Potential Applications of Titanium Alloys in Armor Systems
Potential Applications of Titanium Alloys in Armor Systems
in Armor Systems
William A. Gooch Jr.
WA Gooch Consulting Inc.
10460 Roosevelt Blvd N, Suite 263
St. Petersburg, FL, 33716, USA
ABSTRACT
0B recent years, the cost of titanium has fallen with new
processing technology and the relative higher costs of
Titanium alloys have been investigated for their composite and ceramic armors has made titanium a valid
application as an armor technology since the 1950’s and option for some applications, whether for weight
published technical papers in many forums describe the reduction or improved ballistic performance.
possible replacement of steel wrought plate with
wrought titanium plate. The perceived high cost of As early as 1950, Pitler and Hurlich [1] noted that
titanium, however, has historically prevented greater titanium alloys showed promise as armors against small
application to military ground vehicles. The integration arms projectiles. By the early 1960's, Sliney [2]
of titanium alloys into an armor system may offer presented ballistic performance data for Ti-6Al-4V alloy
greater ballistic advantages when the total performance that demonstrated significant weight reductions over
is evaluated and this paper will examine potential steel armors for small arms threats. Little work with
applications of titanium in these systems. In recent larger threats was conducted due to the then prohibitive
years, the cost of titanium has fallen with new cost of the titanium. Since the early 1990’s, published
processing technology and the relative higher costs of research efforts defined baseline titanium ballistic
composite and ceramic armors has made titanium a valid performance data against a range of penetrators and
option for some applications, whether for weight fragments. The publication of revised military
reduction or improved ballistic performance. The specifications with new classes of titanium alloys,
distinct advantages of low density, high strength, a large processed through lower-cost plasma and electron-beam
competitive industrial base, and well established forming melting technology, has expanded further use of
and shaping techniques establishes titanium as an titanium for military applications
excellent material for many military applications.
Significant research efforts in understanding the material BACKGROUND
processing requirements for ground versus aerospace
applications are documented and this paper will provide Titanium can exist in a hexagonal close-packed crystal
an overview of that research. A major concurrent effort structure (known as the alpha phase) and a body-
has been amending existing military specifications to centered cubic structure (known as the beta phase). In
allow the use of lower cost, higher oxygen content unalloyed titanium, the alpha phase is stable at all
titanium alloys that meet specific ground applications. temperatures up to 882o C, where transformation to the
This paper will review some documented armor beta phase occurs. This transformation temperature is
applications of titanium, with emphasis on potential new known as the beta transus temperature. The beta phase is
titanium technologies and augments previous stable from 882o C to the melting point. As alloying
presentations given in this forum from 2007 to 2010. elements are added to pure titanium, the phase
transformation temperature and the amount of each
INTRODUCTION
1B phase change. Alloy additions to titanium, except tin and
zirconium, tend to stabilize either the alpha or beta
Titanium alloys have long been used for reducing phase. Ti-6Al-4V, the most common titanium alloy,
system weight in airframe structure and jet engine contains mixtures of alpha and beta phases and is
components. The perceived high cost of titanium, therefore classified as an alpha-beta alloy. The
however, has historically prevented greater application aluminum is an alpha stabilizer, which stabilizes the
to military ground vehicles. The integration of titanium alpha phase to higher temperatures, and the vanadium is
alloys into an armor system may offer greater ballistic a beta stabilizer, which stabilizes the beta phase to lower
advantages when the total performance is evaluated. In temperatures. The addition of these alloying elements
raises the beta transus temperature to approximately MILITARY SPECIFICATION MIL-DTL-46077G
996o C. Alpha-beta alloys, such as Ti-6Al-4V, are of
interest for armor applications because the alloys are An important factor in using titanium alloys for military
generally weldable, can be heat treated, and offer applications is Military Specification MIL-DTL-46077G
moderate to high strength [3]. Ti-6Al-4V alloy can be that defines different classes of titanium that can be used
ordered to a variety of commercial and military as armor [4]. While commercial specifications such as
specifications. Extra Low Interstitial (ELI) grade plates, SAE-AMS-T-9046, SAE-AMS4911 or ASTM-B265
simultaneously conforming to MIL-T-9046J, AB-2 maintain quality control through mechanical properties,
(aerospace) and MIL-A-46077G (armor) specifications chemistry and processing, MIL-DTL-46077G
are used in many applications. The specifications define emphasizes ballistic response to maintain quality
alloy chemistry ranges, minimum mechanical properties, control; no processing is specified. This specification
and, in the case of MIL-A-46077G, ballistic covers the thickness ranges of 0.125”- 4.000” and was
requirements. Typical chemical compositions of last revised on 28 September 2006. The main change
titanium plate are listed in Table 1 for a Class 1 ELI from the previous specification was the expansion of the
alloy; mechanical property data for a typical MIL-T- thickness range in thin sections down to 0.125”; the
9046J, AB-2 (aerospace) plate are found in Table 2. The ballistic acceptance tables for this range have not been
hardness values are representative of the plates tested; finalized as an acceptable ballistic test has proven
hardness is not specified in MIL-T-9046J. difficult due to the thin cross-sections and necessity to
discern quality variations due to processing.
