted much attention due the sharp metal-
insulator transition near room temperature (nearly five orders in single crystals). 535 The phase transition time constant in VO2
materials is in sub-picosecond range determined by optical pump-probe methods. 536 Device modeling indicates that the VO2-
channel-based Mott FET lower bound switching time is of the order of 0.5 ps at a power dissipation of 0.1 µW. 537 VO2 Mott
channels have been experimentally studied with thin film devices and the field effect has been demonstrated in preliminary device
structures. 538, 539, 540 Recently, prototypes of VO2 transistors using ionic liquid gating have shown larger ON/OFF ratio at room
temperature than with solid gate dielectrics like hafnia. 541, 542 The conductance modulation happens at a slow speed, however,
due to the large charging time constants. 543 The possibility of electrochemical reactions must also be carefully examined in these
proof-of-principle devices due to the instability of the liquid-oxide interfaces and the ease of cations in such complex oxides to
change valence state.543, 544, 545 On the other hand, unlike traditional CMOS that is volatile and digital, electrochemically gated
transistors exhibit non-volatile and analog behaviors, which can be utilized to demonstrate synaptic transistors 546 and circuits 547
that mimic neural activities in the animal brains. Voltage induced phase transitions in two-terminal Mott switches have also been
implemented to realize neuron-like devices 548 and steep-slope transistors. 549 As a Mott device with purely electrostatic
modulation in the solid-state base, 550 the VO2-FET with a high-k oxide/organic hybrid dielectric gate has been proposed. 551,552
Their reversible as well as quick resistance switching upon an application of gate bias and the maximum resistance modulation
at the Metal-Insulator transition temperature indicate the possibility of purely electrostatic field-induced metal-insulator (Mott)
transition. The gate-tunable abrupt switching device based on a VO2 microwire integrated monolithically with a two-dimensional
tungsten diselenide semiconductor by van der Waals stacking has been reported. 553 Nanofabrication engineering is considered to
possess the possibility to enhance the performance of Mott FET. The 3-dimentional Fe3O4 nanowires on the length scale of 10
nm exhibited the remarkable Verwey transition at about 112 K, which was found to be 6 times larger than that for the thin-film
configuration. 554
Experimental challenges with correlated electron oxide Mott FETs include fundamental understanding of gate oxide-functional
oxide interfaces and local band structure changes in the presence of electric fields. Methods to extract quantitative properties
(such as defect density) of the interfaces are an important topic that have not been explored much to date. The relatively large
intrinsic carrier density in many of the Mott insulators requires the growth of ultra-thin channel materials and smooth gate oxide-
functional oxide interfaces for optimized device performance. It is also important to understand the origin of low room-
temperature carrier mobility in these materials.533 Theoretical studies on the channel/dielectric interfacial electronic band structure
are needed for the modeling of subthreshold behaviors of Mott FETs. Understanding the electronic transition mechanisms while
de-coupling from structural Peierls (lattice) distortions is also of interest and important in the context of energy dissipation for
switching.
While the electric field-induced transitions are typically explored with Mott FET, nanoscale thermal switches with Mott materials
could also be of substantial interest. Recent simulation studies of “ON and “OFF” times for nanoscale two-terminal VO2 switches
indicate the possibility of sub-ns switching speeds in ultra-thin device elements in the vicinity of room temperature. 555,556 Such
devices could also be of interest to Mott memory. 557 One can, in a broader sense, visualize such correlated electron systems as
‘threshold materials’ wherein the conducting state can be rapidly switched by a slight external perturbation, and hence lead to
applications in electron devices. Electronically driven transitions in perovksite-structured oxides such as rare-earth
nickelates 558,559 or cobaltates 560 with minimal lattice distortions would also be relevant in this regard. Three-terminal devices are
being investigated using these materials and will likely be an area of growth. 561,562,563, 564,565 SmNiO3, with its metal-insulator
transition temperature near 130ºC and nearly hysteresis-free transition, is particular interesting due to the possibility of direct
integration onto CMOS platforms. Floating gate transistors have recently been demonstrated on silicon. 566 It has been found that
non-thermal electron doping in SmNiO3 can lead to a colossal increase in its resistivity, which has been utilized to demonstrate a
solid-state proton-gated transistor with large ON/OFF ratio. 567 Clearly, these preliminary results suggest the promise of correlated
oxide semiconductors for logic devices, while the doping process indicates slower dynamics than possible with purely
electrostatic carrier density modulation. The non-volatile nature of the Mott transition in 3-terminal devices suggest combining
memory operations into a single device and could be explored further. Architectural innovations that can create new computing
modalities with slower switches but at lower power consumption can benefit in the near term with results to date while in the
longer term transistor gate stacks need to be studied further for these classes of emerging semiconductors
3.3.5. TOPOLOGICAL INSULATOR ELECTRONIC DEVICES
Topological insulators are recently discovered materials which possess a bandgap in their interior, however the topology of their
electronic states necessitates that the existence of gapless, conducting modes on their boundaries – one dimensional (1D) edges
in the case of two-dimensional (2D) topological insulators, and 2D surfaces in the case of three-dimensional (3D) topological
insulators. 568,569,570,571 These conducting modes are protected from backscattering by symmetry, and in the case of 1D edge modes
of 2D topological insulators, are expected to be ballistic conductors.
Systematic searches of materials databases have found that topological materials are commonplace, representing a significant
fraction of all known materials. 572,573,574 Two-dimensional topological insulators have been realized with very large bandgaps of
360 meV (Na3Bi 575) and 800 meV (bismuthine 576), significantly exceeding the thermal energy at room temperature (25 meV),
which indicates that topological phenomena may be robust at room temperature in suitable materials.
Numerous proposals have been put forward to exploit topological materials in transistor design. 577,578,579,580,581,582,583,584, 585, 586
One topological transistor design envisions switching a 2D material from topological insulator (“ON” with ballistic edge
channels) to a conventional insulator (“OFF”). This switching may be accomplished via electric field through several mechanisms
such as Rashba effect,577 staggered sublattice potential,577,579,585 inversion symmetry breaking,580 or Stark effect.581,582,583,584,575
Electric field effect switching has been proposed in a number of materials including graphene,577 monolayer transition metal
dichalcogenides in 1T’ phase,581 SnTe and Pb1-xSnxSe(Te),580 topological semimetals such as Cd2As3 and Na3Bi,582,575 and
phosphorene.583 Electric-field switching of the topological state has been demonstrated in at least one material Na3Bi.575 Other
transistor proposals have focused on electric-field switching of tunneling between topological edges, 587 or using strong disorder
to produce an off state in a bulk conducting topological insulator.586 Topology may also be controlled by magnetic fields, 588,589
strain, 590 temperature, 591 or time-dependent electric fields, 592 hence topological devices have the prospect of adding additional
new functionality for “More than Moore” devices.
The deep connection between topological insulators and spin-orbit coupling suggests further synergies between topological
electronics and spin electronics. Indeed, 2D topological insulators exhibit a quantized spin Hall effect and can be used to produce
completely polarized spin current,577 of potential use in spintronics devices. Magnetic 2D topological insulators (quantum
anomalous Hall effect) may produce perfectly spin polarised current with spin direction determined by magnetization direction, 593
opening new possibilities for spin transistors and non-volatile random-access memory. Near-perfect ballistic conduction in the
quantum anomalous Hall regime with current-induced magnetization switching at very low currents (1 nA) was recently
demonstrated in graphene/boron nitride heterostructures 594 albeit at cryogenic temperatures. Analogous topological effects may
be realized for other degrees of freedom such as the valley degree of freedom in materials with multiple conduction valleys, with
analogous quantum valley Hall effects switchable by electric field. 595,596,597
Numerous fundamental research challenges remain before topological transistors may become useful. Topological switching via
electric field effect is a fundamentally different mechanism of operation compared to the traditional MOSFET. At present it is
unclear what limits the subthreshold swing and therefore the operating voltage of a topological transistor, and how this depends
on the specific mechanism of electric field switching. Detailed models and device simulations for topological transistors are
needed, as well as experiments on electric-field switching of topological materials in realistic device geometries. It is likely that
new topological materials are needed that optimize large bandgaps and sensitive electric field-driven switching, as well as are
amenable to device fabrication and processing. Realistic theoretical models will be needed to guide materials discovery and
device design.
3.4. BEYOND-CMOS DEVICES: ALTERNATIVE INFORMATION PROCESSING
3.4.1. SPIN WAVE DEVICE
Spin Wave Device (SWD) is a type of magnetic logic devices exploiting collective spin oscillation (spin waves) for information
transmission and processing. 598, 599, 600, 601, 602 The basic elements of the SWD include: (i) magneto-electric cells (e.g. multiferroic
elements) aimed to convert voltage pulses into the spin waves and vice versa; 603, 604 (ii) magnetic waveguides - spin wave buses
for spin wave signal propagation between the magneto-electric cells, 605 (iii) magnetic junctions to couple two or several
waveguides, 606 (iv) spin wave amplifiers, 607 (v) phase shifters to control the phase of the propagating spin waves, 608 and (vi) spin
wave phase error correctors. 609 SWD converts input voltage signals into the spin waves, computes with spin waves, and converts
the output spin waves into the voltage signals. Computing with spin waves utilizes spin wave interference, which enables
functional nanometer scale logic devices. Since the first proposal on spin wave logic,598 SWD concept has evolved in different
ways encompassing volatile 610 and non-volatile, 611 Boolean611, 612 and non-Boolean, 613 single-frequency and multi-frequency
circuits. 614 The primary expected advantage of SWD over Si CMOS are the following: (i) the ability to utilize phase in addition
to amplitude for building logic devices with a fewer number of elements than required for transistor-based approach; (ii) power
consumption minimization by exploiting the intrinsically low energy (µeV) of spin waves in ferromagnets as well as built-in non-
volatile magnetic memory and magnetic reconfigurability 615, and (iii) parallel data processing on multiple frequencies in a single
core structure by exploiting each frequency as a distinct information channel.
Micrometer-scale SWD MAJ gate has been experimentally demonstrated. 616 It is based on ferromagnetic Ni81Fe19 structure,
operates within 1-3 GHz frequency range, and exhibits signal-to-noise ratio of approximately 10 at room temperature.616 The
internal delay of SWD is defined by the spin wave group velocity (e.g. 3×106 cm/s in Ni81Fe19 waveguides). Power dissipation in
SWD is mainly defined by the efficiency of the spin wave excitation. Recent experiments with synthetic multiferroics comprising
piezoelectric (lead magnesium niobate-lead titanate PMN-PT) and magnetostrictive (Ni) materials have demonstrated spin wave
generation by relatively low electric field (e.g. 0.6 MV/m for PMN-PT/Ni). 617 The later translates in ultra-low power consumption
(e.g. 1aJ per multiferroic switching). Recent experimental demonstration604 of parametric spin wave excitation by voltage-
controlled magnetic anisotropy (VCMA) is another promising route towards energy-efficient generation of spin waves.
Recently, a new type of SWD magnonic holographic memory (MHM), was proposed.613 The principle of operation of MHM is
similar to optical holographic memory, while spin waves are utilized instead of light waves. The first 2-bit MHM prototype based
on yttrium iron garnet structure has been demonstrated. 618 MHM also possesses unique capabilities for pattern recognition by
exploiting correlation between the phases of the input waves and the output interference pattern. Pattern recognition using MHM
has been recently demonstrated. 619 The potential advantage of spin wave utilization includes the possibility of on-chip integration
with the conventional electronic devices via multiferroic elements. In addition, magnonic holograms can show very high
information density (about 1Tb/cm2) due to the nanometer scale wavelength of spin waves. According to estimates, the functional
throughput of magnonic holographic devices may exceed 1018 bits/s/cm.2,613
There are several important milestones crucial for further SWD development: (i) nanomagnet switching by spin waves; 620 (ii)
integration of several magneto-electric cells on a single spin wave bus. In order to have an advantage over CMOS in functional
throughput, the operational wavelength of SWDs should be scaled down below 100 nm.611 The success of the SWD will also
depend on the ability to restore/amplify spin waves (e.g. by multiferroic elements or spin torque oscillators). Another recent
direction of research is antiferromagnetic SWD 621 that potentially offer a thousand-time increase in operation speed due to THz
scale frequencies of antiferromagnetic spin waves.
3.4.2. EXCITONIC DEVICES
Excitonic devices are based on excitons as computational state variables. Excitonic devices are suited to the development of an
advanced energy-efficient alternative to electronics due to the specific properties of excitons: 1) Excitons are bosons and can
form a coherent condensate with vanishing resistance for exciton currents and low switching voltage for excitonic transistors.
This allows creating energy-efficient computation with power consumption per switch significantly smaller than in electronic
circuits. 2) Excitonic signal processing can be directly coupled to optical communication in exciton optical interconnects. 3) The
sizes of excitonic devices are scaled by the exciton radius and de Broglie wavelength that are much smaller than the photon
wavelength. Furthermore, excitons can be efficiently controlled by voltage. This gives the opportunity to realize excitonic circuits
at scales much smaller than for photonic devices.
The advantages listed above are realized using specially designed indirect excitons, IXs. An IX is a bound pair of an electron and
a hole in separated layers. The properties of IXs make them different from conventional excitons and suitable for the development
of energy-efficient computing: 1) IXs have oriented electrical dipole moments. As a result, the IX energy and IX currents are
controlled by voltage allowing the realization of a field effect transistor operating with IXs in place of electrons. 2) The IX
emission rate can be tuned over many orders of magnitude. Turning the emission off allows the realization of multi-element IX
circuits with suppressed losses while turning it on allows fast write and readout. 3) The low overlaps between electrons and holes
in IXs allow the realization of a coherent condensate with the suppressed thermal tails and dissipationless IX currents enabling
energy-efficient computation.
Experimental proof-of-principle for excitonic devices including IX transistors, 622 diodes, 623 and CCD 624 was demonstrated. IX
condensate and coherent IX currents 625 and, recently, long range coherent IX spin currents 626 were observed at low temperatures.
New heterostructures based on single-atomic-layers of transition-metal dichalcogenide (TMD) for room-temperature IX circuits
were proposed. 627 Recent progress includes the realization of IXs at room temperature in TMD heterostructures, 628 discovery of
IX coherent spin currents in GaAs heterostructures 629 , development of first split-gate device for IXs, the basic mesoscopic
device 630, development of advanced platform for high-mobility excitonic devices 631, development of TMD heterostructures with
small IX linewidth and finding charged IXs, indirect trions. At present, the studies are focused on the development of basic
concepts of excitonic devices at low temperatures using GaAs heterostructures and development of room-temperature excitonic
devices using TMD heterostructures.
3.4.3. TRANSISTOR LASER
The Light-Emitting Transistor (LET) 632 and Transistor Laser (TL) 633,634 utilize a fundamental characteristic of bipolar transistors
- that electron-hole recombination in the base is an essential feature of the transistor and that the resulting photon signal in a
direct-bandgap base is correlated to the electrical signal driving and being driven by the device. The TL can be thought of as a 5
terminal heterojunction bipolar transistor (HBT) with 3 conventional electrical terminals (emitter, base, and collector) and 2
optical terminals (input-generation and output-recombination). 635 Very-high-speed transmission and processing are enabled by
the projected capability to achieve over 200 GHz bandwidths in the GaAs- or InP-based devices. 636 An advantage of the TL is
that a single epitaxial layer structure can be used for devices that generate photons, detect photons, and perform electronic
functions. The layer structure of the TL resembles a heterojunction bipolar transistor with features added to enhance base
recombination and control base transit time.634,637 When used to realize conventional logic architectures, for example NOR
gates, 638 the key advantage is speed. With processing-intensive operations and using the energy-delay product as a metric for
comparison, a 30–100 times improvement is expected over conventional CMOS, leading to both faster processing and improved
energy efficiency. An even greater benefit might be achieved through the use of architectures that perform electronic-photonic
processing in the analog domain.
The first demonstration of lasing in the TL occurred in 2004. Since that time, progress has been made on understanding the device
physics and on using the TL for discrete optical interconnects. A key initial objective has been examining factors affecting device
bandwidth. Edge-emitting TLs with large active regions (200 μm × 1 μm) have been modulated to 22 Gbps and have shown a
measured bandwidth of 10.4 GHz. 639 Relative intensity noise (RIN) as low as -151 dB/Hz has also been demonstrated, showing
an approximately 28 dB improvement over diode lasers. 640 To improve speed and enable integration, reducing the size of the
active region is critical. For that reason, Vertical-Cavity Transistor Lasers (VCTL) have been examined and demonstrated. 641
Initial VCTLs had limited temperature range due to misalignment of the cavity reflectivity and gain peaks. More recently, work
has been underway to show that electronic-photonic logic can be made using the transistor laser. The initial target of an integrated
TL-based NOR gate has been demonstrated, but significant work is needed to improve performance. 642
The ultimate performance in both power and speed will be achieved as the device is size is scaled, as projected performance to
bandwidths in excess of 100 GHz has a sound rationale but has yet to be realized. The use of vertical-cavity structures to reduce
the device footprint has been a first step in the scaling process but further work is needed on microcavity vertical-cavity transistor
lasers (VCTLs). Scaling beyond micron-scale devices such as this is possible, but the key will be the design of optical structures
such as photonic crystal cavities that will enable small numbers of photons to be captured and directed to act on other TL
structures. As scaling advances, further examination of device physics to reduce the effective minority carrier radiative lifetime
will be key, along with the examination of effects that might impact the modulation response. Further work is also needed on
InP-based devices (1310 and 1550 nm emission) to facilitate the use of silicon waveguides for optical signal routing. Additional
questions at the architecture level involve the best way to use the TL in computer systems. What is enabled by having very high
speed optical links? What architectures make sense for electronic-photonic NOR gates? Are other approaches to computation
enabled, such as analog methods? Initial work to address how the TL might impact computer architecture has been underway in
the Li group at the University of Chicago, in collaboration with the University of Illinois at Urbana-Champaign. 643 Further work
on how TLs might be used in machine learning applications is also underway by this group (unpublished). Other noteworthy
results include demonstration of blue-emitting light-emitting transistors in the GaN/InGaN system. 644
3.4.4. MAGNETOELECTRIC LOGIC
There have been major developments, involving magneto-electric transistor (MEFET) schemes, increasing the range of possible
magneto-electric devices, that would serve as "beyond CMOS" 'plug-in' replacement logic. 645,646,647,648,649,650 There are also some
benchmarking efforts,647,648,649,650 where there has been an effort to compare the most competitive magneto-electric devices with
CMOS.647,648,649,650 The result is that it is now increasingly clear that magneto-electric field effect transistors are more likely to be
competitive or surpass CMOS647,648,649,650 than the earliest magneto-electric device concepts were based on a magnetic tunnel
junction structure. 651,652 The disadvantage, with the magneto-electric magnetic tunnel junction device structure, is that while much
faster than many spintronics devices, there are long delay times in device operation, due to the slow speed of switching a
ferromagnet,647 and the predicted fidelity is likely low, making it difficult to cascade from one device to the next.
Other magneto-electric devices, like the composite–input magnetoelectric–based logic technology (CoMET) 653 and a similar
magneto-electric device structure, but using spin-orbit coupling, have also been proposed. 654 The concern is that both these device
concepts will have long delay times, due to the slow switching speed of the ferromagnetic layer, and in the case of the CoMET
device, the additional complications of the slow speed of ferromagnetic domain wall propagation. are limited by the switching
speed of the ferroelectric and domain wall motion.653,654 The basis of these devices is an input switches a ferroelectric material,
in contact with a ferromagnet with in-plane magnetic anisotropy placed on top of an intra-gate ferromagnet interconnect with
perpendicular magnetic anisotropy. The input voltage nucleates a domain wall while a current is used to drive the domain wall to
the output end of the device. Also using spin orbit coupling, but now explicitly also using a magneto-electric layer for electrical
control of exchange bias of a laterally scaled spin valve is the nonvolatile magneto-electric spin-orbit (MESO) logic, 655 but the
delay time is limited again by the switching speed of the ferromagnetic layer, although 50 ps switching speeds as short as have
been estimated.655
Magneto-electric transistor schemes are based on polarization of the semiconductor channel, by the boundary polarization of the
magneto-electric gate. The advantage to the magneto-electric field effect transistor is that such schemes avoid the complexity and
detrimental switching energetics associated with magneto-electric exchange-coupled ferromagnetic devices. Spintronic devices
based solely on the switching of a magneto-electric, will have a switching speed will be limited only by the switching dynamics
of that magneto-electric material and above all are voltage controlled spintronic devices. Moreover, these magneto-electric
devices promise to provide a unique field effect spin transistor (spin-FET)-based interface for input/output of other novel
computational devices. This is spintronics without a ferromagnet, with faster write speeds (<20 ps/full adder), at a lower cost in
energy (<20 aJ/full adder),647,648,649,650 greater temperature stability (operational to 400 K or more 656), and scalability, requiring
far fewer device elements (transistor equivalents) than CMOS. These do differ from the conventional field transistor in that the
ME-FET must be both top and bottom gated, so the result is that these are 4, not 3 terminal transistors.645,646,647,648,649,650
Obviously, the semiconductor channel will only work if the very thin, so the boundary polarization of chromia 657,658 effectively
polarizes the semiconductor channel.645,646,647 The 2D semiconductors of the trichalcogenide class of quasi one-dimensional
semiconductors, such as TiS3, HfSe3, 659 as well as InP, have the potential to be scaled to transistor widths below 10 nm suggesting
there is a plausible route forward.647
The anti-ferromagnet spin-orbit read (AFSOR) logic device structure has interesting advantages: the potential for high and sharp
voltage ‘turn-on’; inherent non-volatility of magnetic state variables; absence of switching currents; large on/off ratios; and
multistate logic and memory applications. The design will provide reliable room-temperature operation with large on/off ratios
(>107) well beyond what can be achieved using magnetic tunnel junctions.646,647,660 Again, the core idea is the use of the boundary
polarization of the magneto-electric to spin polarize or partly spin polarize a very thin semiconductor, ideally a 2D material, with
very large spin orbit coupling.
If the semiconductor channel retains large spin orbit coupling, then the spin current, mediated by the gate boundary polarization,
may be enhanced and, to some extent, topologically protected. The latter implies that each spin current has a preferred direction.
The silicon CMOS majority gate (left) requires 13 components. The ME-spinFET majority gate requires, including clocking, of
6 components. This represents an area improvement of over 50%, assuming similar size transistors.647 This is equivalent to greater
than one process node. If we split the magnetoelectric side of the gate so that the channel can independently be spin polarized up
or down, this results in a component reduction from the previous best for the MEFET of six, down to four components, a further
50% reduction over the standard MEFET circuit, and a reduction to less than 30% in area compared to CMOS.647
A majority gate, in the form of a single transistor like device, has also been proposed and modeled,648 but depends on the device
scaled to dimensions smaller than the natural antiferromagnetic domain size of about 1 to 3 µm.658
There is a variant where inversion symmetry is not as strictly broken, that leads to a nonvolatile spintronics version of multiplexer
logic (MUX).646,647,660 The magneto-electric spin-FET multiplexer also exploits the modulation of the spin-orbit splitting of the
electronic bands of the semiconductor channel through a “proximity” magnetic field derived from a voltage-controlled magneto-
electric material. Here, by using semiconductor channels with large spin-orbit coupling, we expect to obtain a transverse spin
Hall current, as well as a spin current overall. Depending on the magnitude of the effective magnetic field in the narrow channel,
we anticipate two different operational regimes. Like the AFSOR magneto-electric spin FET, the magneto-electric spin-FET
multiplexer uses spin-orbit coupling in the channel to modulate spin polarization and hence the conductance (by spin) of the
device.646,647 There is a source-drain voltage and current difference, between the two FM source contacts, due to the spin-Hall
effect when spin-orbit coupling is present. This output voltage can be modulated by the gate or gates, which influences the spin-
orbit interaction in the channel especially when it is both top and bottom gated especially. The spin-Hall voltage in the device
can be increased by using different FMs in the source and drain. To increase the spin fidelity of current injection at the source
end, one could add a suitable tunnel junction layer (basically a 1nm oxide layer) between the magnetic source and the 2D
semiconductor channel. This latter modification would result in diminished source-drain currents though. Again, there is a
reduction is delay time and energy cost because these devices are nonvolatile, there is no magnetization reversal of a ferromagnet
involved and the implementation of this device concept would require only 5 components for a majority gate compared to the 13
components required of a silicon CMOS majority gate.647
Magneto-electric coupling can be used to excite parametric resonance of magnetization by an electric field. 661 This has been
considered for the development of spin wave devices based on voltage controlled magnetic anisotropy in in ferromagnetic
nanowires. 662 This in turn, in effect, becomes a spin wave field effect transistor. The threshold voltage for parametric excitation
in this system is found to be well below 1 V, which is attractive for applications in energy-efficient spintronic and magnonic
nanodevices such as spin wave logic.
The challenges in pushing forward these technologies extends not only to the fabrication and characterization of a new generation
of nonvolatile magneto-electric devices, but also to ascertaining the optimal implementation of CMOS plug in replacement
circuits. Questions that need to be resolved include demonstration that the magneto-electric devices can be scaled to less than 10
nm, and this includes finding a suitable 2D channel material that can be polarized by exchange coupling with the boundary
polarization of the magneto-electric and yet does not suffer from large scale edge scattering. Experimental demonstration of limits
to the switching speeds of any antiferromagnetic magnetic electric remain absent. That said, the magneto-electric transistor has
far fewer challenges to implementation than the magneto-electric magnetic tunnel junction, so, not surprisingly, there is a shifting
of development effort toward those and related devices for both memory and logic.647 New device concepts are being considered
as well. These device concepts have advantages like reducing the number of leakage pathways to just one and require only one
clock cycle. The actual demonstration of such devices appears almost "in hand" suggesting that experimental evidence of promise
is not that far away.
3.4.5. DOMAIN WALL LOGIC
The domain wall-magnetic tunnel junction (DW-MTJ) or three-terminal magnetic tunnel junction (3T-MTJ) operates as an in-
memory computing nonvolatile logic device through current-driven manipulation of a single domain wall in a ferromagnetic
patterned wire, 663,664,665 with readout performed using a magnetic tunnel junction. It can be considered as an extension of racetrack
memory to a single domain wall racetrack for compute-in-memory applications.
The domain wall track is composed of heavy metal/ferromagnet/oxide thin films patterned into a wire shape. Standard materials
examples are Ta/CoFeB/MgO. On top of the track is a patterned MTJ hard reference layer with additional related thin films to
promote high switching field of the hard layer compared to the ferromagnetic track.
The ends of the ferromagnetic track can be exchange-biased in opposing directions using antiferromagnets, and/or an additional
electrode can be used to ensure a single domain wall is created in the track.
The simplest form of the device has three terminals: input (IN) and clock (CLK) contacting the ferromagnetic track, and output
(OUT) contacting the top of the MTJ. During the write operation, a voltage applied between IN and CLK drives a current and
moves the domain wall using either spin transfer torque (STT) and/or spin orbit torque (SOT). During the read operation, a voltage
applied between CLK and OUT measures the resistance state of the MTJ relative to the domain wall, which will determine the
amount of current to drive subsequent devices. The device can act as an analog universal NAND gate, in addition to other basic
logic gates: if IN is connected to the OUT of two previous devices, and only if both are in a low resistance state (logic output 1)
will there be sufficient current to depin and move the domain wall to the other side of the MTJ, changing the output of the device
from a low resistance state (logic output 1) to high resistance state (logic output 0).
A related device is the mLogic four-terminal version, which has an additional non-magnetic, non-conducting spacer on top of the
ferromagnetic track that couples the current-manipulated domain wall to a domain wall or nanomagnet in an electrically-separated
layer, which then alters the output MTJ resistance. 666,667,668,669,670 The additional terminal comes from two terminals connected
to the output MTJ. The four-terminal version provides complete input/output isolation.
The device operation has been modeled in micromagnetics including NAND, shift register, and full adder functions,664 and initial
benchmarking was performed up to a full adder simulation. 671,672,673 A SPICE model has been developed to enable larger scale
circuit simulations. 674 Single device operation and three-device circuit operation has been shown in experimental prototypes,665,675
including inverter, buffer, and concatenation operation. The prototypes showed in experiment one of the first examples of
concatenable magnetic logic devices for building larger circuits. The four-terminal mLogic spacer coupling has also been
demonstrated.668
Larger scale system-level simulations have been performed to determine the benefits and drawbacks of DW-MTJ logic. One
circuit-level energy-performance analysis showed that while very low voltage can be used to operate the essentially all-metallic
devices, it comes with increased extrinsic DW pinning effects and thermal noise. 676 They predicted the energy reduction from
increasing the tunnel magnetoresistance (TMR) will saturate when TMR > 100%, but further increasing TMR can mitigate
predicted thermal noise limits. Recent work simulated a 32-bit adder communicating with registers with all DW-MTJ devices
and shows SOT switching can make the technology competitive with a comparable CMOS sub-processor component. 677
The device has recently been extended by many in the community to non-Boolean logic applications in neuromorphic
circuits, 678,679,680,681,682 including spike-timing-dependent-plasticity synapses 683,684 and leaky, integrate, and fire neurons. 685,686
Major challenges exist in understanding and improving the device-to-device and cycle-to-cycle variation of the devices, which
arise from variation in the domain wall location and pinning landscape. A discussion of influence of device variability on circuit
performance is presented in Xiao et al.677 Better understanding of experimental viability of the technology is needed, given TMR
variability and constraints and scaling-induced variability and errors. 687 Example ideal applications of the device technology are
still needed, with some potential areas being radiation-hard environments, lower latency hardware accelerators, and low-area,
low-energy needs of edge-computing internet of things devices.
• Computing with Dynamical Systems (§4.2.3): Analog dynamical systems can be used to solve a variety of problems.
Optimization problems can be solved using simulated annealing (§4.2.3.1) or coupled-oscillator-based approaches
(§4.2.3.2). Dynamical systems can be used to encode associative memories (§4.2.3.3) or to solve differential equations
(§4.2.3.4). Chaotic logic can theoretically enable sub-kT computing (§4.2.3.5).
• Analog Memory and Compute Devices (§4.2.4): There are many different types of analog devices that form the
building blocks of the computational kernels above. These devices include ReRAM, phase change memory, ion insertion
redox transistors, floating gate transistors, capacitive or charge based analog devices, single flux quantum devices,
photonic devices, magnetic devices, and more.
Probabilistic/stochastic circuits (§4.3) – Devices and circuits that produce truly nondeterministic or random outputs at the
hardware level may be useful for accelerating probabilistic algorithms such as Monte Carlo or simulated annealing, for
generating secure cryptographic keys, and for other applications.
Reversible (adiabatic and/or ballistic) computing (§4.4) – Computing paradigms that approach logical and physical rev-
ersibility offer the potential to greatly exceed the energy efficiency of all other approaches for general-purpose digital
computation. While devices for reversible computing may perform fairly conventional functions (such as switching or
oscillating), they should be optimized to utilize quasi-reversible physical processes such as near-adiabatic state transi-
tions, near-ballistic signal propagation, highly elastic interactions, and highly underdamped oscillations. For maximal
efficiency, circuits and architectures must approach reversibility at the logical as well as physical level. 702,703 Careful
fine-tuning and optimization of analog circuit characteristics (e.g., resonator quality factors, elasticity of ballistic inter-
actions) remains a difficult and crucially important engineering challenge that must be met in order to fully realize the
promise of the reversible computing paradigm. In the meantime, potentially commercially viable near-term applications
of reversible computing are beginning to emerge for specialized cryogenic applications. 704,705
Quantum computing – Quantum computing 706 offers the potential to carry out exponentially more efficient algorithms for
a variety of specialized problem classes. 707 Devices for quantum computing are very different from conventional
devices, and fine-tuning device characteristics to avoid decoherence while organizing them effectively into scalable
architectures has so far proved to be a formidable engineering challenge. 708 Since the 2018 edition, IRDS has been
beginning to address quantum computing in a new chapter titled Cryogenic Electronics & Quantum Information
Processing (CEQIP). We will not address quantum computing further in the present chapter.
The reader should note that the material in this section is not intended to comprise an exhaustive list of all possible new computing
paradigms, new devices, new circuits, or new architectures. It is only intended to serve as a representative sample of several new
general computing paradigms and specific technology concepts.
4.2. ANALOG COMPUTING
Analog computing attempts to “let physics do the computation” by using physical processes directly (as opposed to, by going
through the traditional digital abstraction barrier) to compute complex functions. Historically, this required inefficient analog
circuitry for all elements, and expensive analog to digital conversion, resulting in limited applications, specifically those requiring
analog signal processing. Recently, new analog devices have enabled a new generation of efficient analog architectures. This is
especially true for hybrid analog and digital systems where efficient designs may exploit analog preprocessing and computation
prior to digitization. Analog preprocessing can reduce the required A/D precision and therefore reduce the system energy
consumption by orders of magnitude. 709 Additionally, new architectures can be used for ultra-low-power co-processors for
conventional CMOS designs. A key challenge is that analog signals are typically low-precision, with energy and latencies
increasing exponentially with higher bit precision. Fortunately, many machine learning and other applications are being developed
that can tolerate such lower precision computation.
In this subsection, we review a number of recent examples of analog computational technologies, starting at the architectural
level with (in §4.2.1) some currently popular neural-inspired architectures that also have broader applications in linear algebra.
Then §4.2.2 broadens the scope to other neural-inspired computing approaches, and §4.2.3 looks at an even broader variety of
approaches to “physical computing” with analog dynamical systems. Finally, §4.2.4 reviews device technologies that have some
utility in the context of one more of the various analog architectures.
4.2.1. CROSSBAR-BASED COMPUTING ARCHITECTURES
Analog crossbars or memory arrays can perform low-precision matrix operations in parallel, by processing analog data directly
at each memory element. Thus, in 1990, Carver Mead projected that custom analog matrix vector multiplications would be
thousands of times more energy efficient than custom digital computation. 710 Because a digital memory must individually access
each memory cell and move the data to a separate computation unit, digital systems consume more energy and incur longer
latencies. Computing on larger crossbars/matrices allows for any analog overhead to be averaged out over many matrix elements.
Any two- or three-terminal device that features a modifiable internal physical state variable (which might be, for example, a
variable resistance, a variable capacitance, a stored charge, or a stored magnetic field) that modifies the device’s behavior can be
used as a building block for analog operations. Several different types of crossbar architectures are summarized in the following
sections.
4.2.1.1. MATRIX VECTOR MULTIPLICATION (MVM) AND VECTOR MATRIX MULTIPLICATION (VMM)
MVM and VMM are key computational kernels underlying many different algorithms. There are several approaches to
accelerating these kernels. Any programmable resistor such as a two-terminal resistive memory or a three-terminal floating gate
cell can be used. Alternatively, a capacitive MVM can be designed by adding charge from capacitive memory elements. 711
For many algorithms such as neural network inference (of an already-trained network), accelerating MVM accelerates the bulk
of the computation, allowing for large system level gains. An 𝑁𝑁 × 𝑁𝑁 crossbar accelerates O(𝑁𝑁 2 ) operations, leaving only 𝑂𝑂(𝑁𝑁)
inputs and outputs that need to be processed and communicated. This allows each unit of communication and processing costs to
be amortized over 𝑁𝑁 memory elements.
Analog VMMs have been used for experimental demonstration of threshold logic, 712 compressed sensing initial filtering, 713
robotic navigation and control, 714 adaptive filtering, 715 Fourier transforms 716 and more. Additionally, Analog VMM techniques
have been used for ultra-low power classification and neural networks. 717
4.2.1.1.1. RESISTIVE MVM AND VMM
Resistive MVMs are based on using Ohm’s law, 𝑉𝑉 = 𝐼𝐼 × 𝑅𝑅, to perform multiplication, and Kirchhoff’s current law to perform
addition by summing currents. Programmable resistors are used to program the weights. Arranging the memory elements in an
array allows for the entire operation to be performed in a single parallel step, giving a fundamental 𝑂𝑂(𝑁𝑁) energy and latency
advantage over a standard digital memory that, at best, must access a memory array one row at a time. 718 An MVM and the
transpose VMM can be performed on the same memory array, by changing whether the rows of an array are driven and the
columns are read, or vice versa.
The key metrics for a resistive MVM are 1) the energy per multiply-and-accumulate (MAC), 2) latency per MVM, 3) crossbar
and supporting circuitry area per matrix element, 4) crossbar dimensions, 5) input/output bit precision for digitally driven MVMs,
and 5) the standard deviation of the noise or error per weight when programmed as a percentage of the weight range.
If high-resistance memory elements (𝑅𝑅on = 100 MΩ) with good analog properties are developed, one ReRAM based crossbar
design projects that each multiply and accumulate operation will require 12 fJ when using 8-bit A/Ds and only 0.4 fJ when using
2-bit A/Ds. 719 The latency for a 1024 × 1024 MVM will only be 384 ns or 11 ns for 8-bit or 2-bit A/Ds respectively. This is
over 100× better than an optimized SRAM-based accelerator, which would require 2,700 fJ and 4,000 ns for 8 bits. The area per
weight for the 8-bit A/D ReRAM accelerator is 0.05 µm2, 16× better than the 0.8 µm2 needed for an SRAM accelerator. The
energy and latency are dominated by the A/D circuitry and not by the crossbar itself, with the A/D converters and digital circuitry
occupying 10× the area of the ReRAM array itself.
To allow for large arrays and minimize parasitic resistance drops, high resistance (~100 MΩ) memory elements are needed. The
higher the resistance, the larger the array possible, and the more any A/D costs and system level communication costs are
amortized out. However, such high resistances would prolong and potentially complicate the process of programming each
conductance value accurately to encode already-trained neural network weights or matrix element values.
A key design choice is the bit precision of the inputs and outputs to the crossbar. The fewer bits are needed by an algorithm, the
more efficient the crossbar is. If analog or binary inputs/outputs can be used, the A/D costs can also be avoided. The inputs to the
crossbar can be encoded in voltage, time, or digitally. Voltage encoding applies different voltages to represent different analog
input values. This requires circuitry to create different input voltages, and it requires that the memory elements have a linear I-V
relationship, greatly complicating the use of nonlinear access devices. 720 Encoding inputs in variable length pulses requires longer
reads and an integrator to sum the resulting current. Digital encoding applies each bit of the input sequentially and then combines
the result digitally. For digital encoding, the usefulness of the lower-order bits in the input is limited by the noise/errors on the
highest-order bit. To save on ADC costs, each bit position can also be combined in analog using successive integration and
rescaling 721
The precision with which each resistor needs to be programmed depends on the application. For neural network inference, the
algorithm can be robust to read noise of up to 5% of the weight range or more. 722 To extend the precision of computation beyond
the limits of reliable programming, a technique called bit slicing can be used. 723 With bit slicing, a matrix of wide operands is
striped across multiple crossbars, enabling the crossbars to collectively perform computation on arbitrarily wide operands at the
cost of additional digital circuitry to reduce partial results from multiple bit slices. When bit slicing is combined with digital input
encoding, each bit of the input must be applied to each bit slice, analogous to multibit scalar multiplication. Leveraging bit slicing,
accelerators for a wide range of applications have been proposed, including combinatorial optimization,723 neural network
inference, 724,725 graph analytics, 726 and scientific computing. 727
4.2.1.2. OUTER PRODUCT UPDATE (OPU)
Analog resistive memory crossbars can also perform a parallel write or an outer product, rank 1 update where all the weights are
incremented by the outer product of a vector applied to the rows and a different vector applied to the columns. This is a key kernel
for many learning algorithms such as backpropagation722 and sparse coding.718,728 Row inputs are encoded in time and column
inputs are encoded in either time728 or voltage.722
When a VMM and MVM are combined on the same crossbar, extremely efficient learning accelerators can be designed,719,729, 730
with the potential to be 100–1000× more energy efficient and faster than an optimized digital ReRAM or SRAM based
accelerator.719
The same figures of merit and design considerations for a VMM apply to the OPU. Additionally, the 1) write noise and
2) asymmetric write nonlinearity are important for determining how well a learning algorithm will perform. The 3) ability to
withstand failures, and 4) endurance are also important for training systems. To have an efficient learning accelerator, parallel
blind updates are needed where weights are updated without knowing the previous value and without verifying that the correct
value is written. To obtain ideal accuracies, a low write noise is needed, less than 0.4% of the weight range. Even more important
is having low asymmetries in the write process. The change in conductance for a positive pulse should be the same as that for a
negative pulse for all starting states.722 Often the conductance will saturate near a maximum where a positive pulse will not
change the conductance, while a single negative pulse will cause a large decrease in conductance. This significantly lowers
accuracy as it only takes a single negative write pulse to cancel many positive pulses.
