Guide 9 Bitumen Emulsions Storage and Handling PDF
Guide 9 Bitumen Emulsions Storage and Handling PDF
November
2018
9 STORAGE AND HANDLING
OF BITUMINOUS EMULSIONS
Purpose
The purpose of this guide is to provide to the Bituminous Emulsion End User a brief
explanation of Bituminous Emulsions and advice on it’s Safe Storage and Handling, Types,
Care and Equipment Design, Operation and Maintenance.
Disclaimer
Although the information contained in this guide is believed to be fundamentally correct and current at time of printing, the
Australian Asphalt Pavement Association does not accept any contractual, tortious or other form of liability for its content or any
consequences arising from its use.
A colloid mill is used to refine the bulk bitumen into bitumen droplets (approx. 10 micron),
with the mill determining how fine the emulsion is.
The emulsifier adds a charge to the bitumen droplets and this keeps the particles separated
and suspended in the water.
In Australia, the more common variety is Cationic due to having a predominately negatively
charged aggregate in the field. Most important is that Cationic and Anionic emulsions should
never be mixed to avoid coagulation, cleaning cost and/or cross contamination.
Emulsions are inherently unstable and over time, if not circulated and left undisturbed, the
particles will flocculate (stick together), eventually coalescing (merging to form larger
particles) and then sedimenting (dropping to the bottom). If this happens the bitumen is no
longer emulsified and has separated from the water and will not remix.
Because bitumen is denser than water, larger particles settle faster, react more slowly with
aggregates, and can have adverse effects on storage life, cohesion and adhesion.
Well designed and maintained colloid mills, in conjunction with good emulsifiers, make fine
stable emulsions. Other specialist additives can also be used to adjust for changes in
bitumen quality or to adjust the break/storage time.
To reduce settlement and avoid sedimentation (non-redispersible) correct handling and
storage are of major importance.
Any activity that forces particles close together or disrupts their surface charge risks
coarsening and destabilising the emulsion.
These activities include:
Types
There are 2 Emulsion Types:
Standard Emulsions
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Storage life
The length that emulsions can be stored varies according to the emulsion type and
components used. For example rapid-set emulsion has a shorter shelf life than a slow-set
emulsion.
You should seek advice from your emulsion supplier on the shelf life of their products.
Sedimentation and sieve tests are good indicators of an emulsion’s potential storage life.
During long-term storage, sedimentation of the bitumen droplets occurs due to the higher
density of the bitumen versus water. Regular circulation will help increase the shelf life of the
emulsion but care must be taken not over circulating which can shear the emulsion and
cause residue build up.
Emulsions may increase in viscosity (thickness) over time and warming the emulsion prior to
use will reduce the viscosity.
Bulk Storage
Tank design
All regulatory and company engineering standards must be followed when designing and
constructing a tank.
Tanks may be made from mild or stainless steel, high density polyethylene, polypropylene
co-polymer and many engineering plastics. The selection of materials to be used will depend
on the heating system to be employed. It is always recommended that the emulsion supplier
be consulted when considering a new tank or repairing tanks.
AAPA recommends the following features be included:
Vertical Tanks
Vertical tanks are ideal for the storage of standard
Example of a vertical tank
emulsions. With an angled return pipe, a round
shape tank creates a whirlpool, promoting gentle
circulation of the emulsion. This tank type also has
a reduced surface area resulting in less exposure
of emulsion to air and skin formation. They also
occupy less space, are easier to heat, insulate and
monitor for product level.
Horizontal Tanks
Horizontal tanks are generally not recommended
Example of a horizontal tank
because they present a larger surface area to the
air that can form a large skin, are more difficult
clean and circulate. Their use should be limited to
short term field storage. Horizontal tanks may be
set with a slight slope to facilitate draining and a
directional return pipe to promote circulation.
learn the history of the tank eg Age, Previous use, internal design,
thoroughly clean before use to ensure the best environment for the storage of your
Bituminous Emulsion. Cleaning can involve the use of use steam, high pressure
water, low pressure water, dry ice and/or kerosene.
Before commencing any work on a tank care should be taken to ensure it is safe to do so
and that there is no flammable or harmful liquid, gas or residue present.
Never cut a used tank unless an appropriate hot work permit is obtained.
Care is required when siting storage tanks, for example they should not be located near high
tension power lines. Where practicable, they should be located away from waterways.