U.S. rolled homogeneous armor (RHA) steel is used as
the baseline for most ballistic comparisons. RHA The emphasis in recent amendments to the specification
mechanical properties are also provided in Table 2 for has been to incorporate new classes of titanium armor
plate thicknesses ranging from 38-mm to 152-mm; the that utilize lower-cost titanium processing and alternate
mechanical properties of RHA vary as a function of alloys. Table 3 provides the current four classes of
plate thickness due to differences in thermomechanical titanium that can be specified under the MIL-DTL-
processing. A 38-mm RHA plate has higher strength and 46077G. While all four classes have the same strength
hardness than a 152-mm plate. Ti-6-4 Titanium has poor and ballistic requirements, the objective has been to
hardenability in thick sections and cannot be rapidly increase the oxygen content to a maximum of 0.30%
quenched. However, excellent mechanical properties can allowing the use of lower-cost processing technologies
be developed into wrought plate through such as Electron Beam or Plasma Melting for both Class
thermomechanical working (rolling). Titanium 3 and 4. Armor grade titanium has a greater tolerance to
mechanical properties are very uniform across the plate oxygen content than other applications in the aerospace
thickness that increases the relative ballistic performance industry. Class 4 titanium, unlike Class 1-3, allows
when compared to an equivalent thickness of RHA. In alternate armor alloys to be utilized and has opened up
thick sections, titanium has significantly better new alloy designations that utilize different alloying
mechanical properties for ballistic application than elements; this can have additional impact on overall
RHA. alloy cost by utilizing lower cost alloying elements.
BALLISTIC RESPONSE OF TITANIUM TO considered. Even when the impact velocities approach the
FRAGMENTS AND PROJECTILES hydrodynamic limit where material strengths can be ignored,
the penetration density law results in a theoretical
Extensive analysis of the ballistic response of titanium to both performance of 1.3 times that of steel.
projectiles and fragment simulators can be found in the
references [5-12]. As seen in Table 2, titanium has similar Microstructure and processing technology can still have a
strength, hardness and elongation to ballistic steel, but the significant effect on the performance at ordnance velocities.
density is 43% less. This strength to density ratio is the Figures 2 and 3 show two Ti-6Al-4V ELI plates that were
primary factor in the greater performance of titanium over beta- and alpha-beta-processed and then impacted by a 20mm
ballistic steel. Figure 1 illustrates the penetration of a Ti-6Al- fragment simulating projectile. The large difference noted in
V alpha-beta titanium and RHA steel by a long rod penetrator the ballistic performance between the plates tends to indicate
at velocities from 500 m/s up to 2600 m/s. The penetration that the failure mechanisms were in some way different.