Several devices have been examined for neural network training, including phase change memory,729 resistive memory719,731 and
novel lithium-based devices. 732,733 Currently no devices meet all the ideal requirements for training (high resistance >10 MΩ, low
write noise <0.4%, low write asymmetry722). Nevertheless, algorithmic approaches such as periodic carry, 734 Local Gains, 735
Tiki-Taka, 736 or the inclusion of semi-volatile capacitor-on-gate devices 737 can be used to help compensate and achieve ideal
accuracies. Several co-design tools have been developed to model the impact of device level properties on algorithmic
performance729,738,739 which have allowed for the algorithmic development needed. Additionally, lower resistance devices can be
used to give smaller near-term gains in performance.
The need for high on-state resistance and good analog characteristics means that filamentary resistive memories may not work as
well as non-filamentary devices. A resistance higher than a quantum of conductance, 13 kΩ, requires current to tunnel through a
barrier. This presents a fundamental problem for a filamentary device: a single atom can halve that tunneling barrier, resulting in
huge variability and poor analog characteristics.
4.2.1.3. LARGE-SCALE FIELD PROGRAMMABLE ANALOG ARRAYS (FPAAS)
A field programmable analog array has configurable analog components, digital components, configurable interconnects between
those components and off-chip communications. 740 , 741 , 742 FPAAs allow users to build analog applications without having
expertise in IC design. FPAA I/O lines can transmit or receive analog signals, digital signals and create direct connection lines
typical of analog circuits. The routing between analog and digital blocks can occur between the blocks of devices, with converters
between these blocks, or more finely connected heterogeneous analog and digital component populations. The components are
often organized into regions called computational analog blocks (CABs). CAB components vary considerably between
implementations but often include nFET and pFET transistors, transconductance amplifiers [TA or operational transconductance
amplifier (OTA)], other amplifiers, passives (e.g., capacitors), as well as more complicated elements (e.g., multipliers). The most
advanced FPAAs to date utilize Floating-Gate (FG) devices, dramatically improving the analog parameter storage and therefore
the resulting computational capability. 743 FPAAs include aspects of digital computation, such as FPGA blocks or shift registers
or microprocessors, to complete the full end-to-end configurable system.743
The fundamental breakthrough was recognizing that a switch matrix of single floating gate elements could be used for analog
computation. The routing crossbar networks were, in fact, crossbar networks that could support VMM and other computations. 744
Routing was no longer dead weight, as perceived for FPGA architectures. The floating gate cells could also allow for mismatch
calibration at the mismatch source. 745,746 The density for VMM in FPAA architectures is nearly the level of custom IC design.
These analog computations can be made robust to temperature fluctuations. 747 These techniques have been utilized by a number
of students in university courses. 748,749 FPAA based VMMs can be scaled to small geometry (e.g. 40 nm and smaller) and operated
at RF frequencies. 750 , 751 FPAAs have been used for command-word recognition in less than 23 μW with standard digital
interfaces.742 The full classification results in less than 1 μJ per classification (or inference), which has 1000× improvement over
similar digital neuromorphic solutions requiring roughly 1 mJ or higher for just an inference. 752
4.2.1.4. RESISTIVE MEMORY CROSSBAR SOLVER
Resistive memory crossbars can be used to solve matrix problems, such as the linear system of equations 𝐴𝐴𝐴𝐴 = 𝑏𝑏,where 𝑥𝑥 is the
unknown vector and 𝑏𝑏 is the known vector, represented by output voltage and input current, respectively, in Figure
BC4.2(a). 753,754 Each resistive memory element is a programmable resistor that represents an element in the coefficient matrix 𝐴𝐴.
(Alternatively, any programmable analog element can also be used.) The equation 𝐴𝐴𝐴𝐴 = 𝑏𝑏 can be mapped to Ohm’s law,
∑𝐺𝐺𝑖𝑖𝑖𝑖 �𝑉𝑉𝑗𝑗 − 𝑉𝑉𝑖𝑖 � = 𝐼𝐼𝑖𝑖 . The 𝑉𝑉𝑖𝑖 are set to zero by the virtual ground of the op-amps. Currents, 𝐼𝐼𝑖𝑖 , are applied to the crossbar and the
resulting voltages, 𝑉𝑉𝑗𝑗 , are measured. The op-amps provide feedback allowing the 𝑉𝑉𝑗𝑗 to be determined.
Similarly, eigenvectors of a matrix 𝐴𝐴 can be calculated according to the circuit in Figure BC5.2(b). Here, the maximum
eigenvalue is mapped in the feedback conductance 𝐺𝐺𝜆𝜆 , while the voltage yields the corresponding eigenvector 𝑥𝑥. To solve
problems with positive/negative coefficients in 𝐴𝐴, two crossbars can be used in the circuits of Fig. BC5.2. In all cases, crossbar
solvers yield their solution in one computational step, without any iteration, and the solution is generally obtained in less than 1
µs, depending on the poles of the analogue feedback circuit. 755 The same scheme can be extended to one-shot learning by linear/
logistic regression. 756
The biggest challenge in taking advantage of analog solvers for HPC is that analog operations only offer low precision, ~8 bits
fixed point, while HPC applications often demand 32 or more bits of floating-point precision. This can be potentially overcome
by hybrid analog/digital systems where the computationally intense parts of a calculation can be done in analog, while the required
precision can be achieved by refining the solution in digital using a method with lower computational complexity. 757 This allows
for some digital computation, while still getting a reduction in the overall computational complexity. The precision can potentially
be improved by using iterative refinement or by using the crossbar to initialize a digital solver. The analog solution can also be
used as a preconditioner within a Krylov method like CG or GMRES. Large matrices can be broken down into smaller blocks
compatible with the accelerator and scaling can be used to compensate for finite on/off ranges. Work is still needed to show how
noisy crossbar solvers can be used with ill-conditioned matrices. In general, iterative refinement will only converge if the noise
is less than 1/𝜅𝜅 where 𝜅𝜅 is the condition number of a matrix.
4.2.1.5. TERNARY CONTENT ADDRESSABLE MEMORY (TCAM)
Similar to resistive crossbar arrays, content addressable memory (CAM) arrays operate in a highly parallel manner but have a
distinct operation which compares a given search word to a set of stored words in parallel within the circuit, and returns the index
of the matched entry. This CAM array compare operation takes only one or a few clock cycles, enabling massively parallel high-
throughput and low-latency lookups. In addition, Ternary CAMs (TCAMs) have the additional functionality of storing a “don’t
care” or “X” value which acts as a wildcard to match regardless of input, enabling compression of stored CAM entries. While
very powerful, today’s CAMs based on SRAM suffer from high cost, area and power, 758 limiting their modern usage to
networking (QOS/ACL/IP routing lookup tables) and applications which must trade-off power and cost for high throughput and
speed.
To address this gap, a significant body of work has developed TCAM circuits using ReRAM or non-volatile memory (NVM)
devices to replace the large and power-hungry SRAM storage devices in conventional TCAM circuits for reduced power and
area, and potential for larger array sizes. Work on design, simulation and physical silicon tapeouts have been conducted for phase
change memory, metal-oxide memristors, and spin-transfer torque devices. 759, 760, 761, 762, 763, 764, 765 While several designs have
drastically reduced the transistor count per TCAM cell (conventional 16T reduced to 4T, 3T, 2T versions), the limited ON-OFF
ratio of NVM and the relatively high device conductance has led to larger power consumption than desired originating from high
DC currents during search operations and design work is still underway to optimize area (i.e. transistor count), power and device
requirements (ON-OFF ratio, write voltage and conductance state stability). Key challenges for the practical realization of TCAM
arrays remain, such as the need for highly reliable devices, error correction schemes, scaling of array sizes and balance of devices
requirements (ON-OFF ratio, write voltages) and latency-power optimization for different use cases. For example, smaller ON-
OFF ratios can lead to longer latency but may be beneficial for certain applications. Despite these challenges, recent work in this
area is promising with competitive reported values of 0.5 fJ/bit/search,759 and as NVM technologies become more available at
commercial foundries, further performance improvements and tuning of NVM CAM circuits are anticipated.
In addition, as increasing work on NVM CAM circuits progresses sufficiently to lower the (power/area) barrier to widespread
usage, the development of NVM TCAM circuits as a new in-memory computation primitive presents great potential in future
computing systems. Like with the much-studied resistive crossbar array architecture, the large performance benefit for using
CAMs for in-memory computation comes from the vast reduction of data movement for target applications with large numbers
of compare or lookup operations. While resistive arrays enable in-situ vector-matrix multiplication acceleration for applications
in areas such as machine learning, analog signal processing, and scientific computing, CAM circuits provide an orthogonal
functionality. Recent work in this area has proposed using CAMs as in-memory computation blocks for applications such as
associative processing, 766,767,768 approximate computing, 769 spiking NNs, 770 string matching, 771 and regular expression matching
finite state machines. 772 Further application areas are expected to emerge as NVM CAM circuits mature to make their use
advantageous compared to GPU and FPGA approaches.
4.2.2. NEURAL-INSPIRED COMPUTING
There are several characteristics of how the brain computes that have been proposed for efficient computing
technologies. Architecturally, there are two attractive approaches: processing in memory, which is analogous to the analog
computation that occurs at synapses within the brain, and event-based communication, which is analogous to neuronal
spiking. Both approaches potentially yield considerable energy savings, and the brain clearly benefits from both. As discussed
in §4.2.1, analog crossbars can be used as building blocks for conventional neural networks to give significant improvements in
energy, latency and area over digital accelerators. For accelerators specialized to a particular algorithm, various analog neurons
can be used to process the crossbar outputs and avoid the need for and high cost of analog-to-digital conversion.
There is also a lot of work on more biologically inspired neural hardware. For biologically inspired neurons, connections are
often designed to be persistent on short timescales, but (depending on the model) may exhibit mutability/plasticity in their strength
and/or topology on longer timescales to facilitate, for example, adaptive in-situ learning. Connections between neurons can be
modeled as discrete events or spikes (often implemented using an address event representation) or continuous-valued analog
signals such as voltage or current. A key challenge for more biologically inspired architectures is the need for algorithmic co-
design. For many neuro-inspired computational models, further research is needed to demonstrate state of the art machine-
learning performance.
4.2.2.1. LOCAL LEARNING RULES
Recent breakthroughs suggest that local, approximate gradient descent learning is compatible with Spiking Neural Networks
(SNNs) implemented in neuromorphic hardware. 773,774,775,776,777,778 Spiking neural networks can be viewed as a type of recurrent
neural network, where activities are binary and recurrence is both due to connections and the leak of the neurons.773 This analogy
enables the transfer of algorithms of deep learning into local synaptic plasticity dynamics in SNNs. The synaptic plasticity
dynamics that result from these derivations are “three-factor rules.” Three factor rules are popular among computational
neuroscientists for reward-based learning.
Credit assignment for (deep) hidden parameters in SNNs under tight constraints of information locality is a very challenging
issue. All states other than spikes, such as neurotransmitter concentrations, synaptic states, and membrane potentials are local to
the neuron. If a non-local quantity is required for a computational process (e.g. learning), a communication channel is required
to convey it. 779 The cost of this channel is non-negligible regardless of the substrate: axons (white matter) take up most of the
volume in the brain. Similarly, in modern computers, data movement is the major energy requirement. 780
One strategy is to train a SNN using local loss functions and the three-factor rule. An example of a loss function that is local to
the layer of neurons774 is shown in Fig. BC4.3 in diamonds. Local loss functions can be either designed, 781,782 trained using Back-
Propagation (BP) 783or evolved.777
Using this approach, it is possible to perform learning in crossbar arrays using temporal dynamics of SNNs in an error-triggered
fashion. 784 Furthermore, the mathematical derivation shows that circuits used for inference and training dynamics can be shared,
which renders the learning circuits insensitive to the mismatch in the peripheral circuits. Using error-triggered learning, the
number of updates can be reduced a hundredfold compared to the standard rule while achieving performances that are on par with
the state-of-the-art.
Figure BC4.3 A Spiking CNN for Gesture Recognition with Local Learning
Note: (Left) Deep Continuous Local Learning (DECOLLE) network for gesture recognition. DECOLLE is a forward trained spiking
Convolutional Neural Network (CNN) using local loss functions. The network consisted of three convolutional layers with max-pooling. A local
classifier (colored diamond) is attached to every layer via a fixed random projection, i.e. each layer is trained to classify the gesture. The fixed
random projection enables the network to find increasingly disentangled representations as the data flows through the hierarchy. DECOLLE
is fed with 1-ms integer frames recorded from a neuromorphic vision sensor. (Right) Classification Error for the DvsGesture task during
learning for all local errors associated with the convolutional layers. C3D is a 3D CNN commonly used for sequence learning. 785 See Ref. 774
for details.
4.2.2.2. HYPERDIMENSIONAL COMPUTING
Hyperdimensional (HD) computing is a cognitive computing model based on the high-dimensional properties of neural circuits
in the brain. 786 Information is encoded into high-dimensional distributed representations in the form of high-dimensional vectors
or hypervectors.786,787 A hypervector distributes information uniformly across all of its dimensions, resulting in a distributed or
holographic representation. 788,789 This contrasts with conventional positional representations in which different digits or bits can
convey vastly different amounts of information depending on their position. Consequently, incurring bit errors in particular
positions can result in catastrophic failure. In contrast, the distributive nature of hypervectors combined with high dimensionality
provides a robustness to bit errors: errors that occur in any dimension result in the same information loss, and this information
loss is small due to the large number of dimensions. Thus, HD computers exhibit graceful degradation as hardware components
fail, analogous to in the brain when neurons die.789
Computation is performed by systematically transforming hypervectors into other hypervectors (i.e. closure is satisfied) using
operations such as multiplication, addition, and permutation. Due to the distributed nature of hypervectors, these operations
become local to individual dimensions (or bits, in the case of binary hypervectors). Multiplication, for example, becomes element-
wise multiplication and can be used to “bind” hypervectors together into a single hypervector representing a key-value
pair.789, 790, 791 Multiplying by the multiplicative inverse of the key hypervector will “unbind” the key hypervector from its
corresponding value hypervector. Similarly, other operations such as addition and permutation can be used to construct sets and
sequences respectively.789,790,791 These simple operations together enable the construction of more complex compositional
representations, which are ultimately stored in an autoassociative memory for item “cleanup” as hypervectors become noisy
during computation.789,790,791,786
Constructing a physical HD computer will require innovations at all levels of the computing stack but could result in an energy
efficient “thinking” machine. 792,793,794,795,796 The robustness to noise and bit errors provided by the high-dimensional distributed
representations reduces requirements on signal-to-noise ratio. This enables lower supply voltages and greater tolerance for device
variability than in conventional computers.787,792,793,794 Furthermore, HD computing operations are local to individual digits or
bits and are, consequently, highly parallelizable.789,790,795,796 The trade-off is large word sizes, which necessitate processing-in-
memory.792,793,794,795,796 Fortunately, HD computing algorithms are geared towards one-shot or few-shot learning787,792,797,798 and
do not require frequent weight updates. As a result, hypervectors may lie dormant for extended periods of time, allowing for a
greater portion of inactive components for reduced power consumption.
4.2.2.3. SPIKING-BASED NEURAL NETWORKS (SNNS)
Like the brain which couples both the processing in memory and spike-based communication for maximal space and energy
efficiency, a good spiking based neural network needs to couple both. Ultimately, the spiking function by neurons has two
features that must be captured by a proposed device or circuit: its non-linearity and its efficient long-distance
communication. First, it must accomplish the analog-to-spiking conversion, which in its simplest form is a compact 1-bit analog-
to-digital conversion, but ideally would also enable holding some additional state or history from the analog inputs. There have
been many proposed devices for spiking neurons including neuristors, 799 spin torque based devices, 800 stochastic phase change
neurons, 801 superconducting neurons, 802 and others. Second, future spiking systems must be able to communicate this information
efficiently to downstream neurons.
Currently, CMOS systems rely on event-driven communication of packets that contain some source or destination address
relevant to routing the spike to appropriate destinations. Thus, CMOS systems do benefit from the relative rarity of the
communication (only transmit when an event occurs), and are already achieving considerable savings from that, but do not benefit
significantly from the theoretical 1-bit precision of the spike as a multibit address is needed. In this respect, more efficient
mechanisms for direct point to point communication, such as superconducting systems, 3D-nanowires, or perhaps optical
interconnects are needed. The challenge in these systems is how to achieve the necessary level of fan-in / fan-out (i.e., number of
synapses per neuron) between non-local regions and how to deliver that information in a suitable form for processing in the
analog memory circuits used as synapses.
4.2.3. COMPUTING WITH DYNAMICAL SYSTEMS
In computing with dynamical systems, the built-in dynamical behavior of a physical system exhibiting continuous degrees of
freedom is used to compute. The entire computational process can be analog, with only the results being digitized. The following
subsections give a few examples of different types of dynamical systems-based approaches.
Although some of the below methods target NP-hard problems, it’s important to note that, to date, no general physical computing
method (including analog and quantum approaches) has yet been clearly demonstrated to be capable of solving NP-hard problems
without requiring exponential physical resources (energy and/or time) to be invested in the physical process performing the
computation. The prevailing belief among computational complexity theorists 803 is that solving NP-hard problems efficiently
would require uncovering new physics (i.e., beyond standard quantum mechanics).
4.2.3.1. STOCHASTIC/CHAOTIC OPTIMIZATION—SIMULATED ANNEALING
Many of the optimization problems that are found in modern operations research—such as routing, scheduling, and other types
of resource allocation—are intractably hard. Consider this example: finding an optimal route among three cities can be done using
the digits on two hands, but with 15 cities, we are left with more than 40 billion routes to choose from. As the size of the problem
grows, the resources needed to solve the problem increases exponentially. Finding even approximate solutions to large
combinatorial optimization problems are prohibitively resource-intensive with the best supercomputers we have. Exact solutions
to these problems are known in computational complexity theory to be NP-hard (non-deterministic polynomial time hard),
meaning that it is too hard for any computer, analog or digital, to solve exactly, in general, and specifically at large scale. However,
there are many ways to compute approximate solutions, meaning finding a good solution but not necessarily the best one. In
recognition of this, there have been many analog hardware approaches that exploit the inherent computational ability and
parallelism in physical processes to solve these hard optimization problems.
An example solution uses energy minimization using multiple runs on a Hopfield network. 804 A Hopfield network is a popular
neural network with its output being calculated via a simple decision system (e.g.: thresholding of input), which is then weighted
and fed back to its input. The feedback weights define an energy landscape based on values emerging from the output. If a
Hopfield network is initialized to a particular value, the network will follow a trajectory that will take it to a minimum, or local
minimum, of the energy landscape.
As an example, consider using a Hopfield network to solve the Traveling Salesman Problem. The Traveling Salesman Problem
is to find the best route for a salesman that needs to visit a series of cities, each pair separated by some distance. The salesman
seeks the shortest route that visits each city exactly once and then returns to the starting city. In an analog system the weights are
set to encode the intercity distances. The system drives the outputs to a starting point for the salesman’s route. The system will
settle into a candidate salesman’s route in an amount of time equal to a few time constants of the feedback loop.
The method described above may find the ideal solution, or just a better but suboptimal solution. To improve the odds of finding
the best solution, the circuit can include either a true random noise generator or a chaotic pseudo-random noise generator. Under
control of an external digital computer, the Hopfield network is driven to a random starting point and released many times in a
cycle. The randomness causes many of the starting points to be different, making it more likely that the system will find the global
minimum. The digital computer collects all the results, checking each to see which is best.
Such a system leverages multiple new circuit blocks including both a crossbar to encode the n intercity distances (that can be
built using memristors), an analog neuron to run the Hopfield network and either chaos or noise generator to get randomness. As
the Traveling Salesman problem is NP-hard, no solution method can solve it exactly at scale. Nevertheless, the analog solution
seems to be at least comparable in efficiency with some software algorithms. For instance, a memristor based Hopfield network
has been built. 805
Another important application for combinatorial optimization, specifically graph coloring, was described 806 and developed
theoretically with support from experimental demonstrations using relaxation oscillators based on phase-change IMT materials.
An architecture based on non-repeating phase relations 807 between fabricated CMOS oscillators tries to emulate stochastic local
search (SLS) for constraint satisfaction problems.
