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Tutorial 3 PC January 2019

This document provides a tutorial on physical chemistry concepts including heat capacity, specific heat capacity, Hess's Law, enthalpy changes, standard enthalpies of formation and combustion. It contains 15 problems for students to work through involving calculating heat, temperature changes, enthalpy of reaction, and using standard enthalpy values to determine other reaction enthalpies.

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Nur amirah
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Download as PDF, TXT or read online on Scribd
175 views

Tutorial 3 PC January 2019

This document provides a tutorial on physical chemistry concepts including heat capacity, specific heat capacity, Hess's Law, enthalpy changes, standard enthalpies of formation and combustion. It contains 15 problems for students to work through involving calculating heat, temperature changes, enthalpy of reaction, and using standard enthalpy values to determine other reaction enthalpies.

Uploaded by

Nur amirah
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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TUTORIAL : PHYSICAL CHEMISTRY

CLB 10703
January Semester 2019

Name :
Student ID : Group :

Tutorial 3

1. Define heat capacity and specific heat capacity.

2. State the Hess Law.

3. Calculate the amount of heat that will be produced in the thermochemical equation below if
13.5 g of solid aluminium were used.

4. Consider the following thermochemical equation :


2N2 (g) + 4O2 (g)  4NO2 (g)
Calculate the amount of nitrogen gas that must react with the oxygen gas to produce the
enthalpy change of 7.5 kJ.
[email protected]

1 Universiti Kuala Lumpur | Malaysian Institute of Chemical and Bioengineering Technology


TUTORIAL : PHYSICAL CHEMISTRY
CLB 10703
January Semester 2019

5. Calculate the internal energy of a system if 2.25 kg sample of gold are cooled from 1124°C to
187°C. Given the specific heat of gold, sgold = 0.129 J/g.°C.

6. Calculate the heat capacity of a liquid if 934 J of energy is supplied to increase the
temperature from 28°C to 88°C.

7. The heat capacity of 513 g of mercury is 86.52 J K-1. Calculate the specific heat capacity of
mercury.

8. Given that the specific heat capacity of NaCl = 0.864 J/g.°C. Determine how much the
temperature will increase if we added 75 joules of heat to 75 g of NaCl at room temperature.
State the final temperature in degree Celsius.
[email protected]

2 Universiti Kuala Lumpur | Malaysian Institute of Chemical and Bioengineering Technology


TUTORIAL : PHYSICAL CHEMISTRY
CLB 10703
January Semester 2019

9. Combustion of graphite to carbon monoxide is shown in the equation below.


2C (s )  O 2 ( g )  2CO ( g )
Determine the ΔH for the reaction. Given:

10. Differentiate between standard enthalpy change of formation and standard enthalpy change
of combustion.

11. A sample of hydroxyethane weighed 0.85 g was burned in a bomb calorimeter. The
temperature of the calorimeter plus contents was recorded to increase from 29.5°C to 64.7°C.
(Heat capacity of hydroxyethane = 112.4 J/K)
a) Write a balanced chemical equation for the reaction.

b) Calculate the enthalpy of combustion per gram of hydroxyethane.


[email protected]

3 Universiti Kuala Lumpur | Malaysian Institute of Chemical and Bioengineering Technology


TUTORIAL : PHYSICAL CHEMISTRY
CLB 10703
January Semester 2019

c) Calculate the enthalpy of combustion per mole of hydroxyethane.

12. The enthalpies change of formation of ethyne, hydrogen and ethane at 25°C are shown in the
table below.

Substance ΔHf0 (kJ/mol)


Ethyne - 1300
Hydrogen - 285
Ethane - 1560

Calculate the enthalpy change for this reaction : C2H2 + 2H2  C2H6

13. In an experiment, 5.46 g of glucose was completely burn in oxygen. The heat produced was
found to raise the temperature of 18.6 dm3 of water by 14.9°C. Calculate the enthalpy change
of combustion of glucose. (Mr glucose = 180 g/mol; specific heat capacity of water = 4.184
J/g.°C)

[email protected]

4 Universiti Kuala Lumpur | Malaysian Institute of Chemical and Bioengineering Technology


TUTORIAL : PHYSICAL CHEMISTRY
CLB 10703
January Semester 2019

14. Find the enthalpy of formation of butane by using the following data.
ΔHc : C4H10 (g) = – 2877 kJ/mol
C (s) = – 395 kJ/mol
H2 (g) = – 286 kJ/mol

15. Use the following enthalpies of reaction to determine the enthalpy for the reaction of
ethylene with fluorine.
C2H4 (g) + 6F2 (g) → 2CF4 (g) + 4HF (g) ΔH = ?
Given :
H2 (g) + F2 (g) → 2HF (g) ΔH = -537 kJ
C (s) + 2F2 (g) → CF4 (g) ΔH = -680 kJ
2C (s) + 2H2 (g) → C2H4 (g) ΔH = 52.3 kJ
[email protected]

5 Universiti Kuala Lumpur | Malaysian Institute of Chemical and Bioengineering Technology

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