CheCal 1 Reviewer
CheCal 1 Reviewer
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1,. A solution composed of 5O%ethanol, 10% methanol and 40 % HzA is fed at the rate of 100kg/hr
into a separator that produces one stream at the rate of 60 kg/hr with the composition of 8O%
ethanol, 15% methanol and syoH2O, and a second stream of unknown composition. CalcuJate
the composition (in %) of the three compounds in the unknown and its flow rate in kg/hr.
A liquid adhesive, which is used to make laminated boards, consists of a polymer dissolved in a
solvent. The amount of polymer in the solution has to be carefully controlled for this
application. When the supplier of the adhesives receives an order for 3000 kg of an adhesive
solution containing t3 wt% polymer, all it has on hand (1) 500kS of a 10 wt% solution, (2) a very
Iarge quantity of a 2O wlYo solution, and {3) pure solvent. Calculate the weight of each of the
three stocks that must be 'blended tog€ther to fill the order. Use all of the 10 wt% so*ution.
w, 4a tr$\h \
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SoD LD. \D\ + Fa LD'QI\ ' 3o uu [U' B) sbo LD"qD) , rr t o'rb) " 30ou LD'80
Tq ' \-100 \t
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CHEMICAL CALCUL.ATIONS 1: SEATWORK
t. An aqueous solution of methanol containing 20 wt% methanol is to be separated into a
distillate product containing 97 wt% methanol and a bottom product containing Zwt%
methanol. For treating 100 kg feed with a reflux ratio 3.5 on a weight basis, calculate the
following:
a. The amounts of distillate and bottom products
b. The amount of vapour condensed in the condenser per kg of distillate
c. The amount of vapour condensed in the condenser per kg of feed.
2. ln the azeotropic distillation of an ethanol-water solution, a feed mixture containing gS.6%
alcohol is mixed with pure benzene and distilled. The benzene forms a ternary azeotrope
with alcohol-water with a composition of 74.1% benzene, 7.4%owater and 18.5% alcohol,
which is distilled over as the overhead product. Absolute alcohol is obtained as the residue
product. Determine the quantity of benzene required for producing 100 kg of absolute
alcohol.
3. 1000 kg of mixed acid of composition 4}yo H5SO4,45% HNO3 and L5%H2O is to be produced
by strengthening waste acid of composition 31ya H25O4,36% HNO3 and 34% HzO by weight.
Concentrated sulphuric acid of strength 95% and concentrated nitric acid containing 80%
are available for this purpose. How many kilograms of spent acid and concentrated acjds are
to be mixed together?
4. A continuous distillation column is used to regenerate solvent for use in a solvent extraction
unit. The column treats 200 kmofh of a feed containing 10 mol% ethyl alchohol and the
rests water. The overhead product is 89 mol% alcoholand the bottom product is O.3 mol%
alcohol. The overhead is sent to the extraction unit and the bottom is waste. What is the
daily requirement of make-up alcohol in the solvent extraction unit.
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CHEMICAL CALCULATIONS 1: MIXING
1. The liquid effluent from a processing plant having a BOD of 0.15 g/L is discharged at a rate of
4000 cubic meters per day into a stream flowing at a rate of 0.3 cubic meters per second and
having an initial BOD of 5 x 10-3 g/1. Determine the BOD in the stream immediately below the
discharge point?
Z. lt is decided to measure the flow rate of a pure air stream by injecting pure CO2 at a rate of
lgmoUh into the flowing stream. The resulting mixture analysed 8.6%C}zon a mole basis.
What is the flow rate of air?
3. Urea, phosphoric acid and potassium chloride are mixed together to obtain a mixed fertilizer
having NPK content 10:26:26 as %N, %PzOsand %K2O by weight, balance being the weight of
filler materials. Calculate the quantities to be mixed to get 1000 kg of mixed fertilizer.
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P. Fr ' 1o rtru\\h h
1. ln the concentration of orange juice a fresh extracted and strained juice containing 7.08 wt%
solids is fed to a vacuum evaporator. ln the evaporator, water is removed and the solids content
increased to 58 wt% solids. For 1000 kg /h entering, calculate the amounts of the outlet streams
of concentrated juice and water.
2. 1,200 lb of barium nitrate are dissolved in sufficient water to form a saturated solution at 90oC.
Assuming that 5% of the weight of the original solution is lost through evaporation, calculate the
crop of the crystals obtained when cooled to 20oC. Solubility date of barium nitrate at 90oC =
30.6 lb/100 lb water, at 20oc = 9.2 lb/100 lb water.
3. A solution of MgSOa atz2}oF containing 43g MgSOa per 100 g H2O is fed into a cooling
crystallizer operating at 50oF. lf the solution leaving the crystallizer is saturated, whaJ: is the rate
at which the solution must be fed to the crystallizer to produce one ton of MgSO4- 7H2O per
hour?
4. Crystals of NazCOg - of NazCOg in water at L00'C.
10H2O are dropped into a saturated solution
What percent of the NazCO: in the Na2CO3-H2O is recovered in the precipitated solid? The
precipitated solid is NazCOa-HzO. Data at 100oC: the saturated solution is31..2% NazCOa;
molecular weight of NazCOs is 106.
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EXTRACTION (LIQUID _ LIQUID EXTRACTION)
lsopropyl alcohol and water can be separated by extraction with ethylene tetrachloride
(CzCla)'
L.
100 kg of a solution containing 30 wt% isopropyl alcohol and the rest water is mixed with the
solvent ethylene tetrachloride. After extraction, the raffinate phase analysedTl% wi'ter, 28.1o/o
isopropyl alcohol and 0.9% ethylene tetrachloride. The extract phase anatysed 94% ethytene
tetrachlorid e,5.2Yo isopropyl alcohol and the rest water. Calculate the following:
a. The amount of solvent
b. The quantities of raffinate and extract phases
c. The percent extraction of isopropyl alcoholO
2.TwoliquidsAandBareonlypartiallymiscible'Atacertaintemperature'4lkgofAarrd5gkgof
B are mixed well and the mixture is allowed
to settle. The mixture separates into two immiscible
phase analyses 90% A and the B-rich
phases, one rich in A and the other rich in B' The A-rich
phase analyses B.what are the
iloa/o weights of the A-rich and B-rich phases?
Acetic acid is extracted from an aqueous solution
containing 42.86 wt% acetic acid u:;ing
3.
and water may be neglected' when
benzene as the solvent. The mutual solubility of benzene
are mixed and the phases separated' the
equal weights of benzene and the aqueous solution
aqueous solution
aqueous phase analysed 16.25%acetic acid. on the basis of 100 kg of the
being ileated, calculated the following:
a. The masses ofthe aqueous phase and benzene phase
b. The percent recovery of acetic acid into benzen
( cqc\,1)
l.
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LEACHING
1. A tannery extracts certain wood barks which contains tannin,5% moisture, 23% soluble
4O%o
non-tannin materials and the rest insoluble lignin. The residue removed from the extraction
tanks contain 50% water, 3% tannin and 1% soluble non-tannin materials. What percent of the
original tannin remains unextracted?
2. Soybean seeds are extracted with hexane in batch extractors. The flaked seeds conta in 20% oil,
68% solids and 12% moisture. At the end of the extraction process, the ca ke is sepa rated f rom
the hexane-oil mixture. The cake analysis yields 0.8% oil,88% solids, and 1.1..2% moisture. Find
the percentage recovery of oil.
