Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 CHECLIST FOR A MINIMUM NEEDS FOR THE CHAPTERS

Chapter 2: The Structure of the Atom

1. The kinetic theory of matter.

2. Meaning of atom, molecule and ion.
3. Define for melting point.
4. Define proton number and nucleon number.
5. State the meaning of isotopes and uses of carbon-14 and cobalt-60
6. Explain why the temperature remains unchanged during the melting process and
the freezing process.
7. Explain the changes in energy content, forces of attraction between the particles,
and arrangement of particles.
8. State the main subatomic particles of an atom.
27
9. 13 Al is the symbol of aluminium.
(a) Determine the number of neutron ofand electron arrangement of aluminium.

Chapter 3: Chemical Formulae and Equations

1. State the meaning of relative atomic mass based on carbon-12 scale.

2. Define a mole.
3. State the meaning of molar mass
4. State the meaning of molar volume of gas.
5. State the meaning of empirical formula.
6. State the meaning of molecular formula.
7. Determine the empirical formula of copper(II) oxide and magnesium oxide.
8. Describe a laboratory experiment to determine the empirical formula of
magnesium oxide and copper(II) oxide.

Chapter 4: Periodic Table of Elements

1. State the basic principle of arranging the elements in the Periodic Table from its
proton number.
2. State the physical properties of Group 1.
3. State the physical properties of Group 17.
4. State the changes in the atomic size and electronegativity of elements across
Period 3.
5. State three special properties of transition elements.
6. State why helium gas is not reactive.
7. Describe a laboratory experiment to compare the reactivity of elements in
a) Group 1: lithium, sodium and potassium with water and oxygen.
8. Describe a laboratory experiment to compare the reactivity of chlorine,
bromine
and iodine in the reaction with iron wool.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 1. Chapter 5: Chemical Bonds

2. State the meaning of anion and cation.

3. State the physical properties of ionic compounds.
4. State the physical properties of covalent compounds.
5. Explain why sodium chloride can conduct electricity in aqueous state but cannot
conduct electricity in solid state.
6. Describe the formation of ionic bond in sodium chloride, NaCl.
7. By using example, describe the formation of covalent bond between element
from Group 14 and element from Group 17.
8. Draw electron arrangement of the compound formed from the following elements.

a) Nitrogen and hydrogen,

b) Carbon and oxygen,
c) Magnesium and chlorine,
d) Carbon and hydrogen,
e) Hydrogen and chlorine,
f) Sodium and oxygen.

Chapter 6: Electrochemistry

1. State the meaning of electrolyte and electrolysis.

2. State three factors affecting electrolysis of an aqueous solution.
3. Explain why solution of hydrogen chloride in water can conduct electricity but
solution of hydrogen chloride in methylbenzene cannot conduct electricity?
4. Explain how the following factors can determine the selective discharge of ions at
the electrodes.
i. Types of electrodes,
ii. Concentration of the ions.
5. Describe the electrolysis of molten lead(II) bromide.
6. Describe the extraction of aluminium and lead(II) oxide by electrolysis.
7. Describe a laboratory experiment to show that types of electrodes affecting
the selective discharge of ions in electrolysis of copper(II) sulphate
solution.
8. Describe a laboratory experiment to construct the electrochemical series of
magnesium, copper, zinc and lead.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 Chapter 7&8: Acids ,Bases and Salts

1. State the meaning of acid and alkali.

2. State the meaning of strong acid and weak alkali
3. Define salt.
4. Determine the molarity of the solution.
5. Determine the molarity of the nitric acid, HNO3 using titration method.
6. Describe a chemical test to determine a given solution is an acid solution.
7. Describe a laboratory experiment to determine the concentration of sodium
hydroxide by using titration method.
8. Describe the preparation of zinc sulphate, lead(II) chloride and
potassium
9. Describe the confirmatory tests to confirm for the present of nitrate
ions in salt solution.
10. Describe the confirmatory tests to confirm for the present of carbonate
ions besides heating.
11. Describe the confirmatory tests for the present of cations in colourless
solution.

Chapter 9: Manufactured Substance in Industry

1. Define the meaning of alloy and uses.

2. Define the meaning of composite materials
3. State the components of the following composite materials:
a. Reinforced concrete,
b. Superconductor,
c. Fibre optic,
d. Fibre glass,
e. Photochromic glass.

4. State the catalyst, temperature and pressure of the following process:

a. Contact process
b. Haber process

5. Define the meaning of polymers.

6. Name the monomer of polythene and polyvinyl chloride.
7. State four types of glass and their compositions. List the uses of each glass.
8. Define the meaning of ceramics
9. State the properties and list the uses of ceramics.
10. Sate why bronze is harder than copper.
11. Explain how acid rain is formed.
Describe how acid rain causes environmental pollution.
12. Explain the industrial process involved in the manufacture of sulphuric acid.
13. Explain the industrial process involved in the manufacture of ammonia gas.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 14. Describe a laboratory experiment to prepare ammonium sulphate
(ammonium fertiliser)
15. Describe a laboratory experiment to compare the hardness of brass and
copper.

Chapter 10: Rate of Reaction

1. Define the rate of reaction.

2. Define the collision theory, activation energy and effective collision.
3. Explain how surface area (size of reactant) can increase the rate of reaction
based on collision theory.
4. Explain how temperature ,concentration, catalyst and size can increase the rate
of reaction based on collision theory.
5. Describe a laboratory experiment to show that an increase in temperature
will increase the rate of reaction between sodium thiosulphate solution and
sulphuric acid.

Chapter 11: Carbon compounds

1. Define homologous series, saturated and unsaturated hydrocarbon and state an

example for each of them.
2. Isomerism for butane,ethane and propane.
3. Define polimer and an example of polymer and its monomer.
4. Define saturated and unsaturated fats.
5. A test to differentiate between ethane and ethene by using acidified potassium
mangante(II) solution or bromine water.
6. Explain the coagulation process of latex.
7. Explain how to prevent coagulation of latex.
8. Describe a laboratory experiment to prepare ethane gas from ethanol.
9. Describe a laboratory experiment to prepare ethanoic acid gas from
ethanol.

Chapter 12: Oxidation and Reduction

1. Define a meaning of oxidation and deduction based on loss or gain of oxygen.

2. Define a meaning of oxidation and deduction based on transfer of electrons.
3. Define a meaning of oxidation and deduction based on changes in oxidation
number.
4. Define a meaning of redox reactions
State an example of redox reactions.
5. The reaction between zinc and copper(II) sulphate solution is a redox reaction.
Explain why.
6. Explain the observation when bromine water is added to the potassium iodide
solution, the solution changes colour from colourless to brown.
7. Describe the rusting of iron.
8. Describe a change of colur of 111 trichloroethene when chlorine water is added
to potassium iodide solution in a test tube.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 9. Describe a laboratory experiment to change the oxidation number of iron from +2
to +3.
10. Describe a laboratory experiment to change the oxidation number of iron from +3
to +2 by using zinc.
11. Describe the extraction of iron.
12. You are given lead, zinc, copper and their oxides. Describe a laboratory
experiment to compare the reactivity of zinc,copper and other oxides metal
with oxygen.

Chapter 12: Thermochemistry

1. Define exothermic reaction and endothermic reaction.

2. Determine :
i. the heat of precipitation
ii. the heat of displacement.
iii. heat of neutralisation?
iv. heat of combustion?

3. Draw for the energy level diagram.

4. “The higher the number of carbon atoms per molecule, the higher is the
heat of combustion”
Describe a laboratory experiment to prove that the above statement is true
by using methanol, ethanol, propan-1-ol, butan-1-ol and pentan-1-ol.

Chapter 13: Chemicals for Consumers

1. Define soap and detergent.

2. Define a saponification process.
3. State the functions of additives in detergent.
4. Define a meaning of hard water.
5. State the function of food additives:
a. Preservatives ( Sodium nitrite, sodium benzoate)
b. Antioxidants (Ascorbic acid)
c. Flavourings (Monosodium glutamate (MSG), Aspartame)
d. Stabilisers
e. Thickeners

6. State the functions of the following modern medicines.

a. Analgesics ( Aspirin, Paracetamol, Codeine)
b. Antibiotics ( Penicilin, Streptomycin)
c. Psychotherapeutic medicine ( Stimulant, Antidepressant, Antipsychotic)

7. State the side effects of paracetamol and aspirin.

8. Describe the cleansing action of soap.
9. Explain the cleansing action of a detergent and a soap in hard water.
10. Describe a laboratory experiment to prepare soap from palm oil using the
saponification process.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
EXAM FORMAT FOR SPM CHEMISTRY PAPERS

PAPER 1 PAPER 2 PAPER 3

PAPER
[ 4541/1] [ 4541/2] [4541/3]
Subjective question Structured
Objective question Section A question
Multiple choice Structured questions & Open
Item & Section B response
Multiple Limited response questions question
combination Section C
Open response questions
Section A Structured
6 questions questions
(answer all) 1-2 questions
Section B (answer all)
Number of
50 (answer all) 2 question Design and
questions
( choose one) planning the
Section C experiment
2 question 1 question
( choose one) (compulsory)
Total marks 50 100 50
Written in the space provided in Written in the space
Ways to response Marked on OMR form the question paper provided in the
question paper
Duration of time 1 hour 15 minutes 2 hours 30 minutes 1 hour 30 minutes
Knowledge: Knowledge: 14% Sciences process
20 questions Understanding:21% skills:
Understanding: Application: 29% 13 sciences
Construct
15 questions Analysing: 21% process skills
Application: Synthesising: 15%
15 question
L: 25 questions L:50%
Level of difficulty M: 15 questions M:30%
H: 10 questions H:20%

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 ANALYSIS OF THE SPM CHEMISTRY PAPERS
[2003 – 2008]

PAPER 2

YEAR
CHAPTERS
2002 2003 2004 2005 2006 2007 2008
1. Introduction to chemistry
2. The structure of the atom 2 ½ 1 1b 1a
3. Chemical formulae 11 1 1a
and questions
FORM 4

4. Periodic Table of elements 1 1 1 1a 1/2a

5. Chemical bonds 1 1a 1/2a
6. Electrochemistry 1 1 2 1b
7. Acids and bases 1 1 2 1c
8. Salts 1b 1c
9. Manufactured substances 1 2 1 1 1a 1a
in industry
10. Rate of reaction 1 1 1 1 1c 1a
FORM 5

11. Carbon compounds 1 1 2 1c 1a

12. Oxidation and reduction 1 1 1 1a 1c
13. Thermochemistry 1 1 1 2 1a
14. Chemical for consumer 1 1 1 1 1 1a 1b

PAPER 3

YEAR
CHAPTERS
2002 2003 2004 2005 2006 2007 2008
1. Introduction to chemistry
2. The structure of the atom 1
3. Chemical formulae 1
and questions
FORM 4

4. Periodic Table of elements 1

5. Chemical bonds
6. Electrochemistry ½ 1[sps] 1(de)
7. Acids and bases 1 ½
8. Salts
9. Manufactured substances 1 1
in industry
10. Rate of reaction
FORM 5

11. Carbon compounds 1 1 1(sps)

12. Oxidation and reduction 1
13. Thermochemistry 1 1[de]
14. Chemical for consumer

Note: sps – sciences process skills, de – design the experiment

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 THE MOLE

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 MODULE THE MOLE

Relative atomic mass = 1 mole of atoms = (6.02 x 1023 atoms) = ( Ar

in grams

Example :
One mole
Each 7g lithium, 12g carbon, 56g iron, 64g copper, 197g gold contains
atom
6.02 x 1023 atoms (1 mole atom)

[Relative atomic mass: Li,7 ; C,12 ; Fe,56 ; Cu,64 ; Au,197 ]

Relative molecular mass = 1 mole of molecules = (6.02 x 1023 molecules)

= ( Mr in grams )

One mole Example :

molecule Each 2g hydrogen gas, 16g methane gas, 17g ammonia gas, 44g carbon
dioxide gas contains 6.02 x 1023 molecules.
[Relative atomic mass : H,1 ; C,12 ; N,14 ;O,16 ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
ACTIVITY 1

Complete the table below.

Lengkapkan jadual dibawah

[ Relative atomic mass, Ar : C,12 ; Al,27 ; He,4 ; H,1 ; O,16 ; N,14 ]

Ar : Atomic mass
Jisim atom
Mr : Molecular mass
Jisim molekul

Mass of
Symbol Mass of 6.02 x1023 Molar
Substance Ar or Mr
or 1 mole Particles mass
[Bahan]
[Formula] [Jisim 1 [Jisim 6.02 x1023 [Jisim
mol] Zarah] molar]

Carbon
C 12 12g 12g 12gmol-1
[1C]

Aluminium 27g

Helium
He 4g

H2 2x1 2 gmol-1
Hydrogen
[2H]

Carbon 44
Dioxide

17g
Ammonia

Hydrogen
chloride

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 x Molar mass

Mass (g)
Number of moles

Molar mass

Or write in formula,

Mass of substance in gram

Jisim bahan dalam gram
Number of moles of a substance =
Bilangan mol bahan Molar mass of substance
Jisim molar bagi bahan

Example 1:

Calculate the number of moles of an atom which is found in 28g of iron.

Hitung bilangan mol bagi atom yang terdapat didalam 28g besi.
[ Relative atomic mass : Fe, 56 ]

Solution :

mass
Step1 Number of moles =
relative atomic mass

Step 2 28
=
56

= 0.5 mol

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 Example 2 :

Calculate the mass of 0.5 mol carbon dioxide, CO2 ?

Hitung jisim 0.5 mol karbon dioksida, CO2 ?

[ Relative atomic mass : C, 12; O,16 ]

Solution :
mass
Step 1 Number of moles =
Relative molecular mass

Step 2 0.5 = mass

12 + ( 2 x 16 )

0.5 = mass

44

Thus, Mass of carbon dioxide = 0.5 x 44

= 22g

Problem involving relationships between number of moles, number of particles and

mass of substance can be solved using a combination of both equations.
Perkaitan masaalah perhubungan diantara bilangan mol, bilangan zarah dan jisim bahan
boleh diselesaikan dengan mengabungkan kedua-dua persamaan.