4.2.3.2. COUPLED-OSCILLATOR BASED OPTIMIZATION
Coupled-oscillator machines are another class of analog accelerators for combinatorial optimization that share a similar
architecture: they are composed of a network of decentralized nonlinear oscillators, and the programmable strength of the
coupling between them encodes the specific problem to be solved. These networks have been proposed and demonstrated with
electrical, 808,809,810,811,812 optical, 813,814,815 and electromechanical 816 oscillators. These systems are often called “Ising machines”
because they map readily to the Ising graph optimization problem, with each oscillator representing one bistable spin. Any
combinatorial optimization problem can be converted into an equivalent Ising problem that is programmed onto and solved by
the machine. The energy minima of such networks correspond to the solutions of an NP-hard combinatorial optimization problem
and can model other NP-hard problems as well.812
Networks of coupled oscillators have been shown to embed the energy (cost function) of the Ising problem in their physical
dynamics and relax to configurations that minimize this energy. They can thus rapidly sample the local minima of a problem,809
and can potentially also be used to arrive at solutions close to the global minimum.808,811 The sampling speed is determined
fundamentally by the oscillator frequency. The accuracy of the different architectures has been benchmarked using large instances
of the Ising or Max-Cut problems generated by the operations research community. Solutions have been found that match those
obtained by state-of-the-art digital algorithms.810,813 Energy and delay benchmarking remain a future step.
Of the proposed coupled oscillator optimization schemes, the systems which use electrical (LC) or electronic (ring oscillator)
oscillators are the most compatible with CMOS technology. Since the Ising problem is specified by a connectivity matrix, the
oscillators can be densely connected using a resistive crossbar.808,811 In these networks, the oscillators take on a discrete nature
by synchronizing to a second-harmonic master oscillator through a circuit nonlinearity. The nonlinear oscillator properties can
be easily provided by semiconductor components such as diodes, MOS capacitors, or amplifiers. In fact, phase-based Boolean
computing using such nonlinear oscillator circuits was proposed decades ago. 817
The physical limits of coupled oscillator systems are governed by the achievable level of weight precision and circuit delay. The
resistive connections must be linear, programmable to high precision, and have minimal drift. The precision and retention of the
resistive connections limit the accuracy to which a problem can be programmed onto the hardware, and the precision requirements
for an adequate representation increase with problem size. For very large problems, device or process limitations will impose an
upper bound on the quality of the solution; the target error bound depends on the application, but it must be superior to bounds
that are guaranteed by digital approximation algorithms. Since a coupled oscillator network relies on synchronization between
the oscillators, signal delays can also impact performance, especially in high-frequency circuits needed for rapid optimization. In
particular, variability in the distribution delay of the second-harmonic master oscillator by more than a half-cycle are detrimental:
this will be a significant problem in large networks. To this end, architectures have been proposed that separate the oscillators in
time rather than space,814 but this comes at the loss of continuous-time communication among the oscillators, leading to slower
convergence.
Related constraint satisfaction systems have been built. 818 An interesting approach based on memory co-processors was
introduced as Memcomputing. 819 Useful insights can also be obtained by looking into dynamical systems like iterated maps, 820
and 0-1 continuous reformulations of discrete optimization problems. 821
4.2.3.3. ASSOCIATIVE MEMORIES
Hopfield networks are attractor networks proposed for associative memories 822 where the fixed points (or stable states) of the
system correspond to memories, and the dynamics of the network is such that the system settles to the fixed point which is closest
to the initial state the system starts from. These networks can be implemented with coupled oscillators. 823,824,825
The associative memory application is widely used in the tasks of voice and image recognition, which can be performed in a
cellular neural network architecture. 826,827 Five decimal digits, ‘1’–‘5’, are associated with the other five digits, ‘6’–‘0’. Hebbian
learning is used for storing patterns. 828 Patterns with noisy input pixels can still be recalled. The delay per cellular neural network
operation is dependent on the input pattern, input noise, and thermal noise.
A key challenge for oscillator-based associative memories is storage capacity. A fully connected net with 𝑁𝑁 units can only store
around 0.15𝑁𝑁 memories while requiring 𝑁𝑁 2 weights, resulting in a poor memory density. 829
4.2.3.3.1. CELLULAR NEURAL NETWORKS
The cellular neural network 830 (CeNN) is a non-Boolean computing architecture that contains an array of computing cells that
are connected to nearby cells. Since interconnects are major limitations in modern VLSI systems, CeNN systems take advantage
of the local communication and encounter fewer constraints imposed by interconnects. The CeNN is a brain-inspired computing
architecture that relies on neurons to integrate the incoming currents. The accumulated and activated output signal drives nearby
neurons through weighted synapses. CeNNs can be used to create associative memories for voice and image recognition.
CMOS based CeNNs can be implemented by analog circuits using operational amplifiers and operational transconductance
amplifiers (OTAs) as neurons and synapses, respectively. 831,832 Some recent work has also investigated CeNN using beyond-
CMOS charge-based devices, such as TFETs, to potentially improve energy efficiency 833,834 thanks to their steep subthreshold
slope and low operating voltage.
Using novel devices such as all-spin logic (ASL), 835 charge-coupled spin logic (CSL), 836 and domain wall logic (mLogic) 837
whose dynamics match the dynamical state of cells in CeNN can be far more efficient than op-amp and OTA based CeNNs. The
use of these different devices has been benchmarked. 838 It was shown that the digital CeNNs are quite power hungry and slow.
This is because multiple cycles are required to read out the weights from the register and perform the summation in the adder,
which is energy and time consuming. In general, analog CeNNs implemented by TFETs dissipate less energy thanks to their steep
subthreshold slope and lower supply voltage. In contrast to Boolean circuits, spintronic devices are more competitive. This is
because a single magnet can mimic the functionality of a neuron, and these spintronic devices operate at a low supply voltage.
The domain wall device provides the best performance, in terms of Energy-Delay Product, thanks to its low critical current
requirement.
4.2.3.4. DIFFERENTIAL EQUATION MODELING
Analog computation aligns well with the solution of differential equations, both Ordinary Differential Equations (ODE) and
Partial Differential Equations (PDE). 839,840 A key limitation of digital ODE and PDE solution accuracy is the need to discretize
time and amplitude. Continuous time analog solutions eliminate this. Analog summation by charge or current is also ideal and
not subject to round off error. Similarly, analog integration can be ideal and is typically performed as a current sum on a capacitor.
The result of the final computation will have some noise distortion, but the noise is added at the end of the resulting computation
and does not affect the core numerics.
Analog computation builds on an analog numerical analysis techniques,840 analog algorithm complexity theory, 841 and analog
algorithm abstraction theory, 842 where these directions provide guidance on the relative numerical performance, as well as relative
architectural performance, for designs abstracted at multiple levels of representation, respectively. Analog solution of differential
equation computes using real valued quantities, often computing over continuous amplitude and time. 843
Analog solution of PDEs often utilize spatially coupled ODEs 844,845,846 where the physical system is continuous in space, but
practically the parameters change in discrete points with a finite granularity of parameter resolution setting, as well as output
measurement capability. Often differential equations are solved using programmable and reconfigurable techniques, 847,848, 849
enabling utilization of many coupled ODEs or PDEs operating over a range of room-temperature conditions. Differential
equations have also been mapped to cellular automata-based networks. 850,851,852
Solving an application in analog such as the optimization problems in Section 4.2.3.2, can be thought of as solving a differential
equation. These analog solutions involve a transformation between the physical system to be computed to the analog computing
substrate. Efficient transformation to an analog computing system can result in a 1000× or larger computational efficiency
improvement compared to similar digital approaches.840 Differential equations utilize superposition over the linear operating
region of the particular physics being used.843 Computational complexity when solving applications using differential equations
is still unclear. Although it seems likely that real-valued analog solutions provide an improved computational ability over standard,
discrete-valued Turing machines,843 as of this writing, such capabilities have not been convincingly experimentally demonstrated
to date and is an active research area. As a result, physical algorithms, such as the recently proposed ODEs to solve the 3-SAT
problem 853,854,855 must be developed and verified only through physical hardware, and not discrete simulation or analysis of
physical algorithms.
4.2.3.5. SUB-KT CHAOTIC LOGIC AND CHAOS COMPUTING
Shannon’s noisy channel coding theorem 856 shows that one can reliably communicate information on a channel subject to noise
(at a sufficiently low bitrate) even when the transmitted signal power is below the noise floor (i.e., at a signal-to-noise ratio of
less than 1). Moreover, any computational process can be viewed as just a special case of a communication channel, namely, one
that simply happens to transform the encoded data in transit—since the derivation of Shannon’s theorem relies solely on counting
distinguishable signals, and nothing about how the signals are being counted in Shannon’s argument precludes the encoded data
from being transformed as it passes through the channel. This observation suggests that performing reliable computation utilizing
signal energies (that is, energies associated with the information-bearing variability in the dynamical degrees of freedom in the
system) that are at average levels ≪ 𝑘𝑘𝑘𝑘 (i.e., well below the thermal noise floor) should theoretically also be possible—although
the output bit rate (per unit signal bandwidth) will scale down with the average signal energy.
In 2016, Frank and DeBenedictis investigated a theoretical approach for implementing digital computation using chaotic
dynamical systems 857,858,859 which provided evidence that the above theoretical observation is correct. In that approach, the long-
term average value of a chaotically evolving dynamical degree of freedom encodes a digital bit. The interactions between degrees
of freedom are tailored such that the bit-values represented by different degrees of freedom correspond to the results that would
be computed in an ordinary Boolean circuit. This method can also be considered to be related to analog energy-minimization-
based approaches (§4.2.3.1). However, this method does not require cooling the system to low noise temperatures for annealing,
as is frequently done in energy-minimization approaches. Instead, the dynamical network uses a variation on reversible computing
principles (§4.4) to adiabatically cause the system to transition between different warm, chaotic “strange attractors” that represent
different computational states; this transformation can take place reversibly, without energy loss. The dynamical energy of the
signal variables is itself conserved within the (Hamiltonian) dynamical system, and so the total energy dissipated per result
computed can approach zero in this model as the rate of transformation decreases.
One disadvantage of the particular approach explored in that work is that it exhibits an apparent exponential increase in the real
time required for convergence of the results as the complexity of the computation (number of logic gates) increases. However, as
far as is known at this time, it is possible that faster variations on this or similar techniques may be found with further investigation.
An earlier, more extensively-developed proposal that is similar to the chaotic logic concept is called chaos computing. 860
4.2.4. ANALOG MEMORY AND COMPUTE DEVICES
This section lists some specific device technologies that are useful in analog computing.
4.2.4.1. RERAM
ReRAM memory is very dense and can be integrated in the back end of the line, avoiding the use of transistor area for the memory.
Several ReRAM crossbars have been demonstrated for inference. 861,862,863 A key challenge is maintaining good analog properties
and high resistance at the same time. Nanoscale oxide-based cross-bar memristors with analog properties at high resistance were
demonstrated owing to a natural thermal-confinement-effect when reducing the cross-point area. 864, 865 ReRAM for training
remains a challenge due to the non-ideal electrical characteristics of synaptic devices.
4.2.4.2. PHASE CHANGE MEMORY
Phase-change memory (PCM) offers a wide range of analog memory states due to the large contrast between the amorphous and
crystalline phases. 866 For memory applications, PCM devices can be switched between a high-resistance RESET state, formed
by melting and quenching an amorphous plug that blocks a narrow constriction within the device; and a low-resistance SET state
created by a crystallizing voltage pulse, which frequently ramps down in amplitude over a long duration to produce an extremely
low-resistance state.
In contrast, for VMM applications where “device history” is a desirable feature, PCM devices programmed into the RESET state
can be slowly brought to a much lower-resistance SET state using many repeated partial-crystallization pulses. 867 Careful choice
of pulse condition can stretch this procedure out to many hundreds of pulses. 868 Some recent work has shown some evidence for
gradual increases in resistance with multiple successive pulses, 869 although the operating regime must be carefully prepared, and
the underlying mechanisms are not fully understood.
Many early VMM results using PCM focused on in-situ training (see §4.2.1.2 on Outer-Product Update above).729 Challenges for
training include the one-sided nature of PCM programming, the nonlinear evolution of conductance with partial crystallization
pulses, and the stochastic nature of PCM programming.
More recent VMM results using PCM have turned to inference of previously trained weights. Key challenges for inference include
accurate programming of synaptic state despite the inherent stochasticity observed in PCM device programming, 870,871 reducing
resistance drift due to long-term relaxation of the amorphous phase, and ensuring long retention at high operating temperatures.
PCM unit-cell designs that sacrifice some of the inherently large resistance contrast in order to suppress resistance drift have been
proposed and demonstrated, in both memory and VMM contexts. 872, 873, 874 It turns out that intra-device (e.g., shot-to-shot)
variability in the rate at which devices drift over time (the “drift coefficient”) is more problematic than the actual drift itself. 875
This is because any highly-predictable signal loss can be compensated by signal amplification, at least until background noise
becomes strongly amplified.
4.2.4.3. ION-INSERTION REDOX TRANSISTOR:
Ion-insertion redox transistors (IIRT) have recently emerged as promising candidates for analog memory. 876, 733 IIRTs are three-
terminal devices where charge sent to the gate electrode causes an electrochemical redox reaction in the bulk of the channel. The
reaction modulates the source drain conductance. IIRT channel and gate electrodes are made of redox-active materials (organic
or inorganic) that conduct both electrons and ions (i.e. mixed conductors) and an ionically-conducting, electron-blocking
electrolyte. To maintain global charge neutrality in the device, a counter-ion, typically lithium ions or protons, moves between
the gate and channel and compensates for the changing oxidation state of the gate and channel. To retain the analog state and
prevent the IIRT from discharging, an access device such as a diffusive memristor is required on the gate.
In contrast to traditional semiconductor devices where dopants are static after manufacturing, IIRT represents a class of devices
with dynamic dopant control. For analog memory, a major advantage of IIRT is the large, charge-neutral volumetric capacity that
can be exploited to support gradual tuning of the transistor source-drain conductance. Such properties have promise for synaptic
memory for artificial intelligence applications.732 The storage capacity can be several orders of magnitude larger than traditional
semiconductor devices where information is stored at oxide interfaces. For example, flash-based memory store roughly 50 aC for
a 14/16 nm node. By comparison, lithium containing metal oxides report volumetric capacities at ~5,000 C/cm3 and polymer-
based electrodes reported at ~50 C/cm3 which could provide as much as 50 pF/𝜇𝜇m2 for a 10nm thick channel.
Additionally, IIRTs may offer promise for low voltage digital logic. 877 Dynamic doping can lead to sharp metal insulator
transitions, e.g. due to correlated electron effects in redox-active oxides, 878 and may result in abrupt low voltage switching.
4.2.4.4. FLOATING GATE
Floating gate synapses (so-called “synaptic transistors”) were first developed in 1994. 879 They are modified EEPROM devices
which can be fabricated in a standard CMOS process and programmed to within 0.2% accuracy. 880 A number of sophisticated
systems have been developed based on the arrays of synaptic transistors. 881,882,883. The main advantage of analog and mixed-
signal VMMs based on floating gate memories are very high input and output impedances, which help reducing overhead of
peripheral circuitry. The main drawback of synaptic transistor approach is the relatively large cell area, i.e. > 1000F2, where F
is the minimum feature size 884, leading to higher interconnect capacitances and hence larger energy losses and time delays in
analog computing circuits.
Recently, it was shown that much better area may be obtained re-designing, by simple re-wiring, the arrays of the ubiquitous
NOR flash memories with their highly optimized cells. 885,886 One representative example is Embedded SuperFlash (ESF) memory
from Silicon Storage Technology, Inc. 887 The areas of the modified arrays of the ESF1885 and ESF3886 NOR flash memories, with
the latter technology scalable to F = 28 nm, are close to 120F2 and may be further reduced to ~40F2. (Note that such areas are
much smaller compared to the contemporary 1T1R ReRAM.) Modified 180 nm ESF1 technology was successfully utilized to
demonstrate a medium-scale (28×28-binary-input, 10-output, 2-layer, 101,780-synapse) network for pattern classification.885 The
measured delay and energy dissipation compared very favorably with digital approaches, while the results for chip-to-chip
statistics, long-term drift, and temperature sensitivity of the network were also very encouraging.885 Simulations have shown that
similarly superior energy efficiency may also be reached in mixed-signal neuromorphic circuits based on industrial-grade SONOS
floating gate memories. 888,889
Even higher density floating gate neuromorphic circuits can be achieved by utilizing NAND flash memories. 2D NAND memory
devices designed for digital memory application are already capable of storing 4 bits (16 levels) in a single transistor of 100 nm
× 100 nm area in 32nm process. 890 Commercial NAND manufacturers have shown devices at 15 nm 891 and 19 nm. 892 , 893
EEPROM devices are found at every CMOS IC node, including 7 nm and 11 nm nodes. At these nodes, we still expect very small
capacitors to retain 100s of quantization levels (7-10 bits) limited by electron resolution; in practice, larger capacitors are used,
resulting in sufficiently high potential resolution. One expects EEPROM linear scaling down to 10 nm process to result in a 30 nm
× 30 nm or smaller array pitch area. Perhaps, the most exciting opportunity is presented by the modern 3D NAND circuits. 3D
NAND memories already feature 96 layers of floating gate cells. 894 The number of layers is projected to further increase to 512
to enable 10 Tb/in2 density, 895 which will be essential for storing large-scale neuromorphic models. The very high density of 3D
NAND circuits is achieved at the cost of certain restrictions at the circuit level, such as cells connected sequentially in strings and
shared gate (word) voltages for the cells in the same level. The sequential structure of NAND flash memory can be efficiently
exploited by using time multiplexed computations at the architecture level, in which one cell from a string being utilized at a
particular time step in a distributed VMM circuit. 896 Time-domain encoding of inputs was proposed to implement VMM circuits
based on the existing 3D-NAND flash memory blocks with common word plane structure, not requiring any modification. 897
4.2.4.5. CAPACITOR-ON-GATE
A recent proposal called for a small capacitor that can be programmed with standard CMOS devices to be tied to the gate of a
read transistor. 898 In contrast to DRAM, where the charge on the capacitor is transferred through a select transistor onto a bit-line
for readout, here the voltage on the capacitor modulates the conductance of a read transistor by direct attachment to its gate
terminal. Although the charge leaks away with a time-constant of milliseconds, the training process can succeed if the time-per-
example is at least 100,000× smaller than the decay constant (e.g., 20 ms decay constant and 200 ns per training example). 899
One method to obtain good update linearity, so that the amount of charge added and subtracted are balanced, is to use multiple
large transistors to supply the current in each unit cell.898,899 Additional transistors are then added in order to ensure that, as per
the weight-update algorithm, charge is added or subtracted only when both the upstream neuron (say, along the same row) and
the downstream neuron (along the same column) agree that weight update should occur in a particular synapse shared by those
two neurons. Recently, Ambrogio et al. introduced a combined PCM+capacitor-on-gate unit-cell, in which the PCM provided
the non-volatile storage in a “higher significance” conductance, and the capacitor-on-gate devices provided high update linearity
in a “lower significance” conductance, with periodic weight transfer from the lower to higher significance devices. The number
of transistors associated with the capacitor could be reduced to three: The read transistor, an NFET for charge subtraction and a
PFET for charge addition. This was made possible by giving the downstream neuron control over the NFET and PFET gates, and
having the upstream neuron control the source contacts of these same two charge addition/subtraction transistors. Furthermore,
variability between charge-addition and charge-subtraction due to process nonuniformity was compensated upon weight transfer
from capacitor-on-gate cell to the PCM devices using a “polarity inversion” technique.737 Later, it was shown that this same
technique could suppress fixed device variabilities in other kinds of lower-significance conductances, including PCM devices. 900
This combined PCM+capacitor-on-gate unit-cell was shown to allow GPU-equivalent training accuracies, despite the known
imperfections of PCM devices and typical fab-level CMOS variability in the capacitor-on-gate devices.737
4.2.4.6. CHARGE-BASED ANALOG ARRAYS FOR VMM
Charge-based analog arrays are amenable to very low energy and high-density parallel implementations of vector-matrix
multiplication (VMM). Efficient charge storage and weighting in array-based analog computing are achieved through the use of
capacitive reactive elements or other charge-based linear weighting elements such as charge-coupled devices (CCDs) and charge-
injection devices (CID). Their efficiency stems from inherent charge conservation throughout the computational cycle.
Charge injection device (CID) arrays store each bit of the matrix element in a DRAM storage element. The charge for each bit in
a weight is stored in one of two locations. If the input bit that is multiplying the weight bit is 1, the charge is non-destructively
shifted between locations during readout causing a charge to be capacitively induced on the bit line. The charge induced by
multiple weights can be summed and sensed allowing the entire matrix to be read out in a single operation. Multi-bit inputs are
processed serially. Furthermore, charge is recycled during the computation, and so adiabatic techniques can be used to further
lower the energy (at the cost of speed).
High-density mixed-signal adiabatic processors 901,902,903 using CIDs have been developed using these principles. To optimize for
resonant adiabatic energy recovery a stochastic encoding and decoding scheme can be used to ensure a constant capacitive load
of the CID array. This has resulted in better than 1.1 TMACS/mW efficiency excluding on-chip digitization.903
Alternatively, several approaches have combined a capacitive charge based VMM with analog-to-digital conversion to maintain
high overall system efficiencies. Many analog multiply-and-accumulate operations can be performed for each digitization. High
precision implementations of capacitive charge based VMM have achieved low-pJ/MAC energy efficiencies, 904 while low-
precision versions have achieved efficiencies at the level of 100 fJ/MAC. 905 Comparison of key metrics with the state-of-the-art
in analog capacitive VMM ICs 906,907,908,909,904 is given in Table BC4.2 above.
Table BC4.1 Metrics for Analog Capacitive Vector-Matrix Multiply (VMM) ICs
Figure BC4.4 One Generalized Instantiation of a Photonic MVM unit, with Wavelength Multiplexed Inputs
and Outputs and a Coupler-based Tunable Array. Reproduced from931.
One possible instantiation of a photonic MVMs is shown in the figure above. Power or phase can be used to encode information,
while wavelength or phase selectivity can be used to program the network into a desired configuration. Wavelength division
multiplexing (WDM) can further increasing the compute density of the approach. Classic examples include arrays of resonator
weight banks 915,917,918 or Mach Zehnder interferometers 916. The most important metrics are energy efficiency (energy/MAC),
throughput per unit area (MACs/s/mm2), speed (MVM/s), and latency (s), where both speed and latency are measured across an
entire matrix-vector (MVM) operation. In CMOS, MVM operations are typically instantiated using systolic arrays 919 or SIMD
units, 920 although there are some other architectures that use aspects of both. 921 Digital systems are limited by the use of many
transistors to represent simple operations and require machinery to coordinate the data movement involved in both weights and
activations. The state-of-the-art values typically hover around 0.5–1 pJ/MAC, 0.5–1 TMACs/mm2, 0.5–1 GMVM/s, and 1–2 us,
respectively. In contrast, photonics MVM units could perform in range 2–10 fJ/MAC, 50 TMACs/mm2, and ~3 ps (1 clock cycle)
per MVM operation. This performance depends on solving a number of practical problems which are possible to address in the
short term. These are discussed below.
The largest bottleneck in efficient photonic MVM operations is the use of heaters for coarse tuning. Typically, the thermo-optic
coefficient (dn/dT) is the strongest effect in most materials of interest (i.e., silicon), leading to heavy use of heaters in almost any
tunable passive photonic system. There are several ways these can be eradicated, via the use of post-fabrication trimming 922,923
or devices with an enhanced electro-optic coefficient (dn/dT, dalpha/dT) such that heaters are not as necessary. 924,925 The second
largest problem is fabrication variation, which can result in parameter drifts for devices in an array. Resonators, for example, are
highly sensitive to such variation, particularly across a wafer. This can also be remedied by enhancing the electro-optic coefficient
of devices and some other tricks (see 926,927 for resonators). Third, the signal-to-noise ratio of the output must be optimized by
reducing the intrinsic loss of photonic components together with the noise on the receiver. There are a variety of technologies
that can address this—for example, lasers can be coupled on-chip with < 1 dB of loss, 928 photonic devices in state-of-the-art
silicon foundries can be designed with low scattering, 929 while detectors such as avalanche photodiodes, 930 can reduce the relative
contribution of thermal noise to the signal at the receiver.
Photonic arrays ultimately have very similar limits to analog electronic crossbar arrays, as analyzed in Ref. 931: single-digit
aJ/MAC efficiencies, and 100s of PMACs/s/mm2 compute densities. However, photonic MVMs garner an advantage for larger
MVM units, both in the size of the matrix and in the physical footprint of the core. Generally speaking, optimized photonic
systems tend to perform worse than their electrical counterparts for smaller arrays (distances approximately < 100 um), but
perform better for larger arrays (distances approximately > 100 um)931. In that sense, photonic MVM arrays have a similar profile
to photonic communication channels, with better performance over larger distances. However, photonic systems tend to have
worse signal-to-noise ratios, as a result of several factors: (1) photonic channels are ultimately shot noise limited, which is more
than an order of magnitude greater than the thermal noise limits on resistors,931 and (2) to achieve similar compute densities to
electronics, photonic MVMs must run faster to compensate for their larger device sizes, and noise is speed dependent. That being
said, there are some architectural tricks to reduce this issue—for example, optical unitary operations916 can conserve the variation
of the input and output signals, in contrast to other approaches such as resistive crossbar arrays,718 which by default, see a √𝑁𝑁
decrease in effective signal variation from input to output for an 𝑁𝑁 × 𝑁𝑁 matrix operation.
Although photonic arrays exhibit some fundamental advantages over analog electronics (particularly for large matrix sizes or
large physical sizes), a more important question is whether photonics arrays are practical. Thankfully, the transceiver industry
has created a silicon photonic ecosystem fully compatible with high volume manufacturing (HVM). Compared to CMOS chips,
photonics has costlier packaging, largely because light generation cannot be done easily in silicon—in fact, the cost of a
production photonic chip is dominated by packaging. In addition, the tools required for the design and testing of large-scale
photonic systems (>10k components) are still early in early development—analog photonic systems must grapple with the
challenge of addressing yield, variability, precision, and tunability. Nonetheless, the total cost to produce a photonic chip package
at high volume is dipping below one hundred dollars, and it is expected that the trend will continue 932. The orders of magnitude
advantages offered by photonics, and its potential for HVM scalability, makes it a viable inroad for the breakneck performance
and innovation required by artificial intelligence algorithms in the years to come.
4.2.4.9. MAGNETIC NEURAL NETWORK DEVICES
Several types of magnetic circuits can be used to implement neural networks including spin-diffusion-based devices, 933 charge-
coupled spin logic (CSL), 934 and domain wall logic (mLogic). 935. The use of these different devices has been benchmarked. 936
Magnet switching dynamics that follow the Landau-Lifshitz-Gilbert (LLG) equation with a spin-transfer-torque term are quite
similar to the cell dynamics in a Cellular Neural Network (CeNN). CeNNs have been designed based on spin diffusion using all-
spin logic (ASL) with PMA magnets as the basic building block. A CeNN cell can also be implemented by using MTJs as
synapses and using spin Hall effect or domain wall propagation-based devices as the neuron. In all these cases, the read-out circuit
consists of read and reference MTJs and an inverter that amplifies the voltage division between the two MTJs.
In contrast to Boolean circuits, spintronic devices are more attractive compared to charge-based devices. This is because a single
magnet can mimic the functionality of a neuron, and these spintronic devices operate at a low supply voltage. The domain wall
device provides the best performance, in terms of Energy-Delay Product (EDP), thanks to its low critical current requirement.
The spin diffusion based CeNN with IMA magnets consumes more energy due to the large critical current required to switch the
magnet.
For optimal circuit-level performance using spintronic devices, several properties are desired including: MTJs with a large TMR
and a moderate resistance-area product, large spin injection coefficient 𝛽𝛽, large perpendicular anisotropy Ku for PMA magnets,
large spin Hall angle 𝜃𝜃 for SHE materials, and small critical depinning current for domain wall magnets.
4.2.4.10. DEVICE TECHNOLOGIES FOR COUPLED OSCILLATOR SYSTEMS
It is challenging to build compact, low-power oscillators that can also be coupled together to give predictable phase or frequency
dynamics. Standard digital ring oscillators based on CMOS inverter feedback loops, as well as the typical transistor-driven LC
oscillators used in RF designs, are both less than ideal, due to device nonlinearities in the digital regime and the high biasing
currents used in linear-regime analog small-signal oscillators, as well as relatively large oscillator sizes in both cases. Thus,
various “Beyond CMOS” oscillator technologies have been explored. Such technologies can use and manipulate the charge, spin,
or quantum properties of electrons, or use photons. Important examples include spin-torque, 937,938,939 insulator-metal-transition, 940
optical,815,941 and quantum. 942 Memristor-based oscillators have also been constructed. 943,944,945
Non-silicon electrical oscillators include two important kinds which are currently being developed. One prominent effort is the
use of spin torque oscillators (STOs) coupled with using spin diffusion currents, or electrical signals, for providing a
computational platform for machine learning, spiking neural networks, and others.937–939,815,946,947,948 However, the high current
densities of STOs and the limited range of spin diffusion currents continue to pose serious challenges in creating coupled networks
of such oscillators. Optical oscillators have been studied941, 949 and used for computing,815 but challenges include bulky
components, difficult interfacing between the electrical and optical domains, and lack of programmability to enable an optical
computing apparatus. Another promising non-silicon technology for very compact oscillators is the IMT (insulator-metal
transition) material-based oscillator technology. 950, 951 As the oscillation mechanism is completely electrical, the coupling of
oscillators can be done easily using electrical components. There have been other implementation efforts for electrical
oscillators 952,953,954,955,956 but the focus has been to build high frequency and low power individual oscillators, as opposed to the
demonstration of coupled systems of oscillators, or the generation of interesting dynamics for computing. A comparison of some
computing-focused electrical oscillators is shown in Table BC4.3 below.
Recently, Mott memristors, 960 phase change based memristive switches, 961 and chalcogenide threshold switches 962 have all been
reported to be capable of performing temporal voltage signal integration in which the effects of non-simultaneous unitary post-
synaptic potentials add in time. Device candidates to perform the transfer function include STT-MRAM. 963
Ionic diffusion dynamics or electrical instabilities enable a single memristive device to perform analog functions like resistance
tuning or pulse generation after accumulating input,961,964 which typically requires a large number of CMOS transistors. These
analog functions are critical in emulating synaptic and neuronal behavior. Taking into account the simple structure and scalability
of a two-terminal memristor, both the complexity of a circuit and the area consumed to build a neuron network will be much less
compared to a CMOS circuit. Being a passive device, the memristor offers stimulation-dependent electric conductance. However,
the passive nature results in a lack of power to maintain sustainable neural signal propagation in a network if passive synaptic
blocks are employed. Additional power sources are mandatory for neural networks with multiple layers.
The benchmarks used to evaluate electronic spiking neurons generally measure the energy per operation, the fabrication cost, or
the chip area of the integrated functional block, and the fidelity to the desired neuron function (e.g. integrate and fire). High
reliability and low variation of devices are two key factors for the viability of a neuron technology. Device failure will require a
lot more circuitry for error detection and correction. 965 Large variation increases the difficulty for designing peripheral circuits
and degrades the adaptability of the block.
To achieve unsupervised learning in a network, particularly those based on spike-timing-dependent plasticity, neuron blocks
should be capable of programming the synaptic blocks. A key design challenge will be engineering the forward and back-
propagating action potentials from the analog neuron blocks to potentiate or depress synapses for real time and in situ learning.
4.2.5. ANALOG COMPUTING—CLOSING REMARKS
Analog computation, as surveyed above, presents us with an intriguing and varied array of options for transcending the limitations
that apply to the present-day digital approaches to computing. However, more work is needed to better characterize the range of
applications for which analog computation can provide significant advantages over digital.
Enormously complex digital information-processing systems have been constructed by leveraging hardware description
languages and programming languages that enable encapsulation, composability, and hierarchical design. To enable complex
analog systems, more flexible, powerful languages (graphical and/or textual) for representing general classes of analog circuits
and architectures are needed, to allow for a similar “modular” design approach.
Even the most advanced and sophisticated analog computational structures reviewed above in this section are only just the
beginning. It appears that analog computing represents a vast field of future study, one that would likely benefit from a much
more intensive level of exploration than it has received to date.
4.3. PROBABILISTIC CIRCUITS
Traditionally, conventional computational processes are designed to be deterministic, with computational results determined by
the machine’s initial state and inputs. Nevertheless, computations that are intentionally designed to behave randomly or
stochastically, even at the level of individual bit-operations, are of interest and can have many useful applications such as
simulated annealing, Monte Carlo simulation, machine learning or Boltzmann machines, randomized algorithms 966 as studied in
computational complexity theory, and cryptographically secure random number generation for generating secure private keys.
Noise in biological neurons is beneficial for information processing in nonlinear systems, and is essential for computation and
learning in cortical microcircuits. 967,968,969,970
Obtaining randomness in traditional CMOS is difficult and typically relies on a pseudo-random number generator. This requires
a large circuit block and significant computational effort to obtain high quality random numbers. Several new devices have been
proposed to obtain true randomness as discussed in §4.3.1. These allow for a random bit to be generated with a single device.
Chaotic devices can be used to turn poor quality randomness into high quality random numbers. Novel architectures such as
probabilistic p-logic (§4.3.2) or a traveling salesman solver (§4.2.3.1) can be designed using the new true random number
generators.
4.3.1. DEVICE TECHNOLOGIES FOR RANDOM BIT GENERATION
New devices based on memristors, avalanche breakdown, and magnetic tunnel junctions and other technologies have been
proposed for generating random bits. A key enabling functionality for some architectures like probabilistic (p)-logic is the ability
to tunably control the probability of a zero or one based on an input current or voltage. Several proposed devices are listed below.
4.3.1.1. MAGNETIC TUNNEL JUNCTIONS (MTJ)
Existing Embedded MRAM technology can be used to create a tunable random bit, provided that the Magnetic Tunnel Junctions
are engineered to be thermally unstable. Such thermally unstable magnets have been experimentally observed. As MTJ
dimensions are scaled, keeping them thermally stable becomes a hard challenge for memories, therefore destabilizing them in a
controllable manner should be feasible in current technology.
Low-barrier MTJs can convert ambient thermal noise on nanomagnets into a fluctuating resistance, which is then used to build a
device with tunable randomness when integrated with minimal CMOS periphery. The fluctuating resistance change due to thermal
magnetic noise in MTJs can be measured by Tunneling Magneto resistance (TMR). State-of-the-art TMR values range from
upwards of 100% to 600% demonstrated by the Tohoku Group, 971 and commercial STT-MRAM devices exhibit >100% TMR.
A large TMR would enable a robust functional unit for controllable randomness. The theoretical limit for TMR in MgO-based
MTJs has been reported 972 to be 1,000% and can presumably be larger. There is currently intense research activity in half-metallic
ferromagnets to increase TMR.
4.3.1.2. SINGLE-ELECTRON BIPOLAR AVALANCHE TRANSISTOR (SEBAT)
The single-electron bipolar avalanche transistor (SEBAT) is a novel Geiger-mode avalanche bipolar transistor structure. 973,974
The device generates Poisson-distributed digital output pulses at rates between 1kHz and 20MHz. The pulse rate is linearly
proportional to the emitted current. A MOS transistor is also formed within the base region of the device, allowing for voltage
control of the pulse rate. The device is fully compatible with low-voltage CMOS circuits and standard digital process steps.
4.3.1.3. MEMRISTORS/RESISTIVE RAM
The intrinsic variability of memristive switching, particularly the switching delay time of memristors, can be a good source of
stochasticity. 975,976,977 Such stochasticity originates from the ionic dynamics within the memristors. 978
4.3.1.4. CONTACT-RESISTIVE RANDOM ACCESS MEMORY (CRRAM)
CRRAM can be used for random number generation.975, 979 A CRRAM device may be based on a layer of silicon dioxide that is
sandwiched between two electrodes; the bottom electrode could simply be the drain of a CMOS transistor. 980 During operation,
the current flowing in a filament channel will be (randomly) impacted by any electrons trapped in the insulating layer. If a high
voltage is applied to a device, the current in the filament channel will be large and not impacted by trapped electrons. However,
with the application of a lower voltage, the width of a filament will shrink, and the trapped electrons will (randomly) influence
output current.
4.3.1.5. CMOS
There are different ways to obtain random number generators (RNG) in CMOS using different physical noise sources, one being
“jitter” in ring oscillators. 981 These TRNGs can be tuned into tunable random number generators as required but require
significant amounts of area when compared to single device alternatives.
4.3.1.6. STOCHASTIC JOSEPHSON JUNCTION
Single flux quantum (SFQ) logic relies on voltage pulses generated by 2π phase slips of the superconducting order parameter
across a Josephson junction. These voltage pulses have a time-integrated amplitude given by the flux quantum Φ0 = 2×10−15 Wb.
A standard circuit model of a Josephson junction is the parallel connection of a supercurrent up to Ic the critical current, a normal
state resistor, a capacitor, and a channel for the thermal noise term. The resulting dynamics are the same as a forced damped
pendulum. The energy barrier is given by (IcΦ0)/(2π). For stochastic operation one can operate with junctions that meet the
condition δ = (2π kBT)/(IcΦ0) ~ 10, where δ is the stochasticity, kB is the Boltzmann constant and T is the temperature in kelvin.
The exact value of the stochasticity is an important circuit parameter as it determines the frequency of spiking events. In this
regime, the energy in a single flux quantum spike is sub-attojoule while the frequency can be greater than 100 GHz. 982
Because Josephson junctions can be operated near the thermal stability limit, the amount of stochasticity can be varied by
changing the temperature a few degrees. For values of the stochasticity less than 10, the dynamics are basically deterministic,
whereas when the stochasticity is larger there is a significant stochastic component. The value of the stochasticity can be
effectively tuned between the deterministic state and the stochastic state by changing the temperature of the circuit by a few
degrees. 983 Circuits based on these devices have many promising potential applications. For example, stochastic Josephson
junctions have been shown to make effective pseudo-sigmoid generators, 984 and stochastic Josephson junction spiking can
perform the neural accumulate operation at speeds up to 70 GHz. 985
4.3.2. PROBABILISTIC (P)- LOGIC
In a series of recent papers, Camsari, Datta and collaborators proposed a type of probabilistic computing model introducing the
concept of p-bits and p-circuits. 986 , 987 The authors explored how p-bits can be compactly realized by leveraging existing
Magnetoresistive RAM (MRAM) technology 988 and showed different applications of p-circuits including image recognition
(inference), 989 combinatorial optimization, 990 Bayesian networks, 991 and an enhanced type of Boolean logic that allows invertible
operation.987 More recently, potential applications have been extended to include emulation of a class of quantum systems 992 and
on-chip learning for stochastic neural networks. 993 Further, a prototype realization of an 8 p-bit circuit demonstrating a quantum-
inspired integer factorization algorithm that uses MRAM-based p-bits has recently been realized. 994
The main function of a p-bit is to provide tunable randomness of a digitized voltage at its output terminal controlled by an analog
input terminal.987,988 The tunability allows a network of p-bits (p-circuits) to be able to get correlated with one another when
appropriately connected through a programmable feedback circuit. Even though the p-bit concept is hardware agnostic and digital
implementations of invertible logic have been realized, 995, 996 the main advantage of an MRAM-based p-bit comes from its
compact, low-power implementation of a complex functionality (tunable randomness) compared to digital implementations.994
In the context of Machine Learning, this functionality is an approximate hardware representation of a binary stochastic neuron,
allowing a natural mapping of powerful algorithms developed for such stochastic neural networks. Secondly, the generic p-circuit
consists of autonomously operating p-bits without any digital clocking circuitry, leading to a massively parallel architecture
whose performance increases with the number of p-bits in the system. 997 Recent breakthroughs in modern MRAM industry has
led to production-ready integrated chips with up to 1 Gb cell densities, thus leveraging this technology could lead to application
specific probabilistic coprocessors with broad applications for the active fields of Quantum Computing and Machine Learning. 998
4.4. REVERSIBLE COMPUTING
Besides analog computing (§4.2) and probabilistic computing (§4.3), a third dimension along which we may explore departures
from the conventional computing paradigm, is reversible computing. 999 In the present context, when we say that a computation
is reversible, we mean that the lowest-level physical computational processes should be arranged to approach a condition of being
both logically reversible and thermodynamically reversible. To say that a computational process is logically reversible means
that known or deterministically computed information is not obliviously discarded from the digital state of the machine and
ejected to a randomizing thermal environment. To say that the computation process approaches being thermodynamically
reversible here means that the total increase in physical entropy incurred by the machine’s operation per useful computational
operation performed should be extremely small, with the vision that this quantity can be brought closer to zero asymptotically as
the technology continues to be improved.
