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CHM421 Assignment Question

The document contains 25 chemistry problems involving calculations related to concentrations, molarity, and stoichiometry for various substances including salts, acids, and bases. The problems cover a range of concepts such as distinguishing between different concentration units, calculating the mass of a solute needed for a given volume of solution, determining molarity and percent composition from experimental data, and calculating equivalent weights.

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aremyrah Azlan
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147 views

CHM421 Assignment Question

The document contains 25 chemistry problems involving calculations related to concentrations, molarity, and stoichiometry for various substances including salts, acids, and bases. The problems cover a range of concepts such as distinguishing between different concentration units, calculating the mass of a solute needed for a given volume of solution, determining molarity and percent composition from experimental data, and calculating equivalent weights.

Uploaded by

aremyrah Azlan
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Questions

1. Distinguish between the expression of concentration on weight/weight, weight/volume, and volume/volume


bases.
2. Express ppm and ppb on weight/weight, weight/volume and volume/volume bases.
3. Calculate the grams of substance required to prepare the following solutions:
a) 250mL of 5.00% (wt/vol) NaNO₃
b) 500mL of 1.00% (wt/vol) NH₄NO₃
c) 1000mL of 10.0% (wt/vol) AgNO₃
4. What is the wt/vol % of the solute in each of the following solutions?
a) 52.3g Na₂SO₄/L
b) 275 g KBr in 500mL
c) 3.65g SO₂ in 200mL
5. Calculate the formula weights of the following substances:
a) BaCl₂ · 2H₂O
b) KHC₂O₄ · H₂C₂O₄
c) Ag₂Cr₂O₇
d) Ca₃(PO₄)₂
6. Calculate the number of millimoles contained in 500mg of each of the following substances:
a) BaCrO₄
b) CHCl₃
c) KIO₃ · HIO₃
d) MgNH₄PO₄
e) Mg₂P₂O₇
f) FeSO₄ · C₂H₄(NH₃)₂SO₄ · 4H₂O
7. Calculate the number of grams of each of the substances in Problem 12 that would have to be dissolved and
diluted to 100mL to prepare a 0.200M solutions.
8. Calculate the molar concentrations of all the cations and anions in a solution prepared by mixing 10.0mL each
of the following solutions:
a) 0.100 M Mn(NO₃)₂
b) 0.100 M KNO₃
c) 0.100 M K₂SO₄
9. A solution containing 10.0 mmol CaCl₂ is diluted to 1 L. Calculate the number of grams of CaCl₂ · 2H₂O per
milliliter of the final solution.
10. Calculate the molarity of each of the following solutions
a) 10.0g H₂SO₄ in 250 mL of solution.
b) 6.00g NaOH in 500mL of solution
c) 25.0g AgNO₃ in 1.00L of solution
11. Calculate the number of grams in 500mL of each of the following solutions:
a) 0.100 M of Na₂SO₄
b) 0.250 M Fe(NH₄)₂(SO₄)₂ · 6H₂O
c) 0.667 M Ca(C₉H₆ON)₂
12. Calculate the grams of each substance required to prepare the following solutions:
a) 250mL of 0.100 M KOH
b) 1.00 L of 0.0275 M K₂Cr₂O₇
c) 500 mL of 0.0500 M CuSO₄
13. How many milliliters of concentrated hydrochloric acid, 38.0% (wt/wt), specific gravity 1.19, are required to
prepare 1 L of a 0.100 M solution? (Assume density and specific gravity are equal within three significant
figures.)
14. Calculate the molarity of each of the following commercial acid or base solutions:
(Assume density and specific gravity are equal within three significant figures.)
a) 70.0% HClO₄. Specific gravity 1.668
b) 69.0% HNO₃. Specific gravity 1.409
c) 85.0% H₃PO₄. Specific gravity 1.689
d) 99.5% CH₃COOH (acetic acid). Specific gravity 1.051
e) 28.0% NH₃. Specific gravity 0.898
15. A solution contains 6.0 µmol Na₂SO₄ in 250ml. How many mg/L sodium does it contain? Of sulfate?
16. Calculate the mg/L concentrations of 2.50 × 10ˉ⁴ M solutions of each of the following.
a) Ca²⁺
b) CaCl₂
c) HNO₃
d) KCN
e) Mn²⁺
f) MnO₄⁻
17. A 0.456g sample of an ore is analyzed for chromium are found to contain 0.560mg Cr₂O₃. Express the
concentration of Cr₂O₃ in the sample as
a) Percent
b) Parts per thousand
c) Parts per million
18. How many grams NaCl should be weighed out to prepare 1 L of a 100-mg/L solution out of
a) Na⁺
b) Cl⁻
19. One liter of a 500-mg/L solution of KClO₃, contains how many grams K⁺?
20. A 12.5-mL portion of a solution is diluted to 500mL, and its molarity is determined to be 0.125. What is the
molarity of the original solution?
21. A preparation of soda salt is known to contain 98.6% Na₂CO₃. If a 0.678g sample requires 36.8 mL of a sulfuric
acid solution for complete neutralization, what is the molarity of the sulfuric acid solution?
22. A 0.372g sample of impure BaCl₂ · 2H₂O is titrated with 0.100 M AgNO₃, requiring 27.2 mL. Calculate
a) The percent Cl in the sample
b) The percent purity of the compound
23. Calculate the equivalent weights of the following substances as acids or bases:
a) HCl
b) Ba(OH)₂
c) KH(IO₃)₂
d) H₂SO₃
e) CH₃COOH
24. Calculate the equivalent weight of KHC₂O₄
a) As an acid
b) As a reducing agent in reaction with MnO₄⁻
(5HC₂O₄⁻ + 2MnO₄⁻ + 11H⁺ → 10CO₂ + 2Mn²⁺ + 8H₂O)
25. A solution of KHC₂O₄H₂C₂O₄ · 2H₂O (three replaceable hydrogens) is 0.200eq/L as an acid. What is its
concentration in eq/L as reducing agent? (See Problem 45 for its reaction as reducing agent.)

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