Number of particles
[Bilangan zarah] Mass
Number of moles = Number of moles =
[Bilangan mol] NA Ar or Mr

Number of particles Mass

=
NA Ar or Mr

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
To solve questions on the relationship between number of moles, number
of particles and mass of substance, the following step can be used.
Untuk menyelesaikan perhubungan diantara bilangan mol, bilangan zarah dan jisim
bahan, langkah-langkah berikut boleh digunakan.

Step 1
Langkah 1

Write the formula :

Tulis formula:

Number of particles mass

=
NA Ar or Mr

Step 2
Langkah 2

Substitute the values given into the formula.

Gantikan nilai yang diberikan kedalam formula

Example 3 :

Calculate the number of atoms found in 28g of iron.

Hitung bilangan atom yang didapati didalam 28g besi.
[ Relative atomic mass : Fe,56 ; NA = 6.02 x 1023 mol-1 ]

Solution :

Number of atoms mass

=
NA relative atomic mass

Number of atoms 28
=
6.02 x 1023 56

28
Thus, the number of atoms = x 6.02 x 1023 atoms
56

= 3.01 x 1023 atoms

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
Example 4 :

Calculate the mass in gram for 1.5 x 1024 chlorine molecules.

Hitung jisim dalam gram bagi 1.5 x 1024 molekul klorin

( Relative atomic mass : Cl,35.5 ; NA = 6.02 x 1023 )

Solution :

Number of atoms mass

=
NA relative molecular mass

1.5 x 1024 = mass

6.02 x 1023 2 x 35.5

Thus, the mass of chlorine = 1.5 x 1024 x 71

6.02 x 1023

= 177.5 g

ACTIVITY 2:

Complete the table below

Lengkapkan jadual dibawah

[ Relatif atomic mass : Ne,20 ; Zn,65 ; H,1 ; Cl,35.5 ; Na,23 ; O,16 ; Al,27 ; S,32 ; C,12 ;
Ba,137 ;
Avagdro Number, NA = 6.02 x 1023 mol-1 ]

Number of
Mass Number of
No Element moles
(g) particles
( mol )
Neon,Ne
1 4
25 x 1024atoms
2 Zinc, Zn

3 Hydrochloric acid, HCl

1.5

4 Sodium oxide, Na2O 28

Aluminium
5 8.5 x 1022 ions
chloride,AlCl3

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
ACTIVITY 3 : CALCULATING RELATIVE MOLECULAR MASS
MENGHITUNG JISIM MOLEKUL RELATIF

Formula of Relative Molecule Mass/

Name of Compound Compound Relative Formula Mass Ans
No
Nama sebatian Formula Jisim molekul relatif/ Jwp
sebatian Jisim formula relatif
1 Copper(II) chloride CuCl2 64 + 2(35.5) = 135 135

2 Potassium chloride 74.5

3 Sodium sulphate 142

4 Magnesium sulphate 120

5 Zink carbonate 125

6 Potassium nitrate 101

7 Iron(II) oxide 72

8 Calcium nitrate 164

9 Barium sulphate 233

10 Tin(II) chloride 190

11 Lead(II) oxide 223

133.
12 Aluminum chloride
5
13 Ammonium nitrate 80

14 Sodium nitrate 85

15 Silver oxide 232

162.
16 Iron(III) chloride
5
17 Sodium bromide 103

18 Sodium oxide 62

19 Lead(II) sulphate 303

20 Lithium oxide 30

21 Magnesium nitrate 148

22 Potassium iodide 166

23 Potassium sulphate 174

24 Magnesium oxide 40

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 Formula of Relative Molecule Mass/
No Name of Compound Ans
Compound Relative Formula Mass
25 Iron(II) carbonate 116

26 Carbon dioxide 44

27 Copper(II) carbonate 124

28 Sodium iodide 150

29 Ammonium nitrate 80

30 Copper(II) hydroxide 98

31 Calcium carbonate 100

32 Ammonium sulphate 132

33 Sodium carbonate 106

34 Silver sulphate 312

35 Aluminum oxide 102

36 Aluminum sulphate 342

37 Iron(III) oxide 160

38 Iron(III) sulphate 400

39 Potassium carbonate 138

40 Acetic acid 60

41 Sulfuric acid 98

42 Hydrochloric acid 36.5

43 Nitric acid 63

44 Magnesium hydroxide 58

45 Copper(II) nitrate 188

46 Magnesium etanoat (CH3COO)2Mg 142

Magnesium sulphate
47 MgSO4.7H2O 246
hydrate
48 Copper(II) sulphate hydrate CuSO4.5H2O 250

49 Butanoic acid C3H7COOH 88

50 Potassium manganese(VII) KMnO4 158

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
ACTIVITY 4:
1. Calculate the number of moles in each question :
Hitung bilangan mol bagi setiap soalan:
(a) 10 g Sodium hydroxide
Answer:
i. Formula for sodium hydroxide = NaOH
ii. Relative molecular mass for sodium hydroxide = 1(23)+1(16)+1(1)
= 40
iii. Molar mass for sodium hydroxide = 40g
10 g
iv. Number of mole = 40 g = 0.25 mol

(b) 2 g Copper(II) sulphate

(c) 10.44 g Potassium sulphate

(d) 4.75 g Magnesium chloride

(e) 2.97 g zinc hydroxide

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (f) 1.484 g sodium carbonate

(g) 2.769 g aluminum nitrate

(h) 32 g iron(III) sulphate

(i) 5.22 g magnesium hydroxide

(j) 1.655 g lead(II) nitrate

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 2. Calculate the mass of :
Hitung jisim bagi:

(a) 0.5 mol sodium oxide

Answer:
i. Formula for sodium oxide = Na2O
ii. Relative molecular mass for sodium oxide = 2(23) + 1(16) = 62
iii. Molar mass for sodium oxide = 62g
v. Number of mole = 0.5 mol
vi. Mass for 0.5 mol sodium oxide = 0.5 x 62= 31.0g

(b) 1.2 mol tin(II) chloride

(c) 0.25 mol copper(II) carbonate

(d) 0.3 mol calcium chloride

(e) 0.125 mol iron(II) sulphate

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (f) 0.34 mol potassium sulphate

(g) 0.2 mol barium sulphate

(h) 0.3 mol silver nitrate

(i) 0.12 mol magnesium nitrate

(j) 0.05 mol calcium sulphate

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
Answer:
1. (a) 0.25 mol (b) 0.0125 mol (c) 0.06 mol (d) 0.05 mol (e) 0.03 mol (f) 0.014 mol (g) 0.013 mol (h)
0.08 mol (i) 0.09 mol
(j)0.005 mol
2. (a) 31.0g (b) 228.0g (c) 31.0 g (d) 33.30 g (e) 19.0 g (f) 59.16 g (g) 46.60 g (h) 51.0g (i) 17.76 g
(j)6.80 g

ACTICITY 5 :

1. Calculate the number of atoms in :

Hitung bilangan atom didalam:
23
(a) 4 g oxygen atom [answer;1.5 x 10 ]

Answer:

i. Formula for oxygen =O

ii. Total of an atoms in oxygen =1
iii. Relative atomic mass for oxygen = 16
iv. Molar mass for oxygen = 16g
4g
v. Number of mole = 16 g = 0.25

vi. Number of atoms = 0.25 x 1 x 6.02 x 1023 = 1.505 x 1023

22
(b) 1.9 g zinc [answer;1.8 x 10 ]

22
(c) 3 g magnesium [answer:7.5 x 10 ]

24
(d) 2 g hydrogen atom [answer:1.2 x 10 ]

23
(e) 10.08 g iron [answer:1.08 x 10 ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 23
(f) 0.2 mol sulfur [answer:1.2 x 10 ]

22
(g) 0.128 mol nitrogen atom [answer:7.68 x 10 ]

2. Calculate the number of atom in :

Hitung bilangan atom didalam:
23
(a) 4 g oxygen gas [answer:1.505 x 10 ]

Answer:

i. Formula for oxygen gas = O2

ii. Total of an atoms in oxygen gas =2
iii. Relative atomic mass for oxygen = 2(16)
= 32
iv. Molar mass for oxygen = 32g
4g
v. Number of mole = 32 g = 0.125

vi. Number of atom = 0.125 x 2 x 6.02 x 1023 = 1.505 x 1023

23
(b) 5.6 g magnesium oxide [answer:1.68 x 10 ]

23
(c ) 4.9 g sulphuric acid [answer:2.1 x 10 ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 22
(d) 1.8 g magnesium sulphate [answer:5.4 x 10 ]

22
(e) 1.96 g copper(II) hydroxide [answer:6 x 10 ]

22
(f) 2.6625 g aluminum nitrate [answer:9.75 x 10 ]

3. Calculate the number of ion in :

Hitung bilangan ion didalam:
22
(a) 4.9 g dilute sulphuric acid [answer:9 .03 x 10 ]

Answer:

i. Formula for sulphuric acid = H2 SO4

ii. Total of an ions in sulphuric acid = 3 = 2H+ + 1SO42-
iii. Relative atomic mass for sulphuric acid = 2(1) + 1(32) + 4(16) = 98
iv. Molar mass for sulphuric acid = 98g
4.9 g
v. Number of mole = = 0.05
98 g
vi. Number of ions = 0.05 x 3 x 6.02 x 1023 = 9.03 x 1023

22
(b) 1.8 g aqueous magnesium sulphate [answer:1.8 x 10 ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 22
(c) 4.7 g aquase copper(II) nitrate [answer:4.5 x 10 ]

23
(d) 17 g aqueous zinc chloride [answer:2.25 x 10 ]

23
(e) 17 g aqueous silver nitrate [answer:1.2 x 10 ]

24
(f) 414 g aqueous potassium carbonate [answer:5.4 x 10 ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
4. Calculate the mass of :
Hitung jisim bagi:

(a) 3 x 1023 oxygen atom [answer:8.0 g]

Answer:

i. Formula for oxygen atom =O

ii. Relative atomic mass for oxygen atom = 16
iii. molar mass for oxygen = 16g
3 x 10 23 atom
iv. Number of mole = = 0.50 mol
6.02 x 10 23 atom

v. mass for 3 x 10 23 oxygen atom = 0.50 x 16 = 8.0g

(b) 7.2 x 1023 zinc atom [answer:78 g]

(c) 7.5 x 1022 sulfur atom [answer:4.0 g]

(d) 1.8 x 1021 lead atom [answer:0.621g]

(e) 2.4 x 1022 magnesium atom [answer:0.96 g]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 -24
(f) 3 hydrogen atom [answer;5 x 10 g]

-22
(g) 12 helium atom [answer:1.2 x 10 g]

ACTIVITY 6: MOLE IN CHEMICAL EQUATION I

MOL DIDALAM PERSAMAAN KIMIA 1

1. 3.1 g of copper(II) carbonate is heated to produced copper(II) oxide and carbon

dioxide gas.
3.1g kuprum(II) karbonat dipanaskan untuk menghasilkan kuprum(II) oksida dan
gas karbon dioksida.
[ relative atomic mass for Cu,64;C,12;O,16; Molar Volume is 22.4 dm3 at STP]

CuCO3
CuO + CO2

From the reaction, calculate:

Daripada tindakbalas, hitung:

(a) the mass of copper (II) oxide produced.

Jisim kuprum(II) oksida yang terhasil.

(b) the volume of carbon dioxide gas produced at STP

isipadu gas karbon dioksida yang terhasil pada STP.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
2. CaCO3
CaO + CO2

In this reaction, 300 cm3 carbon dioxide gas are produced when calcium carbonate
is heated.
Dalam tindakbalas ini, 300 cm3 gas karbon dioksida dihasilkan apabila kalsium
karbonat dipanaskan.
[ relative atomic mass for Cu,64;C,12;O,16; Molar Volume is 22.4 dm3 at STP]

Calculate:
Hitung:

(a) the mass of calcium carbonate used.

Jisim kalsium karbonat yang digunakan.

(b) mass of calcium oxide produced.

Jisim kalsium oksida yang dihasilkan.

3. 2Na + 2H2O
2NaOH + H2

When 0.23 g of sodium is added to water, the metal will react vigorously at the
surface of the water.
Apabila 0.23g natrium dimasukkan kedalam air, logam tersebut bertindakbalas
dengan cergas dipermukaan air.
[Relative atomic mass for Na,23;H,1;O,16;Molar volume is 24 dm3 at room
temperature]

Calculate:
Hitung:

(a) The mass sodium hydroxide produced.

Jisim natrium hidroksida yang dihasilkan.

(b) Volume of hydrogen gasses yang being produced at temperature room.

Isipadu gas hidrogen yang dihasilkan pada suhu bilik.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
4. 2Mg + O2
2MgO

A strip of magnesium has a weight of 1.2 g are being burn with surplus oxygen to
produced magnesium oxide.
Kepingan magnesium seberat 1.2g dibakar dengan campuran oksigen untuk
menghasilkan magnesium oksida.
[Relative atomic mass Mg,24;O,16]

Calculate:
Hitung:

(a) The mass magnesium oxide being produced.

Jisim magnesium oksida yang dihasilkan

(b) The mass of oxygen that needed for this reaction.

Jisim oksigen yang diperlukan bagi tindakbalas ini.

5. C3H8 + 5O2
3CO2 + 4H2O

Chemical equation above shows when propane gas was burned in oxygen. If 3.36
dm3 of carbon dioxide gas are produced in this reaction at STP,
Persamaan diatas menunjukkan apabila gas propane dibakar didalam oksigen.
Sekiranya 3.36 dm 3 gas karbon dioksida dihasilkan dalam tindakbalas ini pada
STP,
[ relative atomic mass for C,12;O,16;H,1; Molar Volume is 22.4 dm3 at STP]

Calculate:
Hitung:

(a) The mass of propane burned

Jisim propana yang terbakar.

