, S> cH6 o"-J\ E

~ME: INDEX NO: .

CANDIDATE'S SIGNATURE. .

DATE: .
233/2
CHEMISTRY
Paper 2
March/April, 2019
Time: 2 Hours

POST EVALUATION EXAMINATIONS

K. c. s. E. Post Evaluation Examination
233/2
CHEMISTRY
Paper 2
Time: 2 Hours

INSTRUCTIONS TO CANDIDATES

• Write your name and index number in the spaces provided.

• Answer all questions in the spaces provided
• Mathematical tables and silent electronic calculators may be used for calculations.
• All workings must be clearly shown where necessary.
• Candidates should check the question paper to ascertain all the pages are printed as indicated and no
questions are missing.
For Examiners Use Only

Questions Maximum Score Score

1 12
2 12
3 12
4 12
5 08
6 14
7 10
TOTAL 80

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 1

I. The grid below represents part of the periodic table. Study it and answer the questions that
follow. Letters are not the actual symbols of the elements.
- -
B
Q R S
T U V W X Y
Z

(i) S7i a letter that represents the most reactive non-metal Explain (2 marks)
·····>···~···~·X~·····6~···~·····~·~··T··~·····~······ ..
....................................................................................................... :~ .
..................
~~.~~~~ .....
~.~.~.S
..\ ....
~.~~.....
~.~.~~.: .
(ii) Select a letter that represents an element that forms an ion with a charge of 2- (l mark)

::::::::::X:::::::~::::/:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
(iii) Select an alkaline earth metal (l mark)
·············U··~·····~·····f························· .

(iv) Which group 1 element has highest first ionization energy. Explain (2 marks)
............ / ..l /.~ .
......9.: -: ~..7t ~.~.~~
~~.~
~.~c::.. ~~t~.~.
....................
~~~ ~~.~~.~~ ~.~~:-:.~
~ ..~+.~
.: ~.~ ~ ?~.~:.~ ~b ~~.I ~±'.~~~~
~~? ~ 3
X
e
~Vh.~t.i.S.th .f7~~
c~
~.~t~:
~o.~PS~~~~.
3
~~.~~~~
.~~~.~.~
n\~
.~~~~t.~
~.i~~.~~

.................................................................................................................
'' ~~~~~..
,

(vi) What type of chemical bond exists in a compound formed when Rand S react?

............ C
o~kV\
,
V \ . (l mark),
.

(vii) Explain why the atomic radius ofS is srpaller than that ofQ. (2 marks)
................................................. ,.v:-:. , ..- _.,. ,: .
S It-..-0':3' ~~ '\R\."'\ Q
~~~ ""'5'-' ~v...~
....................................................~.···································v··f·········
••••• ~~~.~.I

-to ~
•••• ":-!:~..~ ~
Y'\ \A. J_Qy,. -1 ~ "'-
::--:~~~
Q,
~.~.~<Sj ~~~.~J

(viii) Explain why molten calcium chloride conducts electricity while carbon tetrrchloride
d~\~~t con~u~\ e~c~icity c.J,.J oV"\~k. c~'"~ "" rfrt.t- ~ (, ti2 marks)
....
M ~ \~

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 2

 .0..~~'~~.<?~~.~~ ...~.\.~.~~.0~
..'. s-:~~~.~;.r.~~.~~~~~
....
~.~.... ~.o
...~~ ~~.S.~..{.~~....\.~~~.~....r-::~~~.~\~
...~~.~ ...~.~~..~..~.~..
co~~~ck ~le.~~u:f-;
.......................................... ~ .

2. Study the flow chart below and answer questions that follow:

H2(g)
Step I
Catalyst I-----gas
I.••••• B

GasQ+ ~_B_u_r_n_in_---+Ammonia ZnO Products

water Oxygen gas Step II

Oxygen + catalyst
Step water
III

I Compound P~ :----+:NH3
Nitric (v) acid ! Sten TV Potassium Nitrate
solution

Step V Cu

Excess
Crystals of
. sohd S
1
J
Step VJ I Solution S ~I
I--------.. Product X I
I NH3(aq)

Step VII

Product B + Gas C
+O~~ngM I
(i). F;t:~x.~~,:.r
~asl,'s ~.f A-l\l. 4:9.~....()*.....<-.\'L~~J .....
~ ..(I. ~~rk) ..

