Lesson Plan: Lesson: Zero Order Reaction
Lesson Plan: Lesson: Zero Order Reaction
Aim :
Learning Outcomes :
1. explain the terms rate equation, rate constant and order of reaction.
3. state the integrated form of the rate equation for a zero order reaction.
1. be familiar with the concept that the concentration of reactants decreases with
time during the course of a chemical reaction.
2. know how to derive the instantaneous rate of reaction from the concentration-time
graph.
Underlying Principles
Differentiation
Questions in the student notes are designed to enable all students to complete the activity.
The pop-up answers are provided for the students to view when they have considered their
responses. Worksheet questions include questions that require recall, understanding and
application of the new concepts learned.
1. Order of Reaction
b. rate = k[N2O4]n
where k = rate constant and n = order of reaction.
c. The rate equation relates the rate of a reaction to the concentration of the
reactants. The value n in the rate equation shows exactly how the rate is
affected by the concentration of the reactants.
b. rate = k[X]0
2.2 a. To slow the reaction down so that the change in the concentration of iodine in
the sample is small or insignificant.
b.
19
18
2-/cm3 3
2O33 /cm
17
2-
S 2O
16
of S
Volumeof
15
Volume
14
13
12
0 5 10 15 20 25 30
Time/min
(17.0-14.0) mol dm -3 3. 0
i. Gradient of graph = − =
(20-10 ) min 10
-3 -1
= 0.3 mol dm min
ii. No change.
Time/min
b. Zero order with respect to X. The gradients of the two lines obtained are
constant throughout the experiment. This shows that the rates of the reaction
are independent of the concentration of X.
c. The gradient of the graph obtained at [Y] = 2.0 mol dm-3 is two times greater
than at [Y] = 1.0 mol dm-3. Thus, the rate of the reaction is doubled when the
concentration of Y is doubled.