into both metals is approximately equal up to about 1700 m/s Observation of the rear plate surface failures for perforating
and has a mass efficiency compared to steel of 1.87 at 1000 and near-perforating impacts showed this to be the case. The
m/s dropping off to 1.44 at 2000 m/s when the densities are beta processed plates failed by adiabatic shear plugging. This
300
2
250 Ti: P=348.8*exp(-(1.486/V) )
131W-Ti
2
RHA: P=292.6*exp(-(1.404/V) )
131W-RHA
200
PENETRATION (mm)
150
100
50
0
0 0.5 1.0 1.5 2.0 2.5 3.0
Figure 1. Penetration of a Tungsten Long Rod Penetrator into RHA and Titanium
low-energy failure mode caused a titanium plug to be ejected to the penetration channel. The shear banding happens all
from the rear surface of plate after the FSP penetrated along the circular penetration channel and the titanium
approximately 6-mm into the plate and has been described in fragments mix with the tungsten rod fragments. In a complete
previous work [12-14]. The plates that were alpha-beta perforation of the plate, the adiabatic titanium chips and
processed failed by a mixed process of bulging, delamination, penetrator debris are ejected and the penetration cavity wall
shearing, and spalling. However, this failure occurred only appears very smooth. When an eroded penetrator comes
after the FSP had penetrated approximately 15-mm into the within approximately one penetrator diameter of the rear free
plate, requiring the FSP to penetrate significantly deeper into surface, the plate will eject a spall plug that has a larger
the armor than for the beta-processed plates. Rolling or diameter than the penetrator. This spall plug is generally not
annealing at temperatures above the beta transus significantly penetrated during the interaction and decreases performance.
reduced the performance. Figure 5 shows a large spall plug induced in a four inch plate
that resulted in an approximate 20% loss in penetrator/target
Adiabatic shear plugging is inherent in titanium as a result of interaction. For this reason, titanium is not recommended for
shear-induced strain localizations and the low heat transfer standalone use and low density backings, such as aluminum
properties of titanium. Figure 4 shows the deep penetration of or composites, increase performance as the spall plug is held
a long rod tungsten penetrator into a titanium plate. The in place and contribute to erosion of the penetrator.
adiabatic shear bands in the sectioned plate are visible parallel
PENETRATOR
CHANNEL
PENETRATOR
IMPACT SHEAR BANDS AND
DELAMINATION
Figure 5. Spall Plug Breakout of a 100mm (4.0”) Titanium Plate after Perforation
by a Long Rod Penetrator
EFFECT OF MECHANICAL PROPERTIES ON summarized in Figure 6 where the effect of heat treating
BALLISTIC PERFORMANCE or working the plates over the beta transus temperature
is obvious. The initial vacuum creep-flatten process
The quasi-static mechanical properties of titanium are produced ballistic plate with a performance similar to
very important for most engineering applications and plates subjected to additional annealing below the beta
were included in the property requirements in MIL- transus. Plates annealed above the beta transus have a
DTL-46077G for Class 1 and 2 titanium. However, for microstructure change to a Widmanstätten alpha-beta
armor applications, the impact of varying the mechanical structure as seen in Figure 7. The effect on ballistic
properties is not apparent and processing history is more performance compared to transverse yield strength,
important. The most complete analysis of these effects transverse elongation and Charpy impact data are shown
were conducted by Burkins, Love and Wood where a set in Figures 8-10. The annealing step could be omitted to
of Ti-6Al-4V ELI plates were subjected to a series of reduce cost or the anneal temperature could be increased
annealing temperatures and the effects on the to 900oC to obtain the highest performance.
mechanical properties were determined [13]. The results
on the samples from the original single 28.5mm plate are
1200
1100
V50 LIMIT VELOCITY (m/s)
1000
900
Beta Transus
700
700 800 900 1000 1100
ANNEALINGTEMPERATURE (C)
Figure 6. Effect of Annealing Temperature on Ballistic Performance
1200
200x
1100
V50 LIMIT VELOCITY (m/s)
1000 Partially
recrystallized a +
intergranular ß
900 200x
Beta Transus
VCFOnly, NoAnneal
30Min Anneal, AC
30Min Anneal, WQ
30Min Anneal, FC
800
120Min Anneal, AC
Duplex (1038+788)
700
700 800 900 1000 1100 Coarse prior ß
transformed to
ANNEALINGTEMPERATURE (C) Widmanstatten a-ß
Figure 7. Change in Microstructure for Annealing over the Beta Transus Temperature
1200
831 MPa
1100
V50 LIMIT VELOCITY (m/s)
704 MPa
1000
826 MPa
900
Beta Transus
700
700 800 900 1000 1100
ANNEALINGTEMPERATURE (C)
Figure 8. Change in Transverse Yield Strength with Annealing Temperature
EFFECT OF THERMOMECHANICAL AB-2 plates from RMI Titanium Company, rolled these
PROCESSING ON BALLISTIC PERFORMANCE plates to final thickness, performed the annealing, and
collected mechanical and microstructural information.
