An International Standard Formulation for the Thermodynamic Properties

of 1,1,1,2-Tetrafluoroethane (HFC-134a) for Temperatures From

170 Kto 455 K and Pressures up to 70 MPa

Reiner Tillner·Roth and Hans Dieter Baehr

/nsliIUl fUer Thermudynamik, Univer~'irae1 Hannuver, Callinslrasse 36, 30167 Hanrwver, Oefmu;I>,

Received March 7, 1994; revised manuscript received August 3, 1994

A fundamental equation of state for the Helmholtz free energy of R 134a (1,1,1,2-
tetrafluoroethane) is presented which is valid for temperatures between 170 K and 455 K
and pressures up to 70 MPa. It is based on the most accurate measurements of pressure-
density-temperature (P ,p,T), speed of sound, heat capacity, and vapor pressure which are
currently available. A linear regression analysis and a non-linear least squares fitting
technique, based on the selected measurements, were used to determine the structure of the
fundamental equation of state and the values of its 21 coefficients. The equation represents
nearly all selected experimental data within their estimated accuracy with the exception of
heat capacities and speed of sound in the region close to the critical point. Typica1
accuracies are ±0.05% for density, ±0.02% for the vapor pressure or ::to.5 and ±1 % for
the heat capacity. This equation of state has been compared to equations established by
other research groups by Annex 18 of the International Energy Agency (lEA) and has been
selected as an international standard f011l1ulation for the thermodynamic properties of
R 134a by this group.

Key wurds: data analysis; fundamt:ntw equatiun uf stl1te; Ht:lmhulliG-fn:::c cnergYl:unell1tiun, R 13411; 1,1,1,2-
tetrafluoroethane; thermodynamic properties.

Contents 3.2.3. Ancillary Equations. . . . . . . . . . . ... . . 664

3.2.4. The Residual Part <l>r for HFC-134a . . 664
1. Introduction ............' . . . . . . . . . . . . . . . . . . . 658 4. Comparisons With Experimental Data. . . . . . . . . . 665
1.1. Background. . . .. .. . .. .. . .. . . . . .. .. ... .. 658 4.1. Single-Phase Properties. . . . . . . . . . . . . . . . . . 665
1.2. Other Equations of State for HFC-134a . . . . . 659 4.1.1. (p,p,T)-Data...................... 665
1.3. Urganization ot the Paper . . . .. . . . . . . . . . . . 65Y 4.1.2. ~econd VInal Coefticient. . . . . . . . . . . 66'/
2. Experimental Results. . . . . . . . . . . . . . . . . . . . . . . . 659 4.1.3. Isochoric Heat Capacity ........ ~ . . . 667
2.1. Survey of Available Measurements. . . . . . . . . 659 4.1.4. Isobaric Heat Capacity. . . . .. . . . . .. . 667
2.1.1. Triple point .... '.' . . . . . . . . . . .. . . . . 659 4.1.5. Speed of Sound. . . . . . . . . . . . . . . . . . . 668
2.1.2. Critical point. . . . . . . . . . . . . . . . . . . . . 659 4.1.6. Joule-Thomson Coefficient . . . . . . . . . 668
2.1.3. Single-Phase Properties. . . . . . . . . . . . 660 4.2. Saturation Properties. . . . . . . . . . . . . . . . . . . . 668
2.1.4. Saturation Properties. . . . . . . . . . . . . . . 660 4.2.1. Vapor Pressure . . . . . . . . . . . . . . . . . . . 668
2.2. The Data Set for the Formulation of the 4.2.2. Saturated Liquid Density . . . . . . . . . . . 668
Fundamental Equation of State. . . . . . . . . . . . 660 4.2.3. Saturated Vapor Density. . . . . . . . . . . 669
2.2.1. Consistency Tests Between Thennal 4.2.4. Isochoric Heat Capacity in the
and Caloric Properties . . . . . . . . . .. . . 660 Two-phase Region . . . . . . . . . . . . . . . . 669
3. The Fundamental Equation of State ........... ~ 661 4.3. Critical Point. . . . . . . . . . . . . . . . . . . . . . . . . . . 669
3.1. The Free Energy for the Ideal Gas. . . . . . . . . 661 5. Conclusion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 669
3.2. The Furrnulatiun uf the Resiuual Part <l>r • • • • 662 6. Acknuw leugements . . . . . . . . . . . . . . . . . . . . . . . . . 670
3.2.1. Linearization of Non-linear 7. References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 670
Relationships. . . . . . . . . . . . . . . . . . . . . 663 8. Appendix .•...... ', ... , . . . . . . . . . . . . . . . . . . . . 696
3.2.2. Restrictions in the Critical Area .. . . . 663
List of Tables

1. Summary of experimental critical parameters.. . . 671

©199:; by the: U.S. Sel:lCtW-Y uf CUIllIllCll:t: Ull lJdll1lf uf tlie Uuilc::d Stl1Lcs.
This copyright is assigned to the American Institute of Physics and the
2. Summary of measurements in the single phase. . 672
American Chemical Society. 3. Summary of measurements of saturation
Reprints available from ACS; see Reprints List at back of issue. . properties. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 673

0047-2689/94/23(5)/657/73/$18 657 J. Phys. Chem. Ref. Data, Vol. 23, No.5, 19"

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658 R. TILLNER-ROTH AND H. D.BAEHR'

4. Coefficients of Eq. (4) for liquid HFC-134a. .. . 674, 21. Deviations of isochoric heat capacities measured
5: Relations between the dimensionless free energy by Magee 33 from our own EOS......... .. .... 687
and thermodynamic properties.. . . . . . . . . . . . . . . 674 22. Deviations of isobaric heat capacities from values
6. Exponents of the terms in the bank of terms calculated from our own EOS.. . . . . . . . . . . . . . . 688
(Eq. (12»................................ 675 23. Deviations of speed of sound values in the gaseous
7. Coefficients and exponents of the residual part of phase from our own EOS. ........... ....... 689
the fundamental equation of state for HFC-134a. 675 24. Deviations of speed of sound values in the liquid
8. Thermodynamic properties of HFC-134a at region from our own EOS.. . .. .... .......... 690
saturation ....... '. . . . . . . . . . . . . . . . . . . . . . . . . . 696 25. Deviations of Joule-Thomson coefficients from our
9. Thermodynamic properties of HFC-134a in the own EOS .... ; ......................... '," 691
single-phase region.. . . . . . . . . . . . . . . . . . . . . . . . 700 26. Deviations of selected vapor pressures from the
fundamental equation of state. . . . . . . . . . . . . . . . 691
List of Figures 27. Deviations of measured vapor pressures from the
fundamental EOS not being used during the corre-
1. Distribution of selected measurements in a (p ,T)- lation process. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 692
diagram of HFC-134a. ..................... 676 28. Deviations of saturated liquid densities from the
2. }{esults of the consistency test in the liquid phase of fundamental equation of state. . . . . . . . . . . . . . . . 693
HFC-134a................. '............... 677 29. Deviations of saturated vapor densities from. the
3. Deviations of reported ideal gas heat capacity val- fundamental equation of state. . . . . . . . . . . . . . . . 693
ues from values calculated from Eq. (8). " . . . . . 678 30. Qualitative plot of the isochoric heat capacity on an
4. Optimization cycle during the fonnulatiori"of the isotherm. ......................... . . . . . . . 694
residual part <l>r of the fundamental equation. . . . 678 31. Deviations of two-phase isochoric heat capacities
5. Pressure deviations of (p .p.T)-properties in the measured by Magee33 from our own EOS. ..... 694
gaseous phase from our own EOS. ........... 679 32. Comparison of measured critical parameters Tc and
6. Density deviations of (p ,p,T)-properties in the liq- p with values calculated from our own EOS. . . . 695
uid phase from our own EOS. .............. 680
7. Pressure and density deviations of (p ,p,T)-proper-
ties in near-critical and supercritical states from our 1. Introduction
own EOS................................. 681
8. Density deviations of (p ,p,T)-properties reported 1.1. Background
by Baroncini et a1. 4 from our own EOS ....... 682
9. Density deviations of (P,p,T)-properties reported HFC-134a (1,1,1,2-tetrafluoroethane, CF3CH2F) is an envi-
by Basu and WilsonS from our own EOS....... 682 ronmentally acceptable refrigerant which has replaced the
10. Density deviations of (p ,p,T)-properties reported ozone-depleting CFC-12 (dichloro-difluoro-methane) 'in a
by Doeringll from our own EOS.. . . . . . . . . . . . . 682 wide range of applications especially in automotive air-condi-
11. Density deviations of (p ,p,T)-properties reported tioners and domestic refrigeration. Because of its current and
by Fukushima et aZ. IS from our own EOS. .... . 683 future importance, accurate knowledge of its thermodynamic
12. Density deviations of (p ,p,T)-properties reported properties is essential in order to design economic refrigera-
by Kesselman et aZ. 27 from our own EOS.. . . . . . 683 tion cycles. In particular, a common standard fotthe thermo-
13. Density deviations of (P,p,T)-properties reported dynamic properties of HFC-134a i:s desirable for the refriger-
by Maezawa et at. 32 from our own EOS.. . . . . . . 683 ation industry.
14. Density deviations of (p ,p,T)-properties reported This task has been taken on by a group working under the
by Magee 33 from our own EOS.. . . . . . . . . . . . . . 684 auspices of the Heat Pump Programme of the International
15a. Density deviations of (p ,p,T)-properties reported Energy Agency (IEA). This program was established in 1978
by Morrison and Ward38 • ••••••••••••••••••• 684 and is currently supported by fifteen countries. It offers op-
15b.Density deviations of (p ,p,T)-properties reported portunities of international collaboration in research, develop-
by Morrison and Ward38 from our ownEOS. ... 684 ment, demonstration, and promotion of heat pumping and
16a. Density deviations of (p ,p,T)-properties reported by Piao related technologies. The aim is to accelerate the knowledge,
et aZ. 43 from our own EOS.. . . . . . . . . . . . . . . . . . 685 acceptance, and implementation of this energy saving and
I6b.Density deviations of (p ,p,T)-properties reported environmentally important technology. Eight member coun-
by Piao et a1. 43 from our own EOS.. . . . . . . . . . . 685 tries (Austria, Canada, Germany, Japan, Norway, Sweden, the
17. Density deviations of (P,p,T)-properties reported United Kingdom, and the United States) have joined together
by Park42 from our own EOS. ............... 685 to form Annex 18 - Thermophysical Properties of the Envi-
18. Pressure deviations of (P,p,T)-properties between ronmentally Acceptable Refrigerants. One of the goals of this
350 K and 400 K from our own EOS... .. .. .. . 686 Annex is to provide property formulations that will become
19. Density deviations of (p ,p,T)-properties reported de facto international standards for the most important alter-
by Zhu et aZ. 63 from our own EOS. . . . . . . . . . . . 686 native refrigerants.
20. Deviations of second virial coefficients from the It was proposed at the meeting of Annex 18 in Heidelberg,
EOS. ................................... 686 Gennany, in Novermber 1990 and agreed at the meeting held

J. Phys. Chern. Ref. Data, Vol. 23, No.5, 1994

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) 659

in Boulder, Colorado, USA in June 1991, that comparisons will, therefore, only be used for comparisons in the critical
should be made of existing equations of state for the refriger- region.
ants HFC-134a and HCFC-123. These two fluids have the
most immediate industrial applications, since they are pro- 1.3. Organization of the Paper
posed as replacements for CFC-12 and CFC-11, respectively.
For both of these fluids, a large amount of experimental re- In Sec. 2, a survey of experimental data for the thermody-
sulLs ~xists and more than one equation of state has been namic properties of HPC-134a is summarized. The experi-
correlated for each. mental results which were used to establish the fundamental
Two independent groups were asked to carry out these equation of state are identified.
comparisons, namely the Center for Applied Thermodynamic Section 3 is concerned with the development of the funda-
Studies (CATS) at the University of Idaho, Moscow, Idaho, mental equation of state. Briefly, the optimizatioIl process is
USA and the International Union of Pure and Applied Chem- described, especially the application of different strategies
istry (!UPAC), Thermodynamic Tables Project Centre, Impe.: during different steps of optimization. Furthermore, structure
rial College, London, UK. These two groups prepared inde- and coefficients of the fundamental equation of state together
pendent preliminary reports for the meeting held in July 1992 with relations between thermodynamic properties and the
at Purdue University, West Lafayette, Indiana, USA. The Helmholtz free energy are given.
IUPAC repon comprised comparisons of three equations of In Sec. 4, the equation of state is compared with experimen-
state for HFC-134a with the ideal gas, saturation and single tal data and the equations of state mentioned in Sec. 1.2.
phase PVT -properties while the CATS report gave compari- Tables of thermodynamic properties are also included in this
sons of four equations of state for HFC-l34a and of three paper. More detailed tables will be published separately in a
equations of state for HCFC-123 with all available data. At properties bulletin by the International Institute of Refrigera-
that meeting several suggestions were made for modification tion (IIR).
of the final· report. It was decided that draft final reports All experimental data, .available up to January 1993 are
should be distributed one month before the next Annex meet- discussed. All temperatures for the new equation are based on
ing on April 30, 1993, and with that aim in view, all new the ITS-90. For simplification our own equation of state will
experinemtal results and new equations of state were to be be referred to as EOS or fundamental EOS.
submitted to both participating groups by 1st December 1992-
At the meeting of the Annex 18 in Maastricht, The Nether- 2. Experimental Results
lands, in April 1993 both groups presented their results of the
equation of state eomparis~ns for HFC-134a and for HCFC- 2.1. Survey of Available Measurements
123. After discussion of the advantages and disadvantages of
each equation of state it was decided to recommend the equa': 2.1.1. Triple Point
tion presented in this paper as an international standard for
thermodynamic properties of HFC-134a. Only one experimental value of the triple point temperature
has been reported which is by Magee33 • They found

1.2. Other Equations of State for HFC-134a Ttr - (169.85±O.OI)K.

Three other equations of state (BOS) for HFC-134a were Their measurements were performed with a sample of
reviewed as part of the Annex 18 work. They differ in struc- 99.999% purity; therefore, their value is regarded as highly
ture and also in the ranges of validity. Huber and McLinden reliable. Density and pressure at the triple point have not been
established a 32-term EOS 22 (referred to as HM-EOS) the measured. Calculation from the fundamental EOS yields
structure of which corresponds to the modified BWR-type
originally developed for nitrogen by Jacobsen and Stewares• Ptr 391 Pa and
It is valid in about the same ranges of temperature pressure as
our own equation of state, namely from the triple point tem- 2.1.2. Critical Point
perature to 455 K for pressures up to 70 MPa. Huber and Elil
used a 32-term equation of state for the Helmholtz free energy Experimental values of the critical parameters are summa-
(referred to as HE-EOS) which was originally developed for rized in Table 1. All values are in close agreement. The
oxygen by Schmidt and Wagner~. It is valid 1.J~tweell 170 K IIl~a:sur~d l:ritk:al l~IIlp~ralur~s diff~r by unly 0.18 K, th~
and 453 K for pressures up to 70 MPa. The equation of Piao, pressure pc by less than 0.4%, and the critical density by less
Noguchi, Sato, and Watanabe 44 (referred to as PNSW-EOS) is than 1.6%. Critical parameters were only used to define the
a modified BWR-equation with 18 coefficients. The range of dimensionless variables 'T:-T*/T and B:=p/p*. For this pur-
validity is for temperatures from 180 K to 450 K and pres- pose we selected
sures up to 70 MPa.
Furthermore, a cross-over model was developed by Tang et T* = 374.18 K and p* - 508 kglm3•
ai. S3 describing thermodynamic properties in the critical re-
gion. This model has been extended into regions beyond the We did not constrain the equation of state to any of these
critical, but does not predict these properties accurately. It measurements because this would unnecessarily restrict the

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660 R. TILLNER-ROTH ANDH.D.BAEHR

optimization. Another approach to consider the behaviour in From·available saturation properties four sets of measured
the critical region is described in Sec. 3.2.2. vapor pressures by Goodwin et al.7 Baehr and Tillner-Roth3 ,
Weber8 , and Magee and How ley 34 were selected which· agree
2.1~3. Single-Phase Properties extraordinary well.with each other, cf. Fig. 26. They cover
nearly the whole vapor pressure curve between 180I{ arid the
Extensive measurements of various thermodynamic prop- critical point. We refrained from using measurements of satu-
erties in the single-phase have been carried out for HFC-134a. ration densities because the single-phase. regions adja.cent·to
The sources are listed in Table 2. 18 data sets of (p ,p,T)-prop- the saturation boundary are well-defined by. (p ,p;T)-data. Ad-
erties are reported comprising 2611 data points within 180 K ditionally, isochoric heat capacities· in ,the two-phase region
and·453 K 'at pressures up to. 70 MPa. Numerous caloric by Magee33 below 190-K were included. Those measured at
properties, namely speed of sound, isochoric and isobaric heat higher temperatures were not used because they contain about
capacity and Joule-Thomson coefficients, were measured in the same information of state as the single~phaseheatcapac­
the vapor and liquid regions .as well. ities reported 'from the same source and already' selected.
Second virial .coefficients were reported by six sources
listed in Table 2. These values were derived from other mea- 2.2.1. Consistency Tests Between Thermal
surements such as speed of sound or (P,p,T).,.measure-ments, " and Caloric Properties
covering the range· from 233 K to 453 K.
In this section,a test ()fconsistencybetween thermal.and
2.1.4. Saturation Properties caloric properties in the liquid phase· is described which was
carried out prior to the formulation of the· fundamental equa.,.
The majority of available' saturation 'property measure- tion of state. This test was performed. to find out· the . best
ments are for vapor pressure and saturated liquid density. For combination of thermal and caloric data which obey the laws
the saturated. vapor density;·six data sets· are, available for of thermodynamics. Furthermore, "it has, been. necessary to
temperatures .above 293 .K~ 160 isochoric heat capacities in find an explanation for the systematic. difference between the
the two-phase region have been measured by Magee33 which liquid density values.· reported by Tillner-Roth and Baehrs
are very useful to check an equation of state with respect to and those measured by Hou et al}3.
its representation of the whole (p ,p,T)-surface. Available sat- The consistency test is based on the following thermody.,
uration property measurements are listed in Table 3. namic equations relating caloric properties with the thermal
equation of state p=p(v,T). The speed of sound w is written
2.2. The Data Set for the Formulation of the as
Fundamental Equation of State

In this section, the results of the data analysis are outlined

w-v ~:£
. C
(daTP)2v . :•.. '(EE)'
v av t , (1)

briefly. The selection of single-phase measurements is mainly

based on tests. of consistency as described in Sec. 2.2.1 for the the isobaric heat capacity cp as
liquid phase. Further criteria, which apply to the assessment
of all data sets, are the '. uncertainties claimed by the authors,
(2)
the scatter of a set of data when compared to an equation of
state, or systematic deviations between different sets of data.
The reasons for selecting or rejecting a certain set of measure· and the Joule-Thomson coefficient is given by
ments are givenin detail in Sec. 4 where experimental data are
compared with the fundamental equation of state. _lap) T(oP)
Figure I shows the distribution of experimental values in ~av + . ·aT
T u
(3)
the single-phase region which were used to establish the fun- fJ.== T(a p )2_ cv(ap )·.·
damental equation of state. The values cover the range be- aT v 'aVT
tween J 80 K and 453 K for pressures up to 70 MPa. From the
large amount of available (p ,p,T)-data only those measured Using, these equations, a value of the isoChoric heat capac-
by Tillner-Roth and Baehr 4•sS and of Dressner and Bier12were ity can be transformed into any other desired caloric property
selected because they agree extremely wel1 and cover an when the thermal equation of state is"known. Alternatively,
extended range of pressure and temperature. (p ,p,T)-mea- any other kind of transformation between caloric· properties is
surements of other authors were not used because theygener- possible,for example speed of sound can be calculated from
ally overlap the selected data or show systematic deviations. a value of the.isobaric heat capacity using Eqs. (2) and (I). For
In the liquid and in the vapor phase. speed of sound values of this purpose. the thermal equation of.state must·be consistent
Goodwin and Moldover18 and Guedes and Zollweg 19 , isobaric with the caloric information otherwise a transformation would
heat capacities of GUrtner and Emst20 and of Wirbser9 are produce results which disagree with· reliable measurements.
included in the data set. Furthermore, measurements of iso- Thus, consistency between sets of thermal and caloric. mea-
choric heat capacity by Magee;;;; were selected and found to be surements can be checked by setting up thermal equations of
consistent with the selected data so were included during the state based on different sets of denisty measurements,ttans-
formulation of the fundamental equation of state. forming different caloric measurements· into a unique. prQP-

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) . 661

erty, and comparing the results with measured. values of that properties and, therefore, should not be used to develop a
property.·Results which agree would indicate consistency be- fundamental equation of state with high accuracy. Therefore,
tween the thermal and caloric values while disagreement indi- our equation of state is based on the densities of Tillner-Roth
cates inconsistency. and Baehrs although they do not extend to very low temper-
For liquid HFC-134a, two equations of state were estab- atures. This decision is confirmed by the density measure-
lished. The first one was based exclusively ori the densities of ments by Klomfar et al. 28 which were published after the
Tillner-Roth and Bae~s for temperatures between 243 K and work on the equation of state was finished. The densities of
413 K, for densities p>750 kg/m3, andfor pressures up to 20 Klomfar et al. 28 agree with the. EOS within ±0.05% at tem-
MPa. The second one was fitted to the densities of Hou et al. 23 peratures below 243 K, cf. Fig. 6, that is for temperatures for
in the same ranges ot temperatures and pressure. The equa- which no (P,p,T)-measurements were selected~by us.
tions of state in the liquid had the form: From·· the available caloric measurements the w-values
measured by Guedes and Zollweg 19 , cv-values of Magee23 ,
. :0 == 83 (gl'i'~l + g2 83 + g3 + g4'i'483)+gS'i'86 exp( -8)
and cp -values reported by Wirbser9 were used as input data.
We did not include the cp-values of Nakagawa et ai.39 and of
+ 83 exp( -82)(g6'i's8 + g7'i'-1 + g8'i'8 3+ g9'i' 48 + glO'i'-~8 ) (4)
Saitoh et al. 46 in the data set because they overlap those of
Wirbser9 • Furthermore. the large scatter of the transformed
J oule-Thomson coefficients gave us reason also to exclude
with 'i' == T*IT, 8 == p/p*, po == 1 MPa, T* 374.18 K, and p* == these data in order to prevent convergence problems during
508 kg/m3. The coefficients and exponents are given in Table the optimization process.
4. For both data sets the same structure o(Eq. (4) was used.
Therefore, only the coefficients are different. 3. The Fundamental Equation of State
The choice was· made to transform all available caloric
measurements into speed of sound values because there exists The equation of state for HPC-134a presented here is a
a correlation function w==w(p,T) reported by Guedes and fundamental equation of state for the dimensionless
Zollweg 19 for the·region of interest by which transformed and Helmholtz free energy
originally measured values can be compared. The results are
plotted in Fig. 2. In the upper plots, Fig. 2a, density deviations
from Eq. (4) are shown using the respective set of coeffi-
cients. The densities of Tillner-Roth and Baehrs .are repre-
sented within ±0.05% while the densities of Hou et al. 23 are where R m==8.314471 J/(mol K) is the universal gas constant
predicted within ±0.12% due to their greater uncertainty. On according to Moldover et al. 37, R=Rn/M the gas constant of
the average both equations represent well the (p ,p~T)-be­ HFC-134a with the molar mass M==O.l 02032 kg/mol. Am is the
haviour incorporated in the respective. input values. molar free energy, A the specific free energy, 'i'=T*IT the
The second row of plots, Fig. 2b, shows deviations of inverse reduced temperature, and 8=p/p* the reduced density.
measured speed of sound reported by Guedes and Zollweg 19 For reduction of temperature and density the critical-parame-
and by·TakagiS2 from the correlation function reported by the ters T*==Tc==374.18 K36 and p*==p,,=508 kg/m3 26 were used.
first mentioned authors. The values of Guedes and Zollweg 19 The dimensionless form 4> of the fundamental equation of
are represented within ±0.3% while the results of TakagiS2 state is split into an ideal part <1>0 describing ideal gas proper-
are about 0.7% lower. ties and into a residual part <l>T taking· into account the be-
The last three rows of plots, Figs. 2c-2e, present deviations haviour of the real fluid.
of speed-of-sound values obtained from transformation of
isobaric and isochoric heat capacities and of Joule-Thomson 3.1. The Free Energy for the Ideal Gas
coefficients using the correlation function of Guedes and
Zollwegs. The plots on the left-hand side show the values The ideal part <1>0 of the fundamental equation of state is
transformed with Eq. (4) using the set of coefficients obtained analytically derived from the ideal gas law and an equation for
for the data of Ti11ner-Roth and Raeh~s. The plots on the the isobaric heat capacity c;: of the ideal gas. Starting from the
right-hand side represent values transformed using the coeffi- Helmholtz free energy of the· ideal gas
cients obtained using the density data of Bou et al. 23. Gener-
ally, transformation leads to smaller deviations when using
the densities of Tillner-Roth and Baehrs to establish the ther-
mal· equation of state. Using the information· of the densities and introducing the c;-equation leads to
of· Hou et al. 23 leads to higher systematic deviations. The
maximum deviations in the latter case are 4% for transformed T

cp-values, 1.5% for transformed cv-values,and -8% to 8% A O(p,T) = J cpo dT + hn - RT -

for the Joule-Thomson coefficients, while the respective devi- T. ~

ations are only 1.5%, 0.4% and -2% to 8% when using the
densities of Tillner-Roth and Baehrs.
(7)
Based on this result, we concluded that the densities ofBou
et ai. 23 are not very much consistent with the available caloric

J. Phys. Chem. Ref. Data, Vol. 23, No.5, 1994

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662 R. TILLNER-ROTH AND H. D. BAEHR

where Pn=Pn/(RTn) is a reference density. Equation (7) re- and at are derived from the coefficients of the c;-equation.
quires reference values for the temperature Tn, the pressure The values of the coefficients a ~ and a2 were calculated from
Pn, the entropy Sn, and the enthalpy hn• For HFC-134a, we enthalpy hn and entropy Sn at the reference state chosen above.
chose to set a reference entropy sn=1 kJ/(kg K) and a reference
enthalpy hn=200 kJ/kg at the state of saturated liquid at
Tn=273.15 K and Pn=PsCTn). Since the residual part <l>r of the 3.2. The Formulation of the Residual Part <I>r
fundamental equation of state is needed to calculate the satu-
ration properties at the reference state, the normalization of In contrast to the simplicity of establishing the ideal part
the equation of state· is carried out after the residual part <l>r <1>0, it is much more difficult to find a mathematical expres-
had bt;t;Il t;slablisht;d. siun fur lht; rt;siuual paIt <l>r(T,B) of tIlt; Hdlllholtt, free energy.
Ideal gas heat capacities have been derived by Beckermann Since the laws of thermodynamics do not provide general
and Kohler6 , Goodwin and Moldover l8 , Chen et al. 9 , and relationships about the shape of the residual part, such a
Gurtner and Emseo either from speed of sound measurements, function must be established by fitting an appropriate equa-
extrapolation of heat capacities to zero pressure, or from fre- tion to experimental values with,the lowest standard deviation
quency spectra by the relations of statistical thermodynamics. possible. Because the Helmholtz free energy cannot be mea-
HFC-134a is a derivative of ethane where rotation occurs with sured directly, the information about it must be obtained from
respect to the C--C-axis. The frequency of this energy level other thermodynamic properties accessible to measurement
is very difficult to resolve, thus determination of c;-values and related to the free energy by the equations given in
from frequency spectra becomes quite uncertain. Therefore, Table 5. All measuf(!able thermodynamic properties are ap-
we excluded the c~-values of Chen et al. 9 during the formula- propriate to form the data set for the. optimization process.
tion of the c~-equation which is written as Fitting an equation of state to different thermodynamic prop-
erty data is often called a multiproperty fit.
The goal of any optimzation procedure is to minimize a
(8)
sum of squares. For the formulation of the residual part <l>r we
used a weighted form of the least squares sum:
with T=T*/T according to Sec. 3. Preliminary values of the
coefficients were obtained from fitting Eq. (8) to values re- S= i
i-I
(Zexp,i-ZcalC(Xexp,;,Yexp,i,<\>\it»2 crf2 ~ Min. (10)
ported by Goodwin and Moldover l8 and by Gurtner and
Emseo in the temperature range between 230 K and 420 K. In Z=Z(x ,Y ,<\>r,a) denotes a relationship between any thermody-
subsequent steps the coefficients were improved by fitting the namic property (such as p, Cp , cv , ... ), the residual part qJr of
c;-equation together with the residual part <l>r to caloric mea- the free energy, the parameter vector it to be optimized and
surements of the real fluid which are available in a more the independent variables x and y, which are in our case T and
extended temperature range. Because each caloric property of 8. The relationships given in Table 5 allow us to include
the real fluid is related to the ideal gas heat capacity c;, residuals for experimental values Zexp(Xexp,Yexp) of different
additional information is introduced into the c;-equation, thus thermodynamic properties.
extending its range of validity from 172 K to 473 K. The final The residual quantity ~z = ZexD - Zcalc is divided by the total
coefficient values are cf =-0.629789, C2° = 7.292937, and C3° uncertainty cr obtained from the Gaussian error propagation
= 5.154411. law according to
Figure 3 shows deviations of experimental heat capacities
2_ (a(dZ»)2 Z
az O'z + (a(dax »)2 U'x + (a(dZ»)2
c~ from those calculated with equation (8). The results ob- (11)
tained by Goodwin and Moldover l8 derived from speed of 0' -
2
ay U'y.
2 2

sound measurements and those of Gurtner and Emseo extrap-

olated from cp-measurements are represented within ±0.5%. denote the uncertainties of the variables x, y, and
0'x, 0'Y' 0' z
c;-equations used for the HM-EOS, HE-EOS, and PNSW- Z, respectively which are obtained from estimated experimen-
EOS agree well in the intermediate temperature range, while tal uncertainties. The partial derivatives may be calculated
at higher temperatures deviations exceed 1%. There. devia- from ancillary equations given in Sec. 3.2.3 or from a prelim-
tions are attributed to the fact that the real gas caloric proper- inary fundamental. equation of state when available during the
ties were not taken into account by the other authors during optimization process. However, changing the total uncer-
the formulation of the c~-equation. The equation established tainty by recalculation has negligible influence on the result
by Basu and Wilson5 is based exclusively on c;-values of the optimization.
derived from spectral data and shows deviations up to +2.5% Two optimization strategies have been employed to estab-
similar to the data reported by Chen et al. 9 • lish the fundamental equation of state for HFC-134a. The first
The dimensionless form q,°=A o/(RT) is finally obtained one is the regression analysis deVeloped by Wagne~7. Based
from Eq. (7) using the cpO-Eq. (8), yielding: on statistical significance this algorithm selects from a so-
called bank of terms those terms which form an equation
<l>°(T,8) = af + a2T + a31n T + In 8+ a,fT-112 + atT- 3/4 (9) giving the best fit to a given data set. Since it is a linear
method, only those experimental data can be used which
where af=-1.019535, a2=9.047135, a3=-1.629789, linearly depend on the independent variables 8 and T. Such
a%=-9.723916, and aso=-3.927170. The coefficients a3, a~ linear experimental values are (p ,p,T)-values, isochoric heat

J. Phys. Chern. Ref. Data, Vol. 23. Nn " 1QQ4

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 THERMODYNAMIC PROPERTIES OF1, 1,1~2-TET.RAFLUOROETHANE (HFC-134A) 663

capacities or viria} coefficients. Linear properties are marked and Ps = RTp"(l +B"<I>'8)(T,B"), (14)
in Table 5. Beside these, any other linear relationship may be
included during optimization (see Sec. 3.2.1). However, since
the form of the equation of state is unknown at the beginning
of the optimization process, only measured linear property
data can be used at a first step. Each of these equations is linear with respect to the coeffi-
The bank of terms which we used contained 615 terms. It cients of <l>T when all three saturation properties Ps, pi, pit are
may be written in the following form: given at a unique temperature (cf. Bender7). However, mea-
sured properties which fulfill this requirement are rarely
found. Therefore, the saturation properties have been pre-
(12)
correlated by separate equations for the vapor pressure (19),
saturated liquid density (20), and saturated vapor density (21)
A detailed description of exponents is given in Table 6. A thus enabling artificial measurements to be generated at
similar bank of terms has already successfully been employed unique temperatures. The equations for vapor pressure and
by different correlators to establish various fundamental equa- saturation densities are given in Sec. 3.2.3. For HFC-I34a,
tions of state (Setzmann and Wagner), Saul and Wagner47 , 130 artificial quadruples (Ps,p',p",T) were generated between
Marx et al.35 ). The bank of terms does not include the two- 180 K and the critical temperature every 2 K. At temperatures.
dimensional Gaussian terms which have been used by Wag- close to the critical point the intervals were decreased down
ner his co-workers to improve the representation in the critical to 0.2 K.
region. For HFC-I34a too few experimental data exist in the Further linearization of non-linear data was carried out
immediate vicinity of the critical point to justify the use of after a preliminary equation of state· had been established.
such terms. This linearization is applied to caloric data that are non-linear,
A large initial bank of terms causes a significant increase namely the isobaric heat capacity and speed of sound. It is
of computing time. Therefore, the regression analysis is based based on Eqs. (1) and (2) which connect an isochoric heat
on a subset of about 100 terms. During regression analysis, capacity with derivatives of pressure with respect to density
this subset is continuously modified. Useful terms were kept and temperature. Each of these components is linear itself and
in the working bank of terms while unused terms are ex- the information contents of such a caloric property can be
changed with terms from the mother bank of terms. By this
pre-optimization of the working bank of terms computing
time could be decreased to about 5%. A detailed description
of this procedure is given by TiIlner-Roth56•
Once a preliminary structure of the residual part has been
determined it is transferred to a non-linear optimization rou-
linearized by ca1culating values for

~j = R p (1 + B<I>~ - BT<I>~..) and

RT(l + 2B<I>~ + 82<I>~a)
* =

(16)

tine. For this purpose, we used the Gauss-Newton-method from the preliminary equation of state. These are used to
described by Dennis et al. lO • The non-linear optimization transform speed of sound or isobaric heat capacity into a value
allows U~ tu I.:un~iut!r alsu non-linear experimental data, such of the isochoric heat capaCity which linearly depends on the
as speed of sound, isobaric heat capacities or vapor pressure, fundamental equation and, therefore can be used during re-
according to. the direct method proposed by Ahrendts and gression analysis. Additionally, the derivatives according to
Raehrl. The least squares sum is given according to Eq. (10). Eq. (16) were used as input values. By this linearization Cp - or
The result is a very much improved equation of state which is W -values can be considered during the optimization of the
used to linearize non-linear data to be considered additionally structure. The artificial linearized data must be recalculated at
in a subsequent step of the regression analysis. Therefore, the every iteration, if an improved equation of state has been
whole optimization process is a cycle, Fig. 4, switching con- found after non-linear optimization.
tinuously between regression analysis (improving the struc-
ture) and non-linear optimization. Whenever an improved 3.2.2. Restrictions in the Critical Area
eyuation of state was obtained from the non-linear regression
the linearized non-linear data have been recalculated to al- To obtain a physically correct shape of the isotherms in the
ways provide the actual information of thermodynamic be- immediate vicinity of the critical point a special restriction in
haviour to the regression analysis. the critical region has been introduced during non-linear opti-
mization. It is based on the condition of stability which is
3.2.1. Linearization of Non-linear Relationships written as
caplap)r?:::' O. (17)
The most important relationships to be linearized are those
for the saturation properties, namely the combination of vapor that must be fulfilled at every single-phase state. From this
pressure, saturated liquid and saturated vapor density. These condition the residual '
properties are calculated by iteration tor a given temperature
from the following set of equations written in the free energy
form (18)
ps - RTp'(1+8'<P1;)(T,8') (13)

I DhuC! ~hAm RAf n.Rt.R Vn!. 23. No.5. 1994

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664 R. TILLNER·ROTH AND H. D. BAEHR

has been derived which is considered in the sum of least where po = 516.86 kg/m3 was determined during the formula-
squares at predefined points (T ,p) immediately above the tion of that equation. The definitions of variables correspond
highest measured critical temperature. Those points have to those used in Eq. (19). Equation (21) has been fitted to
been chosen on two isotherms at 374.30 K 374.60 K for experimental values above 293 K and to artificial values
densities between 450 kg/m3 and 560 kglm3 • Outside of this which were calculated down to 180 K from the function for
range there are enough experimental data to ensure a correct the second virial coefficient reported by Goodwin and Mold-
fit of the equation of state. These residuals force the optimiza- overl8. It represents the artificial and originally measured in-
tion process to act in the following way: put data within 0.6% except for temperatures above 368 K
When thermodynamic stability is met the derivative where deviations increase up to 2%.
(ap/ap) is positive and therefore the residual quantity of
Eq. (18) will be zero. When the derivative becomes negative
the stability condition is not fulfilled. This results in a com- 3.2.4. The Residual Part cI»r for HFC-134a
paratively large residual quantity, thus forcing the optimiza-
tion to correct the shape of the (p ,p,T)-surface. The advantage The function of the residual part for HFC-134a resulting from
of this strategy is the smoothness of this restriction compared the optimization process described is written as
to a strategy of constraining the equation of state to a mea-
sured critical point. The optimization process is only influ- 8 11 17
<I>r = I aiTti 8d; + exp( -8) I a;Tti8d; + exp( -82) I d
a;T ti 8 ;
enced, when the equation of state does not obey the stability i-I i-9 i-12
condition (17), while 'there is maximum flexibility for opti- 20
exp( -83) I aiTti 8d; + a'i exp( -84)T'218d21. (22)
miz.atiun,in ulh~r parts uf the. (p ,p,T)-surface when the stabil- i-18
ity condition is fulfilled.
Cgefficients exponents are given in Table 7. The definitions
3.2.3. Ancillary Equations of variables are chosen according to the description given in
Sec. 3.
This section describes three equations which were used to . Derivatives of the fundamental EOS are required to evalu-
linearize saturation properties to be included during the re- ate thermodynamic properties. They are given in the follow-
gression analysis. These are namely a vapor pressure equation ing equations corresponding to the most general form of the
and equations for the densities of saturated liquid and satu- EOS given by Eqs. (9) and (12). The first derivatives are
rated vapor. All equations were established by employing the calculated according to
regression analysis of Wagne~7.
The vapor pressure is represented by
<I>~ = 118 (23)
{}In 8. =
Pc o N°
- 7.6865568 + 2.311791 83/2 - 2.0395548 2 - 3.58375884 <I>~ = a~ ~ + Ia:J~tJ~Ttf-L (24)
T j-4
(19)
where {} = T/374.18 K, 8 = 1 - {} and Pc = 4.05629 MPa. It
is based on the same vapor pressure measurements as used to
establish the fundamental equation of state covering tempera-
tures between 180 K and 374.15 K. The data are represented
within ±20 Pa or ±0.03% whichever is greater. The critical
(26)
pressure used in Eq. (19) was determined by fitting it, simul-
taneously with the coefficients, to the input data.
The equation for the saturated liquid density is based on a
selection of available data. It is valid between 180 K 374 K The second derivatives are obtained from
although its uncertainty increases in the vicinity of the critical
temperature. It is written as (27)

k;~3 = 518.20+884.13 9113+485.8482/3+193.2981013 (20) (28)

with the same definitions used in Eq. (19). It represents the <1>~8 =0 (29)
selected input values within 0.2% except those for tempera-
tures above 370 K where deviations increase up to 1%. No
The equation for the saturated vapor density is written as <1>88 = I aid;(d;-l) 8dj-2T/j
i-I

In ~ = -2.837294 8113
Po
- 7.875988 82/3 + 4.4785868 112 + ~1 exp( - 8\Nt a{ d,' -d,- k8'(2dr<-k-l +k8') ] 8 "i'))
( 1
d

-14.140125 89/4 -52.361297 8 1112 (21) (30)

