CONFIDENTIAL ASIJUN 2019/CMT458/CHM458 UNIVERSITI TEKNOLOGI MARA FINAL EXAMINATION ‘COURSE : CHEMICAL THERMODYNAMICS COURSE CODE : CMT458/CHM458 EXAMINATION : JUNE 2019 TIME : 2HOURS INSTRUCTIONS TO CANDIDATES 1 This question paper consists of four (4) questions. 2 ‘Answer ALL questions in the Answer Booklet. Start each answer on a new page. 3 Do not bring any material into the examination room unless permission is given by the invigitator. 4 Please check to make sure that this examination pack consists of : ji) the Question Paper )_an Answer Booklet - provided by the Faculty ) a Property Table booklet — provided by the Faculty 5. Answer ALL questions in English DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO This examination paper consists of 6 printed pages © Hak ipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 2 ASIJUN 2019/CMT458/CHM458 QUESTION 1 a) List four (4) types of thermodynamic system. (4 marks) b) Explain the differences between closed system and isolated system. (4 marks) ©) Use the property table to fill he missing properties and phase descriptions in the following table of water. No. | Temperature, | Pressure, | Enthalpy, Qual kPa kJikg x i) 500 | 2000 ii) —_ 1.0 aay | iil) 300 800_ iv) 200 5000 — v) 410 a Saturated liquid (8 marks) 4) A rigid tank contains 20 kg of water at 90 °C. If 18 kg of the water is in the liquid form and the rest is in the vapor form. Determine: i) The pressure in the tank. (1 mark) ii) The volume of the tank. (3 marks) QUESTION 2 a) Consider the following properties for one mole of an ideal gas (Cv = 1.5R). The gas undergoes the following processes: State 1 to state 2: Reversible isothermal expansion State 2 to state 3: Isobaric compression State 3 to state 1: Reversible adiabatic compression Given that, R = 0.0821 L-atm/mol-K and y = 1.67. _ _| Pressure, atm Volume, L ‘Temperature, K | State 7 15 2 Th | [State 2 2 V2 Ta | State 3 Ps Vs 50.3 | © Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 3 ASIJUN 2019/CMT458/CHM458 i) Calculate the missing values for T;, Ta, V2, Vs and Ps. (4 marks) ii) Sketch the above process on a P-V diagram. (2 marks) For state 3 to 1 only, identify the value of heat transfer (Q), work (W) and internal energy (AU) (3 marks) b) Based on the reaction and the following data: NHiNOs(s)_ ——* NHs* (aq) + NOs(aq) [Compound | AHP (kJ moh" ‘AS* J mol *K [NH.NO.(s) -365.56 151.08 [NHe (aq 7132.51 113.4 “| -NOs(aq) 205.0 146.4 _| i) Calculate AH*, and AS” for the reaction at 298 K. (4 marks) ii) Find AG° for the above reaction. (2 marks) iii) State whether this reaction is spontaneous or non-spontaneous (1 mark) c) A Carnot heat engine receives 300 ki of heat per cycle from high temperature source at 650 °C and rejects heat to low temperature sink at 50 °C. Determine: i) The thermal efficiency of this Carnot heat engine. (2 marks) ii) Amount of heat rejected to the sink per cycle. (2 marks) QUESTION 3 a) State the entropy changes when the following condition occurs? i) Solid met. ii) Liquid vaporizes. ili) Gas liquefies. iv) Liquid freeze. (4 marks) © Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 4 ASIJUN 2019/CMT458/CHM458 b) Apiston cylinder device contains 2 kg of water at 100 kPa and 70 °C. Heat crosses into the system at constant pressure until the system's temperature increases to 150°C. The temperature of the surrounding is 25 °C. Determine’ i) Initial and final phase (2 marks) ji) The entropy changes for this process. (2 marks) ii) The net entropy changes of the universe due to this process. (3 marks) c) Given the following equations: Ha(g) + Clg) —» 2HCI(g) AH; = -185 kd CaHa(g) + HCI) > C2HsCi() AHa = -65 kJ CaHsCl(g) + He(g) > C2HsC\() ‘Hs = -140 kd Calculate the enthalpy of reaction for: CoHa(g) + Ch(g) —>» CzHsCKg) + HCI(g) (4 marks) d) A copper block with a volume of 1L is heated at 500 °C_and then cooled in a 200 L oil bath initially at 20 °C. Assuming no heat transfer to the surrounding, determine the final equilibrium temperature. (Assume that Ccopper = 0.42 kuikg, K and Car=1.80 kJ/kg.K. Given density copper = 8.9 g/cm®, density oil 0.91 g/cm?) [Hint: 1 g/cm? =1000 kg/ m*] (5 marks) QUESTION 4 a) Define third law of thermodynamics. (2 marks) b) Give three examples on the usage of the third law of thermodynamics. (3 marks) c) Formaldehyde at 1 atmosphere (atm) has a boiling point of 179 °C while the critical point at 46 atm is 422 °C. By using the Clausius-Clapeyron equation, determine the enthalpy (4H) for the formaldehyde system. (5 marks) d) From Helmhotz relation, show dA = -SdT — PdV (3 marks) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,CONFIDENTIAL 5 ASIJUN 2019/CMT458/CHM458 e) From the first law of thermodynamic statement (AU = QW), prove the entropy change of an ideal gas can be derived as. AS = 8° + Rin 2 4 (7 marks) END OF QUESTION PAPER (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL