Page 1 ( 8 )

Issue date: 08/24/2017

Version: 2 (08/24/2017)

SAFETY DATA SHEET

In accordance with 29 CFR 1910.1200

Product: Cheesecake flavor 342331

Version: 2

Section 1. Identification of the substance or the mixture and of the supplier

1.1 Product Identifier

Product identifier: Cheesecake flavor 342331

Other identifiers: None

1.2 Relevant identified uses of the substance of mixture and uses advised against

Product uses: Flavours

1.3 Details of the supplier of the safety data sheet

Company name: Perfumer's Apprentice

Company address: 170 Technology Circle
Scotts Valley
CA 95066
USA
Contact: Elisabeth Hanson
E-Mail address: [email protected]
Company phone: +1 (831) 346 7234
1.4 Emergency telephone number

Emergency phone: +1 (831) 346 7234

Section 2. Hazards identification

2.1 Classification of the substance or mixture

Class and category of Flammable Liquid, Hazard Category 4

danger:
Skin Corrosion / Irritation Category 1B
Eye Damage / Irritation Category 1
Sensitization - Skin Category 1
H227, Combustible liquid.
H314, Causes severe skin burns and eye damage.
H317, May cause an allergic skin reaction.

2.2 Label elements

Signal word: Danger

Hazard statements: H227, Combustible liquid.

H314, Causes severe skin burns and eye damage.
H317, May cause an allergic skin reaction.

Precautionary P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking.
statements: P260, Do not breathe vapour or dust.

Perfumer's Apprentice, 170 Technology Circle, Scotts Valley, CA, 95066, USA
 Page 2 ( 8 )

Issue date: 08/24/2017

Version: 2 (08/24/2017)

SAFETY DATA SHEET

In accordance with 29 CFR 1910.1200

Product: Cheesecake flavor 342331

Version: 2

P264, Wash hands and other contacted skin thoroughly after handling.
P272, Contaminated work clothing should not be allowed out of the workplace.
P280, Wear protective gloves/eye protection/face protection.
P301/330/331, If swallowed: Rinse mouth. Do not induce vomiting.
P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304/340, IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310, Immediately call a POISON CENTER or doctor/physician.
P333/313, If skin irritation or rash occurs: Get medical advice/attention.
P363, Wash contaminated clothing before reuse.
P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction.
P403/235, Store in a well-ventilated place. Keep cool.
P405, Store locked up.
P501, Dispose of contents/container to approved disposal site, in accordance with local
regulations.

Pictograms:

Other hazards: None

Section 3. Composition / information on ingredients

3.2 Mixtures

Contains:

Name CAS EC % GHS Classification

FL 4-ATO 4-SCI 1B-EDI 1;H227-H302-
Butyric acid 107-92-6 203-532-3 5-<10%
H314
Hexanoic acid 142-62-1 205-550-7 1-<5% SCI 1C-EDI 1;H314
Octanoic acid 124-07-2 204-677-5 0.1-<1% SCI 1C-EDI 1;H314

The exact percentage concentrations of components are being withheld as a trade secret.

Substances with Community workplace exposure limits, not listed above:

Name CAS EC %
Propylene glycol 57-55-6 200-338-0 90-95%

Perfumer's Apprentice, 170 Technology Circle, Scotts Valley, CA, 95066, USA
 Page 3 ( 8 )

Issue date: 08/24/2017

Version: 2 (08/24/2017)

SAFETY DATA SHEET

In accordance with 29 CFR 1910.1200

Product: Cheesecake flavor 342331

Version: 2

Section 4. First-aid measures

4.1 Description of first aid measures

If swallowed: Rinse mouth. Do not induce vomiting.

IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Immediately call a POISON CENTER or doctor/physician.
4.2 Most important symptoms and effects, both acute and delayed

Causes severe skin burns and eye damage.

May cause an allergic skin reaction.

4.3 Indication of any immediate medical attention and special treatment needed

None expected, see Section 4.1 for further information.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable media: Carbon dioxide, Dry chemical, Foam.

5.2 Special hazards arising from the substance or mixture

In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds.

5.3 Advice for fire fighters:

In case of insufficient ventilation, wear suitable respiratory equipment.

Section 6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8.

6.2 Environmental precautions:

Keep away from drains, surface and ground water, and soil.

6.3 Methods and material for containment and cleaning up:

Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage
immediately by use of sand or inert powder. Dispose of according to local regulations.

Perfumer's Apprentice, 170 Technology Circle, Scotts Valley, CA, 95066, USA
 Page 4 ( 8 )

Issue date: 08/24/2017

Version: 2 (08/24/2017)

SAFETY DATA SHEET

In accordance with 29 CFR 1910.1200

Product: Cheesecake flavor 342331

Version: 2

6.4 Reference to other sections:

Also refer to sections 8 and 13.

Section 7. Handling and storage

7.1 Precautions for safe handling:

Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as
required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate
ventilation Do not eat, drink or smoke when using this product.

7.2 Conditions for safe storage, including any incompatibilities:

Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving
equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take
precautionary measures against static discharge.

7.3 Specific end use(s):

Flavours: Use in accordance with good manufacturing and industrial hygiene practices.

