1 AITS-FT-VIII (Paper-2)-PCM (Sol.

)-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018

ANSWERS, HINTS & SOLUTIONS

FULL TEST – VIII
PAPER-2

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

ALL INDIA TEST SERIES

1. A 24. B 47. A
2. C 25. A 48. D

3. B 26. D 49. A
4. ABD 27. ABCD 50. ABC
5. BC 28. ABD 51. BD
6. AC 29. AD 52. ABC

7. BCD 30. ABC 53. ACD

8. AD 31. ABCD 54. ABCD

9. C 32. C 55. B
10. B 33. A 56. D

11. 4 34. 4 57. 8

12. 1 35. 2 58. 9

13. 2 36. 7 59. 5

14. 6 37. 9 60. 5

15. 4 38. 5 61. 2

16. 3 39. 4 62. 0
17. 5 40. 2 63. 3

18. 2 41. 3 64. 1

19. 1 42. 6 65. 2

20. 4 43. 9 66. 5

21. 00000.73 44. 02806.28 67. 00102.01

22. 00008.89 45. 00001.02 68. 03600.00
23. 00056.56 46. 00001.48 69. 00007.75

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 2

Physics PART – I

SECTION – A
1. A
Field due to arc A’B’ is equal to field due to side AB at the centre
y
of arc. Similarly it will hold for other pairs also. So the field at the  0,3m  A
incentre is zero. 


ax  bx2  cx3 ay  by2  cy3
x= 1 y 1 
A' 
abc a bc  
3 3 
B' C' C
x= m, y= m B x
    3m,0 
2+ 2 2+ 2

2. C
Since water in the smaller vessel is taking heat from the water in the large vessel. It can reach to
a temperature 100C . Since the temperature of water in the large vessel cannot go
beyond 100°C before boiling completely. Hence water in the smaller vessel will not take heat from
the water outside, it will not boil.

3. B
Magnitude of flux
q I I
 E2  E1 A   2  1 I  ρ1 ρ2
0
q 0 I 1   2

4. ABD
2 1 80 1 16
T+  200   20  16  T  80 / 3 N and  f  10   42  f  N
3 2 3 5 3
For maximum value
1 2 2 1 2
of   T  400 / 3  20    & T  100  10       5rad / sec
2 3 5

5. BC
e=B0 v0  2 y   4 B0v03/ 2 t
e Bv
i  0 where  y  4v0t
 2y 
 B0 v0  2 B02v0 y 4 B02v03/ 2
F    2 y  B0   t
    
  2 B 2v 2 y 4 B 2v5/2
p  F .v  0 0  0 0 t
 
6. AC
From monkey frame
  
v am  va  vm  40 ˆj m / s

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 3 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

40
time= =1sec
40
7. BCD
Taking torque about R.H. side of loop

mg -T1  ibB=0
2
 -πnir 2 Bkˆ
8. AD
T/A 
where T  M    x    x 
2
Y
x/  YA 
  1
 M 
2

And ms   U
2
 
YA  1 
   YA 
2ms   1 
 M  2 

9. C

10. B

SECTION – C
11. 4
Sol: For solid sphere under pure rolling motion
5 1
KE translation = KE total = KX 2max
7 2
 X max =4cm

12. 1
V2  dT 
=4  T-T0  +4  
R  dt 
T dT t dt V2
T0 V 2  0 C  T  T0 
4R
1  et   N  1
 4  T  T0 
R

13. 2

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 4

Sol. 1 
Hence dm  d F
2
Hence radial component of tension, O dθ
d
 2 F sin  Fd F
2
nd 2 m 2 R
Fd   RF 
2 2 F dθ
increment in radius is  R so elongation in length of
2
ring
  2  R  R   2 R  2R
O dθ
 R  
Strain   Y   strain 
2 R R strain Y
2 2
R  m R F
  R  N 2
R Y 2 AY
14. 6
Consider the object as two portion ‘A uniform rod’ and ‘A frustum’ with thermal resistance R1 and
R 2 respectively then
1 
R1  
k1 A1 k r 2
And R2   2  


k2 A2  2k  r1r2  4 k r 2
 Equivalent thermal resistance Req  R1  R2
5
 Req  ....................... 1
4k  r 2
Now if we consider the same lamina with equivalent thermal conductivity K eq , then

keq

 