(b) Volume of oxygen gas that reacted

Isipadu oksigen yang bertindakbalas.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
6. 2Al + 3CuO
Al2O3 + 3Cu

1.35g of aluminium powder and copper (II) oxide was heated strongly in
laboratory to produced aluminium oxide and copper.
1.35g serbuk aluminium dan kuprum(II) oksida dipanaskan dengan kuat didalam
makmal untuk menghasilkan aluminium oksida dan kuprum.
[ relative atomic mass for Al,27;O,16;Cu,64]

Calculate:
Hitung:

(a) The mass of copper (II) oxide reacted

Jisim kuprum(II) oksida yang bertindakbalas.

(b) The mass of aluminium oxide produced.

Jisim aluminium oksida yang dihasilkan.

(c) The mass of copper produced.

Jisim kuprum yang dihasilkan.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
Answer
3 3
1. (a) 2 g (b) 0.56 dm 2.(a) 1.25 g (b) 0.7 g 3. (a) 0.4g (b) 0.12 dm
3
4. (a) 2 g (b) 0.8 g 5.(a) 2.2 g (b) 5.6 dm 6.(a) 6 g (b) 2.55 g (c) 4.8 g

ACTIVITY 6 :MOLE IN CHEMICAL EQUATION II

1. 4K + O2
2K2O

11.7 g of potassium was burnt in oxygen to produce potassium oxide.

11.7g kalium dipanaskan didalam oksigen untuk menghasilkan kalium oksida
[Relative atomic mass: K, 39; O, 16; Molar Volume is 24 dm3 at room temperature]

Calculate:
Hitung:

(a) Mass of potassium oxide being produced

Jisim kalium oksida yang dihasilkan.

(b) Volume of oxygen reacts at room temperature

Jisim oksigen yang bertindakbalas pada suhu bilik.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
2. 2Fe + 3Cl2
2FeCl3

33.6 g of iron react with chlorine gas to produced iron (III) chloride at room
temperature.
33.6g besi bertindakbalas dengan gas klorin menghasilkan Ferum(III) klorida pada
suhu bilik.
[Relative atomic mass: Fe, 56; Cl, 35.5; Molar Volume is 24 dm3 at room
temperature]

Calculate:
Hitung:

(a) Mass of iron (III) chloride produced

Jisim ferum(III) klorida yang dihasilkan.

(b) Volume of chlorine gas reacts

Isipadu gas klorin yang bertindakbalas.

3. 2Mg + O2
2MgO
3.84 g of magnesium was burnt in oxygen gas to produced magnesium oxide in a
laboratory.
3.84g magnesium dibakar didalam oksigen untuk menghasilkan magnesium oksida
didalam makmal.
[Relative atomic mass: Mg, 24; O, 16; Molar Volume is 24 dm3 at room temperature]

Calculate:
Hitung:

(a) Mass of magnesium oxide produced.

Jisim magnesium oksida yang dihasilkan.

(b) Volume of oxygen reacts with magnesium at room temperature.

Isipadu oksigen yang bertindakbalas dengan magnesium pada suhu bilik.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
4. 2KNO3
2KNO2 + O2

5.05 g of potassium nitrate was heated strongly to produce potassium nitrite and
oxygen gas at standard temperature.
5.05g kalium nitrat dipanaskan dengan kuat menghasilkan kalium nitrat dan gas
oksigen pada suhu piawai.
[Relative atomic mass: K, 39; N, 14; O, 16; Molar Volume is 22.4 dm3 at standard
temperature]

Calculate:
Hitung:

(a) Mass of potassium nitrite produced

Jisim kalium nitrat yang dihasilkan.

(b) Volume of oxygen produced

Isipadu gas oksigen yang dihasilkan.

5. 2Pb(NO3)2
2PbO + 4NO2 + O2

7.282 g of lead nitrate was heated strongly to produce products as above at STP.
7.282g plumbum nitrat dipanaskan dengan kuat untuk menghasilkan bahan
tindakbalas seperti diatas pada STP.
[Relative atomic mass: Pb, 207; N, 14; O, 16; Molar Volume is 22.4 dm3 at standard
temperature and pressure]

Calculate:
Hitung:

(a) Mass of lead (II) oxide

Jisim plumbum(II) oksida.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (b) Volume of nitrogen dioxide gas released
Isipadu gas nitrogen dioksida yang dibebaskan.

(c) Volume of oxygen produced in the experiment.

Isipadu gas oksigen yang dihasilkan didalam eksperimen.

6. 2Al + 6HCl
2AlCl3 + 3H2

3.24 g of aluminum powder are added to hydrochloric acid in a conical flask. The
reaction released a hydrogen gas and produced a aluminum chloride solution.
3.24g serbuk aluminium ditambahkan kedalam asid hidroklorik didalam kelalang kon.
Tindakbalas tersebut menghasilkan gas hidrogen dan larutan aluminium klorida.
[Relative atomic mass: Al, 27; Cl, 35.5; H, 1; Molar Volume is 24 dm3 at room
temperature]

Calculate:
Hitung:

(a) Mass of hydrochloric acid reacts with aluminum

Jisim asid hidroklorik yang bertindakbalas dengan aluminium

(b) Mass of aluminum chloride produced

Jisim aluminium klorida yang dihasilkan.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (c) Volume of hydrogen gas released at room temperature
Isipadu gas hydrogen yang dibebaskan pada suhu bilik.

7. 3Mg + Fe2O3
3MgO + 2Fe

3 g of magnesium powder was added to iron (III) oxide and heated very strongly. The
reaction produced a white fume of magnesium oxide and a brown metal of iron.
3 g serbuk magnesium ditambah kepada ferum(III) oksida dan dipanaskan dengan
kuat. Tindakbalas tersebut menghasilkan wasap putih magnesium oksida dan logam
perang besi.
[Relative atomic mass: Mg, 24; O, 16; Fe, 56]

Calculate:
Hitung:

(a) Mass of iron (III) oxide reacts with magnesium.

Jisim ferum(III) oksida yang bertindakbalas dengan magnesium.

(b) Mass of the white fume released in the reaction

Jisim wasap putih yang dibebaskan didalam tindakbalas.

(c) Mass of iron produced

Jisim besi yang dihasilkan.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
Answer
3 3 3
1. (a) 14.1 g (b) 1.8 dm 2.(a) 97.5 g (b) 21.6 dm 3.(a) 6.4 g (b) 1.92 dm
3 3 3
4. (a) 4.25 g (b) 0.56 dm 5. (a) 4.906 g (b) 0.9856 dm (c) 0.2464 dm
3 3
6. (a) 13.14 g (b) 16.02 g (c) 4.32 dm 7.(a) 6.67 g (b) 5 g (c) 4.67 dm

ACTIVITY 7 : OBJECTIVE QUESTIONS

1 The equation below represents the reaction to extract aluminium from aluminium
oxide.
Persamaan dibawah mewakili tindakbalas pengekstakan aluminium daripada
aluminium oksida.
2Al2O3
4Al + 3O2

What is the mass of aluminium that can be extracted from 102 g of aluminium oxide?
Apakah jisim bagi aluminium yang boleh di ekstrak daripada 102g aluminium oksida?
[Relative atomic mass: O, 16; Al,27]

A 13.5 g
B 27.0 g
C 54.0 g
D 108.0 g

2 XCO3
XO + CO2

The equation above shows the action of heat on the carbonate salt of metal X.
How many moles of XCO3 are needed to produced 4.0 g of oxide X?
Persamaan diatas menunjukkan tindak balas pemanasan garam karbonat bagi
logam X.
Berapa mol XCO3 yang diperlukan bagi menghasilkan 4.0g oksida X ?
[Relative atomic mass: C, 12; O, 16; X, 64]

A 0.03
B 0.05
C 0.08
D 0.09

3 Sulphuric acid used as an electrolyte in a car battery has a concentration of 0.5 mol
dm-3.
How many moles of sulphuric acid is there in 100 cm3?
Asid sulfuric digunakan sebagai elektrolit bateri kereta yang berkepekatan 0.5 mol
dm-3 .
Berapakah mol asid sulfuric didalam 100 cm 3 asid itu?

A 0.025
B 0.05
C 0.1
D 0.5

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
4 Diagram 1 shows the set-up of apparatus for the titration of potassium hydroxide
solution with sulphuric acid.
Rajah 1 menunjukkan susunan radas bagi pentitratan larutan kalium hidroksida
dengan asid sulfuric.

Sulphuric acid
0.1 mol dm-3

3
20 cm of potassium hydroxide
-3
solution 0.1 mol dm and
phenolphthalein as an indicator

Diagram 1

What is the total volume of the mixture in the conical flask at the end point of the
titration in Diagram 1 ?
Apakah jumlah isipadu campuran didalam kelalang kon pada titik akhir pentitratan
pada Rajah 1

A 10 cm3
B 20 cm3
C 30 cm3
D 40 cm3

5 Diagram 2 shows an energy level diagram.

Rajah 2 menunjukkan rajah aras tenaga

Energy

J (s) +T2+ (aq)

-1
∆H=-220kJmol

J 2+ (aq)+ T (s)

Diagram 2

Based on Diagram 2, what is the increase in temperature of the solution if excess J

powder is added to 50 cm3 of T salt solution 0.2 mol dm -3?
Berdasarkan Rajah 2, apakah pertambahan suhu terhadap larutan sekiranya serbuk
J secara berlebihan ditambah kepada 50 cm 3 larutan garam T 0.2 mol dm -3 ?
[Specific heat capacity of solution: 4.0 J g-1 0C-1]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 A 4.4 0C
B 5.5 0C
C 8.8 0C
D 11.0 0C

6 Which of the following quantities of substance contain 6 x 1022 molecules?

Manakah antara kuantiti bahan berikut mengandungi 6 x 10 22 molekul.
[Relative atomic mass: H, 1; C, 12; O, 16; Avogadro’s Constant: 6 X 1023 mol -1]

I 1.8 g water
II 1.0 g hydrogen gas
III 3.2 g oxygen gas
IV 4.4 g carbon dioxide

A I and II only
B III and IV only
C I, III, and IV only
D I, II, III, and IV

8 The equation below represents the decomposition of hydrogen peroxide solution.

Persamaan dibawah mewakili penguraian larutan hydrogen peroksida.

2H2O2(aq)
2H2O(l) + O2(g)

Which of the following are produced when 1 mole of hydrogen peroxide is

decomposed completely?
Manakah antara berikut menghasilkan 1 mol hydrogen peroksida apabila penguraian
lengkap berlaku?

[1 mole of gas occupies 24 dm3 at room condition;

Avogadro’s Constant: 6.0 X 1023 mol-1]

I 2 moles of water
II 12x dm3 of oxygen gas
III 3 x 1023 of oxygen molecules
IV 1.2 x 1024 of water molecules

A I and III only

B I and IV only
C II and III only
D II and IV only

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
9. What is the number of molecules in 1 mole of ammonia, NH3?
Use the information that the Avogadro constant = 6.0 x 1023 mol-1
Apakah bilangan molekul didalam 1 mol ammonia, NH3 ?
Gunakan maklumat bahawa pemalar Avogadro = 6.0 x 10 23 mol -1

A 1.5 X 1023 molecules

B 6.0 X 1023 molecules
C 1.2 X 1024 molecules
D 2.4 X 1024 molecules

10. A compound with formula X2CO3 has a relative formula mass of 138.
What is the relative atomic mass of X?
Use the information that the relative atomic mass of C = 12 and O = 16.
Sebatian yang berformula X2CO3 mempunyai jisim formula relative 138.
Apakah jisim atom relative bagi X ?
Gunakan maklumat dimana jisim atom raltif bagi C = 12 dan O = 16

A 39
B 69
C 78
D 110

11. The equation shows the reaction between sulphuric acid and sodium hydroxide.
Persamaan menunjukkan tindakbalas antara asid sulfuric dan natrium
hidroksida.

H2SO4 + 2NaOH
Na2SO4 + 2H2O

What is the volume of 1.0 mol dm-3 sodium hydroxide solution which can neutralize
25.0 cm3 of 1.0 mol -3 sulphuric acid?
Apakah isipadu bagi 1.0 mol dm -3 natrium hidroksida yang boleh meneutralkan
25.0 cm 3 asid sulfuric 1.0 mol dm -3 .

A. 12.5 cm3
B. 25.0 cm3
C. 50.0 cm3
D. 75.0 cm3

12. 3.2 g of cooper(II) oxide powder is reacted with excess dilute nitric acid.
What is the mass of cooper(II) nitrate formed in the reaction?
3.2 g serbuk kuprum(II) oksida berttindakbalas dengan asid nitric cair secara
berlebihan.
Apakah jisim kuprum(II) nitrat yang terbentuk dalam tindakbalas tersebut?

Use the information that the relative atomic mass of N = 14, O = 16 and Cu = 64.
Gunakan maklumat dimana jisim atom relative bagi N=14, O=16 dan Cu=64.

A. 3.76 g
B. 4.96 g
C. 5.04 g
D. 7.52 g
Module dan Bahan Seminar Untuk Guru
@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
13. The following equation shows the combustion of heptane, C7H16, in excess oxygen.
Tindakbalas berikut menunjukkan pembakaran bagi heptana, C7H16, didalam
oksigen berlebihan.

C7H16 (l) + 1102 (g)
7CO2 (g) + 8H2O (l), ∆ H = -5 512 kJ mol-1

The combustion of heptane in excess oxygen released 1,378 kJ of energy.

What is the mass of heptane used?
Pembakaran heptana didalam oksigen berlebihan membebaskan 1,378 kJ tenaga.
Apakah jisim heptana yang digunakan ?

Use the information that the relative atomic mass of H = 1 and C = 12.
Gunakan maklumat dimana jisim atom relative bagi H=1 dan C=12.

A. 25.0g
B. 36.0g
C. 77.0g
D. 88.0g

14. The diagram shows two balloons filled with oxygen gas and hydrogen gas.
Rajah menunjukkan dua belon yang disikan penuh dengan gas oksigen dan gas
hirogen.

Which of the following statements is true about the two gases?

Manakah antara berikut kenyataan benar tentang kedua-dua gas ?

A. The number of moles of oxygen gas is greater than hydrogen gas

Bilangan mol gas oksigen adalah lebih besar berbanding gas hydrogen.

