Sri Chaitanya IIT Academy., India.: 2012 - PAPER-I

Sri Chaitanya IIT Academy., India.
AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sri Chaitanya-Jr.Chaina-I Date: 02-12-19
Time: 09:00 AM to 12:00 Noon Max.Marks:210
Name of the Student: ___________________ I.D. NO:
2012_PAPER–I
02-12-19_Sri Chaitanya-Jr.Chaina-I_Jee-Adv (2012_P1)
CTA-17_Syllabus
Mathematics : 22-04-2019 TO Till Date (29-11-2019)
Physics : 22-04-2019 TO Till Date (29-11-2019)
Chemistry : 22-04-2019 TO Till Date (29-11-2019)

Sri Chaitanya IIT Academy 02-12-19_Sri Chaitanya-Jr.Chaina-I_Jee-Adv(2012_P1)_CTA-17
JEE-ADVANCE-2012-P1-Model
Time: 09:00 AM to 12:00 Noon IMPORTANT INSTRUCTIONS Max Marks: 210

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Single Correct Choice 3 -1 10 30
Sec – II(Q.N : 11 – 15) Questions with Multiple Correct Choice 4 0 5 20
Sec – III(Q.N : 16 – 20) Questions with Integer Answer Type 4 0 5 20
Total 20 70
CHEMISTRY:
Total 20 70
MATHEMATICS:
Total 20 70
Sec: Sr. Chaina-I space for rough work Page 2

PHYSICS Max Marks: 70
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
1. In a special quasi-static process, an ideal mono-atomic gas is supplied heat in such a
way that its volume increases and frequency of collisions of its atoms on unit area of
the walls of the container remains constant. What is the molar heat capacity of the
gas?
A) 0 B) 2R C) 3R D) 4.5R
2. One mole of a mono-atomic gas is supplied heat in such a way that its molar specific
heat during the heating process is 2R, here R is the universal gas constant. If due to
heating, volume of the gas is doubled, by what factor does its temperature change?
1 1
A) B) C) 2 D) 4
4 2
3. Volumes V1 and V2 of a liquid are maintained in two calorimeters at temperatures 1
and  2   2  1  . Coefficient of volume expansion of the liquid is independent of
temperature. Now liquids from both the calorimeter are poured into another
calorimeter of negligible heat capacity. Heat loss to the surroundings is strictly
restricted. Final volume V of the mixture after they are well mixed is best represented
by the equation
A) V = V1 + V2 B) V > V1 + V2 C) V < V1 + V2 D) Insufficient information
4. When two soap bubbles of different radii coalesce, some portions of their surfaces
make a common surface. At any point on the circumference of the common surface,
the three surfaces meet at angles  ,  and  . What relation should these angles bear?
A)    B)      C)      D)     

5. Radii of a slightly tapered cylindrical wire of length L at its ends are a and b. It is
stretched by two forces each of magnitude F applied at its ends. The forces are
uniformly distributed over the end faces. If Young’s modulus of material of the wire is
denoted by Y, extension produced is
4FL FL FL FL
A) 2 B) 2 C) 2 D)
  a  b Y   a  b Y   a  b Y abY
6. One end of a long iron chain of linear mass density  is fixed to a sphere of mass m
and specific density 1/3 while the other end is free. The sphere density of iron is 7; the
height h above the bed of the lake at which the sphere will float in equilibrium is
(Assume that the part of the chain lying on the bottom of the lake exerts negligible
force on the upper part of the chain).
16m 7m 5m 8m
A) B) C) D)
7 3 2 3
7. A solid sphere of uniform density and radius R exerts a gravitational force of
attraction F1 on a particle placed at P. The distance of P from the center of the sphere
R
is 2R. A spherical cavity of radius is now made in the sphere. The sphere (with
2
F
cavity) exerts a gravitational force F2 on the same particle at P. The ratio 1 is:
F2
9 7 1 4
A) B) C) D)
7 9 2 3
8. A rod of mass m and length 2R can rotate about an axis passing through O in vertical
plane. A disc of mass m and radius R/2 is hinged to the other end P of the rod and can
freely rotate about P. When disc is at lowest point both rod and disc has angular
0
velocity  . If rod rotates by maximum angle   60 with downward vertical, then 
in terms of R and g will be (all hinges are smooth).
9g 3g 1 g
A) B) C) D) none of these
16 R 23R 3 R
9. Two particles, each of mass m are attached to the two ends of a light string of length l
which passes through a hole at the center of a table. One particle describes a circle on
the table with angular velocity 1 and the other describes a circle as a conical
pendulum with angular velocity  2 below the table as shown in figure. If l1 and l2 are
the lengths of the portion of the string above and below the table, then:
2 2
l  l  1 1 l 1 1 l
A) 1  22 B) 1  12 C) 2
 2 D) 2
 2
l2 1 l2  2 1  2 g 1  2 g
10. A string of negligible mass going over a clamped pulley of mass m supports a block of
mass M as shown in the figure. The force on the pulley by the clamp is given:
A) 2Mg B) 2mg
2 2 2 2
C)  M  m M g D)  M  m m g
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
11. Figure shows some velocity versus time graphs:
a) b)
c) d)
Only some of these can be realised in practice. These are:

