CONFIDENTIAL =. EHIJUN 2018/CEV432 ER SS UNIVERSITI TEKNOLOGI MARA FINAL EXAMINATION COURSE ENERGY BALANCES COURSE CODE CEV432 EXAMINATION : JUNE 2018 2 HOURS INSTRUCTIONS TO CANDIDATES 1 This question paper consists of three (3) questions. 2 ‘Answer ALL questions in the Answer Booklet. Start each answer on a new page. 3 Do not bring any material into the examination room unless permission is given by the invigitator. 4 Please check to make sure that this examination pack consists of: i) the Question Paper ii) an Answer Booklet - provided by the Faculty iii) aone~page Psychrometric Chart jv) a Chemical Process Principles Booklet ~ provided by the Faculty 5 Answer ALL questions in English, DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO This examination paper consists of 5 printed pages (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL, 2 QUESTION 1 (PO1, CO41, C1, C2, C2, C2) a) Define state property and give one (1) example of state property. EHIJUN 2018/CEV432 (3 marks) b) Figure 1 shows the phase diagram of pure water. Identify the phase of pure water at A, B, and C. c Triple point 1 Pressure Temperature Figure 1 Phase diagram of pure water ©) Byusing steam table, answer the following questions: (3 marks) i) Identify the saturation pressure, specific internal energy, and specific enthalpy of saturated water at 151.8°C. ii) Identify the phase of water at 350°C and 40 bars and its dew point. (3 marks) (2 marks) iil) Find the w, x, y and z value in Table 1. Describe the influence of pressure and temperature on the specific enthalpy based on your observations. (5 marks) Table 1 Unknown specific enthalpy in specific temperature and pressure f ‘Temperature . 5 Pressure. eo Soci | bar | w x 100 bars y Zz CONFIDENTIAL © Hak Cipta Universiti Teknologi MARACONFIDENTIAL 3 EHIJUN 2018/CEV432 d) Figure 2(a-d) show the response of the different processes. Identify each of the process either it is in steady state or transient state. (4 marks) @ (0) (co) (d) PSSIWN Figure 2 Process response over time QUESTION 2 (P02, CO2, C3, C4) a) Air at temperature of 45°C and 20% relative humidity is to be humidified adiabatically by humidifier. Water is being fed to the system in order to increase the humidity of the air at the outlet stream to 50% relative humidity. i) Sketch and label the process flow diagram. (2 marks) ii) Determine the final temperature of the humidified air. (3 marks) iii) Determine the amount of water being fed to the humidifier to maintain the outlet humidified air at 20 kg/min (7 marks) ‘Answer must be shown in the psychrometric chart. Detach and submit the psychrometric chart together with the answer. © Hak Cipta Universiti Teknolog! MARA CONFIDENTIALCONFIDENTIAL, 4 EHIJUN 2018/CEV432 b) The oxidation process of 1200 mol/h acetaldehyde production inside a reactor involves with concurrent reactions as represented in equation 1 and equation 2. The first reaction (R1) produces desired product whilst second reaction (R2) produces an acetic acid (CHsCOOH) as by product. Rt: CzHsOH (g) + 3 (g) > CHsCHO (g) + HzO (v) R2: 2CHsCHO (g) + O2 (g) >» 2CHsCOOH (g) The detailed flow diagram of the process is shown in Figure 3. All components at the both inlet and outlet streams of reactor are in the gas phase. Given the Cp (J/mol-"C) of specific components are: Ethanol (65.5), Acetaldehyde (54.7), Acetic Acid (66.5). i) Determine the standard heat of reaction for both reactions. (6 marks) ji) Determine the total heat released during the oxidation process using heat of reaction method (10 marks) ——— REACTOR > 8000 mol/h C2HsOH 6000 mol/h CzHsOH 1400 mol/h Oz 5300 mol/h No 5300 mol/h Nz 1200 mol/h CHsCHO 400 mol/h CHsCOOH 300°C, 1.5 atm 2000 mol/h HzO 300°C, 1.5 atm Figure 3 Process flow diagram of oxidation process QUESTION 3 (P02, CO2, C6) An adiabatic stirred tank shows in Figure 4 is used to heat 100 kg of 45 wt% glycol solution. The tank is equipped with an electrical heater and overhead stirrer which delivered 3500 W and 500 W of power, respectively. The glycol solution is initially at 15°C. The optimum operational temperature of heating process was set at 90°C. The heating process is required to be kept less than 2 hours in order to avoid glycol's degradation. Given the heat capacity of solution is 3.54 J/g-°C a) Derive an equation of heating process as a function of temperature versus time. (6 marks) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,CONFIDENTIAL, 5 EHIJUN 2018/CEV432 b) Predict the duration required for solution to reach 90°C when the heater delivers energy in two conditions: i) 100% of heater efficiency. ii) 80% of heater efficiency. Suggest the most appropriate energy to be supplied by the heater to maintain the concentration of the solution at optimum condition and justify the reason. (7 marks) 45 wt% glycol ‘solutions: Insulation Figure 4 Adiabatic stirrer tank END OF QUESTION PAPER (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,vey Bojouyay pisiontn edio eH © “WWILNaGIANOS yo 1s ors oo Below 0°C Properties and Enthalpy Deviation Lines Are For Ice 0 25 30 s Dry Bulb Temperature, °C gs Humid Volume, m?/4g Dry Air 15 120 135, a 090 ENt?ay Devaied sje nthe Dy ay 40. Ms 0.033 Foo 031 0.030 0.028 0.078 0027 0.028 0.025 0.028 0029 002 ‘021 0.020 nis ore 017 016 01s Foo 0.012 0.012 ont 0.010 0.008 0.008 ‘007 0.006 0.005 0.006 ‘0.002 ‘0.002 0.007 0.0 Moisture Content, kg/kg Dry Air ‘ai quepnys drop, WILNAGIANOD ALVHO ORLaWOYHOASE zevAgo/st0z NCHA