B. The number of moles of oxygen gas and hydrogen gas is equal

Bilangan mol gas oksigen dan gas hydrogen adalah sama

C. The number of oxygen gas molecules is greater than hydrogen gas molecules
Bilangan molekul gas oksigen adalah lebih besar berbanding molekul gas
hydrogen

D. The number of oxygen gas molecules is fewer than hydrogen gas molecules
Bilangan molekul gas oksigen adalah kurang berbanding molekul gas hidrogen
Module dan Bahan Seminar Untuk Guru
@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
15. A hydrocarbon compound is burnt completely in air to form 17.6 g of carbon dioxide
gas and 7.2 g of water.
What is the molecular formula of the hydrocarbon compound?
Sebatian hidrokarbon terbakar lengkap diudara membentuk 17.6g gas karbon
dioksida dan 7.2 g air.
Apakah formula molekul bagi sebatian hidrokarbon tersebut?

Given that the relative atomic mass of C=12, H=1, O=16.

Diberikan jisim atom relative bagi C=12, H=1, O=16.

A. C2H6
B. C3H8
C. C4H8
D. C4H10

16. The picture shows a waste disposal site. The activity of microorganisms in the waste
produces methane gas.
Gambar menunjukkan kawasan pembuangan bahan buangan. Aktiviti
mikroorganisma terhadap bahan buangan menghasilkan gas methana.

What is the mass of methane gas produced?

Apakah jisim gas methana yang dihasilkan?

Given that the relative atomic mass of H=1, C=12, and 1 mol of gas occupies 24dm3
at room temperature and pressure.
Diberikan jsim atom relatif bagi H=1, C=12 dan 1 mol sebarang gas memenuhi 24
dm 3 pada suhu bilik dan tekanan piawai.

A.12g
B.16g
C.21g
D.27g

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
17. 5 g of element X reacted with 8 g of elements Y to form a compound with the formula
XY2.
What is the relative atomic mass of element X?
5g unsur X bertindakbalas dengan 8g unsur Y untuk membentuk sebatian
berformula XY2.
Apakah jisim atom relatif bagi unsur X?

Given that the relative atomic mass of Y=80.

Diberikan jisim atom relatif bagi Y = 80.

A. 25
B. 40
C. 50
D.100

18. 0.12 g of magnesium reacts with excess hydrochloric acid to produced hydrogen
gas. Given that the relative molecular mass of H=1, Mg=24, Cl=35.5 and 1 mol of
gas occupies 24 dm3at room temperature pressure.
Which of the following is true about the reaction?
0.12g magnesium bertindakbalas dengan asid hidroklorik berlebihan untuk
menghasilkan gas hidrogen.
Diberikan jisim atom relatif bagi H=1, Mg=24, Cl=35.5 dan 1 mol sebarang gas
memenuhi 24 dm 3 pada suhu bilik dan tekanan piawai.
Manakah antara berikut adalah benar bagi tindakbalas tersebut?

I. Mg + 2H+
Mg2+ +H2
II. Volume of gas released is 120 cm3
Isipadu gas yang dibebaskan ialah 120 cm 3
III. Mass of the salt formed is 0.30g
Jisim garam yang terbentuk ialah 0.30g.
IV. This is a redox reaction
Ini merupakan tindakbalas redox

A. I and II only
B. I and III only
C. I, II and IV only
D. II, III and IV only

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
19. In an experiment, the decomposition of 25cm3 of 0.1 mol dm-3 hydrogen peroxide
solution produces oxygen gas.
Didalam eksperimen penguraian 25 cm 3 larutan hidrogen peroksida 0.1 mol dm -3
meghasilkan gas oksigen.

If the experiment is
repeated using another solution, which solution will produce curve Q?
Sekiranya eksperimen diulangi dengan menggunakan larutan lain, larutan yang
manakan menghasilkan lengkung Q ?

A. 25 cm3 of 0.15 mol dm-3 hydrogen peroxide

B. 20 cm3 of 0.15 mol dm-3 hydrogen peroxide
C. 15 cm3 of 0.15 mol dm-3 hydrogen peroxide
D. 10 cm3 of 0.25 mol dm-3 hydrogen peroxide

20. The chemical formula for potassium hexacyanoferrate(III) is K3Fe(CN)6.

What is its relative formula mass?
Formula kimia bagi kalium heksasianoferrat ialah K3Fe(CN)6.
Apakah jisim formula relatifnya?

[Relative atomic mass of C =12, N=14, K=39 and Fe = 56]

A 121
B 199
C 251
D 329

21. If the Avogadro number is represented by the letter x, what is the number of
hydrogen gas particles, H2, with the molar volume of 24 dm3 mol-1 at room
temperature and pressure?
Sekiranya nombor avogadro diwakili oleh huruf x, apakah bilangan zarah gas
hidrogen, H2 dengan isipadu molarnya ialah 24 dm 3 mol -1 pada suhu dan tekanan
piawai ?

A x
B 2x
C x2
D 1x
2
Module dan Bahan Seminar Untuk Guru
@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
22. A dibase acid, H2J has the concentration of 0.5 mol dm-3
Letter J is not the actual symbol of the element. What is the volume of potassium
hydroxide, KOH, 1.0 mol dm-3 that can neutralize 25.0cm3 of the H2J acid solution?
Asid dwibes, H2J mempunyai kepekatan 0.5 mol dm -3.
Huruf J bukan merupakan symbol sebenar bagi unsur. Apakah isipadu bagi kalium
hidroksida, KOH, 1.0 mol dm -3 yang boleh meneutralkan 25.0 cm 3 larutan asid H2J
?

A 6.25 cm3
B 12.50 cm3
C 25.00 cm3
D 50.00 cm3

23. Which of the following reactants produces the highest rate of reaction with zinc
powder?
Manakah antara berikut bahan tindakbalas yang menghasilkan kadar tindakbalas
yang tinggi bagi serbuk zink ?

A 25 cm3 of sulphuric acid 0.1 mol dm-3

B 25 cm3 of ethanoic acid 0.1 mol dm-3
C 25 cm3 of nitric acid 0.1 mol dm-3
D 25 cm3 of hydrochloric acid 0.1 mol dm-3

24. Diagram 2 shows three types of substances.

Rajah 2 menunjukkan tiga jenis bahan

Diagram 2

Which of the following is true about the substance in Diagram 2?

Yang manakah berikut adalah benar bagi bahan pada Rajah 2?

I. The number of particles in gas Z is 3x6·02x1023

Bilangan zarah didalam gas Z ialah 3x6·02x1023
II. All the substances have only 6·02x1023 particles
Semua bahan mempunyai hanya 6·02x1023 zarah
III. The number of particles in liquid X is less than in gas Z.
Bilangan zarah didalam larutan X adalah kurang berbanding gas Z.
IV. The number of particles in solid Y is two times greater than in liquid X.
Bilangan zarah dalam pepejal Y ialah dua kali ganda berbanding
larutan X.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 A I and II only
B III and IV only
C I, II and IV only
D I, III and IV only.

25. Which of the following gases contains 0·4 mol of atoms at room temperature and
pressure?
Manakah antara gas-gas berikut mengandungi 0.4 mol atom pada suhu bilik dan
tekanan piawai ?
[1 mol of gas occupies the volume of 24 dm3 at room temperature and pressure]
[1 mol gas memenuhi isipadu sebanyak 24 dm 3 pada suhu bilik dan tekanan
piawai]

A 4· 8 dm3 He
B 4· 8 dm3 H2
C 4· 8 dm3 SO3
D 4· 8 dm3 CO2

26. The following equation shows the decomposition reaction of copper(II) carbonate
when heated at room temperature and pressure.
Persamaan berikut menunjukkan penguraian bagi tindakbalas kuprum(II)
karbonat apabila dipanaskan pada suhu bilik dan tekanan piawai.

CuCO3
CuO + CO2

Which of the following is not true when 1 mol of copper (II) carbonate is
decomposed?
Yang manakah antara berikut tidak benar apabila 1 mol kuprum(II) karbonat
diuraikan ?
[Relative atomic mass: C=12, O=16, Cu=64 and 1 mol of gas occupies the
volume of 24 dm3 at room temperature and pressure.]
[Jisim atom relative: C=12; O=16 dan 1 mol gas memenuhi isipadu 24 dm 3 pada
suhu dan tekanan piawai]

A 1 mol of copper(II) oxide is formed

1 mol kuprum(II) oksida terbentuk
B 1 molecule of carbon dioxide gas is given off
1 molekul gas karbon dioksida dibebaskan.
C 80 g copper(II) oxide is formed
80g kuprum(II) oksida terbentuk
D 24 dm3 of carbon dioxide gas is given off
24 dm 3 gas karbon dioksida dibebaskan.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 27. Diagram 13 shows the neutralization reaction between a strong acid and a strong
alkali.
Rajah 13 menunjukkan tindakbalas penenutralan diantara asid kuat dan alkali
kuat.

Diagram 13

What is the volume of the alkali needed to produced 1·4625 g of salt?

Apakah isipadu alkali yang diperlukan bagi menghasilkan 1.4625g garam ?

[Relative atomic mass: Na=23, Cl=35·5, H=1, O=16]

[Jisim atom relatif:Na=23, Cl=35.5, H=1, O=16]

A 0·005 cm3
B 0·025 cm3
C 5·000 cm3
D 25·000 cm3

28. In an experiment, 2·4 g of magnesium powder is added to 100 cm3 of 2·0 mol
dm3 copper(II) sulphate solution.
The temperature of the mixture increases by 1·0 0C.
What is the heat of reaction in the experiment?
Didalam satu eksperimen, 2.4g serbuk magnesium ditambahkan kepada 100 cm3
larutan kuprum(II) sulfat 2.0 mol dm-3
Apakah haba tindakbalas bagi eksperimen tersebut?

[Specific heat capacity of a solution = 4·2 J g-10C-1;

Relative atomic mass of Mg = 24]
[Muatan haba tentu larutan = 4·2 J g-10C-1; Jisim atom relatif bagi Mg = 24]

A -0·42 kJ mol-1
B -0·48 kJ mol-1
C -4·20 kJ mol-1
D -4·80 kJ mol-1

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 29. Propane burns completely in oxygen according to the equation shown below.
Propana terbakar dengan lengkap dalam oksigen mengikut persamaan dibawah.

C3H8 (g) + 5O2 (g)
3CO2 (g) + 4H2O (l)

If 1.0 mole of propane gas is burnt completely, which volume of gaseous product
is obtained, measured at room temperature and pressure ?
Sekiranya 1.0 mol gas propana terbakar dengan dengkap, manakah isipadu gas
yang dihasilkan, diukur pada suhu bilik dan tekanan ?

A 0.1 dm3 C 2.4 dm3

B 0.3 dm3 D 7.2 dm3

30. A mixture containing 1 mole of ethane and 4 mole of oxygen is ignited, in a

sealed container at 100 0 C. The reaction occurring is shown by the equation
below.
Campuran yang mengandungi 1 mol ethane dan 4 mol oxygen dinyalakan
didalam bekas yang tertutup pada suhu 100 0 C . Tindakbalas terbentuk
ditunjukkan pada persamaan dibawah.

C2H4 (g) + 3O2 (g)
2CO2 (g) + 2H2O (g)

What was the total number of moles of gas at the end of the reaction?
Apakah jumlah bilangan mol bagi gas pada akhir tindakbalas ?

A 2 C 4
B 3 D 5

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
ACTIVITY 8 : STRUCTURED QUESTIONS

1. Diagram above shows the structural formula of aspirin.

Rajah menunjukkan formula struktur bagi formula aspirin

(a) What is the molecular formula of aspirin?

Apakah formula molekul bagi aspirin ?

(b) What is the molecular mass of aspirin?

Use the information that the relative atomic mass of H = 1, C = 12 and O =
16.
Apakah jisim molekul bagi aspirin
Gunakan maklumat dimana jisim atom relative bagi H=1, C=12 dan O=16.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 [Answer: (a) C9H8O4 (b) 180 ]

2. The ionic equation for the precipitation reaction of silver chloride is:
Persamaan ion bagi tindakbals pemendakan argentums klorida adalah:

Ag+(aq) + Cl-(aq)
AgCl(s)

What is the number of moles of Ag+ ions that reacted with Cl- ions?
Apakah bilangan mol bagi ion Ag + yang bertindakbalas dengan ion Cl - ?

[Answer: 0.0125 mol]

3. When 10cm3 of 0.5 mol dm-3 sodium sulphate solution is added to excess lead(II)
nitrate solution, a white precipitate lead(II) sulphate is formed.
Apabila 10 cm3 larutan natrium sulfat 0.5 mol dm -3 ditambah kepada larutan
plumbum(II) nitrat berlebihan, mendakan putih terbentuk.

i. Write the chemical equation for the reaction.

Tulis persamaan kimia bagi tindakbalas tersebut.

ii. Describe the chemical equation in (3)(i).

Perihalkan persamaan di (3)(i)

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 iii. Calculate the number of mole of sodium sulphate in the solution.
Hitungkan bilangan mol natrium sulfat didalam larutan

iv. Calculate the mass of precipitate formed.

Given that the relative atomic mass of O=16, S=32, Pb=207.
Hitung jisim mendakan yang terbentuk.
Diberikan jisim atom relative bagi O=16, S=32, Pb=207

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
[Answer: (i) Pb(NO3)2 + Na2SO4
PbSO4 + 2NaNO3
(ii) 1 mole lead(II) nitrate reacts with 1 mole of sodium sulphate to produce
1 mole of lead(II) sulphate and 2 moles of sodium nitrate
(iii) 0.005 mol
(iv) 1.515g ]

4. Chemical equation below shows how a nitrogen dioxide is converted into nitric
acid.
Persamaan kimia dibawah menunjukkan bagaimana nitrogen dioksida ditukarkan
kepada asid nitrik

4NO (g) + 2H2O (l) + 3O2
4HNO3 (aq)

Calculate :
Hitung:

(a) The number of mole of nitrogen(II) oxide, NO.

Bilangan mol bagi nitrogen(II) oksida, NO.

(b) The maximum mass of nitric acid which can be produce from 720 dm 3 of
nitrogen(II) oxide, NO at room temperature and pressure.
Jisim maksima asid nitric yang dihasilkan daripada 720 dm3 nitrogen(II)
okside,NO pada suhu bilik dan tekanan.

[Answer: (a) 30 mol (b) 1890g ]

Module dan Bahan Seminar Untuk Guru
@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 MISTAKES ANSWERS COMMONLY MADE BY THE CANDIDATES

1. What is the meaning of scum?

+ +
Ca and Mg ions form in hard water [1 mark]

Correct answer: …………………………………………………………………………

2. What are the two ions in sea water that cause the information of scum?
+ +
Calcium ions, Ca and Magnesium ions, Mg [2 marks]

Correct answer: ………………………………………………………………………….

3. State the name of catalyst used in manufacture of sulphuric acid.

Vanadium oxide [1 mark]

Correct answer:…………………………………………………………………………..

4. Explain how a waster gas produced during manufacture of sulphuric acid can cause
environmental pollution.

Sulphur dioxide will combine with water to form acid rain that can can corrode
buildings and kills plants. [2 marks]

Correct answer: ………………………………………………………………………..

……………………………………………………………………………………………

5. Chlorine reacts with sodium to form a compound.

State the type of chemical bond in this compound

Ionic compound [1 mark]

Correct answer: ………………………………………………..

6.

Diagram above shows part of the periodic Table of Elements. Q,R,T,X and Y do
not represent the actual symbol of the elements.
Arrange all the elements according to the increases in size of the atoms

T,X,Y,Q,R [1 mark]

Correct answer: ……………………………………

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
7. Diagram below shows a sodium chloride compound, NaCl, that is produced by the
+ -
formation of an ionic bond between a sodium ion, Na , and a chloride ion, Cl .

How are a sodium ion and a chloride ion formed from their respective atoms?

Sodium ion : sodium donates electron

Chloride ion : chlorine received electron [2 marks]

Correct answer:

Sodium ion: ………………………………………………………………………………

Chloride ion: ……………………………………………………………………………..

8.

Diagram above shows the arrangement of electron for sodium atom.

From the diagram, the nucleus contains

Eleven proton number and twelve neutron number [ 1 mark]

Correct answer: …………………………………………………………………………….

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 Method of Drawing Diagrams

Set 1:

Set 2:

Set 3:

Set 4:

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 QUESTION A

Table below shows the description and observation for one experiment.

Description Observation
Experiment Electrolysis of 1.0 mol dm-3 of Gas bubbles are released at
sodium sulphate solution using the anode and cathode.
carbon electrodes.

Based on Experiment :
Draw the set up of the apparatus to carry out this experiment.
In your diagram show how the products at the anode and cathode are collected.

[3 marks]

QUESTION B:

Diagram below shows the set-up of apparatus in an experiment to determine the empirical
formula of an oxide of lead.

Which of the following is not correct in the set-up of apparatus for this experiment?

I No Bunsen burner
II Fixing of the cork
III Position of the thistle funnel
IV Position of the deliver tube

A I and III only

B II and IV only
C I, II, and III only
D I, III, and IV only
Module dan Bahan Seminar Untuk Guru
@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 ANSWERING TECNIQUE

QUESTION 1

When 124g of copper(II) carbonate is heated, black colour of the residue and colourless
gas produced.
[Apabila 124g kuprum(II) karbonat dipanaskan,baki pemanasan berwarna hitam dan gas
tanpa warna diahsilkan]
[Given that the relative atomic mass of Cu,64;O,16;C,12: Volume of 1 mol of gas =
3
24 dm at room condition]

i. Write the chemical equation for the reaction. [2 marks]

[ Tulis persamaan kimia bagi tindakbalas yang berlaku]

ii. Describe the chemical equation in (i). [1 mark]

[Perihalkan persamaan kimia di(i).]

iii. Name the residue and the colourless gas produced.[2 marks]
[Namakan mendakan putih yang terbentuk]

iv. Calculate the number of mole of copper(II) carbonate used.[1 mark]

[hitung bilangan mol bagi larutan Natrium sulfat ]

iv. Calculate the volume of colourless gas produced.[3 marks]

[Hitung jisim mendakan putih yang terbentuk]

QUESTION 2

CONCEPT OF OBSERVATION
[KONSEP PEMERHATIAN]
Observation 1

X solution

Y solution

Yellow percipitate

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 Observation 2

QUESTION 3

Balance each of the following equations:

[Seimbangkan persamaan berikut]

i. Chemical equation.

Mg + HCl
MgCl2 + H2

ii. Ionic equation for the forming of water

O2- + H+
H2O

iii. Ionic equation.

+ +
Na + H
Na + H2

iv. Half equation

- + 2+
MnO4 + H
Mn + H2O

v. Half equation
2- + 3+
Cr2O7 + H
Cr + H2O

vi. Ionic equation

2+ - + 3+ 2+
Fe + MnO4 + H
Fe + Mn + H2O

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
QUESTION 4

CHEMICAL TESTS
[UJIAN KIMIA]

Type of gases Method Observation

Hydrogen

Oxygen

Chlorine

Carbon dioxide

QUESTION 5

Sodium metal reacts with oxygen to form a metal oxide compound.

Draw the electrons arrangement of the metal oxide compound formed.
[Logam natrium bertindakbalas dengan oksigen membentuk satu oksida.
Lukiskan susunan electron bagi oksida logam yang terbentuk? ]

[ 2 marks ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
QUESTION 6

The diagram shows the arranggement of outer electrons in a molecules of ethane, C2H6.
[Rajah menunjukkan susunan elektron terluar bagi molekul ethana

Draw similar diagrams to show the arrangement of outer electrons in:

[Lukis rajah yang sama bagi menunjukkan susunan bagi elektron terluar bagi:]

i. Oxygen, O2
ii. Ammonia, NH3
iii. Tetrachlorometane, CCl4

QUESTION 7

Burette

Dilute hydrochloric acid

3 -3
25 cm , 0.5 mol dm sodium hydroxide solution
+ a few drops of phenolphthalein indicator

Diagram 2

Diagram 2 shows the apparatus setup to determine the concentration of hydrochloric acid.
[Rajah 2 menunjukkan susunan radas yang digunakan untuk menentukan kepekatan asid
hidroklorik cair.]

(a) State the colour change occurred in the conical flask when the end point is reached.
[Nyatakan perubahan warna larutan dalam kelalang kon sebaik sahaja takat akhir
tercapai]

[ 1 mark ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (b) Name the analysis technique used and the type of reaction involved in
this experiment.
[Nyatakan kaedah analisis yang digunakan dan tindakbalas yang terlibat dalam
eksperimen itu.]

[ 2 marks ]
3
(c) The average volume of hydrochloric acid used in this experiment is 12.50 cm . Calculate
the molarity of hydrochloric acid used.
[Didapati purata isipadu asid hidroklorik cair yang digunakan dalam eksperimen itu ialah
3
12.50 cm . Hitung kemolaran asid hidroklorik yang digunakan]

[ 3 marks ]

(d) You were given with copper(II) nitrate solution.

[Anda dibekalkan dengan larutan kuprum(II) nitrat.]

(i) Describe briefly how you would test for the presence of copper(II) ion in the
solution.
[Huraikan dengan ringkas bagaimana anda mengesahkan kehadiran ion
kuprum(II) dalam larutan itu ? ]

[ 3 marks ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
QUESTION 8
Hydrogen
Chlorine
gas
gas

-3
1.0 mol dm of
Sodium chloride solution

Carbon
Carbon
electrode X
electrode Y

Explain the reactions at electrodes, X and Y based on the statements below:

Jelaskam tindakbalas pada elektrod X dan Y berdasarkan kenyataan dibawah:

Statement Electrode X Electrode Y

List of Ions that attracted to

electrodes
Senarai ion-ion yang tertarik
kesetiap elektrod

Names of the ion selectively

discharged
Namakan ion yang dipilih
untuk dinyahcaskan

The reason why the ion are

selectively discharged
Nyatakan sebab mengapa
ion tersebut dipilih untuk
dinyahcaskan

Half equation for the

reaction
Setengah persamaan bagi
tindakbalas

Observation
Permerhatian

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
QUESTION 9

Diagram 9

Diagram 9 shows the apparatus set-up for electrochemical cell.

Rajah 9 menunjukkan susunan radas bagi sel elektrokimia.

(a) What is the role of Part X in the electrochemical cell ?

Apakah fungsi bahagian X didalam sel elektrokimia?

[ 1 mark]

(b) State the energy change that occurs in Part X and Part Y.
Nyatakan perubahan tenaga yang berlaku di Bahagian X dan Bahagian Y.

(i) Part X: ...............................................

(ii) Part Y : ................................................

[ 2 marks]

(c) On Diagram 9, mark the

Pada Rajah 9, tandakan

(i) Positive terminal of Part X.

Terminal positif di Bahagian X.

(ii) Direction of the electron flow.

Arah pengaliran elektron [ 2 marks ]

(d) (i) What can be observed on the magnesium ribbon of Part X ?

Apakah pemerhatian yang boleh dibuat pada kepingan magnesium
di Bahagian X?

[1 mark]

(iii) Write the half-equation of the reaction that occurs at (d)(i).

Tulis setengah persamaan bagi tindakbalas yang berlaku di (d)(i).

[1 mark ]
Module dan Bahan Seminar Untuk Guru
@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (e) (i) In Diagram 9 , label the anode of Part Y by writting the word ’ anode’. [1 mark]
Pada Rajah 9, labelkan anod di Bahagian Y dengan menulis perkataan ’anod’

(ii) Write the half-equation of the reaction that occurs at the anode in Part Y.
Tulis setangah persamaan bagi tindakbalas yang berlaku di Bahagian Y.

[ 1 mark]

(f) State what will happen if the magnesium ribbon in Part L is replaced with a silver plate.
Nyatakan apakah yang akan berlaku sekiranya kepingan magnesium di Bahagian Y
digantikan dengan kepingan kuprum.

[ 1 mark]

QUESTION 10

Test Observation
White precipitate formed.
Sodium hydroxide solution is
The white precipitate dissolves in excess
slowly added until excess.
sodium hydroxide solution.
[Larutan natirum hidroksida
[Mendakan putih terbentuk. Mendakan putih
dicampurkan perlahan-lahan sehingga
larut dalam larutan natrium hidroksida
berlebihan]
berlebihan]
A few drops of sulphuric acid is added White precipitate formed.
[ sedikit asid sulfuric cair dicampurkan] [mendakan putih terbentuk]

The table above shows the observations made for a test conducted on a colorless
solution. Among the ions below, which ion will probably exist in the solution?
[Jadual diatas menunjukkan keputusan bagi ujian yang dijalankan ke atas satu larutan
akueus yang tidak berwarna. Antara ion berikut, yang manakah mungkin hadir dalam
larutan itu? ]
3+ 2+ 2+ 2+
A Al B Mg C Pb D Zn

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 QUESTION 11

The following are three examples of sulphate salts.

From these examples, identify the soluble and insoluble salts.
[Berikut adalah tiga contoh garam sulfat.]
[Daripada contoh ini, kenal pasti garam terlarutkan dan garam tak terlarutkan.]

Name of Salts Soluble Insoluble

Potassium sulphate, K2SO4
[Kalium sulfat, K2SO4]

Lead(II) sulphate, PbSO4

[Plumbum(II) sulfat, PbSO4 ]

Zinc sulphate, ZnSO4

[Zink sulfat, ZnSO4 ]

Barium sulphate, BaSO4

[Barium sulfat, BaSO4 ]

QUESTION 12

Gas K
Compound J
[Brown colour
Heat and acidified]

Gas L
Dissolved in [Colourless]
water
+

Solid M
White
precipitate Q
Dissolved in
excess Reaction I Reaction II
sodium Colourless J White
hydroxide solution precipitate R
+ NaOH (aq) + Na2SO4 (aq)
solution

Diagram 4

Diagram 4 shows a series of process done by a student to identify a compound J.

[Rajah 4 menunjukkan beberapa siri tindakbalas yang telah dilakukan oleh seorang pelajar untuk
mengenali sebatian J ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
(a) With refer to reaction I, white precipitate Q is formed which is soluble in excess sodium
hydroxide solution. Name all the ions which are probably presence in solution J.
[Berdasarkan tindakbalas I, larutan J menghasilkan mendakan putih Q yang larut dalam
larutan natrium hidroksida berlebihan. Namakan semua kation yang dijangka hadir dalam
larutan J tersebut. ]

(b) Referring to reaction I and II, name the cation presence in solution J.
[Berdasarkan tindakbalas I dan II, namakan kation yang hadir dalam larutan J itu.]

(c ) Write down the ionic equation for the reaction forming the white precipitate, R.
[Tuliskan persamaan ion bagi tindakbalas pembentukkan mendakan putih R.]

(d) (i) Name two cations which produced white precipitate that will not dissolve
in excess sodium hydroxide solution.
[Namakan dua kation yang menghasilkan mendakan putih yang tidak larut
apabila ditambahkan dengan larutan natrium hidroksida berlebihan]

(ii) State one confirmatory test for one cations presence in (d)(ii).
[Nyatakan satu ujian kimia untuk mengesahkan kehadiran satu kation dalam
d(ii).]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
QUESTION 16

What is the IUPAC name for this alkane ?

[Apakah nama IUPAC alkana itu?] [ 1 mark ]

QUESTION 17

i. Name the homologous series for the hydrocarbon given above.

[Namakan siri homolog bagi hidrokarbon diatas]

ii. Give the IUPAC name for the above compound.

[Apakah nama IUPAC bagi alkena itu ? ] [ 2 marks ]

QUESTION 18

i. Name the homologous series for the hydrocarbon given above.

