Jj, Science Lan, com Chemicals & Laboratory Equipment Personal Protection © Material Safety Data Sheet DL-Malic acid MSDS Section 1: Chemical Product and Company Identification Product Name: DL-Malic acid Contact Information Catalog Codes: SLM3994, SLM1849 Sciencelab.com, Inc. 14025 Smith Ra CASH: 617-48-1 Houston, Texas 77396 RTECS: ON7175000 Us Sales: 1-800-901-7247 International Sales: 1-281-441-4400 TSCA: TSCA &(b) inventory: DL-Malic acid Order Online: ScienceLab.com Clit: Not available. CHEMTREC (24HR Emergency Telephone), call: ‘Synonym: DL-Hydroxysuccinic acid; DL-Malic Acid 1-800-424-9300 Chemical Name: Butanedoic acid, hydroxy- International CHEMTREC, call: 1-703-527-3887 Chemical Formula: C4-H6-05 For non-emergency assistance, call: 1-281-441-4400 Section 2: Composition and Information on Ingredients Composition: Name cAS# % by Weight {OL-)Malic acid 617-48-1 100 Toxicological Data on Ingredients: Malic acid: ORAL (LDS0): Acute: 1600 mg/kg [Ral]. Section 3: Hazards Identification Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available, DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition. Section irst Aid Measures Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15, minutes. Cold water may be used. Get medical attention, Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. plSerious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Inhalation: Ifinhaled, remove to fresh ai. if not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious Inhalation: Not available. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious Ingestion: Not available. Section 5: Fire and Explosion Data Flammability of the Product: May be combustible at high temperature. Auto-Ignition Temperature: 349°C (660.2°F) Flash Points: CLOSED CUP: Higher than 93,3°C (200°F). OPEN CUP: 203°C (397.4°F), Flammable Limits: Not available. Products of Combustion: These products are carbon oxides (CO, C02). ire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks. Explosion Hazards in Presence of Various Substances: Slightly explosive in presence of open flames and sparks. Non-explosive in presence of shacks, Fire Fighting Media and Instructions: ‘SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. ‘Special Remarks on Fire Hazards: As with most organic solids, fire is possible at elevated temperatures Special Remarks on Explosion Hazards: Fine dust dispersed in air in sufficient concentrations, and in the presences of an ignition source is a potential dust explosion hazard, Section 6: Accidental Release Measures ‘Small Spi Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large S| Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7: Handling and Storage Precautions: Keep away from heat. Keep away from sources of ignition. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, alkalis, p2Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Section : Exposure Controls/Personal Protection Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approvedicettfied respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this, product. Exposure Limits: Not available, Section 9: Physical and Chemical Properties Physical state and appearance: Solid (crystalline powder.) Odor: Odoriess. Taste: Not available Molecular Weight: 134.09 gimole Color: White. Coloriess. pH (1% solniwater): Not available. Boiling Point: Decomposition temperature: 150°C (302°F) Molting Point: 131°C (267.8°F) - 1326 criti al Temperature: Not available. Specific Gravity: 1.601 (Water = 1) Vapor Pressure: Not applicable. Vapor Density: Not available. Volatility: 0% (viv). Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available. lonicity (in Water): Not available. persion Properties: See solubility in water, methanol, acetone, Solubility: Soluble in cold water, methanol. Partially soluble in acetone. Very slightly soluble in diethyl ether. Solubility in methanol @ 20 deg.: 82.70 g/100 g solvent Solubility in diethy| ether@ 20 deg. C: 0.84 g/100 g solvent Solubility in ethanol @ 20 deg. C: 45.53 g/100 g solvent Solubility in acetone @ 20 deg, C: 17.75 g/100 g solvent Solubility in dioxane @ 20 deg. C: 22.70 g/100 g solvent Solubility in water @ 20 deg. C: 55. 8 g/100 g solvent Practically insolubility in benzene Section 10: Stability and Reactivity Data p38Stability: The product is stable. Instability Temperature: Not available. Conditions of instability: Excess heat, incompatible materials Incompati ity with various substances: Reactive with oxidizing agents, alkalis. Corrosivity: Non-corrosive in presence of glass. Special Remarks on Reactivity: Also incompatible with amines, and alkali metals. ‘Special Remarks on Corrosivity: Not available, Polymerization: Will not occur. Section 11: Toxicological Information Routes of Entry: Inhalation. Ingestion Toxicity to Animals: Acute oral toxicity for Malic acid (LD50): 1600 mg/kg [Ratt Chronic Effects on Humans: Not available Other Toxic Effects on Humans: Hazardous in case of skin contact (iitant), of ingestion, of inhalation, Special Remarks on Toxicity to Animals: Not available. ‘Special Remarks on Chronic Effects on Humans: Not available. ‘Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: Causes skin irritation. Inhalation: Causes respiratory tract iritation. Ingestion: Moderately toxic by ingestion, May be harmful if swallowed. May cause nausea, vomiting, diarrhea. May affect behavior and respiration causing weakness, and respiratory distress and cyanosis. Chronic Potential Health Effects: Skin: Prolonged or repeated skin contact may cause dermatitis. Eyes: Prolonged or repeated eye contact may cause conjunctivitis. Section 12: Ecological Information Ecotoxicity: Not available. BODS and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself. ‘Special Remarks on the Products of Biodegradation: Not avallable. Section 1: : Disposal Considerations Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14: Transport Information DOT Classification: Not a DOT controlled material (United States), Identification: Not applicable. p4Special Provisions for Transport: Not applicable. Section 15: Other Regulatory Information Federal and State Regulations: TSCA 8(b) inventory: DL-Malic acid Other Regulations: INECS: This product is on the European Inventory of Existing Commercial Chemical Substances. Other Classifications: WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC). DSCL (EEC): R22- Harmful if swallowed. R36/38- Iritating to eyes and skin. $2- Keep out of the reach of children. S46- If swallowed, seek medical advice immediately and show this container or label. HMis (U.S.A,} Health Hazard: 2 Fire Hazard: 1 ty:0 Personal Protection: E Rea National Fire Protection Association (U.S.A.): Health: 2 Flammability: 1 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab coat. Dust respirator. Be sure to use an approvedicertified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles. Section 16: Other Information References: Not available Other Special Considerations: Not available. Created: 10/11/2005 12:17 PM Last Updated: 05/21/2013 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. 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