  3
Req  R1  R2    ........  2 
keq  2 r  2keq r
2 2 2
keq r
By equating the terms of Req from eqn. (1) & (2), we get
5 3
2

4 k r 2keq r 2
6k
k eq 
5
N  6

15. 4
As initial angle of approach with horizontal is 45° whereas
the river velocity is zero then  =45°
At point B, v S / G along the perpendicular to line AB is zero

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 5 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

and   75  45  30 v

u 1  =30°
 v sin 30  u sin 45  
v 2
u 45°
Also at midpoint P, vriver   u
2 B
u u 1 P
 v sin   sin   sin   sin 45 
2 2v 4
1 A
α  sin -1  
 4
N  4

16. 3
p 2 m 2 m v0
r  same T  T 
qB qB qB

As T  3T they will meet at    / 2 +
 
T 6 m 3
Time is     750 s   250  3 s 3v 0
4 4qB

17. 5
Let v1 and v 2 the speed just before collision. Using COAM about point O on the ground
+Q m -2Q
2m
A B


O
2 v 2 v  42
0  mv1 R  mR 2 1  2mv2 R  2mR 2  2   v1  v2
3 R 5 R 25
2
1 12 v 1 5
K A  mv12  mR 2 12  .mv12 
2 23 R 2 3
1  2 1 14
K B  2mv22  1    mv22
2  5 2 5
K B 42  v22  25
  
K A 25  v12  42

18. 2
x=u x t      1
1 2
h  u y t  gt      2 
2

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 6

uy ux
Eliminating t and using sin   and cos = and θ
u u
substituting in equation (1) and (2) h
gx 2
h 1  cos 2   2  x sin 2
u x
Differentiating w.r.t.
x 2u 2  u2 
 for maximum value of x  tan 2  x  h  
h g  2g 
So maximum Area =  x 2  209000m2  0.2km2
19. 1
1 100
X L  wL  100  X C   100
wc
i3
100 100 100 1H
i1 = =1A  i 2   1A  i3   1A
100 100 100
From phasor diagram i2
100μF
i1
i i1
i3
i2
100V,100 rad/sec
So i  i3  1A

20. 4
Using WET from a frame moving with velocity 8  ˆj m / s  
X max 1 2

 0
qv0 B0 x dx cos180   m v0 2
2
   X max  4 meter

SECTION – D
21. 00000.73
Impulse due to ‘N’ would act at the centre of the colliding parts


 L-x 
 
 2 
x N
2
Applying Impulse momentum theorem
  N .dt  M  v  v0     (1)
& Applying Angular impulse, angular momentum theorem
 Lx ML2
N
  2  .dt      (2)
12

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 7 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

 L x
 v
 2 
Also e     (3)
v0
From (1), (2) & (3)
 2
 L x    L  x 2 
v 1  3     v0 3  e
  2    L2 
 for v  0
 e
x  L 1  
 3
For inequality to hold true for all ‘e’
 1 
x  L 1  
 3
or x   
3  1 ,  xmax  0.732

22. 00008.89
Power absorbed by shell
P×2π 1-cos37 

4π
P

10
For equilibrium
P
  3 R 2 T 4
10
P 2400
T 4  2
  8.89
30 R  30  9  
23. 00056.56
Applying conservation of angular momentum w. r. t. the centre of earth,
4 R  mv0 sin 30  mvR, v  2v0
Applying energy conservation
1 2 GMm GMm 1 2
m  2 v0     mv0
2 R 4R 2
GM 64  106
 v0    40 2  100m / s
2R 2
 x  40 2  56.56

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 8

Chemistry PART – II

SECTION – A
24. B
Sol.
O
O
O
*
* *
H  Cl   O
: O: O Cl

Cl

25. A
Octanol and water are insoluble.

26. D
H
N (I)
'X'  NO 2 CH3

N
(II)
First step is EAS and in 2 step N(I) is better nucleophile than other N(II) .
nd

27. ABCD
O O
N N diamagnetic because no unpaired electron
O O

N
paramagnetic due to presence of unpaired electron.
O O

O O
N N
O O O
HNO3, H2SO4 etc. are responsible for acid rain

28. ABD
E0Cr3+ /Cr2+ <E 0Fe3+ /Fe2+ <E Co
0
3+
/Co2+

29. AD
Hydrolysis requires a   galactosidase, showing that galactose and mannose are linked by a
  galactosidic linkage. For sugar to be reducing, one of the hexoses must have free
hemiacetal form.
The methylation /hydrolysis procedure shows the point of attachment of the glycosidic bond to
mannose. C1 is anomeric carbon on mannose ring and both    forms satisfy the above
conditions.