[Namakan siri homolog bagi hidrokarbon diatas]
ii. Give the IUPAC name for the above compound.
[ Apakah nama IUPAC bagi alkena itu] [ 2 marks ]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
QUESTION 19

A student carried out an experiment to determine the value of heat of neutralization. Diagram 3
shows the set-up apparatus used in the experiment.
[Seorang pelajar telah menjalankan satu eksperimen untuk menentukan nilai haba peneutralan.
Rajah 3 menunjukkan susunan radas yang digunakan dalam eksperimen itu]

Diagram 3

The following data obtained:

[Data berikut telah diperolehi]
0
Initial temperature of hydrochloric acid, ө1 = 30 C
[Suhu awal larutan asid hidroklorik]
0
Highest temperature of the mixture of product, ө2 = 43.5 C
[Suhu tertnggi campuran hasil tindak balas]
3 -3 3
In this experiment, 50 cm of 2.0 mol dm of sodium hydroxide solution is added to 50 cm of
-3
2.0 mol dm of hydrochloric acid.
Given that the specific heat of capacity of the solution is 4.2 J g-1 0C-1 and the density of the
-3
solution is 1.0 g cm .
Draw the energy level diagram for the reaction.
3 -3
[Dalam eksperimen ini 50 cm larutan natrium hidroksida 2.0 mol dm ditambah kepada
3 -3
50 cm asid hidroklorik 2.0 mol dm .
-1 0 -1 -3
Diberi muatan haba tentu larutan ialah 4.2 J g C dan ketumpatan bandingan ialah 1.0 g cm .
Lukis gambar rajah aras tenaga bagi tindak balas itu]

[ 2 marks ]
Module dan Bahan Seminar Untuk Guru
@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 MARKING TECHNIQUE FOR PAPER 2
SAMPLE ANSWERS

Section A

1. Diagram 1 shows the manufacture of sulphuric acid.

(a) What is the name of this process?

Sample answers:
Contact process
[1 mark]
(b) State the name of catalyst X.

Sample answers:
1. Vanadium oxide

2. Vanadium(v) oxide
[1 mark]
(c ) (i) State the name of substance Y.
Sample answer:
Oleum

[1 mark]
(ii) Substance Y is formed when sulphur trioxide reacts with concentrated
sulphuric acid.
Sample answers:
1. SO3 + H2SO4
H2S2O7
2. SO3 + H2SO4
S2O7 H2
[ 2 marks]

(d) A waste gas is produced during the manufacture of sulphuric acid.

Explain briefly how this gas can cause environmental pollution.

Sample answers:
1. Sulphur dioxide will combine with water to form acid rain that can corrode
buildings and kills plants

2. The gas produce is sulphur dioxide. In air, sulphur dioxide will combine with
water molecules from rain to form acid rain which is very dangerous to living
things and corrodes iron substances.
[ 2 marks]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (e) The sulphuric acid produced can be used to manufacture fertilisers.

(i) Name one fertilizer manufactured from sulphuric acid.

Sample answers:
1. Ammonium sulphate
2. Sodium sulphate

[1 mark]
(ii) State another use of sulphuric acid.

Sample answers:

1. To manufacture detergent.
2. as a component in making of detergent and dye.
[1 mark]
2. Table 2.1 shows a group of elements.

Jadual 2.1

(a) In which group of the Periodic Table are these elements located?

Sample answes:
1. Group 17

2. Group VII
[ 1 mark]
(b) Write the electron arrangement for an atom of fluorine.

Sample answers:
1. 2.7

2. 2,7
[1 mark]
(c ) Flourine atoms are smaller than chlorine atoms.
Explain why fluorine forms a negative ion more easily than chlorine.

Sample answer:
1. The valence shell of fluorine atom is nearer to its nucleus than of chlorine
atoms, thus, the force of attraction of the fluorine atom and electrons from
outside is stronger, making it easier to form a negative ion compared to
chlorine.

2. Since fluorine atoms are smaller than chlorine atoms, the distance of the
valence electrons from its nucleus is closer as well as increases in strength
to attract electrons, therefore fluorine forms a negative ion easier than
chlorine atom.

[2 marks]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (d) State the type of chemical bond in an iodine molecule
Sample answer:
Covalent bond
[1 mark]
(e) Chlorine reacts with sodium to form a compound.
(i) State the type of chemical bond in this compound.
Sample answer:
1. Ionic bond

2. Ionic compound
[1 mark]

(iii) Draw a diagram to show the electron arrangement in this compound

[Proton number of Na = 11]

Sample answers:

[2 marks]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (f) Table 2.2 shows three pairs of chemicals.
Sample answers:

Put a tick (√) in the box beside the pair of chemicals which will undergo a
displacement reaction.

[1 mark]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
3. (a) Diagram 3.1 shows the results of an experiment to investigate the movement
of bromine particles in air.

(i) State the name of the process involved in this experiment.

Sample answers:
1. Movement of particles.Kinetic process
2. Diffusion

[1 mark]

(ii) State the type of particles present in bromine gas,Br2.

Sample answers:
1. Molecules
2. Gas
[1 mark]

(iii) Explain the observation in this experiment based on the kinetic theory of
matter.

Sample answers:
1. Gases move very fast in all directions in certain space. When the
cover is removed, bromine molecules collide one another and the
wall of the container filling up the empty space in the gas jar.

2. Particles in matter which is in a gaseous state move freely.The

particles are very far apart and frequency collision occurs move
frequently. As the particles are not arranged in an orderly manner, it
is able to move freely.

[3 marks]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (iv) This experiment is repeated at a higher temperature. Predict the time taken for
the bromine vapour to spread throughout the space in both gas jars.

Sample answers:
1. The time taken will reduce, less than 10 minutes (5 minutes)

2. Less than 10 minutes.

[1 mark]

(b) Diagram 3.2 shows two balloons containing oxygen gas and carbon dioxide gas
respectively.

Based in the given information:

(i) Calculate the mass of oxygen gas in ballon A
[Relative atomc mass: O=16]

Sample answers:

1. Molarity = mass/r.m.m

Mass = r.m.m x molarity

3
= 2(16) x 0.5 = 16 cm .

2. Mol = mass/molar mass

0.5 = m/16(2)
-3
M= 16 g dm .
[1 mark]

(ii) Calculate the volume of carbon dioxide gas in balloon B.

[Molar volume of gas= 24 dm 3 mol -1 at room temperature and pressure]

Sample answers:
3 -1
1. Moles= volume/ 24 dm mol
3
Volume = 0.5 x 24 = 12 dm

2. Volume = mole x 24
= 0.5 x 24
-3
= 12.0 dm .

[ 1 mark]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (iii) Compare the number of gas molecules in balloon A and in balloon B.
Explain your answer.

Sample answers:
1. The number of gas molecules in both balloons are the same. This is
23
because they have 6.02 x 10 particles in 0.5 moles of their
respective gas.

2. Ballon A has a lower number of gas molecules than the ballon B.

This is because ballon B has 3 atoms of gas molecules and ballon B
only has 2.

[ 2marks]

4. The following information is about the compound C2H5OH.

• Miscible in all proportions with water

• Undergoes combustion
• A member of a homologous series

(a) What is the name of this compound?

Sample answer:
Ethanol
[1 mark]

(b) What is the general formula for the homologous series of this compound?

Sample answers:
1. CnH 2n+1 OH, n=2,3,4,.......

2. CnH 2n+1 OH, n=1,2,3,4,.......

[ 1mark]

(c ) One mole of this compound undergoes complete combustion to form gas X and
water as shown below.

C2H5OH + mO2
nX + 3H2O

(i) State the name of gas X.

Sample answers;
1. Carbon dioxide gas

2. Carbon dioxide
[1 mark]
(ii) What are the values of m and n ?

Sample answer:
m=3
n=2
[2 marks]
Module dan Bahan Seminar Untuk Guru
@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (d) Compound C2H5OH reacts with ethanoic acid to produce compound Y which has a
sweet pleasent smell.
(i) State the name of compound Y.
Sample answers:
1. Ethyl ethanoate

2. Ethane ethanoic

[ 1 mark]

(ii) Draw the structural formula of compound Y.

Sample answers:

[1 mark]

(e) Compund C2H5OH undergoes dehydration to produce ethane.

(i) Suggest one dehydrating agent for this reaction.

Sample answers:
1. Hydrogen gas

2. Aluminium(III) oxide
[ 1mark]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (f) Draw an apparatus set-up for this dehydration reaction to collect ethane.
Sample answer:

[ 2 marks]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
5. An experiment is carried out to investigate the rate of reaction of zinc with hydrochloric
acid. Excess zinc powder is added to 20 cm 3 of 2.0 mol dm -3 hydrochloric acid. The
volume of gas collected at regular intervals is shown in Diagram 5.1.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (a) State the meaning of the rate of reaction.

Sample answers:
1. The rate of reaction is the time taken of reactant to produce a product.
2. The change in the amount of reactant or product over time.

[1 mark]

(b) From graph in Diagram 5.1, determine:

(i) The rate of reaction at 120s.

Sample answers:
1. 0.2 cm3 s -1
3 -1
2. 0.098 cm s

[2 marks]
(ii) The average rate of reaction between 60s and 120s.

Sample answers:
3 -1
1. 0.356 cm s
3 -1
2. 0,267 cm s

[1 mark]

(c ) Explain why the rate of reaction decreases with time.

Sample answers:
1. The rate of reaction decreases with time because most of the reactants have
been reacted.
2. Concentration of hydrochloric acid is decreasing.

[1 mark]

(d) Another experiment is carried out to study the factors that affect the rate of this
3
reaction. The result of this experiment using excess zinc powder and 50 cm of 1.0
-3
mol dm dilute hydrochloric acid.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (i) Suggest the factors that influence the rate of reaction to obtain the curves
labelled II and III.
Sample answers:
Curve II: 1. the use of a catalyst. ;
2. Temperature

Curve III: 1. size of reactant particles.

2. Concentration
[2 marks]

(ii) Describe briefly how to carry out the experiment to obtain the curve labelled
III.
Sample answers:
1. The curve labelled III can be obtained by using zinc chips instead of
zinc powder.The large surface area decreases the rate of reaction
and thus, the curve become less steep.
3 -3
2. 50 cm of 0.5 mol dm dilute hydrochloric acid is reacted with
excess zinc powder in a conical flask attached to a syringe. The gas
obtained is carbon dioxide. The volume of the gas is measured and
recorded.

[3 marks]

(iii) Give one reason why the final volume of gas obtained in curve III is half the
final volume of gas in curve I.

Sample answers:
1. This happens because not all the zinc chips have been reacted.

2. This is because the concentration of dilute hydrochloric acid used is half

of the concentration of acid used in experiment I. Concentration of dilute
hydrochloric acid is the limiting factor.
[1 mark]

6. The thermochemical equation for the neutralization reaction between nitric acid and sodium
hydroxide solution is given below.

HNO3 + NaOH
NaNO3 + H2O , ∆H = -57.3 kJ mol -1

(a) State the meaning of heat of neutralisation.

Sample answers:
1. The heat change when one mole of water is formed from H+ ions of HNO3
–
and OH of NaOH.
2. Neutralization is 1 mol of water produced from one hydrogen ion of an acid
and one hydroxide ion from an alkali.
[1 mark]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (b) Based on the given thermochemical equation, state one observation when dilute
nitric acid is added to sodium hydroxide solution.

Sample answers:
1. The plastic container becomes hot as the temperature of the mixture
increases because it is an exothermic reaction where heat is released to the
surrounding.
2. The temperature of the mixture is higher as the reaction releases heat to the
surrounding (exothermic).
[2 marks]

3 -3 3
(c ) In an experiment 100 cm of 2 mol dm nitric acid solution was added to 100 cm of
-3
2.0 mol dm sodium hydroxide solution.
-1 0 -1
[Specific heat capacity of solution = 4.2 J g C ]
Calculate:
(i) The heat energy released in this experiment.

Sample answers.
-1
1. Heat released/no.of moles = 57300 Jmol
No. of moles = 100(2) / 1000 = 1.2
Heat released = 0.2 x 57300
= 11460 J
= 11.46 kJ.

2. Heat released (1) /0.2 = 57300 J

Heat released = 11460 J.
[2 marks]

(ii) The temperature change in this experiment

Sample answers:
1. (100 + 100)(4.2)() = 11460
0
 = 13.6
2. H = mc
-57.3 kJ = (100+100)/2 (4.2)
0
 = 136.429 C

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 (d) Draw the energy level diagram for the reaction between nitric acid and sodium
hydroxide.
Sample answers:

[ 2 marks]

(e) Nitric acid and ethanoic acid both react with sodium hydroxide by a neutralisation
reaction.
-1
HNO3 + NaOH
NaNO3 + H2O , ∆H = -57.3 kJ mol
CH3COOH + NaOH
CH3COONa + H2O, ∆H = -55.2 kJmol -1
Explain why the heat of neutralisation for each reaction is slightly different.
Sample answers:
1. This is because ethanoic acid is a weak acid where as nitric acid is astrong
acid. Therefore ethanoic acid dissociate partially in water to produce lower
concentration of hydrogen ion and more energy is released as energy is
used to break the bonds in the molecules is higher than in nitric acid.

2. Nitric acid is a strong acid while ethanoic acid is a weak acid. Nitric acid has
a bigger number of hydrogen ions to be ionised compared to ethanoic acid.
Moreover, some of the energy is needed to ionise the hydrogen completely in
a solution of weak acid.Thus ,the heat of neutralisation of nitric acid is higher
than of ethanoic acid.
[ 2 marks]

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 Section B

Sample answer:

7. (a) i. The two substance used as food additives are sodium benzoate and ethyl
butanoate.
ii. the function of sodium benzoate is to enhance the taste of the food.
iii. the function of ethyl butanoate is to enhance the smell of the food so that
people will addict to it.

(b) i. For aida, the medicine prescribe to her by the doctor is paracetamol.
ii. the type of the medicine is painkiller.
iii. the correct usage of the medicine is to consume 2 tablets in one day as it is
used to decrease the pain of headache.
iv. as for may ling, the medicine prescribe to her by the doctor is vitamin.
v. the type of the medicine is antibiotic.
vi. the correct usage of the medicine is finish all the antibiotic given by the
doctors as to make sure.May ling is fully recovered from bacterial infection.