A) diagram-(a) B) diagram-(b) C) diagram-(c) D) diagram-(d)

12. A disk moving on a frictionless horizontal table collides elastically with another
identical disk as shown. The directions of motion of the two disks make angle  and
 with the initial line of motion as shown. Then:
0 0 0 0
A)   30 B)   60 C)   30 D)   60
13. A string is wrapped over a uniform cylinder, as shown in diagram. When cylinder is
released, string unwraps without any slipping and cylinder comes down. Which of the
following is true?
A) Work done by Tension force on the cylinder is zero

B) Work done by the Tension is negative
C) Ratio of rotational kinetic energy and translational kinetic energy is 1/2
D) Ratio of rotational kinetic energy to translational kinetic energy is 2
14. A uniform ting placed on a rough horizontal surface is given a sharp impulse as shown
in the figure. As a consequence, it acquires a linear velocity of 2m/s. If coefficient of
friction between the ring and the horizontal surface is 0.4:
A) Ring will start pure rolling after 0.25 s

B) When ring will start pure rolling its velocity is 1 m/s
C) After 0.5 s from impulse its velocity is 1 m/s
D) After 0.125 s from impulse its velocity is 1 m/s

15. A tank is filled upto a height h with a liquid and is placed on a platform of height h
from the ground. To get maximum range xm a small hole is punched at a distance of y
from the free surface of the liquid. Then:
A) xm  2h B) xm  1.5h C) y  h D) y  0.75h
SECTION – III
INTEGER TYPE
(This section contains 5 questions. The answer to each question is a single digit integer ranging from 0 to 9.
The correct digit below the question number in the ORS is to be bubbled ).
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
16. A uniform rod of length b capable of turning about its end which is out of water, rests
inclined to the vertical. If its specific gravity is 5/9, find the length immersed in water
b
is . Find x.
x
17. Two identical solid spheres each of radius R are placed in contact with each other. It is
observed that the gravitational attraction between the two is proportional to Rn. Find
the value of n.

18. A soap film of thickness h = 1.0 m is formed in a circular wire loop of radius r = 5.0
cm. If the soap film is punctured in the center, the hole thus made spreads
symmetrically. How long will the soap film take to disappear? Assume that thickness
of the soap film remains almost unchanged during the process. Surface tension and
density of the soap solution are   0.025 N/m and   1000 kg/m3 respectively. Give
time in milliseconds.
19. A cylindrical vessel is filled with water up to a height h0=1.0m and then a large
number of small iron balls are gently dropped in it until the top most layer of the balls
becomes completely submerged in water as shown in the figure. Density of iron is
1  7140kg / m3 .and density of water is 0  1000kg / m3 . If average density of the
contents is   4070kg / m3 . Find the height of the water level in the vessel with the iron
balls.
20. In the setup shown, the block B can slide on a vertical guide rigidly fixed to the wedge
C. Masses of the block A, the wedge C and the block B are m, 2m and 3m and cosine
of angle of inclination of the inclined face of the wedge with the horizontal is 2/3. The
pulley and the thread are ideal and there is no friction between any of the surfaces in
contact. The block B is released from a height 27 cm above the floor. Find the
displacement of the wedge when the block B touches the floor (in cm).