In an effort to provide further data on processing of ARL then tested the plates with 20-mm fragment-
titanium armor plate, the US Army Research Laboratory simulating projectiles (FSPs) and 12.7-mm armor-
(ARL) and the U.S. Department of Energy Albany piercing (AP) M2 bullets in order to determine the
Research Center (ALRC) performed a joint research ballistic limit velocity of each plate. The ballistic limit
program to evaluate the effect of thermomechanical velocities were then compared to assess the effect of
processing on the ballistic limit velocity of an ELI grade changes in rolling and heat treatment.
of Ti-6Al-4V [14-15]. ALRC obtained MIL-T-9046J,
1200
1100
V50 LIMIT VELOCITY (m/s)
1000
Below 12%
900
Beta Transus
VCF Only, No Anneal
30 Min Anneal, AC
30 Min Anneal, WQ
800
30 Min Anneal, FC
120 Min Anneal, AC
Duplex (1038+788)
700
700 800 900 1000 1100
ANNEALINGTEMPERATURE (C)
Figure 9. Effect of Transverse Elongation with Annealing Temperature
1200
L- 27J
1100 T- 29J
V50 LIMIT VELOCITY (m/s)
L- 22J
1000
T- 20J
L- 46J
900
T- 45J
Beta Transus
700
700 800 900 1000 1100
ANNEALINGTEMPERATURE (C)
Figure 10. Effect on Charpy Impact Results with Annealing Temperature
The starting material was commercially produced 127- beta), and step forged to 108-mm first and then 89-mm.
mm-thick Ti-6Al-4V ELI alloy plate product. Each plate The step forging was done without reheating. Upon
was coated with a silica-based material to reduce oxygen completion, the plates were returned to the furnace and
contamination, placed into the furnace, and soaked for reheated for 20 minutes. The plates were then, either
two hours at either 1,066o C (beta) or 954o C (alpha- unidirectionally (straight) rolled or cross-rolled at the
same temperature used in the forging operation (1,066o in the alpha-beta region had a typical structure of
C or 954o C). The rolling schedule consisted of two equiaxed alpha grains and intergranular beta.
passes at 12% reduction in thickness, two passes at 15%
reduction in thickness, three passes at 20% reduction in V50 limit velocities were obtained for all eleven plate
thickness, and one final pass at the final mill setting of conditions, tested with both the 20-mm FSP and 12.7-
25.4 mm. Each plate was reheated for 20 minutes after mm APM2 projectiles. Figure 11 shows graphically the
every second pass through the mill. Following the final V50 difference for the eleven plate conditions. The
pass, the plates were placed on a rack and air cooled to required V50 values were derived from the acceptance
room temperature. tables in MIL-A-46077D. Regardless of the penetrator
used, only three plates (S1, C1, and C4) passed the
Four different annealing heat treatments were used at the ballistic requirements of MIL-A-46077D, even though
completion of rolling and air cooling: (1) a beta anneal these three plates also failed to meet the elongation
at 1,038o C for 30 minutes with an air cool (AC); (2) a requirements of MIL-A-46077D. Beta-processed plates,
beta plus alpha-beta anneal at 1,038o C for 30 minutes either rolled or annealed at temperatures above the beta
with an AC, followed by 788o C for 30 minutes with an transus, had lower V50 ballistic limit velocities for both
AC; (3) an alpha-beta anneal at 788o C for 30 minutes the 20-mm FSP and the 12.7-mm APM2. The magnitude
with an AC; and (4) a solution treat and age (STA) at of the effect was much greater for the 20-mm FSP (~200
927o C for 30 minutes with a water quench (WQ), m/s) than for the APM2 (~40 m/s), confirming a trend
followed by 538o C for 6 hours with an AC. As an that had been indicated in prior data [12]. The plates that
experimental control, the final heat treatment was received no additional anneal treatment (C4 and S5)
omitted for some of the plates. Following heat treatment, gave a ballistic performance comparable to similarly
all the plates were sand-blasted to remove any remaining processed plates that received an alpha-beta anneal
protective coating. All plates forged, rolled, or annealed treatment (C1 and S2). For the APM2 tests, cross rolling
in the beta region had a typical structure of plate-like provided no significant difference in V50 as compared to
alpha and intergranular beta with alpha at the prior beta straight rolling (S1 vs. C1 and C5 vs. S2). For the 20-
grain boundaries. All plates forged, rolled, and annealed mm FSP tests, cross rolling seemed to provide a slightly
No beta processing
Beta processed
Figure 11. Beta processed Ti-6Al-4V Plate Compared to Alpha-Beta Processed Plate
higher V50 than straight rolling in the alpha-beta region processing. The ballistic evaluation of cast titanium
(S1 vs. C1); however, straight rolling seemed to be utilized ASTM 367-87 Grade 5 alloy and was compared
slightly better than cross rolling in the beta region (C5 to wrought Ti-6Al-4V plate as defined in Tables 4 and 5.