Tank plumbing
All pipework should be engineered to:
Tank inspections
A build-up of residue inside a tank will occur over time and can reduce the storage life and
the effectiveness of an emulsion. However with simple proactive maintenance practices,
operators of bituminous emulsion storage tanks will be able to ensure the storage tank is
kept free of excessive residue.
An annual inspection of the inside of the tank is highly recommended to determine the
volume and viscosity of any residue. This will then dictate the best course of action required
in terms of the need for flushing, cleaning or dig out.
Only those with a confined spaces permit and the appropriate PPE should enter a tank.
Prior to changing over emulsion suppliers AAPA recommends that an inspection of the tank
is performed by the new supplier to determine what cleaning procedure will be required to
ensure the emulsion will not be adversely affected by the previous product.
Keeping packaged Emulsion undercover in areas where the product won’t be exposed to
temperatures below 5°C to avoid freezing and damage from frost
Store packaged emulsion in an upright position off the ground (e.g. on a pallet)
Circulating
o IBC’s
Use an agitation tool/pump to stir the emulsion within the IBC
o Pails/Drums
Use an agitation tool to stir the emulsion within the drum
Use an engineered pail/drum rotator to help keep emulsion homogenous
Ensure vessel is sealed and lay the pail/drums on their side and roll them
for several metres along the ground to mix the emulsion and then return
them to their upright position
Ensure good stock rotation practices and use emulsion within 3 months from the date of
manufacture
Heating systems
With Bituminous Emulsions the objective is to stop the emulsion excessively cooling, ie < 5⁰c
rather than actually heating the product.
Avoid heating without stirring as this can result in localised overheating, particularly if
electrical heating is employed, which can lead to breaking of the product inside the tank and
a subsequent build-up of residue.
Types of heating systems suitable for emulsion tanks include:
Rate of heating
Care must be taken to ensure emulsion is not heated rapidly. The heating rate should not
exceed 10°C per hour as this implies excessively high heating surface temperatures.
Exceeding this rate of heating can cause flocculation of the bitumen droplets especially if it
contains polymers around the heating flues or electrical elements.
Standard Emulsion – 10 20 - 30 60
Anionic and Cationic Slow,
Medium or Rapid Set ≤ 69%
Bitumen Content
Pumps
Centrifugal pumps
For storage tanks, centrifugal pumps are most suited for caring for the emulsion and
avoiding shearing of the emulsion.
In a centrifugal pump the material is fed into the centre of the pump under gravity and a high
speed impeller pushing it out to the recirculation or despatch outlet.
Another option is to gravity feed when despatching from the tank.
Loading emulsion
When loading road tankers or sprayers, or filling drums, the emulsion should be passed
through a filter consisting of a mesh sieve with an aperture of 4 – 6 mm. This will prevent
lumps of bitumen blocking nozzles in the spray bar.
These sieves should be checked and cleaned regularly to maintain acceptable loading rates.
Loading of emulsion should be done by sucking the product into to bottom of the sprayer or
by lowering the filling hose to the bottom of the road tanker. This is to avoid foaming or
breaking of the emulsion due to splash filling.
It is not recommended that emulsion be returned into storage as it can compromise the
quality of the product.
Emulsion dilution
On occasion emulsions are diluted with water before use to reduce their viscosity. Slow-set
emulsions, as a rule, can be readily diluted with clean water prior to use, for example as dust
palliatives, tack coats etc.
Rapid-set emulsions are not recommended for dilution as this renders them prone to
irreversible sedimentation in a very short period of time.
Emulsions, once diluted, should be used immediately and not stored.
Water must be added to the emulsion and not vice versa.
Dilution water must be clean and preferably potable. The water may require additives, for
example where hard water is used with some anionic systems. Speak to the supplier for
more detailed advice.
Product changeover
When changing products in a tank follow the appropriate changeover procedure. These are
outlined in section 7 of the Austroads Bituminous Materials Safety Guide (2014).
When considering what ‘clean’ means remember that cationic emulsions react with metal or
anti-rust coatings on new tank walls. If you clean all residue of bitumen off, the first emulsion
will break on the metal and may cause slugs. This is especially true for PME and CRS
emulsions but can also occur with CAM170 and CSS 170 emulsions.
For new storage tanks, problems can be avoided if they are first flushed with a weak
hydrochloric acid solution or diluted CRS soap solution immediately prior to use.
Do clean tanks, pipes, hoses and Don’t do regular small tank top-ups; run
equipment regularly. down tank contents to approx 40% then
refill.