3. Oilseeds containing 49% oils, 40% pulp, 3%, mineral salts and the rest moisture are leerched wjth
hexane as the solvent. The underflow from the leaching operation contains 25% hexane,2.5yo
salts, 15% oil and 7.5% moisture. The extract contains 25% oil. The extract is distilled to recover
the entire hexane in pure form leaving behind the oil, water and salt. The underflow is subjected
to steam distillation which recovers 95% hexane. For treating 100 kg seeds, calculate the
following:
a. The kilograms of hexane used
b. The percent of hexane used that is recovered from the underflow
c. Percent recovery of oil
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e
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, sc(6.15) 1E (0,?5)
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t
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\
"r" hclGn.o uttd recowwd tn ffi',' ft
x \bu
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f.crvc,t1
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Ad so rphort
2. A gas mixture at gOO ( and t bar analysingty volume 20% N2 and 80% CHq is subiected to
liquefaction at a rate of 1500 kg/h. lt is found that only 30 wt% of the entering gas is Iiquefied
and the concentration of N2 in the liquid is 50% by weight. The unliquefied gas leaves the unit at
273 K and 1 bar. Determine:
a. The volume of unliquefied gas, m3/h
b. The composition of the gas leaving expressed as volume %
3. ln the preparation of cooking liquor for a sulphite pulp mill, an absorption column is used to
absorb SOz in a weak liquor. The weak liquor enters the top of the column at a rate of 1.5
m'/min with SOz concentration of 0.5 wt% and leaves with SO2 concentration of 1.0 lvt%. The
gas stream entering the bottom of the column and passing in the counter-current direction to
the liquid stream contains 15% SO2. When the gas leaves the top of the column, 80% SOz is
absorbed. The pressure in the column is 1.5 bar and the temperature is 310 K. Assuming that the
liquor has a specific gravity of L.0, determine the following:
a. The amount of SOz absorbed per minute
b. The molar flow rate of gas entering the absorber
c. The percentage of SOz in the gas leaving the column
d. The volumetric flow rate of gas leaving the absorbe
r)
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ffi\nu\'" 1,1,. ,
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t Ymt\ acetbto
28
RELATIVE SATURATION
5. A fuel saturated with water vapour at 300 K and 100 kPa has a heating value of 250011 kJ/m3 of
the total gas. What will be the heating value in kJ/m3 of the gas at 295 K and 105 kPa if its
relative saturation is only 50%? The vapour pressure of water at 300 K and 295 K are 3.5 kPa and
2.6 kPa resPectivelY.
0.rb' L
&.bYlrr
Yv
0p, " r.?b * \u-t{ [rnt\
CI1r,te
r O. Dqlt trrto\ - S, 3D Y \u-' \trnd
eq
DEW POINT
1,. A mixture of nitrogen and benzene has a dew point of 300 K. The temperature and the pressure
of the mixture are 335 K and 105 kPa, respectively. The vapour pressure if benzene (kPa) is
ln Pc = 13.8858 -2788'5L
' T-s2.36
Calculate the following:
a. Percent saturation of the mixture
b. Kilogram benzene per kilogram nitrogen
c. Kilograms benzene per cubic meter of mixture
d. Dew point of the mixture if the total pressure were 100 kPa
e. Pressure required to condense 60% of the benzene from the mixture at 300 K
2. One cubic meter of a gas at STP is to be dried from a dew point of 300 K to a dew point of 285 K-
/
x P-f tr\bb
q) *1"
srr[,\fctilLil\ ' Pt* =' \V.k\ V?A \rb - Iy, 61
....-
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ul,Scf\l\c{hbn . \1, \1'1,
Pp
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' Y-ltl mp \ft -\z"Yl x:t8'.\\'
a8 ,bl I_
0,
c) vgkHqlh,f rn\Y.
