SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
Not for sale in the USA
Ensure that this SDS is received by the appropriate person
Section 1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
1.1 Product identifier
Trade name BOC THORIATED 2% TUNGSTENS
Article-no Product/Article Diameter(mm) Packaging (pk/ea) Part Number
1.6 10 68616
BOC TUNGSTENS 2% THORIATED Red
2.4 10 68617
3.2 10 68618
1.2 Relevant identified uses of the substance or mixture and uses advised against
Article type GTAW (TIG) Gas tungsten arc welding ISO 6848
Use Gas shielded Arc welding
1.3 Details of the supplier of the safety data sheet
Supplier BOC Limited
Street address Customer Service Centre, Priestley Road,
Worsley, Manchester, M28 2UT,
United Kingdom
Telephone +44 (0)800 111 333
Fax +44 (0)800 111 555
Email
[email protected]1.4 Emergency telephone number
Available outside office hours Yes
Emergency phone number +44 (0)800 111 333
Other
Additional product information Web site www.BOConline.co.uk
Section 2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) 1271/2008 [CLP] applicable
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
2.2 Label elements
Not applicable
2.3 Other hazards
Note: When preparing (grinding) and using these electrodes as part of the welding process additional potential hazards are likely:
Grinding:
Toxic dusts. Ensure adequate dust extraction, ventilation and dust disposal
When the product is used in the welding process the most important hazards are:
Overexposure to fumes and gases from welding can be dangerous to health.
Watch out for splatter, hot metal and slag. It may cause skin burn and cause fire.
Arc rays can injure eyes and burn skin. Electric shock can kill. Avoid touching live electrical parts.
Section 3. COMPOSITION / INFORMATION ON INGREDIENTS
3.1 Substances
This product is a mixture and please refer to Section 3.2
3.2 Mixtures
W (min.) ThO2 Impurities mass
ISO 6848 Classification %
% %
CAS Number 7440-33-7 1314-20-1
WTh 20(Red) Balance 1.7-2.2 0.5 max
Substance CAS Number EG number REACH Reg Concentration Classification Remarks
name Number (%) Hazard R-phrases
attribute
Tungsten 744-33-7 231-143-9 01- >95.8 R11 R11 affects only
2119488910- powder/dust
30-0003
Thorium oxide 1314-20-1 215-225-1 0.8 – 4.2 radioactive R45- Substance
23/24/25-33 affected by
96/29/Euratom.
Section 4. FIRST AND MEASURES
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
4.1 Description of first aid measures
Inhalation IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing. Call a physician if symptoms occur.
Skin contact Burns should be treated by a doctor.
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Burns from radiation, see doctor.
Ingestion Contact a doctor if more than an insignificant amount has been swallowed.
4.2 Most important symptoms and effects, both acute and delayed
Inhalation Inhalation of vapours may cause irritation of the respiratory system in very susceptible persons.
4.3 Indication of any immediate medical attention and special treatment needed
Pulmonary irritation.
In the case of lung irritation: Primary treatment by using Corticoide spray, e.g. Auxiloson spray,
Pulmicort-dosage-spray ( Auxiloson and Pulmicort are registered trademarks).
Section 5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media Carbon dioxide (CO2), powder or diffuse jet of water. In case of major fire: Extinguish fire with
diffuse jet of water or foam.
5.2 Special hazards arising from the substance or mixture
Low radioactive product
5.3 Advice for fire fighters
Special protective equipment for fire Wear self contained breathing apparatus
fighters
Section 6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
General ventilation and local fume extraction must be adequate to keep fume concentrations within safe limits. Use respiratory equipment
when welding in a confined space. Wear protective clothing and eye protection appropriate to arc welding. Skin contact should be avoided to
prevent possible allergic reactions.
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
6.2 Environmental precautions
Try to prevent the material from entering drains or water courses. Waste, dust filters and recipients are to de disposed of in a safe and secure
way, according to respective national regulations in force. Grey washing or grinding water is to be captured and disposed of.
6.3 Methods and material for containment and cleaning up
Not applicable
6.4 Reference to other sections
For Personal protection see section 8. For Disposal see section 13. For Environmental precautions see section 12. For Precautions for safe
handling see 7.1.
