Scribd
Upload
90 views2 pages

Cbse Test Paper-04 CLASS - XII CHEMISTRY (Chemical Kinetics) (Answers)

1. The hydrolysis of ethyl acetate is an example of a pseudo first-order reaction. 2. For a first-order reaction, the half-life period is equal to 0.693 divided by the rate constant k. 3. Using the Arrhenius equation, the rate of reaction will not depend on temperature if the activation energy is zero.

Uploaded by

Shreyash Kolekar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
90 views2 pages

Cbse Test Paper-04 CLASS - XII CHEMISTRY (Chemical Kinetics) (Answers)

1. The hydrolysis of ethyl acetate is an example of a pseudo first-order reaction. 2. For a first-order reaction, the half-life period is equal to 0.693 divided by the rate constant k. 3. Using the Arrhenius equation, the rate of reaction will not depend on temperature if the activation energy is zero.

Uploaded by

Shreyash Kolekar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

CBSE TEST PAPER-04

CLASS - XII CHEMISTRY (Chemical Kinetics)


[ANSWERS]

Topic: - Half life period Temperature dependence.

1. Hydrolysis of ethyl acetate when concentration of water is very large , is an example of


pseudo first order reaction.

CH3COO C2H5 + H2O → CH3 COOH + C2H5OH.

2. For a first order reaction , the half life period is


0.693
T1/2 =
k

0.693
3. t1/2 =
k
0.693
= −14
= 1.26 × 1013 s
5.5 ×10 sec -1

4. 0.011 55 min-1

2.303 [ R ]o
5. t= log
k [ R]
2.303 2 × 10−3
= log
3 × 10−2 min -1 5 × 10−4
2.303
= log 4 (log 4 = 0.6021)
3 × 10−2
= 46.22 min.

6. Arrhenius equation
K = A e –Ea/RT
Where K = rate constant , T = absolute temperature
Ea = Activation energy, R = gas constant.

7. K = A e-Ea/RT
When Ea = 0
K = A e -0/RT

Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in


Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks
= A. e0
K=A
∴ Rate of reaction will not depend upon the temperature if activation energy is
zero.

8. T1 = 295K T2 = 305K
 TT   k 
Ea = 2.303 R  2 1   log 2 
 T2 − T1   k1 
K2 = 2k1
 305 × 295  2k
Ea = 2.303 ×8.314 ×   log 1
 305 − 295  k1
= 2.303 × 8.314 × 8997.5K log 2
= 51855.2 J/mol (log2 = 0.3010)

9. 22.0 KJ/mol.

10.

Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in


Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks

You might also like