ZIMBABWE SCHOOL EXAMINATIONS COUNCIL
General Certificate of Education Ordinary Level
MARKING SCHEME
NOVEMBER 2009
PHYSICAL SCIENCE 5009/2
1. (a) H+ /H2O+; and OH [2]
(b) B; [1]
OH ions migrate to B lose electrons giving oxygen +OH – 4e
→ O2 +2H2O [1]
(c) concentration increases; [1]
[Total: 5]
2. (a) (i) - low melting point
- low boiling point
- does not conduct electricity
- insoluble in water
- soluble in organic solvents (Any one)
Weak intermolecular forces / AW;
No ions present / covalent bond [1]
[Any one]
(ii) ionic / electrovalent (bond); [1]
Electron transfer from A to B; [1]
(b) Fe and Cl; [2]
3. (a) 28 dm3 is the volum 1 mole of CO2 at r.t.p.
56
56 dm3 is the volum /28 moles/of CO2 at r.t.p.;
= 2 moles [1]
(b) No. of carbon atoms = 2; [1]
(c) Alkenes; [1]
(d) C3H8 + 5O2 → 3CO2 + 4H2O [2]
- correct formulae of species [1]
- balanced equation [1]
[Total: 5]
-1
4. (a) /3g; [1]
(b) (i) 1 mole; [1]
(ii) PH, [1]
(c) 1 mole of hydrogen atoms contains
6,0 x 10 23 atoms; [1]
23
3 moles of hydrogen atoms contains 3 x 6 x 10 atoms, [1]
= 1,8 x 1023 atoms; [1]
[Total: 5]
5. (a) (i)
[1]
(ii)
[1]
(b) (i)
[3]
6. (a) Distance = Area under graph / (2 x 1) + ½ (2 + 6) LAW; [1]
(b) Acceleration = 0 – 6 / -3 ms-2 [1]
2
Force = ma/25kg x – 3ms-2/AW; [1]
= -75/N
7. (a) Wire deflected
Vertically out of paper
Switch off: returns to original positon;
Wire has magnetic field when current is flowing; 4 max [3]
(b) deflection greater,
because current greater
(or vice versa) [2]
8. (a) (i) β/beta; symbols i.e. e for β and 42 He for α [1]
(ii) α/alpha; [1]
(b) A and D; (both have to be correct) [1]
(c) α – particle / particle (ii); [1]
(d) β – particle / particle (i); [1]
[Total: 5]
9. (a) (i) 2HCl + CaCO3 → CaCl2 + H2O + CO2
Correct formulae of reactants and products; [1]
balanced equation [1]
(ii) 1. Rate of gas production increases as temperature of
acid rises. [1]
2. rate of gas production increases as surface area of
calcium carbonate increases; [1]
(iii) - do experiment at 2 different temperatures;
- measure rate of gas collection / take readings;
- grind up lumps of CaCO3;
- changes made independently; [5]
(b) Position of metals in reactivity
Series most reactive → sodium aluminium
least reactive → iron; [1]
Sodium readily gives up electrons / reduces atmospheric
oxygen (forming sodium oxide);
4Na + O2 → 2Na2O;
Aluminium readily gives up electrons / reduces atmospheric
oxygen (forming aluminium oxide)/ [1]
4Al + 3O2 → 2Al2O3; [1]
Aluminium oxide forms protective layer outside, metal; [1]
Preventing further reaction of aluminium; [1]
Iron is slowly oxidized by atmospheric oxygen (forms rust /
hydrated)
4Fe + 3O2 → 2Fe2O [9 max 6]
10. (a) (i) g = gas; [1]
(ii) ∆H = reaction is exothermic; [1]
92 kJ of heat are given out
(iii) ↔ = reaction is reversible / proceeds in both the
forward and backward directions; [1]
(b) - hydrogen and nitrogen are mixed;
- in a ration of 3 : 1 by volume;
- at a pressure of 200 atm:
- and temperature of 450oC;
- mixture passed over iron catalyst;
- ammonia separated by condensation
- forward reaction is favoured by high pressure;
- since it proceeds with decrease in volume;
- low temperature;
- since it proceeds with evolution of heat; [9]
[10 max 9]
