Safety Data Sheet

HEMPADUR MASTIC 45889

Conforms to ANSI Z400.1-2010 Standard - HCS 2012

Protective Clothing General Hazard DOT

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : HEMPADUR MASTIC 45889
Product identity : 4588912170
Product type : epoxy primer (base for multi-component product)

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : metal industry, ships and shipyards.
Ready-for-use mixture : 45880 = 45889 3 vol. / 95880 1 vol. 45881 = 45889 3 vol. / 95881 1 vol. 4588W = 45889 3 vol. /
9588W 1 vol.
Identified uses : Industrial/Professional use
TSCA : Unless otherwise stated. All components are listed or exempted.

1.3 Details of the supplier of the safety data sheet

Company details : HEMPEL (USA), Inc. HEMPEL (USA), Inc.
600 Conroe Park North Drive 2728 Empire Central
Conroe, Texas 77303 Dallas, TX 75235
Toll free: (800) 678-6641, Phone number: 1-214-353-1600
if outside area codes 713, 281, 409, 936 E-mail: [email protected]
Regular phone number: (936) 523-6000
E-mail [email protected]
1.4 Emergency telephone number (with hours of operation)
For Transportation Emergencies : CHEMTREC: 1-800-424-9300 (Toll-free in the U.S., Canada and the U.S. Virgin Islands) 703-527-3887
(24 hours) For calls originating elsewhere (Collect calls are accepted). Contract number: CCN10384
To preserve the effectiveness of arrangements for providing accurate and timely emergency response
information, the basic identifying information (shipper name or contract number) must be included on
shipping papers.
If the purchaser of this product is going to be shipping this product to other locations, the purchaser
must arrange for its own Emergency Information Provider to respond to transport incidents. Hempel's
24 hour response contract does not cover non-Hempel shipments.
For all other information : In USA toll free calling available: 1-800- 678-6641 or (936)-523-6000
(8 AM - 5 PM CST) See Section 4 of the safety data sheet (first aid measures).

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.
1200).
GHS Classification : FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs, lungs) - Category
1

2.2 Label elements

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SECTION 2: Hazards identification

Hazard pictograms :

Signal word : Danger

Hazard statements : H226 - Flammable liquid and vapor.
H319 - Causes serious eye irritation.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H350 - May cause cancer.
H372 - Causes damage to organs through prolonged or repeated exposure. (hearing organs, lungs)
Precautionary statements :
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and
understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep
away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use
explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container tightly closed.
Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly
after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF ON SKIN
(or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON
SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Supplemental label elements : None known.

2.3 Other hazards

Hazards not otherwise classified : None known.

SECTION 3: Composition/information on ingredients

Product definition : Mixture

Physical state : Liquid.
Product/ingredient name Identifiers % GHS Classification

bisphenol A-(epichlorhydrin) epoxy resin 25068-38-6 ≥10 - ≤25 SKIN IRRITATION - Category 2
MW =< 700 EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
xylene 1330-20-7 ≥5 - ≤10 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
titanium dioxide 13463-67-7 ≥5 - ≤10 Not classified.
Methylstyrenated phenol 68512-30-1 ≥5 - ≤10 SKIN IRRITATION - Category 2
SKIN SENSITIZATION - Category 1
middle molecular epoxy resin MMW 25068-38-6 ≥3 - ≤5 SKIN IRRITATION - Category 2
700-1200 EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
benzyl alcohol 100-51-6 ≥1 - ≤3 ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
EYE IRRITATION - Category 2A
ethylbenzene 100-41-4 ≥1 - ≤3 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) (hearing organs) - Category 2

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SECTION 3: Composition/information on ingredients

ASPIRATION HAZARD - Category 1
respirable quartz 14808-60-7 ≥1 - ≤3 CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) (lungs) (inhalation) - Category 1
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Occupational exposure limits, if available, are listed in Section 8.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.

SECTION 4: First aid measures

4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 911 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and
seek medical advice.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to
the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Not applicable.
Specific treatments : No specific treatment.

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SECTION 5: Firefighting measures

5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this
material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides halogenated compounds
metal oxide/oxides

5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer to protective
measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training. If the product
contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material.

