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SOP 4 Calibration Dwright V19

The software WAMRF-008 (Rev. 19), Weighing by Double Substitution, SOP 4 was assessed. The assessment found that the spreadsheet is clearly laid out and calculations match the specified SOP. Fields are properly formatted and locked. Embedded data and linked references have been validated. Evaluations showing the software generates accurate results compared to older versions and hand calculations are documented. The software passed all assessment criteria for use in mass calibrations up to the level of precision specified by its published scope.

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Maruthi K
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0% found this document useful (0 votes)
186 views44 pages

SOP 4 Calibration Dwright V19

The software WAMRF-008 (Rev. 19), Weighing by Double Substitution, SOP 4 was assessed. The assessment found that the spreadsheet is clearly laid out and calculations match the specified SOP. Fields are properly formatted and locked. Embedded data and linked references have been validated. Evaluations showing the software generates accurate results compared to older versions and hand calculations are documented. The software passed all assessment criteria for use in mass calibrations up to the level of precision specified by its published scope.

Uploaded by

Maruthi K
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLS, PDF, TXT or read online on Scribd
You are on page 1/ 44

Weights and Measures Program

WAQCF-018, Rev. 04, 8/9/2010


Metrology Laboratory

Software Technical Assessment

Software WAMRF-008 (Rev. 19), Weighing by Double Substitution, SOP 4 Approval November 25, 2014
Description Date
Assessed By Dan Wright Approved Dan Wright
By
Codes Assessment Pass/Fail Evidence
Spreadsheet is clear and makes sense Pass All worksheet are appropriately named and easy to understand
There are instructions for use Pass Instructions worksheet
Instructions and data input appear on the visible portion of the first Pass The workbook opens to the instruction worksheet
worksheet
Data-entry fields are labeled and color coded (it is recommended to avoid Pass Light yellow for blank, light blue for non-blank cells
red and green)
A. Software Inspection

The Standard Operating Procedure (SOP) used is clearly specified Pass Specified on Uncertainty Analysis worksheet
The number of digits to be rounded to is specified Pass Mass corrections and uncertainties are rounded according to NISTIR 6969,
GLP 9

The user is warned/notified whenever data-entry fields are left blank Pass In data validation cells only
Data-entry fields are “blank” when opened, preventing loss of old data and Pass Data entry fields on the workbook template are blank. Instructions tell user
ensuring that old data is not used with the current calculations to break links before saving after a calibration is performed
The software opens at the right location within the file Pass Opens to the Instruction worksheet
Unused fields/cells are locked Pass Unused cells are locked and worksheets are protected
Rows/columns that the operator need not see are hidden N/A No hidden cells or worksheets
Unused sheets are removed Pass No unused worksheets
Worksheets are named appropriately Pass Worksheets are appropriately named
The correct SOP is used Pass SOP 4 is embedded
B. Mathematical
Specification

The formulae and methods chosen from that SOP are specified Pass Formulae are show in SOP 4 and Uncertainty Analysis worksheets
Sources and references for formulae are specified Pass As specified in SOP 4
The chosen SOP, its methods, and its formulae, are appropriate to the level Pass For all Mass Echelon II and III calibrations
of precision/uncertainty
The formulae in the fields exactly match the SOP Pass Formulae on calculation worksheet match SOP 4
C. Code review

Repeated calculations appropriately reference the correct cells Pass


Calculations, when tested using standard data or reference test data, show Pass Tested using SOP 4 example and Data Sets
appropriate accuracy
Rounding is done at the appropriate locations in the file Pass Specified on Calculations worksheet
Calculations are stable as determined by an evaluation that uses large Pass No issues encountered
numbers and small differences
D. Numerical
Stability

Fields, therefore their content, are categorized as “Number” and not Pass Formatted correctly throughout workbook
“General” when appropriate, and vice versa
“Number” cells are locked to a limited number of decimal places; this limit Pass Where appropriate
is appropriate to the values being used

Page 1 of 44
Weights and Measures Program
WAQCF-018, Rev. 04, 8/9/2010
Metrology Laboratory

Software Technical Assessment

Software WAMRF-008 (Rev. 19), Weighing by Double Substitution, SOP 4 Approval November 25, 2014
Description Date
Assessed By Dan Wright Approved Dan Wright
By
Codes Assessment Pass/Fail Evidence
Each macro used is functional N/A No Macros
E. Component

Each command/button is functional N/A No command buttons


Testing

Combinations of interdependent macros are functional Pass No issues encountered


Plotted graphs are accurate Pass Graphs on uncertainty worksheet display properly
Worksheets/reports print properly, if needed to Pass Worksheets formatted for printing as necessary
Conditional (color and non-color) formatting is functional Pass On data entry and calculation worksheets
Look-up tables and lists match the latest calibration report. Pass Linked tables are validated and up to date
Uncertainties match the latest Scope Pass Test on uncertainty worksheet will not allow an uncertainty that is better
F. Numerical

than the latest published scope


Reference

Values that reference another workbook or spreadsheet are dated N/A Linked references have been validated and are up to date
When a master list’s date is updated, the file references (A) an old value, N/A
(B) a default value, (C) displays zero or (D) an error message, as desired by
the user

Embedded data (conversion factors, reference values, etc) is correct Pass All embedded data has been validated
Evaluation
Embedded
Data
G.

The evaluation of the embedded data is dated and documented Pass Records keep in Software Validation folder on computer hard drive

Newer spreadsheets and older spreadsheets agree down to the level of Pass Evaluated and filed
H. Back-
to-Back
Testing

intermediate calculations; this evaluation is dated and documented

Hand calculations agree with those generated by the spreadsheet, or if they N/A No hand calculations were done
Assistance
I. Analysis

Computer
With Out

disagree, the differences are significantly smaller than the reported


uncertainty

Equation and calculation cells are protected against inadvertent editing Pass Cells are locked and worksheets are password protected
J. Security

Cells are locked in place; they cannot be moved/dragged Pass Locked and password protected
Confidentiality of passwords is appropriate Pass State Metrologist and Program Manager only have access
Files are backed up automatically Pass Backed up to agency servers weekly
Additional back-up is available at alternate facilities Pass Agency IT backs up servers weekly
Files on network drives cannot be accidentally deleted Pass Agency IT keeps an additional back up at a remote location

Page 2 of 44
Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Documentation
Date Description Initials
10/4/2002 This spreadsheet was developed by Dan Wright, WA Dept of DAW
Agriculture. This workbook follows the procedure
documented in NISTIR 6969, SOP 4 and SOP 7.

