CBSE Class 12 Chemistry Question Paper Solution 2019

Marking scheme – 2019

CHEMISTRY (043)/ CLASS XII

56/1/1
Q.No Value Points Marks
SECTION A
1 AgCl , Due to large difference in their size/ Due to small size of Ag+ ion. ½,½
2 (CH3)3N < C2H5NH2 < C2H5OH 1
3 Due to large surface area these are easily assimilated or adsorbed. 1
OR
3 Emulsion – both dispersed phase and dispersion medium are liquid 1
Gel- Dispersed phase is liquid while dispersion medium is solid
4 Nucleophiles having two nucleophilic centres. CN- /SCN- / NO2- (any one) ½,½
5 Glucose has aldehydic group while fructose has ketonic group/ Glucose is aldose while fructose is 1
ketose.
OR
5 Glucose and Galactose 1
SECTION B
6 i) 1
ii) 1
OR
6 i) H2O < H2S < H2Se < H2Te 1
ii) HF> HCl > HBr > HI 1
7 For a solution of volatile liquids, the partial vapour pressure of each component of the solution 1
is directly proportional to its mole fraction present in solution.
(i) (ii) (iii) The components have nearly same intermolecular force of ½, ½
attraction (any two)
8 i) Rate = k [H2O2] [ I-] 1
ii) order = 2 ½
iii) Step 1 ½
9 A = K2MnO4 / MnO42- , B= KMnO4 / MnO4-- , C= IO3- or KIO3 , D= I2 ½ ×4
10. Bis(ethan-1,2-diamine)dichloridoplatinum (II) 1

½,½

Cis Trans
OR
10. i) [Co(NH3)6]2(SO4)3 1
ii)K3[Cr(ox)3] 1
11 i) [CoF6]3- ½ ×4
ii)[Co(en)3]3+
iii) [Co(en)3]3+
iv) [CoF6]3-
12 ½ ×4

i) A= B=

ii) A= B=
SECTION C
13 𝑅 0─ 𝑅 𝑡
t=
𝑘 1

[0.1−0.064] 1
=
4𝑋 10 −3

=9s 1
14 i) Adsorption of toxic gases 1
ii) Negative charge ; ½,½
iii) Increases with increase in temperature/ First increases then decreases 1
15 𝑧𝑚 1
d= ; m=Mass of element , N=number of atoms
𝑎3 𝑁
𝑁 = 108 X 4
10.8X27X10-24 1

= 1.48 X 1024 atoms

1
Or
𝑎 3 × 𝑁𝑎 ×𝑑
M= ½
𝑍
27 × 10 −24 ×6.022 × 10 23 ×10.8
1
=
4
= 43.88 g mol -1 ½
43.88 g mol -1 contains 6.02 × 1023 atoms
6.02 × 10 23 × 108
So , 108 g contains = = 1.48 × 1024 atoms 1
43.88
16 ΔTf = Kf m ½
Kf = ΔTf X M2x w1
w2 x1000
= 2x 342 x 96
4x1000
= 16.4 K 1
ΔTf = Kf m’
= Kfw2 x1000
M2x w1
= 16.4 x 5 x 1000
95x180 1
= 4.8 K
ΔTf = Tfo- Tf
4.8 = 273.15 - Tf
½
Tf = 268.35 K
17 a) i)Zone refining ii)Distillation ½,½
b) 1
2Cu2O + Cu2S  6Cu + SO2 1
18 i) Due to variable oxidation state 1
ii)Mn2+ is stable due to exactly half filled 3d5 configuration/ Due to high ΔaH0 and low ΔhydH0for
Cu2+ / Cu is positive. 1
iii) Due to comparable energies of 5f , 6d and 7s orbitals. 1
19. 1 ×3
i) ,