6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy and
amine containing products, they may cause allergic reactions.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities

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SECTION 7: Handling and storage

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.
This product may be applied using several application techniques and methods of handling may be different for each. Application
techniques include [but are not limited to] brushing, rolling, and spray application [conventional, HPLV, airless, pleural component or
aerosol can]. Avoid the breathing of vapors and, if spraying, do not breath spray mist or aerosols.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Product/ingredient name Exposure limit values

xylene ACGIH TLV (United States, 3/2017).

TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 6/2016).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
titanium dioxide OSHA PEL (United States, 6/2016).
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2017).
TWA: 10 mg/m³ 8 hours.
benzyl alcohol AIHA WEEL (United States, 10/2011).
TWA: 10 ppm 8 hours.
ethylbenzene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2016).
STEL: 545 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 435 mg/m³ 10 hours.
TWA: 100 ppm 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
respirable quartz OSHA PEL Z3 (United States, 6/2016).
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form: Respirable
TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form: Respirable
OSHA PEL (United States, 6/2016).
TWA: 50 µg/m³ 8 hours. Form: Respirable dust
ACGIH TLV (United States, 3/2017).
TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction
NIOSH REL (United States, 10/2016).
TWA: 0.05 mg/m³ 10 hours. Form: respirable dust

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the
determination of hazardous substances will also be required.

8.2 Exposure controls

Appropriate engineering controls

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SECTION 8: Exposure controls/personal protection

Provide local exhaust and general ventilation systems to maintain airborne concentrations below OSHA, ACGIH, and manufacturer
recommended exposure limits. Local exhaust ventilation is preferred because it prevents contaminant dispersion into work areas by
controlling it at its source. Use local and general exhaust ventilation to effectively remove and prevent buildup of mists/vapors/fumes
generated from the handling of this product.
Note: Local exhaust ventilation is designed to capture an emitted contaminant at or near its source, before the contaminant has a chance to
disperse into the workplace air. General exhaust ventilation, also called dilution ventilation, is different from local exhaust ventilation
because instead of capturing emissions at their source and removing them from the air, general exhaust ventilation allows the contaminant
to be emitted into the workplace air and then dilutes the concentration of the contaminant to an acceptable level (e.g., to the PEL or below).
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
Hand protection : Wear chemical-resistant gloves in combination with 'basic' employee training. The quality of the
chemical-resistant protective gloves must be chosen as a function of the specific workplace
concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

May be used: nitrile rubber
Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)

Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : If working areas have insufficient ventilation, wear half or totally covering mask equipped with gas filter
of type Organic Vapor, when grinding use particle filter of type P95, P99 or P100. When spraying use a
combined filter (organic vapor / HEPA or organic vapor / P100 type). Be sure to use approved/certified
respirator or equivalent. Always wear an air-fed respirator when spraying in a continuous and
prolonged work situation (e.g. hood with supply of fresh or compressed air or a full face, powered air
purifying filter).
Protective clothing (pictograms) :

Note: Application of paint products by spraying requires additional safety precautions: Full body suit, Full face
respirator with air supplied.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : Testing not relevant or not possible due to nature of the product.
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 37°C (98.6°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.

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SECTION 9: Physical and chemical properties

Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Upper/lower flammability or 0.8 - 13 vol %
explosive limits :
Vapor pressure : Testing not relevant or not possible due to nature of the product.
Vapor density : Testing not relevant or not possible due to nature of the product.
Relative density : 1.626 g/cm³
Solubility(ies) : Partially soluble in the following materials: cold water and hot water.
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Testing not relevant or not possible due to nature of the product.
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Testing not relevant or not possible due to nature of the product.
Explosive properties : Slightly explosive in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information

Solvent(s) % by weight 11.5 % (w/w)
(Included excempt solvent(s)):
Water % by weight : Weighted average: 0 %
VOC content (Coatings) : 1.56 lbs/gal (187 g/l)
VOC content (Regulatory) : 1.56 lbs/gal (187 g/l)
TOC Content (Volatile) : Weighted average: 169 g/l
Solvent Gas : Weighted average: 0.049 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

10.5 Incompatible materials

Highly reactive or incompatible with the following materials: oxidizing materials.
Reactive or incompatible with the following materials: reducing materials.

