Chapter 17-Physics of Solids Important Questions With Answers
Chapter 17-Physics of Solids Important Questions With Answers
Ans. The solids in which the atoms, ions and molecules are arranged periodically are
called crystalline solids.
Examples:
2. Every crystalline solid has sharp melting point i.e., for every crystal there is a
temperature at which the thermal vibrations becomes so great that the structure suddenly
breaks up, and the solid melts.
Examples:
1. As the atom, ions and molecules are not arranged periodically in amorphous solids, so
these solids don’t show the phenomenon of X-ray diffraction.
2. The amorphous solids don’t have sharp melting point. For example, a glass passes
through a paste like state on heating and becomes a very viscous liquid at almost 800C
Ans. Polymeric solids are formed by polymerization reaction in which relatively simple
molecules are chemically combined into massive long chain molecules. Polymers may be
said to be more or less solid materials with a structure that is intermediate between order
and disorder.
Example:
Plastics, synthetic rubber, polythene and nylon etc. are the examples of polymers.
Properties of Polymeric Solids
Polymeric solids have low specific gravity, but yet they exhibit good strength to weight
ratio.
Q # 4. Define following:
i) Unit Cell
Ans.Unit Cell
A crystalline solid consists of three dimensional pattern that repeat itself over and over
again. This smallest three dimensional basic structure is called unit cell.
Crystal Lattice
The whole structure obtained by the repetition of unit cell is known as crystal lattice.
Ans. Deformation
Any change in shape, volume and length of an object when it is subjected to some
external force is called deformation.
Deformation in Crystalline Solids
In crystalline solids atoms are arranged in a certain order. When external force is applied
on such a body, a distortion results because of displacement of the atoms from their
equilibrium position and the body is said to be in state of deformation.
In deformed crystalline solid, the atoms return to their equilibrium position after the
removal of external force. This ability of the body to return to its original shape is called
elasticity.
Ans. The properties shown by the solid material under the action of external force are
called mechanical properties. Physical quantities such as stress, strain and modulus of
elasticity are used to describe the mechanical properties of solids.
The force applied on unit area to produce any change in the shape, volume or length of a
body is called stress. Mathematically, it is described as:
Force(F)
Stress( )
Area( A)
The SI unit of stress is newton per square meter, which is given the name pascal (Pa).
Types of Stress
Tensile Stress: A stress that causes the change in length of an object is called tensile
stress.
Shear Stress: A stress that causes the change in shape of an object is called shear stress.
Volume Stress: A stress that causes the change in volume of an object is called volume
stress.
Q # 8. Define the term Strain. Also describe its different types.
Ans. Strain is the measure of deformation of a solid when stress is applied to it. For the
case of one dimensional deformation, strain is defined as the fractional change in length.
If l is the change in length and l is the original length, then the strain is given by:
l
strain( )
l
Since strain is the ration of lengths, it is dimensionless, and therefore, has no units.
Types of Strain
Tensile Strain: If the strain is due to tensile stress, it is called tensile strain.
Shear Strain: A strain produced in the object when it is subjected to shear stress is called
shear strain.
When the opposite faces of a rigid body are subjected to shear stress, the shear strain
produced is given by:
a
Shear Strain tan
a
Volumetric Strain: When the applied stress changes the volume, then the change in
volume per unit volume is called volumetric strain. Thus
v
VolumetricStrain
v
Q # 9. What do you know about Modulus of Elasticity? Describe its different types.
Ans. Modulus of Elasticity: The ratio of stress to strain is a constant for a given
material, provided the external applied force is not too great, called modulus of elasticity.
Mathematically, it is described as:
Stress
Modulus of Elasticity
Strain
Since the strain is a dimensionless quantity, the units of modulus of elasticity are the
same as that of stress, i.e., Nm-2 or Pa.
Young Modulus: For the case of linear deformation, the ration of tensile stress to tensile
strain is called Young Modulus (Y):
f /A
Y
l / l
Shear Modulus: When the shear stress τ = (F/A) and shear strain (γ = tanθ) are
involved, then their ratio is called shear modulus (G):
F /A
G
tan
Bulk Modulus: For three dimensional deformations, when volume is involved, then the
ratio of applied stress to volumetric strain is called bulk modulus (K):
F /A
K
V / V
Q # 10. How the mechanical properties of a wire are determine in Tensile Test.