Section 8. Exposure controls/personal protection

8.1 Control parameters

Workplace exposure limits:

Ingredient CAS EC Description ppm mg/m³ Reference

Long-term exposure limit (8-hour

- - -
200-338- TWA reference period)
Propylene glycol 57-55-6
0 Short-term exposure limit (15-
- - -
minute reference period)

8.2 Exposure Controls

Eye / Skin Protection

Wear protective gloves/eye protection/face protection
Respiratory Protection
Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure
occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the
following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other
areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the
rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with
organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and
other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is
openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce
possible worker exposures. d) Use closed systems for transferring and processing this material.
Also refer to Sections 2 and 7.

Perfumer's Apprentice, 170 Technology Circle, Scotts Valley, CA, 95066, USA
 Page 5 ( 8 )

Issue date: 08/24/2017

Version: 2 (08/24/2017)

SAFETY DATA SHEET

In accordance with 29 CFR 1910.1200

Product: Cheesecake flavor 342331

Version: 2

Section 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance: Not determined

Odour: Not determined
pH: Not determined
Initial boiling point / range: Not determined
Flash point: 80.56 °C
Vapour pressure: Not determined
Relative density: 1.0290
Solubility(ies): Not determined
9.2 Other information: None available

Section 10. Stability and reactivity

10.1 Reactivity:

Presents no significant reactivity hazard, by itself or in contact with water.

10.2 Chemical stability:

Good stability under normal storage conditions.

10.3 Possibility of hazardous reactions:

Not expected under normal conditions of use.

10.4 Conditions to avoid:

Avoid extreme heat.

10.5 Incompatible materials:

Avoid contact with strong acids, alkalis or oxidising agents.

10.6 Hazardous decomposition products:

Not expected.

Section 11. Toxicological information

11.1 Information on toxicological effects

This mixture has not been tested as a whole for health effects. The health effects have been calculated using the
methods outlined in 29 CFR 1910.1200.

Causes severe skin burns and eye damage.

May cause an allergic skin reaction.
Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: >5000

Perfumer's Apprentice, 170 Technology Circle, Scotts Valley, CA, 95066, USA
 Page 6 ( 8 )

Issue date: 08/24/2017

Version: 2 (08/24/2017)

SAFETY DATA SHEET

In accordance with 29 CFR 1910.1200

Product: Cheesecake flavor 342331

Version: 2

Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity: Not Applicable
Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: Not Available
Inhalation Route: Not Available

Information about hazardous ingredients in the mixture

LD50/ATE LC50/ATE
Ingredient CAS EC LD50/ATE Oral LC50 Route
Dermal Inhalation

Butyric acid 107-92-6 203-532-3 1630 Not available Not available Not available

Refer to Sections 2 and 3 for additional information.

Section 12. Ecological information

12.1 Toxicity: Not available

12.2 Persistence and degradability: Not available

12.3 Bioaccumulative potential: Not available

12.4 Mobility in soil: Not available

12.5 Results of PBT and vPvB assessment:

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.

12.6 Other adverse effects: Not available

Section 13. Disposal considerations

13.1 Waste treatment methods:

Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty
containers should be taken to an approved waste handling site for recycling or disposal.

Section 14. Transport information

14.1 UN number: Not regulated

14.2 UN Proper Shipping Name: Not regulated
14.3 Transport hazard class(es): Not regulated
Sub Risk: Not regulated
14.4. Packing Group: Not regulated
14.5 Environmental hazards: Not environmentally hazardous for transport
14.6 Special precautions for user: None additional
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code:
Not applicable

Perfumer's Apprentice, 170 Technology Circle, Scotts Valley, CA, 95066, USA
 Page 7 ( 8 )

Issue date: 08/24/2017

Version: 2 (08/24/2017)

SAFETY DATA SHEET

In accordance with 29 CFR 1910.1200

Product: Cheesecake flavor 342331

Version: 2

Section 15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

None additional

15.2 Chemical Safety Assessment

A Chemical Safety Assessment has not been carried out for this product.

Section 16. Other information

Concentration % Limits: SCI 1B=90.91% SCI 1C=64.10% SCI 2=12.82% EDI 1=38.46% EDI 2=12.
82%
Total Fractional Values: SCI 1B=1.10 SCI 1C=1.56 SCI 2=7.80 EDI 1=2.60 EDI 2=7.80

Key to revisions:

2.1 Classification of the substance or mixture

Key to abbreviations:

Abbreviation Meaning
ATO 4 Acute Toxicity - Oral Category 4
EDI 1 Eye Damage / Irritation Category 1
FL 4 Flammable Liquid, Hazard Category 4
H227 Combustible liquid.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
P210 Keep away from heat, sparks, open flames and hot surfaces. - No smoking.
P260 Do not breathe vapour or dust.
P264 Wash hands and other contacted skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/eye protection/face protection.
P301/312 IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell.
P301/330/331 If swallowed: Rinse mouth. Do not induce vomiting.
IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with
P303/361/353
water/shower.
P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
P305/351/338
to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction.
P403/235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to approved disposal site, in accordance with local regulations.

Perfumer's Apprentice, 170 Technology Circle, Scotts Valley, CA, 95066, USA
 Page 8 ( 8 )

Issue date: 08/24/2017

Version: 2 (08/24/2017)

SAFETY DATA SHEET

In accordance with 29 CFR 1910.1200

Product: Cheesecake flavor 342331

Version: 2

SCI 1B Skin Corrosion / Irritation Category 1B

SCI 1C Skin Corrosion / Irritation Category 1C

The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions,
recommendations and/or suggestions are made without guarantee.

Perfumer's Apprentice, 170 Technology Circle, Scotts Valley, CA, 95066, USA