In 1961, Rolf Landauer of IBM argued 1000 that there is a fundamental physical limit on the energy efficiency of conventional
irreversible digital operations, meaning those that carry out a many-to-one transformation of the space of computational states
that is used. Landauer’s limit states that an amount kT ln 2 of available energy (where k is Boltzmann’s constant and T is the
temperature of the heat bath) must be (irreversibly) dissipated to heat per bit’s worth of (known or correlated) information that is
lost from the computational state. Landauer’s limit can be rigorously derived from fundamental physical considerations.702,1001
An important caveat to be aware of is that Landauer’s limit only applies to computational information that is correlated with
other available information, as opposed to independent random information.702,1002 A computational bit that bears no correlations
with other available bits is, in effect, already entropy, and thus it can be transferred back and forth between a stable, digital form
in a computer and a rapidly-fluctuating physical form in a thermal environment with asymptotically zero net increase in total
entropy, by, for example, adiabatically raising and lowering a potential energy barrier separating two degenerate states.702
However, most bits in a digital computer are correlated bits, having been computed deterministically from other available bits.
Performing a many-to-one transformation such as destructively overwriting or erasing such a bit obliviously (i.e., without regards
to its existing correlations) therefore typically increases total entropy by one bit’s worth (k ln 2) and thus implies at least kT ln 2
energy consumption (loss of available energy). Fundamentally, then, the only way to avoid Landauer’s limit, in a deterministic
computational process, is to avoid many-to-one transformations of the computational state. Bennett 1003 showed that indeed, this
is always possible; that is, any desired irreversible computation can always be embedded into a functionally equivalent reversible
one. Such an embedding generally appears to incur some algorithmic overheads, 1004 in terms of (abstract) time or space
complexity, but if reversible devices continue to become cheaper and more energy-efficient over time, then, in principle, these
resource overheads can be outweighed by the achievable energy savings, and total cost may be reduced compared to an
irreversible design. In the long run, reversible computing is the only physically possible path by which the amount of general
digital computation that can be performed per unit energy (and cost!) might continue to be increased indefinitely, without any
known fundamental limit.
In existing adiabatic implementations of reversible computing in today’s device technologies (see §§4.4.1–4.4.2 below), one
typically finds that there is a linear tradeoff, at the device level, between the energy dissipation 𝐸𝐸diss resulting from, and the time
interval 𝑡𝑡d required to carry out, a given primitive digital operation in the adiabatic limit. We can express this tradeoff relation by
stating that the dissipation-delay product (DdP) of the technology is a constant, over some range of achievable delay values. E.g.,
within that range, we can write
𝐸𝐸diss ⋅ 𝑡𝑡d ≅ 𝑐𝑐E ,
where 𝑐𝑐E is the constant DdP, which we may also call the energy coefficient of the technology. However, there is no proof that
this same linear tradeoff relation extends to all possible implementation technologies for reversible computing, and in fact, recent
results suggest that an exponential downscaling of energy dissipation with delay may sometimes be possible when quantum
effects are leveraged. 1005 Further, even among cases where the linear relation still applies, there are no known technology-
independent lower bounds on the value of the dissipation-delay constant. Although there are indeed firm quantum lower limits
on the product of energy invested in performing an operation times the delay, 1006 there are no known fundamental lower limits
above zero on energy dissipated for any given delay value. Further, even when a fixed value of the constant is given, thermally
limited parallel processors can still benefit from reversible computing in terms of their aggregate performance. For example, in
cooling-limited stacked 3D logic scenarios, the per-area performance advantage of time-proportionally adiabatic technologies
increases with the square root of 3D processor thickness. 1007 And in loosely-coupled, arbitrarily-massively-parallelizable
applications with fixed power budgets, the aggregate performance gain from adiabatic computing scales up with energy efficiency
arbitrarily.
However, as of today, experimentally realizing reversible computing’s promise to vastly exceed the system-level energy
efficiency of all conventional computers in practice remains a difficult engineering challenge. Although a variety of different
adiabatic 1008,1009,1010,1011,1012,1013,1014,1015,1016,1005 and ballistic 1017,1018,1019,1020,1021,1022,1023,1024,1025,1026,1027,1028,1029,1030, 1031 schemes for
the realization of reversible computation have been proposed, it has so far turned out to be challenging to actually achieve large
energy efficiency gains at the system level in practice while accounting for all of the complexity overheads that are incurred from
using a mostly-reversible design discipline, together with a variety of real-world parasitic energy dissipation mechanisms that
exist and would need to be systematically eliminated or reduced. (See §4.4.4 for further discussion.) There is not yet any “magic
bullet” physical implementation strategy that automatically addresses all the many possible energy-loss mechanisms in a complete
system all at once. Logical reversibility (when suitably generalized703) is indeed a necessary condition for approaching physical
reversibility in deterministic digital computations, but it is by no means a sufficient one.
However, while approaching the ideal of physically reversible computing is by no means an easy path forward, it is at least a way
that general digital computing can move forward. Plausibly, even in CMOS, adiabatic circuits might be able to demonstrate useful
energy efficiency gains for highly energy-limited applications (such as spacecraft) even in the relatively near term if sufficiently
high-Q resonators can be developed. 1032 Further, even some of the existing reversible superconducting logic styles (such as
RQFP 1033,1034,1035,1036,1037,1038 and nSQUID 1039,1040,1041 logic) already appear to be capable of achieving energy dissipation below
the Landauer limit in principle, although the available analyses don’t include dissipation in the clock-power supply. However,
in cryogenic applications, if the dissipation in the power supply can take place in a higher-temperature exterior environment, this
can translate to a significant and highly practically useful reduction in the amount of power that is dissipated internally within
the low-temperature system.704,705 Finally, superconducting technologies operate with extremely small signal energies, which, if
transferred nondissipatively to the room-temperature environment, become relatively insignificant in absolute terms; this can
reduce pressure on AC supply design even for general HPC applications. See §4.4.2 below for further discussion of
superconducting reversible computing technologies.
Reversible computing can also be potentially usefully combined with probabilistic computing (§4.3); if random digital bits are
obtained by taking in entropy from the thermal environment and capturing it in a stable form, this can actually reduce environment
entropy temporarily—albeit without reducing total entropy, of course, since the entropy of the digital state is increased.702 Once
a randomized reversible computation utilizing such bits of “true” entropy has completed, those random bits can later be returned
to the thermal environment with no net thermodynamic cost.702 Thus, the requirement for such a nondeterministic computation
to be thermodynamically reversible is somewhat looser than is the case for a deterministic computation; many-to-one
(irreversible) transformations can be permitted together with compensating one-to-many (nondeterministic) transformations in a
computation, 1042 so long as, overall over the course of the computation, previously-established correlations are not lost.
Reversible computing is normally conceived of as a strategy for making digital computation more energy efficient. More
generally, can a broad variety of analog computing schemes be developed that are also thermodynamically reversible? Record
energy efficiencies for charge-based analog vector-matrix multiplication have been demonstrated using adiabatic principles as
discussed in §4.2.4.6. 1043 Further, fundamental physics is reversible at the microscale, which suggests that a sufficiently carefully-
engineered analog computer might be made to approach macroscopic reversibility, and that its energy efficiency might be
increased without limit as its technology is further refined. The degrees of freedom utilized for the analog physical computation
would likely have to be very well-isolated from the system’s thermal degrees of freedom, and the usual tendency for complex
dynamical systems to devolve towards chaotic behavior would have to be suppressed in some way, or else made into a useful
feature of the computational process. The previously mentioned work on chaotic logic (§4.2.3.4) suggests one potential technique
for harnessing the chaotic analog behavior of conservative dynamical systems usefully for computational purposes, but many
other, more sophisticated methods may be possible.
Figure BC4.5 Energy Dissipation per Stage vs. Frequency in an Adiabatic CMOS Shift Register
4.4.1. REVERSIBLE ADIABATIC CMOS
As mentioned above, currently the most well-developed implementation technologies for reversible computing are those that
utilize classical quasi-adiabatic transformations to carry out digital state transitions. Among such technologies, the most well-
developed class of them at present has been referred to variously as adiabatic CMOS, adiabatic transistor circuits,705 or just
adiabatic circuits. In traditional (irreversible, non-adiabatic) CMOS circuits, the full digital circuit-node signal energy of ½CV2
is dissipated to heat on every digital switching event. In contrast, the use of classical quasi-adiabatic transitions for switching
reduces the associated local dissipation by a factor of ~t/2RC, where t is the transition time for a linear voltage ramp and R is the
resistance of the charging path. This reduction yields a linear tradeoff between speed and energy dissipation per operation over a
certain range of frequencies, where the dissipation-delay product or energy coefficient scales as 𝑐𝑐E ∝ 𝐶𝐶 2 𝑉𝑉 2 𝑅𝑅.
The earliest complete circuit families for sequential, pipelined reversible computing with adiabatic CMOS were developed in the
1990s in Tom Knight’s group at MIT.1011,1044,1045,1046,1047,1048 These methods did not gain widespread traction at the time, perhaps
because, to save energy, adiabatic CMOS must operate relatively slowly compared to the inherent RC propagation delay of the
gates. However, in the period since the end of Dennard scaling in ~2005, multi-core processor performance has become
increasingly limited by power dissipation rather than by raw gate delays (witness the increasing amounts of “dark silicon” in
modern processor designs), so, revisiting the adiabatic energy-delay tradeoff appears timely at present. Adiabatic switching holds
promise as a design technique for the future, since it offers a means by which the dissipation-delay frontier of any given CMOS
technology might be expanded beyond the limits of what can be achieved using more conventional low-power design techniques,
such as subthreshold operation.
Subsequent to the original MIT adiabatic logic families cited above, a number of other adiabatic logic design styles were also
explored, such as two-level adiabatic logic (2LAL),1013,1049 positive feedback logic (PFAL), 1050,1051 and efficient charge recovery
logic (ECRL). 1052,1053 In addition, applications to the design of secure circuits have also been explored, since the unique electrical
behavior of adiabatic CMOS circuits can help to prevent non-invasive side channel attacks. 1054 , 1055 And general-purpose
computing has been pursued in the design of adiabatic microprocessors. 1056,1057 The simulation results shown in Fig. BC4.51057
indicate that, when operated adiabatically, advanced CMOS nodes such as 28 nm technology can dissipate less energy per cycle
than prior nodes at relatively high frequencies, at which dynamic power dissipation exceeds the leakage losses. In contrast, if the
same circuit is operated irreversibly, it dissipates an energy orders of magnitude higher at all frequencies up into the GHz range.
4.4.2. REVERSIBLE ADIABATIC SUPERCONDUCTING LOGIC
After adiabatic CMOS, currently the second most well-developed type of hardware technology for reversible computing based
on classical adiabatic transformations is the class of adiabatic superconducting logic families.1008–1009,1014,1033–1040 A significant
motivation for the consideration of superconducting circuits for energy-efficient computation is the lossless nature of charge
transport in Josephson junctions and superconducting wires, which act as switching elements and interconnects, respectively.
Also, the naturally discrete phenomenon of flux quantization facilitates the restoration and stabilization of digital signals.
Two basic families of superconducting reversible digital elements, the parametric quantron (PQ)1008 and quantum flux
parametron (QFP) 1058,1009 were proposed in early studies. Both approaches were based conceptually on the abstract physical
model of adiabatic digital operations introduced by Landauer,1000,1003 in which the potential energy function of the digital element
is transformed adiabatically between single-well and double-well configurations in the course of the operation. As with adiabatic
CMOS, superconducting reversible logic gates utilizing this approach require AC driving waveforms, in this case to provide a
time-dependent flux bias to each gate. More recently, a DC-powered superconducting reversible logic gate based on a negative-
inductance SQUID (nSQUID) was proposed, 1059 and its energy dissipation was estimated to be a few kT per reversible bit-
operation.1039
Recently, a further reduction of the energy dissipation of the QFP approach was achieved by appropriately optimizing the circuit
parameters for the adiabatic mode of operation1014 and eliminating the junction shunt resistance. 1060 The energy dissipation of this
improved adiabatic QFP (AQFP) was investigated numerically, taking thermal noise into account, 1061 and found to be well below
kT with a low error rate.1033 The energy dissipation of a single AQFP gate was estimated to be 10 zJ per gate at 5 GHz by
measuring the scattering parameters of a superconducting resonator coupled to an AQFP gate. 1062 The energy dissipation per
operation of an (irreversible) AQFP 8-b carry-lookahead adder was experimentally evaluated to be 24 kT per Josephson
junction. 1063
The first demonstration of logically and physically reversible operation of superconducting logic was performed using a newer
reversible QFP (RQFP) design style.1034 The basic RQFP element is a logic gate having three binary inputs x0, x1, x2 and three
outputs y0, y1, y2 that are related by
(𝑦𝑦0 , 𝑦𝑦1 , 𝑦𝑦2 ) = �MAJ(𝑥𝑥0 𝑥𝑥1 , 𝑥𝑥2 ), MAJ(𝑥𝑥0 , 𝑥𝑥
���, 1 𝑥𝑥2 ), MAJ(𝑥𝑥0 , 𝑥𝑥1 , 𝑥𝑥
���, ���)�
2
where MAJ(𝑖𝑖, 𝑗𝑗, 𝑘𝑘) = (𝑖𝑖 ∧ 𝑗𝑗) ∨ (𝑗𝑗 ∧ 𝑘𝑘) ∨ (𝑘𝑘 ∧ 𝑖𝑖). This logically reversible element is composed of three AQFP splitter gates and
three AQFP majority gates. The bidirectionality and time reversal symmetry of the RQFP gate were investigated, revealing the
cause of the energy dissipation in logically irreversible AQFP logic.1035 Using RQFP gates, the functionality of a 1-bit reversible
full adder was demonstrated, and its energy dissipation was numerically calculated, while accounting for thermal noise. Fig.
BC4.6 shows the simulation results for the energy dissipation of the reversible and irreversible full adders as a function of the
frequency of the driving clock. 1064 It was found that the energy dissipation of the reversible full adder is much lower than that
of the irreversible full adder; it becomes lower than the kT thermal energy at 4.2 K at frequencies below 20 MHz.
Figure BC4.6 Energy dissipation of RQFP and irreversible AQFP 1-b full adders
Note: Figure is from Ref. 1064. Simulation results are plotted as a function of the frequency of the excitation (driving) clock. Lines are
calculation results at 0 K, markers show results accounting for thermal noise at T = 4.2 K.
technology concept pioneered at Notre Dame, which has been taken up to the level of complete simulated processor
designs. 1070,1071 However, there is not, as of yet, a viable manufacturing process for fabricating scalable QCA-based processors.
To conclude our review of the adiabatic approaches, we mention an interesting concept for adiabatic capacitive logic. 1072
In addition to the various adiabatic approaches to reversible computing, there are also a number of ballistic reversible computing
concepts.1017–1031 These are based on a rather different picture of the basic physical mechanism of reversible computing than the
adiabatic approach suggested by Landauer.1000 In the adiabatic approach, some external system (i.e., separate from the logic
circuits) drives the adiabatic transformations of the computing system that carry out transitions between digital states. Whereas,
in the ballistic picture, first conceived by Ed Fredkin,1017 the physically-reversible dynamics of the system is instead self-
contained; in other words, individual entities (such as particles or pulses) carrying information-bearing degrees of freedom evolve
forwards reversibly under their own (generalized) inertia, as it were, with no direct external influence.
We should note that the distinction between the two classes of approaches is not a perfectly crisp one, since, even in the adiabatic
approach, the driving system (such as a resonant oscillator) can be viewed as evolving ballistically, and even in the ballistic
approach, the interactions (e.g., elastic collisions) between individual ballistically-propagating information-bearing entities can
be analyzed, on a sufficiently fine timescale, as adiabatic processes. So, to some extent, the distinction between the approaches
is primarily just one of perspective and emphasis. However, generally speaking, the adiabatic approaches are characterized by a
large-scale separation of the ballistic driving systems from the adiabatic logic, whereas in the ballistic approaches, the ballistic
properties are distributed throughout the system, and are associated to the lowest-level information-bearing entities themselves.
We can also imagine that other, future approaches could interpolate between these two extremes; e.g., one could imagine systems
comprising large numbers of small ballistic oscillators, each driving just a small region of local adiabatic logic, with the various
subsystems communicating timing information and data to each other via elastic interactions transmitted via (short- or long-
range) couplings between individual oscillators.
In terms of practical realizations of a (fully-distributed) ballistic approach to reversible computing, the approaches to this that
have been developed most intensively to date are based on superconducting electronics.1019–1031 This is a particularly convenient
technology for ballistic computing, because, unlike in semiconductors, superconductors exhibit the phenomenon of naturally-
discrete single flux quanta (SFQ), which can propagate near-ballistically along interconnects consisting of passive transmission
lines (PTLs) 1073 or long Josephson junctions (LJJs). 1074 Currently active efforts to develop reversible computing technologies
focused on SFQ-based approaches include the synchronous ballistic approach which has been explored since around 2010 at U.
Maryland,1023–1027 and the asynchronous ballistic approach which has been in development since 2016 at Sandia.1028–1031
4.4.4. CHALLENGES FOR REVERSIBLE COMPUTING
Despite the great long-term promise of reversible computing, many fundamental engineering challenges associated with the
development of a practical reversible computing technology remain to be solved at this time. These include the following:
• Even at the level of very basic physics, a more complete understanding is needed of the fundamental (technology-
independent) physical limitations of important cost metrics for reversible computing, such as the dissipation-delay
product (DdP), or, more generally, energy dissipation as a function of delay, D(d). Are there universal lower bounds on
this quantity that we can derive based on parameters such as temperature, or the length scale of devices, or perhaps based
on some kind of generalized viscosity characteristics, or on other fundamental physical or materials-dependent parame-
ters?
• New, more complete abstract (but still realistic) physical models of reversible computing should be crafted to illustrate
how we might more closely saturate the above fundamental limits in real artifacts, pointing the way to new device and
circuit concepts for reversible computing. Are there quantum-mechanical approaches or phenomena that could be use-
fully harnessed, such as shortcuts to adiabaticity (STA), 1075 topological invariants, dynamical variations of the quantum
Zeno effect (QZE) 1076,1077 or others, to help reversible computing technologies to further suppress the rate of entropy
increase while still operating as quickly as possible?
• Facilitated by fundamental advances such as the above, new device and circuit concepts for reversible computing need
to be developed that significantly reduce D(d) at useful operating speeds while still being inexpensively manufacturable.
New physical mechanisms for computing need to be developed with reversible operation in mind from the start.
• Meanwhile, to advance the achievable energy efficiency of adiabatic CMOS for cryogenic applications, novel FET
device structures that are optimized to minimize leakage at particular cryogenic temperatures of interest with minimal
impact on device performance (expressed in terms of, say, DdP) need to be developed.
• For adiabatic reversible computing technologies operating at room temperature, the logic signal energy (e.g., ½CV2 in
CMOS) remains a concern, since it still exists even in adiabatic circuits, and is merely transferred dynamically to the
power-clock generator system, rather than being dissipated locally within the logic. Thus, to achieve significant overall
energy savings at the system level, compared to the corresponding irreversible technology, this generator must be
designed to efficiently recover a large fraction of this signal energy, e.g., by comprising a resonant oscillator with a high
quality factor (Q). Designing extremely high-Q resonators and clock distribution networks already demands advanced,
high-precision engineering. Further, as RF designers know, achieving high Q implies narrow bandwidth. This in turn
implies that the returned clock waveform must be extremely pristine—e.g., any data-dependent back-action from the
logic must be avoided. Thus, we must maintain a careful load balancing discipline, e.g. through complementary signal-
ing. And if bulk semiconductors are used, this adds another level of challenge relating to time-varying loads during
transitions, since device capacitances are more voltage-dependent if depletion regions are not structurally constrained.
• At higher levels, many advances in areas such as reversible architectures, EDA tool enhancements to support reversible
design styles, reversible algorithms and so forth still need to be developed. As useful reversible computing hardware
technologies emerge and develop, systems engineering practice will need to evolve to best leverage the opportunities
and tradeoffs offered by reversible design. However, all these R&D areas remain in their infancy at this time.
4.5. DEVICE-ARCHITECTURE INTERACTION: CONCLUSIONS/RECOMMENDATIONS
In this section, we have surveyed a variety of concepts and R&D directions for the development of novel Beyond CMOS
computing technologies that represent an effort to think “outside the box,” in the sense of looking beyond just developing simple
drop-in replacements for traditional logic and memory cells. More broadly, new hardware designs spanning multiple levels from
the devices up through circuits and architectures must be considered, and the interactions between the various levels explored.
More specifically, we expand the scope of future computing technologies beyond traditional irreversible, deterministic digital
logic to include a broad range of alternative, unconventional computational paradigms, such as analog, probabilistic, and (classi-
cal) reversible computing paradigms.