vs. S2). The beta-processed plates failed by a process of The mechanical properties for the cast material are lower
adiabatic shear plugging. The alpha-beta-processed than the wrought plate, except for the hardness and the
plates failed by a mixed process of bulging, compositions are similar. The cast titanium was also
delamination, shearing, and spalling, which required subjected to post processing procedures to include hot
more energy because the FSP had to burrow much isostatic pressing to reduce porosity and pickling to
deeper into the armor plate before rear surface failure reduce the case hardened layer and surface
occurred. The failure mode for beta and alpha-beta imperfections. The samples were impacted with armor-
processed plates appeared to be the same for the 12.7- piercing and FSP projectiles and the results for the
mm APM2. This observation is consistent with the 20mm FSP are shown in Figure 12.
relatively small differences in V50 performance between
the beta- and alpha-beta-processed plates. The baseline wrought data are plotted in Figure 12 as a
dashed red line and the cast titanium is plotted as a solid
TITANIUM WROUGHT PLATE VS CASTINGS black line. These data show the cast titanium
performance to be, at best, 75% of wrought titanium and
The advantages of utilizing net shape cast titanium results from the reduced strengths as compared to the
components for armor applications and other ballistic rolled wrought plate. The effects of post processing
uses led to an examination of the ballistic performance procedures are minimal with some possible
of cast titanium as compared to wrought plate [16]. The improvement in the ballistic performance due to
main issue is cost reduction by eliminating unnecessary pickling; but the data are scattered. Conjecture would be
1000
950
900
V50 LIMIT VELOCITY (m/s)
850
800
750
700
650
MIL-DTL-46077F (Wrought Ti-6Al-4V)
600 Cast Ti-6Al-4V (1997-HIP)
No HIP - No Pickle
No HIP - Light Pickle
550 No HIP - Heavy Pickle
HIP - No Pickle
500 HIP - Light Pickle
HIP - Heavy Pickle
450
17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33
THICKNESS (mm)
Figure 12. Ballistic Performance of 20mm FSP vs Wrought and Cast Titanium
Table 4. Comparison of Wrought and Cast Titanium Compositions
Heat Part Nominal Al V Fe O C N H
# ID # Thickness
(mm) (%) (%) (%) (%) (%) (%) (%)
970181 25.4
970139 6.27 3.8 0.15 0.21 0.02 0.01 0.002
970179 12.7
970179 12.7
970140 970180 19.1 6.27 3.8 0.17 0.23 0.02 0.01 0.004
970183 38.1
970182 31.8
970138 6.28 3.8 0.16 0.21 0.02 0.01 0.002
970183 38.1
ASTM 367-87 5.5- 3.5- 0.40 0.25 0.10 0.05 0.015
Grade C5 6.75 4.5 max max max max max
970181 25.4
970139 885 989 10.0 318
970179 12.7
970179 12.7
970140 970180 19.1 900 1024 11.0 315
970183 38.1
970182 31.8
970138 879 981 10.0 299
970183 38.1
ASTM 367-87 Grade C5 825 min. 895 min. 6 min. 365 max.
that any post process that homogenizes the surface, over wrought plate. In complex shapes, casting may be
particularly the back of the casting could decrease crack advantageous when compared to steel castings that
initiation points when in tension. The use of cast suffer the same issues.