Section 7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Preventive handling precautions Ensure adequate ventilation for the welder and others. Use respiratory equipment when welding in
a confined space. Wear protective clothing and eye protection appropriate to arc welding. Remove
all flammable materials and liquids before welding.
General hygiene Wash hands before breaks and immediately after handling the product.
7.2 Conditions for safe storage, including any incompatibilities
Store welding consumables inside a room without humidity. Do not store welding consumables directly on the ground or beside walls. Store
away from chemical substances like acids which could cause chemical reactions.
7.3 Specific end use(s)
Welding process.
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
WEL1 STEL²
Welding fume component CAS No. 8hr 15min
TWA TWA
Tungsten and compounds (as W)
Soluble 7440-33-7 1
Insoluble 5
Thorium compounds (as Th) 7440-29-1
Nitrogen dioxide (NO2 ) 10102-44-0 0.5 ppm³ 0.95ppm³
Ozone (O3) 10028-15-6 0.2 ppm⁴
Nitrogen monoxide (NO) 10102-43-9 0.5ppm³ 0.63ppm³
1
WEL Workplace exposure Limits
2
STEL Short term exposure limit
3
As recommended by MAK Commission based on scientific experience and is not established law
4
As recommended by EH40 (2004) in the UK
8.1.1 Exposure limit values Germany
Dust exposures TRGS 900
Radiation exposure: Product not listed in TRGS 905. The following dose limits apply for effective
dose in calendar year:
No person at “work”, who are not exposed to radiation work 6mSv
For persons, who are exposed to radiation during work 20mSv
For the complete dose as a consequence of the profession 400mSv
For persons under 18 years of age 6mSv
8.2 Exposure controls
Environmental Exposure Controls – Refer to Section 6 of this SDS
Technical precaution measures General ventilation and local fume extraction must be adequate to keep fume concentrations
within safe limits.
Eye / face protection Wear eye protection appropriate for welding.
Safety gloves Skin contact should be avoided to prevent possible allergic reactions.
Other skin protection Wear body protection which helps to prevent injury from radiation, sparks and electric shock.
Respiratory protection Use respiratory equipment when welding in a confined space. Wear protective clothing and eye
protection appropriate to arc welding.
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance, colour Grey
Appearance, physical state Rod
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
Auto-ignition temperature Not applicable
Auto-inflammability Not auto-flammable
Decomposition temperature Not applicable
Evaporation rate Not applicable
Explosive properties Not explosive
Flammability (solid gas) Not applicable
Flash point Not applicable
Form Fast
Initial boiling point and boiling range Not applicable
Melting point / Freezing point Not applicable
Odour Odourless
Odour threshold Not applicable
Oxidising properties Not applicable
Partition coefficient: n-octanol / water Not applicable
pH value Not applicable
Relative density Not applicable
Solubility Not applicable
Solubility in water Insoluble
Upper / lower flammability or Not applicable
explosive limits
Vapour density Not applicable
Vapour pressure Not applicable
Viscosity Not applicable
9.2 Other information
Not applicable
Other
Density 18.5 to 19.0 g/cm3
Section 10. STABILITY AND REACTIVITY
10.1 Reactivity
Not applicable
10.2 Chemical stability
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
Stable at normal conditions.
10.3 Possibility of hazardous reactions
Not applicable
10.4 Conditions to avoid
None under normal conditions
10.5 Incompatible materials
Contact with strong acids and/or bases; or with halogens (fluorine, chlorine, bromine, iodine and
their compounds); or with oxidising agents (e.g. Perchlorate, peroxide, permanganate,chlorates,
nitrates, nitrites, chromates); or with alkali/earth alkali metals (e.g. lithium, sodium, potassium,
magnesium, calcium) can cause strong reactions( danger of strong exothermal reactions, dange
of formation of flammable gases, danger of formation of insalubrious/poisonous
substances/gases) must be avoided.
10.6 Hazardous decomposition products
Emerge through oxidation oxids of the product which can evaporate (tungsten trioxide WO3 CAS 1314-35-8) or
be released (thorium oxide ThO2 CAS 1314-20-1)
Welding fumes and gases. Additional fume may arise from coatings and contaminants on the base material.