CHEMISTRY Max Marks: 70
SECTION – I
21. Which of the following radical is most stable
CH2
CH 3  C  CH 2 CH 2  CN
A) B) C) D)
22. Correct IUPAC name of Pyruvic acid is
A) 3-oxo-propanoic acid B) 2-oxo-propanoic acid
C) Propane dioic acid D) Butane dioic acid
23. Which of the following molecule will exhibit diastereomerism.
A) B)
C) D) Br
24. When 0.2g of 1-butanol(M.W. 74) was burnt in a suitable apparatus, the heat evolved
was sufficient to raise the temperature of 100 g of water by 10ºC. The heat of
combustion of 1-butanol in k.cal/mol is(specific heat of water = 1cal/g.ºc)
A) -370 B) 370 C) 148 D) -148

25. The phosphorus present in one gram of a phosphor-lipid is converted to magnesium
pyrophosphate (M.W = 222). The weight of magnesium pyrophosphate formed is
found to be 0.222g. The molecular weight of phosphor-lipid is (each molecule of
phosphor-lipid contain one phosphorus atom)
A) 500 B) 1000 C) 250 D) 125
26. The plot of log Kp vs 1T for a reaction is as shown below
log Kp 
60º
1
T
The H º for reaction is nearly

A) -8 Cal B) -16 Cal C) 8 Cal D) 16 Cal
27. Cleansing action of soap is due to
A) Emulsification of dirt(grease) in water through miscelle formation
B) solubilization of dirt in water by forming a protective layer surrounding dirt particle
C) Coagulating dirt particles by neutralizing the charge present on them
D) Increasing dipole-dipole attraction between dirt and water
28. The following properties are observed for an unknown element. Identify the element
from its properties
i) The neutral atom has two unpaired electrons
ii) One of the valence electrons in the ground state atom has ml=+1
iii) The maximum oxidation state is +4
iv) If the electron in hydrogen atom was excited to the same principal quantum level,
‘n’, as the valence electrons in an atom of this element and fell to the n-1 quantum
level, the photon emitted would have an energy 4.9×10-20J(1 eV = 1.6×10-19 J)
A) Ge B) Sn C) Te D) Se

29. The false statement among the following is
A) Both BeO and Al2O3 are amphoteric but BeO is more acidic than Al2O3
B) The acidic character of the hydroxides is in the order.
Mg  OH  2  Al  OH  3  B  OH  3
C) Borax on strongly heating above its melting point, melts to a liquid which then
solidifies to a transparent glassy bead that contain boric anhydride and sodium
metaborate
D) the solubility order is of KHCO3  NaHCO3  CaCO3
30. The false statement about the following reaction
4731273 K
C s   H 2O g    CO g   H 2 g 
A) It is known as coal gasification

B) It is a redox reaction
C) The product formed in this reaction is known as syn gas
D) It is an exothermic reaction
SECTION – II
31. Which of the following bases are more basic than MeNH 2
NH NH
NH2 NH2 NH2

A) B) NH C) D) Me4 NOH

32. Which of the following reactions will give recemic mixture as a product?
D
H 2 / Pd C
D2 / Pd C  


A) B) D
D2 / Ni  C H 2 / Ni C
   
C) D)
33. NaCl crystal is heated with excess of vapour of sodium metal. Pick out correct
statement(s)
A) Crsytal becomes yellow in colour
B) F-centre are formed
C) The crystal becomes n-type semi-conductor
D) The crystal becomes p-type semi-conductor
34. The correct statement(s) among following is/are
A) B2 H 6 is electron deficient molecule and can act as Lewis acid
B) Electron deficiency and incomplete octet are not same
C) In electron deficient molecules one electron pair is shared in more than one
covalent bond (delocalized) i.e., 3c-2e bonds
D) Electron deficiency is due to lack of sufficient number of electrons to form bonds
between all atoms in a molecule
35. Regarding borax the correct statement(s) is/are
A) It is a tetra nuclear species with four boron centres
B) It consists of two six membered hetero cyclic rings
C) It is a tetra metaborate
D) Its aqueous solution acts as basic buffer solution
SECTION – III
INTEGER TYPE
36. How many of the following carbocation will rearrange.
   O
 