components will require 20-25% thicker cross-sections
SHAPED CHARGE PROTECTION OF TITANIUM
TITANIUM COMPOSITES/LAMINATES
Figure 19. Multiple Impacts on a Titanium/
Aluminum Laminate
Figure 31. Titanium Commanders Hatch and Roof Applique on M2A2 Bradley Fighting Vehicle
Figure 35. BAE Pegasus Titanium
Wheeled Prototype
Figure 32. M777A1 Ultra-light Field Howitzer
The latest prototype titanium vehicle structure was an
early Future Combat Vehicle hull section that was used
to test composite armors (Figure 36) [48]. The lower
body and nose sections were fabricated from Military
Specification MIL-DTL-46077G Class 3 low cost
titanium and were mated to a composite and space frame
composite upper hull section. The vehicle was subjected
to extensive ballistic testing and shock loading to
measure the vehicle response.
• Titanium was first examined for armor applications in 1950 by the Watertown
Arsenal and Ti-6Al-4V become the main alloy of interest
• The main advantage of titanium relates to the lower density at equal or higher
strengths than rolled homogenous armor steel of equal thickness (23.2 vs 40.8
psf for 1” board foot ~43% weight reduction)
• This is the fifth year this overview has been at the ITA and the written paper
provides a detailed review of the ballistic aspects of titanium alloys
• In this short time, I would like to re-emphasize two technical areas that can
lead to increased use of titanium alloys in the future:
Emphasis 1: Class 3 and Class 4 Titanium alloys under MIL-DTL-46077G
Emphasis 2: Dual hard titanium
• The presentation will show some new applications and end with an overview
of current and proposed future applications of titanium for military ground
vehicles
2
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KE Ballistic Performance of RHA and Titanium
300
2
250 Ti: P=348.8*exp(-(1.486/V) )
131W-Ti
2
RHA: P=292.6*exp(-(1.404/V) )
131W-RHA
200
PENETRATION (mm)
150
100
Beta β
Body-Centered
Cubic
Alpha α
Close-packed
Hexagonal
4
WA Gooch Consulting Inc.
Failure Analysis of 20mm Fragment
Simulating Projectile Impact
Failure by a mixed
15mm process of bulging,
delamination, shearing,
and spalling
5mm
αβ
Failure by
low-energy
plugging
β 5
WA Gooch Consulting Inc.
Adiabatic Shear Bands in Titanium
1 µm
7
WA Gooch Consulting Inc.
Spall Plug Breakout of Stand alone Titanium
SPALL RING
BREAKOUT
8
WA Gooch Consulting Inc.
Shaped Charge Penetration
Formation of SC Jet 9
WA Gooch Consulting Inc.
Shaped Charge Penetration into Titanium
~25 inches
1028 lbs/ft2
~27 inches
635 lbs/ft2
10
WA Gooch Consulting Inc.
Titanium MIL-DTL-46077F & G
Max. O2
Chemistry Comments
Content
Class 1 6AL- 4V 0.14% ELI - 10% Elongation Minimum
Historical Armor Alloy
Class 2 6AL- 4V 0.20%
6% Elongation Minimum
Higher Scrap/O2 Content
Class 3 6AL- 4V 0.30%
Electron Beam/Plasma Melting
Lower cost alloying
Class 4 Not Limited 0.30%
Non Aerospace Alloys
All four classes have the same minimum strength and ballistic requirements
MIL-DTL-46077G - Expanded thickness range: 3mm-101.6mm
11
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Emphasis 1
Class 3 and 4 MIL-DTL-46077G Plate
Ti-6Al-4V CP Ti Gr 2
CP
Ti-6Al-4V
17
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Steel P900 Tipping Plate Armors
Yes, that’s
1960
23
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Weight Reduction Application for Air Transportability
24
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Protection and Weight Reduction Applications
Stryker Family of Vehicles
27
BAE/TARDEC/ARL WA Gooch Consulting Inc.
Conclusions
• This presentation provided a cursory overview of the technical
investigation of titanium for military ground applications.
• The written paper has expanded technical detail and references
• The main advantage of titanium relates to its lower density at
equal or higher strengths than armor steel of equal thickness.
Emphasis:
• Military Specification MIL-DTL-46077G increased the thickness
range and defined Class 3 &4 alloys that provide equal protection
at lower processing costs through increased oxygen levels, greater
scrap content, advanced processing and reduced alloying.
• The development of Dual Hard titanium offers higher KE
performance at equal weight and needs to be re-examined again.
Thank you
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