3 RT-23 (Paper-1)-PCM-JEE(Advanced)

Physics PART – I

SECTION – A

Straight Objective Type

This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE is/are correct

1. A disc of radius a and mass m rests between two light rods,

which are smoothly hinged together at point O with their
ends A and B resting on a smooth table and are maintained
in equilibrium by string AB as shown in the figure. Choose OA = OB = C
O
the correct option (s).
A  B
mg
(A) The magnitude of normal force acting on the rod at point A is .
2
mg
(B) The magnitude of normal force acting on the rod at point A is .
2cos 
mg  a 
(C) The tension in the string AB is  cot   sec 2  
2  c 
mg  a 
(D) The tension in the string AB is  tan   cos ec 2  
2  c 

2. A uniform rod of length 4 m and mass 22 kg revolves with constant

A
angular velocity  about a vertical axis through a smooth joint A at one
extremity of the rod so that it describes a cone of semi vertical angle 53
as shown in the figure. Choose the correct statement(s). (g = 10 m/s2) 53
(A) The value of angular velocity  is 2.5 rad/s
(B) The angle between hinge reaction at point A and vertical axis AC is
45
(C) The magnitude of hinge reaction at point A is 40 N B
(D) The angular momentum of the rod is constant.

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3. A uniform cube of mass 4 kg and side 30 cm is placed on a F

frictionless horizontal surface. A vertical force F is applied to the
edge as shown in the figure. Choose the most appropriate
option(s). (take g = 10 m/s2) C
(A) Cube will move in the upward direction if F > 40 N
(B) Cube will not perform any type of translation or rotation motion if 10 N < F < 20 N
(C) Cube will begin to perform rotational motion if 20 N < F < 40 N
(D) Normal reaction applied by the surface shifts to a distance 5 cm from centre C of the cube if
F = 10 N

4. In the given figure, a wire loop has been bent so that it has three y
segments. Portion OABO is a quarter circle in xy plane, portion
OBC is a right angle triangle in xz plane and portion OCDAO is a A (0, a, 0)
square in yz plane. Here are three choices for a magnetic field D (0, a, a) O B(a, 0, 0)
through the loop. x

ˆ ˆ
(1) B1  3i  7 j  5tkˆ C (0, 0, a)
 z
(2) B2  5tiˆ  4ˆj  15kˆ

(3) B3  2iˆ  5tjˆ  12kˆ
  
If the induced current in the loop due to B1,B2 and B3 are i1,i2 and i3 respectively then:
(A) i1  i2 (B) i1  i3
(C) i3  i2  i1 (D) i1  i2  i3

5. Four identical conducting rods are connected by pins. The velocity

Q
of point R is v. A uniform magnetic field B acts out of the paper.
4 3
Choose the correct statement(s). (PQ = PS = 4 and QR = SR = 3)
6Bv 37 53
(A) The motional emf across PQ is
5 R V
P
3Bv
(B) The motional emf across PQ is 3
5 4
S
3Bv
(C) The motional emf across QR is
5
6Bv
(D) The motional emf across QR is
5

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 5 RT-23 (Paper-1)-PCM-JEE(Advanced)

k
6. Magnetic field in a cylindrical region is varying as B = t,
r
where k is a positive constant. ‘t’ is time and r’ is distance from qm
the centre. At the origin where r is zero magnetic field is r0
negligibly small. A charge q of mass m is released from rest at
a distance r0 from the centre. Then choose the correct
option(s).
(A) Force on the charge particle just after the release is qk/2
(B) Force on the charge just after the release is qk.
(C) Magnetic flux in a cylindrical region of radius ‘r’ as a function of time ‘t’ is 2ktr.
(D) Magnetic flux in a cylindrical region of radius ‘r’ as a function of time ‘t’ is ktr

7. In the given diagram R1 = R2 = R3 = R4 = R5 = R. The given

switch is closed at t = 0. Choose the correct option(s). Sw
2E R1
(A) The current in R2 is given by
5R

1  e4t /5RC  E
R2 R3
2 E 4t/ 5RC
(B) The current in R5 is given by e
5R
R5
E  1 4t/5RC  R4
(C) The current in R2 is given by 1 e
2R  5 