(c ) (i) (a) The effectiveness of the cleaning action between I and III are the
same because both cleaning agents A and B succeed to remove the
3
oily stain from the cloth in both 500 cm of soft water.
(b) The effectiveness of cleaning action of experiment II is less effective
than the cleaning action of experiment IV. This is because in
3
experiment II, 20 cm of cleaning agent A failed to remove oily stain
from cloth in
3 3
500 cm of hard water whereas 20 cm of cleaning agent B can
3
remove the oily stain from cloth in the same 500 cm of hard water.
(ii) (a) cleaning agent A is soap
(b) cleaning agent B is detergent.
(c ) the cleaning agent B is more effective than the cleaning agent A.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
8. (a) i. The position of ions in the electrochemical series.
ii. the concentration of the ions in the solution.
iii. the type of electrons used.
-3
(b) in the electrolysis of 1.0 mol dm of sodium chloride solution, using carbon
electrodes, the electrolyte contains 4 ions. The ions from the sodium chloride
Are sodium ions, Na + and chloride ions, Cl - . The presence of water in this
+
solution also explains the presence of hydrogen ions, H and hydroxide ions, OH
-
. Electrode P , which is the negative terminal of this cell acts as the cathode.
+ +
Electrode Q, acts as the anode as it is the positive terminal. Cations Na and H
– –
are attracted towards the cathode (P) while anions Cl and OH are attracted
+
towards the anode (Q). At the cathode, the H ions are selectively discharged.
+
This is because of its position lower than Na in the electrochemical series.
Thus, hydrogen ions have a higher tendency to released electrons to form
+
hydrogen gas. The half equation for the reaction at electrode P is 2H
H2 + 2e.
–
At the anode, Cl ions are selectively discharged.Although the position of OH –
–
ions is lower than Cl ions in the reactivity series, the concentration of chloride
-3 –
ions in the 1.0 mol dm sodium chloride solution is greater than OH ions. Thus
it will have a higher tendency to accept electrons to form molecules, chlorine gas.
The half equation is 2Cl - + 2e
Cl2 . Because of these reasons, hydrogen gas
is collected at electrode P and chlorine gas is collected at electrode Q.

(c ) (i) Silver,Ag
metal M
metal L

Both metals M and L are able to displace silver ions from its salt solution.
This ability tells us that metals M and L are more electropositive than
silver thus placed higher in the electrochemical series. To determine the
position of metal M and L another experiment was conducted with L
nitrate solution and metal M. No reactions were observed. Thus this
states that metal M was not able to displace L from its salt solution. This
tells us that metal M is less electropositive than L in the electrochemical
series. With that, the position of L is above M in the series.

(ii) if the metal is copper, then the solution formed is copper(II) nitrate
solution and the grey deposits are silver metal.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 Section C

9. (a) Metal M is sodium.Sodium will burns brightly with yellow flame when it reacts
with oxygen gas to produce sodium oxide which is white in colour.
+
The half equation for oxidation: Na
Na + e
2-
The half equation for reduction: O2 + 4e
2O

(b) Metal X is lead. This is because lead, Pb is lower in the electrochemical series
than iron,Fe. Metals that are lower in the electrochemical series will accelerate
the rusting process of iron, Fe, when both of them are in contact. The rusting of
2+
iron nail will produce iron(II) ions, Fe which is indicated by the dark blue colour
of the agar which is mixed with potassium hexacynoferrate(III).Potassium
2+
hexacynoferrate(III) detect the present of iron(II) ions, Fe ions by turning colour
from colourless to dark blue.
Metal Y is magnesium.This is because magnesium, Mg is higher in the
electrochemical series than iron,Fe. Metals that are higher in the electrochemical
series will stop rusting process of iron,Fe. If the rusting of iron,Fe does nt occur,
2+ 2+
there will bw no iron(II) ions,Fe produced.The absence of iron(II) ions, Fe is
indicated by the agar which is mixed with potassium hexacynoferrate(III). No
2+
changes in the colour of the agas shows that iron(II) ions ,Fe are not present
thus rusting of iron nail does not occur.

(c ) iron(II) ions can be converted to iron(III) ions. This can be done through the
process of oxidation of iron(II) ions by using chlorine water as the oxidising
agent. First, 3 cm 3 of iron(II) nitrate, Fe(NO3)2 solution is poured into a test tube.
3
Then, chlorine water is added into the test tube, Then 2 cm of sodium
hydroxide, NaOH solution is added into the beaker , after that add the sodium
hydroxide NaOH solution in excess. A brown precipitate which does not dissolve
in excess sodium hydroxide, NaOH solution confirms the present of iron(III)
3+ 2+ 3+
cations, Fe .The half equation that occurs in this experiment are: Fe
Fe
-
+ e, Cl2 +2e
2Cl .
Iron(III) ions can be converted back to iron(II) ions,Fe 2+ through the reduction of
3+ 3
iron(III),Fe by using zinc as the reducing agent. First, 5 cm of iron(III) nitrate,
Fe(NO3)3 solution is added into a test tube. Then, a zinc strip is added into the
3
test tube. Then, pour 2 cm of sodium hydroxide,NaOH solution is added in
excess. A green precipitate which does not dissolve in excess sodium hydroxide,
2+
NaOH solution confirms the presence of iron(II),Fe ions. The half equation in
this experiment are:
3+ 2+
Fe + e
Fe ,
2+
Zn
Zn + 2e

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
10. (a) Example of acid A is sulphuric acid, H2SO4. Example of acid B is nitric acid,HNO3 .
acid A is a strong acid. It ionises completely in water to produce a large amount of
+ +
H ions, hydrogen ions. The amount of H ions present in the solution will influence
+
the pH value. If the concentration of H ions in the solution is high, the pH value will
be low. Since the pH value of acid A is 1 then it is a strong acid. Acid ionises partially
+ +
in water to produce less H ions than in acid A. Since the concentration of H ions
in acid B solution is little, the pH value of the solution is higher, that is 5.
3 -3
(b) A 50 cm of 0.1 mol dm solution of sodium sulphate, Na2SO4 and a solution of
lead(II) nirate, Pb(NO3)2 is prepared. The sodium sulphate solution is poured into a
beaker. Lead(II) nitrate is added into the beaker while stirring the solution with a
glass rod continuously . A precipitate will form at the bottom of the beaker after a few
minutes. The mixture is filtered using a filter tunnel and filter paper. The residue in
the filter paper is lead(II) sulphate. The chemical equation is Na2SO4 + Pb(NO3)2

PbSO4 + 2NaNO3.
The two soluble salt solutions that is sodium sulphate and lead(II) nitrate reacted to
produce an insoluble salt, lead(II) sulphate. The residue is then rinsed with distilled
water. Then it is dried with two sheets of filter paper.

(c ) ethanoate acid should be applied to the skin. It is a an acid it will neutralise the sting
of a jelly fish. Once neutralised it will not cause any more pain to the victim. It is a
weak acid, therefore it will not cause the skin to burn if applied in excess. No further
injury will be caused because it is a weak acid. Although it is a weak acid it can still
neutralise the alkalinity of the sting of the jelly fish.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 MARKING SCHEME FOR MARKING TECHNIQUE

No. Marking Scheme Mark

1(a) Answer: 1 1
Contack process
accept: contact
(b) Answer: 1 1
Vanadium(V) oxide
reject: vanadium oxide
(c)(i) Answer: 1 1
Oleum
a: forming sulphuric acid//pyro sulphuric acid
(ii) Able to write the chemical equation
1. Correct formula and the no of mole for SO3 and H2SO4 1 2
2. Correct formula and the no of mole for H2S2O7 1

Answer:
SO3 + H2SO4
H2S2O7 (1+1) // SO3 (g) + H2SO4(aq/l)
H2S2O7 (aq) – (0+1)
//
SO3 (g) + H2SO4(aq/l)
H2S2O7 (l) – (1+1)

(d) Answer: 2
1. Dissolve/react/combine/mix (r: mixture) with rain water(r:cloud). 1+1
2. Produce acid rain/acidic vapour/solution
r: water/cloud
a: water in the cloud
(e)(i) Answer: 1 1
1. Ammonium sulphate
2. Sodium sulphate
3. Potassium sulphate
4. Magnesium sulphate
(any one)
(ii) Answer: 1 1
1. Electrolyte in car battery
(r: electrolyte; a: electrolyte in battery)
2. [Manufacturing of detergent]
3. [manufacturing of artificial fibres]
4. [manufacturing of paint]
5. [leather tanning]
6. [Manufacturing of dye]
7. As a catalyst
8. As dehydrating agent
9. Remove oxide layer

(any one)

TOTAL 9

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
2(a) 1 1
Answer: Group 17//halogen
a: group seventeen
r: group 7

(b) Answer: 1 1
2.7 // 2,7
(c) Answer: 1 1
1. Attractive forces between nucleus of fluorine and valence
electron/electron/outermost electron are stronger
A: pull of a valance electron by a nucleus is stronger
2. Flourine atom can accept/attract/gain/receive electron easily//
fluorine atom has higher tendency/electron affinity to accept
electron
(d) Answer: Covalent bond 1 1
a: covalent
r: covalent compound
(e)(i) Answer: Ionic bond 1 1
a: ionic, electrovalence

Note:
1. “adp” for compound
2. “wcr” for wrong explanation for each of the bonding.

(e)(ii) Able to draw a diagram to show the electron arrangement of the compound.
1. Correct no of shell and electron for both ions. 1 2
2. Correct charge and label of the ions + nucleus is shown 1

Note:

1. (1+0)

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
 2.
(0+1)

3. (1+1)

(f) Answer: 1 1

Reactants
KI (aq) + Cl2 (aq) √
KCl2 (aq) + Br2 (aq)
KBr (aq) + KCl (aq)

TOTAL 9

No. Marking Scheme Mark

3(a)(i) Answer: Diffusion 1 1
a:diffusion ; r: difuse
(ii) Answer: Molecule
(iii) Answer:
1. Made up tiny/discrete(r:small) particles/molecules 3
2. Continuous/random motion 1
3. Between the air/bromine/another particles // from high 1
concentration to low concentration/region/area// between the 1
particles
a: particles move through the space in the air
(iv) Answer:[Less than 10 minutes] 1 1
a:lesser//time taken is smaller/faster
(b)(i) 1 1
Answer:0.5 x 32g // 16g

(ii) Able to calculate the volume of carbon dioxide gas in balloon B with
correct unit
Answer:
Same 1 2
Able to explain
Answer:
The number of moles is the same 1
a: same volume
TOTAL 10

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
4(a) Answer:Ethanol 1 1
a:ethyl alcohol
(b) Answer: CnH 2n+1 OH 1 1
r:CnH 2n+2 O
Note: if n is given is must be correct
(c)(i) Answer: Carbon dioxide 1 1
(ii) Answer: 1+1 2
m=3
n=2
(d)(i) Answer: Ethyl ethanoate 1 1
(ii) Answer: 1 1

//
//

R;

A: mirror image

(e)(i) Answer: 1 1
1. Concentrated sulphuric acid
2. Porcelain chip
3. Aluminium oxide//alumina/pumice stone
4. Phosphoric acid
(any one)

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
(e)(ii) Able to draw a labelled functional apparatus set-up for the dehydration 1+1 2
reaction and the collection of ethane.
Answer:

water

1. Functional with a correct set-up apparatus and [heat]

2. [collection of gas] and labelling of water, Al2O3, glass wool +
ethanol
TOTAL 10

No. Marking Scheme Mark

5(a) Answer: 1 1
[change of quantity/mol/mass/volume/concentration/amount of
reactant/product] with time taken/time // change in quantity of
reactant/product /[volume of H2 gas] in a certain range of time/per unit
time
(b)(i) 1. Able to draw the tangent at 120s 1 2
2. Able to state the rate of reaction with correct unit 1

Answer:

3 -1 3 -1
Range: [0.15 ± 0.030 cm s [0.12-0.18 cm s ]

Note:
No mark for P2 if tangent is not drawn.

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
(ii) Answer: 1 1
3 -1 3 -1
0.27/0.267 cm s // 16 cm s
3 -1 3 -1
a: 38-22 / 60 cm s // 16/60 cm s
(c) Answer: 1 1
Concentration of hydrochloric acid decreases
a: no of mole of HCl decreases
r; amount/volume of HCl
(d)(i) Able to suggest the factors that influence the rate of reaction 1+1 2
Answer:
Curve II: catalyst/temperature
Curve III: concentration
(ii) Answer:
1. [Repeat the experiment] 3
2. [reduce the concentration] of hydrochloric acid 1
3. The volume of hydrochloric acid remains unchanged// [the volume 1
of acid used must produce less than 0.005 mol of HCl] 1
Alternative answer:
2a: Reduce temperature// use zinc granule
3a: reduce volume of hydrochloric acid

(iii) Able to state the reason why the total volume of gas obtained in curve III 1 1
is half the total volume of gas in curve I

Answer:
[The number of mole of hydrochloric acid used is half of set I]
TOTAL 11

No. Marking Scheme Mark

6(a) Answer:
Heat/energy change/released when 1 mole of water is formed from the 1 1
neutralization/the reaction between acid and alkali // heat/energy
released/change/given out when 1 mole of hydrogen ions/H + , reacts
–
with 1 mole of hydroxide ions / OH

(any one)
(b) Answer:
Observation: the mixture/container become hot//temperature 1
rise/increases
Explanation: [the reaction is exothermic]// heat is released//energy of 1 2
reactants is higher than products
(c)(i) Answer:
1. No of mole of NaOH = 100/1000 x 2 // 0.2 1
2. Energy released = 0.2 x 57.3 kJ // 11.46 kJ // 11460 J // 11.5 kJ 1 2
A: ecf no of mole for P2
(ii) Answer:
1. Correct substitution : 11.46 x 1000 / 200 x 4.2 // 11460/200 x 4.2 1
// 11500 / 200 x 4.2 1 2
0
2. Correct answer with unit: 13.6 C

Note: ecf for energy released

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
(d) Able to draw the correct energy level diagram
Answer: 2
1. Axis with arrow labelled energy and two energy level 1
2. Formula of reactants and products of exothermic reaction written 1
on the correct energy levels

Note: ∆H is optional, ignore wrong value of ∆H

(e) Answer:
1. Ethanoic acid is a weak acid// CH3COOH/ethanoic is partially 1
ionize// nitric acid is a strong acid//HNO3 is totally/fully/completely 1 2
ionize
2. Energy is used to ionize/dissociate CH3COOH/HNO3
TOTAL 11

No. Marking Scheme Mark

7(a) Able to select two substances used as food additives and state the
functions 2+2 4

Sample answers:

Substances Function
Ethyl butanoate √S1 √F1 Flavouring agent //
Improve/give the taste/flavour
Sucrose√S2 √F2 Flavouring agent//
improve/give the taste/flavour
a: sweetener
Citric acid√S3 √F3 Antioxidant// prevent oxidation
Gelatin√S4 √F4 Thickening agent// to thicken
the food
Sodium benzoate√S5 √F5 Preservative// prevent the
growth of microorganism

(any two pairs)

Note: Apply wcr for function only

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
7(b) Able to state the names of the medicine, the types of medicine and the
correct usage 2+2 4
Sample answer

Type of
Name of medicine Usage
medicine
Aida 1.Aspirin // 2. 3. Proper dosage//
paracetamol Analgesic// taken after food//
Pain killer taken with doctor’s
prescription
May 4. 5.antibiotic 6.Proper dosage
ling Penicilin//Streptomysin (a:given/taken by
injection)// taken
after food//
complete course//
taken with doctor’s
prescription

Another sample answers:

1.

