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12 Chemistry Haloalkanes and Haloarenes Test 05 Answer s2l6 PDF

The document contains 8 multiple choice questions from a CBSE Class 12 Chemistry test on the topics of haloalkanes and haloarenes. It provides the questions and answers on various topics within this domain, including: 1) Lucas reagent and optical activity of haloalkanes 2) Factors affecting boiling points of haloalkanes 3) Fittig and Finkelstein reactions involving haloalkanes 4) Reactions of haloalkanes with thionyl chloride and phosphorus tribromide 5) Possible isomers of methylchlorobenzene 6) Methods for chlorination of benzene to produce chlorobenzene 7) Distinguishing alkyl halides from aryl halides

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Shreyash Kolekar
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158 views2 pages

12 Chemistry Haloalkanes and Haloarenes Test 05 Answer s2l6 PDF

The document contains 8 multiple choice questions from a CBSE Class 12 Chemistry test on the topics of haloalkanes and haloarenes. It provides the questions and answers on various topics within this domain, including: 1) Lucas reagent and optical activity of haloalkanes 2) Factors affecting boiling points of haloalkanes 3) Fittig and Finkelstein reactions involving haloalkanes 4) Reactions of haloalkanes with thionyl chloride and phosphorus tribromide 5) Possible isomers of methylchlorobenzene 6) Methods for chlorination of benzene to produce chlorobenzene 7) Distinguishing alkyl halides from aryl halides

Uploaded by

Shreyash Kolekar
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CBSE TEST PAPER-05

CLASS - XII CHEMISTRY (Haloalkanes and Haloarenes)


[ANSWER]
Topic:- Miscellaneous Questions
Ans1. A mixture of HCl and anhydrous ZnCl2 is known as Lucas reagent.
Ans 2. CH3CH2CH2CH2Br CH3CH CH2CH3

Br
1 -- bromobutane
2 -- bromobutane
2- bromobutane will be optically active as it has one chiral carbon (C2).
Ans3. The order of increasing boiling points is

(CH3)3 C Br < CH3 CH CH2 Br < CH3 CH2 CH2 CH2 Br

CH3
Boiling point decreases with increase in branching as it reduces the surface area.

Ans 4. (a) Fittig reaction


Cl Cl
dry
+ Na +
ether

diphenyl
Chlorobenzene

(b) Finkelstein reaction CH3 CH2Cl + Nal CH3 CH2 l + NaCl

chloroethane lodoethane

Ans5. (a) When thionyl chloride acts upon 1- propanol chloropropane is formed .

CH3CH2CH2OH + SOCl2 → CH3CH2CH2Cl+SO2 +HCl

(b) When ethanol reacts with PBr3, bromoethane is formed.

3CH 3CH 2OH + PBr3 → 3CH 3CH 2 Br + H 3 PO3

Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in


Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks
Ans6. C7H7Cl - Three aromatic isomers are possible.

CH3

2 - m e t h y lc h o lo r o b e n z e n e

Cl

CH3

Cl 3 - m e t h y l c h o lo r o b e n z e n e

CH3

4 - m e t h y l c h o lo r o b e n z e n e

Cl
Cl

Ans7 (a) by direct chlorination- Fe


+ Cl2
dark

Benzene Chlorobenzene
(b) by diazotization method.

NH 2 N 2Cl N 2Cl

e
Aniline + NaNO 2 + HCl + N 2 + NaCl
diazotization

Diazoniumsalt
Cu 2Cl2 /HCl

Cl

Chlorobenzen

Ans8. Alkyl halide e.g. C2 H5X, C6H5CH2X etc. can be distinguished from aryl halide, C6H5X,
by AgNO3 test.

HNO 3
Alkyl halide + aqKOH + AgNO 3 AgX
ppt.

HNO 3
Alylk halide + aqKOH + AgNO 3 NO ppt.

Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in


Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks

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