C
E 4t/RC
(D) The current in R5 is given by e
5R

8. The car-A is moving along positive y-axis with uniform speed 6 m/s and car B is moving towards
negative x-axis with uniform speed 8 m/s. At t = 0, car-A is at origin and car B is at point
P(50 m, 0). Choose the correct option(s), if v indicates the rate of change of distance between the
two cars A and B as a function of time.
(A) v (B) v
10 m/s 10 m/s
8 m/s
6 m/s

4 sec t 4 sec t
(C) The minimum distance between two (D) The minimum distance between two cars
cars is 40 m. is 30 m.

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9. Consider a cylinder of mass 100 g and radius 2m is

performing rolling without slipping with angular
velocity 10 rad/s on a piece of paper at rest which, v0
in turn, is placed on a rough horizontal surface as 0
shown. The paper is pulled back and forth Paper
beneath the cylinder, until the cylinder starts sliding. Finally the paper is the pulled out
horizontally. The cylinder is observed to slide on the floor. The coefficient of friction between the
cylinder and paper is 0.2, between the paper and surface is 0.3 and between cylinder and surface
is 0.4. Choose the correct option(s).
(A) The final velocity of centre of mass of cylinder is 10 m/s.
(B) The final velocity of centre of mass of cylinder is 20 m/s.
(C) The total work done by the friction on the cylinder is zero.
(D) The total work done by the friction on the cylinder is negative.

10. Consider two identical particles in free space with velocities, at y

some instant (t = 0). The only force they experience is mutual d

force of gravitational attraction. v1 and v2 are the velocities of M M o x
the particles at t = 0. Choose the INCORRECT statement(s).
 
(A) The particles will collide at some later instant if v1  v0 ˆj and v 2   v 0 ˆj
 
(B) The particles will collide at some later instant if v1  2v 0 ˆj and v 2   v 0 ˆj
 
(C) The particles will collide at some later instant if v1  v 0 ˆj and v 2   v 0 ˆj
 
(D) The particles will collide at some later instant if v  v ˆj and v  2v ˆj
1 0 2 0

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 7 RT-23 (Paper-1)-PCM-JEE(Advanced)

SECTION – C

(One Integer Value Correct Type)

This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive)

1. Two long wires with negligible resistance are + + + + + + +

+
shunted at their end by a large resistor R and
at the other ends are connected to a source of
constant voltage. The radius of the cross E  R
V
section of each wire is smaller than the
distance between the axes of the two wires by
       
a factor of 20. If the value of the resistance R,
at which resultant force of interaction of the
wires vanishes, is (N  90) , then find the
value of N. (given ln20 = 3)

2. An infinite long straight wire that carries a current I1

Infinite current-carrying wire
I1 = 50 A is partially surrounded by a loop as shown in
12 cm
the diagram. The loop has a length  = 50 cm and a I2 Circular
radius R = 25 cm and it carries current I2 = 20 A. The portion
axis of loop coincides with the infinite wire. The force R
that acts on the loop is 4k  104 N. Find the value of
k.
 I1

I2

R Circular
portion

3. A uniform chain of mass per unit length  is sliding down the hill with
constant speed u. Dimension of the hill are h and d as shown. Find the
momentum of the chain at the instant shown. (given  = 1 kg/m, d = 3m,
h
h = 4m, and u = 1 m/s)

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4. Three persons, located at each of the corners of an equilateral triangle, start moving towards one
another with constant speed u until they meet at a point. Side length of the triangle is a. Given
1/4
a = ½ m u = 3 m/s. Find angular acceleration of one person with respect to another at the initial
moment.

5. A body of mass 2 kg is moving in straight line for which v – x graph v(m)

is shown in the figure. Magnitude of force acting on the body at
20
x = 10 m is 5k N. Find the value of k.

10

10 20 x(m)

6. A current I is flowing through a thin cylinder of radius R. The pressure exerted on the cylinder due
0I2
to the flow of current is . Find the value of k.
k 2R2

7. A capacitor in an LC oscillator has a maximum potential difference of 15V and a maximum energy
of 360 μJ. At a certain instant the energy in the inductor is 320 μJ. At that instant, what is the
potential difference across the capacitor in Volts?