(ii) Name the catalysts used in; / I (2 marks)

.....
Ff.~s.I
..~.~~A l~.~ .. ~±.(;Js.t.\.,r.~.~ .
b) Ste~ III , V" f
... ..... .... ..P..'
\
0..~ n \.A. ""'- ?2... ~ c AA ~ IV\.
.

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 3

--
 (iii) Write chemical equations for reactions in; (2 marks)

· .....•. ~~ .. ~~~~ .1.1........•..•...•...•...............•..•....••..•.....•......•....•......... /. .. J ..... ~:~:.:'

3'?-V\O
.••..••.••••••••••••
+ ~NI-f- 3.~)
\~J •••••••••••••••
~3?V\ t>;r
BH- ;:t 0ct) t t\)~.,
GJ .

........ b~t~r. .~[[ ~R-~t :i.' -C'" O········/FN······,······0" 0...f. .

..?:.~ ~.~_)~~ ?: ~ ~~.~: ~~~!~.0. .
(iv) Name the process that takes place in; (2 marks)

........ ~~..~~~~.I.~ ~4~~

N~.~t~.~ v. ! .
b) Step VI -
····················E:;:;1s~~:;.:;t:~~···V····/················ .
(v) Name and write the chemical formula of product X I
Name '-'-~~G\..~~ CoP~[Ll) I o~ / (l mark)
· \ .
Formula t ( (l mark)
· [c. .lA. @. .ff-~.tf-J.~ v. :..
(Vi)p~p~::.~s~f.~O~.~~.~.QJ Q)C/r~.v,( J..(l.~~rk) .

.g:Z~~.7 ~on:~II ?
........fj.~ .

I~:~::~Z
~.:>'&1' 'i'~''0;.~~~;.
(vii) ~.s; i~~ .st~:. ~~rk).

;~i;;;"~~;~.~~~., ~~~.~ .'J. "

...:-:.~~b.~~ ~ ~.~~.~.~ :..
_ \ '-A- c.....()", t" \0 vJb~ '"
····~·······~v~~·v-:·r-·····~····:S.~~·~····~·s·~i0:Q.·V\······· .
3. a) Give the systematic names of the following compounds (2 marks}
(i) CH3CH20K
··········p~·~-'~·~·~····~~Di.;~····~····f.·············· .

(ii) CH3CH2COOCH2CH3
..........ESR:j' \..('<-D' p~;~;;,:o'~ v. j. ,

b) Describe a chemical test other than burning that can be used to distinguish between _

.....
~~6bk~.~~~;,)~t~.~
..~ ...~.\~':.::~
.....~.d~ ::~,.~~4:J~~~
...