Recommendations. In general, computing paradigms outside of the traditional irreversible, deterministic, digital paradigm are
still very under-developed, compared to the conventional paradigm. This is not surprising, considering that the conventional
paradigm historically facilitated the development of a design abstraction hierarchy that permitted enormously complex systems
to be constructed. As a result, the complexity and efficiency of those systems increased exponentially as Moore’s Law made the
underlying devices cheaper and more efficient. However, Dennard scaling has now ended, the end of the CMOS roadmap appears
to be in sight, with no clear successor having been identified, and fundamental thermodynamic limits are also coming into view.
Thus, today there is an increasing level of interest in expanding the scope of our investigations to include unconventional comp-
uting paradigms that may transcend the limits of the traditional computing paradigm.
Overall, the potential utility of new styles of “Beyond CMOS” computing that rethink computation—not just at the device level,
but also in terms of the entire computing paradigm, with changes to the machine design also at the circuit level, the architecture
level, and higher levels—is vast. It is our recommendation that these alternative computing styles deserve a greatly increasing
amount of attention and investment as the apparent end of the CMOS roadmap draws closer.
At present, many emerging technologies being studied in the context of hardware security applications are related to designing
physically unclonable functions (PUFs). Many post-CMOS devices 1081,1082,1083 have been suggested as a pathway to a PUF design.
(More detailed reviews are also available. 1084 ) With a PUF, challenge/response pairs are mapped (typically in a trusted
environment). Responses are derived from natural/random variations and disorders in an integrated circuit that cannot be copied
(or cloned) by an adversary. PUFs have been employed for tasks such as device authentication,1084 to securely extract software, 1085
in trusted Field Programmable Gate Arrays (FPGAs), 1086 and for encrypted storage.1085 Post-CMOS devices also find utility as
random number generators (RNGs) that may be employed for secure communication channels (e.g., to generate session keys1084).
That said, while intriguing, PUFs and RNGs may only cover a small part of the hardware security landscape. (Furthermore, one
must be careful that PUF designs based on emerging technologies do not depend on device characteristics that a designer would
like to eliminate when considering utility for logic or memory.)
Given the many emerging devices being studied1078 and that few if any devices were proposed with hardware security as a “killer
application,” this document also reports initial efforts as to how the unique I-V characteristics of emerging transistors that are not
found in traditional MOSFETs could benefit hardware security applications.
Below, we review the efforts described above, beginning with efforts to design PUFs and RNGs with emerging technologies.
How device characteristics can enable novel circuits to achieve hardware security-centric ends such as IP protection, logic
locking, and the prevention of side channel attacks are also discussed.
5.1.2. PHYSICALLY UNCLONABLE FUNCTIONS (PUFS) AND EMERGING TECHNOLOGIES
A variety of different emerging logic and memory technologies have been considered in the context of PUFs. As has been
reviewed,1084 variations in the required write time in spin torque transfer random access memory (STT-RAM) was proposed to
create a domain wall memory PUF.1081 Other structures based on magnetic tunnel junctions have also been proposed. 1087,1088
Variations in write times have also been exploited to produce unique responses in phase change memory (PCM) arrays. 1089 The
variability of ReRAM presents a natural opportunity for PUF implementation, and array demonstration has been reported. 1090,
1091
At the array-level, variations in diode resistivity have also been used to derive challenge/response pairs from crossbar
structures. 1092 PUFs based on graphene 1093 and carbon nanotubes have also been proposed/considered. 1094
As a more representative case study, prior work1084 considers an array structure based on process variation in memristors 1095,1096
to create a PUF structure (referred to as NanoPUF1084). NanoPUF is based on 1) a crossbar with memristors. 2) A challenge is
applied to the memristor array by using a row decoder to apply a voltage amplitude (Vdd) to a given row that can vary in duration;
a column decoder connects a given column to a resistance Rload. All other rows and columns remain floating. 3) A response circuit
(to collect outputs to different challenges) would consists of Rload and a current comparator that compares Iout from a given column
to a reference current Iref. A logic 1 might be recorded if Iout > Iref, while a logic 0 might be recorded if Iout < Iref. With respect to
PUF functionality, when a write pulse is applied, natural process variations will cause some memristors to turn on (leading to a
logic 1), and others to remain off (leading to a logic 0). While the time of the right pulse serves as one variable,1095 the pulse’s
duration and amplitude may also be varied.1096
5.1.3. RANDOM NUMBER GENERATORS (RNGS) AND EMERGING TECHNOLOGIES
The inherent randomness in emerging devices can also be used to generate random numbers.1084 As a representative case study,
prior work1084 explores an approach based on contact-resistive random access memory (CRRAM). 1097 (Note that a CRRAM
device may be based on a layer of silicon dioxide that is sandwiched between two electrodes; the bottom electrode could simply
be the drain of a CMOS transistor – which in turn suggests that RNGs based on emerging technologies can be CMOS
compatible. 1098)
During operation, the current flowing in a filament channel will be (randomly) impacted by any electrons trapped in the insulating
layer. If a high voltage is applied to a device, the current in the filament channel will be large and not impacted by trapped
electrons. However, with the application of a lower voltage, the width of a filament will shrink, and the trapped electrons will
(randomly) influence output current.1098 Indeed, RNGs based on emerging devices1098 can successfully pass randomness tests
such as those provided by the National Institute of Standards and Technology (NIST).
As random number are derived from current passing through filaments, memristors, PCM, and RRAM devices can also be
leveraged to build similar RNGs.1084
5.1.4. OTHER HARDWARE SECURITY PRIMITIVES BASED ON EMERGING TECHNOLOGIES
Below, other security-centric primitives (non-PUFs and non-RNGs) based on emerging technologies are also discussed. How
new devices might be employed for IP protection and to prevent side channel attacks are considered. In each section, device
characteristics of interest are discussed first. Subsequent discussions then consider how device characteristics can be employed
to achieve a security centric end.
Security Analysis: Logic obfuscation is subject to brute-force attacks. If there are N polymorphic gates incorporated in the design,
it would take 2N trials for an attacker to determine the exact functionality of the circuit. As the value of N increases, the probability
of successfully mounting a brute-force attack becomes extremely low. In a preliminary implementation of 32-bit adder, the
incorporated key size is 32 bit.1110 The probability that an attacker can retrieve the correct key becomes 1/232 (2.33×10-10).
Obviously, polymorphic based logic obfuscation techniques are resistant to a conventional brute-force attack. With respect to
camouflaging layouts, given that our proposed SiNW based camouflaging layout can perform four different functions, the
probability that an attacker can retrieve the correct layout is 25%. Therefore, if N SiNW FET camouflaging layouts are
incorporated in a design, the attacker has to compute up to 4N times to resolve the correct layout design. Compared to polymorphic
gate-based logic obfuscation, camouflaging layout embraces higher security level but with larger area overhead.
5.1.4.2. EMERGING TECHNOLOGIES TO PREVENT SIDE-CHANNEL ATTACKS
Many post-CMOS transistors aim to achieve steeper subthreshold swing, which in turn enables lower operating voltage and
power. Many devices in this space also exhibit I-V characteristics that that are not representative of a conventional MOSFET. An
example of how to exploit said characteristics for designing hardware security primitives is discussed.
Steep slope transistors: TFETs have been exploited to design current mode logic (CML) style light-weight ciphers. 1114,1115 The
high energy carriers in TFETs can be filtered by the gate-voltage-controlled tunneling such that a sub-60 mV/decade subthreshold
swing is achievable at room temperature. 1116 With improved steep slope and high on-current at a low supply voltage, TFETs
could enable supply voltage scaling to address challenges such as undesirable leakage currents, threshold voltage reduction, etc.
Different types of TFETs have been developed and fabricated.1116,1117
Bell-Shaped I-Vs: Emerging transistor technologies may also exhibit bell-shaped I-V curves. Symmetric graphene FETs
(SymFETs) and ThinTFETs are representatives of this group. In a SymFET, tunneling occurs between two, 2-D materials
separated by a thin insulator. The IDS-VGS relationship exhibits a strong, negative differential resistance (NDR) region. The I-V
characteristics of the device are “bell-shaped,” and the device can remain off even at higher values of VDS. The magnitude of the
current peak and the position of the peak are tunable via the top gate (VTG) and back gate (VBG) voltages of the device.1108 Such
behavior has been observed experimentally. 1118,1119 More specifically, VTG and VBG change the carrier type/density of the drain
and source graphene layers by the electrostatic field, which can modulate IDS. ITFETs or ThinTFETs may exhibit similar I-V
characteristics. 1120
Preventing fault injection: Side-channel analysis, such as fault injection, power, and timing, allows attackers to learn about
internal circuit signals without destroying the fabricated chips. Countermeasures have been proposed to balance the delay and
power consumption when performing encryption/decryption at either the algorithm or circuit levels. 1121 These methods often
cause higher power consumption and longer computation time in order to balance the side-channel signals under different
conditions. Thus, an important goal is to prevent fault injection and to counter side-channel analysis by introducing low-cost, on-
chip voltage/current monitors and protectors. Graphene SymFETs, which have a voltage-controlled unique peak current can be
used to build low-cost, high-sensitivity circuit protectors through supply voltage monitoring.
Recent work has developed a SymFET-based power supply protector.1108,1109 With only two SymFETs, the power supply protector
can easily monitor the supply voltage to ensure that the supply voltage to the circuit-under-protection is within a predefined range.
In the event of a fault injection, the decreased supply voltage will power down the circuit rather than injecting a single-bit fault,1109
and can thus protect the circuit from fault injection attacks. If one uses Vout as the power supply to a circuit under protection (e.g.,
an adder), due to the bell-shaped I-V characteristic of the SymFET, an intentional lowering of VDD cuts off the power supply.
Thus, the sum and carry-out of the full adder output is ‘0’, and no delay related faults are induced. A similar CMOS power supply
protector would require op-amps for voltage comparison. As a result of the voltage/current monitors developed thus far,
voltage/current-based fault injections can be largely prevented. By inserting the protectors in the critical components of a given
circuit design, the power supply to these components can be monitored and protected.1110 (SymFET-based Boolean logic is also
possible. 1122)
Preventing differential power analysis (DPA): As an advanced side-channel attack scheme, DPA employs analysis of statistic
power consumption measurements from a crypto system to obtain secret keys. Since the introduction of DPA1124, there has been
many efforts to develop low-cost and efficient countermeasures. Countermeasures are generally classified into two categories: 1)
algorithm-level solutions and 2) hardware-level solutions.
Algorithm-level solutions aim to design cryptographic algorithms that can withstand a certain amount of information leakage, 1123
e.g., frequently changing the keys to prevent the attacker from collecting enough power traces 1124 or using masking bits during
the internal stages to limit information leakage. 1125
A more practical circuit-level method for preventing DPA attack leverages a sense amplifier-based logic (SABL) or current mode
logic (CML) for cryptographic algorithm implementations. 1126 A CML gate includes a tail current source, a current steering core
and a differential load. A CML gate will switch the constant current through the differential network of input transistors, utilizing
the reduced voltage swing on the two load devices as the output. Although CML is not widely used in mainstream circuit design,
its unique features, namely low latency and stable power consumption, can be leveraged to serve as a countermeasure against a
DPA attack.
The strength of the CML-based approach is the constant power consumption of differential logic which can counter power-based
attacks as operation power is independent of processed data. The drawback with these (mostly CMOS-based) logic designs, is
their large area and power consumption when compared to static single ended logic. When considering hardware for the IoT
(where the systems can be severely power constrained), system designers are presented with a dilemma in which they need to
choose either high security or low power consumption. Emerging transistor technologies could help mitigate risks of DPA attacks
while maintaining low power consumption.
Recent work has implemented a standard cell library of TFET CML gates and conducted a detailed study of their performance,
power and area with respect to CMOS equivalents. 1127 Standard cells were used to implement and evaluate TFET-based CML on
a 32-bit KATAN cipher (a light-weight block cipher). All KATAN ciphers share the same key schedule with the key size of 80
bits as well as the 254-round iteration with the same non-linear function units. 1128
The two CML implementations consume less gate equivalents and area compared to the two static counterparts given that the
majority of KATAN32 is made up by the D flip flops. The area of TFET CML KATAN32 is 1.441 μm2, which is about 60% less
than the Static TFET KATAN32. The power consumption of TFET CML (9.76 μW) is slightly lower than static CMOS
(9.96 μW). It also outperforms CMOS CML.
Moreover, the correlation coefficient of a TFET static KATAN32 reaches its highest when the correct keys are applied. By
comparison, the correlation coefficient of TFET CML KATAN32 is much more scattered, and all four hypothetical keys are
equally distributed. Thus, the TFET CML KATAN32 implementation can successfully counteract CPA. Because the power
consumption is mainly determined by AND/XOR logic gates of two nonlinear functions – and the effect of CPA is maximized –
the correlation coefficients for KATAN32 are higher on average than other block ciphers, e.g., CPA on S-box 1129.
6.1.3. SCOPE
The IRDS represents a strategic repositioning of the community’s scope, needs, and set of emergent opportunities. In alignment
with this new perspective, this edition of the emerging materials integration (EMI) sub-chapter represents a work in transition
with a primary goal of aligning with the needs of related IRDS working groups. Much of the associated information in the detailed
requirements and solutions tables comes from prior ERM chapters and input from current IRDS working groups, and will be
updated in future editions. The chapter emphasizes strategic difficult challenges and/or enabling of novel, breakthrough and
potentially disruptive opportunities for emerging material properties, synthetic methods, and metrology, organized in the
following areas:
1. Scaled technology materials needs for More Moore: transistors, memory, interconnects, lithography, heterogeneous
integration, assembly and packaging.
2. Novel materials for Beyond CMOS: emerging logic and information processing devices, emerging memory and storage
devices, and novel computational paradigms and architectures.
3. Potentially disruptive material opportunities for functional scaling and convergent applications: Heterogenous
components, outside system connectivity, and high impact application areas such as energy, environment, agriculture, health,
medical, etc
For all areas, the advancement requires an intergration of emerging materials as illustrated in Figure BC-EMI 1.
Figure EMI1 Emerging Material Integration Promotes the Advancement of Existing Technologies
6.2. CHALLENGES
6.2.1. NEAR-TERM CHALLENGES
Materials and processes that improve copper Mitigate impact of size effects in interconnect structures. Patterning, cleaning, and filling at
interconnect resistance and reliability nano dimensions. Cu wiring barrier materials must prevent Cu diffusion into the adjacent
dielectric but also must form a suitable, high quality interface with Cu to limit vacancy diffusion
and achieve acceptable electromigration lifetimes. Reduction of the k value of inter-metal
dielectrics.
Materials and processes for continued scaling of Low temperature materials for high performance vertical transistor memory select structures.
DRAM/SRAM and embedded NVM High-k, low leakage DRAM dielectrics. Processes for stacking of 3D flash.
Materials and processes that extend lithography to Novel resists to extend 193 nm lithography and support EUV lithography. Directed self-
sub-10 nm dimensions with reproducible properties assembly (DSA) with materials such as block-copolymers to potentially extend lithography
though pattern rectification and pattern density multiplication.
Materials for heterogeneous integration of multi-chip, Materials to modify polymer properties to enable increased product reliability. Novel electrical
multi-function packages. attaching materials to allow lower assembly temperatures and improved product reliability.
Simultaneously achieve package polymer CTE, modulus, electrical and thermal properties, with
moisture and ion diffusion barriers. Nanosolders compatible with <200C assembly, multiple
reflows, high strength, and high electromigration resistance. Nanoinks that can be printed as die
attach adhesives with required electrical, mechanical, thermal, and reliability properties.
Materials and processes that replace copper Synthesis or assembly of CNTs in predefined locations and directions with controlled diameters,
interconnects with improved reliability and chirality and site-density. Carbon and collective excitations. Novel interlayer dielectrics: MOF
electromagnetic performance at the nanoscale (Metal Organic Framework) and COF (Carbon Organic Framework). Metals with less size
effects such as silicides.
Materials and processes for charge-based and non- Achieving a bandgap and full interfaces control in graphene in FET structures and alternative
charge-based beyond CMOS logic that replaces or FETs (TFETs etc). Synthesis of CNTs with tight distribution of bandgap and mobility. Complex
extends CMOS metal oxides with low defect density. High mobility transition metal dichalcogenides with low
defect density and low resistance ohmic contacts. Spin materials: characterization of spin,
magnetic and electrical properties and correlation to nanostructure. Topological materials: large
bandgaps much greater that kT at room temperature, ability to modulate bandgap efficiently with
electric field. BiSFET heterostructures: achieving exciton condensation at room temperature.
Materials and processes for emerging memory and Multiferroic with Curie temperature >400K and high remnant magnetization to >400K.
select devices to replace DRAM/NVM. Ferromagnetic semiconductor with Curie temperature >400K. Complex Oxides: Control of
oxygen vacancy formation at metal interfaces and interactions of electrodes with oxygen and
vacancies. Switching mechanism of atomic switch: Improvements in switching speed, cyclic
endurance, uniformity of the switching bias voltage and resistances both for the on-state and the
off-state.
Materials and processes that enable monolithically 3D Integration on CMOS Platforms. Integration with flexible electronics. Biocompatible functional
integrated complex functionality including thermal and materials. Leveraging convergent materials expertise in adjacent sectors, including More than
yield challenges Moore functionalities (photonics, optics/metamaterials, outside connectivity, energy
transfer/storage, power circuits).
producing such materials with the required level of control. The difficulties could be due to: 1) The inability of a research
environment to produce materials with the required level of control that would express the desired properties; or 2) scaling up
the synthetic and fabrication processes to satisfy commercial manufacturing requirements. In some cases, current materials
growth processes effect unacceptable levels of defect formation, which drive the need for new and more robust fabrication
methods. In other cases, synthetic methods exist for producing high quality materials, but these processes cannot be scaled to
the higher growth rates, yields, or purity needed for insertion into viable commercial applications. While these materials may
provide proof of concept and suggest a potential solution, new cost effective fabrication technologies may be required to
warrant a candidate material’s insertion into high volume manufacturing.
6.3.2. SCALED TECHNOLOGY MATERIALS FOR MORE MOORE
As described in the More Moore chapter, after 2027 there is no headroom for 2D geometry scaling and 3D VLSI integration of
circuits and systems using sequential/stacked integration approaches will likely begin. Whether one is considering 2D geometry
scaling or 3D integration, there are numerous materials challenges to achieving increasing device density and integrated
performance. The following outlines key materials challenges for transistor scaling and integration, lithography, interconnects,
heterogenous integration, assembly and packaging, and outside system connectivity.
6.3.2.1. MATERIALS FOR TRANSISTOR SCALING AND INTEGRATION
Continued increases in transistor device density require a variety of new materials and processes including new channels (Ge,
III-V), improved doping techniques, gate stacks and contacting structures. Table EMI3 provides a set of materials and processes
priorities for transistor scaling and integration.
Table EMI7 Emerging Research Materials Needs for Outside System Connectivity
6.3.3. EMERGING MATERIALS FOR MEMORY, BEYOND CMOS LOGIC AND COMPUTING
Beyond 2030, MOSFET scaling will likely become ineffective and/or very costly. As described in this chapter, completely new,
non-CMOS types of memory, logic devices and maybe even new circuit architectures are potential solutions. Such solutions
ideally can be integrated onto the Si-based platform to take advantage of the established processing infrastructure, as well as
being able to include Si devices such as memories onto the same chip. The following outlines key materials challenges for
emerging materials for memory, beyond CMOS logic and alternative information processing.
6.3.3.1. EMERGING MATERIALS FOR MEMORY
Emerging memory devices includes capacitive memories (Fe FET), and resistive memories including ferroelectric devices,
resistance change devices, devices based on Mott transitions and novel magnetic memories. Another key requirement for memory
technology is the development of corresponding select devices that access only the selected memory cell of interest without
perturbing non-selected cells. Table EMI8 provides a set of materials and associated challenges for emerging memory materials,
and Table EMI 9 provides materials and associated challenges for memory select.
Table EMI10 Emerging Materials for Advanced and Beyond-CMOS Logic Devices
Table EMI13 Metrology Needs and Challenges for Emerging Research Materials
Figure EMI2 An Example of the Role of Machine Learning in the Multiscale Simulation
Note: The left shows conventional multiscale physics where physics to explain mesoscopic level phenomena is required to link molecular and
continuum level phenomena. The right shows a potential role of machine learning that provides output of continuum level phenomena from
inputs of molecular level phenomena.