, , , , ,
N 
Ph Ph
 
, , 
, Ph
 , HN O ,


, , , , 
 ,


 ,
37. (i) No.of diastereomeric pairs of given compound(M) are = X

CH3
CHOH
CHOH
CH2OH
(M)
(ii) No. of enantiomeric paris of mono bromination of given compound(M) are = Y

(iii)
OH
O
+ CH3MgBr Z CH4
(excess)
COOH
SH
( one molecule )
(iv)
1) Mg / dry ether
R  Br 2) H 2O

No.of Possible structures of R-Br give n-pentane in above reaction are = W
Then the value of (X+Z)-(Y+W)
38. G º for dissociation of weak acid (HA) is 7 K cal/mole at 27ºC. The pH of 0.1M
solution of sodium salt of HA is _____
39. 10 ml of a mixture of C2H4 & C3H8 on complete combustion gives 24 ml of CO2. The
volume of C3H8 in the original mixture is ______ ml
(Also volume are measured at same T & P)
40. Silica is composed of heterocyclic rings containing silicon and oxygen. The number of
atoms present in such a heterocyclic ring is

MATHEMATICS Max Marks: 70
SECTION – I
x  x  1
41. If 3x  2 y  1 acts as a tangent to y  f  x  at x  1 2 and if p  lim ,
x 0  e2 x   e 2 x 
f  f  
 2   2 

then,  pr =________
r 1
A) 1/2 B) 1/3 C) 1/6 D) 1/7

42. The curves C1 : y  x2  3 ; C2 : y  kx 2 , k  1 intersect each other at two different points.
The tangent drawn to C2 , at one of the points of intersection A   a, y1  a  0  meets
C1 again at B 1, y2  .  y1  y2  Then value of a = _____?
A) 4 B) 3 C) 2 D) 1
43. Tangent at P1 other than origin on the curve y  x 3 meets the curve again at P2 . The
area of P1P2 P3
tangent at P2 meets the curve again at P3 and so on ......... then equals
area of P2 P3 P4
A) 1 : 20 B) 1 : 16 C) 1 : 8 D) 1 : 2
d2 y dy
44. By introducing a new variable t , putting x  cos t , the expression 1  x 2  2
 x  y is
dx dx
transformed into :
d2 y d 2 y dy d2 y d2 y
A) y B) t  y C) y D)
dt 2 dt 2 dt dt 2 dt 2

45. In ABC orthocentre is (6,10) circumcentre is (2,3) and equation of side BC is
2x + y = 17.Then the radius of the circumcircle of ABC is
A) 4 B) 5 C)2 D) 3

  2x2  4  
46. If sin 1  sin  2 
   3 then x satisfies
 1  x 
  
A) x  1 B) x  1 C) x  1 D) x  1
47. The number of terms common between the two arithmetic progressions, 2+5+8+
…up to 50 terms and, 3 + 5 + 7 + 9 + ….up to 60 terms is
A) 24 B) 26 C) 25 D) None of these
1
2 4
 x  x  2 2 x 1 
48. The domain of the function f  x   9  27 3
 219  3  is
 