9/29/2004 Changed uncertainty analysis DAW


10/6/2006 Total revision and reissue DAW
7/20/2007 Changed check standard test to include control chart DAW
bias/drift
9/24/2007 Rounded air density formula to 6 places and water density to DAW
8 places
2/4/2008 Deleted 'Standards' worksheet. Re-referenced vlookups to DAW
global standards workbooks
7/15/2008 changed range controls to pooled standard deviations DAW
9/11/2008 Deleted triplicate measurement. Added 'Control Data' DAW
worksheet. Revised "Documentation' worksheet.
11/13/2008 Changed "BalID" to "BalUnit" in cells F18 and A19 on Data DAW
Entry worksheet
11/13/2008 Corrected headers and footers on 'Documentation' and both DAW
'Reports' worksheets
11/13/2008 Updated Balance ID comment in cell A14 and created lookup DAW
for balance process standard deviation in I19 on 'Data Entry'
worksheet

11/13/2008 Changed 'Pts' to 'Ptx' in cell A50 on 'Uncertainty Analysis' DAW


worksheet
11/13/2008 Added IF statement in cell H61 for 'Not Applicable' on DAW
'Calculations' worksheet
11/13/2008 Copied formulas for weight identification from 'Data Entry' to DAW
'Equal-Arm Balance Data Entry' worksheets
11/13/2008 Added 'Job Order Number' on 'Data Entry' sheet DAW
11/13/2008 Corrected procedure selection formula on 'Report Pages 1-3' DAW
worksheet
1/21/2009 Converted to Excel 2007, updated links. DAW
1/21/2009 Color coded data entry cells. Edited all comments. DAW
1/21/2009 Added Standards Used table on Data Entry worksheet. DAW

524753224.xls Documentation Worksheet Page 3 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

1/21/2009 Reformatted colors and conditional formatting. DAW


11/1/2009 Deleted Tolerances worksheet, linked to Mass Tolerances DAW
workbook, and updated formulas in the Tolerance Lookup
Table on the Tables and Lists worksheet.

11/1/2009 Validated range names. DAW


11/1/2009 Validated workbook, file name "WA2009-11-01 WAMRF-008 DAW
(Rev. 08), SOP 4 & 7 Workbook V&V.pdf". Electronic copy on
laboratory C:\ drive and agency server H:\ drive and paper
copy in laboratory files.

9/27/2010 Revised the Uncertainty Analysis worksheet and added DAW


Software Technical Assessment and SOP worksheets.
9/27/2010 Validated range names. DAW
9/27/2010 Validated workbook, file name "WA2010-09-27 WAMRF-008 DAW
(Rev. 09), SOP 4 & 7 Workbook V&V.pdf". Electronic copy on
laboratory C:\ drive and agency server H:\ drive and paper
copy in laboratory files.

1/6/2012 Reformatted Control Data worksheet. DAW


1/6/2012 Cleaned up formulas on Calculations worksheet cells H20, DAW
J20, H29, & J29.
1/6/2012 Validated range names. DAW
1/6/2012 Validated workbook, file name "WA2012-01-06 WAMRF-008 DAW
(Rev. 10), SOP 4 & 7 Workbook V&V.pdf". Electronic copy on
laboratory C:\ drive and agency server H:\ drive and paper
copy in laboratory files.

2/24/2012 Added FORMAT_CX and ROUND_UNC visual basic modules for DAW
rounding results and uncertainties IAW NISTIR 6969, GLP 9
using the FmtCX() and Rnd2() functions.

2/24/2012 Added SI statement and conversion factors on the Report


Pages 1-3 spreadsheet.
2/24/2012 Validated range names. DAW
2/24/2012 Validated workbook, file name "WA2012-02-24 WAMRF-008 DAW
(Rev. 11), SOP 4 & 7 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

524753224.xls Documentation Worksheet Page 4 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

4/6/2012 Changed "Certification Statement" to "Accreditation DAW


Statement" on Report Pages 1-3 worksheet to be in
compliance with NVLAP requirement Annex A, l).

8/13/2012 Inserted new WSDA Logo on "Report Pages 1-3" worksheet. DAW

9/15/2012 Revised for SOP 4 only DAW


9/15/2012 Embedded 2012 SOP
9/15/2012 Updated air density formula on CIPM Air Density worksheet DAW

9/15/2012 Modified Data Entry worksheet observations section and DAW


added degrees of freedom and best uncertainty k factor
entries

9/15/2012 Updated k factor based on degrees of freedom IAW SOP 29 DAW


(2012 edition)
9/15/2012 Validated range names. DAW
9/15/2012 Validated workbook, file name "WA2012-09-15 WAMRF-008 DAW
(Rev. 12), SOP 4 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

10/24/2012 Corrected equation reference for tx combined density, Data DAW


Entry worksheet, cell I56, Sc combined density, Data Entry
worksheet, cell J66 & tsc combined density, Data Entry
worksheet, cell K72.

10/24/2012 Validated range names. DAW


10/24/2012 Validated workbook, file name "WA2012-10-24 WAMRF-008 DAW
(Rev. 13), SOP 4 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

2/17/2013 Removed GLP Rounding macros DAW


2/17/2013 Entered new rounding technique and corrected formulas DAW
2/17/2013 Validated range names. DAW
2/17/2013 Validated workbook, file name "WA2013-02-17 WAMRF-008 DAW
(Rev. 14), SOP 4 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

524753224.xls Documentation Worksheet Page 5 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

7/12/2013 Corrected and updated the uncertainty of the air buoyancy DAW
correction formula.
7/12/2013 Updated input for and added the Welch-Satterthwaite DAW
formula for effective degrees of freedom.
7/12/2013 Revised Data Entry, Control Data, Calculations and
Uncertainty Analysis worksheets.
7/12/2013 Included essential information on Report page 4 DAW
7/12/2013 Validated range names.
7/12/2013 Validated workbook, file name "WA2013-07-12 WAMRF-008 DAW
(Rev. 15), SOP 4 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

8/6/2013 Fixed the double substitution differences tests in cells J82 DAW
through J108 on the Data Entry spreadsheet.
8/6/2013 Validated range names. DAW
8/6/2013 Validated workbook, file name "WA2013-08-06 WAMRF-008 DAW
(Rev. 16), SOP 4 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

8/12/2013 Corrected formulas in cells C46 & C47 on Calculations DAW


spreadsheet to correctly convert from milligrams to grams

8/12/2013 Validated range names. DAW


8/12/2013 Validated workbook, file name "WA2013-08-12 WAMRF-008 DAW
(Rev. 17), SOP 4 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

8/22/2013 Corrected fomula for the Csc calculation on the Calculations DAW
worksheet.
8/22/2013 Modified the Tolerance List and Units of Measure to fit the DAW
OIML, ASTM & NIST specifications
8/22/2013 Deleted Equal-Arm Balance Data sheet DAW
8/22/2013 Changed tolerance to maximum permissible error (MPE) DAW
8/22/2013 Validated range names. DAW

524753224.xls Documentation Worksheet Page 6 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

8/22/2013 Validated workbook, file name "WA2013-08-22 WAMRF-008 DAW


(Rev. 18), SOP 4 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

5/7/2014 Made Ub calculation an absolute in D135 of Uncertainty DAW


worksheet.
5/7/2014 Defined nominal values in Report Page 4 worksheet. DAW
10/29/2014 Changed statistical df from 100 to 10000. DAW
11/25/2014 Updated bias test to the 2014 NISTIR 6969, SOP 29, DAW
paragraph 3.2.5.2
11/25/2014 Created an evaluation of the standard deviation vs the DAW
balance resolution per NISTIR 6969, SOP 4, paragraph 5.2.2.

11/25/2014 Embedded the NISTIR 6969, SOP 4 2014 version. DAW


11/25/2014 Corrected reference in effective degrees of freedom on
Uncertainty worksheet. Changed H133^4/J134 to
H133^4/J133.

11/25/2014 Moved uncertainty evaluation to Data Entry worksheet and DAW


added Precision Test.
11/25/2014 Pa was defaulted to nominal (0.0012 g/cm³) so the DAW
uncertainty evaluation calculate before measurement are
made.

11/25/2014 Calculations, conditional formatting and wording for the DAW


Measurement Assurance evaluation were corrected.
11/25/2014 Validated range names. DAW
11/25/2014 Validated workbook, file name "WA2014-11-25 WAMRF-008 DAW
(Rev. 19), SOP 4 Workbook V&V.pdf". Electronic copies in
laboratory computer C:\ drive and agency server H:\ drive
and paper copy in laboratory files.

524753224.xls Documentation Worksheet Page 7 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Unprotect the worksheet, then double click the document to open in Adobe Acrobat

524753224.xls SOP 4 Worksheet Page 8 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

A1: Unprotect the worksheet, then double click the document to open in Adobe Acrobat

524753224.xls Comments Worksheet Page 9 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Unprotect the worksheet, then double click the document to open in Adobe Acrobat

524753224.xls OIML Unc Estimates Worksheet Page 10 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

A1: Unprotect the worksheet, then double click the document to open in Adobe Acrobat

524753224.xls Comments Worksheet Page 11 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Instructions
No. Description
1 Validate this workbook after any changes.
2 The worksheets are password protected: password
3 Carry the same tare on the Check that you do with the
Standard.
4 Update Report worksheets with your laboratory information.

5 Update all worksheet headers and the Report pages footers


with your unique form numbers to make it part of your
document system.

6 Be sure to document all your changes on the Document


worksheet.
Range Names
Name Range
ABC ='Data Entry'!$J$19
Balance ='Data Entry'!$E$15
BalID ='Data Entry'!$C$15
BalUnit ='Data Entry'!$J$15
Best_df ='Data Entry'!$H$21
Best_k ='Data Entry'!$J$21
Best_U ='Data Entry'!$E$21
Cal_Date ='Data Entry'!$C$23
CIPM_Pa_found ='CIPM Air Density'!$D$7
CIPM_Pa_left ='CIPM Air Density'!$D$13
Class_Spec ='Data Entry'!$C$17
Class_Spec_List ='Tables and Lists'!$A$4:$A$33
Condition ='Data Entry'!$C$14
ConvTable ='Tables and Lists'!$O$5:$W$16
Cs ='Data Entry'!$D$42
Csc ='Data Entry'!$D$64
CsUnit ='Data Entry'!$D$38
Csw ='Data Entry'!$D$59
Cts ='Data Entry'!$D$49
Ctsc ='Data Entry'!$D$70

524753224.xls Instructions Worksheet Page 12 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

6 Be sure to document all your changes on the Document


worksheet.
Range Names
Ctx ='Data Entry'!$D$55
CustomerID ='Data Entry'!$J$4
Description ='Data Entry'!$C$10
drift_or_Rmean ='Data Entry'!$F$19
Final_k ='Uncertainty Analysis'!$I$145
Final_U ='Uncertainty Analysis'!$I$146
Final_Veff ='Uncertainty Analysis'!$I$144
hr_1 ='Data Entry'!$I$86
hr_1_left ='Data Entry'!$I$102
hr_2 ='Data Entry'!$I$98
hr_2_left ='Data Entry'!$I$108
hr_3_left ='Data Entry'!$I$115
hr_corr ='Data Entry'!$D$76
hr_found ='CIPM Air Density'!$D$6
hr_left ='CIPM Air Density'!$D$12
ID ='Data Entry'!$C$13
Interval ='Data Entry'!$J$22
IntervalQ ='Data Entry'!$F$22
JobNo ='Data Entry'!$I$14
k ='Uncertainty Analysis'!$I$139
k_hr ='Data Entry'!$H$76
k_P ='Data Entry'!$H$75
k_S ='Data Entry'!$F$42
k_Sc ='Data Entry'!$H$64
k_sw ='Data Entry'!$H$59
k_t ='Data Entry'!$H$74
k_ts ='Data Entry'!$H$49
k_tsc ='Data Entry'!$H$70
k_tx ='Data Entry'!$H$55
LCL =Calculations!$C$47
Left_Start ='Data Entry'!$C$102
Material ='Data Entry'!$I$13

524753224.xls Instructions Worksheet Page 13 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