8. A particle moves along a parabolic path y = 9x 2 in such a way that the x component of velocity
remains constant and has a value 1/3 m/s. The acceleration of the particle is kjˆ m/s2. Find the
value of k.

9. Between two isotherms, a cyclic process ABCDA is

performed with one mole of ideal mono-atomic gas. The
work done in 1 cycle is 25 K Joule. Find K. B C
P2

T1 = 127C

P1 D
A

T2 = 16C

V1 V2

10. In the figure shown, a block B of mass 10 kg rests on a A

bracket A (shaded) of 30 kg, All the surfaces are smooth.
2
Find the magnitude of relative acceleration (in m/s ) of
F = 200 N
bracket A (shaded) with respect to block B. (Pulley and B
string are ideal) m m
3m

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 9 RT-23 (Paper-1)-PCM-JEE(Advanced)

Chemistry PART – II

SECTION – A

Straight Objective Type

This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE is/are correct

1. Which of the following statement(s) is/are not correct?

(A) Na2SO4 is soluble in water while BeSO4 is insoluble.
(B) N2, NO+ and CO+ all are diamagnetic substances.
(C) NO3– is planar while NH3 has pyramidal shape.
(D) Among XeF2, XeF4 and XeF6, maximum number of lone pair are in XeF2.

Me2 CO  i CH CH MgCl 3 i O

2. D-Glyceraldehyde 
HCl
 A 2
 ii H2 O B 
 ii Me2 S  C
 iii H /H2 O

Which of the following statements are correct?

(A) C is CHO
(CHOH)2
CH2OH
(B) A contains carbonyl group as well as C  O  C linkage
(C) hydrogen deficiency index of B is 2
(D) B can decolorize Br2 / H2O

3. The example(s) of sheet silicates is/are

(A) Bentonite (B) White asbestos
(C) Mica (D) None of these

4. Which of the following is/are true?

(A) In  -graphite, the layers are arranged in ABAB…. sequence.
(B) In  - graphite, the layers are arranged in ABCABC…. sequence (rhombohedral).
(C) Graphite is poor conductor of heat as compared to diamond.
(D) When an electric spark is struck between graphite electrodes, soot is produced.

5. The expected spin only magnetic moments of complexes of a transition metal depend on
(A) Nature of ligand (B) Geometry of complex
(C) Oxidation state of metal (D) None of these

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6. Which of the following are not true?

(A) Among lithium halides LiF is most soluble in water.
(B) Anhydrous CuSO4 is a white solid, when dissolved in water, it gives a blue coloured.
solution, on addition of dil. NH3, a green precipitate is obtained, which does not dissolve
in excess NH3.
(C) In vapour state Li may exist as atoms or diatomic molecules.
O

(D) When compound is heated with NH3 an antiaromatic compound is formed

O
7. Which of the following reactions take(s) place during smelting step in carbon reduction process
for extraction of Pb?
(A) PbO  CO   Pb  CO 2 (B) PbO  C  Pb  CO
1
(C) 3PbO  O2  Pb3 O 4 (D) CaO  SiO2  CaSiO3
2

8. In a sample of hydrogen atoms all electrons are in a particular excited state n, when all electrons
returned to ground state, photons with 6 different wavelengths are emitted. Which of the following
is/are incorrect?
(A) Out of 6 different photons only 2 photons have speed equal to that of visible light.
(B) If highest energy photon emitted from above sample is incident on the metal plate having
work function 8 eV, K.E. of liberated photo-electron may be equal to or less than 4.75 eV.
(C) Total number of radial nodes in all the orbital of nth shell is 6.
(D) Total number of angular nodes in all the orbital in (n – 1)th shell is 3.

9. An aqueous solution of glucose (C6H12O6) contains 1 mole glucose in 1.8 litre solution. Thus,
which is/are true statement(s)?
(A) It is 10% (W/V) solution.
(B) Its density is 0.1 gm/cc.
(C) Solution contains 3.33 x 1018 glucose molecules per ml.
(D) Solution contains 24 gm atoms (as molecule) in 1.8 litre.

