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Pseudocapacitance Calculation PDF

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199 views

Pseudocapacitance Calculation PDF

Uploaded by

R.Subramanian
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Application note #20

Pseudo capacitance calculation

I- Introduction
This circuit is not present in the electrical
It can sometimes be useful to substitute a RQ circuits list already in the ZFit tool, so the user
circuit by a RC circuit (Fig. 1). must add this circuit using to the Edit menu.
This calculation is only available for a circuit
(R/Q). It corresponds to the determination of a
capacitance value C at an angular frequency
 c  2f c corresponding to the maximum
imaginary part on the Nyquist circle obtained
by fitting with the circuit (R/Q). Then, this value
is the solution of the following equation
1 1
  C  Q1 /  R (1 /  ) 1
2π RQ 1/ 2πRC

with  and Q as the CPE parameters [1,2].

Fig. 2: PEIS “Parameters Settings” window.

Fig. 1: Equivalent electrical circuit RQ and RC


with the corresponding impedance diagram.

II-Experimental part
A lithium-ion battery, with LiFePO4 as the
positive electrode, was studied in this
application note. The impedance diagram was
recorded considering the setting described in
the Fig. 2, i.e. in the 10 kHz – 10 mHz range
with Va = 10 mV, pw = 1, Na = 1, and the drift
Fig. 3: Nyquist impedance diagram (blue) and
correction button ticked. The impedance
ZFit analysis (red) of a Li-ion battery with a
diagram obtained is given in Fig. 3. L1+R1+Q2/R2+Q3 equivalent circuit.
The ZFit tool was used to fit data with the
equivalent circuit L1+R1+Q2/R2+Q3 (Fig. 4).
Bio-Logic Science Instruments, 1 rue de l'Europe, F-38640 Claix - tel: +33 476 98 68 31 – Fax: +33 476 98 69 09 1
Web: www.bio-logic.info
However, even by clicking on the PseudoC
button, it is not possible to calculate a pseudo-
capacitance value as displayed in Fig. 11. The
pattern in the equivalent circuit is Q/(R+Q) and
not the required one (R/Q).
Fig. 4: L1+R1+Q2/R2+Q3 equivalent electrical
circuit.

In the Equivalent Circuit Edition, the


L1+R1+Q2/R2+Q3 circuit has to be defined
and added with the Add button, as described
in Fig. 5. The new circuit is then displayed in
blue.

Fig. 5: How to add a new electrical equivalent


circuit in the ZFit analysis tool.

Results of the ZFit analysis are given in Fig. 6.


A good agreement is observed between the
experimental diagram and the ZFit diagram as Fig. 6: ZFit analysis window obtained with
shown in Fig. 3. the L1+R1+Q2/R2+Q3 equivalent circuit.
The equivalent circuit used to do the fit on the
experimental data contains the pattern (R/Q).
It is then possible to calculate the pseudo-
capacitance. In the ZFit window, select the
PseudoC button, and the window given in Fig.
7 appears. This means that with the ZFit
analysis tool of EC-Lab® and EC-Lab®
Express, calculation of pseudo-capacitance is
done automatically.
However, the following equivalent circuit
L1+R1+Q2/(R2+Q3) (Fig. 8) can also be
considered to fit the diagram. As shown in Fig.
9, the obtained fit (red) is in good agreement
with experimental data (blue). The parameters
are displayed in the ZFit window given in Fig.
10. Fig. 7: Pseudocapacitance calculation in the
ZFit window obtained with the
L1+R1+Q2/R2+Q3 equivalent circuit.
Bio-Logic Science Instruments, 1 rue de l'Europe, F-38640 Claix - tel: +33 476 98 68 31 – Fax: +33 476 98 69 09 2
Web: www.bio-logic.info
Fig. 8: L1+R1+Q2/(R2+Q3) equivalent electrical
circuit.

Fig. 11: Pseudocapacitance calculation in the


ZFit window obtained with the
L1+R1+Q2/(R2+Q3) equivalent circuit.
Fig. 9: Nyquist impedance diagram (blue) and
ZFit analysis (red) of a Li-ion battery with a
L1+R1+Q2/(R2+Q3) equivalent circuit.
It is not possible to distinguish between the
two fits considering the χ² values, which are
very close. In the same way, the values of the
fit parameters obtained for the two circuits
(Fig. 6 and Fig. 10) are very close.
Note that in some peculiar cases, it is possible
to establish equivalence between the following
two electrical circuits L1+R1+Q2/R2+Q3 and
L1+R1+Q2/(R2+Q3).

References
[1] Electrical circuits containing CPEs, Bio-Logic
website, http://www.bio-logic.info/potentiostat/notes
nd
[2] Impedance spectroscopy, 2 Edition, ed.
Barsoukov E., Ross Mac Donald J., 2005

Fig. 10: ZFit analysis window obtained with the


L1+R1+Q2/(R2+Q3) equivalent circuit.

Bio-Logic Science Instruments, 1 rue de l'Europe, F-38640 Claix - tel: +33 476 98 68 31 – Fax: +33 476 98 69 09 3
Web: www.bio-logic.info

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