6 Be sure to document all your changes on the Document


worksheet.
Range Names
mcr ='Uncertainty Analysis'!$B$116
Meas_Option ='Tables and Lists'!$C$4:$G$5
MeasuredU ='Uncertainty Analysis'!$I$140
Mfg ='Data Entry'!$C$11
MPE ='Data Entry'!$I$17
Ms =Calculations!$C$18
Msc =Calculations!$C$20
Msw =Calculations!$C$23
Mts =Calculations!$C$19
Mtsc =Calculations!$C$21
Mtx =Calculations!$C$22
Nom_Val_List ='Tables and Lists'!$O$4:$O$16
Nx ='Data Entry'!$I$12
Obs1_1 ='Data Entry'!$G$88
Obs1_2 ='Data Entry'!$G$89
Obs1_3 ='Data Entry'!$G$90
Obs1_4 ='Data Entry'!$G$91
Obs2_1 ='Data Entry'!$G$94
Obs2_2 ='Data Entry'!$G$95
Obs2_3 ='Data Entry'!$G$96
Obs2_4 ='Data Entry'!$G$97
Obs3_1 ='Data Entry'!$G$104
Obs3_2 ='Data Entry'!$G$105
Obs3_3 ='Data Entry'!$G$106
Obs3_4 ='Data Entry'!$G$107
Obs4_1 ='Data Entry'!$G$111
Obs4_2 ='Data Entry'!$G$112
Obs4_3 ='Data Entry'!$G$113
Obs4_4 ='Data Entry'!$G$114
Option ='Data Entry'!$I$18
P_0 ='Uncertainty Analysis'!$B$121
P_1 ='Data Entry'!$G$86

524753224.xls Instructions Worksheet Page 14 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

6 Be sure to document all your changes on the Document


worksheet.
Range Names
P_1_left ='Data Entry'!$G$102
P_2 ='Data Entry'!$G$98
P_2_left ='Data Entry'!$G$108
P_3_left ='Data Entry'!$G$115
P_corr ='Data Entry'!$D$75
P_found ='CIPM Air Density'!$D$4
P_left ='CIPM Air Density'!$D$10
Pa =Calculations!$C$9
Pa_left =Calculations!$C$15
Pa1 ='Data Entry'!$J$42
Pn ='Uncertainty Analysis'!$E$117
PO_No ='Data Entry'!$H$5
POC ='Data Entry'!$H$6
POC_Phone ='Data Entry'!$H$7
Pr ='Uncertainty Analysis'!$B$117
Print_Titles =Instructions!$8:$9
Process ='Data Entry'!$C$18
Ps ='Data Entry'!$H$42
Psc ='Data Entry'!$J$64
Psw ='Data Entry'!$J$59
Pt ='Uncertainty Analysis'!$B$118
Pts ='Data Entry'!$J$49
Ptsc ='Data Entry'!$J$70
Ptx ='Data Entry'!$J$55
Px ='Data Entry'!$D$16
Receive_Date ='Data Entry'!$I$11
Resolution ='Data Entry'!$H$15
Rpt_Units ='Data Entry'!$I$24
RptNo ='Data Entry'!$H$1
S ='Data Entry'!$B$42
Sc ='Data Entry'!$B$64
Sc_Meas_Option ='Tables and Lists'!$I$4:$M$5

524753224.xls Instructions Worksheet Page 15 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

6 Be sure to document all your changes on the Document


worksheet.
Range Names
Sdf ='Data Entry'!$G$42
SN ='Data Entry'!$C$12
sp ='Data Entry'!$F$20
sp_df ='Data Entry'!$J$20
sp_unit ='Data Entry'!$A$20
StUnit ='Data Entry'!$A$20
sw ='Data Entry'!$B$59
sw_df ='Data Entry'!$I$59
sw_list ='Tables and Lists'!$W$4:$W$10
t_1 ='Data Entry'!$E$86
t_1_left ='Data Entry'!$E$102
t_2 ='Data Entry'!$E$98
t_2_left ='Data Entry'!$E$108
t_3_left ='Data Entry'!$E$115
t_corr ='Data Entry'!$D$74
t_found ='CIPM Air Density'!$D$5
t_left ='CIPM Air Density'!$D$11
Tech ='Data Entry'!$F$23
Tech_Int ='Data Entry'!$J$23
ts ='Data Entry'!$B$49
ts_df ='Data Entry'!$I$49
tsc ='Data Entry'!$B$70
tx ='Data Entry'!$B$55
tx_df ='Data Entry'!$I$55
U_hr ='Data Entry'!$F$76
U_P ='Data Entry'!$F$75
U_t ='Data Entry'!$F$74
ub ='Uncertainty Analysis'!$B$125
UCL =Calculations!$C$46
uPa ='Uncertainty Analysis'!$B$119
uPr ='Data Entry'!$I$42
uPt ='Data Entry'!$I$16

524753224.xls Instructions Worksheet Page 16 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

6 Be sure to document all your changes on the Document


worksheet.
Range Names
Us ='Data Entry'!$E$42
Usc ='Data Entry'!$F$64
Usw ='Data Entry'!$F$59
Uts ='Data Entry'!$F$49
Utsc ='Data Entry'!$F$70
Utx ='Data Entry'!$F$55
Veff ='Uncertainty Analysis'!$I$138
Xnom ='Data Entry'!$F$12

524753224.xls Instructions Worksheet Page 17 of 44


REPORT OF CALIBRATION

Issued To:

Point of Contact:

Purchase Order Number:

Report Number:

Calibration Date:

Calibration Due Date:

This is to certify that the information contained in this report is true and correct as of the date of
calibration.

Dan Wright, Program Specialist 3 Date of Issue

Accredited by the Accreditation Authority for the specific scope of accreditation under lab code
Accreditation LOGO XXXXXX-X. This report may not be used to claim product endorsement by Accreditation Authority or
any other government agency, and may not be reproduced, except in full, without written approval
from the laboratory.

WAMRF-008, Rev. 19, 11/25/2014 Page 18 of 4


WSDA Weights and Measures Metrology Laboratory
Report Number: Calibration Date:

Artifact(s) Description
Test Item: Date Received:
Serial Number: ID/Asset Number:
Manufacture: Class Specification:
Condition: Material:

Calibration Information
Job Order #: Temperature: ºC
Metrologist: Pressure: mm Hg
Procedure: Humidity: % RH

Laboratory Reference Standards Used


Description Serial Number Cert. Number Cal Date Cal Due

Traceability Statement
The artifact(s) described in this report have been compared to the Standards of the State of Washington. The
Standards of the State of Washington are traceable to the National Institute of Standards and Technology (NIST)
and are part of a comprehensive measurement assurance program for ensuring continued accuracy and
measurement traceability within the level of uncertainty reported by this laboratory. The International System
of Units (SI) for mass is the kilogram (kg) (see Conversion Factors on page 3). The report number for this report
is the only unique report number to be used in referencing measurement traceability for the artifact(s)
described in this report.