10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides halogenated compounds metal oxide/oxides

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SECTION 11: Toxicological information

11.1 Information on toxicological effects

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Epoxy and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after only a short exposure
period.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
bisphenol A-(epichlorhydrin) epoxy LD50 Dermal Rabbit >2000 mg/kg -
resin MW =< 700
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >2000 mg/kg -
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
LD50 Oral Rat 3523 mg/kg -
titanium dioxide LC50 Inhalation Dusts and mists Rat >6.8 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Methylstyrenated phenol LC50 Inhalation Dusts and mists Rat >5 mg/l 4 hours
LD50 Dermal Rat >2000 mg/kg -
middle molecular epoxy resin MMW LD50 Dermal Rat >2000 mg/kg -
700-1200
benzyl alcohol LC50 Inhalation Dusts and mists Rat >4178 mg/m³ 4 hours
LD50 Oral Rat 1620 mg/kg -
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -

Acute toxicity estimates

Route ATE value
Oral 21872.4 mg/kg
Dermal 12504.5 mg/kg
Inhalation (gases) 45693.8 ppm
Inhalation (vapors) 83.36 mg/l
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
bisphenol A-(epichlorhydrin) epoxy Eyes - Mild irritant Rabbit - -
resin MW =< 700
Skin - Mild irritant Rabbit - -
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
titanium dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
Methylstyrenated phenol Eyes - Mild irritant Rabbit - -
benzyl alcohol Eyes - Irritant Rabbit - -
Skin - Mild irritant Rabbit - -
ethylbenzene Skin - Mild irritant Rabbit - 24 hours 15 milligrams
Respiratory - Mild irritant Rabbit - -
Eyes - Mild irritant Rabbit - -
Sensitizer
Product/ingredient name Route of exposure Species Result
bisphenol A-(epichlorhydrin) epoxy skin Guinea pig Sensitizing
resin MW =< 700
middle molecular epoxy resin MMW skin Guinea pig Sensitizing
700-1200
Carcinogen Classification

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SECTION 11: Toxicological information

Product/ingredient name IARC NTP OSHA

xylene 3 - -
titanium dioxide 2B - -
ethylbenzene 2B - -
respirable quartz 1 Known to be a -
human carcinogen.
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
ethylbenzene Category 2 Not determined hearing organs
respirable quartz Category 1 Inhalation lungs
Aspiration hazard
Product/ingredient name Result
ethylbenzene ASPIRATION HAZARD - Category 1

Information on the likely routes of exposure

Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Sensitization : Contains bisphenol A-(epichlorhydrin) epoxy resin MW =< 700, Methylstyrenated phenol, middle
molecular epoxy resin MMW 700-1200, 1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene. May
produce an allergic reaction.
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Harmful to aquatic life with long lasting effects.
When spilled, this product may act as an oil, causing a film, sheen, emulsion, or sludge at or beneath the surface of a body of water. Oils of
any kind can cause: (a) drowning of waterfowl due to lack of buoyancy, loss of insulating capacity of feathers, starvation and vulnerability to
predators due to lack of mobility; (b) lethal effect on fish by coating gill surfaces, preventing respiration; (c) potential fish kills resulting from
alteration in biochemical oxygen demand; (d) asphyxiation of benthic life forms when floating masses become engaged with surface debris
and settle on the bottom; and (e) adverse aesthetic effects of fouled shoreline and beaches.
Product/ingredient name Result Species Exposure
bisphenol A-(epichlorhydrin) epoxy Acute EC50 >11 mg/l Algae 72 hours
resin MW =< 700
Acute EC50 1.4 - 1.7 mg/l Daphnia - Daphnia magna 48 hours
Acute LC50 3.1 mg/l Fish - fathead minnow (Pimephales 96 hours
promelas)
titanium dioxide Acute LC50 >100 mg/l Daphnia 48 hours
Acute LC50 >100 mg/l Fish 96 hours
Methylstyrenated phenol Acute EC50 15 mg/l Algae 72 hours
Acute EC50 14 - 51 mg/l Daphnia 48 hours
Acute EC50 25.8 mg/l Fish 96 hours
middle molecular epoxy resin MMW Acute EC50 >100 mg/l Daphnia 48 hours
700-1200
Acute LC50 >100 mg/l Fish 96 hours
benzyl alcohol Acute EC50 230 mg/l Daphnia 48 hours
Acute IC50 770 mg/l Algae 72 hours
Acute LC50 460 mg/l Fish 96 hours
ethylbenzene Chronic NOEC <1000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours

12.2 Persistence and degradability

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SECTION 12: Ecological information

Product/ingredient name Test Result Dose Inoculum

bisphenol A-(epichlorhydrin) epoxy OECD 302B Inherent 12 % - Not readily - 28 days - -
resin MW =< 700 Biodegradability:
Zahn-Wellens/EMPA
Test
xylene - >60 % - Readily - 28 days - -
benzyl alcohol OECD 301C 301C 92 - 96 % - Readily - 14 days - -
Ready
Biodegradability -
Modified MITI Test (I)
ethylbenzene - >70 % - Readily - 28 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability

bisphenol A-(epichlorhydrin) epoxy - - Not readily
resin MW =< 700
xylene - - Readily
benzyl alcohol - - Readily
ethylbenzene - - Readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
bisphenol A-(epichlorhydrin) epoxy resin MW =< 700 2.64 - 3.78 31 low
xylene 3.12 8.1 - 25.9 low
Methylstyrenated phenol 3.627 - low
middle molecular epoxy resin MMW 700-1200 2.64 - 3.78 31 low
benzyl alcohol 0.87 1.37 low
ethylbenzene 3.6 - low

12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.

12.5 Other adverse effects

No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent
than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not
apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and
physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with
applicable regulations.
Refer to Section 7 and Section 8 for additional handling information and protection of employees.
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners
may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.
United States - RCRA Toxic hazardous waste "U" List

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SECTION 13: Disposal considerations

Ingredient CAS # Status Reference

number
Xylene 1330-20-7 Listed U239

SECTION 14: Transport information

Transport may take place according to national regulation or DOT for transport by road and by train, IMDG for transport by sea, IATA for Air
shipment. Refer to specific Dangerous Goods Transport requirements under 49CFR, ICAO and IATA.
14.1 14.2 14.3 14.4 14.5
UN no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

DOT UN1263 PAINT 3 III No. ERG : 128

Code - Reportable quantity
(xylene, chlorine)
1136.1 lbs / 515.77 kg [83.796 gal /
317.2 L]
Package sizes shipped in quantities
less than the product reportable
quantity are not subject to the RQ
(reportable quantity) transportation
requirements.

TDG UN1263 PAINT 3 III No. Product classified as per the following
sections of the Transportation of
Code - Dangerous Goods Regulations: 2.
18-2.19 (Class 3).

SCT UN1263 PAINT 3 III No. -

Code -

IMDG UN1263 PAINT 3 III No. Emergency schedules F-E, S-E

Code -

IATA UN1263 PAINT 3 III No. -

Code -

Code : Classification
PG* : Packing group
Env.* : Environmental hazards

14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
U.S. Federal regulations : All components are listed or exempted.
TSCA 4(a) final test rules: nonane
TSCA 8(a) PAIR: nonane; poly(dimethylsiloxane); benzaldehyde; benzylchloride
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
Clean Water Act (CWA) 307: ethylbenzene; mercury metal; phenol
Clean Water Act (CWA) 311: epichlorohydrin; ethylbenzene; xylene; benzylchloride; phenol
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) : Listed

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SECTION 15: Regulatory information

Product/ingredient name CAS number Concentration

ethylbenzene 100-41-4 1.9322

xylene 1330-20-7 8.8023
benzylchloride 100-44-7 <0.001
phenol 108-95-2 0.0029712

Clean Air Act Section 602 Class I Substances : Not listed

Clean Air Act Section 602 Class II Substances : Not listed
DEA List I Chemicals (Precursor Chemicals) : Not listed
DEA List II Chemicals (Essential Chemicals) : Not listed
SARA 302/304 - SARA 311/312: SARA 302/304: chlorine; phenol; epichlorohydrin; benzylchloride
SARA 311/312 Hazards identification: Fire hazard, Immediate (acute) health hazard, Delayed
(chronic) health hazard
Product/ingredient name % Fire hazard Sudden Reactive Immediate Delayed
release of (acute) health (chronic)
pressure hazard health hazard

bisphenol A-(epichlorhydrin) epoxy resin 10 - 25 No. No. No. Yes. No.