Do inspect internals of emulsion storage
tanks annually to assess maintenance and Don’t suck back solvent into a tank as this
cleaning needs. will soften bitumen particles over time and
can create sludge, or adversely affect the
Do blow/clean out spray nozzles with properties of the residual binder.
compressed air or suitable cleaning agent
after spraying. Don't return diluted emulsion or any other
product into storage tanks.
Do apply gentle localised heating to clear
blockages. Avoid aggressive heating of Don’t ignore Emulsion Tank site
lines. housekeeping or maintenance.
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Storage and Handling Guide
Whilst HBCE & PME are spray between 80⁰C to 95°C burns can still be suffered so the
same precautions applied to hot binders should be adopted for HBCE and PME. Refer to the
Austroads Bituminous Materials Safety Guide (2014).
Storage life
The length that HBCE and PME can be stored varies significantly to Standard Emulsion, as
these types of Emulsion need to be stored at > 50⁰C.
Bulk Storage
Tank design
All regulatory and company engineering standards must be followed when designing and
constructing a tank.
The storage of HBCE and PME requires heated tanks ie Bitumen Tanks and therefore
require mild or stainless steel construction. It is recommended that the emulsion supplier be
consulted when selecting a tank.
AAPA recommends the following features be included:
Vertical tanks
Vertical tanks are the most suited style for the storage of
Bitumen as they
Example of a vertical
tank
Horizontal tanks
Horizontal tanks are commonly used but generally
not recommended because they present a larger
surface area to the air that can form a skin and it
can be more difficult to achieve adequate
circulation. Their use should be limited to short
term field storage.
Horizontal tanks are often less expensive than
vertical tanks. They may be set with a slight slope
to facilitate draining and circulation.
Tank safety
Used tanks must be thoroughly cleaned before use, for example by using steam or high
pressure water, and any chemical residues flushed from the tank.
Before cutting a used tank, for example for transportation or modification, ensures there is
no flammable product present.
Never cut a used tank unless an appropriate hot work permit is obtained.
Care is required when siting storage tanks, for example they should not be located near high
tension power lines. Where practicable, they should be located away from waterways.
Tank plumbing
Proper plumbing is very important, including:
Stirrers
o propeller stirrers operated at a low speed
o larger anchor sweep stirrers.
HBCE can use either Pump or Stirrers for circulation and the pipework needs to be an
independent system and should not be mixed with other tank farm products.
PME is best cared for with both Pump and Stirrers for circulation.
Do not over mix the emulsion. Mixing is generally only required once a week or for a short
time just before load out.
Tank inspections
Residue build-up inside a tank can reduce the storage life of an emulsion. Operators of sites
with bulk bituminous emulsion storage tanks should have a strategy for ensuring the storage
tank is kept free of excessive residue.
An annual inspection of the inside of the tank is highly recommended to determine the
volume and viscosity any residue in order to determine the best course of action required
clean the tank.
Only those with a confined spaces permit and the appropriate PPE should enter a tank.
Prior to changing over emulsion suppliers AAPA recommends that an inspection of the tank
is performed by the new supplier to determine what cleaning procedure will be required to
ensure the emulsion will not be adversely affected by the previous product.
Heating systems
Types of heating systems suitable for bitumen tanks include:
Rate of heating
Ensure that emulsion is not heated rapidly. The heating rate should not exceed 10°C per
hour as this implies excessively high heating surface temperatures. Exceeding this rate of
heating can cause flocculation of the bitumen droplets especially if it contains polymers
around the heating flues or electrical elements.
Pumps
Pumping/Circulation should only be undertaken once the product is at >80⁰c with warm/hot
binders best served with Positive Displacement Pumps (eg Gear or Vein Pumps)
Positive displacement pumps
Positive displacement pumps, such as rotating gear types, can shear the emulsion if pump
tolerance is tight. If purchasing a new pump request extra gear clearance of 0.08 to 0.1mm.
Alternatively, old or worn gear pumps may be suitable. The pump should be jacketed and
heated. A relief valve/bypass is essential.
References
Austroads. (2002) Guide to the Selection and Use of Bitumen Emulsions, Sydney
Austroads. (2014) Bituminous Materials Safety Guide, Sydney
Downer Group. (2013) Emulsion tank commissioning product sheet.
Downer Group. (2013) Emulsion tank inspection and cleaning product sheet.