Tutorial 1 Ans
Tutorial 1 Ans
Tutorial No:1
Q.1 Show that the effective density of states (N C) represents the density of
states in a strip 1.2 kT wide near the edge of the conduction band.
3 EC + ∆ E ( EC + ∆ E )
2π kTme* 2
4π
Ans : NC = = ∫ = ∫ (2 me* ) 2 ( E − Ec ) 2 dE
3 1
2 ÷ g ( E ) dE
h
2
EC EC
h3
( Ec + ∆ E )
( EC + ∆ E )
4π ( E − Ec )
3
4π 2
= ∫ =
3
( E − Ec )
3 1
(2 me* ) 2 2
dE (2me* ) 2
h3 EC h3
3
2 Ec
4π 2
= × (2 me* ) 2 × ( ∆E ) 2
3
×
3
h3 3
3
2 ∆E 2 3
Thus, = × (∆E) 2 Or,
3
2 (π kT ) 4π × ÷ =
3
2
3 π kT 4π
2
3 3
Therefore, ∆E = ÷ π kT
4π
=1.2kT
[Message : Only states which are very close to E C in the conduction band will be
occupied. Similarly holes will only occupy states very close to the top of valence
band]
Q:2 In a semiconductor sample, donor and acceptor levels are 0.3eV apart
from each other. If 80% of the acceptors are ionized at 300K, evaluate the
fraction of ionized donors. If the donor level is 2kT below the conduction band
edge, determine the position of Fermi level.
Ans:
1
ηA = EA − EF
1 + 2 exp ÷
= 0.8
kT
1
÷−1
Or, E A − EF 0.8
exp ÷=
= 0.125
kT 2
Q: 3 Silicon wafers are doped with (i) 1015 (ii) 1018 arsenic atoms / cm3. Show
whether the assumption of complete ionization is justified in each case at
temperatures of 100K and 300K. Arsenic introduces a donor level E D
0.049 eV below EC.
(a) At T = 100 K
Since NC α T3/2, at 100 K, NC = 2.8 x 10
100 3 2
19
×(
300
)
= 5.3886 x 1018 / cm3
Also, kT = 0.026/3 = 0.008667eV
For ND1 = 1015 atoms / cm3
2 2
= x 100%
ηD1= 1+ 1+
8 N D1 E
exp ion ÷ 1+ 1+
8 x 1015 0.049
exp ÷
= 91.19 %
NC kT 5.3886 x 1018 0.008667
2 2
= x 100%
ηD1 = 1+ 1+
8 N D1 E
exp ion ÷ 1+ 1+
8 x 10 15
0.049
exp ÷
= 99.95%
NC kT 2.8 x 1019 0.026
[ Message : For lightly doped (~10 15 atoms / cm3) silicon, ionization is almost
complete at room temperature. However, for heavy doping (~1018 atoms / cm3), there
is only partial ionization at room temperature]
Taking NA = 1016 atoms / cm3 and NV = 1 x 1019 / cm3 (value at 300K) and ηA = 0.5,
we have
2
0.5 = 8 × 1016 0.16
1+ 1+
8 × 1016 0.16
exp ÷
Or, 1+
1 × 1019
exp
kT
÷ =3
1 × 1019 kT
(b) For Boron, Eion = 0.045 eV, T = 267 K, NA = 1016 /cm3, NV ≈ 1 × 1019 / cm3
2
× 100%
ηA = 1+ 1+
8 × 1016
exp
0.045
÷
= 98.64%
−5
1 × 1019 8.667 × 10 × 267
NC N D E
Q.5 Assuming n = ND+, show that at very low temperature n=
2
exp − ion ÷
2 kT
.
Hence show that is this temperature range, the Fermi level is an n-type
EC + E D kT 2NC
semiconductor is given by EF =
2
−
2
ln
ND
÷ .
Also find EF at 0K
E − EF
(a) n = N C exp − C
kT
(1)
1 1
ηD = ≈
EF − ED
1 + 2 exp
EF − E D
÷ 2 exp ÷
at very low temperatures
kT kT
ND
∴ n = η D ND =
E F − ED
2 exp ÷
(2)
kT
NC N D E
Or, n=
2
exp − ion ÷
2 kT
2 NC − ( E F − ED ) −( EC − E F ) 2 NC E + ED − 2 E F
Or, ND
= exp
kT
−
kT
Or, ND
= exp C
kT
E + ED kT 2 NC
∴ EF = C ÷− ln ÷
2 2 ND
Ans (a) n=
D D
Taking N D+ = N D and N A− = 0
ND + + 4 ni2 ND 4ni2
2 2
ND ND ND
n= = + + ni2 = 1 + 1+ 2
2 2 4 2
ND
2ni
2
ND
Therefore n=
2
1+ 1+ ÷
ND
(b) At T = Ti, N = ni
− Eg Eg
Or, N = ni = Nc Nv exp ÷ Or, 2kTi
= ln ( Nc N v N )
2kT
Ti Eg
=
Therefore, To 2kTo ln Nc Nv N ( )
Eg
Ti =
(c) 2k ln ( N C NV N )
For Si, Eg = 1.1eV, Nc = 2.8 x 1019 / cm3, Nv = 1 x 1019 / cm3 and N = 1 x 1015 / cm3
1.1
Ti =
2.8 × 1019 × 1019 = 653 K
2 × 8.667 × 10− 5 ln ÷
1015 ÷
For Ge, Eg = 0.67eV, Nc = 1 x 1019 / cm3, Nv = 6 x 1018 / cm3 and N = 1 x 1015 / cm3
0.67
Ti =
1× 1019 × 6 × 1018 = 357 K
2 × 8.667 × 10 − 5 ln ÷
1015 ÷
Q.7 Draw the energy band diagram of silicon doped with 10 15 arsenic
atoms/cm3 at 77K, 300K and 600K showing the Fermi level?
0.026
(a) At 77K, kT = 300
× 77 = 6.67 × 10 −3 eV
77 3 2
N C = 2.8 × 1019 × (
300
) = 3.64×1018/cm3
2 2
ηD = =
1+ 1+
8N D E
exp ion ÷ 1+ 1+
8 × 1015 0.049
exp ÷
= 0.3226
NC kT 3.64 × 1018 0.00667
E − EF
n= ηD × N D = 3.226×1014/cm3 and n = N C exp − C
kT
NC 3.64 × 1018
Therefore EC − E F = kT ln
n
÷ = 0.00667 ln 14 ÷
3.226 × 10
= 0.0622eV
− Eg −1.1
ni = Nc Nv exp ÷= 7.92 × 2.828 × 1019 exp ÷ = 1.21× 10 / cm
15 3
2kT 0.104
2 N D 2 10 15
n 1.81
Therefore EF − Ei = kT ln ÷ = 0.052 ln
ni
÷ = 0.021eV
1.21
[ Message : At very low temperature the Fermi level is close to the band edge. With
increase in temperature, the Fermi level moves towards the middle of the bandgap]
Q.8 A silicon wafer is doped with 2 x 1016 boron and 1016 phosphorus atoms/
cm3. Calculate n, p, EF at room temperature, assuming complete
ionization. Repeat the same for 8 x 1015 boron atoms / cm3?
− + − + 2
(N A − N D ) + ( N A − N D ) 2 + 4 ni
p= ≈ (NA – ND) = 1 x 1016 / cm3
2
ni 2
(1.5 × 1010 ) 2
n= = (1 × 1016 ) = 2.25 x 104 / cm3
p
p 1016
EF = Ei − kT ln ÷ = Ei − 0.026 ln 10 ÷
= Ei − 0.349eV
ni 1.5 × 10
(1.5 × 1010 )
2
ni2
p= = = 1.125 × 105 / cm 3
n 2 × 1015
n 2 × 1015
EF = Ei + kT ln ÷ = Ei + 0.026 ln 10 ÷
= Ei + 0.307eV
n
i 1.5 × 10