In tensile test, metal wire is extended at a specified deformation rate. The stresses
generated in the wire during deformation are continuously measured by a suitable
electronic device fitted in the mechanical testing machine. Stress-strain curve is plotted
automatically on XY chart recorder. A typical stress strain curve for a ductile material is
shown in the figure:
In the initial stages of deformation, stress is increased linearly with strain till point A on
stress-strain curve. This is called proportional limit.
Proportional limit is the greatest stress that a material can endure without losing straight
line proportionality between stress and strain.
From A to B, the stress and strain are not proportional, but nevertheless, if the load is
removed at any point between O and B, the curve will be retraced and the material will
return to its original length. The point B is called yield point and the value of stress at this
point is known as yield stress or elastic limit.
Elastic limit is the greatest stress that a material can endure without any permanent
deformation.
If the stress is increased beyond elastic limit, the specimen becomes permanently
deformed. This kind of behavior is called plasticity. The region of plasticity is
represented by the portion of the curve from B to C. The point C represents ultimate
tensile strength (UTS).
Once point C corresponding to UTS is crossed, the material breaks at point D, responding
to fracture stress.
Ductile Substances
Substances that undergo plastic deformation until they break are called ductile
substances. Lead, copper and wrought iron are ductile.
Brittle Substance
The substances which break just after the elastic limit is reached, are known as brittle
substances. Glass and high carbon steel are brittle.
Q # 12. Define the term Strain Energy. Also derive its expression of strain energy by
considering force-elongation graph obtained during the tensile test of a wire.
Ans. Strain Energy: The amount of P.E stored in a material due to displacement of its
molecule from its equilibrium position, under the action of stress, is called strain energy.
Consider a wire whose one end is attached to a fixed support, is stretched vertically by
connecting a weight at its lower end. The suspended weight acts as a stretching force.
The extension in the wire is increased by increasing the stretching force. The graph
plotted between extension l for the different value of stretching force is shown in the
figure:
It is clear from the figure that the force is constant in producing extension l1 but is
changing linearly from 0 to F1. In order to calculate the work done for extension l1 by a
certain force F1, it is convenient to find the work done by graphical method.
The work done for extension l1 by a certain force F1 will be equal to the area under force
– extension curve, which is equal to the area of triangle OAB. Therefore,
1
Work Done = (base)(altitude)
2
Work Done=(OA)(OB)
1
Work Done = (l1 )( F1 )
2
1
Strain Energy = (l1 )(F1 ) ...... (1)
2
If A is the cross-sectional area of the wire of length L, then the modulus of elasticity E of
the wire can be described as:
stress
Modulus of Elasticity
strain
F1 / A
E=
l1 / L
F1 L EAl1
E= F1
l1 A L
l1 1
1 EAl
Strain Energy=
2 L
1 EAl12
Strain Energy=
2 L
Q # 12. What do you mean by electrical properties of solids? Also write a short note
on energy band theory of solids.
Ans. The electrical properties of solids determine its ability to conduct electric current.
The conventional free electron theory based on Bohr Model failed to explain completely
the vast diversity in the electrical behavior of solids. On the other hand, the energy based
on wave mechanical model has been found successful in resolving this problem.
i. Energy Band
ii. Forbidden Band
iii. Valance Band
iv. Conduction Band
When the numbers of atoms are brought together, as in a crystal, they interact with one
another. As the result, each energy level splits up into several sub-levels. A group of such
energy sub-levels are called an energy band.
Forbidden Bands
The energy bands are separated by gaps in which there is no energy level. Such energy
gaps are called forbidden bands.
Valence Bands
The electrons in the outermost shell of an atom are called valance electrons. Therefore,
the energy band occupied by valance electrons is called the valance band. The valance
band may be either completely filled or partially filled with the electrons but can never be
empty.
Conduction Band
The energy band next to the valance band is called the conduction band. The valance and
conduction bands are separated by forbidden energy gaps. The conduction band may be
empty or partially filled. The electrons in the conduction band can drift freely in the
materials and are called free or conduction electrons.
Ans. The width of forbidden energy gap between valance and conduction band decide
whether a material is a conductor, insulator or a semiconductor.
Insulators
Insulators are those materials in which valance electrons are bound very tightly to their
atoms and are not free. In terms of energy bands, it means that an insulator has:
Conductors are those which have plenty of free electrons for electrical conduction. In
terms of energy bands, conductors are those materials in which valence and conduction
band largely overlap each other. There is no physical distinction between the two bands
which ensures the availability of free electrons. That is why, the conductions are good
conductors of electricity.
Semiconductors
In terms of energy bands, semiconductors are those materials which at room temperature
have
Ans. At 0 K, there are no electrons in the conduction band and their valence band is
completely filled. It means at 0 K a piece of Ge or Si is a perfect insulator.