Table EMI15 Summary of Potentially Disruptive Emerging Research Materials Application Opportunities
7. ASSESSMENT
7.1. INTRODUCTION
It is important to assess beyond-CMOS devices considered in this chapter against current CMOS technologies. Two methods of
assessments have been reported previously in the ITRS ERD chapter: a “quantitative emerging device benchmarking” conducted
by the Nanoelectronics Research Initiative (NRI) and a “survey-based assessment” conducted by the ERD working group.
In the “NRI benchmarking”, each emerging device is evaluated by its operation in conventional Boolean Logic circuits, e.g., a
unity gain inverter, a 2-input NAND gate, and a 32-bit shift register. Metrics evaluated include speed, areal footprint, power
dissipation, etc. Each parameter is compared with the performance projected for high performance and low power 5nm CMOS
applications. This “beyond CMOS” chapter will update the quantitative benchmarking section with the latest NRI results.
Up to the 2013 ERD Chapter, a survey-based critical review was conducted based on eight criteria to compare emerging devices
against their CMOS benchmark. Spider chart has been used to visualize the perceived potential of these technology entries.
However, the limited number of survey results sometimes raises questions of the accuracy of this survey. The most recent “survey-
based assessment” was conducted in the 2014 ERD Emerging Memory and Logic Device Assessment Workshops (Albuquerque,
NM). The survey collects voting on emerging technologies evaluated in the workshops in the categories of the “most promising”
and the “most need of resources” to assess the potential of these technology entries perceived by ERD experts. A summary of
previous survey-based assessments is included in this chapter as an archive.
An important issue regarding emerging charge-based nanoelectronic switch elements is related to the fundamental limits to the
scaling of these new devices, and how they compare with CMOS technology at its projected end of scaling. An analysis 1148
concludes that the fundamental limit of scaling an electronic charge-based switch is only a factor of 3 times smaller than the
physical gate length of a silicon MOSFET in 2024. Furthermore, the density of these switches is limited by a maximum allowable
power dissipation of approximately 100W/cm2, and not by their size. The conclusion of this work is that MOSFET technology
scaled to its practical limit in terms of size and power density will asymptotically reach the theoretical limits of scaling for charge-
based devices.
Most of the proposed beyond-CMOS devices are very different from their CMOS counterparts, and often pass computational
state variables (or tokens) other than charge. Alternative state variables include collective or single spins, excitons, plasmons,
photons, magnetic domains, qubits, and even material domains (e.g., ferromagnetic). With the multiplicity of programs
characterizing the physics of proposed new structures, it is necessary to find ways to benchmark the technologies effectively.
This requires a combination of existing benchmarks used for CMOS and new benchmarks which take into account the
idiosyncrasies of the new device behavior. Even more challenging is to extend this process to consider new circuits and
architectures beyond the Boolean architecture used by CMOS today, which may enable these devices to complete transactions
more effectively.
7.1.1. ARCHITECTURAL REQUIREMENTS FOR A COMPETITIVE LOGIC DEVICE
The circuit designer and architect depend on the logic switch to exhibit specific desired characteristics in order to insure successful
realization of a wide range of applications. These characteristics, 1149 which have since been supplemented in the literature,
include:
• Inversion and flexibility (can form an infinite number of logic functions)
• Isolation (output does not affect input)
• Logic gain (output may drive more than one following gate and provides a high Ion/Ioff ratio)
• Logical completeness (the device is capable of realizing any arbitrary logic function)
• Self-restoring / stable (signal quality restored in each gate)
• Low cost manufacturability (acceptable process tolerance)
• Reliability (aging, wear-out, radiation immunity)
• Performance (transaction throughput improvement)
• Span of control (measures number of devices that may be reached within a characteristic delay of the switch 1150)
Devices with intrinsic properties supporting the above features will be adopted more readily by the industry. Moreover, devices
which enable architectures that address emerging concerns such as computational efficiency, complexity management, self-
organized reliability and serviceability, and intrinsic cyber-security 1151 are particularly valuable.
7.2. NRI BEYOND-CMOS BENCHMARKING
The Nanoelectronics Research Initiative (https://www.src.org/program/nri/) has been benchmarking several diverse beyond-
CMOS technologies, trying to balance the need for quantitative metrics to assess a new device concept’s potential with the need
to allow device research to progress in new directions which might not lend themselves to existing metrics. 1152, 1153,1154 Several
of the more promising NRI devices have been described in detail in the Logic and Emerging Information Processing Device
Section. Some results of this benchmark study were included in 2015 ITRS ERD chapter.
While all these efforts are still very much a work in progress – and no concrete decisions have been made on which devices
should be chosen or eliminated as candidates for significantly extending or augmenting the roadmap as CMOS scaling slows –
this section summarizes some of the data and insights gained from these studies. Further benchmarks may alter some of the
conclusions here and the outlook on some of these devices, but the overall message on the challenge of finding a beyond CMOS
device which can compete well across the full spectrum of benchmarks of interest remains.
7.2.1. QUANTITATIVE RESULTS
NRI benchmarking analyzes the potential of major emerging switches using a variety of information tokens and communication
transport mechanisms. Specifically, the projected effectiveness of these devices used in a number of logic gate configurations
was evaluated and normalized to CMOS at the 5nm generation (projection). The initial work has focused on “standard” Boolean
logic architecture, since the CMOS equivalent is readily available for comparison. It should be noted that the majority of devices
are evaluated via simulations since many of them have not yet been built, so it should be considered only a “snapshot in time” of
the potential of any given device. Data on all of them are still evolving.
At a high level, the data from these studies corroborates qualitative insights from earlier works, suggesting that many new logic
switch structures may have some advantages over CMOS in terms of power or energy, but they are also inferior to CMOS in
delay. This is perhaps not surprising; the primary goal for nanoelectronics and NRI is to find a lower power device 1155 since
power density is a primary concern for future CMOS scaling. The power-speed tradeoffs commonly observed in CMOS are also
extended into the emerging devices. It is also important to understand the impact of transport delay for the different information
tokens these devices employ. Communication with many non-charge tokens can be significantly slower than moving charge,
although this may be balanced in some cases with lower energy for transport. The combination of the new balance between switch
speed, switch area, and interconnect speed can lead to advantages in the span of control for a given technology. For some of the
technologies (e.g., nanomagnetic logic), there is no strong distinction between the switch and the interconnect, indicating the need
for novel architecture to exploit unique attributes of these technologies.
A simplified 32-bit arithmetic logic unit (ALU) was built from these devices to evaluate their performance and the result is
summarized in Figure BC7.1(a) 1156. While tunneling devices (e.g., TFET) show limited advantages over CMOS in terms of
energy-delay product, most beyond-CMOS devices are inferior to CMOS in energy and/or delay. For example, the majority of
spintronic devices are slower than CMOS and also show no energy advantage.
(a) (b)
Figure BC7.1 (a) Energy versus Delay of a 32-bit ALU for a Variety of Charge- and Spin-based Devices;
(b) Energy versus Delay per Memory Association Operation Using Cellular Neural Network (CNN) for a Variety of
Charge- and Spin-based Devices1156
At the architecture level, the ability to speculate on how these devices will perform is still in its infancy. While the ultimate goal
is to compare at a very high level – e.g., how many MIPS can be produced for 100 mW in 1 mm2? – the current work must
extrapolate from only very primitive gate structures. One initial attempt to start this process has been to look at the relative
“logical effort” 1157 for these technologies, a figure of merit that ties fundamental technology to a resulting logic transaction.
Several of the devices appear to offer advantage over CMOS in logical effort, particular for more complex functions, which
increases the urgency of doing more joint device-architecture co-design for these emerging technologies.
The direction of device-architecture co-optimization has driven NRI benchmarking to explore non-Boolean applications of
beyond-CMOS devices. Cellular Neural Network (CNN) has been utilized as a benchmarking model that has been implemented
with various novel devices.1156 The energy and delay of CNN based on beyond-CMOS devices are compared with CMOS-based
CNN in Figure BC7.1(b). Tunneling devices have significant performance improvement because of their steep subthreshold
slopes and large driving current at ultra-low supply voltage. Interestingly, spintronic devices are much closer to the preferred
corner in CNN implementation in comparison with 32-bit ALU. This is because some characteristics of spintronic devices (e.g.,
spin diffusion, domain wall motion) may mimic the functionality of a neuron (e.g. integration) more naturally in a single device.
7.2.2. OBSERVATIONS
A number of common themes have emerged from these benchmark studies and in the observations made during recent studies of
beyond-CMOS replacement switches 1158. A few noteworthy concepts:
1. The low voltage energy-delay tradeoff conundrum will continue to be a challenge for all devices. Getting to low
voltage must remain a priority for achieving low power, but new approaches to getting throughput with ‘slow’ devices
must be developed.
2. Most of the architectures that have been considered to date in the context of new devices utilize binary logic to
implement von Neumann computing structures. In this area, CMOS implementations are difficult to supplant because
they are very competitive across the spectrum of energy, delay and area – not surprising since these architectures have
evolved over several decades to exploit the properties of CMOS most effectively. Novel electron-based devices –
which can include devices that take advantage of collective and non-equilibrium effects – appear to be the best
candidates as a drop-in replacement for CMOS for binary logic applications.
3. As the behavior of other emerging research devices becomes better understood, work on novel architectures that
leverage these features will be increasingly important. A device that may not be competitive at doing a simple NAND
function may have advantages in doing a complex adder or multiplier instead. Understanding the right building blocks
for each device to maximize throughput of the system will be critical. This may be best accomplished by thinking
about the high-level metric a system or core is designed to achieve (e.g., computation, pattern recognition, FFT, etc.)
and finding the best match between the device and circuit for maximizing this metric.
4. Increasing functional integration and on-chip switch count will continue to grow. To that end, in any logic
architectural alternative, both flexible rich logic circuit libraries and reconfigurability will be required for new switch
implementations.
5. Patterning, precision layer deposition, material purity, dopant placement, and alignment precision critical to CMOS
will continue to be important in the realization of architectures using these new switches.
6. Assessment of novel architectures using new switches must also include the transport mechanism for the information
tokens. Fundamental relationships connecting information generation with information communication spatially and
temporally will dictate CMOS’ successor.
Based on the current data and observations, it is clear that CMOS will remain the primary basis for IC chips for the coming years.
While it is unlikely that any of the current emerging devices could entirely replace CMOS, several do seem to offer advantages,
such as ultra-low power or nonvolatility, which could be utilized to augment CMOS or to enable better performance in specific
application spaces. One potential area for entry is that of special purpose cores or accelerators that could off-load specific
computations from the primary general purpose processor and provide overall improvement in system performance. If scaling
slows in delivering the historically expected performance improvements in future generations, heterogeneous multi-core chips
may be a more attractive option. These would include specific, custom-designed cores dedicated to accelerate high-value
functions, such as accelerators already widely used today in CMOS (e.g. Encryption/Decryption, Compression/Decompression,
Floating Point Units, Digital Signal Processors, etc.), as well as potentially new, higher-level functions (e.g. voice recognition).
While integrating dissimilar technologies and materials is a big challenge, advances in packaging and 3D integration may make
this more feasible over time, but the performance improvement would need to be large to balance this effort.
As a general rule, an accelerator is considered as an adjunct to the core processors if replacing its software implementation
improves overall core processor throughput by approximately ten percent; an accelerator using a non-CMOS technology would
likely need to offer an order of magnitude performance improvement relative to its CMOS implementation to be considered
worthwhile. That is a high bar, but there may be instances where the unique characteristics of emerging devices, combined with
a complementary architecture, could be used as an advantage in implementing a particular function. At the same time, the
changing landscape of electronics (moving from uniform, general purpose computing devices to a spectrum of devices with
varying purposes, power constraints, and environments spanning servers in data centers to smart phones to embedded sensors)
and the changing landscape of workloads and processing needs (Big Data, unstructured information, real-time computing, 3D
rich graphics) are increasing the need for new computing solutions. One of the primary goals then for future beyond-CMOS work
should be to focus on specific emerging functions and optimize between the device and architecture to achieve solutions that can
break through the current power/performance limits.
7.3. ARCHIVE OF ITRS ERD SURVEY-BASED ASSESSMENT
Although survey-based emerging device assessment has not been continued after the 2015 ITRS ERD chapter, previous survey-
based assessments in ERD chapters are summarized here for references.
7.3.1. EMERGING DEVICE ASSESSMENT IN 2014 ERD WORKSHOPS
In August 2014, ERD organized an “Emerging Memory Device Assessment Workshop” and an “Emerging Logic Device
Assessment Workshop”, where nine memory devices and fourteen logic devices were evaluated. A survey was conducted in the
workshops for the experts to vote on the “most promising” devices and devices “needing more resources”. Figure BC7.2 shows
the relative number of votes received by emerging devices in these two categories, ranked from high to low in the “most
promising” category (red color bars).
In the “most promising” memory device category, the vote clearly accumulated to a few well-known memory devices: STTRAM,
ReRAM (including CBRAM and oxide-based ReRAM), and PCM, ranked from high to low. Some memory devices received few
vote, due to lack of progress. Results in this category reflect consensus among experts based on R&D status of these devices. The
“need more resources” category reflects perceived value of these devices in the view of the experts and also experts’ consideration
of R&D resource allocation based on existing investment (or lack of investment) for each device. For example, with heavy R&D
investment on STTRAM that is considered most promising, it is not surprising that it ranks low in the need of resources. The
strong interest in emerging FeFET memory is closely linked to the discovery of ferroelectricity in doped HfOx. Among emerging
logic devices, “carbon nanomaterial device” (mainly carbon nanotube FET), tunnel FET, and nanowire FET were ranked as one
of the most promising emerging logic devices. Notice that they are all charge-based devices, but involve novel materials,
structures, and mechanisms. “Piezotronic transistors”, “negative-capacitance FET”, and “2D channel FET” were considered top
choices for enhanced research investment.
(a) (b)
Figure BC7.2 (a) Survey of Emerging Memory Devices and (b) Survey of Emerging Logic Devices in 2014
ERD Emerging Logic Workshop (Albuquerque, NM)
7.3.2. 2013 ERD SURVEY CRITERIA, METHODOLOGY, AND RESULTS
In the traditional survey-based assessment conducted by ERD, a set of relevance or evaluation criteria, defined below, are used
to parameterize the extent to which “CMOS Extension” and “Beyond CMOS” technologies are applicable to memory or
information processing applications. The relevance criteria are: 1) Scalability, 2) Speed, 3) Energy Efficiency, 4) Gain (Logic) or
ON/OFF Ratio (Memory), 5) Operational Reliability, 6) Operational Temperature, 7) CMOS Technological Compatibility, and
8) CMOS Architectural Compatibility. Description of each criterion can be found in 2013 ERD chapter.
Figure BC7.3 Comparison of Emerging Memory Devices Based on 2013 Critical Review
Each CMOS extension and beyond-CMOS emerging memory and logic device technology is evaluated against these criteria
according to a single factor. For logic, this factor relates to the projected potential performance of a nanoscale device technology,
assuming its successful development to maturity, compared to that for silicon CMOS scaled to the end of the Roadmap. For
memory, this factor relates the projected potential performance of each nanoscale memory device technology, assuming its
successful development to maturity, compared to that for ultimately scaled current silicon memory technology which the new
memory would displace. Performance potential for each criterion is assigned a value from 1–3, with “3” substantially exceeding
ultimately-scaled CMOS, and “1” substantially inferior to CMOS or, again, a comparable existing memory technology. This
evaluation is determined by a survey of the ERD Working Group members composed of individuals representing a broad range
of technical backgrounds and expertise. Details of the assessment values are also included in 2013 ERD chapter.
Although this survey-based critical review has been conducted in ERD for several versions and has been widely cited in
literatures, the decreasing number of votes of some less popular devices has raised concerns about the accuracy of some of the
results. Figures BC7.3 and EBC7.4 summarize the last critical review conducted in 2013 for emerging memory devices and
emerging logic devices, respectively. Notice that the technology entries in these figures are based on the 2013 ERD chapter, while
some of them have been removed in this chapter (e.g., molecular memory, atomic switch, etc.) and several new technologies are
added in this chapter (e.g., novel magnetic memory, transistor laser, etc.).
8. SUMMARY
The “beyond-CMOS” chapter systematically surveys emerging memory and logic devices (sections 2 and 3), novel technologies
(section 4), and alternative architectures and computing paradigms (section 5), to explore potential solutions beyond the
conventional scaling of CMOS technologies. Although high performance at low power consumption has been a primary objective
of beyond-CMOS devices, novel functionalities and applications have become increasingly important. The recent emergence of
energy-efficient data-intensive cognitive applications is also shifting the emphasis from high-precision computing solutions to
novel computing paradigms with massive parallelism and bio-inspired mechanisms. Research opportunities exist in the co-
optimization of beyond-CMOS devices and architectures to explore unique device characteristics and architectural designs.
Although a beyond-CMOS device competitive against CMOS FET has not been identified, beyond-CMOS devices with
dramatically enhanced scalability and performance while simultaneously reducing the energy dissipation per functional operation
would still be fundamentally important and a worthwhile research objective. In considering the many disparate new approaches
proposed to provide order of magnitude scaling of information processing beyond that attainable with ultimately scaled CMOS,
the following set of guiding principles are proposed to provide a useful structure for directing research on “Beyond CMOS”
information processing technology.
• COMPUTATIONAL STATE VARIABLE(S) OTHER THAN SOLELY ELECTRON CHARGE
These include spin, phase, multipole orientation, mechanical position, polarity, orbital symmetry, magnetic flux quanta, molecular
configuration, and other quantum states. The estimated performance comparison of alternative state variable devices to ultimately
scaled CMOS should be made as early in a program as possible to down-select and identify key trade-offs.
• NON-THERMAL EQUILIBRIUM SYSTEMS
These are systems that are out of equilibrium with the ambient thermal environment for some period of their operation, thereby
reducing the perturbations of stored information energy in the system caused by thermal interactions with the environment. The
purpose is to allow lower energy computational processing while maintaining information integrity.
• NOVEL ENERGY TRANSFER INTERACTIONS
These interactions would provide the interconnect function between communicating information processing elements. Energy
transfer mechanisms for device interconnection could be based on short range interactions, including, for example, quantum
exchange and double exchange interactions, electron hopping, Förster coupling (dipole–dipole coupling), tunneling and coherent
phonons.
• NANOSCALE THERMAL MANAGEMENT
This could be accomplished by manipulating lattice phonons for constructive energy transport and heat removal.
• SUB-LITHOGRAPHIC MANUFACTURING PROCESS
One example of this principle is directed self-assembly of complex structures composed of nanoscale building blocks. These self-
assembly approaches should address non-regular, hierarchically organized structures, be tied to specific device ideas, and be
consistent with high volume manufacturing processes.
• ALTERNATIVE ARCHITECTURES
In this case, architecture is the functional arrangement on a single chip of interconnected devices that includes embedded
computational components. These architectures could utilize, for special purposes, novel devices other than CMOS to perform
unique functions.
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1151 J. Welser and K. Bernstein, “Challenges for Post-CMOS Devices & Architectures,” IEEE Device Research Conference Technical Digest,
Proceedings of the IEEE Special Issue - Nanoelectronics Research: Beyond CMOS Information Processing, Volume 98, Issue 12, Dec
2010, pp. 2169-2184.
1153 D.E. Nikonov and I.A. Young, “Uniform Methodology for Benchmarking Beyond-CMOS Logic Devices,” IEDM Tech. Dig., pp. 573–
1155 T. N. Theis and P. M. Solomon, “In Quest of the ‘Next Switch’: Prospects for Greatly Reduced Power Dissipation in a Successor to the
Silicon Field-Effect Transistor,” Proceedings of the IEEE Special Issue - Nanoelectronics Research: Beyond CMOS Information
Processing, Volume 98, Issue 12, Dec 2010, pp. 2005-2014.
1156 C. Pan and A. Naeemi, “An Expanded Benchmarking of Beyond-CMOS Devices Based on Boolean and Neuromorphic Representative
Circuits,” IEEE J. Exploratory Solid-State Computational Devices and Circuits, vol. 3, pp 101-110, December 2017.
1157 I. Sutherland et al., Logical Effort: Design Fast CMOS Circuits, 1st ed. San Mateo, CA: Morgan Kaufmann, Feb. 1999,
ISBN: 10:1558605576
1158 An extremely valuable collection of different approaches to post-CMOS technology can be found in Proceedings of the IEEE Special
Issue - Nanoelectronics Research: Beyond CMOS Information Processing, ed. G. Bourianoff, M. Brillouët, R. K. Cavin, III, T.
Hiramoto, J. A. Hutchby, A. M. Ionescu, and K. Uchida, Volume 98, Issue 12, Dec 2010.