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) 665

<I>~ = ~ajfj(fi-1)8di,.ti-2+ i (exP(-8k) t a if;(li-1)8 di ,.ti-2)

in slight contradiction to the extensive series of Hou ef al. 23
whose densities deviate from them by almost 0.2%. Ap-
i-I k-l ;-Nk-+I
(31) proaching the critical temperature, the deviations between
<I>~s == both series increase up to 1%. The decision to prefer the data
!a;d;fi 8di -
i-I
1
,.ti-
l
+I (exP( -Sk) t
k-I i-NIc-+1
a j f;(d j -kSk)Sdi-l 1
T ti - ) (32)
of Tillner-Roth and Baehr5 was based on a consistency test
between liquid densities and caloric measurements in the liq-
uid phase described in Sec. 2.2.1. This test indicates that the
densities of Hou et al. 23 are not consistent with the measured
caloric properties in the liquid. Another indicator for the accu-
4. Comparisons with Experimental Data racy of the liquid densities of Tillner-Roth and Baehr5 is the
HM-EOS, originally fitted to the densities ofHou et al. 23. The
In the following section comparisons are given between HM-EOS predicts density values about 0.2% lower than our
experimental values, our own EOS, and the equations of state own· EOS at low temperatures but agreement with the densi-
mentioned in Sec. 1.2. Generally, deviations shown in the ties of Tillner-Roth and Baehr5 improves with rising temper-
figures are based on our own EOS. Where comparisons with ature. Obviously, the influence of the slightly inconsistent
the other equations of state are made, those equations were densities of Hou et ai. 23 is superseded by the influence of
evaluated for temperatures or pressures lying in the middle of caloric input data in the liquid phase forcing the HM-EOS to
the interval of the specific plot. If a deviation plot is con- tend more to the consistent densities of Tillner-Roth and
cerned with a certain isotherm or isochore the equations were Baehr5, although they had not been used for establishing the
evaluated at the temperature or density valuesjndicated in the HM-EOS. Very recently, a new set of liquid densities was
respective plot. published by Klomfar ef al. 28. Their measurements confirm
the densities of Tillner-Roth and Baehr5 within ±0.08%. The
4.1. Single-Phase Properties HE-EOS and the PNSW-EOS show density deviations from
our own correlation of about 0.2% at low temperatures but
4.1.1. (p,p, T)-Oata they increase when approaching the saturation boundary at
higher temperatures.
Because of the large number of measurements the (p ,p,T)- Deviations of pressure and density in the near-critical and
surface is divided into four sections for appropriate discus- supercritical region are shown in Fig. 7. The fundamental
sion: EOS represents the pressures of Tillner-Roth and Baehr 4 •S5
and Dressner and Bier12 within±0.2% even as close as 1 K
• vapor region (p<0.8Pn T<385 K), to the critical temperature. For higher supercritical tempera-
• liquid region (p>l.3pc, T<385 K), tures density deviations are within ±O.2% for these two sets
• near-critical region (0.8pc<p<1.3pc, of data. Good agreement is also observed for the (p ,p,T)-data
370 K <T<385 K ), of Piao ef ai.43 in the vicinity of the critical point. The HM-
• supercritical region 1>385 K. EOS, HE-EOS, and the PNSW-EOS show relatively large
deviations from the experimental data up to 0.5% of pressure
Pressure deviations between values calculated from our in the near-critical region. For higher supercritical tempera-
own EOS and experimental results in the gaseous phase are tures, density deviations of these three equations of state from
shown in Fig. 5. The data of Dressner and Bierl2 and of our own EOS are particularly large for high pressures, ex-
Tillner-Roth and Baehr4 are generally represented within ceeding ±0.5%. Deviations of (p ,p,T)-properties calculated
±0.05%. Deviations are slightly larger for the two lowest from the extended cross-over model developed by Tang
Burnett-isotherms of TiIlner-Roth and Baehr4 reaching ef ai. 53 are included in Fig. 7. The range of validity of Tang's
+0.08%. This is due to the larger uncertainties of the relatively model is from 200 kg/m3 to 800 kg/m3 for temperatures up to
short Burnett-isotherms. Good agreement is also observed 450 K. Differences in pressure are within ±0.5% in the near-
for the values measured by Qian et al. 45 and those ofWeber8 critica1 region and deviations in density are below ±0.5% in
at densities below 100 kg/m;) with deviations mostly below the supercritical region except tor the highest isotherm evalu-
±0.05%. At higher densities, Weber's results show devia- ated .at 447.5 K which is rather close to the upper limit of
tionsup to +0.12% increasing with density. The other three validity of Tang's model. The agreement between our own
equations of state had also been fitted to the values of Tillner- EOS and Tang's model is best for densities and temperatures
Roth and Baehr4 and predict about the same behaviour in close to the critical point where deviations are below ±0.2%
the gaseous phase. Differences in representation are observed of pressure. Generally, deviations of Tang's model increase
near the saturation boundary and for densities approaching for high and low density values.
the critical value, where deviations of the HE-EOS and In the following paragraphs the results of data analysis for
the PNSW-EOS from our own EOS increase up to ±0.3% all available (p ,p,T)-measurements are referred to seperately
which is higher than the estimated uncertainties of the mea- for each source listed in Table 2.
surements.
In the liquid, Fig. 6, our own EOS represents the densities 1. (p ,p,T)-values of Baroncini et al. 4 (Fig. 8)
of Ti1lner-Roth and Baehr5 generally within ±0.06% without These values comprise a temperature range from260 K
considerable systematic deviations. These measurements are to 360 K in the vapor phase and overlap with the

J PhvA. ChAm. RAf. DAtA. Vol. 23. No.5. 1994

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666 R. TILLNER·ROTH AND H. D. BAEHR

selected values of Tillner-Roth and Baehr4• As shown et al. 23 and of Tillner-Roth and Baehrs showing devi-
in Fig. 8, these values show large scatter from -0.5% ations of about -0.1% on the average. Furthermore,
to +1.2% of density and were not selected. deviations on isochores increase with increasing tem-
2. (p ,p,T)-values of Basu and WilsonS (Fig. 9) peratures. Due to these deviations and due to the result
These were among the first experimental (p ,p,T)-val- of the consistency test, Sec. 2.2.1, we decided not to
ues reported for HFC-134a. On the average, these data select the (p ,p,T)-data of Magee33 •
agree with the selected densities. Because of their large 10. (P,p,T)-values of Morrison and Ward38 (Figs. 15a,b)
scatter ranging from -1 % to +1%, indicating their These measurements were performed with a vibrating
larger uncertainty, the measurements of Basu and tube densimeter in the liquid phase between 280 K and
WilsonS were not used as input values. 365 K and pressures up to 5.5 MPa completely over-
3. (p ,p,T)-values of Dressner and Bier 12 (Figs. 5, 7) lapping the results of Tillner-Roth and Baehr5• Al-
Dressner and Bier12 performed Burnett-measurements though deviations from the fundamental EOS are
on 4 isotherms between 333 K and 423 K which agree within ±0.1 % for temperatures below 340 K the scat-
to within ±0.06% with the Burnett-values of Tillner- ter is about two times larger than that of the selected
Roth and Baehr 4 in the whole range of temperature densities of Tillner-Roth and Baehr5• Deviations at
and pressure. Although these data overlap with the temperatures above 340 K occasionally reach 0.4%.
other selected(p ,p,T)-data in the vapor phase, they The densities of Morrison and Ward38 were not used
were used as input values due to their exceptional due to these deviations and due to overlapping the
accuracy. selected measurements.
4. (p ,p,T)-values of Doringll (Fig. 10) 11. (p ,p,T)-values of Piao et al. 43 (Figs. 16a,b)
The investigations of Doring 11 were carried out in the The results of Piao et al. 43 cover both the vapor and the
gaseous phase for temperatures between 260 K and liquid region and agree within ±0.5% with the se-
400 K at medium densities overlapping the values of lected input values. They have not been used as input
Tillner-Roth and Baehr4 • The densities show large data because they completely overlap the selected data
systematic deviations up to +2% and do not supply and because their uncertainty is about three times
accurate information. larger compared to the input values in the region of
5. (p ,p,T)-values of Fukushima etaI. 15 (Fig. 11) interest.
This series has been rejected due to its scatter of 12. (P,p,T)-values of Park42 (Fig. 17)
about ± 1% of density and because it overlaps the Large systematic deviations exceeding - 3% of den-
selected more accurate data. On the average the values sity are observed between the Burnett-measurements
agree with the selected measurements. of Park42 and our own EOS at higher pressures. There-
6. (p ,p,T)-values of Hou et ai. 23 (Fig. 6) fore, these measurements were not selected.
This extensive experimental study comprises 429 liq- 13. (p ,p,T)-values of Qian et ai. 45 (Fig. 5)
uid densities between ·180 K and 380 K and pressures All 21 Burnett-values reported by Qian et al. 45 agree
up to 70 MPa. The values are about 0.2% lower than within 0.1 % with the Burnett-values of Tillner-Roth
the densities obtained by Tillner-Roth and Daclu.55 and Daeh~4. They completely overlap with the se-
used in the selected data set. The consistency test pre- lected measurements and, therefore, can be neglected
sented in Sec. 2.2.1 proves that the values of Hou without loss of experimental information.
et al. 23 are inconsistent with the availahle caloric mea- 14. (p .p.T)-values of Tillner-Roth and Baehr 4 (Figs. 5. 7)
surements in the liquid phase, and thus were not used This set of measurements comprises 411 values for
to develop the EOS. temperatures between 293 K and 453 K at pressures
7. (p ,p,T)-values of Kesselman et al. 27 (Fig. 12) from 0.1 MPa to 16 MPa. Comparisons between these
Most of the liquid densities of Kesselman et al. 27 agree values and measurements of Qian et al. 45 and Dressner
with the selected values within 0.3% but some data and Bier12 show excellent agreement. Furthermore,
points show deviations up to I % of density especially comparisons between derived second virial coeffi-
in the vicinity of the saturation boundary and at very cients and results reported by other suun.:cs IR • 1?5 R (;U11-
high pressures. Since they also overlap the selected firm the accuracy of these measurements. 393 of these
liquid densities they were not included. (p ,p,T)-data were used as input values for thecorrela-
8. (p ,p,T)-values of Maezawa et al. 32 (Fig. 13) tion process except for the first one or two values of the
Ten densities in the liquid phase were measured by supercritical Burnett-isotherms at the highest pres-
Maezawa et al. 32 overlapping other measurements. sures, which are generally of lower accuracy than the
They agree well with the measurements of Hou et al. 23 remaining points of a Burnett .series.
and are, therefore, about 0.2% lower than the measure- 15. (p ,p,T)-values of Tillner-Roth and BaehJ-',5 (Figs. 6, 7)
ments of Tillner-Roth and Baehr5 thus being not se- 432 (p ,p,T)-values in the liquid and supercritical re-
lected. gion at high densities between 243 K und 413 K at
9. (P,p,T)-values of Magee;);) (Fig. 14) pressures up to J 6 MPa arc reported from this source
150 liquid densities were reported by Magee33 obtained measured with a vibrating tubc densimeter. Prom these
during his isochoric heat capacity measurements. His data, 413 values were selected but (hohe ut low densi-
results are located between those of the series of Hou ties in the supcrcritical region Ht pressures below

J. Phys. Chern. Ref. Data. Vol. 23. No.5. 1994

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 THERMODYNAMIC PROPERTIES OF1, 1,1,2-TETRAFLUOROETHANE (HFC-134A) 667
4 MPa were excluded because their accuracy was sig- 4.1.3. Isochoric Heat Capacity
nificantly lower.
16. (P,p,T)-valuesof Weber 8 (Figs. 5, 7, 18) 150 isochoric heat capacities were measured by Magee33 in
The .isochoric measurements perfonned by Weber 8 the liquid region. A detailed sample of the deviations from the
are based upon a Burnett expansion series perfonned at EOS is given in Fig. 21. Most of these .experimental data· are
36M.15 K to which the densities of the isochoric represented within ::!: I % which corresponds to twice the un-
measurements are related. His results agree certainty given by Magee33 . The highest deviations occur for
within ±O.05% of pressure with the Burnett measure- the isochores in the high temperature range while at lower
ments of Tillner-Rothand Baehr54 at low densities but temperatures deviations are generally less than ±0.6%. Al-
show deviations up to +0.12% at pressures above 2 though deviations are comparatively low, it seems that there
MPa (cf. Figs. 5, 7). A more detailed comparison be- are sometimes deviations on an isochore being systematic
tween the (p ,p,T)-data of Tillner-Roth and Baehr\ with respect to temperature~ These effects may be related' to
Dressner and Bier12, and Weber8 is given in Fig. 18. It the deviations observed for Magee's (p ,p,T)-values discussed
shows deviations. of pressure between 360 K and in Fig. 14.
400 K for pressures between 1 MPa and 5 MPa. The There are small differences of data representation between
:esults of Tillner-Rothand Baehr4 and of Dressner and our own EOS and the other three equations of state being .
Bier 12 ,·which were both selected, agree within 0.05% largest at temperatures above 300K whete they reach ±1%.
which is smaller than the combined limit of uncertainty
estimated to be about :!:0.08% for these sets of mea-
surements. The pressures reported by-Weber 8 are sys- 4.1.4. Isobaric Heat Capacity
tematically higher than those of Tillner-Roth and
Baehr .and also than those of Dressner and Bier for Measurements of the isobaric heat capacity Cp are reported
densities around 200 kglm3. Deviations occasionally by Gurtner and Emstl° in the gaseous phase, and by Wirbser 9 ,
exceed the combined limits of uncertainty. Due to Saitohet al. 46 , and Nakagawa et al. 39 in the liquid phase. Only
these systematic deviations,. we· decided not to select those by Gurtner and Ernstl° and 117 of those measured by
the measurements of Weber 8• Wirbser9 were used as input data during the optimization
17. (p ,p,T)-values of Zhu et al. 63 (Fig. 19) process. The values of Saitoh et al. 46 and of Nakagawa et al. 39
The results of Zhu et al. 63 are located in the gaseous overlap those of Wirbser9 and, therefore, were not selected.
phase and show systematic deviations of density Deviations of isobaric heat capacities from the fundamental
from -1 % to +0.7% compared to other reliable values. BaS are plotted for several isobars in Fig. 22. The cp.values
of Wirbser 9 , Nakagawa et al. 39, and of Saitoh et al. 46 are
generally represented within ± 1%. Exceptions are the critical
4; 1.2. Second Vi rial Coefficient region where deviations increase up to 60% and the supercrit-
ical region above 500 K where deviations are up to 2%. In the
Values of the second virial coefficient were reported by six critical region there' are only a few cp-measurements avail-
authors (see Table 2). They were mostly derived from (p ,p,T) able. Therefore, caloric properties are not represented well
or speed of sound measurements. We preferred not to include near the critical point by the analytical equation of state pre-
virial coefficients during the correlation process because they sented here. Thus; calculation of heat capacities and speed of
are derived properties and, therefore, their accuracy may be sound should be avoided for densities within 400 kglm3 to 600
affected by deficiencies of the models used to derive them. kg/m3 at temperatures between 370 K and 380 K. Thisexc1u-
However, the· experimental information of the second.· vitial sian does not apply to (p ,p,T)-properties; they are represented
coefficient is still considered because <speed of sound and within±0.15% of pressure as shown in Fig. 7. For tempera-
(p ,p,T)-properties from which they were ·derived are included turesabove 480 K, HFC-134a is supposed to decompose31 .
during the optimization process. This might explain slightly larger deviations above 500 K~
<DeviationsofB~values from the fundamental EOS are plot- The three other· equations of state show good agreement
ted in Fig. 20. Above 290 K, the virial coefficients of Tillner- with OUf own EOS in the liquid phase, especially at low
Roth and Baehr4, Dressner and Bier12 , and Goodwin and temperatures. In the gas, when approaching the state of satu-
Moldover18 are represented by· our own EOS within ± 1%. At rated vapor, the three other equations of state all exhibit a
temperatures below 290 K the results of Goodwin and Mold- downturn in heat capacity of about 3% compared to our own
over1S are represented within 1.5% because their speed of EOS and available measurements. This effect is particularly
sound values had been included during the formulation of the large for the PNSW·EOS and for the HE-EOS while the
equation of state. Another set of s~cond virial coefficients by amount of deviation between the HM-EOS and our own cor-
Beckermann and Kohler6 was also derived from speed of relation is generally below 2%. These differences between the
sound measurements showing deviations of about +1%. The equations are attributed to the small number of available ex-
49
values reported by Schramm etal. .50 show deviations up to perimental Cp -data in the immediate vicinity of the saturation
3%. line, thus allowing too much flexibility during· the optimiza-
TheHM..EOS and the HE-EOS agree well with the own tion of any equation of state. At higher temperatures, devia-
equation. within ±29'0. The PNSW-EOS shows deviations up tions increase particularly for the HM-EOS and the HE-EOS
to 4% at the upper and lower temperature limits of Fig. 20. exhibiting values up to :!:5%. The PNSW-EOS agrees better

.1 Dh\IC~ ~hAm RAf. DAtA. Vol. 23. No.5. 1994

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668 R. TILLNER-ROTH AND H. D. BAEHR

with our own EOS. Large differences between all four equa- coefficient decreases exhibiting negative values at tempera-
tions of state occur in the critical area also for the cross-over tures below 375 K. These data are represented with deviations
model developed by Tang et al. 53. cp-values calculated from up to 10% due to their small values. Absolute deviations in the
their model show large systematic deviations from the mea- liquid phase are always less than 0.1 K/MPa. In the whole
surements located outside the limits of the diagrams of range of measurements, all equations of state predict about the
Fig. 22. same Joule-Thomson coefficients as indicated in Fig. 25.

4.1.5. Speed of Sound

4.2. Saturation Properties
Four sets of speed of sound measurements are reported in
the literature which are listed in Table 2. In the gaseous phase, 4.2.1. Vapor Pressure
the speed of sound was measured by Goodwin and Mold-
over lS and by Beckermann and Kohler6 for temperatures be- Four sets of measured vapor pressures fulfil the require-
tween 233 K and 410 K at pressures up to 0.6 MPa. In the ments of being highly accurate data and were selected for the
liquid phase, speed of sound measurements are reported by formulation of the EOS. These are namely the measurements
Guedes and Zollweg 19 and by Takagi52 for temperatures be- of Goodwin et ale 17, Weber 8, Tillner-Roth and Baehr\ and
tween 180 K and 380 K at pressures up to 70 MPa. Deviations the six lowest pressures measured by Magee and Howley34.
between values calculated from the fundamental EOS and the Deviations between these values and the fundamental EOS
measurements are plotted in Fig. 23 for the gaseous phase and are shown in Fig. 26. The values are represented within
in Fig. 24 for the liquid phase. ±0.05 % at temperatures above 220 K and within ±20 Pa at
In the gaseous phase, our equation has been fitted to the lower temperatures. The offset of about 0.1 % observed for the
values of Goodwin and Moldover l8 which are represented values of Goodwin et al. 17 at 265 K results from changing the
within ±0.03%. The measurements of Beckermann and apparatus. At temperatures above 310 K the series of Tillner-
Kohler6 generally agree with the values of Goodwin and Roth and Baeh~ and of Weber 8 agree remarkably well,
Moldover l8 within the limits of uncertainty but on some within ±0.01 %. Both series are represented by the EOS
isotherms they reveal systematic deviations up to ±0.07%. within about the same limits of uncertainty. The representa-
Therefore, the values of Beckermann and Kohler6 have not tion of vapor pressure by the HM-EOS is about the same in
been used as input data. The HM-EOS predicts about the the whole temperature range. The HE-EOS and the PNS\y-
same values as our own correlation but deviations increase up EOS show larger systematic deviations up to +0.4% in the
to ±O.06% when approaching the saturated vapor state. This vicinity of the critical temperature.
effect corresponds to the respective Cp -deviations shown in The 12 remaining series listed in Table 3 were not used as
Fig. 22 attributed to the absence of caloric measurements in input values. These data either show larger scatter or system-
the immediate vicinity of the saturation boundary. atic deviations from the above mentioned measurements as
Furthennore, an offset of about 0.02% between our own shown in Fig. 27.
equation of state and the equations of the other authors is
observed at higher temperatuH!S fur diminishing pressure due
to a slightly different representation of the ideal gas heat 4.2.2. Saturated Liquid Density
capacity c; at high temperatures (cf. Fig. 3) corresponding to
the r.:-deviMion of about 0.5%. Available measurements of the satnrated liquid density are
In the liquid, our equation is based on the speed of sound listed in Table 3 and are plotted as deviations from the EOS
values of Guedes and Zollweg 19 which are predicted within in Fig. 28. The equation of state has not been fitted to any
±0.3% except for some values in the critical region. The saturated liquid densities. These were mostly derived from
values of TakagiS2 are up to 0.7% lower than those of Guedes compressed liquid densities of which numerous values were
and Zollweg 19 and, therefore, were not used to establish our used as input data.
EOS. Comparisons with the HE-EOS and the HM-EOS reveal Four data sets agree well within ±0.15% and are repre-
small systematic deviations although these equations still pre- sented by our BOS within the same narrow limits. These are
dict the speed of sound measurements within ±0.3%. The namely the measurements performed by Yokoyama and
PNSW-EOS shows large systematic errors especially at low Takahashi61 , Kruse 29 , Niesen et al. 40, and Ti11ner-Roth and
temperatures and low pressures. Baeh~5. At lower temperatures, the fundamental EOS shows
deviations from the measurements of HOll et ale 23 and
Maezawa ef al. 32 similar to their compressed liquid densities
4.1.6. Joule-Thomson Coefficient (see also Fig. 6). At temperatures approaching the critical
point, the values reported by Fukushima et of. 16 are smaller
108 Joule-Thomson coefficients measured by Wirbser9 while the densities reported by Kabata ef al. 26 are Jarger than
cover the range of temperature between 333 K and 423 K at the pI-values predicted by the EOS.
pressures up to 20 MPa. Deviations are plotted In t'ig. 25. In t'rom the other equations of state, the H M -EOS agrees best
the gaseous phase, the measurements are represented within with our own equation although at low temperatures, system-
± 3 % compared to our own equation of state. In the liquid atic deviations are observed which accord with the results for
phase at increasing pressures the value of the J oule-Thomson the compressed liquid density. The HE-EOS and the PNSW-

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) 669
EOS show their largest deviations when approaching the crit- ments. The good representation was achieved by using
ical te~perature. Magee's single-phase isochoric heat capacities as input values
being related to the two-phase heat capacity d 2) by the rela-
4.2.3. Saturated Vapor Density tions indicated above. For temperatures below 190 K,
Magee's c~2)-values were used to establish the fundamental
There are six sets of measurements for the saturated vapor EOS because for these temperatures no single-phase cv-values
density which are listed in Table 3. Comparisons of them to were available.
our own EOS· are shown in Fig. 29. The results obtained by The equations of other authors reveal deviations which are
Webe~8, Fukushima I4•16, and Niesen etal. 4O agree with our below 1% at temperatures above 260 K but increase for lower
own equation within ±2% which is in most cases within the temperatures. They become larger when approaching the
estimated uncertainty. The deviations for the values reported triple point where the values predicted by the HM-EOS are
by Morrison and Ward38 are considerably large, reaching val- too small while those predicted by the HE-EOS and thl
ues up to 18%. In the vicinity of the critical region the equa- PNSW-EOS are larger than the measured values.
tion agrees best with the data of Fukushima14 while the values
of Kabata et al. 26 show large negative deviations. The predic-
tion of the saturated vapor density by the other three equations 4.3. Critical Point
of state is similar to our own EOS at high temperatures. At
lower temperatures, deviations are up to ±2% due to· the From the conditions of the critical point
different prediction of the second virial coefficient.
P
( dfJv) c =0 and (rip)
(ju2 i; == 0, (37)

4.2.4. Isochorlc Heat Capacity In the Two-phase Region

the critical parameters can be calculated. The critical point of
160 values of the isochoric heat capacity C~2) in the two- the fundamental equation of state is located· at:
phase region were measured by Magee33 • This kind of prop-
erty is very complex. In Fig. 30, the shape of a cv-isotherm is Tc = 374.21 K Pc = 511.95 kglm3 Pc =- 4.05928 MPa.
qualitatively plotted versus volume. A value for the two-phase
heat capacity d 2) is obtained from the two-phase heat capac- Critical te~perature and critical density are compared with
ities at saturated liquid and saturated vapor c~ and c~ according measured critical parameters in Fig. 32. The critical tempera-
to ture is very close to those of Kabata et ai. 26 and of Fukushima
(2) v-vl -11 -I et al. 16. It is located within the estimated uncertainties of most
=- C + -,-,-, (cv-c ).
-I
CV v v (33)
v -v researchers which are indicated by the rectangular areas in
Fig. 32. The critical density agrees within ± 1% with mea-
The jumps ~c~ and ~C~I of the isochoric heat capacity on the sured values being also within the estimated uncertainties.
saturation boundaries are calculated from

Ac~- = c~ - c.(v,T) - -~t -(¥r)J (~r (34)

5. Conclusion
and A fundamental equation of state has been established for
Ac~= c~.;... cv(v",T) = _T[ddT
Ps - (ap )
aT v"
J2 (ap)-l.
av v"
(35) the Helmholtz free energy of HFC-134a. It covers the temper-
ature range from 170 K to 455 K for pressures up to 70 MPa.
The fundamental equation of state represents nearly all avail-
The single phase isochoric heat capacities and the derivatives able measurements within their experimental uncertainties for
(ap/fJv) and (fJp/fJT) are obtained from the fundamental equa- the properties in the single-phase regions as well as for satu-
tion of state according to the relations given in Table 5. The ration properties. The only exception is the representation of
first derivative of the vapor pressure is calculated from the heat capacity and speed of sound in the vicinity of the critical
law of Clausius-Clapeyron point because only very few experimental data are available
in this part of the thermodynamic surface to support the equa-
tion of state. The results for the isobaric heat capacity at
(36)
temperatures above 453 K show that extrapolation up to
523 K is possible within narrow limits· of uncertainty. Com-
These relations illustrate the complexity of the two-phase heat parisons with the HM-EOS at high pressure shows that rea-
capacity which contains information about the whole sonable results can be expected even at pressures up to 100
isotherm reaching from ideal gas to compressed liquid. Thus, MPa.
comparisons of this property are a sensitive test for an equa- Although there are about 4000 experimental data available,
tion of state concerning the consistency of the whole data set. there are stilI some additional experimental data needed. Re-
Deviations between the measured values and values calcu- ferring to the Secs. 4.1 ~4 and 4.1.5, there are only a few caloric
lated from the EOS are shown in Fig. 31. They are less than measurements in the immediate vicinity of saturated vapor
± 1% in the whole temperature rWlge of Magee's experi- state which lend to different predictions from different equa-

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670 R. TILLNER-ROTH AND H. D. BAEHR

ions of state. Furthermore, a set of liquid densities of high 13Elhassan, A.E.; deReuck, K.M.: Preliminary report on equations of state for
accuracy at temperatures below 240 K would be very valuable environmentally acceptable refrigerants. Prepared for lEA Annex 18 meet-
ing, Purdue University 13th July 1992, IUPAC Thermodynamic Tables
because the only set of densities available in this region (Hou
Project Centre, Imperial College, London 1992.
et al. 23 ) has been proven to be somewhat inconsistent with 14 Fukushima, M.; Watanabe, N;; Kamimura, T.: Measurements of the vapor-
other reliable measurements. Due to these deficiencies in the liquid coexistence curves and the critical parameters of HCFC 123 and
experimental uata, Aunex 18 uedueu tu reupenlhe pru~e:s:s of HFC 134a. Trans. of the JAR, 7 (1990) 2,85.
data evaluation for HFC-134a in the future when new reliable 15 Fukushima, M.; Watanabe, N; Kamimura, T: Measurements of PVT-prop-

erties of HCFC123 and HFCI34a. Trans. of the JAR, 7 (1990) 2, 243.

measurements become available. Nevertheless, with this large
16 Fukushima, M.: Saturated liquid densities of HCFC 123, HFC 134a,
amount of experimental infonnation available, HFC-l ~4a is CFC 11, ana CFC 12. Trans. of the JAR, 8 (1991) 65.
already one of the fluids for which the thermodynamic prop- 17 Goodwin, A.R.H.; Defibaugh, D.R.; Weber, L.A.: The vapor-pressure of
erties are known at a superior level of accuracy. 1,1,I,2-tetrafluoroethane (R 134a) and chlorodifluoromethane (R 22). Int.
'J. Thermophysics 13 (1993) 837.
18 Goodwin, A.R.H.; Moldover, M.R: Thermophysical properties of gaseous
6. Acknowledgements refrigerants from speed of sound measurements. I. Apparatus, model, and
results for 1,1,I,2-tetrafluoroethane R134a. J. Chern. Phys. 93 (1990) 4,
The authors are grateful to all participants of Annex 18 for 2741.
their fruitful discussions. Special thanks are dedicated to 19 Guedes, H.J.R.; Zollweg, J.A.: Speed of sound in liquid R 134a. Int. 1

K. M. deReuck from IUPAC, London and to S.G. Penoncello Refrig. 15 (1992) 6, 381.
20 Gurtner, 1.; Ernst, G.: Personal Communication, Universitat Karlsruhe
from CATS, Moscow, Idaho who kindly corrected the En-
1992.
glish language and whose reports on the eguations of state 21 Huber, M.L.; Ely, J.P.: An equation of state fonnulation 01 the thermODY-
comparisons were very helpful during the preparation of this namic properties of R 134a (1,I,I,2-tetrafluoroethane). Int. J. Refrig. 15
paper. We would also like to thank all authors from whom we (1992) 6, 393.
received their experimental information prior to publication 22 Huber, M.L.; McLinden, M.O.: Thermodynamic properties of R 134a
(l,I,I,2-tetratluoroethane). Proc. Int. Ketrtg. Conf., PUraue university,
and M.O. McLinden who sent us his data base of thermody-
USA, Vol. II, (1992) pp. 453.
namic properties. Furthermore, we thank the Deutsche 23 Hou, H.; Holste, lC.; Gammon, B. E.; Marsh, K. N.: Experimental densi-
Forschungsgemeinschaft (DFG) for her financial support. ties for compressed R 134a. Int. J. Refrig. 15 (1992) 6, 365.
24 Penoncello, S.G.; Jacobsen, RT.; Williams, R.c. Lemmon, E.W.: Thenno-

physical Properties of the Environmentally Acceptable Refrigerants-Equa-

7. References tion of State Comparisons for HFC-134a and HCFC-123. Final Report to
the lEA-Annex 18, Center for Applied Thermodynamic Studies, University
1 Ahrendts, J.; Baehr, H.D.: Direct application of experimental values for any of Idaho, Moscow, 1993.
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state. Int. Chern. Eng. 21 (1981) 557. cluding liquid and vapor phases from 63 K to 2000 K with pressures to
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methane and l,l,I,2-tetrafluoroethane. Fluid Phase Equil. 63 (1991) 151. vapor-liquid coexistence curve and the critical parameters for 1,1, l,2-tetra-
3 Baehr, H.D.; Tillner-Roth. R: Measurements and correlation of the vapour fluoroethane. Int. J. Thermophysics 10 (1989) 3, 605.
pressures of 1,1,1 ,2-tetrafluoroethane (R 134a) and of 1, I-difluoroethane 27 Kesselman, P. M.; Zheleznyii, V. P.; Semenyuk, Y. V.: Thermophysikalis-
(R 152a). J. Chern. Thermodynamics, 23 (1991) 1063. che Grossen des Kaltemittels R 134a in der ftussigen Phase. Kholoa. Telch.
4 Baroncini, C.; Giuliani, G.; Pacetti, M.; Polonara, F.: Experimental study of 7 (1991) 9.
thermodynamic properties of 1,1,1,2-Tetrafluoroethane (R 134a). In: Ther- 28 Klomfar, J.; Hruby, J.; Sifner, 0.: Measurement of the p-v-Tbehaviour of
mophysical Properties of Pure Substances and Mixtures for Refrigeration. refrigerant R 134a in the liquid phase. Int. J.Thermophysics, 14 (1993)
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7. Bender, E.: Zur Aufstellung von Zustandsgleiehungen, aus denen sich die schaften des Kaltemittels R 152a und seiner Mischungen mit R 134a bzw.
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Methans. Kiiltetechnik-Klimatisierung 23, 1971. 32 Maezawa, Y.; Sato, H.; Watanabe, K.: Saturated liquid densities of HCFC-
II Bier, K.; Oellrich, M.; Turk, M.; Zhai, J.: Untersuchungen zum 123 and HFC-134a. J. Chern. Eng. Data 35 (1990) 225.
Phasengleichgewicht von neuen Kaltemitteln und Kaltemittelgemischen in 33 Magee, J.W.: Measurements of molar heat capacity at constant volume (Cv )
einem grossen Temperaturbereich. DKV Tagungsbericht 17 (1990) 2, 233. for 1,I,I,2-tetrafluoroethane (R 134a). Int. J. Refrig. 15 (1992) 6, 372.
9 Chen, S.S.; Rodgers, A.S.; Chao, J.; Wilhoit, RC.; Zwolinski, BJ.: Ideal 34 Magee, J.W.; Howley, J .B.: Vapor-pressure measurements on 1,1,1,2-
gas thermodynamic properties of six fluoroethanes. J. Phys. Chem. Ref. tetrafluoroethane (R 134a) from 180 to 350 K. Int. J. Rcfrig. 15 (1992) 6,
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algorithm. Technica:l summary report No. 20 I 0, Mathematics Research R 22, R 11 und R 113 - Beschreibung des thermoJynarnischen Zus-
Center, Madison 1979. tandsverhaltens bei Temperaturen bis 525 K und Driickcn his 200 MPa.
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(CH 2 F-CF 3 ) and R 123 (CHCh-CF3 ). Proc. Meet. I.I.R Comm. BI, Tel 36 McLinden, M.O.; Gallagher, J.S.; Weber, L.A.; Morrison. G.: Ward, D.K.;
Aviv (1990) 1,57. Goodwin, A.R.H.; Moldover, M.R; Schmidt. J.W.: Chac, H.B.; Bruno,
12 Dressner, M.; Bier, K.: Thermische Mischungseffekte in biniiren Gas- TJ.; Ely, J.F.; Huber, M.L.: Measurement and formula/ion of the thenno-
mischungen mit neuen Kaltemitteln. Fortschr.-Ber. VOI-Z., Reihe 3, Nr. dynamic properties of refrigerants l34a (1,1.1 ,2-lctranuDroclhane) and 123
332, Dusseldorf: VDI-Verlag 1993. (I,I-dichloro-2.2,2-trifluoroethane). ASHRAE TrailS. <)) (1989) 2, 263.

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 THERMODYNAMIC PROPERTIES OF 1,1, 1,2-TETRAFLUOROETHANE (HFC-134A) 671

37 Moldover, M.R; Trusler, J.P.M.; Edwards, TJ.; Mehl, J~B.; Davis, RS. SI Setzmann,U.; Wagner, W.: Anew equation of state and tables of thermo-
-Measurement. of the universal- gas' constant Rusing . a sperical- acoustic.' dynamic propertiesJor meth~e covering the range from,the melting line to
resonator. J. Res. Natl.: Bur. Stand. 93 (1988) 85. 625 Katpressures up to 1000 MPa. J. Phys.Chem. Ref. Data 20 (1991)
38 Morrison, G.; Ward, D.K.: Properties of two alternative refrigerants,l;1- 1061.
dichloro-2,2,2-trifluoroethane (R 123) and l,l,I,2-tetrafluoroethane s~ Takagi, T.:Thennophysical properties of environmentally acceptable fluo.,.
(R 134a). Fluid Phase Equil. 62 (1991) 65. rocarbonsHFC 134 and HCFC 123. JAR and Japan Flon Gas Ass. (1991)
3~ Nakagawa, S.; Sato, H.; Watanabe, K.: Specific heat at constant pressure 56.
for, liquid':new refrigerants. Proc. '27th Nat. Heat Trans. Symp. Japan, S3 Tang, S.; Jin, G.X.;Sengers, lV.: Thermodynamic properties ofl,I,l,2-
Nagoya (199Q) 42 L tetrafluoroethane (R 134a) in the critical region. Int. J. Therinophysics 12
40 Niesen, V.G.; vanPoolen, LJ.; Outcalt, S.L.; Holcomb, C.D.: Coexisting (1991) SIS.
densitie~ and vapor pressures of refrigerants R 22, R 134a, and R 124 at 300 13 Tillner-Roth, R; Baehr, H.D.: Burnett meaSurements and correlation of

to ,395-1C': 'Fluid Phase Equil. 97 (1994)81; gas-phase (p ,p,T) of 1; l,l,2-tetrafluoroetharie (R 134a) -and of 1,1-
41 Nishiul11i,H.; Yokoyama, T.: VapOr-liquid eqUilibrium for the system of difluoroethane (R 152a).J. Chern. Thennodynamics, 24 (1992) 413. '
R 134a-R 22. Proc. 11th Japan Symp. Therm. Prop~,Paper BIOS (1990) 95~ , IS Tillner-Roth, R; Baehr,H.D.: Measurements of liquid; near-critical; and
42Park, Y. J.:' Bestimmungdes thennischen Verhaltens neuer ArbeitsStoffe supercritiCal (P,p,T) of 1,I,l,2-tetrafluoroethane (R 134a)'andoil;1-diflu'-
derEnergietechnik mitHilfe einer Burnett-Apparatur, Dissertation, Univer- oroethane(R 152a). J. Chern. Thermodynaniics 25 (1993) 277;
sitiitKarlsruhe 1993; 56 Tillner-Roth, R.: Die thermodynamischen Eigenschaften.von R:l34a"

43 Piao,C.C.; Sato., H.; Watanabe~K.: An experimental study for PVT R 152a und ihren Gemischen-Messungen lind Fundamentalgleichungen:
properties ·"'of CFC' ··alternative 'refrigerant 1,I,I,2-tetrafluoroethane Forsch.':'Ber. DKV Nr.41, Deutscher. Kalte- undKlimatechnischer'Verein~
-(RJ34a).ASHRAE Trans., 96 (1990) 132. Stuttgart 1993 ..
44'Piao, C.C.; Noguchi, M;; Sato, K; ,Watanabe, K.: Equauon or state for 57 Wagner; W.: Eme mathematisch statistische Methode zurtl Aufstellen ther-
HFC l34a. in: Penoncello, S.G.; Jacobsen, RT.; Williams, R.C.Leminon, modynamischer Gleichungen-gezeigt am Beispiel der Oampfdruckkurve
E.W.: ThermophysicalProperties of the Environmentally Acceptable Re- reiner fluider Stoffe.Fortschr.-Ber. VDI-Z." Reihe 3, Nr. 39, Diisseldorf;
frigerants~EquatioIiof State Comparisons for HFC-134a and HCFC-123; VDI-Vedag: 1974.
Final.Report to the lEA-Annex 18, Center for Applied Thermodynamic 58 Weber, L.A: Vapor pressure and gas phasePVT data for l,l,I,2~tetm.>

Studies, University of Idaho, Moscow, 1993. fluoroethane. Int. J. ThermophysicslO (1989) 3,,617.
4S Quian, Z.Y.; Sato, H.; Watanabe, K.: Compressibility measurements ,of, S9, Wirbser, H.: Hochdruckstromungskalorimetrie: Spezifische Wannekapazi-
R-134aby the Burnett technique. Fluid Phase Equil. 78 (1993)323-329. tiiten und differentieller Joule-Thomson.,Koeffizienthalogenierter Kohlen.,.
46Saitbh, A~; Nakagawa,'S.; Sato, H.; Watanabe, K.:lsobaricheat capacity wassersloffe. Dissertation, UniversiUilKarlsnihe 1994.
data fot'liquid HFC-134a;J. Chern; Eng. Data 35(1990) 107. 60 Yamashita, T.; Kubota,B.; Tanaka, Y.; Makit~ T.; Kashiwagi,H.: Pl1ysi:
47 Saul, A; Wagner, W.: Afundamental equation for water covering the range cal properties of newhalogenatedhydrocarbons.Proc. '10th JapanSymp~·
from the melting line to 1273 K at pressures up to 25000 MPa. J; Phys. Thenn.Ptop. (1989) 75.
Chem. Ref. Data 18(1989) 1537. 61 Yokoyama, C.; Takahashi, S.: Saturated liquid densities of2,2-dichloro-
48 Schmidt, R; Wagner, W.: A new form of the equation of state for pure , 1,1 ,l-trifluoroethane (HCFC-123), 1,2-dichloro-l,2;2-trifluoroethane
"substances and its application to oxygen. Fluid Phase Equil. 19 (1985) 175. (HCFC-123a), 1,1,1 ,2-tetrafluoroethane (HFC-134a)and l,l,l-trifluo-
49 Schramm, B.; Hauck, J.;' Kern, L.: Messungen der 2. Virialkoeffizienten roethane (HFC-143a).' Fluid Phase Equil. 67 (1991) 227.
einiger neuer Chlorfluorkohlenwasserstoffe und ihrerbinaren Mischungeil ,2 Zhu, M.; Wll, J.; FU,Y.D.: New experimental vapor pressurerlata and a
beLTemperaturen vort296 K-475K. Ber. Bunsenges. phys.,Chemie, 96 new vapor pressure equation for HFC 134a.Fluid Phase Equil. 80(1992)
(1992} 6; 745. 99.
iO Schramm, R; Weber, C.: Measurements of the second virial coefficients of 63 Zhu, M.; Fu,. Y.; Han, L.: An experimental study of PV1propemes ot eFt:
some new chlorofluorocarbons and of their mixtures at temperatures in the alternative HFC 134a.FIuid Phase Equil. 80 (1992) 149.
range from 230 Kto 300 K. J. Chern. Thermodynamics 23 (1991) 281.

TABLE 1. Summary of experimental critical parameters. The sample purity is given in mass percent

Source Year Purity TJK pJMPa pJ(kglm3)

Basu and WilsonS 1989 99.95 374.22::!:0.lS 4.067::!:0.027 512.2::!:S

McLinden et al. 36 1989 99.94 374.18±0.01 4.056::!:0.0l 51S.3± 1
Yamashitaetal.6QO 1989 99.9 374.24::!:0.05 4.065±0.OOS
Kubota et ai. 3O • 1989 99.9 374.24::!:0.05 4.06S::!:0.005
Kabata et al. 26 1989 99.8 374.27::!:0.01 S08.0::!:3
Bier etal.
s 1990 99.9 374.09::!:0.05 4.052::!:0.06 SI4.0::!:10
Bier et ai. 8 1990 99.9 374.10::!:0.05 4.050::!:0.06 514.0::!:10
Fukushima et al. 14 1991 99.99 374.16±0.02 4.067::!:0.005 S07.0::!:5
Morrison and Ward 38 1991 99.95 374.23::!:0.01 4.068::!:0.005 515.2::!:2

·The values reported by60 and30 probably result from the same measurements .

•1. Phvs. Chern. Ret Data. Vol~23~ 1" ___ 5,'1994

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&72 R. TILLNER-ROTH AND H. D. BAEHR

TABLE 2. Summary of measurements in the single phase (v: vapor, I: liquid)1

Source Year Purity Number Range of data Uncertainties

total/used TIK p/MPa ST sp Sy

(p ,p,T)-measurements (y .. p)

Basu and Wilsons 1989 v 99.95 52/0 317-447 \-6.7 30mK O.OOlp 0.003p
Dressner and Bierl2 1993 v 99.9 121/121 333-423 0.3-58 5mK 0.OOO2p O.OOlp
DOring II 1990 v 11210 247-368 0.1-3.5
Weber8 1989 v 99.95 69/0 321-423 0.2-5.3 1 mK 10-4 p 0.OOO5p
Piao et al. 4l 1989 v,l YY.lS I~WU 3L.i-423 U.lS-12 IUmK 2 kPa ,U.OO2p
Maezawa et al. 32 1990 I 99.99 10/0 280-340 0.5-2 15 mK 5 kPa 0.002p
Kesselmann et al. 27 1991 1 99.9 65/0 212-345 0.4-21 20mK 1.5 kPa 0.OOO8p
Morrison and Ward38 1991 I 99.95 120/0 278-367 0.7-5.8 5mK 1 kPa 0.OOO3p
Hou etal. 23 ·1992 I 99.98 429/0 180-380 0.9-70 10mK 10 kPa O.OOlp
Baroncini et al. 4 1990 v 99.98 46/0 263-358 0.2-2.0 20mK 0.OO3p 0.002p
Tillner-Roth and Baehr4 1992 v 99.97 4111393 293-453 0.1-16 5mK 10- 4 P 0.OOO3p
s
Tillner-Roth and Baehr 1993 I,v 99.97 4321413 243-413 0.6-16 lOmK 0.OOO2p 0.OOO3p
Fukushima et al. '" 1990 v 99.8 63/0 294-424 0.6-5.7 10mK 3 kPa 0.002p
Magee33 1992 I 99.99 150/0 186-340 2.9-35 30mK 0.OOO7p 0.0015p
4S
Qian et al. 1992 v 99.99 21/0 320-340 0.1-2 lOmK 0.3 kPa 0.002p
Zhu et al. 63 1992 v 99.95 4210 283-353 0.1-1.3 l5mK 2 kPa
Park42 1993 v 220/0 333-423 0.3-14 5mK 0.OOO2p O.OOlp
Klomfar et al. 28 1993 99.9 89/0 204-298 1-56 50mK O.OOlp O.OOlp

Speed of sound (y - w)

Beckermann and Kohler6 1993 v 99.9 230/0 253-410 0-0.6 IOmK 0.OOO2p 2.10- 4 w
Guedes and Zollweg l9 1992 99.8 206/193 180-380 0.9-70 IOmK 0'OO15p <1m1s
Goodwin and Moldover l8 1990 v 99.94 94194 233-340 0-0.5 ImK 50Pa 10- 4 w
TakagiS2 1991 I 99.9 80/0 290-370 2-70 30mK O.OOlp 0.OO2w

Isobaric heat capacity (y - cp )

Wirbser9 1993 l,v 99.95 151/117 273-523 0.5-30 5mK 0.OOO2p (O.00I-O.1)cp
Gurtner and Ernst20 1992 v 99.95 42142 253-423 0-0.5 5mK O.OOOlp 0.002cp
Nakagawa et al. 39 1990 '1 37/0 273-356 0.5-3 lOmK 3 kPa 0.003cp
Saitoh et al. 46 1990 I 99.97 31/0 275-356 1-3 lOmK 3 kPa 0.003cp

Isochoric heat capacity (y - CII)

Magee33 1992 99.99 150/150 186-340 2.9-35 30mK 0.OOO7p 0.005clI

Joule-Thomson coefficient (y - I-L)

Wirbser9 1993 I,v 99.95 108/0 333-423 0.3-20 5mK 0.OOO2p (0.003-0.1)1-L

Second virial coefficient (y == B)

6
Beckermann and Kohler 1993 v 99.9 15/0 233-420 lOmK O.OIB
Goodwin and Moldover l8 1990 v 99.94 10/0 235-440 1 mK <O.OIB
Schramm et al. so 1992 v 5/0 303-473 10mK <0.02B
Schramm and Weber49 1991 v 410 233-293 lOmK <0.03B
Tillner-Roth and Baehr4 1992 v 99.97 19/0 293-453 5mK <0.015B
Dressner and Bier l2 1993 v 99.9 410 333-423 5mK <O.OlB
Weber8 1989 v 99.95 1210 323-423 5mK <O.OIB

IThe sample purity is given in mass per cent

J. Phys. Chem. Ref. Data, Vol. 23, No.5, 1994

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 THERMODYNAMIC PROPERTIES, OF1 ~ 1.,1,2;.TErRAFlUOROETHANE (HFC-134A) 673

TABLE 3. Summary :of m~ui~ments:QLsi:\turationproperties*

Source Year Purity ",Number Temperature-

totalluse4,. range TIK ST Sy

Vapor pressure (y - p,)

BaSu and WilsonS 1989 99.95 3210 :21<>:-369 30mK

Webers 1989· 99.95 22122 313-3.73 1 mK
Pi~9 ,~t~l.43 1,9~9 99~99 46/0 308-374 tOroK 2 kPa
Morrison and Ward38 1991 99~95, 1210 268-374 ImK 1.5 kPa
Maeiawa el al. 32 1990 9~.99 13f() 27.9~350 15 mK 7 kPa
Ktl~t~et ~1;3Q 1989 99.9 2510 ,25J..:.n3 50mK L2kPa',
BierS 1990 99.9 4110 204-37~ 10mK :(0;00 1--0.0 l)p
lJOring'l 1990 2210 218-358
Baroncini et al. 4 1990 99.98 6410 242-358 20mK 0.003p
Baehr and Tillner-Roth 3 1993 ~9.94 37/37 303-374 5mK O.OOO2p
FUkushima et al. IS 1990 99.99 4110 262~371 tOmK' 3 kPa
Nishhnni and Yokoyama41 1990 16/0 247-373 tomK O.0015p
Aritaet al. 2 ' 1991 99.5 3/0 27J..:.323 20mK 0.7 kPa
Goodwin et al. 17 1993 99.95 37/37 214-265 lOmK 20Pa
99.95 20120 266-313 1 mK 0;1 kPa
Niesen et al. 40 1993 99.9 1210· ' 316-370, ,0.1 K 3.5 kPa
zhuet al. 62 1992 99.95 ,43/0, 279-:-363 lOmK 0.5 kPa
Magee and Howley34 1992 99.99 1915 180-350 30mK 0.02-1.8 kPa

Sa~rated liqu,~d density <y ... p') "

Basu and Wilson' 1989 99.95 ' 9/0 238-371 0.003p
Doring II 1990 20/0 243-338
F\lkushima et a£. 15 19!:lU '99.Y':J 3/U 323-357 IOmK O.OO2p
FukUshima et al. 14 1991 99.99 8/0 369-374 20mK 1.5 kg/m3
,Fukushima16 1991 99:99 710 244-291 20mK 3 kg/m3
Houetal. 23 1992 99.98 10/0 180-360 10mK O~OOlp
26
Kabata el al. 1989 99.8" 1210 343-374 10 rriK' O.OO55p
Kruse29 1990 9/0 232-312 20mK O.OOlp
Maezawa et al. 32 1990 99~99 '25/0 199-370 "15fuK O.OO2p
Morrison and Ward38 1991 99.95 26/0 268-368 ImK O.OO3p
Niesen el al. 40 1993' .99.9 1210 316-370 ,O.lK 0.5 kglm3
Piab et al. 43 1989, 99.6 710 313~372 20mK O.OO5p
Tillner~Roth and BaeruJs 1993 99.91' 13/0 243-353 10mK O.OOO5p
Yok(>,yama and Takahashi 61 1991 99.8 2110 251-367 20mK O.003p

Satuptted vapor density (y - pI')

Fukushimal6 1991 99.99 6/0 29J..:.371 20mK O.OO2p

Fukushima er al. 14 1991 99~99 ':JIO 371-374 20'mK 1.5 kglm~
Kabata et al. 26 1989 99.8 1510 361-374 lOmK 0.OO55p
Morrison and Ward38 1991 99;95' 8/0 298-365 ltriK 0.003p
Niesen et al. 40 3
1993 99.9 1210 316-370 0.1 K "0.5 kglm
Webers 1989 99.95 510 '·32();';'365 ImK O.OOlp

"'The sample puritie are given in mass per cent

.1 I)hVA: Cham. Ref/Data. Vol. 23. No.5, 1994

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674 R. TILLNER .. ROTH AND H. D. BAEHR

TABLE 4. Coefficients oj I\~I. (>l) for liquid HFC-134a

... ..
~ ;-, '"

gi gl gl gi

Based on the data of Tillner-Roth and Bllehr\~

1 14.4523550 4 5.07020933,10- 4 7 22.22226808 10 ---1.58754782

2 0.491185102 5 -2.7877891524 8 3.986022479
3 -13.9840437 6 52.2926435 9 -66.2525696

Based on the data of Hou et al. 23

J 14.4937330 4 5.84703389,10- 4 7 25.29622142 10 -2.95713405

2 0.505043520 5 -2.9525905643 8 4.745207617
3 -13.9754460 6 62.3707965 9 -78.4183305

TABLE 5. Relations b.etween the dimensionless free energy and thermodynamic properties

Property Relation

Pressure! p(7,8) - RT pO +8<1l~)

u(7,8)
InternaJ Energy! - l' (ct>~ + 4>!)
liT
h(T,8)
Enthalpy!
liT
$(7,8)
Entropy!
Ir-
g(T,8)
Gibbs Energyl
RT
c v (T,8)
Isochoric Heat Capacity I -R-
cpfT,8)
Isobaric Heat Capacity
R
W2(T,8)
SPeed of Sound
~
Joule-Thomson Coefficient .,.(1',8) R P
(l + 8<1)~ - 8,.cl)~)i + (c,,/R)(1 + 28ct>~ + 82ct>h)
Max we 11 Rule! "iT (~ -~) .. <l>r(T,8')-<I>r(1',8") + In ~

Second Virial Coefficient I B(T) Pc ~ <1>~(1',8)

Third Virial Coefficient! C(T) p~ - ~ <1>~(T,8)

!Depending linearly on the Helmholtz free energy.

Abbreviations: <1>5 - (:~)T' <1>T - (~;)5' <1>8& - (~), <1>5T - (:~:), <1>TT - (~).

J. Phys. Chem. Ref. Data, Vol. 23, No.6, 1994

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THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETR.AFLUOROETHANE (HFC-134A) 675

TABLE 6. Exponents of the tenns in the bank of tenns (Eq. (12»

Sort of tenn 8-Exponents (d;)

(Counter) 1'-Exponents (fj)

d; - 1; 1.5; ... 7; 8
(No == 210) t/ - -0.5; 0; 0.5; ... 4; 5; 6; 7; 8; 10

exp (-8) 1'''8ai d;- 1; 1.5; ... 7

(N\ - 353) Ii - -0.5; 1; ... 4; 5; 6; 7; 8; 10; 12; 15

exp (-8 2) 'Tliaa; . d; ... 1; 2; ... 6

(Nz - 443) tj - 2; 2.5; ... 8; 9; 10

exp d/ - 3; 3.5; ... 6

(N3 - 520) 1/ - 5; 7.5; ... 27.5; 30

exp (-8 4) T li 8dl dj ... 3; 4; 5; 6; 8

(N4 == 565) fi-1; 5; 10; ... 40

exp (-8 5) 'T1i8d; di - 3; 4; 5; 6; 8

(Ns == 615) f/ - 1; 5; 10; ... 45

TABLE 7. Coefficients and exponents of the residual part of the fundamental equation of state for HFC-134a

aj Ii d; OJ Ii d;

1 0.5586817E-l -112 2 12 0.1017263R-3 1 4

2 0.4982230E+0 0 1 13 -0.5184567E+0 5 1
3 0.2458698E-l 0 3 14 -0.8692288E-l 5 4
4 0.8570 145E-3 0 6 15 0.2057144E+0 6
5 0.4788584E-3 3/2 6 16 -0.5000457E-2 10 2
6 -0. 18oo808E+1 312 17 0.4603262E-3 10 4
7 0.2671641 E+O 2 1 18 -0.3497836E-2 10 1
8 -0.4781652E-l 2 2 19 0.6995038E-2 18 5
9 0.1423987E-l 1 5 20 -0.1452184E-l 22 3
10 0.3324062E+0 3 2 21 -0.1285458E-3 50 10
11 -0.7485907E-2 5 2

.1 DhUQ ~hAm RAf. DAtA. Vol. 23. No.5. 1994

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 ~
0)

100 8

+ +++

~ • 7 + +++ +
"""">1<"*' ......... ,,, ..... ~EI.ffl
10 o
x
~~ + +:j:+++ +

!
+

o
o
o ~~,tr'tt'*~~!I~~~
xxx
xxx
xxx
6
+ +++
+
+e++ +
+++ X
. ?J
-t
r=r-
Z
o
(L
1 00 0
Xxx
xxx
xxx +++++ + 8 +
.
m
::D
::D
xxx + ~
2 xxx
xxx +
+++++ + 8 x
J:
»
xxx

" 5 + .... + + 0 + z
-xxx + c
0.. ~xxlxXX 8 x ;:t
flxX xxx
Xx xxx + x !='
o. 1
iilii 1
)!xxfjxxx
tIIxx x m
[J II
*" »
m
x J:
:D
4 +
x
•• x
x
x
De x
0.01 x
~ x
3
150 200 250 300 350 400 450 500 365 370 375 380 385

T/K
FIG. 1. Distribution of selected measurements in a (p ,T)-diagram of HFC-134a. +: Tillner-Roth and Baeh~5 (p ,p,T), X: Tillner-Roth and Baeh~4 (p ,p,T), 0: Dressner and Bier12 (p ,p,T), 0: Guedes and Zollweg 19 (speeu
of sound), .: Goodwin and Moldover 18 (speed of sound), 0: Magee33 (cv ), [I: Gurtner and Ernst20 (cp ), . : Wirbse~9 (cp )'

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) 677

(ppT)-information from (ppT)-information from

Tillner-Roth & Baehr Hou et 01.

~.
~
G)
~
0.1
0.2
0.0
.~
3o -0.1'
~ -0.2

~:~ ~.
+BB~~~""(b)~B ~ BB~~~~
0.0
-0.5
-1.0
II

:3 =;t·o.o:~~~; : ~r (C)f ~ o.o!oU~~§ ~ ~ r

i =: ~ : : ~f':~j (d)~ : : ~~~~~tj
j ~ : : ee9~BI~~~ i ~
0.5 2 5 10 20
(e)
0.5
: ~ e~ ~!~·~~!1
2
e
5 10 20

p/MPa -

FIG. 2. Results of the consistency test in the liquid phase of HFC-134a. (a): Deviations of densities at T<350 K and p<20 MPa from Eq. (4) using the respective
set of coefficients. x: TiIlner-Roth and Baehr', +: Hou et al.23. (b)-(e): Deviations of measured speed of sound from the correlation function reported
by Guedes and ZolIweg 19• (b): Measured speed of sound: [I: Guedes and ZoUweg 19 • +: TakagiS2 • (c): Speed of sound calculated from isobaric heat
capacities: 0: Wirbser9 • 0: Saitoh et al. 46 • •: Nakagawa et aI.39. (d): Speed of sound calculated from isochoric heat capacities: <): Magee33 • (e):
Speed of sound calculated from Joule-Thomson coefficients: !!'!!: Wirbser9•

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678 R. TILLNER-ROTH AND H. D. BAEHR

~
~ 2 ......
.""
0
0
0 ....-
,.. .""
.""

0
"" "-
0
00.
0 0
•
""
00.
U
"'--'"
0 -1
0
0
0
,.- 200 250 300 350 400 450 500

T/K ..
FIG. 3. Deviations of reported ideal gas heat capacity values from values calculated from Eq. (8). +: Gurtner and Emst 20 , . : Goodwin and Moldover 18 , 0;
Beckermann and Kohler6, 0: Chen etal. 9, - - HM-EOS and HE-EOS, -.-.- PNSW-EOS, - - - Basu and Wilson'.

Fundamental equation

Data base

Reg ression Linear data

Ana lysis Non-linear
Non-linear Optim ization
Optimization
of structure data

Linearization

FIG. 4. Optimization cycle during the fonnulation of the residual part <1>' of the fundamental equation .

.1 I)hu~ r.h~"" A~f n!!llt!!ll \/nl ~~ Nn r;. 1004

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 THERMODYNAMIC PROPERTIES OF 1,1,1 ,2~TETRAFLUOROETHANE (HFC-134A) 679

2 5 10 20 50 100 200 500

p!(kg/: t11 3) •
rIG. 5. PressuredeVia:tionsof (p;P?T)-properties in the gaseous phase from out own Eoi 0: Tillner-Roth and Baeh~, +: Tillner-Roth andBaeh~s ,.: Qian
et al. 45 , 0: Dressner and Bie~~12 ,~: Weber 58 , - . .- HM;.EOS, -- - - HE-EOS, -. -. - PNSW-EOS.

. 1 DhUQ ~h"m RAf nAt~_ Vnl. 2a.No. 5.1994·

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680 R. TILLNER.. ROTH AND H. D. BAEHR

=r; ~ · : ::6:-:0; :~i ~ :~.~~~::~.;:~~;;::~~

=~:; ~._._:._:.;. .:0~;2~ ;.~.;.~ ~ :~~I.c_:~~~~.I::;-'~:~
78 =~:; ~'-'-?-';'i~~~;:i~~i~~~1 ~ .: 3~:' ~]
1 ~'-'~!';~'~~~~~;§3
(360-370). K

=1:; \ ,./
"
I.".......
't'
.
.-._._-_._.-.-.
<><>0

II
....'
•
.....

~'_'~'~~'~'~9~:6§§.~~.:.~~
(370-375) K

=1:;

=1:;
0.5
~~~;~~;~~~~~ ~~~:--'--:_(~
1 2
7: ;~;-.-. .I.; _:;- ,- ~ ~
___
5 10 20 50 100 ·0.5 1 2 5· 10 20 50 100

p/MPa -
FiG. 6. Density deviations of (p ,p,T)-properties in the liquid phase from our own EOS. 0: Tillner-Roth and Baehr4 , 0: Tillner-Roth and Baehr5 , ~: Klomfar
28
etal. , . : Hou etal. 23 , - HM-EOS, --- HE-EOS, -.-.- PNSW-EOS.

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 THERMODYNAMIC PROPERTIESOF1,1,f;2-TETRAFLUOROETHANE(HFC-t34A) 681

(370-373}K
0.6

'aU'
o
o
0.0

~.0.6
~~'?-~i/I.: .: : .~ (373~~76) is (380-390) K .
",. 0.6 ----~----~--~~~~--~--~
.~:D..
.~

C)
0: --_--0.,. ...... [J .'
.................
-0.6
200 300 400 500 600 700 800 200 300 400 500 600 700 800

p/{kg/.m 3). ; -

O'6r<~~:
(41 Q-42S) K.

~.
~~ti6~':bl~
0.0
-0.6· f
.

. ....
-
er
......
/
.........
.
-.-.-.-.-
.
..• : 1
. .(3~O~400) K. .
o
.0

~
()

---------------
• , ......
Q.
.~
o
o (400-410) K
:0.6 . r---~----.---......-..,..;----.,;..-____~_ (440-455) K

-0.6
0.5 2 5 10 20 50 0.5 '2 5 10 20 50

J<IG~·7.Piessure and deris~tY devl~ti~n~~ot:<p,p,i)-properiies in near-crl\ical and supercritical states from our
()WIt EOS. 0: Tillner-Roth and Baeh~~, .:
. Tillner-Roth andBaehrs, e:Basu and Wilsons, 0: Dressnenind Bier12, I1: Piao et 01. 43 , ~.Weberg, I: Saturation, - - HM-EOS, - - - HE;.J;!OS,
s3
-.-.- PNS\V~EOS, ... ~~.; Tang et al. ..

J;Phys. Chem. Ref. Data, Vol. 23" No. 5, . 1994

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682 R. TILLNER·ROTH AND H. D. BAEHR

~
.,...- 2
0
0 1 o DO
ct
0
o 000
""-
ct 0
o
............",
0 CD~¢ 0
0 o
~ -1
250 275 300 325 350 375
T/k .,
FIG. 8. Density deviations of (p ,p,T)-properties reported by Baroncini et al. 4 from our own EOS. 0: 9 kglm3• 0: 20 kg/m3, 0: 40 kg/m3, ~: 56 kglm3, I!!!!: 88
kglm3•

~
~
0.8

Q..
0
0
0
0.4
0.0
• • •
""-
Q..
............",
0
-0.4 -I¢t 0
0
~ -0.8
300 350
• 400 450
.,
T/'K

FIG. 9. Density deviations of (P,p,T)-properties reported by Basu and Wilsons from our own EOS. +: 51 kglm3, 0: 156 kg/m3, 0: 261 kglm3, . : 361 kglm3,
0: 520 kglm3•

2
o
o
o 1
~ o
ct
............",
o DDDDDDDDDDDDD
o
-1
230 270 310 350 390
TIK ..
3
FIG. lO. Density deviations of (P,p,T)-properties reported by Doeringll from our own EOS. ~: 3.75 kg/m3, 0: 12.8 kg/m'\ [): 24.5 kg/m\ X: 35 kglm , .:
51 kglm , 0: 72 kglm3 , +: 93.5 kg/m3, 0: 114 kglm3, . : 156 kglm\ ~: 232 kg/m3•
3

J. Phys. Chern. Ref. Data, Vol. 23, No.5, 1994

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) 683

~
.,- 2
0 1

,
0
0
Q.. 0
<:t
"--" -1
•• [J
0

0
0
.,- -2
280 320 360 400 440
T/K ...

l 3
FIG. 11. Density deviations of (P,p,T)-properties reported by Fukushima et al. IS from our own BOS. 0: 23 kg/ml, .:28 kg/m , 0: 51 kg/m'\.: 75 kg/m , +:
109 kg/m3, 0: 152 kg/ml , iii: 218 kglm3• ~: 313_kg/m3, [I: 501 kg/m3, ~: 548 kg/m3• ~: 700 kg/m3• ~: 897 kg/m3, IJ: 968 kg/m • ~: 1100 kg/m
3 3
•

~
1 .0

•
~

0
0.5 ~

,
0
0
Q.. «I> .
Q.. 0.0
"--"
0
0
~ -0.5
200 230 260 290 320 350 380
T/K ...

FIG. 12. Density deviations of (P.p,T)-properties reported by Kesselman eta1. 27 from our own BOS. 0: <1 MPa, 0: 1-2 MPa, 0: 2-5 MPa,~: 5-10 MPa,
.: 10-20 MPa.

,--.
.,- 0.0 I I I

0
0
0
-0.1 I-

~ -0.2
o o
Q..
"--"'"
f-
e
0
0 I I
.,- -0.3 I

0.0 0.5 1 .0 1 .5 2.0

p/MPa ..
FIG. 13. Density deviations of (p ,p,T)-properties reported by Maezawa et al. 32 from our own BOS. 0: 280 K. 0: 300 K, .: 320 K, +: 340 K.

J. Phys. Chern. Ref. Data, Vol. 23, No.5, 1994

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684 R. TILLNER·ROTH AND H. D. BAEHR

0.1
o 0.0
o
o
o
~ -0.1

3o -02
.
~ -0.3
170 200 230 260 290 320 350
T/K ..
FIG. 14. Density deviations of (P,p,T)-properties reported by Magee33 from our own EOS. 0: 1130 kglm3, . : 1215 kg/m3, 0: 1225 kg/m3, . : 1280 kg/m3 , 0:
1345 kg/m3 , +: 1385 kglm3, iii: 1440 kglm3, +: 1475 kglm3, ~: 1500 ke:lm3. X: 1545 ke:/m3•

~
~
o. 1
0

,Q..
-0
0
0.0 • ~W
¢e¢
0
Q..
"--"
x
3 x
0
x
eo e 0
0
-0.1 x x x x
~

0 1 2 3 4 5 6

p/MPa ..
FIG. 15a. Density deviatioris of (P,p,T)-properties reported by Morrison and Ward38 • X: 279 K, .: 288 K, 0: 293 K, +: 298.5 K, 0: 304.5 K, .: 308 K, +:
314.5 K, *: 318 K, 0: 324 K, [I: 328 K.

~
~
0.4
0 0.2

~
0
0

0.0 •
Q..
"--" -0.2 x
0
0
~ -0.4
x
•
0 1 2 3 4 5 6

p/MPa ..
FIG. 15b. Density deviations of (P,p,T)-properties reported by Morrison and Ward 38 from our own EOS. 0: 333 K, .: :rn.5 K. '?r\.l2.5 K, .: 347.5 K, 0:
352 K, X: 357 K, +: 365 K, IJ: 367 K.

J. Phys. Chern. Ref. Data, Vol. 23, No.5, 1994

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2';'TETRAFLUOROETHANE (HFC-134A) 685

.....-... 1.0
~

0 0.5
c
0

~
••
0.0
C-..
-0.5 ~
•
~

0 0
0
-1.0
<>
~

300 350 400 450

T/K •
3 3
FIG. 16a. Density deviations of (P,p,T)-properties reported by Piao etal. 43 from our own EOS . •: 37 kg/m 3 , [I: 87 kglm3 , 0: lSI kg/m , +: 155kglm , 0:
203 kg/m3, . : 242 kglm3, ~: 273 kglm3 , 0: 380 kglm3, ~: 459 kglm3•

.....-... 1 .0
~

,c..
c
0
Q..
0.5

X
i I ~c ~
a
"---""
0
0
0.0
xxx~*+~+~+e •8 t
~ -0.5
300 350 4'00 450
T/K ..
3
FIG. 16b. Density deviations of (P,p,T)-properties reported by Piao et al. 43 from our own EOS. 0: 483 kglm3, 0: 495 kg/m 3 , 0: 508 kg/m 3 , . : 590 kglm , .:
3
691 kg/m3 , +: 780 kglm3 , +: 839 kglm3 , X: 903 kglm3 , ii: 1064 kglm , ~: 1143 k~m3 .

.....-... t
~

0 0

,
0
0
Q.. -1
Q..
o <>~
~

0
-2 ~i1 <>
0
~ -3
0.2 0.5 2 5 10 20
p/MPa ..
FIG. 17. Density deviations of (p ,p,T)-properties reported by Park
42
from our own EOS . •: 333 K, .: 348 K, +: 363 K, 0: 378 K, 0: 393 K, 0: 408 K, ~:
423 K~

J. Phys. Chern. Ref. Data, Yol. 23, No.5, 1994

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 686 sR. TILLNER·ROTH AND H. D. BAEHR

~
0.12
T-

~
0
0
0.06
0..

" 0..
.........",
0
0
0
T-

-0.06
20 50 100 200 500
p/(kg/m 3 )

FIG. 18. Pressure deviations of (P,p,T)-properties between 350 K and 400 K from our own EOS . • : Weber (Bumett-measurements)S8 , 0: Weber (isochoric
measurementsi8 , X: TiHner-Roth and Baehr4.

~
-r-- 1.0
0 0.5
0
0
ct. 0.0
"'-
ct.
.........." -0.5
0
0
-r-- -1.0
0.0 0.3 0.6 0.9 1 .2 1 .5

p/MPa ..
FIG. J 9. Density deviations of (P.p.T)-properties reported by Zhu er aJ. 63 from our own EOS . • : 283 K. 0: 293 K. 0: 303 K .•: 313 K, 0: 325 K. ~: 333 K,
X: 343 K,~: 353 K.

,-.....
-r-- 4 11
11m
0 2 11 11

CO
0
()

0
• --
"'-
en /
...................
.......... ..........
"'-"" -2 + .......... ...........
0
0
-r-- -4
. -----.
200 250 300 350 400 4~O 500

T/K ...
18
FIG. 20. Deviations of second virial coefficients from the EOS. +: Tillner-Roth and Baehr4 • 0: Dressner and Bier l2 , . : (j,)I'(\\\'lIl and Moldover , 0:
Beckermann and Kohler6 , IJ: Schramm etal. 50.49, - - HM-EOS, ---HE-EOS, -.-.- PNSW-EOS.

J. Phys. Chem. Ref. Data, Vol. 23, No.5, 1994

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) 687

T/K -
FIG. 21. Deviations of isochoric heat capacities measured by Magee33 from our own EOS. 0: Magee33 , - HM-EOS, - _ _ HE-EOS, _. _._
PNSW-EOS.

J. Phys. Chern. Ref. Data, Vol. 23, No.5, 1994

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 Gaa R. TILLNER-ROTH AND H. D. BAEHR

(3.5-4.5) MPa

0.5 MPa 5 MPa

. .. -------::-,:::...
.""

o
......o

,/ ..,-.-.-... .........
o

T/K ...
FIG. 22. Deviations of isobaric heat capacities from values calculated from our own EOS. 0: Saitoh et al. 46 , ~: Nakagawa el al. \') . e. (;lirtllcf and Emst20,
0: Wirbser , I: saturation boundary, - - HM-EOS, - - - HE-EOS, -.-.- PNSW-EOS, ...... Tang el{/I.~l.
9

J. Phys. Chern. Ref. Data, Vol. 23, No.5, 1994

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) 689

(260-280) K
o 0.1

I : :· -.:.'.:.-.-:.~~~:.-.j
I I I I I. I
o .I
~
,/
o ,~;:." .."",."".
.~:;.,...-:,...~
A A.
0.0
• • .-e.
V'.!A.,/ .
e-

-0.1 I , I I I I

(280-300) K (380-400) K

0.1 I
0.0

-0.1

0.1
0.0
I
-0.1
0.01 0.1 0.01 0.1

p/MPa ----..
FIG. 23. Deviations of speed of sound values in the gaseous phase from our own EOS. 0: Goodwin and Moldover 18 , . : Beckermann and Kohler6 , I: saturation
boundary, - HM-EOS, - - - HE-EOS, -.-.- PNSW-EOS.

J. Phvs. Chern. Ref. Data, Vol. 23, No.5, 1994

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690 R. TILLNER·ROTH AND H. D. BAEHR

(178-210) K (290-310) K

(310-330) K

_~ f___ ~9:= ~-~7~

_~ t~--~- ~~ I ~;;~~
()

o
()

(250-270) K (350-370) K

__ ~.,.."lo....._ .....

(270-290) K 380 K

o _..... ---- ...

- - - !'- - - -~ - -~ -:; ~
-1
2 5 10 20 50 100 2 5 10 20 50 100

p/MPa ..
FIG. 24. Deviations of speed of sound values in the liquid region from our own EOS.~: Takagi S2 19
,0: Guedes and Zollweg ,I: saturation boundary, -
HM-EOS, - - - HE-EOS, -.-.- PNSW-EOS.

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 THERMODYNAMIC PROPERTIESOF"1,1 ,t,2.;.TETRAFLUOROETHANE' (HFC~134A) 69.1·:

333 K

.''-''.;~.-- ......
~ 0.0 ,...--,....--- ,.
o
0.- -0.6 ~~~~~~""""""'~_..I....-_'---:-___
2 363 K " 393 K

~ :::~~~-i·i~ii;~:;}~~~:~·(t- ~';5:;-::;$1~~~1
a . - O. 6 L...-~-.L...._--l..;.._~~_.L.---"';L.",,;.;,;...---'

::t
! _:::.~~!·~:~;;~;~!!·~~.-;f·. ···~:·::·~·~:~f~.~$!B
.<> : 374K •.•. .•..• .•.. ......J . . . . . . ....• . .......... ... . 423K •. .. ....

0.2 0.5 2 5 10 200.2 0.5 1 2 5 10 20

p/MP'g),,,," ."
FIG. 25~ Deviations of Joule-Thomson coefficients from our own E()S. e:Wirbser9 ',1 : saturation boundary, l11illL±·3%-boundary, -',- HM-EOS, _ _ _
, HE':EOS, -. -. - PNSW-EOS.· " .. " ," '

0
0... 60

"
~

0
() "
30
--' --
[J
()
0
VI
,,'!+

CL
I (/)
'--3'0
-60
Ttr . ~..."",-. . .
~
,
.......... ...../
160 180 200 220
.....-... 240
~
0.2
()
/
0 /
() O. 1 /
(/)

0...

" 0
0..
(I)

............"
0.0

-0.1
0 210 240 270
~
300 330 360 390

T/K ..
FIG. 26. Deviations of selected vapor pressures from the fundamental equation of state. II: Magee and Howl ey34 , 0: Goodwin et al. 17 , e: Baehr and
Tillner-Roth , 0: Weber8 , -HM-EOS, ~-- HE-EOS, -.-.- PNSW-EOS.
ll

.t 'Phvs.Chem. Ref. Data. Vol. 23., No. 5,1994

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692 R. TILLNER-ROTH AND H. D. BAEHR

4
2
0 o
-2
4
~
~

u
0
(.)
10
5
•
+ •
(I)
CL
0 +
"'"
CL
'--'"
0
(I)

-5
0 -10
0
20
10
IJ •
4>
0
-10
-20
210 240 270 300 330 360 390
T/K ..
FIG. 27. Deviations of measured vapor pressures from the fundamental EOS not being used during the correlation process. Ii: Arita et al. 2 , +: Baroncini et al. 4,
e. Fukushima et al. IS , . : Bier et al.8 , X: Piao et al. 43 , 0: Kubota et al. 30 , . : Maezawa et al. 32,0: Magee and Howley34 , 0: Morrison and Ward38
. +: Niesen et al. 40 , 11: Nishiumi and Yokoyama41 • IJ: Basu and Wilsons , ~: Zhu et ai. 62 , ~: Doring et al. 11 •

J. Phys. Chem. Ref. Data, Vol. 23, No.5, 1994

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 THERMODYNAMIC F»,ROPERTIES" Of, 1,1 ,t~2~Tl.:T~~FLUOROE;THANE(HFC-134A) 693

"0.4. :"~~-----.......-~..........,...-~-~......-.......---~---.-~~--~
XX
O~"2
~ 0.0
"\1 ",

u -0.2 >'0
o
- 0 -0.4
~ 170 210 :2str 290 370
Q..
""-'"
o 2
o 1
o ". .-.--'~ "---- . ~
",.;

- - --
-1
----
--2
365 367 369 371 375
"'TjK' ..
FIG. 28. Deviations ofsaturatedUquiddensities from the fundamental equation of state. x; Doring et al. 11,0, 'iii, !I: Fukushimaet aJ. 15,14,16, 0: Hou et aJ. 23, +:
Yokoyama and Takahashi6 1, ~; Kabataet al. 26 , ~: Maezawa et al. 32 , ~: Kruse29 , . : Morrison and Ward38 , +: Niesen et al. 4O , 0: Piao et al. 43,
'(I; BliSu "and Wilsons t".: Tillner-RotharidBai~hr~;"-"-""HM':EOS~~":';': - HE~EOS. ",,;;,;;;';';.;::: PNSW)~OS. "

0.0 .----- .. -.-.-.

"I
",,·0
....... ...

......
~

_-"

-...;..-

~~
-~""
a0 -1.5
"~ 170 210 250 290 330 370
"-Q..
""---'" 3
o
b
-- - - . .;. ~+- - -
o .m-._._._ . --- ......... --..... . I!I
.......... . -......
-3
365 367 369 371 373 375
T/K ..
l'io. 29. Deviations of saturated vapor densities from the fundamental equation of state. O,!!!: Fukushima et al. 14,16, ~; Kabata et al. 26, .: Morrison and
Ward38 • +: Nie!ren ptaL 40, I } Wehe,.ss. HM-P.O~. HE-P.O~.-·-·-PNSW-P.OS.

J. Phys. Chern. Ret Data,Vi)t'23, No. 5;'1994

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694 R. TILLNER-ROTH AND H. D. BAEHR

liquid two-phase region

. gas

1> c~
C(2)
v : >
IU
U <l

- >
IU
<l
CV
c"v
cV'
v' v"
v ...
FIG. 30. Qualitative plot of the isochoric heat capacity on an isothenn .

.....-....
. ....... -- .
-r--
."".
."".

..-...
N
'-'" > 0
(J

"
..-...
~
'-'" >
(J
"'-'"
-1 .....
.,.--..._ . .,.. . .
.".. .""..
". ".
0
0 -2
~ 170 200 230 260 290 320

T/K •
3
FIG. 31. Deviations of two-phase isochoric heat capacities measured by Magee33 from our own EOS. The other equations of state were evaluated at 1100 kg/m
which is about in the middle of the density range covered by the experiments. - - HM-EOS, - - - HE-EOS, -.-.- PNSW-EOS.

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 THERMODYNAMIC PROPERTIES.· OF>1,1~t,2-TETRAFLUOROETHANE (HFC-134A) 695

Kabata
374.-3
E McLinden et al.

374.--1

:3.74.0 Fukl..rshima,~ et oJ. Bier et 01.

37·3.9
49-$. 50~O- --505 510- 515 520 525 530
-p/(kg/n]3)
FIa. 32. Cornpari~o~ of rneasu~~critical pararnete~ T~ and Pc with values ~aJcuJ<llcd fr0rnoufOwn EOS. The rectan~les indicate th_e uncertainty of the respective
experimental value. -

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696 R. TILLNER-ROTH AND H. D. BAEHR

8. Appendix consistency. Temperature and pressure intervals were chosen

Tables of Thermodynamic Properties in order to minimize the inaccuracy in interpolation. How-
ever, interpolation in the critical region is not recommended
All values in Tables 8 and 9 were calculated from the because of the extreme shape of the (p ,p,T)-surface.
fundamental equation of state to preserve thermodynamic

TABLE 8. Thennodynarnic properties of HFC-134a at saturation

T Ps P h s c" ---E£....-. w
K MPa kglm3 kJlkg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

169.85a 0.00039 1591.1 71.454 0.4126 0.7922 1.1838 1119.9

0.02817 334.94 1.9639 0.5029 0.5853 126.79
170 0.00040 1590.7 71.632 0.4136 0.7921 1.1838 1119.2
0.02862 335.02 1.9630 0.5033 0.5856 126.84
172 0.00049 1585.4 74.000 0.4275 0.7914 1.1840 1109.0
0.03529 336.18 1.9518 0.5080 0.5904 127.49
174 0.00061 1580.1 76.368 0.4412 0.7910 1.1844 1098.8
0.04325 337.34 1.9410 0.5126 0.5952 128.14
176 0.00075 1574.8 78.738 0.4547 0.7909 1.1851 1088.6
0.05270 338.51 1.9307 0.5173 0.6000 128.78
178 0.00092 1569.5 81.109 0.4681 0.7909 1.1860 1078.5
0.06388 339.69 1.9208 0.5220 0.6048 129.42
180 0.00113 1564.2 83.482 0.4813 0.7912 1.1871 1068.3
0.07701 340.88 1.9113 0.5267 0.6096 130.05
182 0.00137 1558.9 85.858 0.4945 0.7916 1.1884 1058.1
0.09239 342.07 1.9022 0.5313 0.6145 130.67
184 0.00165 1553.5 88.236 0.5075 .0.7923 1.1898 1048.0
0.11030 343.26 1.8935 0.5360 0.6193 -131.29
186 0.00198 1548.2 90.618 0.5203 0.7930 1.1914 1037.8
0.13106 344.47 1.8852 0.5407 0.6242 131.90
188 0.00237 1542.8 93.002 0.5331 0.7939 1.1931 1027.7
0.15503 345.68 1.8771 0.5453 0.6290 132.51
190 0.00282 1537.5 95.391 0.5457 0.7949 1.1949 1017.6
0.18259 346.89 1.8695 0.5500 0.6339 133.11
192 0.00334 1532.1 97.783 0.5582 0.7961 1.1969 1007.5
0.21416 348.12 1.8621 0.5546 0.6388 133.70
194 0.00394 1526.7 100.17 0.5707 0.7973 1.1989 997.55
0.25017 349.34. 1.8550 0.5593 0.6437 134.28
196 0.00463 1521.3 102.57 0.5830 0.7986 1.2011 987.54
0.29110 350.57 1.8483 0.5639 0.6486 134.85
198 0.00541 1515.9 104.98 0.5952 0.8000 1.2034 977.55
0.33745 351.81 1.8418 0.5685 0.6536 135.42
200 0.00631 1510.4 107.39 0.6073 0.8015 1.2057 967.60
0.38977 353.05 1.8356 0.5732 0.6586 135.98
202 0.00733 1505.0 109.80 0.6193 0.8031 1.2081 957.68
0.44864 354.30 1.8297 0.5779 0.6636 136.53
204 0.00849 1499.5 112.22 0.6312 0.8047 1.2106 947.80
0.51465 355.55 1.8240 0.5825 0.6687 137.07
206 0.00979 1494.0 114.65 0.6430 0.8063 1.2132 937.94
0.58846 356.80 1.8185 0.5872 0.6737 137.60
208 0.01126 1488.5 117.08 0.6548 0.8081 1.2159 928.12
0.67075 358.06 1.8133 0.5919 0.6789 138.l2
210 0.01'c)1 14-R~.0 1!C).51 0.6664 0.8098 1.2186 918.33
0.76222 359.32 1.8083 0.5966 0.6841 138.63
212 0.01475 1477.5 121.95 0.6780 0.8116 1.2214 908.57
0.86364 360.58 1.8036 0.6013 0.6893 139.12
214- 0.01681 1471.9 124.40 0.6894- OJW~5 1.2242 898.84
0.97578 361.84 1.7990 0.6060 0.6946 139.61
216 0.01909 1466.3 126.85 0.7008 0.8154 1.2271 889.15
1.0994 363.11 1.7946 0.6108 0.7000 140.09
218 0.02163 1'160.8 129.31 0.7122 0.8173 1.2301 R7C).48
1.2355 364.38 1.7905 0;6155 0.7054 140.55
220 0.02443 1455.1 131.77 0.7234 0.8193 1.2331 869.85
1.3850 365.65 1.7865 0.6203 0.7109 141.00

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 THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (HFC-134A) 697

TABLE 8. Thermodynamic properties of HFC-134a at saturation - Continued

T Ps P h s Cu
~ w
K MPa kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

222 0.02753 1449.5 134.25 0.7346 0.8212 1.2362 860.24

1.5486 366.92 1.7826 0.6251 0.7164 141.44
224 0.03094 1443.9 136.72 0.7457 0.8233 1.2394 850.67
1.7275 368.19 1.7790 0.6300 0.7221 141.86
226 0.03469 1438.2 139.21 0.7567 0.8253 1.2426 841.12
1.9227 369.46 1.7755 0.6348 0.7278 142.27
228 0.03879 1432.5 141.70 0.7677 0.8274 1.2459 831.60
2.1351 370.73 1.7722 0.6398 0.7336 142.67
230 0.04329 1426.7 144.19 0.7785 0.8295 1.2492 822.10
2.3659 372.00 1.7690 0.6447 0.7395 143.05
232 0.04819 1421.0 146.70 0.7894 0.8316 1.2526 812.63
2.6162 373.27 1.7660 0.6497 0.7455 143.42
234 0.05354 1415.2 149.21 0.8001 0.8337 1.2561 803.19
2.8872 374.54 1.7631 0.6547 0.7516 143.77
236 0.05935 1409.4 151.72 0.8108 0.8359 1.2596 793.77
3.1801 375.80 1.7603 0.6597 0.7578 144.11
238 0.06565 1403.5 154.25 0.8215 0.8380 1.2632 784.37
3.4962 - 377.07 1.7577 0.6648 0.7641 144.43
240 0.07248 1397.7 156.78 0.8320 0.8402 1.2669 774.99
3.8367 378.33 1.7552 0.6699 0.7705 144.73
242 0.07987 1391.8 159.32 0.8426 0.8424 1.2706 765.63
4.2030 379.59 1.7528 0.6751 0.7770 145.02
244 0.08784 1385.8 161.87 0.8530 0.8447 1.2745 756.29
4.5965 380.85 1.7505 0.6803 0.7837 145.28
246 0.09643 1379.9 164.43 0.8634 0.8469 1.2784 746.97
5.0185 382.10 1.7483 0.6855 0.7904 145.53
b
246.78 0.10000 1377.5 165.44 0.8675 0.8478 1.2799 743.30
5.1932 382.59 1.7474 0.6876 0.7931 145.63
248 0.10568 1373.8 166.99 0.8738 0.8492 1.2824 737.67
5.4707 383.35 1.7462 0.6908 0.7973 145.77
250 0.11561 1367.8 169.56 0.8841 0.8514 1.2864 728.38
5.9545 384.60 1.7442 0.6961 0.8044 145.98
252 0.12627 1361.7 172.14 0.8943 0.8537 1.2906 719.11
6.4715 385.84 1.7423 0.7015 0.8116 146.11
254 0.13768 1355.6 174.73 0.9045 0.8560 1.2948 709.85
7.0233 387.07 1.7405 0.7069 0.8189 146.35
256 0.14989 1349.5 177.33 0.9147 0.8584 1.2992 700.60
1.6117 388.31 1.1388 0.7123 0.8263 146.50
258 0.16293 1343.2 179.94 0.9248 0.8607 1.3036 691.36
8.2384 389.53 1.7372 0.7178 0.8340 146.63
260 0.17684 1337.0 182.55 0.9348 0.8631 1.3081 682.14
8.9051 390.15 1.1356 0.1234 0.8411 146.1~
262 0.19166 1330.7 185.18 0.9449 0.8655 1.3128 672.92
9.6138 391.97 1.7341 0.7289 0.8497 146.84
264 0.20742 1324.4 187.81 0.9548 0.8679 1.3176 663.71
10.366 393.17 1.1327 0.7346 0.8578 146.91
266 0.22418 1318.0 190.46 0.9648 0.8703 1.3224 654.51
11.165 394.37 1.7314 0.7402 0.8660 146.95
268 0.24197 1311.6 193.11 0.9747 0.8727 1.3275 645.31
12.011 395.56 1.7301 0.7459 0.8745 146.!:IH
270 0.26082 1305.1 195.78 0.9845 0.8752 1.3326 636.12
12.908 396.75 1.7289 0.7517 0.8832 146.98
272 0.28080 1298.5 198.45 0.9943 0.8776 1.3379 626.93
13.857 397.93 1.7277 0.7574 0.8920 146.!:I6
274 0.30193 1291.9 201.14 1.0041 0.8801 1.3433 617.74
14.861 399.09 1.7266 0.7633 0.9011 146.91
276 0.32426 1285.3 203.84 1.0139 0.8826 1.3489 608.55
15.923 400.25 1.7255 0.7691 0.9103 146JS4
278 0.34784 1278.5 206.54 1.0236 0.8851 1.3547 599.36
17.044 401.40 1.7245 0.7750 0.9198 146.74
280 0.37271 1271.7 209.26 1.0332 0.8877 1.3606 590.17
18.227 402.54 1.7235 0.7809 0.9296 146.62
282 0.39892 1264.9 212.00 1.0429 0.8902 1.3667 580.98
19.476 403.67 1.7226 0.7869 0.9396 146.47

J. Phvs. Chem. Ref. Data. Vol. 23, No.5, 1994

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698 R. TILLNER-ROTH AND H. D. BAEHR

TABLE 8. Thennodynamic properties of HFC-134a at saturation Continued

T -P..L. ~ w
K MPa kJ/(kgK) mls

284 0.42651 1258.0 214.74 1.0525 0.8928 1.3730 571.78

20.794 404.79 1.7217 0.7929 0.9498 146.30
286 0.45553 1251.0 217.50 1.0621 0.8954 1.3796 562.57
22.182 405.89 1.7208 0.7990 0.9603 146.10
288 0.48603 1243.9 220.27 1.0717 0.8981 1.3863 553.36
23.645 406.99 1.7200 0.8051 0.9712 145.87
290 0.51805 1236.7 223.05 1.0812 0.9007 1.3933 544.14
25.186 408.07 1.7192 0.8112 0.9823 145.61
292 0.55165 1229.5 225.85 1.0907 0.9034 1.4005 534.91
26.808 409.14 1.7184 0.8174 0.9938 145.32
294 0.58688 1222.2 228.66 1.1002 0.9061 1.4080 525.68
28.516 410.19 1.7177 0.8236 1.0057 145.01
296 0.62378 1214.7 231.49 1.1097 0.9088 1.4158 516.42
30.313 411.23 1.7169 0.8299 1.0180 144.66
298 0.66241 1207.2 234.33 1.1192 0.9116 1.4239 507.16
32.204 412.25 1.7162 0.8362 1.0306 144.28
300 0.70282 1199.6 237.18 1.1286 0.9144 1.4324 497.88
34.192- 413.26 1.7155 0.8426 1.0438 143.87
302 0.74506 1191.9 240.06 1.1380 0.9172 1.4412 488.59
36.284 414.25 1.7148 0.8490 1.0574 143.43
304 0.78918 1184.1 242.95 1.1475 0.9201 1.4504 479.28
38.483 415.22 1.7142 OJ~554 1.0715 142.95
306 0.83524 1176.1 245.86 1.1569 0.9230 1.4600 469.95
40.796 416.18 1.7135 0.8620 1.0862 142.44
308 0.88330 1168.1 248.78 1.1663 0.9259 1.4701 460.60
43.228 417.11 1.7128 0.8685 1.1016 141.90
310 0.93340 1159.9 251.73 1.1756 0.9288 1.4806 451.23
45.785 418.03 1.7121 0.8751 1.1176 141.32
312 0.98560 1151.5 254.69 1.1850 0.9318 1.4917 441.83
48.475 418.92 1.7114 O.RRIR 1.1344 140.70
314 1.0399 1143.1 257.68 1.1944 0.9349 1.5034 432.42
51.305 419.79 1.7107 0.8886 1.1521 140.05
316 1.0965 1134.5 260.68 1.2038 0.9380 1.5157 422.97
54.282 420.63 1.7100 0.8954 1.1706 139.36
318 1.1554 1125.7 263.71 1.2132 0.9411 1.5288 413.50
57.415 421.45 1.7092 0.9023 1.1902 138.62
320 1.2166 1116.7 266.76 1.2226 0.9443 1.5426 403.99
nO.714 422.25 1.7085 0.9093 1.2108 137.85
322 1.2802 1107.6 269.84 1.2320 0.9475 1.5572 394.45
64.189 423.01 1.7077 0.9163 1.2328 137.03
324 1.3462 1098.3 272.94 1.2414 0.9508 1.5729 384.88
67.851 423.74 1.7068 0.9235 1.2561 136.18
326 1.4148 1088.7 276.07 1.2508 0.9542 1.5896 375.26
71.713 424.44 1.7060 0.9307 1.2811 135.27
328 1.4860 1079.0 279.23 1.2603 0.9576 1.6074 365.60
75.789 425.10 1.7050 0.9381 1.3078 134.32
330 1.5599 1069.0 282.41 1.2698 0.9611 1.6267 355.89
80.093 425.72 1.7041 0.9456 1.3366 133.32
332 1.6364 1058.8 285.63 1.2793 0.9647 1.6474 346.13
81\.61\1\ 426.31 1.7030 0.9532 1.3677 132.28
334 1.7158 1048.3 288.89 1.2888 0.9684 1.6699 336.30
89.459 426.85 1.7019 0.9609 1.4015 131.18
336 1.7981 1037.5 292.18 1.2984 0.9722 1.6944 326.41
94.563 427.34 1.7007 0.9688 1.4384 130.03
338 1.8833 1026.4 295.51 1.3081 0.9761 1.7212 316.43
99.978 427.78 1.6994 0.9769 1.4789 128.83
340 1.9715 1015.0 298.88 1.3177 0.9801 1.7507 30636
lOS.73 428.17 1.6980 0.9851 1.5237 127.56
342 2.0628 1003.2 302.29 1.3275 0.9843 1.7834 296.19
111.86 428.49 1.6965 0.9936 1.5736 126.24
344 2.1574 990.99 305.76 1.3373 0.9888 1.8199 285.89
118.40 428.74 1.6948 1.0023 1.6296 124.86
346 2.2552 978.30 309.27 1.3472 0.9934 1.8610 275.45
125.40 428.92 1.6930 1.0112 1.6930 123.42

J. PhV8. Chem. Ref. Data. Vol. 23. No.5. 1994

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 THERMODYNAMIC PROPERTIES OF 1,:1,1,2~TETRAFLUOROETHANE (HFC·134A) 699
TABLE 8. Thennodynamic properties of HFC,~134aat satura~ion - Continued

T .J!i... ~ w
K MPa kJ/(kgK) mls

348 965.10 312.85 l-,3572 0~9984 ' 1;9077 264.85' ,

13~2.9.0 429.02 1.6911' 1~0205 1.7655 121.91
350 2.4610 951.31 316.49 1.3674 1.0036 1.9613 254.05
140.99 429.02 1.6889 1.0300 1.8493 120.33
352 2.5693 936.88 320.21 ,1.3776 ' 1.0094 2~0239 243.03
14932 428~92 :' L68~5 1.0400 1.9476 IJ8~67:'
354 2.6812 921.68, 324;01 1:3880 1.0156 ' 2.0978 " 23L76~-
159.20 428.70 1.6838 1.0504 2.0645 116.94
356 2.7969 905.61 327.91 1.3987 1.0225 2.1870 220.20
169.56- 4~8;33: 1.6808 L0614 2.2063 115i13:,
358 ,,888.49 331.91 L4095 1.0302 2.297.1 ' 20831'
i80.95 427.80 1;6774 1.0730 2;3822 113023
360 3.0404 870.11 336.05 1.4207 1.0389 2.4367 196.04
193.58 427.07 1.6735 1.0853 2.6063 111.24
362 3.1685 850.16 340.36 1.4322 1.0490 ,2.6206 lS3.36
207:75 426JO' , ",1~6690 1.0986 2~902~ rQ9.15
'364 3.3010 828.21, 344;87 1.4442 1.0608 " 2;8751 170;21
223.89 424.82 1.6638 1.1131 3.3131 106.94
366 3.4382 803.56 349.65 1.4568 1.0749 3.2526 156.54
242.67 4~3 .• 4 1.6576 1.1291 3.9212 104.60
368 35803 . 775,05 ; 354.83:,'; 1.4704 1.0923 3.8750 142.26
265j4' 420.87' };6499 1.1474 .:4.9182 102;10,
370 3.7278 740.31 '360~64 1.4856 Ll145 5;1048 127.23
293.89 417.68 1.6398 1.1690 6.8621 99.370
372 3.8811 693.10 367.71 1.5041 1.1459 8.7028 111;10
334.83 412.67 1.6250 1.1965 12.375 96.219
374 4.0416 587.91 380.85 1.5387 , :1.2120 101.66 92.401
,434.05 .399;50 ,'1.5885' 1.2409 137.23 9L389
374.21C 4.0593 511.95 389.63 1.5620
511.95 389~63 ,.1,,5620

IIJ:'riple point.,
bNormal boilfng: poi,nt.-
(Critical pOint.

J.Phvs. Chem~ Ref. Data. Vol. 23.N(). 5. 1994

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 .....
TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region o
o
T p h s Cv
----EL- w T p h s Cv
---EE- w
K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mi.; K kg/m3 kJ/kg kJ/(kgK) kJ/(1:gK) kJ/(kgK) mls

0.01 MPa 0.02 MPa

170 1590.7 71.636 0.4136 0.7921 1.1838 1119.2 170 1590.7 71.641 0.4136 0.7921 1.1838 1119.2
175 1577.5 Ti.557 0.4479 0.7909 1.1847 1093.8 175 1577.5 77.562 0.4479 0.7909 1.1847 1093.8
180 1564.2 83.486 0.4813 0.7912 1.1871 1068.3 180 1564.2 83.491 0.4813 0.7912 1.1871 1068.3
185 1550.9 89.430 0.5139 0.7926 1.1906 1042.9 185 1550.9 89.435 0.5139 0.7926 1.1905 1043.0
190 1537.5 95.394 0.5457 0.7949 1.1949 1017.6 190 1537.5 95.398 0.5457 0.7950 1.1949 1017.7
195 1524.0 101.38 0.5768 0.7980 1.2000 992.56 195 1524.0 101.38 0.5768 0.7980 ].2000 992.61
200 1510.4 107.39 0.6073 0.8015 1.2057 967.62 200 1510.4 107.40 0.6073 0.8015 1.2057 967.67
205 1496.8 113.43 0.6371 0.8055 1.2119 942.87 205 1496.8 113.44 0.6371 0.8055 1.2119 942.92
206.29 1493.2 115.00 0.6448 0.8066 1.2136 936.50 210 1483.0 119.52 0.6664 0.8098 1.2186 918.36
206.29
210
0.60000
0.58902
356.99
359.49
1.8177
1.8298
0.5879
0.5937
0.6745
0.6797
137.67
138.86
215
216.74
1469.1
1464.3
125.63
'127.76
0.6952
0.7050
0.8144
0.8161
1.2256
1.2282
894.00
885.57
:u
-t
215
220
0.57487
0.56142
362.91
366.37
1.8459
1.8618
0.6020
0.6107
0.6874
0.6956
140.42
141.97
216.74
220
1.1483
1.1303
363.58
365.87
1.7931
1.8036
0.6125
0.6171
0.7019
0.7058
140.26
141.30 .-r=
Z
225 0.54863 369.87 1.8775 0.6196 0.7041 143.49 225 1.1038 369.42 1.8195 0.6247 0.7125 142.88 m
230 0.53643 373.41 1.8931 0.6287 0.7128 144.99 230 1.0787 373.00 1.8352 0.6329 0.7199 144.42 ::D
I
235 0.52478 377.00 1.9085 0.6378 0.7217 146.47 235 1.0548 376.62 1.8508 0.6413 0.7278 145.94 ::D
240 0.51364 380.63 1.9238 0.6470 0.7307 147.94 240 1.0320 380.28 1.8662 0.6500 0.7360 147.44
~
245 0.50298 384.31 1.9390 0.6563 0.7397 149.38 245 1.0102 383.98 1.8815 0.6588 0.7444 148.92 :J:
250 0.49277 388.03 1.9540 0.6655 0.7488 150.81 250 0.98939 387.72 1.8966 0.6677 0.7529 150.38 »
Z
255 0.48297 391.79 1.9689 0.6747 0.7579 152.22 255 0.96944 391.51 1.9 II 6 0.6767 0.7615 151.82
260 0.7702 153.24
C
0.47356 395.61 1.9837 0.6839 0.7669 153.62 260 0.95030 395.34 1.9265 0.6S56
265 0.46452 399.46 1.9984 0.6931 0.776J 155.00 265 0.93194 399.21 1.9412 0.6946 0.7789 154.64 ;t:
270 0.45582 403.37 2.0130 0.7022 0.785:> 156.37 270 0.91429 403.13 1.9559 0.7036 0.7877 156.03 P
275 0.44744 407.31 2.0275 0.7113 0.7940 157.73 275 0.89732 407.09 1;9704 0.7125 0.7964 157.41 OJ
280 0.43938 411.31 2.0419 0.7203 0.8029 159.07 280 0.88098 411.09 1.9848 0.7214 0.8052 158.77 »
m
285 0.43160 415.34 2.0562 0.7293 0.8118 160.40 285 0.86525 415.14 1.9992 0.7303 0.8139 160.11
J:
290 0.42410 419.43 2.0704 0.7382 0.8207 161.72 290 0.85008 419.23 2.0134 0.7392 0.8226 161.45 ::D
295 0.41685 423.55 2.0845 0.7471 0.8295 163.03 295 0.83544 423.37 2.0275 0.7480 0.8313 162.77
300 0.40985 427.72 2.0985 0.7560 0.8383 164.32 300 0.82131 427.55 2.0416 0.7567 0.8399 164.08
305 0.40309 431.93 2.1124 0.7647 0.8470 165.61 305 OJ~)766 431.77 2.0555 0.7655 0.8486 165.37
310 0.39654 436.19 2.1263 0.7735 0.8557 166.88 310 0.79447 436.03 2.0694 0.7742 0.8572 166.66
315 0.39021 4W.49 2.1400 0.7822 0.8644 168.14 315 0.78170 440.34 2.0832 0.7S28 0.8657 167.93
320 0.38408 444.84 2.1537 0.7908 0.8730 169.40 320 0.76935 444.69 2.0969 0.7914 0.8742 169.19
325 0.37814 449.22 2.1673 0.7994 0.8816 170.64 325 0.75738 449.08 2.1105 0.8(00 0.8827 170.44
330 0.37238 453.65 2.1808 0.8080 0.8901 171.87 330 0.74579 453.52 2.1241 0.8085 0.8912 171.69
335 0.36680 458.12 2.1943 0.8165 0.8986 173.09 335 0.73455 457.99 2.1375 0.8170 0.8996 172.92
340 0.36138 462.64 2.2077 0.8250 0.9070 174.31 340 0.72365 462.51 2.1509 0.8254 0.9080 174.14
345 0.35612 467.19 2.2210 0.8334 0.9154 175.51 345 0.71307 467.07 2.1642 0.8338 0.9163 175.35
350 0.35101 471.79 2.2342 0.8418 0.9238 176.71 350 0.70280 471.68 2.1775 0.8422 0.9246 176.56
355 0.34605 476.43 2.2474 0.8-501 0.9321 177.90 355 0.69282 476.32 2.1906 0.8505 0.9329 177.75
360 0.34122 481.11 2.2604 0.8584 0.9404 179.08 360 0.68313 481.01 2.2037 0.8588 0.9411 178.94
365 0.33653 485.84 2.2735 0.8667 0.9486 180.25 365 0.67371 485.73 2.2168 0.8670 0.9493 180.11
370 0.33197 490.60 2.2864 0.8749 0.9568 131.41 370 0.66454 490.50 2.2298 0.8/52 0.9575 181.28

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 TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region - Continued
----- ---

T P h s w T p h s Cv ~
w
Cv ~
K kg/m3 kJ/kg U/(kgK) kJ/(kgK) kJ/(kgK) rnIs K kg/m3 kJ/kg kJ/(kgK) kJ/(lgK) _ kJ/(kgK) rnIs

0.01 MPa 0.02 MPa -I

~
375 0.32753 495.40 2.2993 0.8831 0.9649 182.57 375 0.65562 495.31 2.2427 0.8834 0.9656 182.44 m
::D
380 0.32320 500.25 2.3122 0.8912 0.9731 183.72 380 0.64694 500.16 2.2555 0.8915 0.9737 183.60 3:
385 0.31899 505.13 2.3249 0.8993 0.9811 184.86 385 0.63849 505.04 2.2683 0.8996 0.9817 184.74 o
390 0.31489 510.06 2.3377 0.9074 0.9892 185.99 390 0.63026 509.97 2.2810 0.9076 0.9898 185.88 c
395 0.31090 515.03 2.3503 0.9154 0.9972 187.12 395 0.62224 514.94 2.2937 0.9156 0.9977 187.01
-<
z
400 0.30700 520.03 2.3629 0.9234 1.0052 188.23 400 0.61442 519.95 2.3063 0.9236 1.0057 188.13 »
410 0.29949 530.17 2.3879 0.9393 1.0210 190.45 410 0.5~936 530.09 2.3313 0.9394 1.0215 190.36 3:
(;
420 0.29235 540.45 2.4127 0.9550 1.0367 192.64 420 0.5~503 540.38 2.3561 0.9551 1.0371 192.55
0.9707 1.0527 194.72 "tJ
430 0.28554 550.90 2.4373 0.9706 1.0523 194.80 430 0.57137 550.83 2.3807 ::D
440 0.27903 561.50 2.4617 0.9860 1.0677 196.94 440 0.55834 561.44 2.4051 0.9862 1.0681 196.87 o
"tJ
450 0.27282 572.26 2.4858 ,1.0014 1.0831 199.06 450 0.54589 ' 572.19 2.4292 1.0015 1.0834 198.99
460 0.26688 583.16 2.5098 1.0166 1.0982 201.15 ·460 0.53398 583.10 2.4532 1.0167 1.0985 201.09
m
::D
-I
iii
en
0.03 MPa 0.04 MPa
o
."
....
170 1590.7 71.645 0.4136 0.7921 1.183g 1119.3 170 1590.7 71.650 0.4136 0.7921 l.l837 1119.3 :...
175 1577.5 77.566 0.4479 0.7909 1.1847 1093.8 175 1577.5 77.571 0.4479 0.7909 1.1847 1093.9 :...
180
185
1564.2
1550.9
83.495
89.439
0.4813
0.5139
0.7912
0.7926
1.1871
1.1905
1068.4
1043.0
180
185
1564.2
1550.9
83.500
89.443
0.4813
0.5139
0.7912
0.7926
1.1870
1.1905
1068.4
1043.0
~
190 1537.5 95.402 0.5457 0.7950 1.194~ 1017.7 190 1537.5 95.407 0.5457 0.7950 1.1949 1017.8 ~
::D
195 1524.0 101.39 0.5768 0.7980 1.2000 992.65 195 1524.0 101.39 0.5768 0.7980 1.2000 992.69 »
."
200 1510.5 107.40 0.6073 0.8015 1.2057 967.71 200 1510.5 107.40 0.6072 0.8015 1.2057 967.76
r-
205 1496.8 113.44 0.6371 0.8055 1.2119 .942.96 205 1496.8 113.45 0.6371 0.8055 1.2119 943.01 c:
210 1483.0 119.52 0.6664 0.8098 1.2185 918.41 210 1483.1 119.52 0.6664 0.8098 1.2185 918.46 o
~ 215 1469.2 125.63 0.6951 0.8144 1.2256 894.05 215 1469.2 125.63 0.6951 0.8144 1.2256 894.10 ::D
"U o
::r 220 1455.2 131.78 0.7234 0.8193 1.2331 869.88 220 1455.2 131.78 0.7234 0.8193 1.2331 869.93 m
-I
~ 223.46 1445.4 136.06 0.7427 0.8227 1.2385 853.21 225 1441.0 137.97 0.7512 0.8243 1.2410 845.93
::J:
o
::r
223.46 1.6784 367.85 1.7800 0.6287 0.7205 141.75 228.55 1430.9 142.39 0.7707 0.8279 1.2468 828.96 »
Z
CD 225 1.6660 368.95 1.7849 0.6306 0.7220 142.25 228.55 2.1!)72 371.08 1.7713 0.6411 0.7352 142.78
? 230 1.6272 372.58 1.8008 0.6375 0.7277 143.84 230 2.1~21 372.14 1.7759 0.6428 0.7364 143.25
m
:II 235 1.5903 376.23 1.8165 0.6451 0.7343 145.40 235 2.1315 375.84 1.7918 0.6493 0.7413 144.86 %
~ 240 1.5552 379.92 1.8321 0.6532 0.7415 146.94 240 2.0~35 379.56 1.8075 0.6565 0.7474 146.43
."
C
245 1.5218 383.65 1.8474 0.6615 0.7492 148.45 245 2.0380 383.31 1.8230 0.6M3 0.7542 147.98 9....
~ 250 1.4899 387.41 1.8627 0.6700 0.7571 149.94 250 1.9946 387.10 1.8383 0.6/24 0.7615 149.50 ~
.c:.
< 255 1.4594 391.22 1.8777 0.6787 0.7653 151.40 255 1~9532 390.93 1.8534 0.6807 0.7691 150.99 .!:
~ 260 1.4303 395.07 1.8927 0.6874 0.7736 152.85 260 1.9136 394.80 1.8684 0.6892 0.7770 152.46
I\)
? 265 1.4023 398.96 1.9075 0.6962 0.7821 154.28 265 1.8757 398.70 1.8833 0,6977 0.7851 153.91
z 270 1.3754 402.89 1.9222 0.7050 0.7904 155.69 270 1.8393 402.65 1.8981 0.7C64 0.7932 155.34
~
275 1.3496 406.86 1.9368 0.7138 0.798~ 157.08 275 1.8D45 406.63 1.9127 0.7150 0.8015 156.76
$1'
....co 280 1.3248 410.88 1.9512 0.7226 0.8075 158.46 280 1.7710 410.66 1.9272 0.7237 0.8098 158.15
--..
co 285 1.3009 414.94 1.9656 0.7313 0.8160 159.82 285 1.7388 414.73 1.9416 0.7324 0.8181 159.53 o....
0Iloo

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 ~
9. Thennodynamic properties of HFC-134a in the single-phase region - Continued
TABLE
2
T p h s w T p h s ~
w
Cv
~ Cv
K kglm 3 kJ:kg kJ/(kgK) kJ/(kgK) kJ/(kgK) m1s K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) m1S

0.03 MPa 0.04 MPa

290 1.2779 419.04 1.9799 0.7401 0.8245 161.17 290 1.7078 418.84 1.9559 0.7411 0.8265 160.90
295 1.2558 423.18 1.9940 0.7488 0.8331 162.51 295 1.6179 423.00 1.9701 0.7497 0.8349 162.24
300 1.2344 427.37 2.0081 0.7575 0.8416 163.83 300 1.6491 427.19 1.9842 0.7583 0.8433 163.58
305 1.2137 431.60 2.0221 0.7662 0.8501 165.14 305 1.6213 431.43 1.9982 0.7669 0.8517 164.90
310 1.1937 435.37 2.0360 0.7148 0.8586 166.43 310 1.5945 435.71 2.0122 0.7755 0.8601 166.21
315 1.1744 440.[9 2.0498 0.7834 0.8671 167.72 315 1.5685 440.03 2.0260 0.7841 0.8684 167.50
320 1.1558 444.54 2.0635 0.7920 0.8755 168.99 320 1.5434 444.40 2.0397 0.7926 0.8768 168.78
325 1.1317 448.94 2.0772 0.8005 0.8839 170.25 325 1.5192 448.80 2.0534 0.8011 0.8851 170.05
330 1.1202 453.38 2.0907 0.8090 0.8923 171.50 330 1.4957 453.25 2.0670 0.8095 0.8934 171.31
335 1.1032 457.86 2.1042 0.8175 0.9006 172.74 335 1.4729 ,457.73 2.0805 0.8179 0.9017 172.56 ;0
340 1.0868 462.39 2.1176 0.8259 0.9090 173.97 340 1.4509 462.26 2.0939 0.8263 0.9099 173.80 -f
345
350
1.0708
1.0553
466.95
471.56
2.1309 0.8342 0.9172 175.19
176.40
345 1.4295 466.83 2.1072
2.1205
0.8346
0.8429
0.9182
0.9264
175.03
176.24
r=
r
2.1442 0.8426 0.9255 350 1.4087 471.45
Z
355 1.0403 476.21 2.1574 0.8509 0.9337 177.60 355 1.3886 476.10 2.1337 0.8512 0.9345 177.45 m
360 1.0257 480.90 2.1705 0.8591 0.9419 178.79 360 1.3690 480.79 2.1468 0.8594 0.9427 178.65 ::D
365 1.0115 485.63 2.1835 0.8673 0.9500 179.98 365 1.3500 485.53 2.1599 0.8676 0.9508 179.84 :D
370 0.99772 490.40 2.1965 0.8755 0.9582 18i.15 370 1.3315 490.30 2.1729 0.8758 0.9589 181.02 o
-I
375 0.98429 495.21 2.2094 0.8836 0.9663 182.32 375 1.3135 495.11 2.1858 0.8839 0.9669 182.19 J:
380 0.97122 500.06 2.2223 0.8917 0.9743 183.48 380 1.2960 499.97 2.1987 0.8920 0.9749 183.35 »
Z
385 0.95850 504.95 2.2351 0.8998 0.9823 184.62 385 1.2790 504.86 2.2115 0.9001 0.9829 184.51
0.9903 185.77 1.2624 509.80 2.2242 0.9081 0.9909 185.66
C
390 0.94610 509.89 2.2478 0.9078 390
395 0.93403 514.36 2.2605 0.9158 0.9983 186.90 395 1.2462 514.77 2.2369 0.9161 0.9988 186.79 ;z:
400 0.92227 519.87 2.2731 0.9238 1.0062 188.03 400 1.2305 519.79 2.2495 0.9240 1.0067 187.93 !='
410 0.89961 530.01 2.2981 0.9396 1.0219 190.26 410 1.2002 529.93 2.2745 0.9398 1.0224 190.17 m
420 0.87805 540.31 2.3229 0.9553 1.0376 192.46 420 1.1714 540.24 2.2994 0.9555 1.0380 192.38 »
m
430 0.85751 550.76 2.3475 0.9709 1.0531 194.64 430 1.1439 550.69 2.3240 0.9710 1.0535 194.56
J:
440 0.83791 561.37 2.3719 0.9863 1.0684 196.79 440 Ll177 561.31 2.3484 0.9864 1.0688 196.72 ::D
450 0.81919 572.t3 2.3961 1.0016 1.0837 198.92 450 1.0927 572.07 2.3726 1.0017 1.0840 198.85
460 0.80130 583.05 2.4201 1.0168 1.0988 201.02 460 1.0688 582.99 2.3966 1.0169 1.0991 200.96

0.06 MPa 0.08 MPa

[70 1590.7 71.659 0.4136 0.7921 1.1837 lt19.4 170 1590.8 71.668 0.4135 0.7921 l.l837 1119.4
[75 1577.5 77.580 0.4479 0.7909 1.1847 1094.0 175 1517.5 17.589 0.4479 0.7909 l.l847 1094.0
[80 1564.3 83.509 0.4813 0.7912 1.1870 1068.5 180 1564.3 83.517 0.4813 0.7912 l.l870 1068.6
185 1550.9 89.452 0.5139 0.7926 1.1905 1043.1 185 1551.0 89.461 0.5138 0.7926 1.1905 1043.2
190 1537.5 95.416 0.5457 0.7950 1.1949 1011.8 190 1537.6 95.424 0.5456 0.7950 l.l948 1017.9
195 1524.1 10 lAO 0.5768 0.7980 1.2000 992.78 195 1524.1 101.41 0.5767 0.7980 1.1999 992.87
200 1510.5 107.41 0.6072 0.8015 1.2056 967.85 200 1510.5 ·107.42 0.6072 0.8015 1.2056 967.94
205 1496.8 113.46 0.6371 0.8055 1.2118 943.10 205 1496.9 113.46 0.6370 0.8055 1.2118 943.20
210 1483.1 119.53 0.6663 0.8098 1.2185 918.56 210 1483.1 lt9.54 0.6663 0.8098 1.2185 918.66
215 1469.2 125.64 0.6951 0.8144 1.2256 894.21 215 1469.3 125.65 0.6951 0.8144 1.2256 894.31
220 1455.2 131.79 0.7234 0.8193 1.2331 870.04 220 1455.3 131.80 0.7233 0.8193 1.2330 870.14

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 TABLE 9. ThennOdynRI11ic properties otH,FC'-134a 1Ii)he single~phase, r~~iqn. Continued

T p h s __
Cv_ ~ w T h s ~ ~L·
K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgJ(), mls K kim 3 , kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

0.06 MPa 0~08 Mrs

-I
:t:
225 1441.1 137.~7 0.7512 0.8243 1.2409 846.04 225 1441.1 137.98 0.7511 0.8243 1.2409 846.15 m
230 1426;8 144.20 0~7785 0.8295 1.2492 822.20 2,30 1426.8 144~21 0.7785 0.8295 1.~491 822.31 :D
3:
235 1412.3 150.47 0.8055 0.8348 1.2578 798.50 235 1412.3 150.47 0.8055 0.8348 1.2578 798.62
o
236.-21 1408.8 152.00 0.8120 0.8361 1.2600 792.75 240 1397.7 156.79. 0.8320 0.8402 ].2669 775.04 c
236.21 3.2130 375.94 1.7600 0.6603 0.7584 144.14 242.03 1391;7 159.37 0.8427 0.8425 1.2767 765.47 -<
z
240 3;1560 378.81 1.7721 0.6642 0.7608 145.39 242.03 4.2®6 379.6} 1.7527 0.6752 0.7771 145.02 »
245 3.0844 382.63 1.7878 0.6705 0.7653 147.01 245 4.1507 381.92 1.7622 0;6778 0.7782 146.02 3C
250 3.0165 386~47 1.8033 0.6775 0.1709 148.60 250 4.0560 385.82 1.7779 0.6~33 0.7815 ]47.68 5
255 2.9519 390.34 1.8187 0.6851 0.7'773 150.15 255 3.9564 389.74 1.7935 0.6898 0.7863 149.29 ."
260 2.8904 394.24 1.8338 0.6929 0.7842 151.67 260 3.8g14 393.68 1.8'088 0.6969 0.7919 150.87 :D
265 2.8317 398.18 1.8488 0.7010 0.7915 153.17 265 3.8006 397.66 1.8'239 0.7045 0.7983 1,5~.42
o
270
215
2.1'756
2.7219
402.16
406.17
1.8637
1.8784-
0.7093
0.7176
0.7990
0.8067
154.65
156.10
270
275
3.7234
3.64,98
,401.67
4()5.71
1.8389
1.8537
0.7123
0.7203
0.8050
0.8121
153.94
155,43
"....m
:D
280 2.6703 410.23 1.8930 0.7260 0.8145 157.53 280 3.5793 409.79 1.8684 0.7284 0.8195 156.90 iii
285 2.6209 414.32 1.9075 0.7345 O.~225 158.94 285 3.5117 413.90 1.8830 0.7366 0.8270 158.35 tn
290 2.5733 418.45 1.9219 0.7430 0.8305 160.34 290 3.44:69 418.06 1.8975 0.1449 0.8346 159.78 o
."
295 2.5276 422.63 1.9362 0.7515 0,.8386 161.72 295 , 3.3M7 422.25 1.9118 0:7532 0..8424 16J.l~8 .....
300 2.4836 426.84 1.9503 0.7599 0.8467 163.08 300 , 3.3248 426.48 1.9260 0.7616 0.8502 162.57 :...
305 2.4411 431.09 1.9644 0.7684 0.8548 164.42 305 3.2672 430.15 1.9401 0.7699 0.858J 163.9.4 :...
310 2.4002 435.39 1.97~4 0.7769 0.8630 165.75 3io 3.2117 435.06 1.9542 0.7783 0.8660 165.30 'k»'
315 23607 439.72 1'.9922 0.7853 0.8712 167.07 315 3.1581 439.41 1.9681 0·786(i 0.8739 166:64 .!f
m
320 , 2.3225 444.10 2.0060 0.7938 0:8793 168.37 320 3.1065 443.80: 1.9819 0.7949 0.8819 167.96 .....
325 2.2856 448.52 2.0197 0.8022 0.8875 169.66 325 '3.0565 448.23 1.995,6 0.8033 0.8899 169.27 :D
.)iIl
330 2.2498 452.98 2.0333 0.81Q5 0.8956 170.94 330 3.0083 452.70 2.0Q93 0.8115 0.8979 110.56 'TI
335 2.2153 457.47 2.0469 0.8189 0.9038 i72.20 335 2.9616 457;21 2.0229 0.8198 0.9059 i'71.85 r0-
c:
340
345
2.1818
2.1493
462.0,1
466.59
2:0603
2:0737
0.8272
Q.8355
0.9119
0.9200
173.46
174.70
340
345
.2.9164
2.8726
46L76
466.35
2.0363
2.0497
0.82~1
0.8363
0.9139
0.92]9
113.12,
114.37
o
:D
350 2.1179 471.21 2.0870 0.8437 0.9281 175.93 350 1302 470.98 2.0631 0~8445 0.9299 175;62 om
355 2.0873 475.88 2.1002 0.8519 0.9362 177.15 355 2.7891 475.65. 2.0763 0.8527 0.9379 176.85 -I
360 2.0577 480.58 2.1134 0.8601 0.9442 17,8.36 360 2.7492 48036 2.0895 0.8608 0~9458 178.08 :t:
365 2.0289 485.32 2.1264 0.8683 0.9523 179.57 365 2:7104 485.11 2..I026 0.8689 0.9537 179~2~ »
Z
370 , 2.0009 490..10 2.1394 0.8764' 0.9()Q3 18Q..76 379 2.6728 489.90 2.1156 ().8770 0.9617 180.49 m
375 '1.9737 494.92 2.i524 0.8845 0.9682 181.94 375 '2.6362 494.73 2.1286 0.8850 0.9696 1'81.69 %
380 1.9472 499;78 2.1653 0.8925 0.9762 183;11 380 2.6007 49~.59 2.1415 Q.8931 0.9774 182Jp ."
385 1.9215 504.68 2.1781 0'9006 0.9841 184.28 385; 2.5661 504.50 2.1543 0.9011 0.9853 184.04 9....
390 1.8965 509.62 2'.1908 0.9085 0.9920 '1~5A3 390 , ;2.5325 509.45_ 2:1671 0.9090 0.9931 1~5.21 (A)

~
395
400
410
1.8721
1.8483
1.8026
514.60
519.62
529.78
2.2035
2.2161
2.2412
0.9165
0.9244
0.9402
0.9999
1.0077
1.0233
186.58
187.72
189.97
395
400
410
2.4997
2.4678
2.4065
514.43
519.46
529.62
2.17_98
2.1924.
2.2175
0.9169
0.9248
0.9406
1.0010
1.0088
1.0243
186.36
187.51
189.78
-
420 1.7591 540.09 2.2661 0.9558 1.0388 192.20 420 2.3.482 539.94 2.2424 O.?561 1.0397 192.02
430 1.7177 550.56 2:2907 0.9713 L0542 194.40 430 2.2927 550.42 2.2670 0.9716- L0550 194~23
440 1.6782 561.18 2.3151 ,0.9867 1.0695 ,196.57 440 2.2398 561.04 2.2914 0.9870 1.0702 196.41
450 1.6405 571.95 2.3393 1.0020 1.0847 198.71 450 2.1893 571.82 2.3157 1.0022 ].0853 198.57 .....
o~
460 1.6045 582.87 2.3633 1.0171 1.0991 200.83 460 2.]411 582:75 ' 2.3397 1.0173 1.1004 200.69

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 ~ .....
"'0
TABLE 9. T1ennodynamic properties of HFC-134a in the single-phase region Continued o
~
:::J'

~ T p h s __
C v_ ~ w T p h s Cv ----EL- ...
o:::J' K kglm3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls K kglm3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) ms
CD
? 0.10 MPa 0.12 MPa
::u
~
c 170 1590.8 71.671 0.4135 0.7921 1.1837 1119.5 170 1590.8 71.686 0.4135 0.7921 1.1837 1119.6

J 175
180
1577.6
1564.3
77.591
83.526
0.4478
0.4812
0.7909
0.7912
1.18L6
1.1870
1094.1
1068.7
175
180
1577.6
1564.3
77.606
83.535
0.4478
0.4812
0.7909
0.7912
1.1846
1.1870
1094.2
1068.7
<
~ 185 1551.0 89.470 0.5138 0.7927 1.1905 1043.3 185 1551.0 89.479 0.5138 0.7927 1.1904 1043.4
I\) 190 1537.6 95.433 0.5456 0.7950 1.1948 1018.0 190 1537.6 95.442 0.5456 0.7950 1.1948 1018.1
~
195 1524.1 101.42 0.5767 0.7980 1.1999 992.95 195 1524.2 101.42 0.5767 0.7980 1.1999 993.04
z 1.2056 968.12
? 200 1510.6 107.43 0.6072 0.8015 1.2056 968.03 200 1510.6 107.44 0.6071 0.8015
.9' 205 1496.9 113.47 0.6370 0.8055 1.2118 943.29 205 1497.0 113.48 0.6370 0.8055 1.2118 943.39
....
CD 210 1483.2 119.55 0.6663 0.8098 1.21~4 918.75 210 1483.2 119.56 0.6663 0.8099 1.2184 918.85
CD 1.2255 894.51
-110 215 1469.3 125.66 0.6950 0.8144 1.2255 894.41 215 1469.3 125.67 0.6950 0.8145 :0
220 1455.3 131.80 0.7233 0.8193 1.2330 870.25 220 1455.3 131.81 0.1233 0.8193 1.2329 870.35 ~
225 1441.2 131.99 0.7511 0.8243 1.24()8 846.26 225 1441.2 138.00 0.7511 0.8243 1.2408 846.37 r
230 1426.9 144.21 0.7785 0.8295 1.24S1 822.43 230 1426.9 144.22 0.7784 0.8295 1.2490 822.54 r
Z
235 1412.4 15().48 0.8054 0.8348 1.2517 798.74 235 1412.4 150.49 0.8054 0.8348 1.2577 798.85 m
240 1397.7 15<i.79 0.8320 0.8402 1.26t8 775.16 240 1397.8 156.80 0.8320 0.8402 1.2668 775.29 :p
245 1382.9 163.15 0.8582 0.8458 1.2764 751.68 245 1382.9 163.16 0.8582 0.8458 1.2763 751.81 :0
246.78 1377.5 165.44 0.8675 0.8478 1.2759 743.30 250 1367.8 169.56 0.8841 0.8514 1.2864 728.41 o
~
246.78 5.1932 382.59 1.7474 0.6876 0.7931 145.63 250.84 1365.3 170.65 0.8884 0.8524 1.2882 724.48 :J:
250 5.1144 385.14 1.7577 0.6901 0.7936 146.73 250.84 6.1676 385.12 1.7434 0.6984 1).8074 146.06 l>
255 4.9976 389.12 1.7734 0.6952 0.79t:2 148.42 255 6.0465 388.48 1.7567 0.7012 0.8074 147.52 Z
260 4.8873 393.11 1.7889 0.7013 0.8OC3 150.05 260 5.9088 392.52 1.7724 0.7062 0.8095 149.22
o
265 4.7827 391.12 1.8042 0.7082 0.8055 151.66 265 5.7788 396.57 1.7878 0.7122 0.8133 150.88 ;x:
270 4.6833 4OI.i6 1.8193 0.7155 0.8114 153.22 270 5.6557 400.65 1.8031 0.7188 0.8181 152.49 !='
275 4.5886 405.24 1.8343 0.7231 0.8118 154.76 275 5.5387 404.76 1.8181 0.7260 1).8237 154.07 0:1
280 4.4981 409.34 1.8491 0.7309 0.82-46 156.27 280 5.4272 408.89 1.8330 0.7334 1).8299 155.62 »
285 4.4116 413.48 1.8637 0.7389 0.8316 157.75 285 5.3209 413.06 1.8478 0.7411 1).8364 157.14 m
J:
290 4.3288 417.66 1.8783 0.7469 0.83~8 159.21 290 5.2192 417.26 1.8624 0.7490 0.8432 158.64 lJ
295 4.2494 421.87 1.8927 0.7550 0.8M:2 160.65 295 5.1218 421.49 1.8769 0.7569 0.8502 160.10
300 4.1731 42<i.12 1.9070 0.7632 0.8537 162.06 300 5.0284 425.76 1.8912 0.7649 1).8574 161.55
305 4.0997 43().41 1.9211 0.7714 0.8614 163.46 305 4.9387 430.06 1.9055 0.7730 0.8647 162.97
310 4.0291 434.74 1.9352 0.7797 0.8690 164.84 310 4.8525 434.41 1.9196 0.7811 0.8721 164.37
315 3.9611 439.10 1.9492 0.7879 0.8768 166.20 315 4.7696 438.79 1.9336 0.7892 1).8797 165.76
320 3.8955 443.50 1.9630 0.7961 0.88-46 167.54 320 4.6897 443.20 1.9475 0.7973 1).8872 167.12
325 3.8322 447.95 1.9768 0.8044 0.8924 168.87 325 4.6126 447.66 1.9613 0.8055 0.8949 168.47
330 3.771 45:.43 1.9905 0.8126 0.9OC2 170.19 330 4.5382 452.15 1.9750 0.8136 0.9025 169.81
,,", 3.7120 456.95 2.0041 0.8208 0.90~1 171.49 335 4.4664 456.69 1.9887 0.8217 0.9103 171.12
~ ..:'.l) 3.65.+8 461.51 2.0176 0.8290 0.9159 172.77 340 4.3970 461.26 2.0022 0.8298 0.9180 172.43
)-!5 3.5995 466.11 2.0310 0.8371 0.9238 174.04 345 4.3298 465.87 2.0157 0;8379 0.9257 173.71
350 3.5'+59 470.75 2.0444 0.8453 0.9317 175.30 350 4.2648 470.51 2.0290 0.8460 1).9335 174.99
355 3.4939 475.43 2.0577 0.8534 0.93S5 176.55 355 4.2018 475.20 2.0423 0.8541 0.9412 176.25
360 3.4435 480.14 2.0709 0.8615 0.9414 177.79 360 4.1408 479.93 2.0556 0.8622 0.9490 177.50
365 3.3947 484.90 2.0840 0.8695 0.9552 179.01 365 4.0816 484.69 2.0687 0.8702 0.9568 178.74
370 3.3472 489.70 2.0970 0.8776 0.9631 180.23 370 4.0242 489.49 2.0818 0.8782 1).9645 179.96

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 TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region - Continued
- -_ .. _----

T p h s Cv
--EL- w T p h s Cv
~
w
K kg/m3 kJlkg kJl(kgK) kJ/(kgK) - k1/(kgK) mls K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

().10MPa 0.12 MPa .....

%
375 3.3011 494.53 2.1100 0.8856 0.9709 181.43 375 3.9684 494.34 2.0948 0.8862 0.9723 181.18 m
380 :lJ
3.2563 499.41 2.1229 0.8936 0.978, 182.63 380 3.9142 499.22 2.1077 0.8941 0.9800 182.38
3C
385 3.2128 50432 2.1358 0.9016 0.9865 183.81 385 3.8615 504.14 2.1206 0.9021 0.9877 183.58 o
390 3.1704 50927 2.1486 0.9095 0.9943 184.98 390 3.8103 509.10 2.1334 0.9100 0.9954 184.76 c
395 3.1292 51426 2.1613 0.9174 1.0021 186.15 395 3.7605 514.09 2.1461 0.9178 1.0031 185.93 -<
z
400 3.0891 51929 2.1739 0.9253 1.0098 181.31 400 3.7121 519.13 2.1588 0.9257 1.0108 187.10 »
410 3.0119 529.47 2.1990 0.9409 1.0252 189.59 410 3.6189 529.31 2.1839 0.9413 1.0262 189.40 3:
420 2.9386 53930 2.2239 0.9565 1.0405 191.85 420 3.5304 539.65 2.2088 0.9568 1.0414 191.67 (;
430 2.8689 550.~8 2.2486 0.9719 1.0558 194.07 430 3.4463 550.14 2.2335 0.9722 1.0566 193.91 "'0
::0
440
450
2.8024
2.7391
560.91
571.70
2.2730
2.2973
0.9872
1.0025
1.0709
1.086<J
196.26
198.43
440
450
3.3662
3.2898
560.78
571.58
2.2580
2.2822
0.9875
1.0027
1.0717
1.0867
196.11
198.29
o"'0
460 2.6786 58253 2.3213 1.0176 1.10HJ 200.56 460 3.2169 ' 582.52 2.3063 1.0178 1.1016 200.43 m
:D
.....
0.14 MPa 0.16 MPa iii
Cb
170 1590.8 71.595 0.4135 0.7921 1.1837 1119.7 170 1590.9 71.704 0.4135 0.7921 l.l837 1119.7 o
."
175 1577.6 77.515 0.4478 0.7909 1.18~ 1094-.3 175 1577.6 77.624 0.4478 0.7910 1.1846 1094.3 .....
180 1564.4 83.544 0.4812 0.7912 1.187C 1068.8 180 1564.4 83.553 0.4812 0.7912 1.1869 1068.9 ':.A.
185 1551.0 89.487 0.5138 0.7927 1.1904 1043.4 185 1551.1 89.496 0.5137 0.7927 1.1904 1043.5 ':.A.
190 1537.7 95.450 0.5456 0.7950 1.1948 1018.2 190 1537.7 95.459 0.5455 0.7950 1.1948 1018.3 ~
195 1524.2 101.43 0.5767 0.7980 1.1999 993.13 195 1524.2 101.44 0.5766 0.7980 1.1998 993.22 ~
200 1510.6 107.45 0.6071 0.8015 1.2055 968.21 200 1510.7 107.45 0.6071 0.8016 1.2055 968.30 !!I
:D
205 1497.0 205 - 0.8055 1.2117 943.57
210 1483.2
113.49
119.56
0.6370
0.6662
0.8055
0.8099
1.2117
1.2184
943.48
918.95 210
1497.0
1483.3
113.50
119.57
0.6369
0.6662 0.8099 1.2184 919.05
--»
."
215 1469.4 125.57 0.6950 0.8145 1.2255 894.61 215 1469.4 125.68 0.6950 0.8145 1.2254 894.71 r-
c:
220 1455.4 131.~2 0.7233 0.8193 1.2329 870.46 220 1455.4 131.83 0.7232 0.8193 1.2329 870.56 o
:lJ
~ 225 1441.2 138.00 0.7510 0.8243 1.2408 846.48 225 1441.3 138.01 0.7510 0.8243 1.2407 846.59
"U
=r 230 1426.9 14423 0.7784 0.8295 1.249C 822.66 230 1427.0 144.24 0.7784 0.8295 1.2490 822.77 o
m
oc::::
!" 235 1412.5 150.50 0.8054 0.8348 1.257f. 798.97 235 1412.5 150.50 0.8053 0.8348 1.2576 799.09 .....
:I:
o
=r
240
245
1397.8
1383.0
156.&1
163.16
0.8319
0.8582
0.8402
0.8458
1.2667
1.2763
775.41
751.94
240
245
1397.9
1383.0
156.81
163.17
0.8319
0.8581
0.8402
0.8458
1.2667
1.2762
775.53
752.07
»
Z
C1>
i3 250 1367.9 169.57 0.8840 0.8514 1.2863 72&.55 250 1367.9 169.58 0.8840 0.8514 1.2863 728.68 m
:D 254.39 1354.4 175.24 0.9065 0.8565 1.2957 708.04 255 1352.6 176.03 0.9096 0.8572 1.2969 705.34 %
~ 254.39 7.1353 38731 1.7402 0.7080 0.8203 146.38 257.56 1344.6 179.37 0.9226 0.8602 1.3026 693.39 ."
C 255 7.1141 387JH 1.7421 0.7082 0.8201 146.60 257.56 8.0978 389.26 1.7375 0.7166 0.8323 146.61 ....~
~ 260 6.9468 391.CJl 1.7581 0.7116 0.8197 14&.37 260 8.0022 391.29 1.7454 0.7176 0.8311 147.50 w

~
<
~
N
265
270
275
6.7895
6.6411
6.5005
396J)2
400.13
404.27
1.7737
1.7891
1.8043
0.7165
0.7224
0.7290
0.8217
0.8253
0.8300
150.08
15l.75
153.38
265
270
275
7.8156
7.6401
7.4744
395.45
399.60
403.78
1.7612
1.7767
1.7920
0.7212
0.7263
0.7323
0.8310
0.8331
0.8366
149.28
151.00
152.68
-t
Z 280 6.3669 408.44 1.8193 0.7361 0.8354 154.97 280 7.3175 407.97 1.8072 0.7389 0.8412 154.31
~ 285 6.2396 412.63 1.8341 0.7435 0.8413 156.53 285 7.1683 412.19 1.8221 0.7459 0.8465 155.91
9' 416.44 0.7532 0.8523 157.47
.... 290 6.1182 416.85 1.8488 0.7510 0.8476 15&.06 290 7.0263 1.8369
~
CD
CD
295 6.0021 421.10 1.8633 0.7588 0.8543 159.56 295 6.8907 420.72 1.8515 0.7607 0.8584 159.00 o
~ CJ'I

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f- ......
"U
TABLE 9. ThermodynamIc properties of HFC-134-a in the single-phase region - Continued o
0)
::s-
~ T P h s w T h s w
o c" ~ P c~
~
::s- K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) rnls K kg/rr? kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) rnls
CD
? 0.14 MPa 0.16 MPa
:u
~
,
C
m

<
300
305
310
5.8910
5.7844
5.6821
425.39
429.72
434.08
1.8778
1.8921
1.9062
0.7666
0.7745
0.7825
0.8611
0.8681
0.8753
161.03
162.48
163.91
300
305
310
6.7611
6.6369
6.5179
425.02
429.37
433.74
1.8660
1.8803
1.8946
0.7683
0.7761
0.7839
0.8649
0.8716
0.8785
160.51
161.99
163.44
~ 315 5.5837 438.47 1.9203 0.7905 0.8826 165.32 315 6.4036 438.15 1.9087 0.7918 0.8856 164.87
I\.) 320 5.4890 442.90 1.9343 0.7985 0.8900 166.70 320 6.2937 442.60 1.9227 0.7998 0.8927 166.28
~
325 5.3978 447.37 1.9481 0.8066 0.8974- 168.07 325 6.1880 447.08 1.9366 0.8a77 0.9000 167.67
z
~ 330 5.3099 451.88 1.9619 0.8146 0.9049 169.42 330 6.0861 451.60 1.9504 0.8157 0.9073 169.04
$" 335 5.2250 456.42 1.9755 0.8227 0.9125 170.76 335 5.9878 456.15 1.9641 0.8237 0.9147 170.39
~
CO 340 5.1430 461.00 1.9891 0.8307 0.9200 172.08 340 5.8930 460.75 1.9777 0.8316 0.9221 171.73
CO
~ 345 5.0638 465.62 2.0026 0.8388 0.9277 173.38 345 5.8014 ' 465.38 1.9912 0.8396 0.9296 173.05 ;0
350 4.9871 470.28 2.0160 0.8468 0.9353 174.67 350 5.7128 470.04 2.0046 0.8476 0.9371 174.35 -I
355
360
4.9129
4.8410
474.97
479.71
2.0293
2.0426
0.854S
0.8628
0.9430
0.9506
175.95
177.21
355
360
5.6270
5.5441
474.75 2.0180
2.0312
0.8556
0.8635
0.9447
0.9522
175.64
176.92
r=r
479.49
Z
365
370
375
4.7712
4.7036
4.6380
484.48
489.29
494.14
2.0557
2.0688
2.0818
0;8708
0.8788
0.8867
0.9583
0.9660
0.9736
178.46
179.70
180.92
365
370
375
5.4636
5.3857
5.3101
484.27
489.09
493.94
2.0444
2.0575
2.0706
0.8715
0.8794
0.8873
0.9598
0.9674
0.9750
178.18
179.43
180.67
m
.
:IJ
:IJ
380
385
4.5743 499.03 2.0948 0.8947 0.9813 182.14 380 5.2367 498.84 2.0835 0.8952 0.9826 181.89 ~
4.5124 503.95 2.1077 0.9026 0.9890 183.34 385 5.1654 503.77 2.0964 0.9031 0.9902 183.11 :J:
390 4.4522 508.92 2.1205 0.9104 0.9966 184.53 390 5.0961 508.74 2.1093 0.9109 0.9978 184.31 »
Z
395 4.3937 513.92 2.1332 0.9183 1.0043 185.72 395 5.0288 513.75 2.1220 0.9187 1.0054 185.50
400 4.3368 518.96 2.1459 0.9261 1.0119 186.89 186.68
C
400 4.9633 518.80 2.1347 0.9265 1.0129
410 4.2274 529.16 2.1711 0.9417 1.0271 189.21 410 4.8375 529.00 2.1599 0.9421 1.0281 189.02 ;r:
420 4.1236 539.50 2.1960 0.9572 1.0423 191.49 420 4.7182 539.36 2.1849 0.9575 1.0431 191.32 P
430 4.0250 550.00 2.2207 0.9725 1.0574- 193.74 430 4.6048 549.86 2.2096 0.9728 1.0582 193.58 OJ
440 3.9310 560.65 2.2452 0.9878 1.0724- 195.96 440 4.4970 560.52 2.2341 0.9881 1.0731 195.81 »
m
450 3.8416 571.45 2.2695 1.0030 1.0873 198.15 450 4.3943 571.33 2.2584 1.0032 l.0880 198.01
:J:
460 3.7561 582.40 2.2935 1.0180 1.1022 200.30 460 4.2963 582.28 2.2824 1.0182 1.l028 200.17 :IJ

0.18 MPa O.20MPa

170 1590.9 71.713 0.4134 0.7922 1.1836 1119.8 170 1590.9 71.722 0.4134 0.7922 1.1836 1119.9
175 1577.7 77.633 0.4478 0.7910 1.1846 1094.4 175 1577.7 77.642 0.4477 0.7910 1.1846 1094.5
180 1564.4 83.562 0.4812 0.7912 1.1869 1069.0 180 1564.4 83.571 0.4811 0.7913 1.1869 1069.1
i85 1551.1 89.505 0.5137 0.7927 1.1904 1043.6 185 1551.1 89.514 0.5137 0.7927 1.1904 1043.7
190 1537.7 95.468 0.5455 0.7950 1.1941 1018.4 190 1537.7 95.476 0.5455 0.7950 1.1947 1018.4
195 152·U 101.45 0.5766 0.7980 1.1998 993.30 195 1524.3 101.46 0.5766 0.7980 1.1998 993.39
20) 1510.7 107.46 0.6071 0.8016 1.2055 968.39 200 1510.7 107.47 0.6070 0.8<ll6 1.2055 968.48
205 1497.1 113.51 0.6369 0.8055 1.2117 . 943.67 205 1497.1 113.51 0.6369 0.8e55 1.2117 943.76
210 1483.3 119.58 0.6662 0.8099 1.2183 919.14 210 1483.3 119.59 0.6662 0.8(J99 1.2183 919.24
215 1469.4 125.69 0.6949 0.8145 1.2254 894.81 215 1469.5 125.70 0.6949 0.8145 1.2254 894.91
220 1455.5 131.84 0.7232 0.8193 1.2323 870.67 220 1455.5 131.84 0.7232 0.8193 1.2328 870.77
225 1441.3 138.02 0.7510 0.8243 1.2407 846.70 225 1441.4 138.03 0.7510 0.8243 1.2406 846.81
230 1427.0 144.24 0~7784 0.8295 1.2489 822.88 230 1427.1 144.25 0.7783 0.8295 1.2489 823.00

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 TABLE?; Thennod~nanjc properties Qf:IIFC~~34airith,~ sil1g1e~phas~regi9n Co~~ued
. ~.' .,. :, .: . : :_, i'." I{ '. .: . ~ .. -' ;

T , ,h" ,J:"...... w T ,P··.' ,;JL. s , ,C".,. ~ w.. '

P ~. ~
K kg/mJ kJlkg k1/(kgK). kJ/(kgK) kJ/(kgK). mls K kg/m3 ' ;kJ/kg kJ/({(gJ() kJ/(kgK) kT/(kgK) m/s

0.18 MPa 0.2~ M,Pa

-I
X
23$ 1412.~. 15051 0.8053 0.8348 1.2576 799.21 235 141-2.6 150,.52 0.8053 0.~348 1.2575 799.33 m
1,2666 175.78.
:D
240 1397.9 156;82 0.S319 0.8402 L2666 775.6~ 240 1398.0. 1,56.83 0.8~18 0.8402 3C
245 1383.1 1.63.1S 0.8?8,t 0.S45~ 1.2762 752.20 245 1383.1 163.18 Q.8581 0.8458 1.276,1 752.33 0
250 1368.0 1.69.58 0.8840 0.8514 1.2862 728.82 250 1368;0 169.59 0,.8839 0.85,14 1.2861 728.95 C
255 1352,6 176,04 0.9096 0.8572 1.29158 705~48. 255. 13523 1:76.05 0~9q95; 0.8572 1:2968 705.6~ -<
Z
260 1337.0, 18~.55 0.9348 0.863L 1.308.l 682;16 260 1337.1 182.56 0.9348 0.8~31 1,3080 682,3} »
260.43 1335.6 183.13 0.9~70 0;8(i36 1309l 680.12 263.07 1327.3. 18~.59 0.9?02 0.8667 L~l53 667.98 3C
26Q.43 9.0565 391.02 1.7353 0.7246 0.8435 1#.77 263.07 10.012 39~.6! .,.7334 0.7320 0,8540 146.88 (;
265 8.8578 394,86 1.7499 0.7265 0.841l, 148.45 265 9.9171 394.26 1:.7396 0.7323 0.8?~3 147.61 ."
0,8504 149.45 :D
270 8~6534 399,06 1.7656 0.7305 0.8414- 150.23 27(J 9.6815 398:5.1 1,.7555 0.7350. 0
275 8·4:6U -403,28 1.7811 0.n5? 0.8,437 151.96 275 9,4609 402.17 1.7711 0.7~9~ 0,8512 151.23 ."
280 8~2794 407,50 1;7963 ~.7418 0,.8473 153.64 280 9.2!)30 407,03 1.1865 C).7MB 0,8537 152.96 m
:D
2.85 8.1072 4U,75 L8114 0.7484 0~8S1,8 155.28 285 9.0566 411 ..31 1.8016 0.7510 Q,8574 154.64 ~
290 7.9435 416,02 1.8262. 0.7554 0.8570 156;8~ 290 ,8.8793 415.60 l.ffl66 0.7577 0.8620 156.28 iii
tJ)
295 7.7876 420.32 1.8409 0.,,6'),6 0.8628 15,8.44 295 8.6931 419.9,3 1.8313 0'.1647 0,8672 157.88
~oo .7.6388 424,65 L8555 0.7701 0.8688 159.98 309 ;~.5243 424.~8 l.8i~ 0.77,19 0,8729 159.45 .,.,
0
305 7.4965 4~9.o1. •.. 8699 0·777.1 0.8752 161.49 305 ·8.3631 428.66 1.86.o~ 0.7793 0,8789 160.98 ....
310 7.3,602 433,41 ~·~88.42 0.7854 Q.881S 162.97 311) 8.2089 4~~.07 1.8748 0.7869 0,8852 162.49 :...
:...
315
320
325
7~2294
,7.1039
.. 6.9831
43,7,83
442,29
446,79
L8983
1..9124
L9~63
0.7932
0..8.010
0.8.088
0.8886
0.8955
0.90+6
164.42
165;85,
167~26
315
3~0,
325
8.0612
.7.9195
7:~834
437.51
44,1.98
+16-49,
1.889Q
1.903~,
J.9171
.0.7945
0.8022
O.~I00
0,8917
Q,~984.
Q,~5f
163,97
1,§S.4~
166.86
.
kI
-I
m
330 .6.8669 451.32 1.9~ 9..8161 Q.9097 168.65 330 7;6524 4$L~4 i,?3Q9 .0.8178 0,9122 168.27 -I
:a
33,5.
340
6.7549
6.6469
45$.89
460.49,
L9539
1.9675
0.8246
0.8326
0.9170
0.9243
170.02
171:38
335
340
7.5263
7.4048
455;(i2
460.23
1.;9,447
1.9584
0.8256
0.8335
0,9193
(),9~q4
169.66
17L()3
»
.,.,
...
0.8~lj .0;9,336 p~~38
r-
~45 6.5426 465.13 1.9811 0.8405 0~9316 p2.7.1 345 7.2876 464.~8 1.9729 c:
350 6.4419 469,81 1.9.945 0.8484 0.9~90 174.03 350 ·7.1744 469.57 1.9855, 0.8492 0,9409 113.71 0
f- 355 6.3444 474.52 2.0079 .0.8563 Q.9464 .l75.34 355 7.0650 474.29 t.9988 0.857.0 0,9482 1'75;03 :a
~.Q122 0.8649 .0,9556 176.33 0
"<£D
::J'
360 6.2501 479,27 2;0212 0.8642 Q;9.539 176.63 360 ,6.9592 479·.0$ m
365 6.1588 484,06 2 ..0344 R8721 0.9614- 177.90 365 6~8568 ~83.85 7·()254 0.8728 0,9629 177.62 -I
:I:
(')
::J'
31.0 6 ..0703 488,88 2.0475
2;0606
.0.8800 .0.9,689 179.16 ~70 ·6.7576
.6.6615
488.68
49,3.55
2.Q38?
2 ..0516
0.~806
.0;8884
0,9704
.0.9778
178.89
180.15
»
Z

-
CD 375 5.9845 493,75 0.8879 0.9764 180.41 375
~ 380 5,.9013 498,65 7·.0736 .0.8957 0.9839 181.65 38Q ' .6.5682 498.46 2.0646 0.8963 0,9852 .~8~.40 m
:II 385 5.8205 5.03,59 2 ..0865 (t9036 Q.99}'! ·182;87 385 6.4777 S03.40. 2.0776 Q.9()41 0.9927 182.63 :c
~ 390 5.7420 508,56 2.0993 .0.9114 0.9~99 !~4;08 39.0 ,6.3899 SQ8.39 2.6904 0.9118 1.00pl 183.86 ."
C
;. 395 5.6657 513.58 2.H21 .0;9192 1.0065 185;~8 395 6.3.045 SI3.40
518.46,
il()~i
2.1 ~S9
.0.9196
Q.9274
1.0076
LQ151
.185.07
186.27
....9
~
400 5.5915 518,63 2.1248 .0.9269 1;0149 186.48 400 ,.6.2215
~
<
0
:-
1'1)
~
410
420
430
5.4491
5.3141
5.1860
528,84
539,21
549.73
2~1500
2.175,0
2.1998
0.9424
0.9578
0.9731
L0290
1.0440
1.0589
188:83
191.14
193;41
·410
42.0
430
6.0623
5.9115
5.7683
528~69
539.06
549.59
2,1412
2~1662
2.1909
0.9428
0.9582
0.9734
1.0300
1.0449
1..0597
188.63
190.96
193.2S
-»
Z 440 5.0641 560.39 '2,2243 0.9883 1.0738 195.66 440 ,5.6322 560i~6 2,2155 0.9886 1.0746 195.S0
P 45.0 4.948.0 571.20 2~2486 1.0034 1.0887 197.86 450 5.5027 57:1.08 '2.2398 L0037 1.0893 . 197.72
Y' 460 4.8373 58216 2.2727 ,1.0185 1.l03~ 200.04 460 . 5.3791 582.05 2;2639 1.0187 1.1040 199.91
.....
U)
.....
U)
0
~
~

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 .....
TABLE 9. Thennodynamic properties of HFC-134a in the single-phase region Continued o(II)
T p s __
C v_ --E2- w T p h s Cu --E2- ~
K kg/m3 kJ/kg kJ1(kgK) kJ/(kgK) kJ/(kgK) mls K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

0.25 MPa O.30MPa

170 1591.0 71.745 0.4134 0.7922 1.1836 1120.1 170 1591.0 71.767 0.4133 0.7922 1.1836 1120.3
175 1577.8 77.665 0.4477 0.7910 1.1845 1094.7 175 1577.8 77.687 0.4476 0.7910 1.1845 1094.9
180 1564.5 83.593 0.4811 0.7913 1.1869 1069.3 180 1564.6 &3.615 0.4810 0.7913 1.1868 1069.4
185 1551.2 89.536 0.5136 0.7927 1.1903 1043.9 185 1551.3 89.558 0.5136 0.7927 I.l903 1044.1
190 1537.8 95.L98 0.5454 0.7950 1.1947 1018.6 190 1537.9 95.520 0.5454 0.7950 1.1946 1018.9
195 1524.4 lOLLS 0.5765 0.7980 1.1997 993.61 195 1524.4 101.50 0.5765 0.7980 1.1997 993.83
200 1510.8 107.L9 0.6070 0.8016 1.2054 968.70 200 1510.9 107.51 0.6069 0:8016 1.2054 968.93
205 1497.2 113.54 [).6368 0.8056 1.2116 944.00 205 1497.3 113.56 0.6368 0.8056 1.2115 944.23
210 1483.4 119.61 [).666 1 0.8099 1.2182 919.48 210 1483.5 1l9.63 0.6660 0.8099 1.2182 919.73
215
220
1469.6
1455.6
125.72
131.86
0.6949
0.7231
0.8145
0.8193
1.2253
1.2327
895.17
871.04
215
220
1469.7
1455.7
125.74
1~1.88
0.6948
0.7230
0.8145
0.8193
1.2252
1.2326
895.42
871.30
::u
-I
225
230
1441.5
1427.2
138.()5
144.27
0.7509
0.7783
0.8243
0.8295
1.2406
1.2488
847.08
823.28
225
230
1441.6
1427.3
138.07
144.29
0.7508
0.7782
0.8243
0.8295
1.2405
1.2487
847.35
823.57
r=
r-
Z
235
240
245
1412.7
1398.1
1383.3
150.54
156.85
163.20
[).8052
0.8318
0.8580
0.8348
0.8402
0.8458·
1.2574
1.2664
1.2760
799.63
776.09
752.66
235
240
245
1412.9
1398.2
1383.4
150.S5
156.86
163.22
0.80S1
0.8317
0.8579
0.8348
0.8402
0.8458
1.2573
1.2663
1.2758
799.92
776.40
752.98
.
m
:II
:II
250 1368.2 169.61 ().8839 0.8514 1.2860 729.29 250 1368.3 169.62 0.8838 0.8515 1.2858 729.63 o
-I
255 1352.9 176JJ6 0.9094 0.8572 1.2966 705.98 255 1353.0 176.08 0.9093 0.8572 1.2964 706.34 :J:
260 1337.2 182.57 [).9347 0.8631 1.3078 682.69 260 1337.4 182.S9 0.9346 0.8631 1.3076 683.06 »
Z
265 1321.3 189.14 0.9597 0.8691 1.3198 659.38 265 1321.5 189.16 0.9597 0.8691 1.3196 659.77
268.86 1308.7 194.26 0.9789 0.8738 1.3297 641.33 270 1305.2 19S.79 0.9844 0.8751 1.3324 636.44
C
268.86 12.393 396.08 1.7295 0.7484 0.8782 146.98 273.82 1292.5 200.90 1.0032 0.8799 1.3428 618.56 ;C
270 12.322 397.07 1.7332 0.7483 0.8766 147.43 273.82 14.77G 398.99 1.7267 0.7627 0.9002 146.92 P
275 12.022 401.44 1.7493 0.7498 0.8724 149.36 275 14.679 400.05 1.7305 0.7625 0.8981 147.40 tD
280 11.741 405.80 1.7650 0.7533 0.8714 151.22 280 14.314 404.52 1.7467 0.7631 0.8921 149.41 »
m
285 11.478 410.16 1.7804 0.7580 0.8726 153.01 285 13.975 408.98 1.7624 0.7660 0.8899 151.33
:J:
290 11.230 414.53 1.7956 0.7637 0.8753 154.75 290 13.657 4[3.43 1.7779 0.7704 0.8900 IS3.18 :II
295 10.996 418.92 1.8106 0.7699 . 0.8790 156.44 295 13.35E 417.88 1.7931 0.7756 0.8918 154.97
300 10.773 423.32 1.8254 0.7766 0.8834 158.09 300 13.076 422.35 1.8081 0.7815 0.8948 156.71
305 10.562 427.75 1.8401 0.7835 0.8884 159.70 305 12.809 426.83 1.8230 0.7879 .0.8986 158.40
310 10.360 432.21 1.8546 0.7907 0.8939 161.28 310 12.555 431.34 1.8376 0.7946 0.9031 160.05
315 10.167 436.69 1.8689 0.7980 0.8997 162.82 315 12.31A. 43S.86 1.8521 0.801S 0.9081 161.66
320 9.9833 441.21 1.8831 0.8054 0.9058 164.34 320 12.08A 440.42 1.8664 0.8086 0.913S 163.23
325 9.8067 445.75 1.8972 0.8129 0.9120 165.82 325 11.863 44S.00 1.8806 0.8159 0.9191 164.78
330 9.6372 450.33 1.9112 0.8205 0.9185 167.29 330 11.653 449.61 1.8947 0.8232 0.9251 166.29
335 9.4743 454.94 1.9250 0.8281 0.9251 168.72 335 11.450 454.25 1.9087 0.8306 0.9312 167.78
340 9.3176 459.58 1.9388 0.8358 0.9319 170.14 340 11.256 458.92 1.9225 0.8381 0.9375 169.24
345 9.1667 464.26 1.9525 0.8435 0.9387 171.53 345 11.07() 463.63 1.9363 0.8456 0.9440 170.67
350 9.0213 468.97 1.9660 0.8512 0.9457 172.90 350 10.890 468.36 1.9499 0.8532 0.9506 172.09
355 8.8809 473.71 1.9795 0.8589 0.9527 174.26 355 10.717 413.13 1.9634 0.8608 0.9573 173.48
360 8.7453 478.50 1.9929 0.8667 0.9598 175.60 360 10.550 417.94 1.9769 0.8684 0.9641 174.85
365 8.6142 483.31 2.0061 0.8744 0.9669 176.92 365 10.389 432.77 1.9902 0.8760 0.9710 176.21
370 8.4874 488.l7 2.0193 0.8821 0.9741 178.22 370 10.234 437.65 2.0035 0.8837 0.9779 177.54

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 tABLE .9...__ Thefuiodylla~pro~itiesp(HFC- f34a 1n; the single.;ph~e region· .. --.::... lbptPlued
:"!:'~.,' <'~:": ':"'~.:'.;.,.
".:":". . " ;:;,.:.{ ~
. .;)...:.: .. : .... ::/:'...~::.-\:
" : ..';.:.. ';". .
'''''-:~<''"
.-
. .' "., ' .
j,', ' ... .: " ,.... ,
T --p Ii ,·s .
~ w. T . .s., : C v ·;
~ w·
~
"t:;v
K kglm3 kJikg kJ/(k~K) kJ/(kgK) kJ/(kgl() rnls K kglm kJ/kg kJ/(~gl<) kJ/(kgK) kl/(kgK) rnI~
. -.'

()~SMPa O.30MPa
-t
:t:
375 83647 493.05 2.032$ 0.13899 0.9~13 179.~1 375 IO.Q83 49255 2.0166 0.8913 0.9849 178.86 m
380 : ,8.2457 2~0455 IS0.16 :D
497.98 0.8976 0.~~86 18'0.78 380 9.9380 49750 2.0297 ().S990 0.9920
3C
385
390
8.1304 507.94 2.05S5 0.~0$3 0.9Q58 182.04 3~5 9.7969 502.47, 2.0427 ~.9066 ' 0.9991 IS 1.45 oo
8.0185 507.94 f·0714 0.9ilo 1.0031 18~;29 390 ,,9.6601 507.49.. 2.0557 0.9142 1.0067 182.72
395 .7;~100 512.97 ~.08~2 0.9207 1.0104 184,~2 ~95 95275 51254 2.0685 0.9219 1.0133 183.97 -<
z
40Q .7.8045 5'i8.04. 2.097Q 0.9~84 1.()178 185;74 400 ·9.3988 517.62 2.0813 0.9~95 1.0205 185.22 »
410 7.6024 528.29 2.1223 0.9438· L0324 ISS~15 410 9.1524 527.90 2.1067 0.9447 1.0349 . IS7.67 3C
420 7.4111 53S.69 2 •.1473. 0.9590 1.0471 190.52 420 8.9196 53832 2.13t8 0.9599 1.0493 190.07 o
430 7.2298 549.24 2.1722 0.9742 L0618 192.84 430 8.6991 548.89 2.1567 0.9750 1.0638 192.43 ."
:D
440
450
7.0576
6.8938
559.93
570ft
2. 19f)7 0.9893
1.0043
1.0764
l.09IC
195.12
197.37
449 8.4899
8.2912
559.60
570.45
2.1813
2.2057
0.9QQ()
1.0049
~.~7~3
1.0927
194.74
J97.02
o
."
2.2211 450
460 6.7378 581.15 2.2452 1.0192 l.lpS6 199.59
,
460 8.1020 581.4.5 2.2299 1.0198 1.1071 19~.26 m
1 t :D
-t
,f).3SMPa O.40.MPa m
tn.
I70 1591.1 71.790 004133 0.7922 L1835 1120.4., 17Q 1591.1. 71.813 0.4132 0.7922 1.1835 1120.6 o
."
175 1577.9 77.700 0.4476 Q;791O 1.1844 1095.1··· 175 1577.9: 77;732 - Q.447S 0.7910 1.1844 1095.2 .....
180 1564.6 83.(i37 OA810 0.7913 1.1868 1069.6 180 1564.7.', 83.659 0.tt8()9 Q.7913 1.1867 1069.8 :...
185 1551.3 .89.580 0.5135 0.1927 L19Q2 1044.3 i8s 1551.4 ~9.602 0.5135 0. 7927 1.1902 1044.5 :.a.
190 1538.0 . ,Q5.542 0.5453 0.7950 1.19Mi 1019.1 190 1538.0 :95.563 0.5453 0.7951 L1945 1019.3 ~
195 1524.5 lQ1.52 Q.7981 1,.1996 994.04 195 1524.6\ 101.54 0.5.764 0.7981 1.1996 994.26 -t
0..5.764 m
200 15H~0. 107.53 0.6069 0.~016 1.2053 969.16 200 1511.0 107.56 Q.6068 0.8016 1.2052 969.38 -I
205 1497.3 113.58 0.6367 0.8056 1.2115 944A6 205 1497.4 Il~.60 0.6366 0,8056 1.2114 944;70 :D
l>
210
215
1483.6
1469.8 .
119.6?
125.16
0.6660
0.6947
0.8099
0.8145
1.2181
~.2251
919.97
895~67
210
215
1483.7
146~·9
1l~.67
125.78
0.Q65~
0.6947
0.8<>99
0.8145
1.2180
L2251
920.21
895.92
-"r-
c:
220 1455,8 131.90 0.7230 0.~193 1.232<: 871.56 ~20 1455;9 131.92 0.7229 0.S193 12325 87.l.82 o
~
225 1441.7 138.09 0.7508 0.8243 i.2404 ~47.63 225 1441.8 138.10 0.7507 0.8244 1.2403 847.90
230 1427.4 144.31 0~7781 0.8~95 1.248<: 823.85 230 1427,5 . 144.33 0.7780 0.8295 12485 824.14 m
235 1413.0 150.57 0.S051 0.8348 1.2572 800.22 235 1413.1 150.59 0;S050 0.8348 12570 800.52 -t
240 1398.4. 0.8403 1.2662 776.71 240 1398.5 156.90 0.8403 1.2661 777.02 %
15p.&8 0.8316 0.831' l>
~
o 245 1383.5 163.24 0.8578 Q.8458 1.275; 753.30 245 1383.7 163.25 0;8577 0.8458 12755 753.63 Z
:i 250 1368.5 169.64 0.8837 0.8515 1.285, 729.97 250 136.8.6. ,169.66 0.88~ 0.8515 12855 730.31 m
D 255 1353.2 176.09 0.9093 0.8572 1.2962 706.69 255 1353~3 176.11 0.9092 0.8572 12961 707·05 %
~ 260 1337.6 182.6Q 0.9345 0.8631 .1.3074 683.43 260 13n·7: 182.62 0.~34S 0.8631 13072 683.80 ."
9.....
lc 265 1321.7 189.17 0.9596 0.~691
0~8751
1.3194
~.3.321
660.17 265 1321.8 189. 18
19:5~81
0.9595 0.8690
0.8751
13192
13319
660.56
637.27

-E
270 1305.4 195.&0 0.9843 636.86 270 1305.6 0.9842
275 1288.7 202.49 . 1.()o89 0.88i3 1.3459· 613.47- 275 1288.9 202.50 1.0088 0.8813 ·13456 613.90
~ 278.17 1277.9 206.79 l.0244 0.8854 1.3552 598.54 280 1271.9 209.27 1.0332 0~8877 13604 590.42
~ 278.17 17.147 401.50 1.7244 0.7755 0.920; 146.73 282.08 1264.6 212;11 1.0433 0;8903 13670 ·580.60
z 280 16.982 403.18 1.7304 0.7749 0.9l6S 147.51 .282.08 19528 403.71 1.7225 9·7872 0.9400 1.46.47
? 285 16.553 407.14 L7466 0~7752 0~909S 149.58 ·.285 19.223 406.45 ··i.7322 0~7859 0.9330 147;75
f"
~
co
290
295
16.156
15.785
412.28
416JH
1.7624
1.7778
0.7778
0.7818.
0.9066
0.906()
15L55
1?3.45
290
295
18.734
18.281
411.09
415.71
1.7483
1.7641
0.7862
0.7887
0.9254 .
0.9218
149.86
151.88 ....o
g CD

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 TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region - Continued ...........
o
---- -~ --.. -.~ ---- _ .. _----

T p It s Cv
~ w T p h s Cv
~
w
K kg/m3 kJJkg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(tgK) mls

0.35 MPa 0.40MPa

300 15.437 421.35 1.7931 0.7869 0.9072 155.28 300 17.859 420.31 1.7796 0.7926 0.92D7 153.82
305 15.108 425.89 1.8081 0.7926 0.9096 157.06 305 17.462 424.92 1.7948 0.7975 0.9214 155.69
310 14.798 430,44 1.8229 0.7987 0.9129 158.79 310 17.089 429.53 1.8098 0.8031 0.9234 157.50
315 14.503 435.02 1.8375 0.8052 0.9170 160.47 315 16.737 434.16 1.8246 0.8091 0.9254 159.26
320 14.223 439.61 1.8520 0.8120 0.9215 162.11 320 16.403 438.80 1.8392 0.8154 0.93{}0 160.97
325 13.956 444.23 1.8664 0.8189 0.9265 163.71 325 16.085 443.46 1.8537 0.8221 0.9343 162.63
330 13.701 448.88 1.8805 0.8260 0.9319 165.28 330 15.782 448.14 1.8680 .0.8289 0.93~0 164.26
335 13.457 453.55 1.8946 0.8332 0.9375 166.82 335 15.494 452.85 1.8822 0.8358 0.9441 165.85
340 13.223 458.26 1.9085 0.8405 0.9434 168.33 340 15.218 457.58 1.8962 0.8429 0.94~4 167.41
345 12.999 462.99 1.9223 0.8478 0.9494 169.81 345 14.953 462.34 1.9101 0.8501 0.9551 168.93 ?:J
350 12.783 467.75 1.9361 0.8553 0.9557 171.26 350 14.700 4,67.13 1.9239 0.8573 0.96D9 170.43 -t
355 12.576 472.55 1.9497 0.8627 0.9621 172.69 355 14.456 471.95 1.9375 0.8646 0.9669 171.90 F
360 12.376 477.37 1.9632 0.8702 0.9686 17410 360 14.222 476.80 1.9511 0.8720 0.9731 173.35 r
Z
365 12.184 482.23 1.9766 0.8777 0.9752 175,49 365 13.997 481.69 1.9646 0.8794 0.97'~4 174.77 m
370 11.998 487.12 1.9899 0.8852 0.9818 176.86 370 13.780 486.60 1.9779 0.8868 0.9858 176.17 :IJ
375 11.818 492.05 2.0031 0.8928 0.9886 178,20 375 13.570 491.54 1.9912 0.8942 0.9924 177.54 :D
380
385
11.645
11.477
497.01
502.01
2.0162
2.0293
0.9003
0.9079
0.9954
1.0023
179,53
180,85
380
385
13.368
13.172
496.52
501.53
2.0044
2.0175
0.9017
0.9092
0.9990
1.0057
178.90
180.24
~
:J:
390 11.315 507.04 2.0423 0.9154 1.0093 182.14 390 12.983 506.58 2.0305 0.9167 1.0124 181.57 )I-
395 11.157 512.10 2.0552 0.9230 1.0163 183,42 395 12.800 511.66 2.0435 0.9242 1.0192 182.87 Z
400 11.004 2.0680 1.0233 18469 1.0261 184.16
C
517.20 0.9306 400 12.622 516.77 2.0563 0.9316
410 10.712 527.50 2.0934 0.9457 1.0374 187.18 410 12.283 527.10 2.0819 0.9466 1.0399 186.69 ~
420 10.437 537.95 2.1186 0.9607 1.0516 189,62 420 11.963 537.57 2.1071 0.9616 1.0539 189.17 !='
430 10.176 548.54 2.1435 0.9757 1.0659 192m 430 11.661 548.18 2.1320 0.9765 1.0679 191.60 a:J
440 9.9294 559.27 2.1682 0.9907 1.0801 194.36 440 11.376 558.93 2.1568 0.9913 1.0820 193.98 »
m
450 9.6950 570.14 2.1926 1.0055 1.0944 196.67 450 11.105 569.82 2.1812 1.0062 1.0962 196.31
:J:
460 9.4720 581.16 2.2168 1.0204 1.1087 198.93 460 10.847 580.86 2.2055 1.0209 1.1103 198.61 :XJ

0.50 MPa 0.60 MPa

175 1578.1 77.777 0.4474 0.7911 1.1843 1095,6 175 1578.2 77.821 0.4473 0.7911 1.1843 1096.0
180 1564.8 83.704 0.4808 0.7913 1.1867 1070.2 180 1565.0 83.748 0.4807 0.7914 I.l866 1070.6
185 1551.5 89.646 0.5134 0.7928 1.1901 1044.9 185 1551.7 89.690 0.5133 0.7928 l.I900 1045.3
190 1538.2 95.607 0.5452 0.7951 1.1944 1019.7 190 1538.3 95.650 0.5450 0.7951 1.1943 1020.1
195 1524.7 101.59 0.5763 0.7981 1.1995 994.70 195 1524.9 101.63 0.5761 0.7981 1.1994 99.5.13
200 1511.2 107.60 0.6067 0.8016 1.2051 969.83 200 1511.4 107.64 0.6066 0.8017 1.2050 970.28
205 1497.6 113.64 0.6365 0.8056 1.2113 945.16 205 1497.8 113.68 0.6364 0.8057 1.2111 945.63
210 1483.9 119.7 1 0.6658 0.8099 1.2179 920.70 210 1484.1 119.75 0.6657 0.8100 1.2177 921.18
215 1470.0 125.82 0.6945 0.8145 1.2249 896.43 i15 1470.2 125.86 0.6944 0.8146 1.2247 896.93
220 1456.1 131.96 0.7228 0.8194 1.2323 872.35 220 1456.3 132.00 0.7226 0.8194 1.2321 872.87
225 1442.0 138.14 0.7506 0.8244 1.2401 848.44 225 1442.2 138.18 0.7504 0.8244 1.2399 848.99
230 1427.7 144.36 0.7779 0.8295 1.2483 82470 230 1428.0 144.40 0.7778 0.8296 1.2430 825.27
235 1413.3 150.63 0.8048 0.8348 1.2568 801.11 235 1413.6 150.66 0.8047 0.8349 1.2566 801.70

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 TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region Continued

T p h s C v_
__ ---EL- w T p h s Cv ~ ..!!..
K kglm 3 kJ/kg kJf(kgK) kJ/(kgK) kJ/(kgK) mls K kglm3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

(J.50MPa 0.60 MPa

-t
::t
240 1398.7 156.93 0.8314 0.8403 1.2658 777,64 240 1399.0 156.97 0.8312 0.8403 1.2656 778.26 m
245 ::II
1383.9 163.29 0.8576 0.8458 1.2753 754.27 245 1384.2 163.32 0.8574 0.8458 1.2750 754.92
3:
250 1368.9 169.69 0.8835 0.8515 1.2852 730,99 250 1369.2 169.72 0.8833 0.8515 1.2849 731.66 o
255 1353.6 176.14 0.9090 0.8572 1.2957 707:75 255 1353.9 176.17 0.9088 0.8572 1.2954 708.46 c
260 1338.1 182.65 0.9343 0.8631 1.3068 684,55 260 1338.4 182.68 0.9341 0.8631 1.3065 685.29 -<
z
265 1322.2 189.21 0.9593 0.8690 1.3187 66134 265 1322.5 189.24 0.9591 0.8690 1.3183 662.12 »
270 1306.0 195.84 0.9841 0.8751 1.3314 638,09 270 1306.3 195.86 0.9839 0.8751 1.3309 638.92 3:
275 1289.3 202.53 1.0086 0.8813 1.3450 614.78 275 1289.8 202.55 1.0084 0.8813 1.3444 615.64 o
2BO 1272.3 209.29 1.0330 0.8876 1.3597 59135 280 1272.7 209.31 1.0328 0.8876 1.3591 592.27 "tJ
::II
2B5
2B8.88
1254.7
1240.7
216.13
221.50
1.0572
1.0759
0.8941
0.8992
1.3758
1.3894
567.76
549.28
285
290
1255.2
1237.2
216.14
223.06
1.0570
1.0810
0.8941
0.9007
1.3750
1.3925
568.73
545.00
o"tJ
2B8.88 24.317 407.47 1.7196 0.8078 0.9761 145.76 294.72 1219.5 229.68 1.1037 0.9071 1.4108 522.34 m
::II
290 24.162 408.55 1.7234 0.8068 0.9722 146.29 294.72 29.154 410.57 1.7174 0.8259 1.0101 144.88 -t
295 23.509 413.38 1.7399 0.8049 0.9595 148.59 295 29.105 410.85 1.7184 0.8255 1.0088 145.03 m
en
300 22.908 418.16 1.7560 0.8058 0.9521 150.76 300 28.274 415.84 1.7352 0.8218 0.9914 147.50
305 22.352 422.91 :.7717 0.8085 0.9482 152.84 305 27.517 420.77 1.7515 0.8214 0.9806 149.82 ~.
310 21.834 427.64 :.7871 0.8125 0.9468 154.84 310 26.821 425.66 1.7673 0.8232 0.9741 152.03 .....
315 21.349 432.38 :.8022 0.8173 0.9470 156.76 315 26.175 430.52 1.7829 0.8265 0.9707 154.14 ':.&.
320 20.893 437.12 1.8171 0.8228 0.9485 158.61 320 25.574 435.37 1.7982 0.8307 0.9693 156.16 .....
325 20.462 441.87 :.8319 0.8286 0.9510 160.41 325 25.010 440.22 1.8132 0.8357 0.9695 158.11 ~
330 20.053 446.63 i.8464 0.8348 0.9541 162.16 330 24.479 445.07 1.8280 0.8411 0.9708 160.00 -t
m
335 19.666 451.41 :.8608 0.8413 0.9579 163.87 335 23.978 449.92 1.8426 0.8470 0.9730 161.82 -t
::II
340
345
19.297
18.945
456.21
461.03
1.8750
:.8891
0.8479
0.8547
0.9622
0.9668
165.53
167.15
340
345
23.504
23.054
454.80 1.8571
1.8713
0.8531
0.8594
0.9759
0.9795
163.60
165.32
-»
459.69 ."
350 18.609 465.8B 1.9030 0.8616 0.9718 168,74 350 22.625 464.59 1.8855 0.8659 0.9834 167.00 r-
c:
355 18.288 470.75 :.9169 0.8686 0.9771 170.29 355 22.217 469.52 1.8994 0.8726 0.9878 168.64 o
350 17.979 475.65 1.9306 0.8756 0.9826 171.81 360 21.826 474.47 1.9133 0.8794 0.9925 170.25 ::II
355 17.683 480.58 i.9442 0.8828 0.9883 173.30 365 21.453 479.45 1.9270 0.8863 0.9975 171.82 o
m
370 17.399 485.53 1.9576 0.8900 0.9941 174.77 370 21.094 484.45 1.9406 0.8932 1.0028 173.35 -t
:z:
375 17.125 490.52 1.9710 0.8972 1.0001 176.21 375 20.751 489.48 1.9541 0.9002 1.0082 174.86
»
3BO 16.861 495.53 1.9843 0.9045 1.0063 177.63 380 20.420 494.53 1.9675 0.9073 1.0139 176.34 zm
3B5 16.606 ~OO.5B 1.9975 0.9118 1.0126 179.03 385 20.102 499.62 1.9808 0.9144 1.0197 177.80
390 16.361 505.65 2.0106 0.9191 1.0189 180,40 390 19.796 504.73 1.9940 0.9216 1.0256 179.23 %
395 16.123 510.77 2.0236 0.9265 1.0254 181.76 395 19.500 509.87 2.0071 0.9288 1.0317 180.63 ."
400 15.894 515.91 2.0366 0.9338 1.0319 183.09 400 19.215 515.05 2.0201 0.9360 1.0379 182.02 9.....
410 15.456 526.30 2.0622 0.9485 1.0451 185,71 410 18.672 525.49 2.0459 0.9505 1.0505 184.73 (".)

420
430
440
15.045
14.657
14.291
536.82
547.47
558.26
2.0876
2.1126
2.1374
0.9633
0.9780
0.9927
1.0586
1.0722
1.0859
188,27
190,77
193.21
420
430
440
18.164
17.686
17.236
536.06
546.76
557.59
2.0714
2.0966
2.1215
0.9650
0.9796
0.9941
1.0634
1.0765
1.0898
187.36
189.93
192.44
-
~

450 13.944 569.19 2.1620 1.0074 1.0997 195,60 450 16.811 568.56 2.1461 1.0087 1.1033 194.90
460 13.616 580.26 2.1863 1.0220 1.1135 197.95 460 16.408 579.66 2.1705 1.0232 1.1168 197.30

......
.....
.....

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 TABLE 9. Thermodynamc properties of HFC-134a in the single-phase region Continued .......
I\)

T p h s __
Cv_ ~ w T p h s c, ~..!!::...
K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls K kglJI13 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

0.70 MPa 0.80 MPa

175 1578.3 77.866 0.4472 0.7911 1.1842 1096.4 175 1578.4 77.911 0.4471 0.7912 1.1841 1096.8
180 1565.1 83,793 0.4806 0.7914 1.1865 1071.0 180 1565.2 83.837 0.4805 0.7914 1.1864 1071.4
185 1551.8 89.733 0.5131 0.7928 1.1899 1045.7 185 1551.9 89.777 0.5130 0.7929 1.1898 1046.1
190 1538.5 95.694 0.5449 0.7951 1.1942 1020.5 190 1538.6 95.737 0.5448 0.7952 1.1941 1021.0
195 1525.0 101.67 0.5760 0.7982 1.1993 995.56 195 1525.2 101.72 0.5759 0.7982 1.1992 996.00
200 1511.5 107.68 0.6065 0.8017 1.2049 970.73 200 1511.7 107.73 0.6063 0.8017 1.2048 971.18
205 1497.9 113.72 0.6363 0.8057 1.2110 946.10 205 1498.1 113.76 0.6362 0.8057 1.2109 946.56
210 1484.2 119.79 0.6655 0.8100 1.2176 921.66 210 1484.4 119.84 0.6654 0.8100 1.2175 922.15
215 1470.4 125.90 0.6943 0.8146 1.2246 897.43 215 1470.6 125.94 0.6941 0.8146 1.2244 897.93
220 1456.5 132.04 0.7225 0.8194 1.2320 873.39 220 1456.7 132.08 0.7224 0.8194 1.2318 873.91 ;II
225 1442.4 138.22 0.7503 0.8244 1.2397 849.53 225 1442.6 I 138.26 0.7502 0.8244 1.2395 850.07 -f
230 1428.2 144.44 0.7776 0.8296 1.2478 825.84 230 1428.4 144.48 0.7775 0.8296 1.2476 826.40 ;=
235 1413.8 150.70 0.8046 0.8349 1.2564 802.29 235 1414.0 150.74 0.8044 0.8349 1.2561 802.88 r
Z
240 1399.2 157.00 0.8311 0.8403 1.2653 778.87 240 1399.5 157.04 0.8309 0.8403 1.2651 779.49 m
245 1384.5 163.35 0.8573 0.8458 1.2747 755.56 245 1384.7 163.39 0.8571 0.8458 1.2744 756.20 :u
250 1369.5 169.75 0.8831 0.8515 1.2846 732.33 250 1369.7 169.79 0.8830 0.8515 1.2843 733.01 :D
255 1354.2 176.20 0.9087 0.8572 1.2950 709.17 255 1354.5 176.23 0.9085 0.8572 1.2947 709.87
~
260 1338.7 182.70 0.9339 0.8631 1.3061 686.03 260 1339.0 182.73 0.9338 0.8631 1.3057 686.77 ::t:
265 1322.9 189.26 0.9589 0.8690 1.3178 662.90 265 1323.2 189.29 0.9587 0.8690 1.3174 663.67 »
Z
270 1306.7 195.88 0.9837 0.8751 1.3304 639.74 270 1307.1 195.91 0.9835 0.8751 1.3299 640.55
275· 616.51 1.3433 617.37
C
1290.2 202.57 1.0082 0.8813 1.3439 275 1290.6 202.59 1.0080 0.8812
280 1273.2 209.33 1.0325 0.8876 1.3584 593.18 280 1273.6 209.34 1.0323 0.8875 1.3578 594.10 ;t
285 1255.7 216.16 1.0567 0.8940 1.3743 569.71 285 1256.2 216.17 1.0565 0.8940 1.3735 570.68 !='
290 1237.7 223.07 1.0808 0.9006 1.3916 546.03 290 1238.2 223.08 1.0805 0.9006 1.3908 547.07 OJ
295 1219.0 230.08 1.l047 0.9074 1.4109 522.10 295 1219.6 230.08 1.1045 0.9073 1.4098 523.21 »
m
299.86 1200.1 236.99 1.1280 0.9142 1.4318 498.52 300 1200.2 237.19 1.1283 0.9143 1.4312 499.04
::t:
299.86 34.053 413.19 1.7156 0.8421 1.0428 143.90 304.47 1182.2 243.64 1.1497 0.9208 1.4526 477.05 :u
300 34.024 413.33 1.7161 0.8419 1.0421 143.97 304.47 39.025 415.45 1.7140 0.8570 1.0750 142.84
305 33.007 418.49 1.7331 0.8370 1.0206 146.60 305 38.890 416.02 1.7158 0.8561 1.0717 143.14
310 32.087 423.55 1.7496 0.8357 1.0069 149.07 310 37.684 421.31 1.7330 0.8505 1.0471 145.91
315 31.246 428.57 1.7656 0.8368 0.9982 151.39 315 36.598 426.50 1.7497 0.8487 1.0310 148.49
320 30.470 433.54 1.7813 0.8395 0.9930 153.61 320 35.610 431.63 1.7658 0.8493 1.0205 150.92
325 29.749 438.50 1.7967 0.8433 0.9902 155.72 325 34.702 436.71 1.7816 0.8516 1.0138 153.23
330 29.076 443.45 1.8118 0.8479 0.9892 157.76 330 33.861 441.77 1.7970 0.8551 1.0098 155.43
335 28.444 448.40 1.8266 0.8530 0.9895 159.72 335 33.079 446.81 1.8122 0.8594 1.0077 157.54
340 27.850 453.35 1.8413 0.8585 0.9909 161.61 340 32.346 451.85 1.8271 0.8642 1.0071 159.56
345 27.288 458.31 1.8558 0.8644 0.9930 163.45 345 31.658 456.89 1.8418 0.8695 1.0077 161.52
350 26.756 463.28 1.8701 0.8705 0.9959 165.23 350 31.009 461.93 1.8563 0.8752 1.0092 163.41
355 26.250 468.27 1.8842 0.8768 0.9993 166.96 355 30.396 466.98 1.8707 0.8811 1.0115 165.24
360 25.769 473.27 1.8983 0:8832 1.0031 168.65 360 29.8]4 472.05 1.8848 0.8872 1.0143 167.03
365 25.310 478.30 1.9121 0.8898 1.0073 170.30 365 29.260 477.13 1.8988 0.8935 1.0177 168.76
370 24.871 483.35, 1.9259 0.8965 1.0119 171.91 370 28.733 482.22 1.9127 0.8999 1.0215 170.45
375 24.451 488.42 1.9395 0.9033 1.0167 173.49 375 28.230 487;34 1.9265 0.9065 1.0256 172.10

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 T"BLE 9. Thermodynamic properties (jf HFC-134a in the single-phase region - Continued
-- ----- --~-- - - - -~ ~----- -- ------ - - - -

T p h 8 w T p h s ~ w
Cv
~ Cv
K kg/m3 kJ/tg kJi(kgK) kJ/(kgK) kJ/(kgK) mls K kg/m J kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

0.70 MPa 0.80 MPa

-I
::J:
380 24.049 493.51 1.9530 0.9102 1.0218 175.04 380 27.749 492.48 1.9401 0.9131 1.0301 173.71 m
385 23.662 175.29
::0
498.64 1.9664 0.9171 1.0271 176.55 385 27.289 497.64 1.9536 0.9199 1.0349
3:
390 23.290 503.79 1.9797 0.9241 1.0326 178.04 390 26.846 502.83 1.9670 0.9267 1.0398 176.83 o
395 22.932 508.96 1.9928 0.9312 1.0382 179.50 395 26.422 508.04 1.9802 0.9336 1.0450 178.35 c
400 22.587 514.17 2.0059 0.9382 1.0440 180.93 400 26.013 513.28 1.9934 0.9405 1.0504 179.84 -<
z
410 21.933 524.67 2.0319 0.9525 1.0560 183.73 410 25.241 523.84 2.0195 0.9544 1.0617 182.73 »
420 21.322 535.29 2.0575 0.9668 1.0683 186.45 420 24.521 534.52 2.0452 0.9685 1.0734 185.54 3:
430 20.750 546.04 2.0827 0.9811 l.081O 189.10 430 23.849 545.31 2.0706 0.9827 1.0855 188.26 (5
440 20.211 556.91 2.1077 0.9955 1.0939 191.67 440 23.218 556.23 2.0957 0.9969 1.0980 190.90 -0
::0
450
460
19.704
19.224
567.92
579.05
2.1325
2.1570
1.0099
1.0243
1.l069
1.1202
194.19
196.64
450
460
22.624
22.064
567.27
578.44
2.1205
2.1451
1.0112
1.0254
1.1107
1.1236
193.47
195.99
o-0
m
::0
-I
100 MPa 1.20 MPa iii
(J)

175 1578.7 78.001 0.4469 0.7912 1.1839 1097.5 175 1578.9 78.090 0.4467 0.7913 1.1838 1098.3 o
."
180 1565.5 83.926 0.4803 0.7915 1.1862 1072.2 180 1565.7 84.015 0.4800 0.7916 1.1861 1073.0 ....
185 1552.2 89.865 0.5128 0.7929 1.1896 1046.9 185 1552.5 89.953 0.5126 0.7930 1.1895 1047.7 -.
190 1538.9 95.824 0.5446 0.7952 1.1939 1021.8 190 1539.2 95.911 _0.5444 0.7953 1.1937 1022.6 ....
195 1525.5 101.8D 0.5757 0.7982 1.1989 996.86 195 1525.8 101.89 0.5754 0.7983 1.1987 997.72 ~
200 1512.0 107.81 0.6061 0.8018 1.2045 972.07 200 1512.3 107.90 0.6059 0.8018 1.2043 972.97 -I
m
205 1498.4 113.85 0.6359 0.8058 1.2106 947.49 205 1498.8 113.93 0.6357 0.8058 1.2104 948.42 -I
::0
210
215
1484.8
1471.0
119.92
126.02
0.6652
0.6939
0.8101
0.8147
1.2172
1.2241
923.11
898.93
210
215
1485.1
1471.3
120.00
126.10
0.6649
0.6936
0.8101
0.8147
1.2169
1.2238
924.07
899.93
»
."
220 1457.1 132.16 0.7221 1.2315 874.95 220 1457.5 132.24 0.7219 0.8195 1.2311 875.99 r'"
0.8195 c:
225 1443.0 138.34 0.7499 0.8245 1.2392 851.15 225 1443.4 . 138.41 0.7496 0.8245 1.2388 852.23 o
::0
230 1428.8 144.55 0.7772 0.8296 1.2472 827.53 230 1429.3 144.63 0.7769 0.8297 1.2468 828.65
235 1414.5 150.81 0.8041 0.8349 1.2557 804.05 235 1415.0 150.88 0.8038 0.8350 1.2553 805.22 om
240
245
1400.0
1385.2
157.11
163.46
0.8306
0.8568
0.8403
0.8459
1.2646
1.2739
780.71
757.48
240
245
1400.5
1385.8
157.18
163.53
0.8303
0.8565
0.8404
0.8459
1.2641
1.2733
781.93
758.76 5!
»
250 1370.3 169.85 0.8827 0.8515 1.2837 734.34 250 1370.9 169.92 0.8823 0.8515 1.2830 735.68 z
m
255 1355.1 176.30 0.9082 0.8572 1.2940 711.27 255 1355.7 176.36 0.9078 0.8572 1.2933 712.67
260 1339.7 182.79 0.9334 0.8631 1.3049 688.24 260 1340.3 182.85 0.9331 0.8631 1.3041 689.70 3:
."
265 J323.9 189.35 0.9584 0.8690 1.3165 665.22 265 1324.6 189.40· 0.9580 0.8690 1.3156 666.76
270 1307.8 195.96 0.9831 0.8750 1.3289 642.18 270 1308.5 196.01 0.9827 0.8750 1.3279 643.80 9
....
275 1291.4 202.64 . 1.0076 0.8812 1.3422 619.09 275 1292.1 202.68 1.0072 0.8812 1.3410 620.80 ~

t
280
285
290
1274.5
1257.1
1239.2
209.38
216.20
223.11
1.0319
1.0561
1.0801
0.8875
0.8939
0.9005
1.3565
1.3720
1.3890
595.91
572.60
549.12
280
285
290
1275.3
1258.0
1240.2
209.42
216.24
223.13
1.0315
1.0556
1.0796
0.8874
0.8938
0.9004
1.3552
1.3705
1.3873
597.72
574.52
551.15
-
295 1220.7 230.10 1.1040 0.9072 1.4078 525.40 295 1221.8 230.11 1.1035 0.9071 1.4057 527.57
300 ]201.5 237.19 1.1278 0.9142 1.4287 501.39 300 1202.7 237.19 1.1273 0.9140 1.4263 503.72
305 ]181.4 244.39 1.1516 0.9213 1.4523 477.00 305 1182.8 244.38 1.1510 0.9211 1.4494 479.51 ......
....
310 1160.4 251.72 1.1754 0.9288 1.4794 452.14 310 1161.9 251.69 1.1748 0.9285 1.4758 454.86 c".)

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~
TABLE 9. Thennodynamic properties of HFC-134a in the single-phase region - Continued
.....
.....
"
:T
~ T
-- ~-
~

p h s Cv
---EL- w T p h s Cv
~
w
o
:T K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kg1C) mls K kglm3 kJ/kg kJ/(kgK) kJJ(kgK) kJ/(kgK) mls
CD
? 1.00 MPa 1.20MPa
:D
~
C 312.53 1149.3 255.49 1.1876 0.9327 1.4948 439.30 315 1139.9 259.15 1.1987 0.9362 1.5065 429.65
~ 312.53
315
49.222
48.366
419.16
421.94
1.7112
1.7201
0.8836
0.8789
1.1391
1.1200
140.53
142.11
319.46
319.46
Q19.1
59.814
265.94
422.04
1.2201
1.7087
0.9434
0.9074
1.5388
1.2052
406.54
138.06
<
~ 320 46.785 427.46 1.7375 0.8732 1.0916 145.10 320 59.558 422.68 1.7107 0.9060 1.1993 138.45
I\) 325 45.374 432.87 1.7543 0.8712 1.0725 147.88 325 57.358 428.56 1.7289 0.8964 1.1554 141.89
~
330 44.097 438.20 1.7705 0.8716 1.0594 150.48 330 55.435 434.26 1.7463 0.8918 1.1260 145.03
z
? 335 42.929 443.47 1.7864 0.8736 1.0506 152.93 335 53.723 439.83 1.7631 0.8903 1.1058 147.93
,91 340 41.854 448.71 1.8019 0.8767 1.0448 155.26 340 52.178 445.33 1.7794 0.8909 1.0916 150.64
cD 345 40.856 453.92 1.8171 0.8806 1.0411 157.49 345 50.769 450.76 1.7952 0.8930 1.0816 153.20
CD
~ 350 39.927 459.12 1.8321 0.8851 1.0392 159.63 350 49.475 456.15 1.8107 0.8961 1.0747 155.63 ?:J
355 39.056 464.32 1.8468 0.8901 1.0385 161.68 355 48.277 461.51 1.8260 0.8999 1.0701 157.94 -t
360
365
38.237
37.465
469.51
474.71
1.8614
1.8757
0.8954
0.9011
1.0390
1.0402
163.67
165.59
360
365
47.163 466.85 1.8409
1.8556
0.9043
0.9091
1.0672
1.0658
160.15
162.28
r=r-
46.121 472.18
Z
370 36.735 479.91 1.8899 0.9069 1.0422 167.44 370 45.144 477.51 1.8701 0.9143 1.0654 164.33 m
375 36.042 485.13 1.9039 0.9129 1.0448 169.25 375 44.223 482.84 1.8844 0.9197 1.0660 166.31 ::D
380 35.383 490.36 1.9177 0.9191 1.0478 171.01 380 43.354 488.17 1.8985 0.9254 1.0674 168.22 :iJ
385 34.755 495.61 1.9315 0.9255 1.0513 172.72 385 42.530 493.52 1.9125 0.9313 1.0694 170.08 ~
390 34.156 500.88 1.9450 0.9319 1.0552 174.39 390 41.747 498.87 1.9263 0.9373 1.0719 171.88 :E:
395 33.583 506.16 1.9585 0.9384 1.0594 176.02 395 41.003 504.24 1.9400 0.9434 1.0749 173.64 »
400 33.033 511.47 1.9719 0.9450 1.0639 177.62 400 40.292 509.62 1.9535 0.9497 1.0783 175.35 Z
C
410 32.000 522.16 1.9983 0.9585 1.0735 180.71 410 38.964 520.44 1.9803 0.9626 1.0862 178.66
420 31.044 532.95 2.0242 0.9721 1.0839 183.69 420 37.743 531.35 2.0065 0.9757 1.0951 181.82 ;t:
430 30.155 543.84 2.0499 0.9859 1.0950 186.56 430 36.614 542.35 2.0324 0.9891 1.l049 184.86 !='
440 29.326 554.85 2.0752 0.9998 1.l065 189.35 440 35.567 553.45 2.0579 1.0026 1.1154 187.79 m
450 28.549 565.97 2.1002 1.0137 l.I184 192.05 450 34.589 564.66 2.0831 1.0163 1.1264 190.62 »
m
460 27.818 577.22 2.1249 1.0277 1.1305 194.67 460 33.675 575.98 2.1080 1.0300 1.1378 193.36 :E:
::D
1.40 MPa 1.60 MPa

175 1579.2 78.180 0.4465 0.7913 1.1836 1099.0 175 1579.4 78.270 0.4462 0.1914 1.1835 1099.8
180 1566.0 84.104 0.4798 0.7916 1.1859 1073.7 180 1566.3 84.193 0.4796 0.1917 1.1857 1074.5
185 1552.8 90.042 0.5124 0.7930 1.1893 1048.5 185 1553.0 90.130 0.5122 0.1931 1.1891 1049.3
190 1539.5 95.999 0.5441 0.7954 1.1935 1023.5 190 1539.8 96.086 0.5439 0.7954 1.1934 1024.3
195 1526.1 101.97 0.5752 0.7984 l.I985 998.58 195 1526.4 102.06 0.5750 0.1984 1.1983 999.44
200 1512.6 107.98 0.6056 0.8019 1.2041 973.86 200 151.3.0 108.07 0.6054 0.8020 1.2038 974.75
205 1499.1 114.02 0.6354 0.8059 1.2101 949.34 205 1499.4 114.10 0.6352 0.8059 1.2099 950.26
210 1485.5 120.08 0.6647 0.8102 1.2166 925.03 210 1485.8 120.17 0.6644 0.8102 1.2164 925.99
215 1471.7 126.18 0.6934 0.8148 1.2235 900.93 215 1472.1 126.26 0.6931 0.8148 1.2232 901.92
220 1457.9 132.32 0.7216 0.8196 1.2308 877.02 220 1458.2 132.40 0.7213 0.8196 1.2305 878.05
225 1443.9 138.49 0.7493 0.8246 1.2384 853.31 225 1444.3 138.57 0.7491 0.8246 1.2381 854.38
230 1429.7 144.70 0.7766 0.8297 1.2464 829.77 230 1430.2 144.78 0.7764 0.8297 1.2460 830.88
235 1415.4 150.96 0.8035 0.8350 1.2548 806.39 235 1415.9 151.03 0.8033 0.8350 1.2544 807.55
240 1401.0 157.25 0.8301 0.8404 1.2636 783.15 240 1401.4 157.33 0.8298 0.8404 1.2631 784.36

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 TABLE 9. Thennodynamic properties of HFC-134a in the single-phase region Continued

T p h s __
Cv_ ~ w T p h s Cv C~ w
K kglm3 kJfkg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls K kg/m3 kllkg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

1.40 MPa 1.60 MPa

-t
::I:
245 1386.3 163.60 0.8562 0.8459 1.2728 760.03 245 1386.8 163.66 0.8559 0.8459 1.2722 761.29 m
250 1371.4 169.98 0.8820 0.8515 1.2824 737.00 250 170.05 0.8515 1.2819 738.32
:::D
1372.0 0.8817
3:
255
260
1356.3
1340.9
176.42
182.9;
0.9075 0.8572 1.2926 714.06 255 1356.9 116.48 0.9072 0.8572 1.2920 715.44 oc
0.9327 0.8631 1.3034 691.16 260 1341.6 132.97 0.9324 0.8631 1.3026 692.61
265 1325.3 189.46 0.9576 0.8690 1.3148 668.29 265 1325.9 189.51 0.9573 0.8690 1.3140 669.81 -<
z
2iD 1309.3 196.06 0.9823 . 0.8750 1.3269 645.41 270 1310.0 196.11 0.9820 0.8750 1.3260 647.01 »
2i5 1292.9 202.73 1.0068 0.8811 1.3399 622.50 275 1293.7 202.77 1.0064 0.8811 1.3389 624.18 3:
280 1276.2 209.46 1.0311 0.8874 1.3539 599.51 280 1277.0 209.50 1.0307 0.8873 1.3527 601.29 o
285 1259.0 216.27 1.0552 0.8938 1.3691 576.42 285 1259.9 216.30 1.0547 0.8937 1.3677 578.31 "'0
:::D
290
295
1241.2
1222.9
223.16
230.13
1.0791
1.1030
0.9003
0.9070
1.3856
1.4038
553.17
529.73
290
295
1242.2
1224.0
223.18
~30.15
1.0787
1.l025
0.9002
0.9068
1.3839
1.4018
555.18
531.86
o"'0
3eO 1203.9 237.20 1.1267 0.9138 1.4239 506.02 300 1205.1 237.20 1.1262 0.9137 1.4216 508.31 m
:::D
3C5 1184.2 244.37 1.1504 0.9209 1.4466 481.99 305 1185.5 244.37 1.1499 0.9207 1.4438 484.44 -t
310 1163.5 251.67 1.1742 0.9282 1.4724 . 457.54 310 1165.0 251.65 1.1735 0.9280 1.4690 460.19 iii
315 1 ~ 41.7 259.10 1.1980 0.9359 1.5022 432.57 315 1143.4 259.06 1.1973 0.9356 1.4980 435.46 en
320 L18.5 266.70 1.2219 0.9439 1.5375 406.94 320 1120.5 266.64 1.22 II 0.9435 1.5322 410.10 o'"11
325 1093.8 274.49 1.2460 0.9524 1.5804 380.42 325 1096.0 274.40 1.2452 0.9519 1.5734 383.93 ....
325.57 1090.8 275.~ 1.2488 0.9534 1.5859 377.32 330 1069.6 282.39 1.2696 0.9610 1.6248 356.68 :...
325.57 70.870 424.29 1.7062 0.9292 1.2756 135.47 331.05 1063.7 284.11 "1.2748 0.9630 1.6374 350.75 :...
330 68.277 429.81 1.7230 1.2216 331.05 426.04 0.9496 132.78 i\)
0.9179 138.91 82.464 1.7035 1.3527 I
335 65.748 435.8] 1.7410 0.9109 1.1804 142.42 335 79.481 431.24 1.7191 0.9375 1.2892 136.20 -t
m
340 63.534 441.6L 1.7583 0.9078 1.1522 145.62 340 76.253 437.54 1.7378 0.9284 1.2348 140.08 -t
345 61.562 :::D
350 59.783
447.35
452.97
1.7750
1.7912
0.9072
0.9083
1.1322
1.1179
148.59
151.37
345
350
73.473
71.029
443.62
449.54
1.7556
1.7726
0.9239
0.9222
1.1979
1.1719
143.58
146.79
»
'"11
355 58.161 458.53 1.8069 0.9106 1.1075 153.98 355 68.847 455.35 1.7891 0.9225 1.1531 149.78 r
C
360 56.673 464.05 1.8224 0.9138 I.IOO2 156.47 360 66.874 461.08 1.8051 0.9242 1.1393 152.57 o
:::D
365 55.296 469.54 1.8375 0.9177 1.0951 158.83 365 65.074 466.75 1.8207 0.9269 1.1293 155.21
370 54.016 475.00 1.8524 0.9220 1.0918 161.09 370 63.420 472.38 1.8361 0.9303 1.1219 157.72 o
m
375 52.821 480.46 1.8670 0.9268 1.0898 163.26 375 61.890 477.97 1.8511 0.9343 1.1168 160.10 -t
::I:
300
385
51.700
50.645
485.91
491.35
1.8815
1.8957
0.9319
0.9373
1.0890
1.0892
165.35
167.37
380
385
60.467
59.137
483.55
489.11
1.8658
1.8804
0.9387
0.9435
1.1133
1.1112
162.38
164.58
»
Z
390 49.648 496.80 1.9098 0.9428 1.0901 169.32 390 57.890 494.66 1.8947 0.9486 1.l102 166.69 m
395 48.705 502.25 1.9237 0.9486 1.0917 171.21 395 56.716 500.21 1.9089 0.9539 1.1101 168.72 X
'"11
4C0 47.810 507.72 1.9374 0.9545 1.0939 173.04 400 55.608 505.76 1.9228 0.9595 1.l108 170.69
410 46.146 518.68 1.9645 0.9668 1.0997 176.57 410 53.562 516.89 1.9503 0.9711 1.1142 174.46 9
....
420 44.628 529.72 1.9911 0.9794 1.1069 179.93 420 51.710 528.05 1.9772 0.9832 I.ll95 178.02 ~
~
430 43.233 540.83 20172 0.9924 1.1153 183.14 430 50.021 539.28 2.0036 0.9957 1.1264 181.40
440 41.946 552.03 20430 1.0055 1.1247 186.22 440 48.470 550.59 2.0296 1.0085 1.1344 184.64
~
450 40.750 563.32 20683 1.0189 1.1347 189.18 450 47.037 561.98 2.0552 1.0215 1.1434 187.75
460 39.636 574.72 20934 1.0324 1.1453 192.05 460 45.706 513.46 2.0804 1.0347 l.IS31 190.74

....
~

<n

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 ......
.....
TABLE 9. Thennodynamic properties of HFC-134a in the single-phase region Continued
0)

T p h s __
Cv_ ~ w T p h Cv
--..E2.- ~
K kg/m 3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls K kglm3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/t:kgK) mls

1.80 MPa 2.00 MPa

175 1579.7 78.360 0.4460 0.7915 1.1833 1100.5 175 1579.9 78.449 0.4458 0.79[5 U832 1101.3 .
180 1566.5 84.282 0.4794 0.7917 1.1856 1015.3 180 1566.8 84.371 0.4792 0.79[8 1.1854 1076.1
185 1553.3 9~.218 0.5119 0.7932 1.1889 1050.1 185 1553.6 90.306 0.5117 0.7932 U888 1050.9
190 1540.0 95.173 0.5437 0.7955 1.1932 1025.1 190 1540.3 96.260 0.5435 0.7955 1.1930 1025.9
195 1526.7 102.15 0.5748 0.7985 1.1981 1000.3 195 1527.0 102.23 0.5745 0.7985 1.[979 1001.1
200 1513.3 IOB.15 0.6052 0.8020 1.2036 91 5.63 200 1513.6 108.24 0.6049 0.8021 1.2034 976.52
205 1499.8 114.18 0.6349 0.8060 1.2096 951.18 205 1500.1 114.27 0.6347 0.8060 1.2094 952.10
210 1486.2 12().25 0.6642 0.8103 1.2161 926.94 210 1486.5 120.33 0.6639 0.8103 1.2158 927.89
215 1472.5 126.35 0.6929 0.8149 1.2229 902.91 215 1472.8 126.43 0.6926 0.8149 1.2226 903.90
220 1458.6 132.48 0.7211 0.8197 1.2302 879.08 220 1459.0 ,132.56 0.7208 0.8197 1.2298 880.11 ;0
225 1444.7 13B.65 0.7488 0.8246 1.2377 855.45 225 1445.1 138.73 0.7485 0.8247 1.2374 856.51 -I
230 1430.6 144.86 0.7761 0.8298 1.2456 832.00 230 1431.0 144.93 0.7758 0.8298 1.2453
1.2535
833.10
809.86
r=r-
235 1416.4 151.11 0.8030 0.8351 1.2539 808.71 235 1416.8 151.18 0.8027 0.8351
Z
240 1401.9 151.40 0.8295 0.8404 1.2626 785.56 240 1402.4 157.47 0.8292 0.8405 1.2621 786.77 m
245 1387.3 163.73 0.8556 0.8459 1.2717 762.55 245 1387.8 163.80 0.8553 0.8460 1.2712 763.80 :D
250 1372.5 170.12 0.8814 0.8516 1.2813 739.64 250 1373.1 170.18 0.8811 0.8516 1.2807 740.95 :D
255 1357.5 176.55 0.9068 0.8573 1.2913 716.82 255 1358.1 176.61 0.9065 0.8513 1.2907 718.19 o
-I
260 1342.2 183.03 0.9320 0.8631 1.3019 694.05 260 1342.8 183.09 0.9317 0.8631 1.3012 695.49 :J:
265 1326.6 189.57 0.9569 0.8689 1.3131 671.32 265 1327.3 189.62 0.9566 0.8689 1.3123 672.83 >
Z
270 1310.7 196.16 0.9816 0.8749 1.3251 648.60 270 1311.4 196.21 0.9812 0.8749 1.3241 650.18
1.3367 627.53
C
275 1294.5 202.82 1.0060 0.8811 1.3378 625.86 275 1295.3 202.87 1.0056 0.88:0
280 1277.9 209.54 1.0302 0.8873 1.3515 603.06 280 1278.7 209.58 1.0298 0.8812 1.3503 604.82 ;z:
285 1260.8 216.34 1.0543 0.8936 1.3663 580.18 285 1261.7 216.37 1.0539 0.8935 1.3649 582.04 P
290 1243.2 223.21 1.0782 0.9001 1.3823 557.16 290 1244.2 223.24 1.0777 0.9000 1.3807 559.14 a:J
295 1225.1 230.16 1.l020 0.9067 1.3999 533.98 295 1226.2 230.18 1.1015 0.9066 1.3981 536.07 >
m
300 1206.3 231.21 1.1257 0.9135 1.4194 510.57 300 1207.5 237.22 1.1251 0.9134 1.4172 512.80 :J:
305 1186.8 244.36 1.1493 0.9205 1.4411 436.87 305 1188.1 244.36 1.1487 0.9204 1.4385 489.27 :D
310 1166.5 251.63 1.1729 0.9278 1.4657 462.81 310 1167.9 251.61 1.1723 0.9276 1.4625 465.39
315 1145.0 259.03 1.1966 0.9353 1.4940 438.30 315 1146.7 258.99 1.1959 0.9350 1.4900 441.10
320 1122.4 266.58 1.2204 0.9432 1.5270 413.21 320 1124.3 266.52 1.2196 0.9428 1.5221 416.27
325 1098.2 274.31 1.2444 0.9514 1.5667 387.37 325 1100.4 274.22 1.2435 0.95:0 1.5603 390.75
330 1072.2 282.26 1.2686 0.9603 1.6157 360.54 330 1074.7 282.14 1.2677 0.9597 1.6071 364.32
335 1043.6 29~.49 1.2934 0.9701 1.6791 332.32 335 1046.7 290.31 1.2923 0.9692 1.6670 336.63
336.04 1037.3 292.25 1.2986 0.9722 1.6950 326.18 340 1015.5 298.84 1.3176 0.9800 1.'1482 307.08
336.04 94.681 427.35 1.7007 0.9690 1.4393 130.00 340.63 1011.3 299.95 1.3208 0.98:4 l.1606 303.17
340 90.885 432.87 1.7170 0.9548 1.3568 133.80 340.63 107.62 428.28 1.6975 0.9878 1.5389 127.16
345 86.873 43~.47 1.7363 0.9441 1.2881 138.04 345 102.38 434.72 1.7164 0.9700 1.4224 131.78
350 83.474 445.79 1.7545 0.9385 1.2423 141.82 350 97.518 441.61 1.7362 0.9582 1.3391 136.34
355 80.521 451.92 1.7718 0.9360 1.2101 145.27 355 93.460 448.16 1.7548 0'.9518 1.2844 140.38
360 77.909 457.91 1.7886 0.9357 1.1869 148.44 360 89.973 454.48 1.7724 0.9487 1.2463 144.03
365 75.565 463.80 1.8048 0.9369 1.1697 151.40 365 86.914 460.64 1.7894 0.9480 1.2188 147.38
370 73.441 469.61 1.8207 0.9392 1.1570 154.19 370 84.188 466.68 1.8059 0.9488 1.1984 150.49
375 71.498 475.37 1.8361 0.9422 1.1475 156.82 375 81.730 472.64 1.8219 0.9507 U832 153.40

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 TAB~ 9.Tlu~rIIlcxlYnaihicpr()perties of lIFC-134a in the single-phaSe'region - Contillhed
- -

'",

'T h s ' 'w T p h s ,c" w

t" ----EL- ~
K kg rm3 kJlkg kJ/(kgK) kN(kgK) kJ/(k.gJ<:) m1s K kg/m3 kJtkg kJ/(kg~) kJ/(kgK) kJ/(kgK) lnIs

1~80 MPa 2~~MPa -I

.. :::E:
380' 69~709 481.0'9 1.8513 0'.9459 1.1406 159.32 380' ,79.494 478.52 1.8374 O'~9534 1.17J8 156.14 m
385 68.652 486.78 L8662 b.9500 1.1356 161.70' 385 77,.,442 484.~6 1.8527 {)'9569 1.1632, 158.74
:a
3i:
390' '66'.509 492A5 1.880'8 b~9546 1.1323 163.99 390 75.548 490.i6 i.8~77 0'.9608 1.1568 161.21 o
498.1 r 4~S·.93
~
395 65.0'66 1~8952 0'.9594 1.13O'2 i66.18 395 ' '73:.790 1.8824 0'.9651 1.1523 163.58
400 63.712 50'3.75 1.90'94 0.9646 1.1292 168.29 409 72.150' 50'1.68 1.8969 0'.9698: 1.1492 ~65~85 z
410 61;230' 515;0'5 1.9373 0'.9754 1.1297 17231 410 69.170' 513.16 1:-9252 0'.9799 1.1464 170..I3 »
=:,
420' 59.0'0'3 526;36 1.9645 q.987O' 1.1328 1,1~,·~ 420' 66.521 524.62 1.9528 0'.990'9 1.1471 ,I74.14
430' ' 56.986 537.71 1.9913 0'.999.0' 1.1380' 179.66 430' 64.139 53:6.1r 1~9798 1.0024 U5O'3 177.91 o
440 55.145 549.12 2.0'175 1.0'114 1.1446 183.06 440 61.979 547.64 2.,0%3 1.0'144 1.1553 181.47 "tJ
:D
450'
460
53.453
51.889
560'.61
572.18
2.0'433
2.0687
1.0'241
1.0'371
1.1524
1.1612
186.31
189.43
450'
460'
6Q.CQ4
58.188
559.22
570'.88
2.0'324
2.0'580'
1.0'268
I.O'~Q5
1.1619
1.1695
184.87
188.12
o
"tJ
m
'I
::b
2.S0 MPa 3.00,MPa -I
in
175 1580'.5 78.674 0'.4453 O'.~917 1.1828 1103.1 175 158'1.2 ' 78.899 0'.4448 0'.791,8; 1.1824 1105.0' en
180' 1567.4 84.593 0.4787 0'.7920' l.1850 1078.0. i8O' 1568.1 84.816 0'.4781 0'.7921 1.184? 1079.9; o
."
185 1554.3 90'.526 0.5112 ().7934 1.18~3 1052.9 185 1554.9' 90.747 0.5'1~ 0'.7935 1.1879 10'54.9' ~
190' 1541.0' 96.478 0'.5429 0'.7957 1.1925 1028.0' 190' 1541.7 96~697 0'.5424 0'.7958 1.1920' lQ3O'.O', :...
195 1527.7 102.45 0'.5739 0'.7987 1.1974 1003.2 195 1528.5 102.66 0.5734 0".7988 1.1969' 1005.3 ~
i\)'
200 1514.4 10'8.45 0'.6043 0'.80'22 1.20'28 978.72 200 1515.2 108.66 0'.60'38 0.80'23 1.2023 980'.,91 I"

20'5 1500.9 114.48 0'.6341 0'.8062 1.20'88 954.38 20'5 150'1.7 11.4.69 0'.6335 0'.8963, 1.20'82 956;,65, -I
m
210 1487.4 120'.54 0'.6633 0'.8105 1.2152 930'.26 210 1488.2 120'.75 0'.6627 0'.8106 1.2145: 932.61 -I
:D
215
220'
1473.7
1460'.0'
126~63
132j6
0'.6920'
0'.720'2
0'.8150'
0'.8198
1.2219
1.2290'
906.35
882.66
215
220'
1474.6
1460.9
12,6.8~
13'2.96
0'.691'4
0'.7(95
~.8152
0'.8199
1.2212
1•.2 f 82
QOK7Q
885,..19 ..,r
'J>
225 1446.1 138.92 0'.7479 0'.8248 1.:i365 859.16 225 1447.1 139.12 0'.7472 0'.8249 1.2356 861.79 c:
230 1432.1 145~12 0.7751 0'.8299 1.2443 835.86 230' 143:b 14;5.32 0'.7744; O'.8~OO 1.2434 838.59 o:D
~ 235 1417.9 151.37 0'.80'20' 0'.8352 1.2525 812.73 235 1419.1 151.55 0'.8013 0.8353 L2?14 815.57
240 ;
0,
"
~

~ 245'
1403.6
1389.1
157.65
163.98
0'.8284
0'.8545
0'.8405
0.8460
1.2610
1.2699
7~9.75
766.92
240
245
1404.8
1399.4
157.83
164.15
0'.8277
0'.853,8
0.8406
0'.8461
1;2598
1.2686
792.71
770.00
m
-I
:::E:
o
~
250'
255
1374.4'
1359.5
170.35
176.77
0'.880'3
0'.9057
0'.8516
'0'.8573
1.2792
1.2891
744.20
721.59
250'
255
1375.8
1361.0
170'.52
176.93
0'.8795
0'.9049
0.8517
0'.8573
1.2778
1.2875,
747.42
724.95
»
Z
CD
~ 260 1344.4 183.24 0'.9308 0'.8631 1.2994 699.0'5 260 1345.9 1'83.39 0'.9300 0'.8631 1.2976 702.56 m
::0 265 1328.9 189.77 0.9557
.' ,"-.
0'.8689 1.3103 6~6.56 265 1330'.6 189.91 0'.9548 0.8689 1.3083 68{}.24 %
~
c
270'
275
1313.2
1297.2
196.35
20'2.99
0'.980'3
1.0047
(18749
O'~8809
1.3219
1.3342
654.10
631.65
270'
275
1315.0
1299.1
196.48
203.11
0'.9794
i.OO37
0'.8748
0'.880'9
1.3197
1.3317 ..
657.97
635.71 "
....9
J<
,
i -~. ," :

280 128O'~8 2O'9~69 1.0'288 O.887i 1.3474 609.17 280' 1282.8 209.80 1.0'278 0.8870' 1.3445 613.44' (,.)
..a:..
~
~
285
290
295
1263.9
1246.7
1228.8
216.46
223.31
230'.23
1.052~
u)166
1.1003
0'.8934
0'.8998
0'.9064
1.3615
1.3769
1.3936
586.63
564.00
541.24
285
290'
295
1266.1
1249.0
1231.4
216.56
223.38
230.29
1.0'517
1.0755
1.0991
0'.8933
,0'.89.96
0.9061
1.3583
1.3732
1.389~
591.14
568.77
546.30
-
»

z 300 1210:4 237.25 1.1238 O'~9131 '104119 518.31 300 1213J 237.28 1.1226 0.9.28 'l;4()69 523.69
!' 305 1191.4 244.36 1.1473 0'.9199 1.4322 495.16 305 1l94.~ 244.36 1.1460 0'.9196 ,J.4263 500.90
.!"
-a.
310 1171.5 251.57 1.170'8 0'.9270 1.4550' 471.72 310 1175.0 251.55 1.1694 0'.9266 1.4479 477.88 .....
....
CO 315 1150'.7 258.91 1.1943 0'.9344 1.480'8 447.94 315 1154.6 258j~5 1.1927 0'.9338 1.4722 454.56 .....
~

Downloaded 22 Feb 2013 to 132.203.235.189. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
~ ......
......
'U TABLE 9. Thennodynamic properties of HFC-134a in the single-phase region - Continued
:T 0)

~
-- ------ -~

T P h s w T h w
C')
Cu ~ P oS Cu ~
:T K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) m/s K kglm 3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/CkgK) mls
CD
~
:u 2.50 MPa 3.00MPa
~
cQ) 320 1128.8 266.39 1.2178 0.9420 1.5HJ5 423.71 320 1133.2 266.27 1.2161 0.9412 1.5000 430.88
pr 325 1105.7 274.03 1.2415 0.9499 1.5455 398.92 325 1110.7 273.85 1.2396 0.9490 1.5322 406.74
330 1080.9 28i.85 1.2654 0.9584 ·1.5876 373.39 330 1086.6 281.61 1.2633 0.9571 1.5704 382.01
<
~ 335 1054.0 289.92 1.2897 0.9674 1.6400 346.89 335 1060.8 289.57 1.2872 0.9658 1.6169 356.51
N 340 1024.5 298.28 1.3145 0.9773 1.7083 319.00 340 1032.8 297.80 1.3116 0.9752 1.6756 329.96
~
345 991.37 307.05 1.3401 0.9888 1.8036 289.00 345 1001.6 306.36 1.3366 0.9856 1.7537 301.90
z
9 350 952.48 316.41 1.3670 1.0032 1.9531 255.42 350 966.21 315.39 1.3626 0.9979 1.8662 271.48
9' 350.72 946.14 317.84 1.3711 1.0057 1.9829 250.07 355 923.81 325.14 1.3903 1.0]40 2.0524 236.94
cD 350.72 144.08 429.00 1.6880 1.0336 1.8832 119.73 359.35 876.21 334.70 1.4170 1.0360 2.3876 200.05
U)
355 134.91 436.49 1.7092 1.0085 1.6473 125.6] 359.35 189.34 427.33 1.6748 1.0812 2.5274 111.90
~

360
?l
126.89 444.31 1.7311 0.9917 1.4977 131.24 360 186.15 428.92 1.6792 1.0138 2.3968 113.25 -I
365
370
120.55
115.31
451.56
458.44
1.7511
1.7698
0.9823
0.9773
1.4072
1.3470
136.04
140.29
365
370
168.26
156.44
439.35
448.06
1.7080 1.0364
1.0]72
1.8670
1.6425
121.69
128.11
r=
r-
1.7317
375 110.83 465.06 1.7876 133.47
Z
0.9750 1.3046 144.12 375 147.53 455.93 1.7528 1.0065 1.5163 m
380 106.92 471.50 1.8047 0.9746 1.2736 147.63 380 140.36 463.30 1.7723 1.0006 1.4355 138.13 :u
385 103.45 477.81 1.8212 0.9756 1.2503 150.89 385 134.37 470.33 1.7907 0.9976 1.3797 142.31
•
:u
390
395
100.34
97.517
484.01
490.14
1.8372
1.8528
0.9776
0.9803
1.2326
1.2189
153.94
156.80
390
395
129.22
124.71
477.12
483.74
1.8083
1.8251
0.9967
0.9972
1.3393
1.3090
146.11
149.61
S
::t:
400 94.935 496.21 1.8681 0.9836 1.2085 159.52 400 120.69 490.23 1.8414 0.9987 1.2859 152.87 l>
410 90.360 508.22 1.8977 0.9916 1.1945 164.56 410 113.81 502.91 1.8728 1.()()40 1.2542 158.80 Z
420 86.400 520.12 1.9264 1.0009 1.1871 169.19 420 108.05 515.35 1.9027 1.0114 1.2349 164.14
C
430 82.915 531.98 1.9543 LOllI 1.1842 173.48 430 103.12 527.64 1.9317 1.0201 1.2236 169.01 ;:t
440 79.810 543.82 1.9815 1.0221 1.1846 177.49 440 98.811 539.84 1.9597 1.0299 1.2178 173.51 !='
450 77.012 555.68 2.0082 1.0336 l.l873 181.28 450 94.993 552.01 1.9871 1.0404 1.2158 177.71 OJ
460 74.471 567.57 2.0343 1.0454 1.1920 184.87 460 91.570 564.17 2.0138 1.0515 1.2167 181.66 l>
m
::t:
3.50 MPa 4.00 MFa :u
175 1581.8 79.124 0.4443 0.7920 1.1821 1106.8 175 1582.4 79.349 0.4437 0.7921 1.1817 1108.7
180 1568.7 85.039 0.4776 ·0.7923 1.1842 1081.8 180 1569.4 85.262 0.4771 0.7924 1.1838 1083.7
185 1555.6 90.968 0.5101 0.7937 1.1875 1056.9 185 1556.3 9 l.I 89 0.5095 0.7938 1.1870 1058.8
190 1542.4 96.916 0.5418 0.7960 l.I916 1032.1 190 ]543.1 97.134 0.5412 0.7961 1.1911 1034.1
195 1529.2 102.88 0.5728 0.7990 1.1964 1007.5 195 1530.0 103.10 0.5722 0.7991 1.1959 1009.5
200 1515.9 108.88 0.6032 0.8025 1.2017 983.09 200 1516.7 109.09 0.6026 0.8()26 1.2012 985.26
205 1502.6 114.90 0.6329 0.8064 1.2076 958.90 205 1503.4 115.11 0.6323 0.8C66 1.2070 961.15
210 1489.1 120.95 0.6621 0.8107 1.2139 934.94 210 1490.0 121.16 0.6615 0.8109 1.2132 937.27
215 1475.6 12:.04 0.6907 0.8153 1.2205 911.21 215 1476.5 127.24 0.6901 0.8154 1.2198 913.62
220 1461.9 133.16 0.7189 0.8201 1.2275 887.70 220 1462.8 133.36 0.7182 0.8202 1.2267 890.20
225 1448.1 139.31 0.7465 0.8250 1.2348 864.40 225 1449.1 139.51 0.7459 0.8251 1.2340 866.99
230 1434.2 145.51 0.7738 0.8301 1.2424 841.30 230 1435.3 145.70 0.7731 0.8302 1.2415 843.99
235 1420.2 15:.74 0.8006 0.8354 1.2504 818.39 235 1421.3 151.93 0.7999 0.8354 1.2494 821.19
240 1406.0 158.01 0.8270· 0.8407 1.251r7 795.65 240 1407.2 158.20 0.8263 0.8408 1.2576 798.56
245 139l.7 164.33 0.8530 0.8462 1.2674 773.06 245 1392.9 164.51 0.8523 0.8462 1.2662 776.09

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 lABLE 9. Thermodynamic properties 'Jf HFC-134a in the single-phase region Continued

T p h s __
Cv_ ~ w T p h Cv ~ ~
K kg/m3 kJ/kg I:1/(kgK) kJ/(kgK) kJ/(kgK) mls K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

3.50 MPa 4.00 MPa

-t
:I:
250 1377.1 170.69 0.8787 0.8517 1.2765 750.61 250 1378.4 170.86 0.8779 0.8518 1.2751 753.77 m
731.57
:lJ
255 1362.4 177.09 0~9041 0.8574 1.2860 728.28 255 1363.8 177.26 0.9033 0.8574 1.2845
3:
260 1347.4 183.55 0.9292 0.8631 1.2959 706.04 260 1348.9 183.70 0.9283 0.8631 1.2943 709.48 oc
265 1332.2 190.05 0.9539 0.8689 1.3064 683.88 265 1333.8 190.20 0.9531 0.8689 1.3046 687.48
270 1316.7 196.61 0.9785 0.8748 1.3175 661.78 270 1318.4 196.75 0.9776 0.8748 1.3155 665.55 -<
z
275 1300.9 203.23 1.0027 0.8808 1.3293 639.71 275 1302.7 203.36 1.0018 0.8808 1.3270 643.66 »
280 1284.8 209.91 1.0268 0.8869 1.3418 617.65 280 1286.8 210.02 1.0258 0.8868 1.3392 621.80 3:
285 1268.3 216.65 1.0507 0.8931 1.3552 595.58 285 1270.4 216.75 1.0496 0.8930 1.3522 599.94 o
290 1251.4 223.46 1.0744 0.8995 1.3696 573.46 290 1253.7 223.55 1.0733 0.8993 1.3662 578.06 "'0
:lJ
295
300
1234.0
1216.1
230.35
237.32
1.0979
1.1213
0.9059
0.9125
1.3852
1.4021
551.26
528.95
295
300
1236.5
1218.8
230.42
,237.36
1.0968
1.1201
0.9057
0.9122
1.3813
1.3976
556.12
534.11
o"'0
305 1197.6 244.37 1.1447 0.9192 1.4207 506.50 305 1200.5 244.39 1.1434 0.9189 1.4154 511.98 m
:lJ
310 1178.3 251.53 1.1679 0.9261 1.4412 483.86 310 1181.6 251.52 1.1665 0.9257 1.4350 489.70 -t
315 1158.3 258.1 9 1.1912 0.9332 1.4642 460.99 315 1162.0 258.75 1.1897 0.9327 1.4568 467.23 iii
320 1137.4 266.:8 1.2144 0.9405 1.4902 437.81 320 1141.5 266.09 1.2128 0.9399 1.4812 444.52 en
325 1115.4 273.'70 1.2378 0.9481 1.5201 41L.26 325 1120.0 273".57 1.2360 0.9474 1.5090 421.50 o-n
330 1092.1 281.39 1.2612 0.9561 1.5550 390.24 330 1097.3 281.19 1.2593 0.9551 1.5411 398.11 ...A.
335 1067.2 289.26 1.2849 0.9644 1.5967 365.61 335 1073.3 288.99 1.2827 0.9632 1.5789 374.24 ...A.

340
345
350
1040.4
1010.9
978.08
297.37
305.77
314.55
1.3089
1.3335
1.3587
0.9733
0.9831
0.9940
1.6480
1.7138
1.8032
340.17
313.62
285.45
340
345
350
1047.4
1019.4
988.60
296.99
305.25
313.83
1.3064
1.3305
1.3552
0.9718
0.9809
0.9910
1.6244
1.6811
1.7547
349.76
324.44
297.97
~.
...A.

-t
m
355 940.10 323.87 1.3852 1.0073 1.9361 254.71 355 953.80 322.85 1.3808 1.0026 1.8566 269.80 -t
:lJ
360
365
893.69
828.82
334.07
346.11
1.4137
1.4469
1.0254
1.0577
2.1686
2.7721
219.41
174.01
360
365
913.11
862.29
332.49
343.18
1.4078
1.4373
1.0169
1.0370
2.0126
2.3000
238.94
203.34
»
'TI
1.4729 1.0747 3.1454 157.31 r-
366.87 791.62 351.87 1.4626 1.0821 3.4836 150.35 370 787.42 356.29 c:
366.87 252.01 422.22 1.6544 1.1368 4.2922 103.53 373.49 632.86 375.56 1.5247 1.1854 26.325 97.697 o
~ 370 223.39 432.44 1.6821 1.0889 2.6737 111.78 373.49 390.23 405.37 1.6045 1.2261 37.631 93.112 :lJ
"tJ 375 199.47 443.83 1.7127 1.0532 2.0098 120.57 375 309.97 421.21 1.6469 1.1550 5.5638 101.80 om
:r
< 380 184.26 453.14 1.7374 1.0351 1.7428 127.25 380 251.91 438.79 1.6935 1.0887 2.6008 114.10 -t
~ :I:
o
=r
385
390
173.03
164.11
461.45
469.18
1.7591
1.7791
1.0249
1.0192
1.5957
1.5023
132.81
137.65
385
390
225.87
208.71
450.16
459.64
1.7232
1.7477
1.0616
1.0471
2.0370
1.7837
122.12
128.50
»
Z
en
~ 395 156.73 476.53 1.7978 1.0164 1.4381 141.97 395 195.91 468.17 1.7694 1.0388 1.6380 133.92 m
:D 400 150.43 483.59 1.8156 1.0154 1.3915 145.91 400 185.71 476.11 1.7894 1.0343 1.5433 138.70 X
~ 410 140.11 497.17 1.8491 1.0173 1.3300 152.90 410 170.04 490.91 1.8259 1.0315 1.4288 146.93 'TI
C
Do) 420 131.84 510.27 1.8807 1.0223 1.2928 159.04 420 158.21 504.85 1.8595 1.0337 1.3640 153.96 9
...A.

r» 430 124.98 523.08 1.9108 1.0294 1.2698 164.55 430 148.77 518.27 1.8911 1.0389 1.3242 160.15 W
~
< 440 119.13 535.70 1.9398 1.0379 1.2557 169.57 440 140.94 531.38 1.9212 1.0460 1.2991 165.71
~
~ 450 114.04 548.21 1.9679 1.0474 1.2476 174.21 450 134.27 544.28 1.9502 1.0544 1.2833 170.80
N 1.2739 175.50
460 109.55 560.67 1.9953 1.0576 1.2439 118.53 460 128.49 557.07 1.9783 1.0638
~
Z
~

..
91
CD
CD
~
...A.
CO
~

Downloaded 22 Feb 2013 to 132.203.235.189. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
 ~
TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region Continued
.....
I\)

"
':3'

~
o
T p h s __
C v_ ~ w T p h s Cv ~ w
o':3' K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls K kglmJ kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls
CD
~
:D 5.00 MPa 6.00 MPa
~
C 175 1583.6 79.799 0.4427 0.7925 1.181O 1112.3 175 1584.8 80.250 0.4417 0.7928 1.1803 1115.9
Q)
§I 180 1570.6 85.709 0.4760 0.7927 l.l831 1087.5 180 1571.9 86.156 0.4750 0.7931 1.1823 1091.2
185 1557.6 91.632 0.5085 0.7942 1.1862 1062.7 185 1558.9 92.075 0.5074 0.7945 1.1854 1066.6
<
~ 190 1544.5 97.573 0.5401 0.7964 1.1902 1038.1 190 1545.9 98.012 0.5391 0.7968 1.1893 1042.1
I\) 195 1531.4 103.53 0.5711 0.7994 1.1949 1013.7 195 1532.9 103.97 0.5700 0.7997 1.1939 1017.8
~
200 1518.2 109.52 0.6014 0.8029 1.2001 989.55 200 1519.8 109.95 0.6003 0.8032 1.1991 993.79
z
? 205 1505.0 115.53 0.6311 0.8069 1.2059 965.59 205 1506.6 115.96 0.6300 0.8072 1.2047 969.98
!JI 210 1491.7 121.58 0.6603 0.8111 1.2120 941.87 210 1493.3 122.00 0.6591 0.8114 . 1.2108 946.41·
cD 215 1478.2 127.65 0.6889 0.8157 1.2184 918.38 215 1480.0 128.07 0.6876 0.8159 1.2171 923.09
co 220 1464.7 133.76 1.2238 900.01
~ 0.7170 0.8204 1.2252 895.14 220 1466.6 134.17 0.7157 0.8207 ?J
225 1451.1 139.91 0.7446 0.8254 1.2323 872.12 225 1453.1 140.31 0.7433 0.8256 1.2308 877.17 -t
230 1437.4 146.09 0.7717 0.8304 1.2397 849.31 230 1439.4 146.48 0.7704 0.8307 1.2380 854.55 r=
r-
235 1423.5 152.31 0.7985 0.8356 1.2475 826.71 235 1425.7 152.69 0.7971 0.8359 1.2456 832.15
Z
240 1409.5 158.56 0.8248 0.8410 1.2555 804.30 240 1411.8 158.93 0.8234 0.8412 1.2534 809.95 m
245 1395.4 164.86 0.8508 0.8464 1.2638 782.06 245 1397.8 165.22 0.8494 0.8465 1.2616 787.93 :D
250 1381.1 171.20 0.8764 0.8519 1.2725 759.99 250 1383.6 171.55 0.8749 0.8520 1.2700 766.09
•
:D
255 1366.6 177.59 0.9017 0.8575 1.2816 738.05 255 1369.3 177.92 0.9002 0.8576 1.2789 744.41 ~
260 1351.9 184.02 0.9267 0.8632 1.2911 716.25 260 1354.7 184.34 0.9251 0.8632 1.2881 722.87 ::r::
265 1336.9 190.50 0.9514 0.8689 1.3011 694.55 265 1340.0 190.81 0.9497 0.8690 1.2977 701.45 l>
270 1321.8 197.03 0.9758 0.8748 1.3115 672.94 270 1325.0 197.32 0.9741 0.8748 1.3078 680.15 Z
1.3184 658.94
C
275 1306.3 203.62 1.0000 0.8807 1.3225 651.40 275 1309.8 203.88 0.9982 0.8807
280 1290.6 210.26 1.0239 0.8867 1.3342 629.92 280 1294.3 210.50 1.0220 0.8866 1.3295 637.81 ;r:
285 1274.6 216.96 1.0476 0.8928 1.3466 608.47 285 1278.6 217.18 1.0457 0.8927 1.3413 616.74 P
290 1258.1 223.73 1.0712 0.8990 1.3598 587.03 290 1262.4 223.92 1.0691 0.8988 1.3538 595.72 OJ
295 1241.3 230.56 1.0945 0.9053 1.3739 565.59 295 1246.0 230.72 1.0923 0.9050 1.3672 574.72 l>
300 1224.0 237.47 1.1177 0.9118 1.3891 544.11 300 1229.1 237.59 1.1154 0.9114 1.3814 553.73 m
::r::
305 1206.3 244.45 1.1408 0.9183 1.4056 522.57 305 1211.7 244.54 1.1384 0.9178 1.3968 532.72 :D
310 1187.9 251.53 1.1638 0.925() 1.4236 500.95 310 1193.9 251.56 1.1612 0.9244 1.4133 511.69
315 1168.9 258.69 1.1868 0.93Hl 1.4433 479.21 315 1175.5 258.67 1.1840 0.9311 1.4313 490.60
320 1149.2 265.96 1.2097 0.9388 1.4651 457.33 320 1156.4 265.88 1.2067 0.9379 1.4511 469.44
325 1128.6 273.35 1.2326 0.9460 1.4895 435.26 . 325 1136.7 273.19 1.2294 0.9449 1.4728 448.18
330 1107.1 280.87 1.2555 0.9535 1.5172 412.96 330 1116.0 280.61 1.2520 0.9521 1.4970 426.80
335 1084.4 288.53 1.2786 0.9612 1.5488 390.38 335 1094.5 288.16 1.2747 0.9595 1.5242 405.25
340 1060.3 296.36 1.3018 0.9692 1.5858 367.43 340 1071.8 295.86 1.2975 0.9671 1.5552 383.51
3.!,5 1034.5 304.40 1.3252 0.9776 1.6297 344.02 345 1047.8 303.72 1.3205 0.9750 1.5909 361.53
350 1006.7 312.68 1.3491 0.9865 1.6835 320.00 350 1022.2 311.78 1.3437 0.9833 1.6328 339.24
355 976.37 321.26 1.3734 0.9962 1.7516 295.18 355 994.81 320.07 1.3672 '0.9920 1.6831 316.57
360 942.46 330.23 1.3985 1.007] 1.8419 269.24 360 964.98 328.63 1.3911 1.0013 1.7449 293.41
365 903.68 339.74 1.4247 1.0197 1.9704 241.70 365 932.15 337.54 1.4157 1.0114 1.8236 269.61
370 857.42 350.06 1.4528 1.0357 2.1738 211.76 370 895.34 346.91 1.4412 1.0228 1.9282 244.98
375 797.97 361.77 1.4843 1.0582 2.5623 178.12 375 853.01 356.90 1.4680 1.0359 2.0756 219.34
380 707.99 376.73 1.5239 1.0968 3.6466 138.88 380 802.55 367.79 1.4969 1.0520 2.3000 192.53
385 526.36 402.59 1.5914 1.1591 6.5852 106.37 385 739.25 380.14 1.5292 1.0725 2.6718 164.91

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 TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region - Continued
-~--- --- - ~ ~

T p h s ell w T p h s w
~ e" ~
K kg/m 3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kg:{) mls K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls

5.00 MPa 6.00 MPa

~
:::t
390 377.18 429.39 1.6606 1.1305 3.9290 110.04 390 655.55 394.91 1.5673 1.0982 3.2729 139.14 m
395 318.11 445.28 1.7011 1.0985 2.65:3 117.81 551.84 412.68 1.6125 1.1196 3.7256 123.06 ::0
395
3:
400 285.05 457.15 1.7310 1.0802 2.15")9 124.51 400 458.74 430.63 1.6577 1.1188 3.3383 119.99 o
410 245.61 476.32 1.7783 1.0630 1.7~7 135.45 410 354.00 458.21 1.7259 1.0949 2.3028 127.67 c
420 221.02 492.74 1.8179 1.0578 1.56~9 144.32 420 302.04 478.75 1.7754 1.0818 1.8656 137.00 -<
z
430 203.38 507.84 1.8535 1.0584 1.4650 151.89 430 269.64 496.26 1.8166 1.0775 1.6582 145.35 »
440 189.75 522.17 1.8864 1.0623 1.4057 158.53 440 246.66 512.21 1.8533 1.0781 1.5421 152.75 3C
450 178.72 536.02 1.9175 1.0684 1.36")7 164.50 450 229.10 527.25 1.8871 1.0818 1.4706 159.37 C;
460 169.50 549.57 1.9473 1.0759 1.3~8 169.93 460 215.04 541.71 1.9188 1.0875 1.4240 165.38 ."
::0
7.00 MPa 8.00 MPa
o
."
m
::0
175 1586.0 80.702 0.4406 0.7931 1.1796 11l9.5 175 1587.2 81.154 0.4396 0.7934 1.1790 1123.0 ~
180 1573.1 86.604 0.4739 0.7934 1.1816 1094.9 180 1574.4 87.053 0.4729 0.7937 1.1809 1098.5 iii
185 1560.2 92.520 0.5063 0.7948 1.18"6 1070.4 185 1561.5 92.965 0.5053 0.7951 1.1838 1074.1 en
190 1547.3 98.452 0.5380 0.7971 1.1885 1046.0 190 1548.6 98.893 0.5369 0.7974 1.1876 1049.9 o
."
195 1534.3 104.40 0.5689 0.8000 1.19:30 1021.9 195 1535.7 104.84 0.5678 0.8003 1.1921 1025.9 ~

200 1521.3 1l0.38 0.5992 0.8035 1.19U 997.99 200 1522.7 110.81 0.5980 0.8038 1.1971 1002.1 ~
205 1508.2 116.38 0.6288 0.8074 1.20~7 974.32 205 1509.7 116.81 0.6277 0.8077 1.2026 978.61 ~
NI
210 1495.0 122.42 0.6579 0.81l7 1.2096 950.90 210 1496.6 122.84 0.6567 0.8120 1.2084 955.34
...m
215
220
225
1481.7
1468.4
128.48
134.58
0.6864
0.7145
0.8162
0.8209
1.21:8
1.22'24
927.74
904.82
215
220
1483.5
1470.2
128.90
134.99
0.6852
0.7132
0.8165
0.8212
1.2146
1.2211
932.32
909.57
887.07
...
::0
230
1455.0
1441.5
140.71
146.87
0.7420
0.7691
0.8258
0.8309
1.2293
1.2364
832.15
859.71
225
230
1456.9
1443.5
141.11
147.26
0.7407
0.7678
0.8261
0.8311
1.2278
1.2348 864.80
»
."
235 1427.8 153.07 0.7958 0.8361 1.2438 837.50 235 1429.9 153.46 0.7944 0.8363 1.2420 842.78 r-
c:
240 1414.1 159.31 0.8220 0.8413 1.2514 8[5.50 240 1416.3 159.69 0.8207 0.8416 1.2495 820.97 o::0
!- 245 1400.2 ' 165.59 0.8479 0.8467 1.2594 793.70 245 1402.5 165.95 0.8465 0.8469 1.2573 799.37
"0
~
250 1386.1 171.90 0.8734 0.8522 1.26")7 772.09 250 1388.6 172.26 0.8720 0.8523 1.2654 777.97 om
to< 255 1371.9 178.26 0.8986 0.8577 1.2763 750.64 255 1374.6 178.61 0.8971 0.8579 1.2738 756.76 -t
!'l :r:
o
~
(I)
260
265
1357.6
1343.0
184.67
191.12
0.9235
0.9481
0.8633
0.8690
1.2852
1.294 5
729.36
708.21
260
265
1360.3
1345.9
185.00
191.43
0.9219
0.9465
0.8635
0.8691
1.2824
1.2915
735.71
714.83
»
z
? 270 1328.2 197.61 0.9724 0.8748 1.3042 6&7.20 270 1331.4 197.91 0.9707 0.8749 1.3009 694.09 m
:II 275 1313.2 204.16 0.9964 0.8806 1.3144 666.30 275 1316.6 204.44 0.9947 0.8807 1.3107 673.48 3:
~ 280 1298.0 210.76 1.0202 0.8866 1.3251 645.50 280 1301.5 211.02 1.0184 0.8865 1.3210 652.99 ."
o
C 285 1282.5 217.41 1.0437 0.8926 1.3364 624.78 285 1286.2 217.65 1.0418 0.8925 1.3318 632.60 ....
I

~ 290 1266.6 224.12 1.0671 0.8986 1.3483 61)4.14 290 1270.7 224.34 1.0651 0.8985 1.3432 612.31 ~
~
<
~
I\)
SItl
295
300
305
1250.5
1233.9
1217.0
230.90
237.74
244.64
1.0902
1.1132
1.1360
0.9048
0.9111
0.9174
1.3~9
1.3744-
1.3887
533.55
563.00
542.49
295
300
305
1254.8
1238.6
1222.0
231.09
237.90
244.77
1.0882
1.1110
1.1338
0.9046
0.9108
0.9171
1.3552
1.3679
1.3813
592.11
571.97
551.90
-»
Z 310 1199.6 25~.63 l.l588 0.9239 1.4041 521.98 310 1205.1 251.71 1.1563 0.9235 1.3957 531.87
? 315 1181.7 258.69 1.1813 0.9305 1.4207 501.47 315 1187.6 258.73 1.1788 0.9299 1.4111 511.88
!" 320 1163.3 265.83 1.2039 0.9372 1.4386 430.95 320 1169.7 265.82 1.2011 0.9365 1.4276 491.92 .....
-a.
co 325 1144.2 273.08 1.2263 0.9440 1.4583 460.39 325 1151.3 273.01 1.2234 0.9432 1.4454 471.98 ....
I\)

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 ~
TABLE 9. Thermodynanic properties of HFC-134a in the single-phase region - Continued
.....
i':)
~ i':)
::r - -
~
- - -----

T p h s w T p h s w
o
Cv
~ C" ~
::r K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) m/s K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) m/s
CD
~
7.00 MPa 8.00MPa
~
oQ) 330 1124.4 280.42 1.2487 0.9510 1.4798 439.78 330 1132.2 280.28 1.2456 0.9500 1.4648 452.05
§1 335 1103.8 281.88 1.2712 0.9581 1.5036 419.11 335 1112.4 287.66 1.2678 0.9570 1.4860 432.13
340 1082.2 295.46 1.2936 0.9655 1.5302 398.36 340 1091.8 295.15 1.2900 0.9641 1.5093 412.20
<
~ 345 1059.6 303.19 1.3162 0.9730 1.5602 177.50 345 1070.4 302.75 1.3122 0.9714 1.5350 392.26
I\) 350 1035.8 311.07 1.3389 0.9808 1.5943 356.52 350 1047.9 310.50 1.3345 0.9788 1.5637 372.32
_CI)
355 1010.5 319.14 1.3618 0.9889 1.6338 335.39 355 1024.3 318.40 1.3569 0.9865 1.5961 352.35
z
~ 360 983.54 321.42 1.3849 0.9973 1.6801 314.06 360 999.45 326.47 1.3795 0.9944 1.6328 332.37
,91 365 954.44 335.96 1.4085 1.0062 1.7354 292.52 365 972.99 334.74 1.4023 1.0026 1.6749 312.38
<0 370 922.80 344.80 1.4325 1.0157 1.8030 'Il0.72 370 944.72 343.23 1.4254 1.0111 1.7238 292.39
CO
,J:o. 375
380
887.95
849.03
354.01
363.71
1.4573
1.4830
1.0260
1.0373
1.8876
1.9963
248.65
226.36
375
380
914.32
881.39
351.99
361.06
1.4489
1.4729
1.0200
1.0294
1.7812
1.8493
272.44
252.59
:u.
-f
385 .
390
804.82
753.72
374.03
385.19
1.5100
1.5387
1.0499
1.0641
2.1396
2.3290
204.03
182.21
385
390
845.45
805.95
, 370.50
380.39
1.4976
1.5232
1.0394
1.0500
1.9307
2.0278
232.99
213.88
r=r
Z
395
400
410
694.22
626.75
493.97
391.40
410.79
438.89
1.5699
1.6035
1.6729
1.0795
1.0942
1.1061
2.5628
2.7806
2.6996
162.21
146.32
133.10
395
400
410
762.38
714.52
609.72
390.81
401.81
425.44
1.5497
1.5774
1.6357
1.0611
1.0725
1.0924
2.1404
2.2616
2.4324
195.71
179.21
155.02
.
m
::u
::u
420
430
403.92
348.97
463.43
483.81
1.7321
1.7801
1.0992
1.0933
2.2163
1.8903
135.79
142.46
420
430
511.20
436.95
449.50
471.54
1.6937
1.7456
1.1013
1.1018
2.3311
2.0734
145.45
145.87.
~
%
440 312.32 501.70 1.8212 1.0919 1.7007 149.50 440 384.99 491.13 1.7906 1.1016 1.8560 150.28 »
450 285.70 518.11 1.8581 1.0938 1.5886 156.18 450 347.58 508.89 1.8305 1.1031 1.7077 155.83 Z
460 265.18 533.60 1.8921 1.0980 1.5150 162.39 460 525.44 1.1067 1.6084 161.56
C
319.31 1.8669
;J:
IO.ooMPa 12.00 MPa P
OJ
175 1589.5 82.060 0.4376 0.7941 1.1777 1130.1 175 1591.8 82.968 0.4356 0.7948 1.1764 1136.9 »m
180 1576.8 81.952 0.4708 0.7944 1.1795 1105.8 180 1579.2 88.854 0.4688 0.7950 1.1781 1112.9
J:
185 1564.1 93.857 0.5032 0.7958 1.1823 1081.6 185 1566.6 94.751 0.5011 0.7964 1.1809 1088.9 ::u
190 1551.3 99.778 0.5347 0.7980 1.1860 1057.6 190 1554.0 100.66 0.5326 0.7987 1.1845 1065.1
195 1538.5 105.71 0.5656 0.8010 1.1904 1033.8 195 1541.3 106.59 0.5635 0.8016 1.1887 1041.6
200 1525.7 111.68 0.5958 0.8045 1.1953 lOlO.3 200 1528.6 112.55 0.5936 0.8051 1.1935 1018.3
205 1512.8 111.67 0.6254 0.8084 1.2006· 987.06 205 1515.8 118.53 0.6231 0.8090 1.1986 995.32
210 1499.8 123.68 0.6544 0.8126 1.2062 964.06 210 1503.0 124.54 0.6521 0.8132 1.2042 972.59
215 1486.8 129.73 0.6828 0.8171 1.2122 941.34 215 1490.2 139.57 0.6805 0.8176 1.2100 950.14
220 1473.8 135.81 0.7108 0.8218 1.2185 918.89 220 1477.2 136.64 0.7084 0.8223 1.2160 927.98
225 1460.6 141.92 0.7382 0.8266 1.2250 fJ96.70 225 1464.3 142.73 0.7358 0.8272 1.2224 906.10
230 1447.4 143.06 0.7652 0.8316 1.2317 fl74.78 230 1451.2 148.86 0.7627 0.8321 1.2289 884.48
235 1434.0 154.23 0.7918 0.8368 1.2387 853.10 235 1438.1 155.02 0.7892 0.8372 1.2356 863.13