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 9 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

30. ABC
2+ 3.2×10-11
Step-I:  Mg  = 3 =2×10-4 M
4
2+ -4
Step-II:  Mg  =2×10 M

2+ -4 100
Step-III:  Mg  =2×10 × = 3.33 10-5 M
100+500 
Step-IV:

Mg(OH) 2 (25ml of 2×10-4 M or 0.005 mmole) is mixed with MgCl2 (225ml of 0.06M or 13.5 mmole)
13.5
so  Mg 2+  mainly from MgCl  M
2 250

31. ABCD
Na/EtOH Li / NH3   
 
N H3C N CH3 H3C N CH3
H H
P Q
H 2 O/H +


H3C N CH3
H

H 2O


OH
H3C O H3C N
NH2 CH3
H

Tautomerism

O
NH

H 3O +

O
O
R 
OH 
 Aldol reaction 
O

CH3
S 

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 10

32. C
O O

A= B=

33. A
O
O O +
S
S H 5C 6
H5 C6 -
F= (E)= O
O or
H
CH=CH2
CH=CH2 CH=CH2

SECTION – C

34. 4
K a2  K a1
G    RT ln K a
ΔG1° >ΔG °2 ,ΔG 1° and ΔG °2 are both +ve due to K a <1
ΔG10  ΔH10  TΔS10 and ΔG 2 0  ΔH 2 0  TΔS2 0
ΔH10  ΔH 2 0
 ΔS10 is more negative than ΔS2 0 .
ΔS10 and ΔS2 0 both are negative because water is more organised due to hydration.

35. 2
N2   2 NH 3
3H 2 
t 0 4 16 
t  teq. 4  a 16  3a 2a
P  1  20  R  T
9
P  1   20  2a   R  T  a  1
10
On adding 'x' moles of inert gas at constant volume, equilibrium composition does not change
9
 P  1  18  R  T
10
P  1  18  x  RT
x2
36. 7
CFSE  Eligand field  Esymmetric field

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 11 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

0.6 0

0.4 0

  -2   3  
= 5×  Δ 0  +  2× Δ 0  +2P  -2P
 5   5  
4
= 0
5
4
  87.5  x  70
5
x
 7
10

37. 9
Λ m =Λ m0 -A C
For KCl
120=150-A 0.0625
A  120
'A' will remains same for KCl and NaCl (1:1 electrolyte)
For NaCl
x
90=126-120
100
x9
38. 5

ClF3 , XeF2 , SF4 ,  SbF4  , XeOF2 are having lone pairs at equitorial position.

39. 4
degenerate states are

2s1 2s1 2s1 2s1

1s1 1s1 1s1 1s1

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 12

40. 2
  CCl2
CHCl3 +OH - 
H

 CCl Cl
2
C OH 
Cl
Cl
 CCl
2

Cl
OH - C
Cl Cl Cl
Cl
It has two plane of symmetry

41. 3
LiCN,Na 2CO3 ,NaHCO3

42. 6
Chalcocite Cu2S, Argentite Ag2S, Horn silver AgCl, Siderite FeCO3,
Azurite 2CuCO3 .Cu  OH  2 , Limestone CaCO3. MgCO3, Magnesite MgCO3, Kieserite
MgSO4.H2O

43. 9
A and B are same
α obs.
 αsp.rot. =
c(g/ml)×l(dm)
α
60= obs.
1.5
×1
10
α obs. =90

