Scribd
Upload
109 views2 pages

DPPS-3 - Chemical Kinetics

This document contains 10 practice problems related to the topic of chemical kinetics from a fresher course for the IIT JEE (Main & Advanced) exam. The problems cover concepts such as reaction order, rate constants, integrated rate laws, and the effect of catalysts and pH on reaction rates. Sample calculations are provided for determining rates of reaction from concentration-time graphs and for deriving rate laws from experimental data.

Uploaded by

Shrish Pratap
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
109 views2 pages

DPPS-3 - Chemical Kinetics

This document contains 10 practice problems related to the topic of chemical kinetics from a fresher course for the IIT JEE (Main & Advanced) exam. The problems cover concepts such as reaction order, rate constants, integrated rate laws, and the effect of catalysts and pH on reaction rates. Sample calculations are provided for determining rates of reaction from concentration-time graphs and for deriving rate laws from experimental data.

Uploaded by

Shrish Pratap
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

CAREER POINT

Fresher Course for IIT JEE (Main & Advanced)–2017


DAILY PRACTICE PROBLEM SHEET
Course : Fresher(XL) Batch Subject : Chemistry DPPS-3
Topic : Chemical Kinetics
Q.1 Consider a reaction A + B  C, in which both reactants are in the same phase may be
(A) unimolecular elementary reaction (B) Exothermic
(C) Heterogeneous (D) Photochemical

Q.2 In the following gaseous phase first order reaction


A(g)  2B(g) + C(g)
initial pressure was found to be 400 mm of Hg and it changed to 1000 mm of Hg after 20 min. Then
(A) Half life for A is 10 min
(B) Rate constant is 0.0693 min–1
(C) Partial pressure of C at 30 min is 350 mm of Hg
(D) Total pressure after 30 min is 1150 mm of Hg

Q.3 Identify the true statement(s)


(A) A catalyst is chemically unchanged at the end of a reaction
(B) A catalyst may appear in the kinetic rate equation of the reaction
(C) A catalyst will not affect the composition of an equilibrium mixture
(D) A catalyst cannot cause a non-spontaneous (G > 0) reaction to proceed

k1sec–1
Q.4 For the reaction A B following graph is given,
k2sec–1
k1 = 4 × 10–2 sec–1. Which is/are correct statement (s) (n 2 = 0.7, n 8/7 = 0.14)

2.0
1.6 B
Conc.
(M)
0.4 A
time (in sec) 
(A) Equilibrium constant is 4.0
(B) Time taken for the completion of 50% of equilibrium conc. of B is 14 sec.
(C) Time taken for the completion of 10% of initial conc. of A is 2.8 sec.
(D) Rate constant of backward reaction is 10–2 sec–1

Q.5 Following is the plot between concentration of A versus time for the reaction 2A  B. Calculate rate of
reaction at 10s.
[A]

135º
t
10s
CAREER POINT, CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744 -5151200 www.careerpoint.ac.in Page # 1
Q.6 Following is the plost between concentration of B versus time for the reaction 3A 2B. Calculate rate of
reaction at 5s.
[B]

45º

t
5s
Q.7 The inversion of sucrose proceeds with constant half life of 600 minute at pH = 5 for any concentration of
sucrose. However, if pH = 6, the half life changes to 60 minute. Derive the rate law for inversion of sucrose.

Q.8 The acid catalysed hydrolysis of an organic compound A at 303 K has time for half change of 100 minute when
carried out in a buffer solution at pH = 5 and 10 minute when carried out at pH = 4. Both time of half change are
d[ A]
independent of the initial concentration of A. if the rate constant k is given by  k[ A ]x [ H ]y , what are the
dt
values of x and y ?

Q.9 Show that for a first-order reaction R  P the concentration of product can be represented as a function of
time by-
[P] = a + bt – ct2 + ………
And express a, b and c in terms of [R]0 and k.
[ R ]0 K 2
(A) a = 0 (B) b = [R]0 K (C) c  (D) a = [R]0 K
2

Q.10 The high temperature ( 1200K) decomposition of CH3 COOH(g) occurs as follows as per simultaneous 1st
order reactions
k1
CH 3 COOH  CH 4  CO 2
k2
CH 3COOH  CH 2 CO  H 2 O
What would be the % of CH 4 by mole in the product mixture (excluding CH3COOH) ?
50k1 100k1 200k1
(A) (B) (C) (D) it depends on time
(k1  k 2 ) (k1  k 2 ) (k1  k 2 )

ANSWERS
1 1
1. (B,C,D) 2. (A,B,C,D) 3. (A,B,C,D) 4. (A,B,C,D) 5. M/s 6.  M / s
2  2

7. Rate = K[Sucrose]1[H+]º 8. x = 1, y = 1 9. (A, B, C) 10. (A)

CAREER POINT, CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744 -5151200 www.careerpoint.ac.in Page # 2

You might also like