_h.= unr nry 'JJ$. j D,0SZ1
Bosts , \rn] rnY PT
\m
(tru, vtn\c t nn' hJt " t\,{baq X\u-e Y.nlb\
RIT
tv.anclsY) conc. = q ,q tu a \ t\o-? Yntl\ [1r' rz;
hr ' C. Of34 trrqo\ \rn3 grr rn)y
Co hL.= 0 3r-l1 L1 rruo
3D
Pp tb \\ts
d') T6rpo,rt'1 Y" \ooYf61 )' = 0, 1b\1
Krrrc\
Yrrto\ 'l$a
?- ?p
e ' ' ?At
dcu: go't$ Pn
Pfi '
Dq))
h Pr' \60 V?cr t(l'
?1 " q'to L?q' ff
A-tEs.rl ar\\. ?8 \(
0n[q.tDv?a] ( \? 8818 _
Iarr,,ptr\ - 5l'3b
- 0,qu)
DRYING / HUMIDIFICATION
of water in kilograms is
1. Wood containing 40% moisture is dried to 5% moisture. what mass
evaporated per kilogram of dry wood?
point of 20oc and leaves al70%
2. Air at 101.3 kpa enters an adiabatic drier at 87.5"C with a dew
5% moistur':. content'
humidity. Wet paper enters the drier with 25% moisture and leaves with
Determine the following:
a. water evaporated in kilograms per 100 cubic meters of air entering
b.Finishedproductinkilogramsperl00cubicmetersofair
During tlrying, the
3. A batch of leather leaving a dryer weighs 1000 kg and contains 5% moisture.
leather loses 50% of its original weight. Determine the following:
a. The moisture content of the leather entering the dryer on a dry basis 1.105 kg of water per
kg of drY leather
The amount of moisture removed per kg of bone dry leather (1.05 kg of
water p€rr kg of dry
b.
leather)
C'WaterremovedaSpercentoftheoriginalWaterpresent(95-74%\
3l
\.
J'u'l 'L ;
rolr rnb\Ji-
4o'),rnrv 0 z'lt, l1
ko'[, d'r] {\olu Artl
W' \60 -P r
&is\t IbD\c9 6\ Ur06d, 0.60 water
{11 : 31.xnv1
rr,) bc\On((:
Bu[ c\3,r.ood
J'ln \\aD
F*t.r', 'l,l
'-------)u
I
nA
5/
2. Final purification stage in the preparation of certain pharmaceutical product A from natural
sources requires centrifuging and continuous filtration as depicted below. Determine the flow
rate of recycle stream in kS / h.
A ba\qnrc:. l+=wlB
\00.[0,Q6) , P L0,r,o J\. z lr. L\q r lu ' 53
Da\anra il F\fYer.
B ! R YP
B-R=0\.51V9 lh-'--O
h V"\anct ct) $'lt(n
eLb-br) = -o.y cR) + e\.rl fo.ff)
r V0.5
rT
\R=
l#tr
\q,o? tqlh I
$z 40. sr Blh
3?
7
3. Wet solid containing water is mixed with recycled dry solid to reduce the water content to
TAYo
50% before being admitted into the granulator. The solid leaving the granulator is fed to a drier
where it is brought into contact with dry air initially containing 0.25% water by weight. ln the
. drier, the air picks up moisture and leaves with a moisture content of 5%. The solids eaving the
drier contains?O% water. A portion of this solid is recycled.
For 1000kg/h of wet solid sent to the granulator as fresh feed, determine the following:
34
7
RECYCLE AND BYPASS
1. Air at 320 saturated with water vapour is dehumidified by cooling to 285 K and by consequent
K
condensation of water vapour. Air leaving the dehumidifier, saturated at 285 K is mi>:ed with a
part of the original air which is bypassed. The resulting air stream is reheated to 320 K. lt is
desired that the fina[ air contains water vapour not more than 0.03 kg per kg of dry air,
Calculate:
a. The mass of dry air (in kilograms) bypassed per each kg of dry air sent through the
dehumidifier
b. The mass of water vapour (in kilograms) condensed in the dehumidifier per 1"00 cubic
meters of air sent through it
c. The volume of final air obtained per 100 cubic meters of air passed through the
dehumidifier
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36