(c) - manufacture of nitrogenous fertilizer / ammonium nitrate
/ ammonium sulphate;
- refrigerant;
- manufacture of nitric acid;
- manufacture of household cleaners; [2]
[Any two]
[Total: 15]
11. (a) (i) ethanol / C2 H3 OH; [1]
(ii) oxidation; [1]
(iii) acidified potassium manganate (vii) / bacterial oxidation /
Potassium dichromate; [1]
(iv) Ethanol: K2Cr2Oлaq turns from arrange to green /
potassium permanganate decolourised; [1]
Vinegar: If added to CO2- 3 produces efferveseence /
turns blue litmus paper red / universal
indicator (green) turns red / orange;
(b) (i) butane
(ii)
(c) (i) No, ot empirical formula units = 60 /60 / = 2; [1]
12 + 2 + 16/ 30 /
Molecular formula C2H4O2; [1]
(ii) carboxylic acids / organic acids; [1]
(iii)
[1]
(iv) 2CH3COOH + Na2CO3 → 2CH3COONa + CO2 + H2O; [2]
- correct formulae of species, both reactants and
products [1]
- balancing [1]
[Total: 15]
2. (a) - mass is the amount of matter in an object: [1]
- weight is the force due to gravity that is acting on an
object; [1]
- weight = mass x acceleration due to gravity;
(b) Y is more stable; [1]
The centre of mass / gravity is close to the base in Y/AW; [1]
(c) (i) Clockwise moments = anticlockwise moments; [1]
4 x (30 – 5) = W x (50 – 30) [1]
4 x 25 = W x 20 [1]
W = 5.0 N; [1]
Mass = 0.5 kg; [1]
(ii) - Centre of mass is at 50 cm mark;
- new centre of mass shifts to the left;
- it is on 40 cm mark, (Any two) [2]
(d) (i) passengers are in motion in a straight line; without
external force on passengers; they stay in motion when
the vehicle stops; [2]
(ii) - the air shoots out of the balloon with a force; due
to pressure difference; the balloon experiences an
equal and opposite force / AW; max [2]
[Total: 15]
13. (a) (i) P.d = IR/0,25 A x 18 Ω; [1]
= 4,5 V [1]
(ii) P.d across R = (12 – 4.5) V/4.5; [1]
(iii) R = V / 7.5V
I / 0.25 [1]
= 30 Ω [1]
(b) (i) Vlt/Pt = mcθ;
2 x 103t = 1.5 x 4 200 x 85; [1]
t = 267 75s/268s [1]
(ii) Cost = 2kW x 267 75h x $3.50/ kWh; [1]
60 x 60
= 50,52; [1]
(iii) 1. Resistance = V2 / 2502 [1]
P / 2 x 103
31,25 Ω / 31,3 Ω; [1]
2. Current = P / 2 x 103
V/ 250 = 8A; [1]
(iv) Fuse rating = 9A (c.c.f depends on the amperage
candidate got) [1]
4. (a) (i) - clouds become charged by friction / rubbing
against each other;
- top of cloud becomes positively charged and
bottom negatively charged;
- when p.d becomes too great excess electrons are
discharged between the top and bottom of the
cloud / between cloud and earth;
- discharge appears as a flash; [4]
(ii) - do not stand under a tree during a thunderstorm;
- fit lightning conductors on buildings;
- do not stand in an open place during a
thunderstorm / lie down on the ground;
- keep away from fences;
- do not tough water taps;
(Any two) [2]
(b) (i) electrostatics / electrostatic attraction; [1]
(ii) - electrons flow from P;
- through the high voltage supply / into earth;
- electrons on the metal sphere attracted towards P /
positive charge on the metal
- sphere repelled / separation of charges in metal
sphere / induction;
- positive and negative charges attract; [4]
(iii) - electrons flow through P to high voltage supply /
into earth;
- leaving sphere positively charged;
- positive charges repel;
- sphere swings backwards. [4]
[Total: 15]