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F + H O HF + O: # 2naoh (Cold and Dilute) + CL Nacl +naocl +H O # 6naoh (Hot and Conc.) + 3Cl 5nacl +naclo +H O

This document provides 54 chemical reactions involving p-block elements. It begins by listing reactions of copper, sodium, chlorine, nitrogen, phosphorus, fluorine, and xenon with various acids and bases. Subsequent sections provide additional reactions involving sulfur, carbon, nitrogen, phosphorus, and halogens. The document concludes by providing incomplete reactions for students to balance and complete, involving elements such as chlorine, fluorine, xenon, nitrogen, phosphorus, sulfur, and metals.

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85 views4 pages

F + H O HF + O: # 2naoh (Cold and Dilute) + CL Nacl +naocl +H O # 6naoh (Hot and Conc.) + 3Cl 5nacl +naclo +H O

This document provides 54 chemical reactions involving p-block elements. It begins by listing reactions of copper, sodium, chlorine, nitrogen, phosphorus, fluorine, and xenon with various acids and bases. Subsequent sections provide additional reactions involving sulfur, carbon, nitrogen, phosphorus, and halogens. The document concludes by providing incomplete reactions for students to balance and complete, involving elements such as chlorine, fluorine, xenon, nitrogen, phosphorus, sulfur, and metals.

Uploaded by

Ss
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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R E A C T I O N S O F p-B L O C K E L E M E N T S

by A. K .Panda, PGT (Chem) ,KV NO-3 BBSR

1(a)# Cu + 8 HNO3(Dil. )  Cu(NO3)2 + 2NO +4 H2O


1(b)# Cu + 4 HNO3( conc.) Cu(NO3)2 + 2NO2 +2H2O

2(a)# 2NaOH (cold and dilute) + Cl2  NaCl +NaOCl +H2O


2(b)# 6NaOH (hot and conc.) + 3Cl2  5NaCl +NaClO3 +H2O

3(a)# 8NH3 (excess) + 3 Cl2  6NH4Cl + N2


3(b)# NH3 + Cl2 ( excess)  NCl3 (explosive ) + 3 HCl

4(a)# PCl3 + H2O  H3PO3 + 3 HCl


4(b)# PCl5 + H2O  POCl3 + 2 HCl
└> + H2O H3PO4 + 3 HCl

5(a)# F2 + H2O  HF + O2
5(b)# X2(g) + H2O(l)  HX(aq) + HOX (aq) ] 1/3 ClF + H2O  HF + H—O—Cl
 X2(Hydrated) ] 2/3

6(a) # 2XeF2 (s) + 2H2O(l) 2Xe (g) + 4 HF(aq) + O2(g)


6(b) # 6XeF4 + 12 H2O  4Xe + 2Xe03 + 24 HF + 3 O2
[Hydrolysis of XeF4 and XeF6 with water gives Xe03.]

7(a)# # C + 2H2SO4 (Conc.)  CO2 + 2 SO2 +2H2O


7(b)# # Cu + 2H2SO4 (Conc.) CuSO4 + SO2 +2H2O

8(a)# # 4 H3PO3  3 H3PO4 + PH3


8(b)# (NH4)2Cr2O7 —(Heat ) - N2 + Cr2O3 +H2O
8(c)# HNO2 --(Heat)  HNO3 + H2O + 2NO
8(d)# PCl5 + Heat  PCl3 + Cl2

9(a)# Cu + 2H2SO4 (Conc.) CuSO4 + SO2 +2H2O


9(b)# Cu + 4 HNO3( conc.) Cu(NO3)2 + 2NO2 +2H2O

10(a)# XeF6 + 3 H2O  XeO3 + 6 HF

10(b)# XeF6 + H2O  XeOF4 + 2 HF [Partial hydrolysis of XeF6 gives oxyfluorides, XeOF4 and XeO2F2]
10(c)# XeF6 + 2 H2O  XeO2F2 + 4HF

11(a)# XeF2 + PF5 [XeF]+ [PF6]– ;


11(b)# XeF4 + SbF5 [XeF3]+ [SbF6]–
11(c)# XeF6 + MF M+ [XeF7]– (M = Na, K, Rb or Cs)

12(a)# Ca3P2 + 6H2O  3 Ca(OH)2 + 2 PH3


12(b)# P4 + 3NaOH + 3 H2O  PH3 + 3 NaH2PO2
13(a)# 2 Fe3+ + SO2 + 2H2O  2 Fe2+ + SO4 2ˉ + 4 H+
13(b)# 5 SO2 + 2 MnO4 ˉ + 2 H2O  5 SO4 2ˉ + 4 H+ + 2 Mn2+