Uncertainty Statement
The combined standard uncertainty includes uncertainties reported for the standard, uncertainties associated
with the measurement process, uncertainties for any observed deviations from reference values which are less
than surveillance limits, and other uncertainties associated with the particular artifact (i.e., material density,
air buoyancy corrections, etc.). The combined standard uncertainty is multiplied by a coverage factor, k, to give
the expanded uncertainty, which defines an interval with a 95.45 % level of confidence. The expanded
uncertainty presented in this report is consistent with NIST Technical Note 1297. Surface Roughness and
Magnetic testing has not been performed, therefore, there are no components for the effects of either in the
uncertainty budget.

Accreditation Statement
Accredited by the Accreditation Authority for the specified scope of accreditation under lab code XXXXXX-X.
This laboratory meets the requirements of ISO/IEC 17025 and ANSI/NCSL Z540-1.

WAMRF-008, Rev. 19, 11/25/2014 Page 19 of 4


WSDA Weights and Measures Metrology Laboratory
Report Number: Calibration Date:

Pertinent Information
● In-accordance-with ISO/IEC FDIS 17025, General Requirements for the Competence of Testing and Calibration
Laboratories, paragraph 5.10.4.4 ‘A calibration certificate (or calibration label) shall not contain any
recommendation on the calibration interval except where this has been agreed with the client. This
requirement may be superseded by legal regulations.’

● In-accordance-with Washington Administrative Code (WAC) Chapter 16-663, Service Agents -- Reporting, Test
Procedures, Standards And Calibration Of Weighing And Measuring Devices, Section 16-663-130, Adequacy of
standards and submission of standards for certification, paragraph 2, ‘… All standards used for servicing,
repairing and/or calibrating commercial weighing and measuring devices must be submitted at least every two
years for examination and certification…’

● The artifact(s) listed above have been found and/or left within the maximum permissible error for the
specification stated above, except as noted. An artifact is considered in-compliance when the correction plus
the measurement uncertainty is equal to or less than the maximum permissible error. RED print indicates an out-
of-compliance reading.

● “Conventional Mass” (CM), also known as ‘apparent mass”, values stated in this report correlate to a scale
verses 8.0 g/cm³ reference mass density and an air density of 1.2 mg/cm³ at 20 ºC. "True mass" values are based
on an explicit treatment of displacement volumes.

● All corrections stated in this report correlate to a “Conventional Mass” (CM), also known as ‘apparent mass”,
scale verses 8.0 g/cm³ reference mass density and an air density of 1.2 mg/cm3 at 20 ºC.
● The results listed in this report relate only to the artifacts described and extent of calibrations performed.

Conversion Factors
From NIST Special Publication 811, Guide for the Use of the International System of Units (SI)
Factors in boldface are exact
To convert from to multiply by
carat, metric to kilogram (kg) 2.0 E-04
grain (gr) to kilogram (kg) 6.479 891 E-05
ounce (avoirdupois) (oz) to kilogram (kg) 2.834 952 E-02
ounce (troy or apothecary) (oz) to kilogram (kg) 3.110 348 E-02
dram (apothecary) (dr) to kilogram (kg) 3.8879346 E-03
scruple (apothecary) (s) to kilogram (kg) 1.2959782 E-03
pennyweight (dwt) to kilogram (kg) 1.555 174 E-03
pound (avoirdupois) (lb) to kilogram (kg) 4.535 923 7 E-01

WAMRF-008, Rev. 19, 11/25/2014 Page 20 of 4


WSDA Weights and Measures Metrology Laboratory
Report Number: Calibration Date:

As Found / Left Calibration Results


Uncertainty
Conventional Degrees Assumed
True Mass of Assumed Air Density
Nominal Mass ID Mass Uncertainty k-factor of MPE Density
Correction Density (g/cm³)
Correction Freedom (g/cm³)
(g/cm³)

As Left Calibration Results


Uncertainty
Conventional Degrees Assumed
Nominal True Mass of Assumed Air Density
ID Mass Uncertainty k-factor of Tolerance Density
Mass Correction Density (g/cm³)
Correction Freedom (g/cm³)
(g/cm³)

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Data Entry Report Number:

Customer Information
Customer ID

PO#

POC
Phone

Calibration Item & Measurement Information


Item Description

Manufacture Date Received

Serial Number Nominal Value (pick from list)

ID/Asset Number Artifact Material

Artifact Condition Job Order Number

Balance ID Balance Resolution Bal Unit


Assumed Density (g/cm³) Unc. Of Assumed Density (g/cm³)

Class Specification Maximum Permissible Error (mg)

Measurement Type Measurement Option

Use SOP 2 ABC?

Degrees of Freedom

Accredited U (e.g, NVLAP,A2LA, etc.) df k factor

Was a Calibration Interval Requested or is one Required? What is the Interval (months)?

Calibration Date Technician Initials


Reported corrections and uncertainty in nominal value units or metric units?

Standards Used
Note: If the 'Calibration Due' date turns RED the standard calibration is void, calibrate before use.

Description Serial Number Report Number Calibration Date Calibration Due

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Data Entry Report Number:

Mass Standard(s) Data


Enter the information for the reference weight(s) (S)
Degrees of u(ρr)
Correction Density ρa1
Std ID Nominal Mass (g) Us (mg) k factor Freedom (g/cm³)
(mg) (g/cm³) (g/cm³)
(df) k=1
S1
S2
S3
S=
Enter the information for the tare weight(s) (t s)

Degrees of
Density
Std ID Nominal Mass (g) Correction (mg) Uncertainty (mg) k factor Freedom
(g/cm³)
(df)

ts1
ts2
ts3
ts4
ts = 1
Enter the information for the tare weight(s) (tx)
tx1
tx2
tx3
tx4
tx = 1
Enter the information for the sensitivity weight(s) (sw)
sw1
sw2
sw =
Enter the information for the control standard weight(s) (S c)
Sc1
Sc2
Sc3
Sc =
Enter the information for the tare weight(s) carried with the control standard weight(s) (t sc)
tsc1
tsc2
tsc3
tsc4
tsc = 1

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Data Entry Report Number:

Environmental Standard(s) Data


Parameter Correction Uncertainty k factor Unit
Temperature (t) ºC
Barometric Pressure (P) mm Hg
Humidity (hr) % RH

Uncertainty Evaluation
Criteria: NIST HB 143, Table 4, "The expanded uncertainty
must be less than 1/3 of the maximum permissible error."
1/3 of mpe =
Expanded Uncertainty =
Precision Test (Pn) =

As Found Measurements
Artifact Measurement

Start Time t (ºC) P (mm Hg) hr (% RH)


Observation No. Weights Balance Units:

Duplicate Measurement

Observation No. Weights Balance Units:

1
2

Finish Time t (ºC) P (mm Hg) hr (% RH)

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Data Entry Report Number:

As Left Measurements
Artifact Measurement
Start Time t (ºC) P (mm Hg) hr (% RH)
Observation No. Weights Balance Units:
1
2
3
4
Finish Time t (ºC) P (mm Hg) hr (% RH)
Duplicate Measurement
Observation No. Weights Balance Units:
1
2
3
4
Finsh Time t (ºC) P (mm Hg) hr (% RH)

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Control Chart Information


Note: Copy and Paste Appropriate Row(s) to Control Chart

X-Chart Information

Start Air Finish Air Start Finish Start Finish


Technician Report Balance Temperature Temperature Pressure Pressure Humidity Humidity
Initials Date Number Csc vs 8.0 () Description (ºC) (ºC) (g/cm³) (g/cm³) (% RH) (% RH)

R-Chart Information

Cx vs 8.0 Cx vs 8.0 Start Air Finish Air Start Finish Start Finish
Technician Report (corr. 1) (corr. 2) Balance Temperature Temperature Pressure Pressure Humidity Humidity
Initials Date Number () () Description (ºC) (ºC) (g/cm³) (g/cm³) (% RH) (% RH)
As Found
As Left

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Calculations

Air Density Calculation

Air density results are rounded to 9 digits (g/cm³)


As Found Air Density
tAVERAGE = ºC
PAVERAGE = mm Hg
hrAVERAGE = % RH
ρa = 0.0012 g/cm³

As Left Air Density


tAVERAGE = ºC
PAVERAGE = mm Hg
hrAVERAGE = % RH
ρa = g/cm³

Standard(s) Conventionals
Reference Standard (CMs) = g
Tare w/Reference Standard (CMts) = g
Check Standard (CMsc) = g
Tare w/Check Standard (CMtsc) = g
Tare w/Unknown Weight (CMtx) = g
Sensitivity Weight (CMsw) = g

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Calculations

Measurement Calculations
As Found Determinations Check Standard Determinations
Mx = g Msc g
Cx = g Csc g
CMx vs 8.0 g/cm³ = g CMsc vs 8.0 g/cm³ = g
Cx vs 8.0 g/cm³ = g Csc vs 8.0 g/cm³ = g
As Left Determinations

g g

g g

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Calculations

Maximum Permissible Error Compliance Evaluation


Criteria: The conventional mass shall not differ more than the maximum permissible error minus the
expanded uncertainty from the nominal value of weight. (NIST HB 105-1, ASTM E 617 & OIML R 111)
MPE (�) =
Expanded Uncertainty (�) =
As Found Cx vs 8.0 =

Measurement Assurance Evaluations


Criteria: If the value for standard deviation is outside of the warning limit but inside the control limit,
a second set of duplicate calibrations should be made. (NISTIR 7383,SOP 20, 4.3.4)

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Calculations

Report Conventional Mass Correction and Uncertainty (uc*k) As Follows:

Mass corrections and uncertainties are rounded according to NISTIR 6969, GLP 9

Mass Values in Nominal Value Units


Nominal Value =
As Found True Mass Correction (Cx) =
As Left True Mass Correction (Cx) =
As Found Conventional Mass Correction =
As Left Conventional Mass Correction =
Effective Degrees of Freedom =
k factor =
Uncertainty (uc*k) =
MPE (�) =
Assumed Density = g/cm³
Uncertainty of Assumed Density = g/cm³
As Found Air Density = 0.0012 g/cm³
As Left Air Density = g/cm³

Mass Values in Metric Units


Nominal Value =
As Found True Mass Correction (Cx) =
As Left True Mass Correction (Cx) =
As Found Conventional Mass Correction =
As Left Conventional Mass Correction =
Effective Degrees of Freedom =
k factor =
Uncertainty (uc*k) =
MPE (�) =
Assumed Density = g/cm³
Uncertainty of Assumed Density = g/cm³
As Found Air Density = 0.0012 g/cm³

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Calculations

As Left Air Density = g/cm³

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

Specify Procedure
NISTIR 6969, SOP 4,Weighing by Double Substitution

Specify Equation(s)
Double Substitution Optional Sequence A (SXXS) w/o Air Buoyancy Correction
O2 - O1 ) + ( O3 - O 4 ) CMsw
C x = C s + CMt - CM tx +
s [( 2 ][
O3 - O 2
+ Ns - N x
]
Double Substitution Optional Sequence B (XSSX) w/o Air Buoyancy Correction

O1 - O2 ) + ( O 4 - O3 ) CMsw
C x = C s + CMt - CM t +
s x [( 2 ][
O3 - O 2
+ Ns - N x
]
Double Substitution Optional Sequence A (SXXS) with Air Buoyancy Correction

ρa

Mx =
(
Ms 1 -
ρa
ρs ) + Mt
s ( 1 -
ρa
ρts ) - Mt
x ( 1 -
ρa
ρt x ) [+
( O 2 - O 1 ) + ( O3 - O 4 )
2 ] [ (
M sw 1 -

O3 - O 2
ρ sw )
]
ρa
( 1 -
ρx )

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

Double Substitution Optional Sequence B (XSSX) with Air Buoyancy Correction

ρa

][ ]
ρa ρa ρa ( O 1 - O 2 ) +( O4 - O 3 ) (
M sw 1 -
ρsw )
Mx =
Ms 1 -
( ρs ) + Mt
s ( 1 -
ρt
s
) - Mt
x ( 1 -
ρt
x
) [
+
2 O3 - O 2
ρa
( 1 -
ρx )
Conventional Mass
ρn

CMx =
Mx ( 1 -
ρx )
ρn
( 1 -
8.0 )
where
S= standard weight
X= weight calibrated
t= small calibrated tare weight, A subscript s or x is used to indicate the larger weight with which it is associated
sw = small calibrated weight used to evaluate the sensitivity of the balance