240 1420.6 160.45 0.8180 0.8420 1.2459 831.66 240 1424.8 161.22 0.8153 0.8424 1.2426 842.03
245 1407.1 166.70 0.8437 0.8473 1.2534 810.45 245 1411.5 167.45 0.8410 0.8477 1.2498 821.18
250 1393.4 172.98 0.8691 0.8527 L2611 189.45 250 1398.1 173.72 0.8663 0.8531 1.2571 800.56
255 1379.6 17~.31 0.8942 0.8582 1.2691 168.67 255 1384.6 180.02 0.8913 0.8585 1.2648 780.17
260 1365.7 185.67 0.9189 0.8637 1.2713 748.07 260 1370.9 186.37 0.9159 0.8640 1.2726 759.99
265 1351.6 192.08 0.9433 0.8693 1.2858 '127.66 265 1357.1 192.75 0.9403 0.8696 1.2807 740.01

Downloaded 22 Feb 2013 to 132.203.235.189. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
 TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region - Continued

T
K
p
kg/mJ "
k.llkg
s
kJ/(kgK)
Cv
kJ/(kgK)
~
kJ/(kgK)
w
mls K
T P
kglm3
h
kJ/kg
s
kJ/(kgK)
Cv
kJ/(kgK)
~
kJ/(kgK)
w
mls

10.00 MPa 12.00 MPa

.....
::t
270 1337.4 198.53 0.9674 0.8750 1.2'}47 707.43 270 1343.2 199.17 0.9643 0.8752 1.2891 720.23 m
275 1323.0 205.03 0.9913 0.8807 1.})39 687.35 :D
275 1329.1 205.64 0.9880 0.8809 1.2977 700.64
:s:
280
285
1308.3
1293.5
211.57
218.16
1.0149 0.8865 1.3135 667.43 280 1314.8 212.15 l.Oll5 0.8866 1.3067 681.22 o
c
. 1.0382 0.8924 1.3l34 647.65 285 1300.4 218.71 1.0347 0.8924 1.3160 661.98
290 1278.4 224.81 1.0613 0.8983 1.3339 628.00 290 1285.8 225.31 1.0577 0.8983 1.3256 642.89 -<
z
295 1263.1 231.50 1.0842 0.9043 1.3448 608.48 295 1270.9 231.96 1.0804 0.9042 1.3357 623.97 »
300 1247.5 238.26 t.l069 0.9104 1.3562 589.07 300 1255.8 238.67 1.1029 0.9102 1.3461 605.20 3:
305 1231.6 245.07 1.1294 0.9166 1.3583 569.78' 305 1240.5 245.43 1.1253 0.9162 1.3571 586.57 n
310 1215.3 251.94 1.1518 0.9223 1.3310 550.59 310 1224.9 252.24 1.1474 0.9223 1.3685 568.09 "'tJ
315 :D
320
1198.7
1181.7
258.88
265.89
1.1740
1.1960
0.9291
0.9355
1.3}44
1.4:>87
531.50
512.50
315
320
1209.0
1192.7
259.11
266.05
1.1694
1.1913
0.9285
0.9348
1.3805
1.3931
549.75
531.56
o
."
325 1164.3 272.97 1.2180 0.9420 1.4239 493.60 325 1176.2 273.05 1.2130 0.9411 1.4063 513.51 m
:D
330 1146.4 230.13 1.2399 0.9485 1.4400 474.80 330 1159.2 280.11 1.2345 0.9475 1.4202 495.61 .....
335 1128.0 237.37 1.2616 0.9552 1.4574 456~09 335 1141.9 287.25 1.2560 0.9539 1.4349 477.86 in
340 1109.0 2~4.70 1.2834 0.9621) 1.4760 437.48 340 1124.1 294.46 1.2774 0.9605 1.4504 460.27 en
345 1089.4 302.13 1.3051 0.9689 1.4}60 418.98 345 1105.8 30l.76 1.2987 0.9671 1.4669 442.85 o"II
350 1069.0 309.67 1.3267 0.9759 1.5177 400.59 350 1087.1 309.13 1.3199 0.9738 1.4843 425.61 ~

355 1047.9 317.32 1.3484 0.9830 1.54-13 382.34 355 1067.7 316.60 1.3411 0.9806 1.5028 408.57 ~
360 1026.0 325.09 1.3702 0.9902 1.5570 364.24 360 1047.8 324.16 1.3622 0.9875 1.5225 391.76 ~
365 1003.0 332.99 1.3920 0.9976 1.5;)50 346.31 1.5434 375.20 i\)
365 1027.2 331.83 1.3834 0.9944
370 979.11 341.04 1.4139 1.0052 1.6258 328.60 370 1006.0 339.60 1.4045 1.0015 1.5657 358.91 .....
I

m
375 953.96 349.25 1.4359 1.0129 1.6596 311.14 375 983.98 347.49 1.4257 1.0086 1.5892 342.95 .....
380 927.52 357.64 1.4581 1.0207 1.6;)67 1.4469 :D
385 899.67 356.23 1.4806 1.0283 1.7373
294.00
277.25
380
385
961.17
937.52
355.50
363.63 1.4682
1.0158
1.0231
1.6142
l.6405
327.35
312.16
»
"II
390 870.28 375.02 1.5033 1.0371) 1.7B16 261.01 390 913.00 371.90 1.4895 1.0304 1.6680 297.46 r-
C
395 839.26 334.05 1.5263 1.0453 1.8290 245.42 395 _887.58 380.32 1.51lO 1.0378 1.6965 283.33 o
~ 400 806.57 393.32 1.5496 1.0537 1.8786 230.68 400 861.28 388.87 1.5325 1.0452 1.7255 269.83 :D
"U
::T
410 736.54 412.59 1.5972 1.0704 1.9748 204.66 410 806.18 406.41 1.5758 1.0600 1.7822 245.18 o
m
~ 420 662.77 432.70 1.6457 1.0855 2.0382 184.94 420 748.53 424.49 1.6194 1.0743 1.8302 224.35 .....
::J:
o':T
(I)
430
440
590.89
527.11
453.13
473.12
1.6937
1.7397
1.0972
1.lO53
2.0326
1.9573
172.69
167.19
!
430
440
690.08
633.33
442.95
461.56
1.6628
1.7056
1.0875
1.0992
1.8583
1.8577
208.05
196.55
»
Z
? 450 474.40 492.17 1.7825 1.1113 1.8513 166.41 450 580.83 480.01 1.7470 1.1092 1.8279 189.50 m
:u 460 432.14 510.17 1.8220 1.1167 1.7502 168.34 460 534.24 498.05 1.7867 1.1l79 1.7784 186.10 '3:
~
..
I
"II
c 14.00 MPa 16.00 MPa 9
p I (,)
~
<
~
~
180
185
190
1581.6
1569.1
1556.6
89.758
~5.648
t[H.55
0.4668
0.4991
0.5306
0.7957
0.7971
0.7994
1.1769
1.1795
1.1830
1119.8
1096.1
1072.5
I
180
185
190
1583.9
1571.5
1559.1
90.663
96.548
102.44
0.4648
0.4970
0.5285
0.7964
0.7978
0.8000
1.1756
1.1782
1.1816
1126.7
1103.l
1079.8
-
»
z 195 1544.0 W7.48 0.5613 0.8023 1.1871 1049.2 195 1546.7 108.36 0.5592 0.8030 1.1856 1056.7
!:> 200 1531.4 113.42 0.5915 0.8057 1.1918 1026.1 200 1534.2 114.30 0.5893 0.8064 1.1901 1033.8
...
J1t
co
205
210
1518.8
1506.1
119.39
125.39
0.6209
0.6498
0.8095
0.813~
1.1968
1.2022
1003.4
980.94
205
210
1521.7
1509.2
120.26
126.25
0.6188
0.6476
0.8102
0.8144
1.1951
1.2003
1011.3
989.11
.....
I\)
(,)
~

Downloaded 22 Feb 2013 to 132.203.235.189. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
!=- ......a
"U TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region Continued N
::r ~

~ T p h s _C_,,_, ~ w T p h s w
o Cv
--EL-
::r K kglm3 U/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) m/s K kg/m
3
kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) m/s
CD
? 14.00MPa
:::D 16.00 MPa
~
C 215 1493.4 131.42 0.6782 0.81S2 1.2078 958.75 215 1496.6 132.27 0.6759 0.8189 1.2058 967.18
ID
§1 220 1480.6 137.47 0.7060 0.8229 1.2138 936.86 220 1484.0 138.31 0.7037 0.8235 I.2116 945.55
225 1467.8 143.56 0.7334 0.82'77 1.2199 915.26 225 1471.3 144.38 0.7310 0.8283 1.2175 924.21
<
~ 230 1454.9 149.67 0.7603 0.8327 1.2262 893.94 230 1458.6 150.49 0.7578 0.8332 1.2237 903.17
I\) 235 1442.0 155.82 0.7867 0.8378 1.2327 872.90 235 1445.8 156.62 0.7842 0.8383 1.2300 882.42
~
240 1428.9 162.00 0.8127 0.8429 1.2395 852.12 240 1432.9 162.79 0.8102 0.8434 1.2365 861.94
z
? 245 1415.8 168.21 0.8384 0.8482 1.2464 831.60 245 1420.0 168.99 0.8358 0.8487 1.2432 841.74
$I' 250 1402.6 174.46 0.8636 0.8535 1.2535 811.33 250 1407.0 175.22 0.8609 0.8540 1.2501 821.79
cO 255 1389.3 180.75 0.8885 0.8589 1.2608 791.30 255 1393.9 181.49 0.8858 0.8593 1.2571 802.10
fD
~ 260
265
1375.9
1362.4
187.07
193.43
0.9131
0.9373
0.8644
0.8699
1.2683
1.2760
771.50
751.93
260
265
1380.8
1367.5
187.79
194.13
0.9103
0.9344
0.8648
0.8703
1.2643
1.2716
782.65
763.44
::a
-I
270 1348.8 199.83 0.9612 0.8755 1.2839 732.56 270 1354.1 200.51 0.9582 0.8758 1.2792 744.45 r=
r-
275 1335.0 206.27 0.9849 0.88:1 1.2921 713.40 275 1340.6 206.93 0.9818 0.8814 1.2870 725.69
280 132l.1 212.75 1.0082 707.15
z
0.8868 1.3006 694.44 280 1327.0 213.38 1.0051 0.8870 1.2950 m
285 1307.0 219.28 1.0313 0.8925 1.3093 675.68 285 1313.3 219.88 1.0280 0.8927 1.3032 688.81 ::D
290 1292.7 225.85 1.0542 0.8983 1.3183 657.10 290 1299.4 226.41 1.0508 0.8985 1.3117 670.68
•
::D
295 1278.3 232.46 1.0768 0.9042 1.3276 638.70 295 1285.3 232.99 1.0733 0.9042 1.3204 652.76 o
-I
300 1263.7 239.13 1.0992 0.9101 1.3373 620.48 300 1271.1 239.62 1.0956 0.9101 1.3295 635.03 :::z:
305 1248.8 245.84 1.1214 0.9160 1.3473 602.44 305 1256.7 246.29 1.1176 0.9160 1.3388 617.50 »
z
310 1233.8 252.60 1.1433 0.9221 1.3577 584.57 310 1242.1 253.01 1.1395 0.9219 1.3484 600.17
315 1218.4 259.42 1.1652 0.9281 1.3686 566.88 315 1227.3 259.77 1.1611 0.9279 1.3583 583.03
c
320 1202.9 266.29 1.1868 0.9343 1.3799 549.36 320 1212.3 266.59 1.1826 0.9339 1.3685 566.10 ;t
325 1187.0 273.22 1.2083 0.9404 1.3916 532.02 325 1197.1 273.46 1.2039 0.9400 1.3792 549.36 p
330 1170.9 280.20 1.2296 0.9467 1.4039 514.86 330 1181.7 280.38 1.2250 0.9462 1.3902 532.83 OJ
335 1154.4 287.26 1.2508 0.9530 1,4.167 497.89 335 1165.9 287.36 1.2460 0.9524 1.4016 516.52 »
340 1137.6 294.37 1.2719 0.9594 1,4.301 481.12 340 Il49.9 294.40 1.2669 0.9586 1.4134 500.42 m
:::z:
345 1120.5 301.56 1.2929 0.9658 1,4441 464.55 345 1133.7 301.50 1.2876 0.9649 1.4256 484.56 ::D
350 1102.9 308.81 1.3138 0.9723 1,4.587 448.21 350 Il17.1 308.66 1.3082 0.9712 1.4382 468.93
355 1084.9 316.15 1.3346 0.9789 1.4740 432.10 355 1100.2 315.88 1.3287 0.9776 1,4513 453.57
360 1066.5 323.56 1.3553 0.9855 1,4.899 416.25 360 1082.9 323.17 1.3491 0.9841 1.4648 438.47
365 1047.6 331.05 1.3760 0.9922 1.5066 400.68 365 1065.3 330.53 1.3694 0.9906 1.4788 423.67
370 1028.2 338.62 1.3966 0.9989 1.5240 385.42 370 1047.4 337.96 1.3896 0.9971 1.4931 409.19
375 1008.4 346.29 1.4172 1.0057 1.5421 370.49 375 1029.1 345.46 1.4097 1.0036 1.5079 395.03
380 987.97 354.05 1.4377 1.0125 1.5609 355.93 380 1010.4 353.04 1.4298 1.0102 1.5230 381.25
385 966.99 361.90 1.4582 1.0194 1.5802 341.78 385 991.31 360.69 1.4498 1.0169 1.5383 367.85
390 945.45 369.85 1.4788 1.0263 1.6001 328.08 390 971.83 368.43 1.4698 1.0235 1.5539 354.88
395 923.35 377.90 1.4993 1.0332 1.6202 314.88 395 951.97 376.23 1.4897 1.0302 1.5695 342.36
400 900,70 386.05 1.5198 1.0402 1.6404 302.23 .400 931.73 384.12 1.5095 1.0369 1.5851 330.33
410 853.86 402.66 1.5608 1.0540 1.6798 278.81 410 890.24 400.12 1.5490 1.0502 1.6153 307.89
420 805.38 419.64 1.6017 1.06'76 1.7149 258.26 420 847.65 416.42 1.5883 1.0633 1.6429 287.81
430 756.07 436.93 1.6424 1.0808 1.7415 240.97 430 804.43 432.97 1.6272 1.0762 1.6657 270.34
440 707.07 454.42 1.6826 1.0932 1.7555 227.16 440 761.21 449.71 1.6657 1.0887 1.6817 255.63
450 659.73 471.99 1.7221 1.1047 1.7544 216.81 450 718.77 466.57 1.7036 1.1007 1.6893 243.70

Downloaded 22 Feb 2013 to 132.203.235.189. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
 TABLE 9. Thermodynamic properties ofHFC-134a in the single-phase region - Continued
---- ------ - -

T p h s w T h s w
c" ~ f) c" ~
K kg/m3 kJ/kg kJ/(kgK) k~/(kgK) kJ/(kgK) mls. K kg'm3 kJlkg kJ/(kgK) kJ/(kgK) kJ/(kgK) miS
14.OQMPa 16.00·MPa
-t
::J:
460 615.30 489.46 1.7605 1.1153 1.7387 209.68 460 6'~T7.90 483.47 1.7407 1.1122 1.68~0 23'4.45 m
::D
s:
20.riQ MPa 25.00·MPa o
o
180 1588.5 92.481 0.4609 0.7978 1.1733' 1140.1 180 1594.1 94.764 0.45~1 0.1996 1.1707 11.56.2 -<
z
.85 1576.3 98.354 0.49.31 0.7992 1.1758 1116.9 185 1582.1 10<>.62 0.4882 0.8009 1.1"729 1133.5 »
190 1564.1 104.24 0.5245 0.8014 1.1790 1093.9 190 1570.1 106.49 0.5195 0.8031 1.1760 1111.0 s:
195 1551.9 110.14 0.5551 0.8043 l.i828 l(i71.2 195' 155.8,2 112,38 0.5501 0.8060 1.1796 1088.7 C;
200 1539.6 11~.07 0.5851 0.8077 1.1871 1048.8 200 1546,2 i18.29 0.5800 0.8094 1.1837 1066;8 ~
205
210
1527.4
1515.1
122~01
127.98
0.6145
0.6433
0.Si16
0.8157
1..19.18
1.1968
1026.7 205
210
1534.2
1522,2
124.22
t30.l7
0.6093
0.6380
0.U32
0.8174 "
1.1882
1.1929
1045.2
1023.9
.~
"'CJ
1004.9.
215 1502.8' 133.98 0.6715 0.8201 1.2021 983.51 215 15J0'2 i36.15 0.6661 0.82i7 1.1979 1003.0 m
::D
220 1490.4 140.01 0.~992 0.8247 1.2076 962.36 220 1498.1 142.15 0.6937 0.8263 1.2031 '982.44 -t
225 1478 .0 146.06 0.7264 0.8295 1.2133 941.52 225 l486,1 148.18 0.n08 0.831() 1.2085 962.16 iii
230 14(;5.6 152.14 0.7~31 0.8344 1.2191 921.00 230 1474,0 154.24 0.7475 0.8359 1.2140 942.21 t/)
235 1453.2 158.25 0.7794 0.8394 1.225l 900.77 235 1461.9 160.32 ~.t73ti 0.8409 1.2196 922.57 o
240
245
1440.6
1428.1
164.39
170.56
0.8053
0.8307
0.8445
0 ..8497
1.2312
1.2375
880.85
861.21
240
245
1449,8
.437,6
166.43
172.57
0.7994
0.8247'
0.8459
0.8511
i.2254
1.2313
903.25
884.23'
"....
.:....
250 .1415.~ 176.77 0.8,558 0.8549 1.1439 841.85 250 1425,4 178.75 0.8496 0.8563 1.2312 865.52 .-
255
260
1402.8
1390.0
183.00
189.27
0.8805
0.9048
0.8603
0.8656
1.2504
1.2571
822.76
803.95
255
260
1413.2
1400,9
184.95
191.18
0.8742
0.8984
0.86i5
0.8668
1.2433
1.2495
847.Q9
828.95 ~m
265 1377.2 195.57 0.9288 0.8711 1.2639 785.39 265 1388,6 197.44 0.9223 0.8722 1.2558 811.08 -t
::D
270
275
1364.3
1351.3
201.91
208.28
0.9525
0.9759
0.8765
0.8820
1.2709
1.2780
767.08
749.0f
270
275
1376.2
136,3.7
203.74
210.07
0.9458"
0.9690
0.8776
0.8830
1.2622
1.2687
793.49
776.17
»
'\'Ii
280 1338.3 214.69 0.9990 0.8876 1.2853 731.20 280 1351.2 216.43 0.9919 0.8885 1.2753 759.11 r
c:
285 1325.1 22I.14 1.0218 0.8932 1.29~8 713.62 285 1338.7 ~22.82 1.0146 0.8941 1.2820 742.30 o
::D
~ 290 1311.8 227.62 1.0444 0.8989 1.3004 696.27 290 1326.0 229.25 1.0369 0.8996 1.2888 725.75
"'0 295 1298.4 234.14 1.0667 0.9046 1.3082 679.15 295 1313.3 235.71 1.0590 0.9052 1.2958 709.45 o
:l" m
'<
sn 300 1284.9 240.70 1.0887 0.9103 1.3162 662.26 300 1300.5 242.20 1.~808 0.9109 1.3029 693.40 -t
::J:
o
:l"
305 1271.3 247.30 1.1106 0.9161 1.3243 645.59 305 1287.7 248.74 1.1024 0.91'66
0.9223
1.3.101
1.~174
677.60
662.05
»
CD 310 1257.5 253.95 1.1322 0.9219 1.3327 629.15 310 1274.7 255.31 1.1238 Z
~ 315 L243.6 260.63 1.1536 0.9277 1.34 I} 612.94 315 1261.7 261.91 1.1449 0.9280 1.3248 646.74 m
:D 320 1229.6 267.36 1.1747 0.9336 1.3501 596.96 320 1248.6 268.55 1.1659 0.9338 1.3324 631.68 3!
~ 325 1215.3 27~U:3 1.1957 0.9396 1.3591 581.21 325 t235.4 275.24 1.1866 0.9396 1.3401 616.87 ."
C 330 1201.0 280.95 1.2166 0.9456 1.3683 565.69 330 1222.0 281.96 1.2071 0.9455 1.3479 602.31 9.-
~ 335 1186.4 287.82 1.2372 0.9516 1.3777 550.42 335 1208,6 288.72 1.2274 0.9.513 1.3559 . 588.00 (,,)
.~
<
~
J\)
~
340
345
350
1171.7
1156.8
1141.7
294.73
301.69
308.70
1.2577
1.2780
1.298 7
0.9577
0.9638
0.9699
1.3874
1.3973
1.4074.
535.39
520.61
506.09
340
345
. 350
1195.1
1181.4
1167.7
295.52
302.36
309.24
1.2476
1.2676
1.2874
0.9573
0.9632
0.9692
1.3639
1.3721
1.3803
573.95
560.17
546.65
-»
z 355 1126.4 315.77 );3182 0.9761 L4177 491.85 355 1153.8 316.16 1;3070 '0.9752 1:3887' 533;41
? 360 1110.9 322.88 1.3381 0.9823 1.4282 477.89 360 1139,8 323.12 1:3265 0.9812 1.3971 520.45
.PI 365 1095.2 330.05 1.3579 0.9885 1.4389 464.23 365 1125.7 330.13 1.3458 0.9873 1.4057 507.77 .....
..a. I\)
CD
CD
370 1079.3 337.27 1.3776 6:9948 1.4497 450.88 370 'il i 1.5 337.18 1.3650 0.9933 1.4142 495.40 en
~

Downloaded 22 Feb 2013 to 132.203.235.189. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
 ~
TABLE 9. Thermodynamic properties of HFC-134a in the single-phase region - ContiiriIed
.....
~
"tJ 0)
::T
---
~
- - - - - - - -

T p h s w T p h s w
o Cv ~ C" ~
::T
(1)
K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) rrils K kg/m
3
kJ/kg kJ/(kgK) . kJ/(kgK) kJ/(kgK) mls
? 20.00 MFa
::D 25.00 MPa
~
C 375 1063.2 344.55 1.3971 ' l.00ll 1.4607 437.85 375 1097.1 344.27 1.3840 0.9994 1.4228 483.3~
OJ
yS' 380 1046.8 351.88 1.4165 i.0074 1.4717 425.16 380 1082.7 351.41 1.4029 1.0055 1.4314 471.56
385 1030.3 359.26 1.4358 1.0137 1.4828 412.83 385 1068.1 358.59 1.4217 1.0117 1.4400 460.12
<
~ 390 1013.5 366.71 1.4550 1.0201 1.4940 400.87 390 1053.5 365.81 1.4403 1.0178 1.4486 449.02
395 996.61 374.20 1.4741 1.0264 1.5050 389.31 395 1.4588 1.0240 1.4570 438.25
~ 400 979.46 381.76 1.4931 1.0328 1.5160 378.15 400
1038.7
1023.9
373.07
380.38 1.4772 1.0301 1.4654 427.83
z
~ 410 944.64 397.03 1.5308 1.0455 1.5372 357.14 410 994.00 395.12 1.5136 1.0425 1.4818 408.08
'jn 420 909.27 412.50 1.5681 1~0582 1.5570 337.98 420 963.85 410.01 1.5495 1.0548 1.4973 389.82
....
co 430 873.59 428.16 1.6050 1.07(J7 1.5747 320.76 430 933.58 425.06 1.5849 1.0671 1.5116 373.10
co
~ 440
450
837.87
802.44
443.98
459.94
1.6413
1.6772
1.0831
1.0953
1.5894
1.6006
305.55
292.38
440
450
903.34
873.30
440.24
455.55
1.6198
1.6542
1.0793
1.0915
1.5245
1.5358
357.95
344.38
:u
-I
460 767.68 475.98 1.7i25 1.1072 1.6079 281.20 460 843.62 470.95 1.6881 1.1035 1.5452 33~j5 F
r
Z
30.00 MIa 35.00MPa m
:D
180 1599.5 97.057 0.4514 0.8014 1.1683 1171.8 185 1593.2 105.19 0.4789 0.8045 1.1681 1164.9 :D
185 1587.7 102.90 0.4835 0.8027 1.1704 1149.4 190 1581.6 111.04 0.5101 0.8067 1.17.08 1143.2 ~
190 1576.0 108.76 0.5147 0.8049 1.1732 1127.4 195 1570.1 116.90 0.5405 0.8096 1.1741 1121.8 :x:
195 1564.2 114.63 0.5453 c).8078 1.1767 1105.6 200 1558.6 122.78 0.5703 0.8129 1.1779 llOO.7 »
z
200 1552.5 120.53 0.5751 0.8112 1.1806 1084.1 205 1547.1 128.68 0.5994 0.8167 1.1820 1080.0
205 1540.7 126.44 0.6043 0.8149 1.1849 1062.9 210 1535.6 134.60 0.6280 0.8207 1.18(;3 1059.6
c
210 1529.0 132.38 0.6329 0.8190 1.1894 1042.1 215 1524.1 140.54 0.6559 0.8251 1.1909 1039.6 ;t:
215 1517.3 138.34 0.6610 0.8234 1..1942 1021.7 220 1512.6 146.51 0.6834 0.8296 1.1957 1019.9 ~
220 1505.5 144·32 0.<?885 0.8279 1.1992 1001.6 225 1501.1 152.50 0.7103 0.8342 1.2006 1000.6 m
225 1493.8 15p.33 0.7155 0.8326 1.2043 981.81 230 f489.6 158.52 0.736.7 0.8390 1.2056 981.61 l>
230 1482.0 156.36 0.:1 420 0;8374 1.2096 962J7 235 1478.1 164.56 0.7627 0.8439 1.2107 962.97 m
:t
235 1470.2 162.42 0.7681 0.8424 1.2149 943.26 240 14C6.6 170.63 0.7883 0.8489 1.2159 944.65 :D
240 1458.'4 168.51 0.7937 ' 0.8474 1.2204 924.47 245 1455.1 176.72 0.8134 0.8540 1.2212 926.67
245 1446.6 174.63 0.8189 0.8525 1.2259 906.00 250 l443.6 182.84 0.8381 0.8591 1.226.6 909.00
250 1,434.8 180.77 0.8438 0.8577 1.2315 887.84 255 1432.1 188.98 0.8625 '0.8643 1.2320 891.64
25,5 1422.9 186.94 0.8682 0.8629 1.2372 869.98 260 1420.6 195.16 0.8864 0.8695 1.2375 874.59
260 1411.0 193.15 0.8923 0.8681 1.2430 .852,42 265 1409.1 201.36 0.9.101 0.8748 1.2430 8'57.84
265 1399.1 199.38 0.9160 0.8734 1.2489 835.15 270 1397.5 207.59 .0.9333 0.8801 1.2486 841.38
270 1387.2 205.63 0.9394 0.8788 1.2548 818.17 275 1386.0 213.85 0.9563 0.8854 1.2543 825.21
275 1375.2 211.92 0.9625 0.8842 1.2609 801.47 280 1374.4 220.13 0.9790 0.8908 1.26<,>0 809.32
280 1363.2 218.24 0.9853 0.8896 1.2670 785.04 285 1362.8 226.45 1.0013 0.8962 1.2658 793.71
285 1351.2 224.59 1.0077 0.8951 1.2732 768.88 . 290 1351.2 232.79 1.0234 0.9017 1.2716 778.38
290 1339.1 230.98 1.0299 0.9006 1.2794 752.99 295 1339.5 239.16 1.0452 0.9072 1.2775 763.31
295 1326.9 237.39 1.0519 0.9061 1.2858 737.36 300 1327.8 245.57 1.0667 0.9127 1.2835 748.51
300 1314.8 243.83 1.0735· 0.9117 ·1.2922 721.99 305 1316.1 252.00 1;0880 0.9182 . 1.2895 733.98
305 1302.5 250.31 1.0949 0.91,3 1.2987 706.89 310 1304.4 258.46 1.1090 0.9238 1.2956 719.71
310 1290.2 256.82 1.1161 0.9229 1.3053 692.03 315 1292.6 264.95 1.1298 0.9294 1.3017 705.70
315 1277.9 263.37 1.1371 0.9286 1.3120 677.44 320 1280.8 271.48 1.1503 0.9350 1.3079 691.95

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 TABLE. 9. Thermodynamic properties of HFC-134a in the single-phase region - Continued
---------- - -- -- - --- -

T h s w s c,. w
Cv '
~ T P h ~
K kg rm3 kJlkg kJ/(kgK) kJ/(kgK) kJ/(kgK) nils K kg/Ii13 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) I1l/s

30.00 MPa 35.00 MPa ....

:::J:
320 1265.5 269.94 1.1578 0.9343 1.3188 663.10 325 1269.0 278.03 1.1706 0~9407 1.3141 678.46 m
325 1253.0 276.55 0.9464' 665.23 II
1.1783 0.9400 1.3256 649.02 330 1257.1 284.62 1.1907 1.3204
3:
330 1240.5 283.20 1.1986 0.9458 1.3325 635.20 335 1245.2 291.24 1.2106 0.9521 1.3268 652.25 o
335 1228.0 289.88 1.2187 0.9516 1.3395 621.64 340 1233.3 297.89 1.2304 0.9579 1.3331 639.54 c
340 1215.3 296.59 1.2386 0.9574 1.3465 608.33 345 1221.3 304.51- 1.2499 0.9636 1.3396 627.08 -<
z
345 1202.6 303.35 1.2583 0.9632 1.3537 595.29 350 1209.3 311.28 1.2692 0.9694 1.3460 614.89 »
350 1189.8 310.13 1.2778 0.9691 1.3608 582.52 355 1197.3 318.03 1.2883 0.9'152 1.3525 602.96 3:
355 1177.0 316.95 1.2971 0.9750 1.3680 570;01 360 1185.2 324.81 1.3073 0.9811 1.3590 591.29 (5
360 1164.1 323.81 1.3163 0.9809 1.3753 557.78 365 1173.1 331.62 1.3261 0.9869 1.3655 579.89 -0
365 1151.1 330.71 1.3354 0.9869 1.3826 545.82 568.75 II
370 1138.1 337.64 1.3542 0.9928 1.3899 534;15
370
375
1161.0
1148.8
338.47 1.3447 0.9928 1.3720
557.89
o
345.34 1.3632 0.9987 1.3785 "'C
375 1125.0 344.61 1.3729 0.9988 1.3972 522.76 380 1136.6 352.25 1.3815 1.0046 1.3850 547.30 m
ll,
380 1111.9 351.61 1.3915 1.0048 1.4045 511.66 385 1124.4 359.19 1.3996 1.0106 1.3915 536.98 ....
385 1098.7 358.65' 1.4099 1.0108 1.4117 500.86 390 1112.2 366.17 L4176 1.0~65 1.3979 526.94 iii
390 1085.4 365.73 1.4281 1.0168 1.4190 490.36 395 1099.9 373.17 1.4355 1.0225 1.4043 517.18 en
395 1072.1 372.84 1.4463 1.0229 1.4261 480.16 400 1087.7 380.21 1.4532 1.0285 1.4107 507.70 o
-n
400 1058.8 379.99 1.4643 1.0289 1.4332 470.27 410 1063.1 394.38 1.4881 1.0404 1.4231 489.60 ~
410 1032.0 394.39 1.4998 1.0410 1.4471 451.45 420 1038.6 408.67 1.5226 1.0524 1.4352 472'.64 ....
420 1005.2 408.93 1.5348 1.0532 1.4604 433.90 430 1014.2 423.08 1.5565 1.0645 L4469 456.83 :...
430 978.35 423.60 1.5694 1.0653 1.4731 417.67 1.4580 442.17 i\)
440 989.87 437.61 1.5899 1.0765
440 951.58 438.39 1.6034 1.0774 1.4849 402.75 450 965.11 452.24 1:6228 1.0885 1.4685 428.65 ~
m
450 925.00 453.30 1.6369 1.0895 1.49.57 389.13 460 94UO 466.98 1.6552 1.1005 1.4783 416.26 -f
II
40.00 MPa
:'"

50.00MPa
».
-n
r
c:
185 1598.4 107.49 0.4744 0.8063 1.1659 1179.8 185 1608 ..5 112.12 0.4657 0.8099 1.1622 1208.2 o
:- 190 1587.1 113.33 0.5055 0.8085 1.1685 1158.5 190 1597.5 117.94 0.4967 0.8121 1.1646 1181-.6 II
"'D
::r 195 1575.7 119.18 0.5359 0.8113 1.1717 1137.4 195 1586.6 123.77 0.5270 0.8;49 1.1676 1167.2 o
m
~ 200 1564.4 125.05 0.5656 0.8147 1:1754 1116.7 200 1575.") 129.61 0.5566 0.8182 1.1710 1147.2 ....
:::J:
205 1564.~
o
::r
(1) 210
1553.2
1541.9
130.93
136.84
0.5947
0.6232
0.8184
0.8225
1.1793
1.1835
1096.4
1076.4
205
210 1553.9
135.48
141.36
0.5856
0.6139
0.8219
0.8259
1.1748
1.1787
1127.6
1108.3
»
Z
? 215 1530.6 142.77 0.6511 0.8267 1.1880 1056.8 ; 215 1543'<) 147.27 0.6417 0.8301 1.1829 1089.3 m
220 1037.5, %
~
1519.4 148.72 0.6784 0.8312 1.1926 220 1532.2 153.19 0.6690 0.8346 1.1873 1070.8
225 1508.1 154.70 0.7053 0.8359 1.1973 1018.6 225 1521.4 159.14 0.6957 0.8392 1.1917 1052.6· ~
c 230 1496.9 160.69 0.7316 0.8406 1.2021 1000.0. 230 1510.1 165.11 0.7219 0.8439 1.1962 1034.7 9....
~ 235 1485.7 166.72 0.7576 0.8455 1.2071 981.82 235 1499.9 171.10 0.7477 0.8487 1.2009 1017.3 w
~

~
~
240
245
250
1474.5
1463.3
1452.1
172.77
178.84
184.94
0.7830
0.8081
0.8327
0.8505
0.8555
0.8606
1.2121
1.2171
1.2222
963.93
946.38
929.15
'240
245
250
1489.2
1478.5
1467.S
177.12
183.16
189.22
0.7730
0.7979
0.8224
0.8536
0.8586
0.8636
1.2055
1.2103
1.2151
1000.1
983.35
966.87
-
»
z 2~5 1440.9 191.06 0~8570 0.8657 1.2274' 912.23 255 1457.1 195~31 0.8466 0:8687 1.2199 950.72
9 260 1429.7 197.21 0.8808 0.8709' 1.2326 895.63 260 1446.5 201.42 0.8703 0.8738 1.2247 934.88
9' 265 1418.5 203.39 0.9044 0.8761 ' 1.2379 879.34 ' 265 1435.9 207.56 0.8937 0.8790 1:2296 919.35 ......
.....
co
co 270 1407.3 209.59 0.9276 0.8814 1.2432 863.34 270 1425.2 213.72 0.9167 0.8842 1.2345 904.12 ~
~

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~ -...J
9. Thermodynamic properties of HFC-134a in the single-phase region - Continued
"tJ
:r
TABLE
'"
CX)

~
------

T p h S Cll ~ W T il h S Cll ~ W
o:r K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls K kg!m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls
CD
~
JJ 40.00 MPa 50.00 MPa
~
C 275 1396.1 215.82 0.9504 0.8867 1.2486 847.63 275 14146 219.90 0.9394 0.8894 1.2395 889.19
Q)
§! 280 1384.9 222.08 0.9730 0.8921 1.2540 832.21 280 14040 226.11 0.9618 0.8947 1.2445 874.55
285 1373.6 228.36 0.9952 0.8974 1.2595 817.08 285 13935 232.35 0.9839 0.9000 1.2495 860.20
<
~ 290 1362.4 234.67 1.0172 0.9028 1.2650 802.22 290 1382.9 238.61 1.0056 0.9053 1.2545 846.13
I\) 295 1351.2 241.01 1.0388 0.9083 1.2706 787.63 295 1372.4 244.89 1.0271 0.9107 1.2596 832.33
~
300 1339.9 247.38 1.0602 0.9138 1.2762 773.32 300 1361.8 251.21 1.0483 0.9161 1.2647 818.80
z
? 305 1328.7 253.78 1.0814 0.9193 1.2818 759.27 305 1351.3 257.54 1.0693 0.9215 1.2698 805.54
91 310 1317.4 260.20 1.1023 0.9248 1.2875 745.49 310 1340.8 263.90 1.0900 0.9270 1.2750 792.54
..... 315 1306.1 266.65 1.1229 0.9304 1.2932 731.97 315 1330.3 270.29 1.1104 0.9325 1.2802 779.80
co
co
~ 320
325
1294.8
1283.5
273.13
279.64
1.1433
1.1635
0.9359
0.9416
1.2990
1.3048
718.71
705.71
320
325
1319,8
1309.3
,276.71
283.15
1.1306
1.1506
0.9380
0.9435
1.2854
1.2906
767.32
755.09
:n
~
330
335
1272.2 286.18 1.1835 0.9472 1.3107 692.96 330 1298,8 289.61 1.1703 0.9491 1.2959 743.11 r=
r
1260.8 292.75 1.2032 0.9529 1.3165 680.47 335 1288,4 296.11 1.1899 0.9547 1.3012 731.38
Z
340 1249.5 299.35 1.2228 0.9586 1.3224 668.24 340 1277.9 302.63 1.2092 0.9603 1.3065 719.90 m
345 1238.1 305.97 1.2421 0.9643 1.3284 656.26 345 1267,5 309.17 1.2283 0.9659 1.3118 708.66 Jl
350 1226.7 312.63 1.2613 0.9700 1.3343 644.54 350 1257,0 315.74 1.2472 0.9716 1.3171 697.67
•
Jl
355
360
1215.3
1203.9
319.32 1.2803 0.9758 1.3403 633.07 355 1246,6 322.34 1.2659 0.9773 1.3225 686.91
~
326.03 1.2991 0.9815 1.3463 621.86 360 1236.2 328.97 1.2845 0.9830 1.3278 676.40 ::J:
365 1192.5 332.78 1.3177 0.9874 1.3523 610.90 365 1225.8 335.62 1.3028 0.9887 1.3332 666.12 »
Z
370 1181.1 339.56 1.3361 0.9932 1.3583 600.20 370 1215.5 342.30 1.3210 0.9945 1.3385 656.08
375 1169.7 346.36 1.3544 0.9990 1.3643 589.76 375 1205.1 1.3439 646.27
C
349.01 1.3390 1.0002
380 1158.2 353.20 1.3725 1.0049 1.3702 579.57 380 1194,8 355.74 1.3568 1.0060 1.3493 636.70 ;r:
385 1146.8 360.07 1.3904 1.0108 1.3762 569.64 385 1184.4 362.50 1.3745 LOll 8 1.3546 627.37 P
390 1135.3 366.96 1.4082 1.0166 1.3821 559.97 390 1174.2 369.29 1.3920 1.0176 1.3600 618.26 OJ
395 1123.9 373.89 1.4259 1.0225 1.3880 550.56 395 1163.9 376.10 1.4094 1.0234 1.3653 609.39 »
m
400 1112.4 380.84 1.4434 1.0285 1.3939 541.41 400 1153,6 382.94 1.4266 1.0293 1.3706 600.74 ::J:
410 1089.6 394.84 1.4779 1.0403 1.4055 523.90 410 1133.2 396.70 1.4606 1.0410 1.3811 584.14 Jl
420 1066.8 408.95 1.5120 1.0522 1.4168 507.42 420 1112.9 410.56 1.4940 1.0528 1.3916 568.44
430 1044.2 423.18 1.5454 1.0642 1.4278 491.99 430 1092.8 424.53 1.5268 1.0646 1.4018 553.64
440 1021.6 437.51 1.5784 1.0761 1.4385 477.59 440 1072.8 438.60 1.5592 1.0765 1.4119 539.71
450 999.34 451.95 1.6108 1.0881 1.4487 464.21 450 1053.0 452.77 1.5910 1.0883 1.4218 526.64
460 977.22 466.48 L6428 1.1001 1.4585 451.83 460 1033.5 467.04 1.6224 l.lOO3 1.4315 514.41

60.00 MPa 70.00 MPa

185 1618.1 116.78 0.4574 0.8136 1.1591 1235.1 185 1627.2 121.46 0.4493 0.8171 1.1565 1260.6
190 1607.4 122.58 0.4883 0.8157 1.1614 1215.0 190 1616.8 127.25 0.4802 0.8192 1.1586 1241.1
195 1596.8 128.39 0.5185 0.8184 1.1642 1195.3 195 1606.5 133.05 0.5103 0.8219 1.1613 1221.9
200 1586.2 134.22 0.5480 0.8217 1.1674 1175.9 200 1596.2 138.86 0.5398 0.8252 1.1644 1203.0
205 1575.7 140.07 0.5769 0.8254 1.1710 1156.8 205 1586,0 144.69 0.5686 0.8288 1.1678 1184.5
210 1565.2 145.93 0.6052 0.8293 1.1748 1138.2 210 1575,8 150.54 0.5968 0.8327 1.1715 1166.4
215 1554.7 151.82 0.6328 0.8335 1.1788 1119.8 215 1565,6 156.41 0.6244 0.8368 1.1754 1148.6
220 1544.2 157.72 0.6600 0.8379 1.1829 1101.9 220 1555.5 162.29 0.6515 0.8412 1.1793 1131.2

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 TABLE 9. Thermodynamic properties of HFC·134a in the single·phase region Continued

T p h s __
C,,_ ~ w T p h s C" ~ ~
K kg/m3 kJ/kg kJ/(kgK) kJ/(kgK) kJ/(kgK) mls K kg/mJ kJ/kg kI/(kgK) kJ/(kgK) kJ/(kgK) mls

'60.00 MPa 70.00 MPa

-4
J:
225 1533.8 163.55 0.6866 0.8424 U872 1084.3 225 1545.4 168.20 0.6780 0.8457 I.J834 1114.2 m
230 1.1876 1097.5
:tJ
1523.4 169.59 0.7128 0.8411 1.191S 1067.1 230 1535.4 174.13 0.7041 0.8503
3:
235 1513.1 175.56 0.7384 0.8519 1.1959 1050.2 235 1525.4 180.08 0.7296 0.8550 1.1918 1081.2 o
240 1502.8 181.55 0.7637 . 0.8567 1.2003 1033.7 240 15(5.5 186.05 0.7548 0.8593 1.1961 1065.2 c
245 1492.5 181.56 0.7885 0.8616 1.2048 1017.5 245 1505.6 192.04 0.7195 0.8647 1.2004 1049.5 <
z
250 1482.3 193.50 0.8128 0.8666 1.2094 1001.7 250 1495.1 198.05 0.8038 0.8695 1.2048 1034.2 »
255 1472.0 199.56 0.8368 0.8116 1.2139 986.21 255 1485.8 204.09 0.8277 0.8746 1.2092 1019.2 3:
260 1461.9 205.14 0.8605 0.8167 1.2185 971.01 260 1476.0 210.14 0.8512 0.8796 1.2136 1004.6 5
o"
265 1451.7 211.&4 0.8837 0.8818 1.2232 956.11 265 1466.3 216.22 0.8744 0.8847 1.2180 990.25
270 1441.6 217.91 0.9066 0.8810 1.2278 941.51 270 1456.6 222.33 0.8972 0.8893 1.2225 976.18
:u
275 1431.5 0.9197 0.8949 1.2269 962.41
280
285
1421.4
1411.3
224.12
230.30
236.50
0.9292
0.9514
0.9734
0.8922
0.8974
0.9026
1.2325
1.2372
1.2419
927.21
913.20
899.47
275
280
285
1446.9
1437.2
1427.6
228.45
234.59
240.76
0.9418
0.9636
0.9001
0.9053
1.2314
1.2359
948.92
935.71
"m
:tJ
-4
290 1401.3 242.72 0.9950 0.9079 1.2466 886.03 290 1418.0 246.95 0.9852 0.9105 1.2405 922.78 iii
295 1391.3 248.96 1.0164 0.9132 1.2514 872.85 295 1408.5 253.17 1.0064 0.915& 1.2450 910.11 -0
300 1381.3 255.23 1.0374 0.9186 1.2562 859.94 300 1398.9 259.41 1.0274 0.9211 1.2496 897.71 o
305
310
1371.4
1361.4
261.52
267.&4
1.0582
1.0788
0.9240
0.9294
1.2610
1.2658
847.29
834.90
305
310
1389.5
1380.0
265.66
271.95
1.0481
1.0685
0.9264-
0.9313
1.2542
1.2588
885.56
873.67
"....
:..
315 1351.5 274.l8 1.0991 0.9348 1.2706 822.77 315 1370.6 278.25 1.0887 0.9312 1.2634 862.02 :..
320 1341.7 280.55 1.1191 0.9403 , 1.2755 , 810.89 320 1361.2 284.58 1.1086 0.9426 1.2680 850.62 bI
325 1331.8 286.94 1.1389 0.9457 1.2804 799.25 325 1351.9 290.93 1.1283 0.9480 1.2727 839.46 -f
m
-4,
330 1322.0 293.35 1.1585 0.9512 1.2853 787.86 330 1342.6 297.31 1.1478 0.9535 1.2774 828.53
:tI
335
340
1312.2
1302.4
299.79
306.25
1.1779
1.1971
0.9568
0.9623
1.2902
1.2952
776.70
765.79
335
340
1333.3
1324.1
303.71
310.13
1.1670
1.1861
0.9589
0.9645
1.2821
1.2868
817.83
807.36
»
."
345 1.2049 1.2915 797.12 r-
1292.1 312.74 1.2160 0.9619 1.3001 755.10 345 1314.9 316.58 0.9700 c:
350 1283.0 319.26 1.2347 0.9735 1.3051 744.65 350 1305.1 323.05 1.2235 0.9755 1.2962 787.10 o
:.. 355 1273.3 325.79 1.2533 0.9791 1.3101 734.43 355 1296.6 329.54 1.2419 0.9811 1.3010 777.29 :a
'U
:r 360 1263.6 332.36 1.2716 0.9848 1.3151 724.43 360 1287.S' 336.06 1.2601 0.9867 1.3058 767.70 o
m
c 365 1253.9 338.95 1.2898 0.9904 1.3201 714.66 365 1278.4 342.60 1.2782 0.9924- 1.3106 758.33 -4
."
370 1244.3 345.56 1.3078 0.9961 1.3251 705.11 370 1269.4 349.16 1.2961 0.9980 1.3153 749.16 ::r:
o
':I'
J>
375 1234.8 352.20 1.3256 1.0018 1.3301 695.78 375 1260.4 355.75 1.3137 1.0037 1.3202 740.20 Z
~ 380 1225.2 358.86 1.3433 1.0076 1.3351 686.66 380 1251.4 362.36 1.3313 1.0093 1.3250 731.44 m
:D 385 1215.1 365.55 1.3608 l.0133 1.3401 677.16 385 1242.5 369.00 1.3486 1.0150 1.3298 722.89 X
!l
c
;
390
395
1206.2
1196.7
372.26
379.00
1.3781
1.3953
1.0191
1.0249
1.3451
1.3502
669.08
660.60
390
395
1233.6
1224.8
375.66
382.35
1.3658
1.3828
1.020&
1.0265
1.3346
1.3394
714.53
706.37 9....
CI)
400 1187.3 385.76 1.4123 1.0306 1.3552 652.34 400 1216.0 389.06 1.3997 1.0323 1.3443 698.40

-
~
<
~
410 1168.6 399.37 1.4459 1.0423 1.3652 636.42 410 1198.6 402.55 1.4330 1.0438 1.3539 683.04 »
420 1150.0 413.07 1.4789 1.0540 1.3751 621.32 420 1181.3 416.14 1.4658 1.0554- 1.3636 668.42
~ 430 1131.6 426.87 1.5114 1.0657 1.3850 607.02 430 1164.1 429.82 1.4980 1.0671 1.3733 654.53
z 440 1113.4 440.17 1.5433 1.0775 1.3948 593.49 440 1147.2 443.60 1.5297 1"0783 1.3829 641.35
9 450 1095.4 454.17 1.5748 1.0893 1.4045 580.72 450 1130.5 457.48 1.5608 1.0905 1.3925 628.86
JI' 460 1077.6 468.86 1.6057 UOIt 1.4141 568.70 460 1113.9 471.45 15916 1.1023 1.4020 617.03
.....
C) ~
C) <0
~

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