14(a)# P4 + 8 SOCl2  4 PCl3 +4 SO2 + 2 S2Cl2


14(c)# P4 + SO2Cl2  4 PCl5 + 10 SO2

15(a)# 3CuSO4 +2PH3  Cu3P2 + 3 H2SO4


15(b)# 3HgCl2 +2 PH3  Hg3P2 + 6 HCl

16(a)# Cu2+ (aq) + 4 NH3(aq) [Cu(NH3)4]2+(aq)


(blue) (deep blue)
16(b)# AgCl (s) + 2 NH3(aq) [Ag(NH3)2] Cl (aq) {colourless soluble complex}

17(a)# NH4Cl(aq) + NaNO2 (aq)  N2(g) +2H2O (l) + NaCl (aq)


17(b)# (NH4)2Cr2O7+Heat N2 + 4H2O + Cr2O3
17(c)# Ba(N3)2  Ba + N2

18(a)# PCl3 + H2O  H3PO3 + 3 HCl


18(b)# PCl5 + H2O  POCl3 + 2 HCl
└> + H2O H3PO4 + 3 HCl

19(a)# C2 H5 OH + PCl5 C2 H 5Cl + POCl3 + HCl


19(a)# CH 3COOH + PCl5 CH3 COCl + POCl3 +HCl

20(a)# 2Ag (Finely divided )+ PCl5 2AgCl + PCl3


20(b)# Sn(Finely divided ) + 2PCl5  SnCl4 + 2PCl3

21(a)# NCl3 + H2O  NH3 + 3 HOCl


21(b)# PCl3 + H2O  H3PO3 + 3 HCl

22(a)# 2FeSO4 + H2SO4 + Cl2 → Fe2(SO4)3 + 2HCl


22(b)# Na2SO3 + Cl2 + H2O → Na2SO4 + 2HCl
22(c)# SO2 + 2H2O + Cl2 → H2SO4 + 2HCl

23(a)# Cl2+F2 [437K]→2ClF;


(equal volume)
23(b)# Cl2 + 3F2 (excess) [573K ]→2ClF3 ;

24(a)# I2 +3Cl2 [437K]→2ICl3;


24(b)# I2 +Cl2 (equimolar)→2ICl

25(a)# Br2 + 3F2 →2BrF3


(Diluted with water)
25(b)# Br2 + 5F2 →2BrF5
(excess)

26(a)# 2 Na2S2O3 + I2  Na2S4O6 + 2 NaI


26(a)# Na2S2O3 + 4 Cl2 +5 H2O  2 NaHSO4 + 8 HCl
R E A C T I O N S O F p-B L O C K E L E M E N T S
by A. K .Panda, PGT (Chem)
,KV NO-3 BBSR
Balance and Complete the following :-
(1) Cl2 + NaOH (hot and conc.)  (2) F2 + H2O 

(3) XeF2 + PF5  (4) XeF6 + NaF 

(5) Au + Aqua Regia  (6) Cu + Conc.HNO3 

(7) C12H22O11 + Conc.H2SO4  (8) SO2 + MnO4ˉ + H + 

(9) PbS + O3  (10) CH3COOH + PCl5 

(11) Ca3P2 +H2O  (12) I2 + conc. HNO3 

(13) Cu + Dil. HNO3  (14) Cu + Conc.H2SO4 

(15) Ca(OH)2 +Cl2  (16) NaCl + MnO2 + H2SO4 

(17) HgCl2 + PH3 (18) U + ClF3 

(19) XeF4 + H2O  (20) XeF6 + H2O 

(21) KMnO4 + HCl  (22) KI (aq) + H2O(l) + O3 (g) 

(23) CuSO4 + NH3  (24) PCl5 + H2O(excess) 

(25) (NH4)2Cr2O7 --(heat) (26) P4 + NaOH +H2O 

(27) Al2O3 + NaOH + H2O  (28) HCl + O2 + CuCl2(Catalyst)

(29) XeF2 (s) + H2O (l)  (30) NH3 + Cl2 (excess) 

(31) Fe3+ + SO2 + 2H2O  (32) Br2 + KI 


(33) Cl2 + H2O  (34) NaOH + SO2 
(35) SO2 + MnO4ˉ + H+  (36) Fe + HCl 
(37) Cl2(g) + NaI(aq)  (38) Na2S2O3 + I2 
(39) Na2S2O3 + Cl2 + H2O  (40) ClF + H2O 
(41) XeF4 + O2F2  (42) Cl2 + NaOH (cold and
dil.) 
(43) NH3 (excess) + Cl2  (44) SO2 + V2O5 
(45) H3PO3 + Heat  (46) SF4 + H2O 
(47) Al2O3 + HCl + H2O  (48) HNO3 + P4O10 
(49) NH4NO3 + Heat  (50) AgCl + NH3 
(51) NaN3 + Heat  (52) Ag + PCl5 
(53) PCl3 + H2O  (54) Zn + dil. HNO3 

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