M = the mass (true mass) of a specific weight. Subscripts s, x, t, sw are used to identify the weight (equals Nominal plus Correction)

N = the nominal value of a specific weight. Subscripts s, x, are used to identify the weight.
C = the correction for a specific weight. Subscripts s, x, are used to identify the weight.
CM = the conventional mass of a specific weight. Subscripts s, x, t, sw are used to identify the weight.
ρa = density of air at time of calibration
ρn = density of normal air (1.2 kg/m³)
ρ = density of masses; subscripts s, x, ts, tx, sw are used to identify the weight

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

CIPM 2007 Air Density Formula, NISTIR 6969, SOP 2, Paragraph 8.2, Option B
pM a Mv
ρ=
ZRT ( (
1−x v 1−
Ma ))
ρsv
x v =( h/100 ) f
p

p p2
Z =1− a 0 + a1 t+ a2 t 2 + ( b0 +b1 t ) x v + ( c 0 + c1 t ) x 2v + 2 ( d + ex 2v )
[ ]
T T
where
Mv = 18.015 28 (17) x 10-3 kg m-3
Ma = molar mass of the air within laboratory 28.965 46 x 10-3 kg/mol
p = ambient barometric pressure in Pascal
T = ambient temperature in Kelvin
R = universal gas constant: 8.314 472 J mol-1 K-1
h = relative humidity in %
f = 1.000 62 + (3.14 x 10-8) p + (5.16 x 10-7) t2
t = ambient temperature in degrees Celsius
ρsv = 1 Pascal x exp (AT2 + BT + C + D/T)
A = 1.237 884 7 x 10-5 K-2
B = -1.912 131 6 x 10-2 K-1
C = 33.937 110 47
D = -6.343 164 5 x 103 K
a0 = 1.581 23 x 10-6 K Pa-1
a1 = -2.933 1 x 10-8 Pa-1
a2 = 1.104 3 x 10-10 K-1 Pa-1
b0 = 5.707 x 10-6 K Pa-1
b1 = -2.051 x 10-8 Pa-1
c0 = 1.989 8 x 10-4 K Pa-1
c1 = -2.376 x 10-6 Pa-1
d = 1.83 x 10-11 K2 Pa-2
e = -0.765 x 10-8 K2 Pa-2

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

Uncertainty of the Air Buoyancy Correction, OIML R111-1:2004(E), (C.6.3-1)


2 2 2
ρr −ρt
( ρ −ρ () ) [ ( ( u) ( ρ )2 u ρ2t
2 u 2 ( ρr ) 2
u ( ρr )
c
2
u=m [[
u2b = mcr r
cr ρ r ρ t
ρ ρ
t
u ρ a + m cr ρa −ρ0
a
r t
)] ρ ) ]
u ( ρ ) +[ m ( ρ − ]]
cr a
ρ 0ρ4t
m2crt ρa −2ρ0 ρa −ρ0
−2
cr aa
ρ
( +m ( ρ) [ ( −ρ ) [ () ρ −( ρa 1) −20 )(]ρ −ρ
+
0 0
−ρ
t4
a 1ρ 4r 0 ) ]
ρ
r4
where
mcr = conventional mass of the reference weight (g)
pr = density of the reference weight (g/cm³)
u(pa) = uncertainty associated with the variance of the air density (g/cm³)
pt = density of weight being tested
pa = density of moist air (g/cm³)
p0 = density of air as a reference value equal to 0.0012 g/cm³
u(pr) = uncertainty associated with the density of the reference weight (g/cm³)
u(pt) = uncertainty associated with the density of the test weight (g/cm³)
pa1 = air density during (previous) calibration of the reference weight (g/cm³)

Uncertainty associated with the variance of the air density, OIML R111-1:2004(E), (C.6.3-3)
2 2 2
ρ ρ ρ
2
u ( ρ )=u a
2

F+ ( ∂
∂p
a
u p )( +

∂t
a
u t )( ∂
+ ∂ hr
a
u hr )
where
uF = uncertainty of the CIPM formula

∂ a
=
ρ10-5ρaPa-1
∂p
∂ ρ= a 3.4 x 10-3K-1ρa
∂t

∂ a ρ
= 10 ρa
-2

∂ hr

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

Estimating the Magnitude of the Air Buoyancy Correction, NISTIR 6969, SOP 2, Paragraph 2.3.2.
1 1
MABC =m0 ( ρa −ρn )
( −
ρ x ρs )
where
m0 = nominal mass in grams
ρa = density of air at time of measurement or normally found in the laboratory, i.e., 0.00119 g/cm³
ρn = density of "normal" air, i.e., 0.0012 g/cm³
ρX = density of the unknown mass
ρS = density of the mass standard

Standard uncertainty for disparity due to standard deviation over time, NISTIR 6969, SOP 29, Paragraph 3.2.5.4.
bias 1
ud = or more simply : 0. 29 d , where d is the bias
2 √3

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

Identify Components
Component Description Reference
s(p) Uncertainty associated with the measurement NISTIR 6969, SOP 29, Para. 3.2.1.1. Standard deviation of a check
process using a check standard standard from a control chart

s(p) Uncertainty associated with the measurement process NISTIR 6969, SOP 29, Para. 3.2.1.2. Standard deviation from a set of
from the average range of several sets of replicate measurements and NISTIR 6969, Statistical Techniques,
measurements paragraphs 8.3 & 8.4, Pooled standard deviation from standard
deviation for each set of replicates from a control chart

u(s) Uncertainty associated with the mass standards Calibration Report divided by the k factor
u(b) Uncertainty of the air buoyancy correction OIML R 111-1: 2004(E), para. C.6.3, formula (C.6.3-1)
u(pa) Uncertainty associated with the variance of the OIML R 111-1: 2004(E), para. C.6.3, formula (C.6.3-3)
air density

u(F) Uncertainty associated air density equation, 2007 CIPM Air Density paper, 22 ppm
NISTIR 6969, SOP 2, Option B

u(t) Uncertainty associated with device used to Calibration Report divided by the k factor
take the air temperature

u(hr) Uncertainty associated with device used to Calibration Report divided by the k factor
take the relative humidity

u(P) Uncertainty associated with device used to Calibration Report divided by the k factor
take barometric pressure

u(ρr) Uncertainty associated with the density of the Use reported or typical from manufactures stated density (typical
reference weight range noted by NIST Mass Group on densities of 8.0 g/cm³ is 0.008 %
or 0.00064 g/cm3)

u(ρt) Uncertainty associated with the density of the Use reported or typical from manufactures stated density (typical
test weight range is 0.05 g/cm³). (See OIML R111-1:2004(E) B.7.9 Test Method
F)

u(MABC) Uncertainty associated with the magnitude of the air NISTIR 6969, SOP 2, Paragraph 2.3.2., Estimating the Magnitude of
buoyancy correction where air buoyancy is not used the Air Buoyancy Correction

u(d) Standard uncertainty for disparity due to standard NISTIR 6969, SOP 29, Assignment of Uncertainty, para. 3.2.5.4.
drift over time (0.29 * d - where d is the observed standard bias)