SECTION – D
44. 02806.28
10CO2  g   4 H 2O   
C10 H 8  s   12O2  g  
14000×2
For 1 mole Napthalene, heat liberated = =28×105 J/mole
0.01
ΔU=-28×105 J/mol
U at 300 K  28 105  10  2  35  4  75  2
 but here product and reactant both are at 300K 
  28  105  1300  J
  2800  1.3 kJ  2801.3 kJ
H  U   n  g RT
 2801.3   2  8.3  300  103

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 13 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

 2801.3  4.98
 2806.28 KJ/mol

45. 00001.02
The rate of change of pH with the volume of alkali added is maximum at equivalence point.
So volume required to neutralisation = 25.5ml
25.5×2×0.2=M×1×10
So, M=1.02

46. 00001.48
Z=4×0.999
4×0.999×40
d= 3
gm/cm3
1/3
6×1023  0.18 ×10-7 
 
3
=1.48g/cm

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 14

Mathematics PART – III

SECTION – A

47. A
 
2 tan 1  sec 2  x   & sin 1  x 3  x 2  x  2  
2 2
3 2 2
Equality holds if x  x  x  2  1 & sec  x  1
 x 3  x 2  x  1  0, x  n, n  N but equation has no integral roots.

48. D
Sol. Factor of W  24.32.51  5  3  2  30
2 8 4 2
Factor of W  2 .3 .5  9  5  3  135

1 66 W 66 W2
Hence 66  28  38

49. A
Sol.
S1 : sphere

 0, 0,0 
O

M  P

S 2 : circle
Plane:x  y  z 1
Let OM be  distance from ‘O’ to plane
1 1
 OM  
12  12  12 3
OP  1 given
OMP is a right angled triangle
1 2
 MP  1  
3 3
The required curve is the cone with S2 as circular base and vertex at O  0,0,0
2
1 1  2 1
V   r 2 h       
3 3  3 3
2 2 3
  
9 3 27

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 15 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

50. ABC
Sol.
0 x  1

1 1  x  1
0 1  x  2
2 
 x  1  
1 2  x 3

2 3x2
3 x2
0 x  1
 x 1  x  0

 x 0  x  1

x  x 2  1  0 1  x  2

x 2x 3
2 x 3 x2

3x x2
 x x  1
 x  1 1  x  0

 x 1 0  x  1

x   x 2  1   x 1 x  2

x 1 2x 3
x  2 3x2

 x  3 x2
1/ 2 0 1/ 2
1
  f  x   g  x   dx    2 x  1 dx    2 x  1 dx  2
1/ 2 1/ 2 0

51. BD
Sol. Divide S in 7 partition of form 7k  r  r  0,.....,6 we can choose a element from partition of

form 7k  r . We cannot use 7  k  1  r.r  1,.....,6 and we can select 1 element from
partition of form 7 k .

52. ABC
2
Let Q  x   x 2  bx  c, Q  P  x     P  x    bP  x   c as P  x  | Q  P  x    c  0 and
Q  x  P  x  b

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 16

53. ACD

c b

B a C
D  A
D  A case-I case-II

b a c

E B F C  E B b F C 

case-I
sin C c b
Let a  b  c ,    b2  ac
sin B b a
case-II
sin A b a
Let a  b  c ,    b 2  ac
sin B c b
 2
Let  a , b, c   c , c , c as triangle is 
2 2 1 5
formed b  c  a      1  0  
1 5 2

54. ABCD

2
 16 sin
4
x cos 2 x   f  x   4sin 2 x cos x  dx
0

2
     f  x   4sin 2 x cos x   
0

f  x   4sin 2 x cos x

55. B

56. D
Sol. (55 – 56)
Y
B

C   ,1   
 0,1    E
x  y 1
P
 x, y 
O A X
D
 , 0 

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 17 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

x y
 1
 1
AM  GM
x y

 1  xy
2  1   
 1   
 xy 
4
1
xy 
16
2
Region traced by point P is  y  x  1  4 x
1
1

 Area   x  1  2 x dx 
0
 6

SECTION – C
57. 8
 1  2ei
Sol. f  i   tan  i ei  f  i    2
 f  i   sin 2 i
4  1 
 ei  f i     8
i 1  f   i  
58. 9
Sol.  2 1, ,   is the ordered triplet which satisfy first two equations so it must satisfy third
2 2 2
equation &  2  1     must be minimum which happens
1 1 1 1
at    so  ,  ,     ,  ,  which satisfies third equation, i.e.
3 3 3 3
1  1 1
a   a  b     6   1
3  3 3
b  3& a  R