5
A)  3,3 B) 3, C)  ,   D) 0,1
2
 
49. The equation 2x = (2n + 1)  1  cos x  , (where n is a positive integer)
A) has infinitely many real roots B) has exactly one real root
C) has exactly 2n + 2 real roots D) has exactly 2n + 3 real roots
2
50. Let f  x   x 2  5 x  6 , then the number of real roots of  f  x    5 f  x   6  x  0 is
1) 1 2) 2 3) 3 4) 0
SECTION – II
51. Which of the following pairs of curves intersect orthogonally?
x2 y 2 x2 y 2 x2 y2 x2 y 2
A)   1 and  1 B)   1 and  1
31 41 91 19 71 17 31 23
x2 y 2 x2 y 2 x2 y2 x2 y 2
C)   1 and  1 D)   1 and  1
37 41 47 31 13 17 19 23
3
52. Given f  x    x  x 2 sin (1.5 a) – x sin a. sin 2a – 5 sin 1  a 2  8a  17  then:
3
A) f '  x   x 2  2x sin 6  sin 4sin8 B) f '  sin8  0
C) f ' x  is not defined at x = sin 8 D) f '  sin8  0
53. A line passes through (2, 0). The slope of the line, for which its intercept between
y = x – 1 and y = –x + 1 subtends a right angle at the origin, is/are
1 1
A) 3 B)  3 C) D) 
3 3
54. Let a  b and a , b are the roots of the equation x2   x    0. If   b 1, then the
2
x
equation log a    1  0 has at least one
b
A) root lying between  ,a  B) root lying between  b, 
C) negative root D) positive root
55. If the equation whose roots are the squares of the roots of the cubic x 3  ax 2  bx  1  0
is identical with the given cubic equation, then
A) a,b are roots of x 2  x  2  0 B) a = b = 0
C) a = b = 3 D) a = 0, b = 3
SECTION – III
INTEGER TYPE
1
56. Three normals are drawn from the point (c, 0) to the curve y 2  x, c  . One normal is
2
always the x-axis. Then the value of 4c for which other two normals are perpendicular
to each other is
57. Let f : R  R and g : R  R be twice differentiable functions satisfying
f ''  x   g ''  x  , 2 f ' 1  g ' 1  4 and 3 f  2   g  2   9 then the value of
15  f  4   g  4  is equal to
58. If Sn = 1.n + 2.(n–1) + 3.(n–2) + ……. + n.1 and S25  325 then  is
59. The number of solutions of the equation x2   x  4 x  3  0 is ([.]  denotes the greatest
integer function)
60. The ratios of the lengths of the sides BC and AC of a triangle ABC to the radius of a
circumscribed circle are equal to 2 and 3/2 respectively. If the ratio of the lengths of
  1
the bisectors of the interior angles B and C is    ,  &  being natural
 9  
numbers, then    is

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Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

Name of the Student: ___________________ I.D. NO:

Physics : 22-04-2019 TO Till Date (29-11-2019)

Chemistry : 22-04-2019 TO Till Date (29-11-2019)

Time: 09:00 AM to 12:00 Noon IMPORTANT INSTRUCTIONS Max Marks: 210

Sec: Sr. Chaina-I space for rough work Page 2

Sec: Sr. Chaina-I space for rough work Page 3

Only some of these can be realised in practice. These are:

Sec: Sr. Chaina-I space for rough work Page 6

A) Work done by Tension force on the cylinder is zero

A) Ring will start pure rolling after 0.25 s

Sec: Sr. Chaina-I space for rough work Page 7

Sec: Sr. Chaina-I space for rough work Page 8

Sec: Sr. Chaina-I space for rough work Page 9

Sec: Sr. Chaina-I space for rough work Page 10

The H º for reaction is nearly

Sec: Sr. Chaina-I space for rough work Page 11

A) It is known as coal gasification

NH2 NH2 NH2

Sec: Sr. Chaina-I space for rough work Page 12

37. (i) No.of diastereomeric pairs of given compound(M) are = X

Sec: Sr. Chaina-I space for rough work Page 14

Sec: Sr. Chaina-I space for rough work Page 15

A) 1/2 B) 1/3 C) 1/6 D) 1/7

C1 again at B 1, y2  .  y1  y2  Then value of a = _____?

Sec: Sr. Chaina-I space for rough work Page 16

49. The equation 2x = (2n + 1)  1  cos x  , (where n is a positive integer)

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