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

Quantify & Convert


Standard Deviation (drift/bias) Test
Criteria: Can be combined if less than the combined uncertainty,
not including the drift/bias. (NISTIR 6969, SOP 29, para. 3.2.5.2.2)
uc (mg) =
Drift/Bias (mg) =

Uncertainty of the Air Buoyancy Correction


mcr = g
pr = g/cm³
pt = g/cm³
u(pa) = g/cm³
pa = 0.0012 g/cm³
p0 = 0.0012 g/cm³
u(pr) = g/cm³
u(pt) = g/cm³
pa1 = g/cm³
u2 b = mg

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

Combined & Expand

Component Reported
Symbol Unc Factor to Standard Unc % Degrees of
Component Description (mg) Type Distribution Normalize (mg) Contribution Freedom
Standard Deviation from CC s(p) 0 A Normal 1 0 1
Report U divided by k-factor u(s) 0 B Normal 1 0 1
Report U divided by k-factor u(ts) 0 B Normal 1 0 1
Report U divided by k-factor u(tx) 0 B Normal 1 0 1
Report U divided by k-factor u(sw) 0 B Normal 1 0 1
Magnitude of ABC u(MABC) 0 B Rectangular 1.732050808 0 1
Air Buoyancy Correction Unc u(b) 0 B Rectangular 1.732050808 0 1
Standard Drift/Bias u(d) 0 B Rectangular 3.464101615 0 1
Combined U (uc) = mg
Effective Degrees of Freedom, Welch-Satterthwaite formula, NIST Technical Note 1297, (B-1) (v eff) =
k factor =
Expanded U (uc*k) = mg
NVLAP Effective Degrees of Freedom (veff) =
NVLAP k factor =
NVLAP U = mg
Final Effective Degrees of Freedom (veff) =
Final k factor =
Final U (uc*k) = g

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Uncertainty Analysis

Value in mg
Uncertainty Analysis
SOP 4 Double Substitution Calibration
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
s(p) u(s) u(ts) u(tx) u(sw) u(MABC) u(b) u(d)
Impact Components

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

CIPM Air Density


Air Density, SOP 2, Option B, 2012 (CIPM 2007)
Air Density For As Found Measurement Observations
Barometric Pressure (mm Hg)
Temperature (ºC)
Relative Humidity (%)
Calculated Air Density (mg/cm³)

Air Density For As Left Measurement Observations


Barometric Pressure (mm Hg)
Temperature (ºC)
Relative Humidity (%)
Calculated Air Density (mg/cm³)

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Tables & Lists

Class Specification Measurement Option Lookup Table Measurement Option Lookup Table
Dropdown List (Meas_Option) (Sc_Meas_Option)
(Class_Spec_List)

ASTM E 617, Class 000 Option A (SXXS) S + ts X + tx X + tx + sw S + ts + sw Option A (SXXS) S + ts Sc + tsc Sc + tsc + sw S + ts + sw
ASTM E 617, Class 00 Option B (XSSX) X + tx S + ts S + ts + sw X + tx + sw Option B (XSSX) Sc + tsc S + ts S + ts + sw Sc + tsc + sw
ASTM E 617, Class 0
ASTM E 617, Class 1
ASTM E 617, Class 2
ASTM E 617, Class 3
ASTM E 617, Class 4
ASTM E 617, Class 5
ASTM E 617, Class 6
ASTM E 617, Class 7
NIST HB 105-1, Class F
NIST HB 105-1, Class E1
NIST HB 105-1, Class E2
NIST HB 105-1, Class F1
NIST HB 105-1, Class F2
NIST HB 105-1, Class M1-2
NIST HB 105-1, Class M2
NIST HB 105-1, Class M2-3
NIST HB 105-1, Class M3
Not Specified
OIML R 111, Class E1
OIML R 111, Class E2
OIML R 111, Class F1
OIML R 111, Class F2
OIML R 111, Class M1
OIML R 111, Class M1-2
OIML R 111, Class M2
OIML R 111, Class M2-3
OIML R 111, Class M3
User Specified

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Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Tables & Lists

Conversion Table
(ConvTable) &
Nominal Value Unit
(Nom_Val_List)

Nominal Value (pick from list) Nominal Value (g) True Mass As Found True Mass As Left CM As Found CM As Left Uncertainty (k=) Tolerance
Nominal Value (carat) #DIV/0! #DIV/0! 0
Nominal Value (grain) #DIV/0! #DIV/0! 0
Nominal Value (avdp. ounce) #DIV/0! #DIV/0! 0
Nominal Value (apoth. ounce) #DIV/0! #DIV/0! 0
Nominal Value (apoth. dram) #DIV/0! #DIV/0! 0
Nominal Value (apoth. scruple) #DIV/0! #DIV/0! 0
Nominal Value (troy ounce) #DIV/0! #DIV/0! 0
Nominal Value (pennyweight) #DIV/0! #DIV/0! 0
Nominal Value (avdp. pound) #DIV/0! #DIV/0! 0
Nominal Value (gram) #DIV/0! #DIV/0! 0
Nominal Value (kilogram) #DIV/0! #DIV/0! 0
Nominal Value (milligram) #DIV/0! #DIV/0! 0

524753224.xls Tables and Lists Worksheet Page 43 of 44


Weighing By Double Substitution WAMRF-008, Rev. 19, 11/25/2014

Conversion Table
(ConvTable) &
Nominal Value Unit
(Nom_Val_List)

Symbol
carat
gr
oz
oz ap
dr ap
s ap
oz t
pwt
lb
g
kg
mg

524753224.xls Tables and Lists Worksheet Page 44 of 44

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