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A sample of iron ore was dissolved in acid and titrated with potassium manganate solution. The results were used to calculate the percentage of iron in the sample, which was found to be ___%. A sample of bleaching powder was dissolved and treated with potassium iodide. The liberated iodine was then titrated with sodium thiosulfate. The results were used to calculate the percentage of available chlorine in the bleaching powder sample, which was found to be ___%. A sample was shaken with iodine to react any ethyl mercaptan present. Excess iodine was back-titrated and the results used to calculate the percentage of ethyl mercapt

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427 views

Answer Key

A sample of iron ore was dissolved in acid and titrated with potassium manganate solution. The results were used to calculate the percentage of iron in the sample, which was found to be ___%. A sample of bleaching powder was dissolved and treated with potassium iodide. The liberated iodine was then titrated with sodium thiosulfate. The results were used to calculate the percentage of available chlorine in the bleaching powder sample, which was found to be ___%. A sample was shaken with iodine to react any ethyl mercaptan present. Excess iodine was back-titrated and the results used to calculate the percentage of ethyl mercapt

Uploaded by

James Sparrow
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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A 0.8040 g sample of iron ore was dissolved in acid.

The iron was reduced to Fe2+ and titrated with


47.22mL of 0.02242M KMnO4 solution. Calculate the result of the analysis in terms of % Fe

Balanced Chemical Equation:

𝑀𝑛𝑂4 − + 5𝐹𝑒2+ + 8𝐻+ → 𝑀𝑛2+ + 5𝐹𝑒3+ + 4𝐻2O

Calculation

Weight of Iron titrated

0.02242 𝑚𝑜𝑙 𝐾𝑀𝑛𝑂4 5 𝑚𝑜𝑙𝑒 𝐹𝑒 2+ 1 𝑚𝑜𝑙𝑒 𝐹𝑒 55.845 𝑔 𝐹𝑒


𝑤𝑒𝑖𝑔ℎ𝑡𝐹𝑒 = ( )(0.04722 𝐿)( )( )( )
1𝐿 1 𝑚𝑜𝑙𝑒 𝐾𝑀𝑛𝑂4 1 𝑚𝑜𝑙𝑒 𝐹𝑒 2+ 1 𝑚𝑜𝑙𝑒 𝐹𝑒
𝑤𝑒𝑖𝑔ℎ𝑡𝐹𝑒 = ____________
%Fe in sample

𝑤𝑒𝑖𝑔ℎ𝑡𝐹𝑒
%𝐹𝑒 = ( ) 𝑥100
0.8040 𝑔
%𝐹𝑒 = ___________

1.25 g of a sample of bleaching powder (OCl-) is dissolved in 100 mL of water. 25 mL of it is treated with
KI solution. The iodine so liberated required 12.5 mL of 0.4 M hypo solution (Na2S2O3) for complete
titration. Find percentage of available chlorine from the sample of bleaching powder

Balanced Chemical Equation:


− − + −
𝑂𝐶𝑙⬚ + 3𝐼⬚ + 2𝐻⬚ → 𝐶𝑙⬚ + 𝐼3− + 𝐻2 𝑂
−
𝐼3− + 2𝑆2 𝑂3−2 → 3𝐼⬚ + 2𝑆4 𝑂6−2
Calculation

Weight of Cl titrated in 25 mL aliquot

−
0.4 𝑚𝑜𝑙 𝑆2 𝑂3−2 1 𝑚𝑜𝑙𝑒 𝐼−
3 1 𝑚𝑜𝑙𝑒 𝐶𝑙⬚ 1 𝑚𝑜𝑙𝑒 𝐶𝑙 35.453 𝑔 𝐶𝑙
𝑤𝑒𝑖𝑔ℎ𝑡𝐶𝑙 = ( )(0.0125 𝐿)( )( )( − )( )
1𝐿 2 𝑚𝑜𝑙𝑒 𝑆2 𝑂3−2 1 𝑚𝑜𝑙𝑒 𝐼−
3 1 𝑚𝑜𝑙𝑒 𝐶𝑙⬚ 1 𝑚𝑜𝑙𝑒 𝐶𝑙
Calculation 𝑤𝑒𝑖𝑔ℎ𝑡𝐶𝑙 = __________
Weight of Iron titrated
%Cl in sample
𝑤𝑒𝑖𝑔ℎ𝑡𝐶𝑙 100 𝑚𝐿
%𝐶𝑙 = ( )( )𝑥100
1.25 𝑔 25 𝑚𝐿
%𝐶𝑙 = ___________
The ethyl mercaptan (EM) concentration in a mixture was determined by shaking a 2.043-g sample with
50.00 mL of 0.01204 M I2 in a tightly stoppered flask:

2𝐶2𝐻5𝑆𝐻 + 𝐼2 → 𝐶2𝐻5𝑆𝑆𝐶2𝐻5 + 2𝐼 − + 2𝐻+

The excess I2 was back-titrated with 18.23 mL of 0.01437 M Na2S2O3 . Calculate the percentage of
C2H5SH (62.13 g/mol).

Mole of I2 consumed by ethyl mercaptan


−
0.01204 𝑚𝑜𝑙 𝐼2 0.01437 𝑚𝑜𝑙 𝑆2 𝑂3−2 1 𝑚𝑜𝑙𝑒 𝐼3 1 𝑚𝑜𝑙𝑒 𝐼2
𝑚𝑜𝑙𝑒 𝑜𝑓 𝐼2 = [( ) (0.050 𝐿)] − [( ) (0.01823 𝐿) ( )( − )]
1𝐿 1𝐿 2 𝑚𝑜𝑙𝑒 𝑆2 𝑂3−2 1 𝑚𝑜𝑙𝑒 𝐼3

Weight of ethyl mercaptan(EM)


1 𝑚𝑜𝑙𝑒 𝐸𝑀 62.13 𝑔 𝐸𝑀
𝑤𝑒𝑖𝑔ℎ𝑡𝐸𝑀 = 𝑚𝑜𝑙𝑒 𝑜𝑓 𝐼2 ( )( )
1 𝑚𝑜𝑙𝑒 𝐼2⬚ 1 𝑚𝑜𝑙𝑒 𝐸𝑀

%EM in sample
𝑤𝑒𝑖𝑔ℎ𝑡𝐸𝑀
%𝐸𝑀 = ( ) 𝑥100
2.043 𝑔
%𝐸𝑀 = ___________

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