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page L1

 .> j.i

~~~~.~~~ .
.~~.~ ;:~£"~~'" ()~.i.i~':':~""~" ~ ';;1';'" ~ ~
r .....~ e:.~.~ ~ ~~~LQ.J,: ~'t:l.l.\ 'LQ .
c) Study the flow chart below and answer the questions that follow.
Polvmeri
o ymenza tiIOn
I CH3CH3 I I AI
I I .QJ
Step 5

K(s) I
C+ i Ethanol
I
~ C02(g)+ H20(1) I
Hydrogen gas Step 4

Acidified
Step 1 KMn04(aq)

I. E l.r-----'-'S.>..LIOdULaj.J,J]j.ll.mu...e_-i~I-------- ••1 Propyl ethanoate

r Step 2 step 3
(i)
~ame ~~:.~e.~.b
-s.\~.'"'"..~~ '? Y. (~~ ..•. ~ .. ;. ...•............•.
(l mark)

II. E -?.~.~.l.~.r::-~~~::.c:.'::~ ~ z:. .

ii) Write the equation for the reaction in f (2 marks)
Step I C {-f l-\ M.V'\C;.> .. C ~ .
.. .... ., ~ ~.~ ~ ~ ~~~ ~ H. ! ~
~ =:~.~~ ? ~?:- ~.t.x ~ {
Step 3 (..: H-~ .~~Ptl.~v'+" C. H'2>'(.H~C.f:f-~.0..H-b; ...• " " ~ .C./h CO.O c. U~~.~ C~
... ..: G-~ ..~-t:.H~q:;. ~
~~l? ~.lL~~~~;,e.t~~~
.9:~l.p.~:~~~~C~JJ~~~·.~cl.
~ !. ~~.~~~~~~.
.............
y~~~ v. ~ .
iv) Calculate the mass of ethanol which when burnt in air at room temperature and
pressure would produce 10dm3 of carbon (IV) oxide gas
(C = 12.0, 0 = 16.0, Molar gas volume = 24dm3) + 3 Ii 0 V' ( (3 marks)

···~~1~~~i9L~:-·t;;,:c~·······:?·~~·~~·c4):·~6k····
···································3·················· _ .
\ ~&l - ~ If'J.. ""- ~
..................................~ ·················································v··t
................ vI.:L ..~.?~ ~ v..~ -:-: 0.: .~Q. .?~.~~o~
........~.? ~ ..1 ::;:; 9:. f.~.~
..~.~~~ .
'J..-lf
M

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 5

4. In an experiment to determine the molar heat of neutralization of hydrochloric acid with
sodium hydroxide, students of a secondary school reacted 100cm3 of 1.0M hydrochloric acid ..
with 50cm3 of 2M sodium hydroxide and obtained the following results.
Initial temperature of acid = 25.0°C
Initial temperature of alkali = 25.5°C
Highest tempature reached with acid and alkali mixture = 34.0°C

~~
..~~~~::.~~.~~~~~~~~~~~~~.~:.q.<:~~
~~ ...~ ..~~~~~I
....~~ ....,:\.~~.~ ...~~ ..~ ...~ ...P~~.0: ~.~ ....~?~~..~-f..~.~
b) Write an ionic equation of the reaction between hydrochloric acid and sodium hydroxide.
+
.........H..(t\-t;>.. f ..~.1}: .. ~'&J
-
:?>
H 0
;;L.
..,/' I
(1)' ..•...••......•......•................•............
(1 mark)

c) Calculate: I
(i) The change in temperature. / (1 mark)
..............3'~: .~.: '~j-;:i?".~ <3',''f~' . c······\."'<6 ': ~~'K"
0 .
.................. I.

(ii) The amount of heat of neutralization of sodium hydroxide. (Specific heat

___________
\P'~Ci~~~.~~)_\?_,
\ OOD
+c- __
:= ~_S; -s; --k.T- _ v.- -I- <1_~":,k)_.
•••••••••••• , •••••••• II •••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••

0'\ - ~ 'rS~J sS'/o<-,1 ~(\

d) Write the thermochemical equation for the reaction. ' \ .- ~~ {;l-I rr mark)
-----1't CT -~- --+--".1:':- O\1-~-~-----------y.:-N;';: cr~-+ -H';"q;; --Eft";'C- -~S-,;,J M .('

······················································································C
.~~.~ ...)L:':-:~~
e) Draw an energy level diagram for the reaction. \0 ~ ('L'~k~)
~ J--v

-'\
c.-k v ~~ '" ~3:1
\ f-!---=---~~"':"":"----.:J~I:L

ClV\ ''''~ ~~.u

f) Use the information given below to answer the questions that follow.
2H2(g)+ 02(g) • 2H20(l) ~He = -572KJmol-1
2H202(1) • 2H20(1) + 02(g) ~He = -196KJmol-1
© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 6
 (i) Calculate the standard enthalpy of formation of Hydrogen peroxide (2 marks)
H C) 6.W.?.. :7 ~ H.;>..O~q LIi:l- -=- ~ 1-+,- tx H-.3 V I
:l. :L~ + ~ ) I) ~d+.;l.-::=. E59-~X0- (-I ~G X ~ V /
6~ 4 '-1 .- fI Lf-tf- r 3,S'~ -z: - 1-'1 :J... liS
/::>\\ \ o'r ;;Z ~ol~ - 'tCj~Kf
~ . H J...0C1.J + I tv-. <1:13 -== .- 3968'
o2..e..J ~\ _

(ii) Draw an energy cycle diagram for the information above linking it with the enthalpy IV\.() \ -\

of formation of Hydrogen peroxide. (2 marks)

:z H :l. ~..>
+ 0
;;l~
6.H :::::-1-9.2.~ .:z H.;>..O~ I
( J

:tHO -1- 0
~ (I.J ~..J

5.

Lead (lI) oude 1

I

Dry
--..!+-=- =::::=
ffplrllgell """'--..GIfIII-----
~

~~~~~-·liquid Q

.1.
 a)i) State and explain the observation(s) made in the combustion at the end of the
experiment I V
Observation e (l mark)
......... &.~.-:~.~.~ ..... ~~.~.~~.~!.'.~....~~.':.~~...~ ...:. ..~~.j ... ~Rh.~ ..