However, with the increase of temperature, some electrons possess sufficient energy to
jump across the small energy gap from the valance band to conduction band. This
transfers some free electrons in the conduction band and create some holes in the valance
band. The vacancy of electron in the valence band is known as a hole. It behave like a
positive charge. Thus at room temperature, Ge or Si crystals becomes a semiconductor.
Intrinsic Semiconductor
A semiconductor in its extremely pure form is known as intrinsic semiconductors.
Extrinsic Semi-conductors
Pure elements of silicon and germanium are intrinsic semi-conductors. These semi-
conductor elements have atoms with four valence electrons. In solid crystalline form, the
atoms of these elements arrange themselves in such a pattern that each atom has four
equidistant neighbors. Each atom with its four valence electrons, shares an electrons from
its neighbors. This effectively allocates eight electrons in the outermost shell of each
atom, which is a stable state.
Q # 19. Describe the different types of extrinsic semi-conducting materials.
The conductivity of silicon and germanium can be drastically increased by the controlled
addition of impurities to the intrinsic (pure) semi conductive material.
N-Type Semi-conductors
When a silicon crystal is doped with a pentavalent element, e.g., arsenic, antimony or
phosphorous etc., four valance electrons of impurity atom form covalent bond with the
four neighboring Si atoms, while the fifth valence electron provides a free electron in the
crystal. This extra electron becomes a conduction electron because it is not attached to
any atom. Such a doped extrinsic semi-conductor is N-type semi-conductor.
P-Type Semi-conductors
When a silicon crystal is doped with the trivalent element, e.g., aluminum, boron, gallium
or indium etc., three valence electrons of the impurity atom form covalent bond with
three neighboring Si atoms, while the one missing electron in the covalent bond with the
forth neighboring Si atom, is called a hole which in fact is vacancy where an electron is
accommodated. Such a semi-conductor is called P-Type Semi-conductor.
Q # 20. What is effect of battery on the motion of charge carrier in a semi-conductor
crystal?
i. Superconductors
ii. Critical Temperature
iii. High Temperature Superconductors
Superconductors
The materials whose resistivity becomes zero below a certain temperature are called
superconductors.
Critical Temperature
The temperature at which the resistivity of a material falls to zero is called critical
temperature.
High Temperature Superconductors
Any superconductor having a critical temperature above 77K (the boiling point of liquid
nitrogen) is referred as high temperature superconductor.
The magnetism produced by electrons within an atom can arise from two motions:
i) Electron orbiting the nucleus behaves like an atom sized loop of current that
generate small magnetic field.
ii) The spin motion of electron also gives rise to a magnetic field.
The net magnetic field generated by the electrons within an atom is due to combined field
created by their orbital and spin motion.
Paramagnetic Substances
The solids in which the orbital and spin axes of the electrons in an atom are so oriented
that their fields support each other are called paramagnetic substances. In these solids,
each atom behaves like a tiny magnet.
Diamagnetic Substance
In diamagnetic substance, there is no resultant field as the magnetic field produced by
both orbital and spin motions of the electron might add up to zero. For example, the
atoms of water copper, bismuth and antimony are diamagnetic.
Q # 25. Write a note on Ferromagnetic Substances. Also describe its different types.
In ferromagnetic substances, e.g., Fe, Co, Ni, Chromium dioxide and Alnico, the atoms
cooperate with each other in such a way so as to exhibit a strong magnetic effect. In
ferromagnetic substance, there exist small regions called domains (contain 1012 to1016
atoms). Within each domain, the magnetic fields of all spinning electrons are parallel to
one another, i.e., each domain is magnetized to saturation. Each domain behaves as a
small magnet with its own north and south poles.
In soft ferromagnetic substances, the domains are easily oriented on applying an external
field and also readily return to random positions when the field is removed. This is
desirable in an electromagnet and also in transformers. Iron is a soft magnetic material.
i. Hysteresis
ii. Saturation
iii. Remanence or Retaintivity
iv. Coercivity
v. Area of Hysteresis Loop
Hysteresis
The value of flux density for any value of current is always greater when the current is
decreasing, then when it is increasing, i.e., magnetism lags behind the magnetizing
current. This phenomenon is known as hysteresis.
Saturation
The alignment of all domains of magnetic materials under the influence of external
magnetic field is called saturation. The magnetic flux density increases from zero and
reaches a maximum value. At this stage, the material is said to be magnetically saturated.