Name of Type of
Usage
medicine medicine
Aida Analgesic × Aspirin √2 √3 Proper dosage//
taken after food//
taken with doctor’s
prescription
May ling Antibiotic × Penicillin √4 √ 6 Proper dosage
(a:given/taken by
injection)// taken after
food// complete
course// taken with
doctor’s prescription

2.

Type of Name of
Usage
medicine medicine
Aida Aspirin × Analgesic√2 √3 Proper dosage//
taken after food//
taken with doctor’s
prescription
May ling penicilin × antibiotic√5 √ 6 Proper dosage
(a:given/taken by
injection)// taken after
food// complete
course// taken with
doctor’s prescription

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
7(b)
3. not mention the name but in correct order

Type of
Name of medicine Usage
medicine
Aspirin // paracetamol Analgesic// √3 Proper dosage//
√1 Pain killer √2 taken after food//
taken with doctor’s
prescription
Penicilin//Streptomysin Antibiotic √5 √6 Proper dosage
√4 (a:given/taken by
injection)// taken
after food// complete
course// taken with
doctor’s prescription

4. not mention the name but in wrong order

Name of Type of
Usage
medicine medicine
Penicilin × antibiotic √5 √ 6 Proper dosage//
taken after food//
taken with doctor’s
prescription
aspirin× analgesic√2 √ 3 Proper dosage
(a:given/taken by
injection)// taken after
food// complete
course// taken with
doctor’s prescription

5. name is mention but wrong medicine is precribe

Type of Name of
Usage
medicine medicine
May Ling Aspirin × Analgesic √2 √ 6 Proper dosage//
taken after food//
taken with doctor’s
prescription
Aida penicilin × Antibiotic √5 √ 3 Proper dosage
(a:given/taken by
injection)// taken after
food// complete
course// taken with
doctor’s prescription

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
7(c)(i) Sample answer

Experiment I and III

1. Soft water does not contain calcium ions /Ca 2+ / magnesium 1

ions/ Mg 2+ / metal ions
2. Cleaning agents A and B both dissolve in soft water// not form 1
scum in soft water
3. Cleaning action/agent in experiment I is as effective 1
as/same/equal cleaning action in experiment III

Experiment II and III

4. Hard water contains calcium ion/Ca 2+ / magnesium ions/ Mg 2+ 1

/ metal ions
5. Cleaning agent A reacts with Ca 2+/ Mg 2+ to form 1
scum/insoluble salt/precipitate
6. Cleaning agent B does not from scum/precipitate/insoluble salt 1
7. Cleaning agent/action in experiment IV is more effective than 1 7
cleaning action in experiment II
a:detergent is more effective than soap if soap and detergent
mention in Experiment II and experiment IV.

Notes:
1. If Ca 2+/ Mg 2+ in hard water is mentioned in P5 or P6, P4 can be
awarded
2. P4 and P5 (apply adp for Ca 2+ and Mg 2+)
i.e: (a) hard water contain calcium and magnesium - XP4
cleaning agent A reacts with Ca and Mg to form
scum.√P5
(b) Hard water contain Na + and Ca 2+ - .√P4
Cleaning agent A reacts with Na + and Ca 2+ to form
scum - XP5
(c ) Hard water contain Na + ion – XP4
Cleaning agent A reacts with Na + to form scum - XP5

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
7(c)(ii)
Sample answer

1. Cleaning agent A : soap

2. Cleaning agent B: Detergent 1
1
Able to state which cleaning agent is more effective

Sample answer

3. Cleaning agent B is more effective than cleaning agent A

a:B 1 3

20

No. Marking Scheme Mark

8(a) Sample answer
1. At electrode P : the position of ions in electrochemical series 1
2. At electrode Q: concentration of ions 1
a: concentration of electrolyte// concentration

Note: 2
1. P & Q is not mentioned (follow the order)
- Position of ion in electrochemical series – √P1
- Concentration of ions - √P2 (1+0)

2. P & Q is not mentioned and answer given more than two

(a) - Position of ion in electrochemical series – √P1
- Concentration of ions - XP2 wcr
- type of electrode – X (1+0)

(b) - Position of ion in electrochemical series – √P1

- type of electrode - X
- Concentration of ions – ignore because not in sequence
(1+0)

(c) - type of electrode - X

- Concentration of ions – √P2
- Position of ion in electrochemical series – ignore (0+1)

(d) - type of electrode - X

- Position of ion in electrochemical series – ignore
- Concentration of ions – ignore (0+0)

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
(b) Sample answer

Electrode P/cathode Q/anode

Ions that are + +
√P1 Na , H √Q1 Cl - , OH -
attracted
Name the
ions that are
√P2 Hydrogen ion √Q2 Chloride ion
selectively
discharged
√Q4 Concentration
√P3 H + is lower in the
Reason of Cl – higher than
electrochemical series
OH -
√P4 √P5 2H + + 2e
H2 √Q5 √Q6 2Cl -
Cl 2
Equation
+ 2e
P4 & Q4 :
correct formula of reactant and product
P5 & Q5:
correct coefficient of reactant and product

No. Marking Scheme Mark

8(b) Note:
1. Q2 – chlorine ion – X
Q3 – chlorine ion - √ adp

2. 2H+ + 2e = H2 – X P5 √P4
2Cl - = Cl2 + 2e – X Q5 √Q4

3. If ion attracted to opposite – ecf XP1 √Q1

4. H + + e
H – 0+0
5. H + + e
H2 – (1+0) XP5 √P4
6. H++e
H
H + + e
H2 - X P4 √P5
7. Cl -
Cl + e
Cl + Cl
Cl2 - X Q4 √Q5

8. Equation given but wrong explanation - X P4 √P5

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
8 (c)(i)
Sample answer

Experiment I II III
√1 L is more √3 M is more √5 L is more
electropositive electropositive electropositive
than silver// L than silver// M than M// L is
is higher than is higher than higher than
Explanation
silver in the silver in the silver in the
electrochemical electrochemical electrochemical
series series series
a:L ion a:M ion a:L ion
√2 L can √4 M can √6 M cannot
displace silver displace silver displace L
from its from its from its
solution solution solution
(1+1) (1+1) (1+1) Max
5

8. The order of the three metals: Ag/Silver, M/Cu/Copper, L 1 6

8(c)(ii) Able to name the products formed in experiment II 1+1 2

Answer:
1. Copper(II) nitrate
a: copper nitrate

2. Silver
20

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
9(a) 1. Able to suggest a suitable metal 1
2. Able to describe the observation when M reacts with oxygen 1
3. Able to write the half-equation for oxidation 1
4. Able to write the half-equation for reduction 1 4

Sample answer:

1. Potassium/Sodium/Lithium/Rubidium/Cecium/Francium
2. White solid//white fume/bright (for all metals)
Burns with purple (a:lilac) /yellow/red flame

3. M
M + + e
(M is either K/Na/Li/Ru/Ce/Fr)

4. O2 + 4e
2O 2-

Note:
1. P2 and P3 must corresponding to P1
i.e:
1. Potassium
2. burn with purple flame
3. K
K + + e

2. 1. magnesium - X
2. white solid - √
3. Mg
Mg 2+ + 2e - X
4. O2 + 4e
2O 2- - √

3. 1. Lead - X
2. white solid - X
3. Pb
Pb 2+ + 2e - X
4. O2 + 4e
2O 2- - √

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
9(b) Able to suggest metal X and give reason
Sample answer:

1. X: copper/silver 1
[any metal less electropositive than iron]

2. X is less electropositive than iron// x is lower than iron in 1

electrochemical series
3. Iron rust/oxidised/lose electron to form [Fe 2+ ] ions 1
Ie: Iron rust, Fe
Fe 2+ + e.

Able to suggest metal Y and give reason

Sample answer:

4. Y: magnesium/aluminium/zinc 1
[any metal more electropositive than iron]

5. Y is more electropositive than iron // Y is higher than iron 1

in electrochemical series
6. [Y] oxidised/lose electron to form [Y] ions // prevent 1 6
/inhibit iron from being oxidised/rusted

Note:
1. Adp for ECS
2. Metal X – magnesium - X
Magnesium is less electropositive than iron – X
Magnesium is more electropositive than iron - X

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
9(c) Sample answer:
Fe 2+
Fe 3+

1. [suitable metal] 1
Magnesium/zinc //
[any other suitable metal more electropositive than iron]
2. Add the [metal] to [solution containing Fe 3+ ] 1
3. Heat/shake/stir 1
4. Decant/filter the mixture/solution 1
5. Add sodium hydroxide /potassium hexacynoferate(II)/(III) 1
solution 1
6. Green/blue/dark blue precipitate is formed
[note: if insoluble iron(III) compound is used, no marks for
P2,P4 and P6. Ie. Fe2(CO3)3

Fe 3+
Fe 2+

7. [suitable halogen] 1
Chlorine/bromine/iodine 1
( mark given if mention chlorine gas // bromine gas/vapour 1
at P7and at P8 must pass the gas through FeSO4) 1
8. Add chlorine/bromine water to [solution containing Fe 2+ ]
9. Heat/stir/warm 1
10. Add sodium hydroxide /KSCN/Potassium
hexacynoferate(II)/(III) solution Max
11. Brown /blood red solution/blue/dark blue precipitate 10
formed

Note:
1. P11 must corresponding to P10
2. If U-tube is used, P8 and P9 as follows:
P8a – pour H2SO4 into U-tube, pour FeSO4 solution into
one arm of the U-tube and chlorine water into another arm
P9a – place/immerse/dip carbon/graphite electrode into
chlorine water and FeSO4 and connect to
galvanometer/voltmeter
3. If insoluble iron(II) compound is used, no marks for P8 10
and P11

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
10(a)
Sample answer:

Acid A Acid B
√A1 Hydrochloric acid// √B1 Ethanoic acid//
sulphuric acid [any named of weak acid]
√A2 Strong acid √B2 Weak acid
1+1
√A3 Ionises completely in √B3 Ionises partially in water
water 2+2
Max
√A4 HCl
H + + Cl – √B4 CH3COOH
CH3COO - 4
+H+
√A5 Concentration H + is high √B5 Concentration H + is low

(any two) (any two)

6

Note:
1.
Acid A Acid B
Ethanoic acid - X Nitric acid – X
Strong acid – X Weak acid – X
Ionises partially in water - X

2.
Acid A Acid B
Ethanoic acid - X Nitric acid – X
Weak acid acid – √ strong acid – √
Ionises partially in water - √ Ionises completely in water -
√

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
10(b) Able to describe the preparation of lead(II) sulphate and include
the chemical equation involved

Sample answer:

1. Substances 1
Lead(II) nitrate/lead(II) ethanoate/sulphuric acid// [any
soluble sulphate]
2. Apparatus: 1
Beaker, filter funnel, filter paper

Procedures:

3. Pour 20 cm 3 /[20 – 100 cm 3] of 0.5 mol dm -3 /[0.1 – 2.0 mol 1

dm -3] lead(II) nitrate into a beaker
4. Add 20 cm 3 of 0.5 mol dm -3 sodium sulphate 1
[adp for concentration and volume if didn’t mention in P3 and
P4 but word “ into a beaker “must present]
5. [Stir the mixture] 1
6. Filter 1
7. Wash/rinse the residue/solid/PbSO4 / salt/ precipitate 1

Equation
√8 √10 √9
Pb(NO3)2 + Na2SO4
PbSO4 + 2NaNO3 //
√8 √10 √9
2+ 2-
Pb + SO4
PbSO4
1
8. Formula for reactants 1
9. Formula for products 1 10
10. Balance equations

Note:
1. P1 and P2 can be inferred from the labelled diagram or
procedure.
2. If insoluble salt other than PbSO4 or not using double
decomposition reaction, give P2,P5,P6 and P7
3. If soluble salt is prepared only given P5 and P2
4. If lead(II) sulphate is prepared by recrytalitation , no mark
given

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/
No. Marking Scheme Mark
10(c)
Sample answer:

Substance : vinegar(acetic acid)/ethanoic acid/citric acid/lemon 1

juice
[any substance that containing weak acid]
a:lemon/lime/any other acidic substance

Reasons: 1
1. Weak acid 1
2. Neutralise the alkali 1 4
3. Does not produce too much heat 1
4. Acid is less corrosive// acid does not [harm] skin
Max
[ any three] 3

Note:
If strong acid given – only P2 given

20

END OF MARKING SCHEME

Module dan Bahan Seminar Untuk Guru

@JUJ 2009

JUJ SPM 2009

http://edu.joshuatly.com/
http://www.joshuatly.com/