ii) HO-CH2-CH2-OH ,

iii) ,
OR
19 i) Homopolymers , single repeating unit ½,½

1
ii) , (Or names of monomers)
iii) Sulphur forms cross links at the reactive sites of double bonds and thus the rubber gets 1
stiffened / To improve the physical properties of rubber by forming cross links.
20. i) Tranquilizers 1
ii) Anionic detergents 1
iii) It is difficult to control the sweetness. 1
OR
20. i) Antibiotics which kill or inhibit a wide range of Gram-positive and Gram-negative bacteria. ½,½
Example- Chloramphenicol (or any other)
ii) The chemicals which either kill or prevent the growth of microorganisms when applied to ½,½
inanimate objects such as floors, drainage system, instruments, etc.Example – 1% Phenol
solution (or any other)
iii) Cationic detergents are quarternary ammonium salts of amines with acetates, chlorides or
½,½
bromides as anions where Cationic part is involved in cleansing action. Example –
Cetyltrimethylammonium bromide (Or any other)
21 i) (CH3)3C-I , Due to large size of iodine / better leaving group / Due to lower electronegativity. ½,½
1

ii)
iii) Because enantiomers have same boiling points / same physical properties. 1
22 ½ ×6

A = , B= , C=
A= Benzamide , B= Aniline , C= Phenylisocyanide / Benzeneisonitrile
23 i) C6H5-CH(OH)-CN 1
ii) 2 CH3COCH2C6H5 + CdCl2 1
iii) (CH3)2-C(Br)COOH 1
 OR
23 1

i)

1
ii)

iii)
24 i) Amylose is water soluble component while amylopectin is water insoluble 1
ii) Peptide linkage is –CONH- formed between two amino acids while glycosidic linkage is an
oxide linkage between two monosaccharides. 1
iii) In fibrous protein ,the polypeptide chains run parallel while in globular , the chains of 1
polypeptides coil around to give a spherical shape
(or any other correct difference.)
OR
24

1
i)

1
ii)

1
iii)
SECTION D
o
25 Ecell = E cell -
0.059 logKc 1
n
= Eocell - 0.059 log10-3 1
2 10-2
= 2.71+ 0.0295
1
Ecell = 2.7395 V
i)Cu to Mg / Cathode to anode / Same direction
1
ii)Mg to Cu / Anode to cathode / Opposite direction
1
OR
25 (a) 𝑚 = 𝑧 𝐼 𝑡 ½
56 ×2 ×𝑡 ½
2.8 g =
2 ×96500 ½
t= 4825 s / 80.417 min
𝑚1 𝐸1 ½
=
𝑚2 𝐸2
 2.8 56 2 1
= X
𝑚𝑍𝑛 2 65.3
mZn = 3.265 g 1
b) i)A- strong electrolyte , B-Weak electrolyte 1
ii)Λ0m for weak electrolytes cannot be obtained by extrapolation while Λ0m for
strong electrolytes can be obtained as intercept.

26

a) i)
PCC,Heat i)CH3MgBr ii)H+
ii) CH3CH2OH CH3-CHO CH3CH(OH)-CH3 1
(or any other correct method)

½
b)

1
c) Due to involvement of lone pair of oxygen in delocalisation makes the benzene ring electron
1
rich.
OR
26 a) i) o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding while p-nitrophenol 1
is less volatile due to intermolecular hydrogen bonding.
ii) Due to the formation of stable intermediate tertiary carbocation / CH3O- being a strong base 1
favours elimination reaction.

1
b) i)
ii) (Award 1 mark if attempted in any way)
1
c) Add neutral FeCl3 to both the compounds, phenol will give violet colouration while ethanol does
1
not.

27 a) i) In vapour state sulphur partly exists as S2 molecule which has two unpaired electrons like 1
O2 .
ii) Due to greater interelectronic repulsion 1
iii) Because decomposition of ozone into oxygen results in the liberation of heat (H is
negative) and an increase in entropy (S is positive), resulting in large negative Gibbs energy 1
change (G) for its conversion into oxygen.
b) i) NO gas/ Nitric oxide
ii) NO2 gas / Nitrogen dioxide
1,1
OR
27 1
a) i)
 1

1
1
ii) 1
b) i) Due to small size and low bond dissociation enthalpy
ii) As the size increases, electronegativity decreases / non-metallic character decreases
c)