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Procesos Con Gas Ideal

The document discusses thermodynamic processes involving ideal gases. It defines equations for changes in internal energy (ΔU), enthalpy (ΔH), and heat (q) for various processes including isothermal, isobaric, isochoric, and adiabatic. It also defines relationships between specific heats at constant pressure and volume (Cp and Cv) and provides the ideal gas law equations relating temperature, pressure, and volume.

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Alejandra Vergara
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13 views

Procesos Con Gas Ideal

The document discusses thermodynamic processes involving ideal gases. It defines equations for changes in internal energy (ΔU), enthalpy (ΔH), and heat (q) for various processes including isothermal, isobaric, isochoric, and adiabatic. It also defines relationships between specific heats at constant pressure and volume (Cp and Cv) and provides the ideal gas law equations relating temperature, pressure, and volume.

Uploaded by

Alejandra Vergara
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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∆𝑈 = 𝑞 + 𝑤 Procesos con gas ideal

𝑤 = − ∫ 𝑝𝑑𝑉
Proceso isotérmico T constante
𝑖
𝑇𝑓
𝑉𝑓

𝑞 = ∆𝑈 − 𝑤 = ∆𝑈 + ∫ 𝑝𝑑𝑉 ∆𝑈 = 𝑛 ∫ 𝐶𝑣 𝑑𝑇 = 0
𝑇𝑖
𝑉𝑖
𝑇𝑓
∆𝑈 = 𝑞𝑣
∆𝐻 = 𝑛 ∫ 𝐶𝑝 𝑑𝑇 = 0
∆𝐻 = 𝑞𝑝 𝑇𝑖
𝑇𝑓 𝑓

∆𝐻 = 𝑛 ∫ 𝐶𝑝 𝑑𝑇 𝑞 = −𝑤 = ∫ 𝑝𝑑𝑉
𝑇𝑖 𝑖
𝑇𝑓 𝑉𝑓
𝑑𝑉 𝑉𝑓
∆𝑈 = 𝑛 ∫ 𝐶𝑣 𝑑𝑇 𝑤 = −𝑛𝑅𝑇 ∫ = −𝑛𝑅𝑇 ln
𝑉 𝑉𝑖
𝑇𝑖 𝑉𝑖

∆𝐻 = 𝑛𝐶𝑝 (𝑇𝑓 − 𝑇𝑖 ) 𝑃𝑖
𝑞 = −𝑤 = 𝑛𝑅𝑇 ln
𝑃𝑓
∆𝑈 = 𝑛𝐶𝑣 (𝑇𝑓 − 𝑇𝑖 )
Proceso isobárico p constante
𝜕𝐻
𝐶𝑝 = ( ) 𝑇𝑓
𝜕𝑇 𝑝
𝑞𝑝 = ∆𝐻 = 𝑛 ∫ 𝐶𝑝 𝑑𝑇
𝜕𝑈
𝐶𝑣 = ( ) 𝑇𝑖
𝜕𝑇 𝑉
𝑇𝑓
𝐶𝑝 − 𝐶𝑣 = 𝑛𝑅 (𝑔𝑎𝑠 𝑖𝑑𝑒𝑎𝑙)
∆𝑈 = 𝑛 ∫ 𝐶𝑣 𝑑𝑇
𝑇𝑖

𝑤 = −𝑝∆𝑉
Proceso Isocórico V constante
𝑇𝑓

𝑞𝑣 = ∆𝑈 = 𝑛 ∫ 𝐶𝑣 𝑑𝑇
𝑇𝑖

𝑤=0
𝑇𝑓

∆𝐻 = 𝑛 ∫ 𝐶𝑝 𝑑𝑇
𝑇𝑖

Proceso Adiabático

𝑞=0

∆𝑈 = 𝐶𝑉 (𝑇𝑓 − 𝑇𝑖 ) = 𝐶𝑉 ∆𝑇
1⁄𝑐
𝑉𝑖
𝑇𝑓 = 𝑇𝑖 ( )
𝑉𝑓
𝛾
𝑉𝑖
𝑝𝑓 = ( ) × 𝑝𝑖
𝑉𝑓
𝐶𝑝
𝛾=
𝐶𝑉
Gas ideal

∆𝐻 = ∆𝑈 + ∆𝑛𝑅𝑇
Termoquímica

∆𝐻𝑟∅ = ∑ ∅
𝜈𝐻𝑚 − ∑ ∅
𝜈𝐻𝑚
𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠

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