Remanence or Retaintivity
When the current is reduced to zero, the material still remain strongly magnetized
represented by point R on the curve. It is due to the tendency of domains to stay partially
in line, once they have been aligned.
Coercivity
To demagnetize the material, the magnetizing current is reversed and increased to reduce
the magnetization to zero. This is known as coercive current, represented by C on curve.
The Coercivity of steel is more than that of iron, as more current is needed to
demagnetize it.
The area of the loop is the measure of the energy needed to magnetize and demagnetize
the specimen during each cycle of the magnetizing current. This is the energy required to
do work against internal friction of the domains. This work is dissipated as heat. It is
called hysteresis loss.
Hard magnetic material like steel cannot be easily magnetized and demagnetized, so they
have large loop area as compared to soft magnetic materials such as iron which can easily
be magnetized. The energy dissipated per cycle, thus, for iron is less than for steel.
Q # 29. Describe the advantages of Hysteresis Loop.
Suitability of magnetic material for different purposes can be studied by taking the
specimen through a complete cycle and drawing the hysteresis loop.
A material with high Retaintivity and large coercive force would be most
suitable to make a permanent magnet.
The cores of electromagnets used for alternating current where the specimen
repeatedly undergoes magnetization and demagnetization should have narrow
hysteresis curve of small area to minimize the waste of energy.
MCQs Related to the Article “17.1 CLASSIFICATIONS OF SOLIDS”
(a) Amorphous Solids (b) Polymeric Solids (c) Glassy Solids (d) Crystalline Solids
(a) Crystalline Solids (b) Amorphous Solids (c) Polymeric Solids (d) Glassy Solids
(a) Radio Waves (b) Infrared Waves (c) X-rays (d) Ultraviolet Rays
(a) Metals (b) Ionic compounds (c) Ceramics (d) All of them
(a) Polymeric Solids (b) Glassy Solids (c) Crystalline Solids (d) Brittle Solids
(a) Polymeric Solids (b) Glassy Solids (c) Crystalline Solids (d) Ductile Solids
11. How many crystal systems are there on the basis of geometric arrangement of
the atoms:
(a) Tensile stress (b) Shear stress (c) Volumetric stress (d) Longitudinal stress
(a) Tensile stress (b) Shear stress (c) Volumetric stress (d) Longitudinal stress
5. Which one of the following physical quantities does not have the dimensions of
force per unit?
(a) Stress (b) Strains (c) Young’s modulus (d) Pressure
N N
(a) (b) (c) Nm (d)no unit
m2 m
(a) Young’s modulus (b) Shear modulus (c) Bulk modulus (d) Tensile modulus
1 1 2 1 2 1 22
(a) U F1l1 (b) U F1 l1 (c) U F1l1 (d) U F1 l1
2 2 2 2
(a) Lead (b) Copper (c) Glass (d) Lead and copper
11. Substances which break just after the elastic limit is reached are called:
(a) Ductile substances (b) Hard substances (c) Soft substances (d) Brittle substances
(a) Proportional Limit (b) Elastic Limit (c) Permanent Stress (d) Ultimate Tensile Stress
13. Materials that undergo plastic deformation before breaking are called ________
MCQ # 9: (c) MCQ # 10: (d) MCQ # 11: (d) MCQ # 12: (d)
5. Germanium is:
8. At 0K piece of Ge or Si is a perfect:
(a) Conduction band (b) Valence band (c) Forbidden band (d) Empty band
(a) Conduction band (b) Valence band (c) Forbidden band (d) Core band
(a) Conductors (b) Insulators (c) Semiconductors (d) All of the above
(a) Holes only (b) Electrons only (c) Both Electrons and Holes
17. The net charge on N-type material is ________
(a) Electronic Current (b) Current due to Hole (c) Both a & b
MCQ # 9: (a) MCQ # 10: (b) MCQ # 11: (c) MCQ # 12: (a)
MCQ # 13: (d) MCQ # 14: (c) MCQ # 15: (c) MCQ # 16: (c)
MCQ # 5: (d)
(a) Spin motion (b) Orbital motion (c) Spin & orbital motion
5. The substances in which atoms cooperate with each other in such a way so as to
exhibit strong magnetic field are called:
(a) 103 to 106 (b) 106 to 109 (c) 109 to 1012 (d) 1012 to 1016
7. Curie temperature for iron is:
(a) Applied current (b) Coercive current (c) Maximum current (d) None of these
11. The energy need to magnetize and demagnetize the specimen during the each
cycle of magnetizing current is
MCQ # 9: (d) MCQ # 10: (b) MCQ # 11: (d) MCQ # 12: (a)