10. 20 ml of H2O2 is reacted completely with acidified K2Cr2O7 solution. 40 ml of K2Cr2O7 solution
required to oxidize the H2O2 completely. A 2 ml of same K2Cr2O7 solution required 5 ml of a 1 M
H2C2O4 solution to reach equivalence point. Which of the following are correct statements?
(A) The H2O2 solution is 5 M.
(B) The volume strength of H2O2 is 56 V.
(C) The volume strength of H2O2 is 112 V.
M
(D) If 40 ml of H2O2 is further added to the 10 ml of above H2O2 solution, the volume
8
strength of the resulting solution is changed to 16.8 V.

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 11 RT-23 (Paper-1)-PCM-JEE(Advanced)

SECTION – C

(One Integer Value Correct Type)

This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive)

1. How many sequences given are correct?

(i) CO2 < SiO2 < SnO2 < PbO2 (Oxidising power)
(ii) Picric acid < HF < HCl < HBr (acidic strength)
(iii) LiCl < BeCl2 < BCl3 < CCl4 (Covalent character)
(iv) o - methoxy aniline < m - methoxy aniline < p - methoxy aniline (basic strength)
(v) Benzoic acid > o - methoxy benzoic acid > carbolic acid (acidic strength)
(vi) H2CO3 > CH3COOH > H2O > C2H2 > NH3 (acidic strength)

2. Assume KBr, Li2O, Zinc blende, Fe2O3, CaF2, NaCl - all have perfect undistorted structures
(exact fitting). How many above given compounds have void fraction greater than 0.3?

3. How many square faces are there in truncated octahedron?

4. HgS, PbS, CuS, CdS, SnS, Bi2S3

(i) Among above sulphides, the no. of sulphides which are more soluble in water than MnS is x.
(ii) Pb(OH)2, Ba(OH)2, Zn(OH)2, Ca(OH)2, Cu(OH)2, Fe(OH)2. Among the given hydroxides, the
no. of hydroxides which are less soluble in water than Mg(OH)2 is y.
xy
The value of is
2
5. The conductivity of a saturated solution of Co2[Fe(CN)6] is 2  10 6  1 cm1 & that of H2O used
is 4  107  1 cm1 & the ionic molar conductivities of [Fe(CN)6] 4  & Co2+ are 444 & 86  1 cm2
x
mol1 respectively. If Ksp of Co2[Fe(CN)6] is 70.3  10  x , find the value of . (all data is at 25oC)
3

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6. How many of the following compounds can’t exhibit tautomerism?

O

Benzophenone Ph O C2H5 PhOH

O
O
H3C CH3
NH
O O _
AcO
Ph CH2 C CH2 C O CH2 Ph

NH

7. OH

CCl4 Ac2O AlCl3

A B C
NaOH H3PO4 

How many hydrogen’s in C are more acidic than H2O?

8. Br
+ A+B
N
H
The sum of  electrons  e  of  bonds  present in A & B is x. Find the value of x.

9. Number of hydroxides which are soluble in excess of NaOH among the following given
hydroxide?
Al(OH)3, Zn(OH)2, Cr(OH)3, Pb(OH)2, Mn(OH)2, Fe(OH)3, Ni(OH)2, Cu(OH)2, Sn(OH)2.

10. How many O atoms are there in final product (per molecule)?
Cl
i) aq. OH
ii) pcc in CH2 Cl2
 iii) OH
 Product.
iv) H

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 13 RT-23 (Paper-1)-PCM-JEE(Advanced)

Mathematics PART – III

SECTION – A

Straight Objective Type

This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE is/are correct

1. As n   which of the following tend to infinity

n! nn
(A) n (a > 0) (B)
a n!
 2n !
(C) (n!)1/n (D)
n! nn

x 1

 sin  e  dt
t
2. Let f  x   then
x
 
(A)  f  x  dx  2 (B)  f  x  dx  e
0 0

  
(C) f(x) has local/global maxima at x  n   (D) f(x) is continuous
 1 e 

3. f: N  A and g: N  B are two onto functions such that

f(n) = [n sec2 ] and g(n) = [n cosec2 ], for some . If sec2  is irrational, then (where [.] denotes
the greatest integer function)
(A) A  B =  (B) A  B = N
(C) f and g are bijective (D) A  B is non-empty finite set

n n
4. If  ar sin r x   sin x  x  R for real numbers a1 a2 ….. an, then  r ar can be equal to
r 1 r 1

