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Gravimetry - Activity

The document discusses several gravimetric analysis problems involving the precipitation of silver halides from mixtures of salts. It includes questions about: 1) Converting between weights of related metal oxides and determining sample weights needed for percentage calculations. 2) Calculating equivalent weights of compounds based on a given weight of one component. 3) Determining weights of possible precipitates given weights of samples and precipitates. 4) Calculations to find percentages of halides in mixtures based on weights before and after precipitation and conversion reactions.
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0% found this document useful (0 votes)
368 views1 page

Gravimetry - Activity

The document discusses several gravimetric analysis problems involving the precipitation of silver halides from mixtures of salts. It includes questions about: 1) Converting between weights of related metal oxides and determining sample weights needed for percentage calculations. 2) Calculating equivalent weights of compounds based on a given weight of one component. 3) Determining weights of possible precipitates given weights of samples and precipitates. 4) Calculations to find percentages of halides in mixtures based on weights before and after precipitation and conversion reactions.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Gravimetry - Activity

Gravimetric Factor-

1. a. How many grams of Mn3O4 can be obtained from 1.00 g MnO2?

b. how many ounces of Mn3O4 can be obtained from 1.00 lb MnO2?

c. What wt of Mn ore should be taken so that the percentage of MnO2 in the ore can be found by

multiplying by 5 to the number of centigrams og Mn3O4

2. What weight of As2O3 and of CuO are equivalent to 1.000 g Paris green, Cu3(AsO3)2.Cu(C2H3O2)2

( Formula weight = 1014)

Analysis of soluble salts

1. If a sample of silver coin weighing 0.2500 g gives a precipitate of AgCl weighing 0.2991 g, What wt

of AgI could have been obtained from the same wt of sample?

2. If 1.00 g of a mixture of AgCl and AgBr contain 0.6635 g of Ag, what is the percentage of bromine?

3. A precipitate of AgCl + AgBr weighs 0.8132 g. On heating on a current of Cl2, the AgBr is converted to

AgCl, the mixture loses 0.1450 g in wt. Find the percentage Cl in the original sample.

Ans. 6.10 %

4. A sample of soluble salts weighs 1.200 g and contains chloride , bromide, and iodide. With AgNO3,
a precipitate is obtained which weighs o.4500 g. On heating this precipitate in Cl2 gas, the AgBr and
AgI are converted to AgCl, and the precipitate then weighs 0.3300 g. A similar sample , when treated
with PdI2 , and this precipitate weighs 0.0900 g. Find the approximate percentage of chlorine, bromine,
and iodine in the original sample ? ( ans. Cl= 0.40% , Br = 11 % , I =5.3 %)

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