59. 5
14
17 k
Sol. Coeff. of x14 in 1  x  1  2 x  3x 2  .......  15 x14  ......... is   1 15  k  17
Ck .
k 0
15
Which is same as coeff. of x14 in 1  x  15 C14  15

60. 5
th th th
Sol. Let r ,  r  2  ,  r  6  terms be a, a  2d , a  6d respectively.
2
  a  2 d   a  a  6d   a  2 d .

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 18

1
Terms are  2d ,4d ,8d  so common ratio of G.P is .
2
u u u
Let u , , 2 ,...... 2 p are 2 p  1 terms in  p,2018 p 
2 2 2
i.e.
u
u  2018 p & p
22 p
p.2 2 p  u  2018 p
4 p  2018
p5
61. 2
Sol. f  x   x2 x  R  1
f  f  x    f 2  x  x  R  1,0
2
f  f  x   f 2  x    x2  x  R  1, 0

 
f f  f  x    f 2  f  x    f 4  x   x8 x  R  1
f  f  f  x   x 8
has solution only at x  1

62. 0
 2 1 
 sin x  4  4 sin x  4 
Sol. min  f  t      
1
 4  sin x 
 4 
 4  sin x
 /2
 /2
 I1    4  sin x  dx   4 x  cos x 
0
0

I1  2  1
  /2  1  
I 2  min    t 2 sin x  t sin x  4  dx 
 0 4  
 /2
 1 2  
 min    t cos x  t cos x  4 x  
 4  0 

 1 
 min  2  t 2  t 
 4 
 1 2 
 min  2   t  2   1
 4 
I 2  2  1
 I1  I 2  0

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 19 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

63. 3
 x  2 2 x  3  p n
Case 1: One of the factors is 1 which is possible only when x  2, 3
Case 2: Let x  2  p & 2x  3  ps
r

 p s  2 p r  s  1  7
 p  7&x  5
64. 1
Sol. a2  bc  b2  ca  c2  ab    ab  bc  ca 
So given expression reduces to
2 2 2 2
 ab    bc    ca  
 ab  bc  ca   2abc  a  b  c 
2 2
 ab  bc  ca   ab  bc  ca 
1
65. 2
cos   x  1 cos   x  1 cos   x 
  3
k k k
cos   x   cos  
 2  3  0
k  k 
 
  k 6
k 6

 cos  4    8
3
66. 5
1
Let chosen points be 1 , 1  &  2 ,  2  . The area of the triangle 1 2   2 1 must be
2
integer.
 2  64  16  .16  5
 1 2   2 1 is even integer. Total probability   1  
 64  64  8

SECTION – D
67. 00102.01
dv Adh
  A    A
dt dt
0 t

 dh     dt
15.7 0
 15.7   t

dv 2 dh
   10.1  
dt dt
0 t
2
 10.1
15.7
dh    dt
0
2
 t  10.1 15.7 

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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 20

2
10.1 15.7   15.7     10.1
2
As t is same in both case
  

68. 03600.00
As z1  z2  z3  0  z1 , z2 , z3 are vertices of an equilateral triangle and z4 , z5 are end points of
2
diameter. So zi  z j  3r 2 if
2 2
i, j  1, 2,3 ; zi  z j  4r 2 if i  1, 2, 3 & j  4, 5 & z4  z5  4r 2
2
   z z i j  25r 2  3600
1 i  j  5

69. 00007.75
Let A denotes the probability that every box have three balls each. B is the probability that each
box has balls of the colour as that of the box.

Required probability =P B/A =1  P  B/A  
Cases: R  B, B  G, G  R or R  G, B  R, G  B
1 1 1 1 1 1
P  A  . .  . .
2 2 2 2 2 2
1 1 1 1 1
P  A  B   . . . . 
2 2 4 2 4
1 1
.
1
So P  B / A   8 16 
1 1 32

8 8
31
P  B / A 
32

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