MW =< 700
xylene 5 - 10 Yes. No. No. Yes. No.
Methylstyrenated phenol 5 - 10 No. No. No. Yes. No.
middle molecular epoxy resin MMW 3-5 No. No. No. Yes. No.
700-1200
benzyl alcohol 1-3 No. No. No. Yes. No.
ethylbenzene 1-3 Yes. No. No. Yes. Yes.
respirable quartz 1-3 No. No. No. No. Yes.

SARA 313 : SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS
shall include copying and redistribution of the notice attached to copies of the MSDS subsequently
redistributed.
Form R - Reporting requirements : Product/ingredient name CAS number Concentration

xylene 1330-20-7 5 - 10
ethylbenzene 100-41-4 1-3
mercury metal sec. (92786-62-4) 0-1

Supplier notification : Product/ingredient name CAS number Concentration

xylene 1330-20-7 5 - 10
middle molecular epoxy resin MMW 700-1200 25068-38-6 3-5
ethylbenzene 100-41-4 1-3

State regulations : Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed.
Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: SILICA, CRYSTALLINE, QUARTZ;
ETHYL BENZENE; ETHYLBENZENE; XYLENE; DIMETHYLBENZENE; BENZYL ALCOHOL;
TITANIUM DIOXIDE; TIN DIOXIDE DUST
Michigan Critical Material: None of the components are listed.
Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: The following components are listed: SILICA, QUARTZ;
QUARTZ (SiO2); ETHYL BENZENE; BENZENE, ETHYL-; XYLENES; BENZENE, DIMETHYL-;
TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2)
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: The following components are listed: Ethylbenzene;
Xylene mixed
New York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: The following components are listed: QUARTZ DUST;
QUARTZ; BENZENE, ETHYL-; BENZENE, DIMETHYL-; BENZENEMETHANOL; TITANIUM OXIDE
Rhode Island Hazardous Substances: None of the components are listed.
California Prop. 65 PFF : WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause
birth defects or other reproductive harm.

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SECTION 15: Regulatory information

Product/ingredient name Cancer Reproductive No significant risk level Maximum acceptable
dosage level

epichlorohydrin Yes. Yes. Yes.

2-phenylpropene Yes. No.
ethylbenzene Yes. No. Yes.
cadmium Yes. Yes.
mercury metal No. Yes.
carbonblack Yes. No.
titanium dioxide Yes. No.
respirable quartz Yes. No.
benzylchloride Yes. No. Yes.

SECTION 16: Other information

Remarks : Note: In USA, consult Code of Federal Regulations, Title 29, Labor, Parts 1910 and 1915 concerning
occupational safety and health standards and regulations, as well as any other applicable Federal,
State or local regulations that apply to safe practices in coating operations.
Warning! If you scrape, sand, or remove old paint, you may release lead dust. LEAD is TOXIC.
Validation : Validated by US - HSE Products Coordinator on 30 January 2018
GHS Classification
Procedure used to derive the classification.
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 1A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs, lungs) - Category 1 Calculation method

Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)

Health *3 Flammability
3
Fire hazard 3 Health 2 0 Instability
Physical hazards 0
Personal protection X Special

Personal Protective Equipment (PPE) shown in this section is a suggestion. Since conditions vary from one work location to another consult the facility safety & health program. Customer or end
user is responsible to evaluate worker exposure conditions at the site of application and determine the appropriate PPE suitable for workers at that particular facility or location.
Abbreviations and acronyms :
ANSI = American National Standards Institute OECD = Organisation for Economic Co-operation and Development
HCS = Hazardous Communication System BCF = Bioconcentration Factor
TSCA = Toxic Substances Control Act DOT = United States Department of Transportation
CFR = Code of federal Regulations ERG = Emergency Response Guide
GHS = Globally Harmonized System of Classification and Labelling of Chemicals TDG = Transport of Dangerous Goods, Canada
OSHA = United States Occupational Health and Safety Administration SCT = Transportation & Communications Ministry, Mexico
NIOSH = National Institute for Occupational Safety and Health IMDG = International Maritime Dangerous Goods
ACGIH = American Conference of Industrial Hygienists IATA = International Air Transport Association
IARC = International Agency for Research on Cancer. SARA = Superfund Amendments Reauthorization Act
NTP = National Toxicology Program EPCRA = Emergency Planning and Community Right to Know Act
ATE = Acute Toxicity Estimate

Notice to reader
Indicates information that has changed from previously issued version.

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries
assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any
material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that exist.

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