1 2
(A) (B)
 
(C) 2 (D) 1

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5. a, b, c are sides BC, CA, AB of ABC on xy plane. If abscissa and ordinate of vertices of the
triangle are integers and R is its circum radius, then 2R can be equal to
8
(A) abc (B) abc
9
9 abc
(C) abc (D)
8 2

6. Let A, P, B are collinear points on the lines y = 0, y = 2x, y = 3x respectively. If PA·PB is minimum
(for a fixed P), then
(A) PA = PB (B) PA > PB
(C) Slope of PA lies in (–, –1) (D) A, B are equidistant from origin
2
7. The area of the region described by P(x, y) on xy plane, if roots of z + xz + y = 0 (x, y  R)
satisfy |z| < 1, is greater than or equal to
(A) 1 (B) 2
(C) 4 (D) 8

x2 y 2
8. If P be a point on ellipse   1 whose foci are S, S and tangent at P is at a distance d from
a2 b2
origin, then PS  PS' d2 is
a
(A) independent of a and b (B) independent of ratio
b
(C) independent of eccentric angle of point (D) less than or equal to max(a4, b4)
 
9. If a, b, c are direction cosines of a line and A  aiˆ  bjˆ  ckˆ , B  biˆ  cjˆ  akˆ , then angle between
 
A and B can be
(A) 45º (B) 135º
(C) 115º (D) 125º

10. A, B, C, D, E are points in space such that plane passing through any three points is
perpendicular to the line passing through other two. If A, B, C, D form a tetrahedron with all faces
acute angled triangles and E lies inside the tetrahedron, then
(A) DE is orthogonal to AB
(B) DE cuts the plane of ABC at orthocenter of ABC
(C) ABCD is a regular tetrahedron
(D) AB is orthogonal to CD

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 15 RT-23 (Paper-1)-PCM-JEE(Advanced)

SECTION – C

(One Integer Value Correct Type)

This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive)

2
1x  1 f 0 
1. Let f: [0, )  R satisfies   f  t  dt   f  0  f  x   x  [0, ). If f 1  f  0  , then is
x  4 f  2
 0 
equal to _____

 
2. Let f: [0, ]  R be a continuous function and  f  x  sin x dx =  f  x  cos x dx  0 . The minimum
0 0
number of solution of f(x) = 0 in (0, ) is _____

 8 2 2 
1 
3. If M, N are 3  2, 2  3 matrices such that MN   2 5 4  , then  10  det NM  is equal to
 2 4 5 
 

_____ (NM is invertible and [.] denotes the greatest integer function)

 2 2 4 4 6 6 8 8 
4.    1  3  3  5  5  7  7  9 .....   is equal to _____ (where [.] denote the greatest integer
 
function)

5. Let polynomial nx2 + ax + b has integral co-efficients and two distinct roots in (0, 1). If n  N, then
smallest value of n is _____

1 1
1
6. Let f(x) be a continuous function f: R  R with period 1 and lim  sin2  x   f  nx  dx  f  x  dx ,
n 
0
k 0
then k is equal to _____

Space for rough work

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RT-23 (Paper-1)-PCM-JEE(Advanced)
16

7. If |ax2 + bx + c|  1  x  [0, 1], then the maximum value of |b| is _____

 
 1
8. Let f: R  R is a continuous function and  f  x  dx  L . If  f  x  x  dx  kL , then k is equal to
 
_____

 1 
9. The value of 8  x x dx  is equal to _____ (where [.] denotes the greatest integer function)
 0 

10. Let polygon A1A2A3A4 ….. A8 is inscribed in a circle of radius R.

R2 
If A1A2 = A2A3 = A3A4 = A4A5 = 3 and A5A6 = A6A7 = A7A8 = A8A1 = 2, then   is equal to _____
2
(where [.] denotes the greatest integer function)

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com