Explanation • / I (l mark)
....~j-~4~~~~ :.~.&.:.~.~ ~.~.~.~.9Y
..~::;.~ ~ ~.~.~ ~~~ .

b) Write the balanced chemical equation for the reaction in the combustion tube (1 mark)
········P·b·6~~·:t··H·~·~···········:;···P·b······i-···H~o····v····l·················
................................ fO) ~) C\) ,,- ..

c) Give one chemical test for liquid Q . (l mark) ./ I

.....- B.\.~ ~<?.!q~.l.t..(I.'.-I ~~.l.~.~ <:-:I::.~~~..~ E\~.'S ~j.Q.'!'!l .
.......~.~.~~~ ~~.f.q.~~~..~.~.\f.~:~ 0.-:~.~.~~ ~.~.~..: .
d) Explain what would happen if magnesium oxide was used instead of lead (II) oxide in
the experiment
ND
( 1_
6 b s; e--... v CJ~\0 ~
r- n
L,X,~o..
v-... 0{) V
/ (112 mks) 1-
......•.......••.••••••.••.........•...•........••...•. .0-:--.•......•....•.•.•........... t·······················
.......
y:t~·~~~·~····~~:~·?~\·····~·~~···~···~·····7:·~.~
...~.~~~
~o,"\ ~<A~~..s~'-"-"\ ox;c:l!t. \-\-~~~ \0 W~ ~A...~~ \~",'
...... ·~·o..:.~1· ~ ~ .., .
ii) State one observation made when a small piece of potassium metal is dropped into a
trough containing liquid Q V I
......
\.~.~.~ ~.f.~.:~~.:.~~.~~
~ ~ f.~.c:..~..~.~~.~~~~~ ..
e) Name anyone source of Hydrogen gas. (l mark)
........ ~. ~.c:-:-.~ .~ ~.-S- ~ \~ ~~ ,y...J. .
......... ~~.~.~.j~.~:.$ ~ ~~~~~~~ ~~ .. (~rJ yr.~.~?~J

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 8

 6. The flow chart below shows a sequence of reactions involving a mixture of two salts,
mixture M. Study it and answer the questions that follow.

I ,Mixture M I
Step 1 (i) Addition of water
(ii) Filtration
,

I Solid N I
1
I Solution P I
Heat (i) Acidified barium
Step II Step VI nitrate solution
(ii) Filtration
Black solid Q and gas
which forms a white 1
precipitate when Colourless I White solid I
bubbled through calcium solution
hydroxide solution
Step VII 1·
Excess aqueous ammonia
Step III Dilute
Sulphuric (vi) acid
..--~---.L--, White ppt which
Blue dissolves to form
solution S colourless solution

Step IV Excess queous Step V

ammoma
r--..1...----,
magnesium powder
Deep blue Products
solution

a) Write the formula of the following; ./ J

(i) Anion in solid N c.. 0 2.. - C ~~ Gt- Y\ ••••~ ~ (1 mark)
.............................................. .? .
(ii) The two salts ..nresent in mixture M V ~ (1 mark)
Cv... CO v1/Ovv--cl L- ~ SOLL..
.......................... 1> -1 ••••••••••••••••••••••••••••••••••••• •• ••• •••••••••••

b) Write the ionic equation for the reaction in step VI I (1 mark)

0000000 o@;~::l-~o 0 0 of" S0 0 °b::~~o 0 0 0 0 0 0 0 00 jO 0 0 B~ 0 So.;.:;~ 0000 0 C~ ~ i,.;:';;";~ 0 ~

...................................................... ·······························4~~···\rIY:'i)·~
c) State the observations made in step V r V t (1 mark)
......(6..~.~. ~: s;..~ h.~ ~.9.~.\ ~.J.. 0.-:t:- .
.......
e.\.~ ~.~].~~:.?t ~~.f.~~J~..~~.\p.~.~.~ .