Classification CLP (1272/2008) Concentration of
Welding fume
CAS No. (67/548EEC) classified fume
component
components
Tungsten and its - - - >95.8
7440-33-7
compounds (W)
R23/24/25: Toxic by Acute Tox 3 H331 0.8 to 4.2
inhalation, in contact with H311
skin & if swallowed H301
Thorium oxide (ThO2) 1314-20-1
R45: May cause cancer Carc. 1B H350
R33: Danger of STOT RE 2 H373
cumulative effect
Classification H phrase Text
Acute Tox.: H302 Harmful if swallowed
Category 4
H312 Harmful in contact with skin
H332 Harmful if inhaled
Carcinogenicity: H350 May cause cancer
Category 1B
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
The classification information above relates to the fume during use.
Section 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Conditions to avoid: none in the form supplied
When welding, fumes and gases generated can be dangerous to health.
Acute toxicology This product does not feature an acute oral, dermal toxicity or toxicity through inhalation
Irritation Not applicable
Corrosive effects Not applicable
Sensitisation May cause sensitisation by skin contact
Mutagenicity Not applicable
Carcinogenicity Welding fumes are possibly carcinogenic to humans
Repeated dose toxicity Finding after intratracheal application of 50mg tungsten dust per week during 3 weeks on guinea pigs
lead to the conclusion that the substance is relatively inert. Still an effect on the pulmonary tissue
could be proved which must not be neglected.
Reproductive toxicity Not applicable
Section 12. ECOLOGICAL INFORMATION
12.1 Toxicity
The welding process can effect the environment if fume is released directly into the atmosphere.
LC50 Fish 96h:
15.6mg/L (rainbow trout, oncorhynchus mykiss,28d)
Aluminiumoxide: >100 mg/l Salmo trutta
IC50 Amphibians 72h:
2.9mg/L (toad,gastrophryne carolinensis, 7d)
12.2 Persistence and degradability
Tunsten forms a series of oxohalogenides (e.g. WOCL4 )
12.3 Bio accumulative potential
No data vailable
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
12.4 Mobility in Soil
Not applicable
12.5 Results of PBT and vPvB assessment
Not applicable
12.6 Other adverse effects
Not applicable
Section 13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Disposal considerations Dispose of any product, residue or packing material according to national and local regulations. Spent
;fume extraction filters shall be disposed of as dangerous waste.
Other
Waste code (EWC) 12 01 13 – welding waste
12 01 04 – non-ferrous metal dust and particles
Section 14. TRANSPORT INFORMATION
14.1 UN number
Land transport (ADR/RID/GGVSEB) UN 2909: radioactive substances, released package, products made of natural thorium; class 7; LQ not
possible
Sea transport (IMDG-Code/GGVSee)
UN 2909: radioactive substances, released package, products made of natural thorium; class 7; LQ not
Air transport (ICAO-TI/IATA-DGR) possible; EmS: F-I, S-S: pack up category A
UN 2909: radioactive substances, released package, products made of natural thorium; class 7; LQ not
possible
Section 15. REGUATORY INFORMATION
15.1 Safety, health and environmental regulations / legislation specific for the substance or mixture.
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SAFETY DATA SHEET
TE002 Tungsten Electrodes (Thoriated)
Version number: 2
Replaces SDS: 2009-11-23
Issued: 2014-01-21
EU regulations 67/548/EWF idgF (Dangerous Substances)
99/45/EG idgF ( Dangerous Preparations regulations)
96/29/Euratom (only affecting thorium oxide)
Labelling 215-225-1
National regulations EH40/2005 Workplace exposure limits
The Waste Regulations 2011 No. 988
Local laws and regulations should be carefully observed.
15.2 Chemical safety assessment
No data available
Section 16. OTHER INFORMATION
References to key literature and Regulation (EC) No 1907/2006 of the European Parliament and of the Council, (REACH).
data sources Regulation (EC) No 1272/2008 of the European Parliament and of the Council.
EH40/2005 Workplace exposure limits.
The Waste regulations 2011 No.988
C&L Inventory database
Annex VI CLP Regulation (EC) 1272/2008
Phrase meaning
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H350 May cause cancer.
Other
Manufacturer’s notes Read this Safety Data Sheet carefully and become aware of hazards implied and the safety
information.
End of Document
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