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 9

l~ -===--
 d) In an experiment to determine solubility of potassium chlorate, 5g of potassium chlorate
(KCI03) was dissolved in water and solubility of the salt was determined at various
temperatures as shown in the table.

Volume of distilled water Temperature at which 1st Solubility of solid of I

(em") crystal appears (OC) (g/100g of water)
4 68.0 I::tS'o V
6 58.5 g.3 f 3 V
8 53.0 6.:l.'~ v ..
10 47.5 5:'0,0 1/'

12 35.0 Y-l' 1- JI A •
~~--~MVK.-

~).. ~.l~~~.SOI~b~~.~.~t .... ~ .. ~ ~.\~ .. ~~t~~~

.... '. ~ ~~ ~.~ c:-: ~c:.\~::.t .I.~~~~
c:.:t. ~ ~~ ~.r

b) Complete the table by calculating the solubility of potassium chlorate (2 Yz marks

c) On the grid provided, plot a graph of solubility of potassium chlorate (gllOOg of water)
against temperature (OC) (3 marks)
'1~()

i,

-V1
01
- "1 -

I
l::t
L"
m
_

© 2019 POST EVALUATION

I
EXAMINATIONS CHEMISTRY PAPER 2 Page 10
 d) State the relationship'~between SOlUbilit~siUn; chlorate and tem~n (! ma~ J

······~~·~~~····~~·1:~··············\·~
....... \.~ kl ~ ~ ~ ;~.

e) Use the graph to determine:' /

.... (i) ~;;lr;·::~·SiU~;I~~:.~·j:··r···············

(~.~~~)
(ii) The molarity of the solution at temperature stated in e(i) above (2 marks)
(K = 39, Cl = 35.5, 0 = 16)
········································V··~·······························~·t················
.......~.~ ~ ££-:- :::;;Q:.'+Cf.:fl.g ~ .
r~~(sr /.k. .
...................~.§ tyr b-< .
"'-"- S\ ~ - '0 ''f-4-e=:-:g•• ~\t•••.•••••••••••••••••••••••••••••••••.•••••••..••••.•.•.•
(0 D 0
10
•••••••••••••••••••• • ••••• ~ •••••••• i ••••••••

D ', '

:::::::::::::::::::::::::::::~::::::if:i:if.f::~::::~:~:::::::::::::::::::::::::::::~::
7. The diagram below represent the blast furnace for extraction of iron metal. Study it and
answer the questions that follow.

Iron ore. carbon

and limestone

•••••
a)..~~~~~.~~~$.~~.;N~e.~~~~C~~J.i~.;tC}jO.firO~
(I.~~k).

b) In the blast furnace carbon (II) oxide is used as a reducing agent. Write an equation for

....tF;act~n.b.~t:~;C~~.(II)~~i~;~~.~.~~r~~
2... 3LS",
..Co. ..... /.
~ (J) ~ a,
!..
.... ~~.~~~l~~..

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 11

 c) Silica impurities react with calcium oxide from the kiln.
(i) Write an equation for the reaction (1 mark)
Co..O t .£~0..2. ~ C C\ ~ltcJ.3
V I
{51 c~ (I)

(ii) Explainwhyit is possibleforthereactionto occur. / J (I mark)

.....
'[,'~\j 'o'X;'~"~""
'~':;"~'" b'~~" 'Dic' C1ti ... ~J;":,:{;;'(fi""W"\'tt: 'qi'~
.......S'L'~L))"
\\:X)'· '6'Xi~':+o'" .~ (:0( ('t\:.~.~ ~\ '(:,,(c&L .

~).~~I::~r:~i.~.~.~~:;~.;lec~::·lt;;;·::·J·;:S··P~·~·1~I;t)··
d~.c.t:.~J::"""G::L'c.t:~ t·:·················································],v
........
e) Iron is malleable and ductile. Give the difference between malleability and ductility
(2 marks)
Malleability ~ • V, I
.......
h.~.~~~ ~ ~ ~.c::.~.~~ \.~~ ~~ .

:::.~iiY~t::~:::::.~:::.~:~;....:\~~~.:
...;':\;?'J::..::::.>

© 2019 POST EVALUATION EXAMINATIONS CHEMISTRY PAPER 2 Page 12